KR100663887B1 - Water-soluble supramolecular platinum complexes and process for preparation thereof - Google Patents

Water-soluble supramolecular platinum complexes and process for preparation thereof Download PDF

Info

Publication number
KR100663887B1
KR100663887B1 KR1020040035183A KR20040035183A KR100663887B1 KR 100663887 B1 KR100663887 B1 KR 100663887B1 KR 1020040035183 A KR1020040035183 A KR 1020040035183A KR 20040035183 A KR20040035183 A KR 20040035183A KR 100663887 B1 KR100663887 B1 KR 100663887B1
Authority
KR
South Korea
Prior art keywords
platinum
water
ptcl
soluble
poly
Prior art date
Application number
KR1020040035183A
Other languages
Korean (ko)
Other versions
KR20050110238A (en
Inventor
게켈러케이이
박지용
Original Assignee
광주과학기술원
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 광주과학기술원 filed Critical 광주과학기술원
Priority to KR1020040035183A priority Critical patent/KR100663887B1/en
Publication of KR20050110238A publication Critical patent/KR20050110238A/en
Application granted granted Critical
Publication of KR100663887B1 publication Critical patent/KR100663887B1/en

Links

Images

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B60—VEHICLES IN GENERAL
    • B60L—PROPULSION OF ELECTRICALLY-PROPELLED VEHICLES; SUPPLYING ELECTRIC POWER FOR AUXILIARY EQUIPMENT OF ELECTRICALLY-PROPELLED VEHICLES; ELECTRODYNAMIC BRAKE SYSTEMS FOR VEHICLES IN GENERAL; MAGNETIC SUSPENSION OR LEVITATION FOR VEHICLES; MONITORING OPERATING VARIABLES OF ELECTRICALLY-PROPELLED VEHICLES; ELECTRIC SAFETY DEVICES FOR ELECTRICALLY-PROPELLED VEHICLES
    • B60L5/00—Current collectors for power supply lines of electrically-propelled vehicles
    • B60L5/18—Current collectors for power supply lines of electrically-propelled vehicles using bow-type collectors in contact with trolley wire
    • B60L5/22—Supporting means for the contact bow
    • B60L5/24—Pantographs
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B60—VEHICLES IN GENERAL
    • B60M—POWER SUPPLY LINES, AND DEVICES ALONG RAILS, FOR ELECTRICALLY- PROPELLED VEHICLES
    • B60M1/00—Power supply lines for contact with collector on vehicle
    • B60M1/12—Trolley lines; Accessories therefor
    • B60M1/13—Trolley wires
    • B60M1/135—Trolley wires composite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B60—VEHICLES IN GENERAL
    • B60L—PROPULSION OF ELECTRICALLY-PROPELLED VEHICLES; SUPPLYING ELECTRIC POWER FOR AUXILIARY EQUIPMENT OF ELECTRICALLY-PROPELLED VEHICLES; ELECTRODYNAMIC BRAKE SYSTEMS FOR VEHICLES IN GENERAL; MAGNETIC SUSPENSION OR LEVITATION FOR VEHICLES; MONITORING OPERATING VARIABLES OF ELECTRICALLY-PROPELLED VEHICLES; ELECTRIC SAFETY DEVICES FOR ELECTRICALLY-PROPELLED VEHICLES
    • B60L2200/00—Type of vehicles
    • B60L2200/30—Trolleys
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B60—VEHICLES IN GENERAL
    • B60Y—INDEXING SCHEME RELATING TO ASPECTS CROSS-CUTTING VEHICLE TECHNOLOGY
    • B60Y2200/00—Type of vehicle
    • B60Y2200/30—Railway vehicles
    • B60Y2200/31—Locomotives
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T30/00—Transportation of goods or passengers via railways, e.g. energy recovery or reducing air resistance

Abstract

본 발명은 초고분자 백금 착화합물(water-soluble supramolecular platinum complexes) 및 그 제조방법에 관한 것으로, 본 발명에 따라 사염화백금칼륨염(potassium tetrachloroplatinate, K2(PtCl4))과 폴리(옥시알킬렌)기를 가진 알킬아민(poly(oxyalkylene)alkylamine)을 반응시켜 합성한 사아민화백금 착이온([Pt(NH2R)4]2+)에 다시 K2(PtCl4)를 반응시켜 제조한 백금 착화합물은 수용성 및 우수한 반도체로서의 전기 전도성을 나타내므로, 생의학(biomedical) 및 반도체(semiconducting materials) 분야에서 산업적으로 유용하게 활용될 수 있다.The present invention relates to ultra-high molecular weight complex (water-soluble supramolecular platinum complexes) and a method for producing the same. According to the present invention, potassium tetrachloroplatinate (K 2 (PtCl 4 )) and poly (oxyalkylene) groups with an alkyl amine (poly (oxyalkylene) alkylamine) the Saha folk platinum complex ion synthesized by reacting ([Pt (NH 2 R) 4] 2+) again with K 2 platinum complex prepared by reacting (PtCl 4) is water-soluble And because it exhibits excellent electrical conductivity as a semiconductor, it can be usefully used industrially in the field of biomedical and semiconductor (semiconducting materials).

Description

수용성 초고분자 백금 착화합물 및 그 제조방법{WATER-SOLUBLE SUPRAMOLECULAR PLATINUM COMPLEXES AND PROCESS FOR PREPARATION THEREOF} Water-soluble ultra high-molecular platinum complex and its manufacturing method {WATER-SOLUBLE SUPRAMOLECULAR PLATINUM COMPLEXES AND PROCESS FOR PREPARATION THEREOF}             

도 1은 실시예 1에서 제조한 수용성 백금 착화합물(platinum complexes)의 열 중량 분석(thermogravimetric analysis) 결과이고, 1 is a result of thermogravimetric analysis of water-soluble platinum complexes prepared in Example 1,

도 2는 수용성 백금 착화합물의 UV-가시 분광 분석(UV-visible spectrum) 결과이고, 2 is a UV-visible spectrum of the water-soluble platinum complex (UV-visible spectrum) results,

도 3은 수용성 백금 착화합물의 퓨리에 전환 적외선 분광 분석(FT-IR) 결과이고, 3 is a Fourier transform infrared spectroscopy (FT-IR) result of the water-soluble platinum complex,

도 4는 수용성 백금 착화합물의 온도 역수(inverse temperature)에 따른 전도도(conductivity) 로그 그래프이다. 4 is a logarithmic conductivity graph of the water soluble platinum complex with the inverse temperature.

본 발명은 수용성 초고분자 백금 착화합물(water-soluble supramolecular platinum complexes) 및 그 제조방법에 관한 것이다.The present invention relates to water-soluble supramolecular platinum complexes and a method for preparing the same.

백금 착화합물은 백금 금속에 이온이나 분자가 배위결합한 백금 착이온을 포함하는 화합물을 의미하며, 최근에는 백금 착화합물의 항암효과 및 나노구조의 전도성으로 인하여 생의학 및 반도체 등의 여러 산업 분야에서 많은 관심의 대상이 되고 있다. Platinum complex compound refers to a compound containing a platinum complex ion in which ions or molecules are coordinated to a platinum metal. Recently, due to the anticancer effect and the conductivity of nanostructures, platinum complex compounds are of interest to many industries such as biomedical and semiconductors. It is becoming.

특히, 본 발명의 백금 착화합물 구조의 원조격인 마그너스 녹색 염(Magnus' green salt, [Pt(NH3)4][PtCl4])은 200년 전 처음으로 합성되었으며, Pt를 금속 주쇄(metallic main-chain)로 하여 자가 결합된 독특한 초분자 구조(self-assembled supramolecular structure)로 반-일차원 구조(quasi-one-dimensional structure)의 상대적으로 짧은 Pt-Pt 결합으로 반도체로서의 특성을 가진다. 그러나, [Pt(NH3)4][PtCl4] 및 이의 유도체인 [Pt(NH2CH3) 4][PtCl4]는 물 및 통상의 유기 용제에 불용성을 나타내었고, 이를 극복하기 위해 R로 헵틸(heptyl) 내지 테트라데실(tetradecyl) 범위의 알킬기를 포함하는[Pt(NH2R)4][PtCl4] 유도체들이 연구되었으나, Pt-Pt사이의 공간이 넓어짐으로 인해 녹색 염 고유의 성질을 잃고, 분홍색(pink salts)의 절연체가 되는 문제점이 발생하였다. 따라서, 이러한 물질들의 다양한 응용 가능성에도 불구하고 가공 및 산업화에 상당한 제약이 있어 왔다(M.Fontana 외, Chem. Mater., 14, 1730-1735, 2002).In particular, Magnus' green salt ([Pt (NH 3 ) 4 ] [PtCl 4 ]), which is a precursor of the platinum complex structure of the present invention, was synthesized for the first time 200 years ago. It is a unique self-assembled supramolecular structure that is self-assembled as a chain, and has a relatively short Pt-Pt bond of a quasi-one-dimensional structure. However, [Pt (NH 3 ) 4 ] [PtCl 4 ] and its derivatives [Pt (NH 2 CH 3 ) 4 ] [PtCl 4 ] showed insolubility in water and common organic solvents. Although derivatives of [Pt (NH 2 R) 4 ] [PtCl 4 ] containing alkyl groups in the range of heptyl to tetratradecyl have been studied, the nature of green salts is due to the widening of the space between Pt-Pt. The problem of losing the salt and becoming an insulator of pink salts occurred. Thus, despite the wide range of applications of these materials, there have been significant limitations in processing and industrialization (M. Fontana et al. , Chem. Mater. , 14, 1730-1735, 2002).

본 발명의 목적은 수용성이면서 반도체로서의 전도성이 우수한 백금 착화합 물 및 그 제조방법을 제공하는 것이다.An object of the present invention is to provide a platinum complex and a method for producing the same, which are water soluble and excellent in conductivity as a semiconductor.

상기 목적에 따라, 본 발명에서는 하기 화학식 1의 화합물을 반복단위로 가진 수용성 초고분자 백금 착화합물을 제공한다:In accordance with the above object, the present invention provides a water-soluble ultra-high molecular platinum complex having a compound of formula 1 as a repeating unit:

Figure 112004020880826-pat00001
Figure 112004020880826-pat00001

상기 식에서 R은 폴리(옥시알킬렌)기를 가진 C1 내지 C5 알킬아민의 잔기(moiety)를 의미한다.In the formula, R means a moiety of C 1 to C 5 alkylamine having a poly (oxyalkylene) group.

상기 다른 목적에 따라, 본 발명에서는 상기 수용성 백금 착화합물의 제조방법을 제공한다.According to another object, the present invention provides a method for producing the water-soluble platinum complex compound.

이하, 본 발명을 상세히 설명한다.Hereinafter, the present invention will be described in detail.

본 발명자들은 수용성이면서도 반도체로서의 전기 전도성이 우수한 백금 착 화합물([Pt(NH2R)4][PtCl4])을 개발하기 위해 예의 연구한 결과, 사염화백금칼륨염(potassium tetrachloroplatinate, K2(PtCl4))과 폴리(옥시알킬렌)기를 가진 알킬아민(poly(oxyalkylene)alkylamine)을 반응시켜 제조한 상기 화학식 1의 백금 착화합물이 수용성 및 우수한 반도체로써의 전기 전도성을 나타냄을 발견하였다.The present inventors have found that water-soluble, yet is excellent in electrical conductivity of platinum complex compound as the semiconductor ([Pt (NH 2 R) 4] [PtCl 4]) for example The results tetrachloride platinum potassium salt which to develop (potassium tetrachloroplatinate, K 2 (PtCl It was found that the platinum complex compound of Formula 1 prepared by reacting 4 )) with an alkylamine having a poly (oxyalkylene) group exhibits water solubility and electrical conductivity as an excellent semiconductor.

본 발명의 화학식 1의 수용성 백금 착화합물은 백금을 금속 주쇄(metallic main-chain)로 하여 사아민화백금 착(+)이온([Pt(NH2R)4]2+) 및 사염화백금 착(-)이온([PtCl4]2-)이 자가결합된 독특한 초분자 구조(self-assembled supramolecular structure)로 반도체로서의 전도성을 가지고 있으며, 특히, 사아민화백금 착이온에 존재하는 산소로 인해 우수한 수용성을 나타낸다. The water-soluble platinum complex compound of the formula (1) of the present invention comprises platinum tetraamine complex (+) ions ([Pt (NH 2 R) 4 ] 2+ ) and platinum tetrachloride complex (-) using platinum as a metallic main-chain. A unique self-assembled supramolecular structure in which ions ([PtCl 4 ] 2− ) are self-bonded, has conductivity as a semiconductor, and exhibits excellent water solubility due to the oxygen present in the platinum tetraamine complex ion.

본 발명에 따른 수용성 백금 착화합물은 하기 반응식 1 및 2와 같이 사염화백금칼륨염을 폴리(옥시알킬렌)기를 가진 알킬아민과 반응시켜 합성한 사아민화백금 착이온에 다시 사염화백금칼륨염을 반응시킴으로써 제조할 수 있다. The water-soluble platinum complex compound according to the present invention is prepared by reacting the platinum tetrachloride potassium ion with the platinum tetrachloride synthesized by reacting the platinum tetrachloride salt with an alkylamine having a poly (oxyalkylene) group as shown in Schemes 1 and 2 below. can do.

Figure 112004020880826-pat00002
Figure 112004020880826-pat00002

Figure 112004020880826-pat00003
Figure 112004020880826-pat00003

상기 반응식 1 및 2에서 R은 폴리(옥시알킬렌)기를 가진 알킬아민의 잔기이다.R in Schemes 1 and 2 is the residue of an alkylamine having a poly (oxyalkylene) group.

구체적으로, 화학식 1의 수용성 초고분자 백금 착화합물을 제조하기 위하여, 본 발명에서는 상기 반응식 1에서와 같이, 화학식 2의 사염화백금칼륨염(potassium tetrachloroplatinate, K2(PtCl4))과 폴리(옥시알킬렌)알킬아민을 반응시켜 화학식 3의 사아민화백금 착이온([Pt(NH2R)4]2+)을 얻은 후, 상기 반응식 2에서와 같이, 생성된 [Pt(NH2R)4]2+에 다시 K2(PtCl4)를 반응시키는 과정을 포함한다.Specifically, in order to prepare a water-soluble ultra-high molecular platinum complex of formula (1), in the present invention, as shown in Scheme 1, potassium tetrachloride potassium salt of formula (K 2 (PtCl 4 )) and poly (oxyalkylene) ) To react the alkylamine to obtain a platinum tetraamine complex ion ([Pt (NH 2 R) 4 ] 2+ ) of Chemical Formula 3, and then to produce [Pt (NH 2 R) 4 ] 2 And reacting K 2 (PtCl 4 ) to + again.

이때, 반응식 1의 과정에서 사용되는 폴리(옥시알킬렌)기를 가진 알킬아민은 하기 화학식으로 나타낼 수 있다:At this time, the alkylamine having a poly (oxyalkylene) group used in the process of Scheme 1 can be represented by the following formula:

Figure 112004020880826-pat00004
Figure 112004020880826-pat00004

상기 식에서 R1 및 R2는 각각 독립적으로 C1 내지 C5의 선형 또는 분지형 알킬렌, W는 H 또는 NH2, n은 2 내지 50의 정수이며, 이때, 상기 반복단위 내 R2는 서로 동일하거나 다를 수 있다. Wherein R 1 and R 2 are each independently C 1 to C 5 linear or branched alkylene, W is H or NH 2 , n is an integer of 2 to 50, wherein R 2 in the repeating unit It can be the same or different.

상기 폴리(옥시알킬렌)기를 가진 알킬아민의 구체적 예로는

Figure 112006010585830-pat00005
,
Figure 112006010585830-pat00006
(R은 H 또는 CH3) 또는
Figure 112006010585830-pat00007
(a＋b＋c는 2 내지 50의 정수)등이 있다.Specific examples of the alkylamine having the poly (oxyalkylene) group include
Figure 112006010585830-pat00005
,
Figure 112006010585830-pat00006
(R is H or CH 3 ) or
Figure 112006010585830-pat00007
(a + b + c is an integer of 2 to 50) and the like.

상기 착이온 형성 반응에 사용되는 사염화백금칼륨염:폴리(옥시알킬렌)아민의 몰비는 1:1 내지 1:10 범위, 바람직하게는 1:2 내지 1:4 범위일 수 있으며, 반응은 50 내지 60℃, 바람직하게는 55℃에서 10 내지 30시간, 바람직하게는 22 내지 24시간 동안 수행할 수 있다.The molar ratio of platinum tetrachloride potassium: poly (oxyalkylene) amine used in the complex ion formation reaction may be in the range of 1: 1 to 1:10, preferably in the range of 1: 2 to 1: 4, and the reaction is 50 To 60 ° C., preferably 55 ° C., for 10 to 30 hours, preferably 22 to 24 hours.

또한, 반응식 2의 과정에서, 생성된 [Pt(NH2R)4]2+에 추가로 첨가하는 K2(PtCl4)의 양은, 반응식 1의 과정에서 사용된 K2(PtCl4) 몰 대비 0.5 내지 4배, 바람직하게는 1 내지 2배로 사용할 수 있으며, 이때 반응은 20 내지 30℃, 바람직하 게는 25℃에서 10 내지 50시간, 바람직하게는 20 내지 40시간 동안 수행할 수 있다.In addition, in the process of Scheme 2, the amount of K 2 (PtCl 4 ) added to [Pt (NH 2 R) 4 ] 2+ additionally, compared to the mole of K 2 (PtCl 4 ) used in the process of Scheme 1 0.5 to 4 times, preferably 1 to 2 times can be used, wherein the reaction can be carried out at 20 to 30 ℃, preferably 25 ℃ 10 to 50 hours, preferably 20 to 40 hours.

본 발명을 이하 실시예에 의해 상세히 설명한다.The invention is illustrated in detail by the following examples.

단, 하기 실시예는 본 발명을 예시하는 것일 뿐, 본 발명의 내용이 하기 실시예에 한정되는 것은 아니다.However, the following examples are merely to illustrate the invention, but the content of the present invention is not limited to the following examples.

<실시예 1><Example 1>

50 ㎎(0.12 mM)의 K2(PtCl4)를 10 ㎖의 물에 녹여 55℃에서 교반한 후, 이 용액에 59 ㎕(0.24 mM)의 폴리(옥시프로필렌)이소프로필디아민(poly(oxypropylene)isopropyldiamine)을 첨가하여 55℃에서 24시간 동안 교반하면서 반응시켜 사아민화백금 착이온([Pt(NH2R)4]2+)을 생성시켰다. 이 반응생성물에 0.12 mM K2 (PtCl4) 10 ㎖을 첨가한 다음, 100 ㎖의 탈 이온수(deionized water)와 혼합시켜 한외(限外) 여과 셀(ultrafiltration cell)로 옮겼다. 이를 상온에서 24시간 동안 교반하면서 막(membrane)을 이용한 여과로 반응하지 않은 폴리머 및 불순물을 제거하였다. 여과 후, 생성된 용액은 동결건조(freeze-dry)로 물을 제거시켜 본 발명에 따른 수용성 백금 착화합물([Pt(NH2R)4][PtCl4])을 제조하였다. 50 mg (0.12 mM) of K 2 (PtCl 4 ) was dissolved in 10 ml of water, stirred at 55 ° C, and then 59 µl (0.24 mM) of poly (oxypropylene) isopropyldiamine (poly (oxypropylene)) in this solution. isopropyldiamine) was added and reacted with stirring at 55 ° C. for 24 hours to produce platinum tetraamine complex ion ([Pt (NH 2 R) 4 ] 2+ ). 10 ml of 0.12 mM K 2 (PtCl 4 ) was added to the reaction product, which was then mixed with 100 ml of deionized water and transferred to an ultrafiltration cell. This was stirred for 24 hours at room temperature to remove unreacted polymer and impurities by filtration using a membrane (membrane). After filtration, the resulting solution was freeze-dryed to remove water to prepare a water-soluble platinum complex ([Pt (NH 2 R) 4 ] [PtCl 4 ]) according to the present invention.

열중량 분석(thermogravimetric analysis, TGA)Thermogravimetric analysis (TGA)

상기 실시예 1에서 제조한 수용성 백금 착화합물의 열안정성을 TGA 분석으로 확인하였다. The thermal stability of the water-soluble platinum complex compound prepared in Example 1 was confirmed by TGA analysis.

그 결과, 도 1에 나타난 바와 같이, 160℃ 및 270℃에서 나타난 두 번의 분해로 본 발명의 수용성 백금 착화합물에 [Pt(NH2R)4]2+ 및 [PtCl4 ]2-가 존재하고 있음을 확인하였으며, 300℃ 내지 800℃의 고온에서도 수용성 백금 착화합물 중량의 45％가 남아있음을 확인하였다. As a result, as shown in FIG. 1, [Pt (NH 2 R) 4 ] 2+ and [PtCl 4 ] 2- are present in the water-soluble platinum complex compound of the present invention by two decompositions at 160 ° C. and 270 ° C. It was confirmed that 45% of the water-soluble platinum complex weight remained at a high temperature of 300 ° C to 800 ° C.

자외선-가시광선 분광법(UV-visible spectrum)UV-visible spectrum

상기 실시예 1에서 제조한 수용성 백금 착화합물을 자외선-가시광선 분광법으로 분석한 결과, 도 2에서 나타낸 바와 같이, 파장 292 ㎚에서 최대 흡수율을 나타내었다. 이러한 흡수율은, 개개의 배위 단위의 분광(spectra of individual coordination unit) 없이, [PtCl4]2- 쪽 백금 원자의 5dz2 전자궤도로부터 [Pt(NH2R)4]2+ 쪽 백금 원자의 6pz 전자궤도로의 전하 이동(charge transfer)을 의미한다. As a result of analyzing the water-soluble platinum complex compound prepared in Example 1 by ultraviolet-visible spectroscopy, as shown in FIG. 2, the maximum absorption was shown at a wavelength of 292 nm. This absorptivity is calculated from the 5dz2 orbital of the [PtCl 4 ] 2- side platinum atom without the spectra of individual coordination unit, and the 6pz electron of the [Pt (NH 2 R) 4 ] 2+ side platinum atom. It means the charge transfer to orbit.

FT-IR 분광법FT-IR spectroscopy

실시예 1에서 제조한 수용성 백금 착화합물을 FT-IR 분광법으로 분석한 결 과, 도 3에 나타낸 바와 같이, N-H, C-H 및 C-O의 결합은 각각의 팽창 피크(stretching peak) 3213, 2856 및 1078 ㎝-1에서 확인되었으며, Pt-N의 결합은 588 ㎝-1의 피크로 확인되었다. 따라서, 목적하는 화합물이 제조되었음을 알 수 있다.As a result of analyzing the water-soluble platinum complex prepared in Example 1 by FT-IR spectroscopy, as shown in FIG. 3, the binding of NH, CH, and CO was shown at the stretching peaks 3213, 2856, and 1078 cm −, respectively. It was confirmed at 1 , the binding of Pt-N was confirmed with a peak of 588 cm -1 . Thus, it can be seen that the desired compound was prepared.

전도도(conductivity) 분석Conductivity Analysis

상기 실시예 1에서 제조한 수용성 백금 착화합물의 전도율(conductivity)을 온도 역수(inverse temperature, 1/T)에 따라 측정하여 그 결과를 도 4에 로그로 나타내었다. Conductivity of the water-soluble platinum complex compound prepared in Example 1 was measured according to an inverse temperature (1 / T), and the results are shown in logarithmic manner in FIG. 4.

도 4에 나타난 바와 같이, 본 발명의 수용성 백금 착화합물이 반도체의 특성인 온도 역수에 선형(linear)으로 반비례하는 전도율을 가짐을 알 수 있다. As shown in FIG. 4, it can be seen that the water-soluble platinum complex compound of the present invention has a conductivity that is inversely proportional to the temperature inverse of the characteristics of the semiconductor.

상기에서 살펴본 바와 같이, 본 발명에 따라 사염화백금칼륨염(potassium tetrachloroplatinate, K2(PtCl4))과 폴리(옥시알킬렌)알킬아민(poly(oxyalkilene)alkylamine)을 반응시켜 제조한 수용성 백금 착화합물은 열적 안정성 및 반도체로서의 전기 전도성이 우수하며 수용성을 나타내므로, 생의학 및 유기 반도체 등의 다양한 산업에 유용하게 활용될 수 있다.As described above, according to the present invention, a water-soluble platinum complex compound prepared by reacting potassium tetrachloroplatinate (K 2 (PtCl 4 )) with poly (oxyalkylkilene) alkylamine Because of excellent thermal stability and electrical conductivity as a semiconductor and water solubility, it can be usefully used in various industries such as biomedical and organic semiconductors.

Claims (7)

하기 화학식 1의 구조를 반복단위로 가진 백금 착화합물:Platinum complex compound having a structure of Formula 1 as a repeating unit: <화학식 1><Formula 1>
Figure 112006042332116-pat00008
Figure 112006042332116-pat00008
 상기 화학식에서 R은
Figure 112006042332116-pat00019
이며, 이때 R1 및 R2는 각각 독립적으로 C1 내지 C5의 선형 또는 분지형 알킬렌, W는 H 또는 NH2, n은 2 내지 50의 정수이고, 이때 상기 반복단위 내 R2는 서로 동일하거나 다를 수 있다.R in the above formula
Figure 112006042332116-pat00019
Wherein R 1 and R 2 are each independently C 1 to C 5 linear or branched alkylene, W is H or NH 2 , n is an integer of 2 to 50, wherein R 2 in the repeating unit It can be the same or different. (1) 하기 화학식 2의 사염화백금칼륨염(potassium tetrachloroplatinate, K2(PtCl4))과 하기 화학식 4의 폴리(옥시알킬렌)알킬아민을 반응시켜 화학식 3의 사아민화백금 착이온([Pt(NH2R)4]2+)을 합성하는 단계, 및 (2) 상기 사아민화백금 착이온을 K2(PtCl4)와 추가로 반응시키는 단계를 포함하는, 제 1 항의 백금 착화합물의 제조방법:(1) The potassium tetrachloride platinum salt of formula (2) (K 2 (PtCl 4 )) and the poly (oxyalkylene) alkylamine of formula (4) react with platinum tetrachloride platinum ion ([Pt ( A method for preparing the platinum complex of claim 1, comprising the step of synthesizing NH 2 R) 4 ] 2+ ), and (2) further reacting the platinum tetrachloride complex ion with K 2 (PtCl 4 ).
Figure 112006042332116-pat00009
Figure 112006042332116-pat00009
Figure 112006042332116-pat00010
Figure 112006042332116-pat00010
 <화학식 4><Formula 4>
Figure 112006042332116-pat00011
Figure 112006042332116-pat00011
 상기 화학식에서, R은
Figure 112006042332116-pat00020
이며;In the above formula, R is
Figure 112006042332116-pat00020
Is; R1 및 R2는 각각 독립적으로 C1 내지 C5의 선형 또는 분지형 알킬렌, W는 H 또는 NH2, n은 2 내지 50의 정수이며, 이때, 상기 반복단위 내 R2는 서로 동일하거나 다를 수 있다.R 1 and R 2 are each independently C 1 to C 5 linear or branched alkylene, W is H or NH 2 , n is an integer of 2 to 50, wherein R 2 in the repeating unit is the same or can be different. 제 2 항에 있어서,The method of claim 2, 폴리(옥시알킬렌)알킬아민이
Figure 112006010585830-pat00012
,
Figure 112006010585830-pat00013
(R은 H 또는 CH3) 및
Figure 112006010585830-pat00014
(a＋b＋c는 2 내지 50의 정수)으로 이루어진 군으로부터 선택됨을 특징으로 하는 제조방법. Poly (oxyalkylene) alkylamine
Figure 112006010585830-pat00012
,
Figure 112006010585830-pat00013
(R is H or CH 3 ) and
Figure 112006010585830-pat00014
(a + b + c is an integer of 2 to 50). 제 2 항에 있어서,The method of claim 2, 단계 (1)에서 사염화백금칼륨염과 폴리(옥시알킬렌)알킬아민이 1:1 내지 1:10 몰비 범위로 사용되는 것을 특징으로 하는 제조방법.Platinum potassium tetrachloride salt and poly (oxyalkylene) alkylamine in step (1) are used in the range of 1: 1 to 1:10 molar ratio. 제 2 항에 있어서,The method of claim 2, 단계 (2)에서 사용되는 사염화백금칼륨염의 사용량이 단계 (1)에서 사용된 사염화백금칼륨염 몰 대비 0.5 내지 4 배 범위인 것을 특징으로 하는 제조방법.The production method, characterized in that the amount of the platinum tetrachloride salt used in step (2) is 0.5 to 4 times the molar amount of the platinum tetrachloride salt used in step (1). 제 2 항에 있어서,The method of claim 2, 단계 (1)의 반응이 50 내지 60℃에서 수행되는 것을 특징으로 하는 제조방법.The process of (1), characterized in that the reaction is carried out at 50 to 60 ℃. 제 2 항에 있어서,The method of claim 2, 단계　(2)의 반응이 20 내지 30℃에서 수행되는 것을 특징으로 하는 제조방법.Process according to step (2) is carried out at 20 to 30 ℃.
KR1020040035183A 2004-05-18 2004-05-18 Water-soluble supramolecular platinum complexes and process for preparation thereof KR100663887B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
KR1020040035183A KR100663887B1 (en) 2004-05-18 2004-05-18 Water-soluble supramolecular platinum complexes and process for preparation thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
KR1020040035183A KR100663887B1 (en) 2004-05-18 2004-05-18 Water-soluble supramolecular platinum complexes and process for preparation thereof

Publications (2)

Publication Number Publication Date
KR20050110238A KR20050110238A (en) 2005-11-23
KR100663887B1 true KR100663887B1 (en) 2007-01-03

Family

ID=37285789

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020040035183A KR100663887B1 (en) 2004-05-18 2004-05-18 Water-soluble supramolecular platinum complexes and process for preparation thereof

Country Status (1)

Country Link
KR (1) KR100663887B1 (en)

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR850003408A (en) * 1983-10-19 1985-06-17 사까노 쓰네가즈 Method for preparing platinum-diamine complex

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR850003408A (en) * 1983-10-19 1985-06-17 사까노 쓰네가즈 Method for preparing platinum-diamine complex

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
2000

Also Published As

Publication number Publication date
KR20050110238A (en) 2005-11-23

Similar Documents

Publication Publication Date Title
Ortega et al. Amine and ammonium functionalization of chloromethylsilane-ended dendrimers. Antimicrobial activity studies
Fei et al. Construction of co-ordination networks of 1, 6-bis (4′-pyridyl)-2, 5-diazahexane with silver (I) and copper (I). Structural diversity through change in metal ions and counter ions
Luo et al. Synthesis, crystal structure and bioactivity of a novel linear trinuclear nickel (II) complex
Layek et al. Synthesis, crystal structure and magnetic properties of nickel (II) and cobalt (III) complexes of a pentadentate Schiff base
Lozano-Cruz et al. Synthesis, characterization and antibacterial behavior of water-soluble carbosilane dendrons containing ferrocene at the focal point
Chandraleka et al. Synthesis, characterization and thermal analysis of the copper (II) complexes with 2, 2'-bipyridyl and 1, 10-phenanthroline
Molčanov et al. A novel type of coordination mode of chloranilic acid leading to the formation of polymeric coordination ribbon in the series of mixed-ligand copper (II) complexes with 1, 10-phenanthroline
KR100663887B1 (en) Water-soluble supramolecular platinum complexes and process for preparation thereof
Abu-Safieh et al. Novel palladium (II) and platinum (II) complexes with a fluoropiperazinyl based ligand exhibiting high cytotoxicity and anticancer activity in vitro
US6664408B2 (en) Process for preparing organically-substituted polyoxometalates
Seo et al. Polybenzobisimidazole‐derived two‐dimensional supramolecular polymer
KR101329021B1 (en) Catalyst comprising Hydrogel and active ingredient
Xu et al. Assembly of silver-oxo complexes based on N-diphenylphosphanylmethyl-3-aminopyridine and their structures, photocatalysis and photocurrent responses
Öztürk et al. Synthesis of 5, 6-O-Cyclohexylidene-l-amino-3-azahexane and Its Co (II), Ni (II), and Cu (II) Complexes
Ge et al. Stepwise assembly of linearly-aligned Ru–M–Ru (M= Pd, Pt) heterotrimetallic complexes with σ-4-ethynylpyridine spacer
JP2022069882A (en) Novel compound and anion receptor
El-Habeeb et al. Charge transfer complexes beneficial method for determination of fluoxetine HCl pure drug: Spectroscopic and thermal analyses discussions
Parkash et al. SYNTHESIS AND THERMAL BEHAVIOR OF Ni (II), Cu (II), Co (II) AND Fe (III) METAL COMPLEXES WITH ONO TYPE SCHIFF BASE LIGAND
JP5790250B2 (en) Novel sulfonated triarylamine polymer and process for producing the same
JPH0597809A (en) Metal complex diamine compound and its production
OLAWALE et al. Synthesis and structural characterization of nano-scale twin crystal of copper tartarate
Patil et al. Synthesis, Physical and Spectral Investigations and Biological Studies of Mixed Ligand Lanthanum Complexes
Ahmed et al. Synthesis and binding mode of N, N’-bis (4-methoxybenzylidene) ethan-1, 2-diamine with Co (II), Ni (II) and Hg (II)
JP5790252B2 (en) Novel sulfonated triarylamine polymer and process for producing the same
Neuse et al. Carboranylene-bridged poly (benzimidazole)

Legal Events

Date Code Title Description
A201 Request for examination
E902 Notification of reason for refusal
E902 Notification of reason for refusal
E701 Decision to grant or registration of patent right
GRNT Written decision to grant
FPAY Annual fee payment

Payment date: 20121005

Year of fee payment: 7

FPAY Annual fee payment

Payment date: 20130930

Year of fee payment: 8

LAPS Lapse due to unpaid annual fee