KR100644152B1 - Composition of Calcium Ingredient for Food Additives - Google Patents
Composition of Calcium Ingredient for Food Additives Download PDFInfo
- Publication number
- KR100644152B1 KR100644152B1 KR1020040104657A KR20040104657A KR100644152B1 KR 100644152 B1 KR100644152 B1 KR 100644152B1 KR 1020040104657 A KR1020040104657 A KR 1020040104657A KR 20040104657 A KR20040104657 A KR 20040104657A KR 100644152 B1 KR100644152 B1 KR 100644152B1
- Authority
- KR
- South Korea
- Prior art keywords
- calcium
- potassium
- calcium carbonate
- food
- sodium
- Prior art date
Links
- 239000011575 calcium Substances 0.000 title claims abstract description 92
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical group [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 title claims abstract description 88
- 229910052791 calcium Inorganic materials 0.000 title claims abstract description 88
- 239000000203 mixture Substances 0.000 title claims abstract description 85
- 239000002778 food additive Substances 0.000 title claims abstract description 45
- 235000013373 food additive Nutrition 0.000 title claims abstract description 44
- 239000004615 ingredient Substances 0.000 title 1
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 218
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 108
- 239000007788 liquid Substances 0.000 claims abstract description 65
- 235000013305 food Nutrition 0.000 claims abstract description 35
- 238000002360 preparation method Methods 0.000 claims abstract description 22
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 claims abstract description 8
- 125000002467 phosphate group Chemical group [H]OP(=O)(O[H])O[*] 0.000 claims abstract description 4
- 239000000843 powder Substances 0.000 claims description 31
- 235000019832 sodium triphosphate Nutrition 0.000 claims description 19
- 238000000034 method Methods 0.000 claims description 17
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 13
- 229960003975 potassium Drugs 0.000 claims description 13
- 239000011591 potassium Substances 0.000 claims description 13
- 229910052700 potassium Inorganic materials 0.000 claims description 13
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 claims description 10
- OQZCJRJRGMMSGK-UHFFFAOYSA-M potassium metaphosphate Chemical compound [K+].[O-]P(=O)=O OQZCJRJRGMMSGK-UHFFFAOYSA-M 0.000 claims description 9
- 239000001508 potassium citrate Substances 0.000 claims description 8
- 229960002635 potassium citrate Drugs 0.000 claims description 8
- QEEAPRPFLLJWCF-UHFFFAOYSA-K potassium citrate (anhydrous) Chemical compound [K+].[K+].[K+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O QEEAPRPFLLJWCF-UHFFFAOYSA-K 0.000 claims description 8
- 235000011082 potassium citrates Nutrition 0.000 claims description 8
- RYCLIXPGLDDLTM-UHFFFAOYSA-J tetrapotassium;phosphonato phosphate Chemical compound [K+].[K+].[K+].[K+].[O-]P([O-])(=O)OP([O-])([O-])=O RYCLIXPGLDDLTM-UHFFFAOYSA-J 0.000 claims description 8
- 235000019830 sodium polyphosphate Nutrition 0.000 claims description 7
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 claims description 7
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 claims description 7
- 229910019142 PO4 Inorganic materials 0.000 claims description 6
- 239000001509 sodium citrate Substances 0.000 claims description 6
- HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 claims description 6
- 229940038773 trisodium citrate Drugs 0.000 claims description 6
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 5
- ATGAWOHQWWULNK-UHFFFAOYSA-I pentapotassium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [K+].[K+].[K+].[K+].[K+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O ATGAWOHQWWULNK-UHFFFAOYSA-I 0.000 claims description 5
- HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 claims description 5
- 229940099402 potassium metaphosphate Drugs 0.000 claims description 5
- 239000011734 sodium Substances 0.000 claims description 5
- 229910052708 sodium Inorganic materials 0.000 claims description 5
- 229940048086 sodium pyrophosphate Drugs 0.000 claims description 5
- UGTZMIPZNRIWHX-UHFFFAOYSA-K sodium trimetaphosphate Chemical compound [Na+].[Na+].[Na+].[O-]P1(=O)OP([O-])(=O)OP([O-])(=O)O1 UGTZMIPZNRIWHX-UHFFFAOYSA-K 0.000 claims description 5
- 235000019818 tetrasodium diphosphate Nutrition 0.000 claims description 5
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 claims description 5
- SUZJDLRVEPUNJG-UHFFFAOYSA-K tripotassium 2,4,6-trioxido-1,3,5,2lambda5,4lambda5,6lambda5-trioxatriphosphinane 2,4,6-trioxide Chemical compound [K+].[K+].[K+].[O-]P1(=O)OP([O-])(=O)OP([O-])(=O)O1 SUZJDLRVEPUNJG-UHFFFAOYSA-K 0.000 claims description 5
- 239000000654 additive Substances 0.000 claims description 4
- 230000000996 additive effect Effects 0.000 claims description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 4
- ZPWVASYFFYYZEW-UHFFFAOYSA-L dipotassium hydrogen phosphate Chemical compound [K+].[K+].OP([O-])([O-])=O ZPWVASYFFYYZEW-UHFFFAOYSA-L 0.000 claims description 3
- 239000010452 phosphate Substances 0.000 claims description 3
- 235000015424 sodium Nutrition 0.000 claims description 3
- 229920000388 Polyphosphate Polymers 0.000 claims 1
- 239000001205 polyphosphate Substances 0.000 claims 1
- 235000011176 polyphosphates Nutrition 0.000 claims 1
- 102000004169 proteins and genes Human genes 0.000 abstract description 21
- 108090000623 proteins and genes Proteins 0.000 abstract description 21
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 abstract description 13
- 229910001424 calcium ion Inorganic materials 0.000 abstract description 13
- 230000008859 change Effects 0.000 abstract description 12
- 239000000796 flavoring agent Substances 0.000 abstract description 9
- 235000019634 flavors Nutrition 0.000 abstract description 9
- 230000002776 aggregation Effects 0.000 abstract description 7
- 239000006185 dispersion Substances 0.000 abstract description 7
- 238000004220 aggregation Methods 0.000 abstract description 5
- 230000008901 benefit Effects 0.000 abstract description 3
- 239000003795 chemical substances by application Substances 0.000 abstract description 3
- 230000007774 longterm Effects 0.000 abstract description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 37
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 28
- 235000010489 acacia gum Nutrition 0.000 description 27
- 244000215068 Acacia senegal Species 0.000 description 22
- 229920000084 Gum arabic Polymers 0.000 description 22
- 239000000205 acacia gum Substances 0.000 description 22
- 241000220259 Raphanus Species 0.000 description 21
- 235000018102 proteins Nutrition 0.000 description 20
- 238000001556 precipitation Methods 0.000 description 16
- 235000013336 milk Nutrition 0.000 description 15
- 239000008267 milk Substances 0.000 description 15
- 210000004080 milk Anatomy 0.000 description 15
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 14
- 239000001569 carbon dioxide Substances 0.000 description 13
- 229910002092 carbon dioxide Inorganic materials 0.000 description 13
- 238000006243 chemical reaction Methods 0.000 description 13
- 238000009472 formulation Methods 0.000 description 12
- 239000000243 solution Substances 0.000 description 12
- 239000002245 particle Substances 0.000 description 11
- 239000007787 solid Substances 0.000 description 11
- ODINCKMPIJJUCX-UHFFFAOYSA-N Calcium oxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 10
- 239000000920 calcium hydroxide Substances 0.000 description 10
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 10
- 235000019738 Limestone Nutrition 0.000 description 9
- 239000006028 limestone Substances 0.000 description 9
- 238000004519 manufacturing process Methods 0.000 description 9
- 239000002244 precipitate Substances 0.000 description 8
- 238000010438 heat treatment Methods 0.000 description 6
- 229910021645 metal ion Inorganic materials 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- 239000002994 raw material Substances 0.000 description 6
- 102000002322 Egg Proteins Human genes 0.000 description 5
- 108010000912 Egg Proteins Proteins 0.000 description 5
- 239000001785 acacia senegal l. willd gum Substances 0.000 description 5
- 239000007900 aqueous suspension Substances 0.000 description 5
- 210000000988 bone and bone Anatomy 0.000 description 5
- 239000000292 calcium oxide Substances 0.000 description 5
- 235000012255 calcium oxide Nutrition 0.000 description 5
- 239000011248 coating agent Substances 0.000 description 5
- 238000000576 coating method Methods 0.000 description 5
- 235000013365 dairy product Nutrition 0.000 description 5
- 210000003278 egg shell Anatomy 0.000 description 5
- 239000010419 fine particle Substances 0.000 description 5
- 230000005484 gravity Effects 0.000 description 5
- 229910021532 Calcite Inorganic materials 0.000 description 4
- 235000021317 phosphate Nutrition 0.000 description 4
- 235000019828 potassium polyphosphate Nutrition 0.000 description 4
- 239000011435 rock Substances 0.000 description 4
- 239000013049 sediment Substances 0.000 description 4
- 230000001954 sterilising effect Effects 0.000 description 4
- 238000004659 sterilization and disinfection Methods 0.000 description 4
- 235000014653 Carica parviflora Nutrition 0.000 description 3
- 244000132059 Carica parviflora Species 0.000 description 3
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 3
- RHZUVFJBSILHOK-UHFFFAOYSA-N anthracen-1-ylmethanolate Chemical compound C1=CC=C2C=C3C(C[O-])=CC=CC3=CC2=C1 RHZUVFJBSILHOK-UHFFFAOYSA-N 0.000 description 3
- 239000003830 anthracite Substances 0.000 description 3
- 230000000903 blocking effect Effects 0.000 description 3
- 239000003245 coal Substances 0.000 description 3
- 239000003814 drug Substances 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 235000020189 fortified milk Nutrition 0.000 description 3
- 235000020191 long-life milk Nutrition 0.000 description 3
- 239000004579 marble Substances 0.000 description 3
- 239000008213 purified water Substances 0.000 description 3
- 238000004062 sedimentation Methods 0.000 description 3
- 230000001953 sensory effect Effects 0.000 description 3
- 210000004974 shell Anatomy 0.000 description 3
- 238000003786 synthesis reaction Methods 0.000 description 3
- LWIHDJKSTIGBAC-UHFFFAOYSA-K tripotassium phosphate Chemical compound [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 description 3
- 239000011882 ultra-fine particle Substances 0.000 description 3
- NPHULPIAPWNOOH-UHFFFAOYSA-N 2-[4-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]-3-(2,3-dihydroindol-1-ylmethyl)pyrazol-1-yl]-1-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethanone Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C=1C(=NN(C=1)CC(=O)N1CC2=C(CC1)NN=N2)CN1CCC2=CC=CC=C12 NPHULPIAPWNOOH-UHFFFAOYSA-N 0.000 description 2
- HVTQDSGGHBWVTR-UHFFFAOYSA-N 2-[4-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]-3-phenylmethoxypyrazol-1-yl]-1-morpholin-4-ylethanone Chemical compound C(C1=CC=CC=C1)OC1=NN(C=C1C=1C=NC(=NC=1)NC1CC2=CC=CC=C2C1)CC(=O)N1CCOCC1 HVTQDSGGHBWVTR-UHFFFAOYSA-N 0.000 description 2
- VXZBYIWNGKSFOJ-UHFFFAOYSA-N 2-[4-[5-(2,3-dihydro-1H-inden-2-ylamino)pyrazin-2-yl]pyrazol-1-yl]-1-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethanone Chemical compound C1C(CC2=CC=CC=C12)NC=1N=CC(=NC=1)C=1C=NN(C=1)CC(=O)N1CC2=C(CC1)NN=N2 VXZBYIWNGKSFOJ-UHFFFAOYSA-N 0.000 description 2
- WTFUTSCZYYCBAY-SXBRIOAWSA-N 6-[(E)-C-[[4-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]piperazin-1-yl]methyl]-N-hydroxycarbonimidoyl]-3H-1,3-benzoxazol-2-one Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)N1CCN(CC1)C/C(=N/O)/C1=CC2=C(NC(O2)=O)C=C1 WTFUTSCZYYCBAY-SXBRIOAWSA-N 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 2
- 102000011632 Caseins Human genes 0.000 description 2
- 108010076119 Caseins Proteins 0.000 description 2
- MKYBYDHXWVHEJW-UHFFFAOYSA-N N-[1-oxo-1-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propan-2-yl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(C(C)NC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 MKYBYDHXWVHEJW-UHFFFAOYSA-N 0.000 description 2
- 239000005862 Whey Substances 0.000 description 2
- 102000007544 Whey Proteins Human genes 0.000 description 2
- 108010046377 Whey Proteins Proteins 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 238000005054 agglomeration Methods 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- 238000013019 agitation Methods 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 238000007664 blowing Methods 0.000 description 2
- 230000003139 buffering effect Effects 0.000 description 2
- 239000001506 calcium phosphate Substances 0.000 description 2
- 229910000389 calcium phosphate Inorganic materials 0.000 description 2
- 235000011010 calcium phosphates Nutrition 0.000 description 2
- 235000011089 carbon dioxide Nutrition 0.000 description 2
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 2
- 238000005119 centrifugation Methods 0.000 description 2
- 150000001860 citric acid derivatives Chemical class 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- 235000014106 fortified food Nutrition 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 230000036571 hydration Effects 0.000 description 2
- 238000006703 hydration reaction Methods 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 208000015122 neurodegenerative disease Diseases 0.000 description 2
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 2
- 229920000193 polymethacrylate Polymers 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 239000000606 toothpaste Substances 0.000 description 2
- 229940034610 toothpaste Drugs 0.000 description 2
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 2
- MGGVALXERJRIRO-UHFFFAOYSA-N 4-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]-2-[2-oxo-2-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethyl]-1H-pyrazol-5-one Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C=1C(=NN(C=1)CC(=O)N1CC2=C(CC1)NN=N2)O MGGVALXERJRIRO-UHFFFAOYSA-N 0.000 description 1
- DEXFNLNNUZKHNO-UHFFFAOYSA-N 6-[3-[4-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]piperidin-1-yl]-3-oxopropyl]-3H-1,3-benzoxazol-2-one Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C1CCN(CC1)C(CCC1=CC2=C(NC(O2)=O)C=C1)=O DEXFNLNNUZKHNO-UHFFFAOYSA-N 0.000 description 1
- 241001474374 Blennius Species 0.000 description 1
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- 241000195493 Cryptophyta Species 0.000 description 1
- 241000282414 Homo sapiens Species 0.000 description 1
- 208000001132 Osteoporosis Diseases 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 150000008064 anhydrides Chemical class 0.000 description 1
- 206010003246 arthritis Diseases 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000002981 blocking agent Substances 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- NKWPZUCBCARRDP-UHFFFAOYSA-L calcium bicarbonate Chemical compound [Ca+2].OC([O-])=O.OC([O-])=O NKWPZUCBCARRDP-UHFFFAOYSA-L 0.000 description 1
- 229910000020 calcium bicarbonate Inorganic materials 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- 159000000007 calcium salts Chemical class 0.000 description 1
- SMHNUIFHMAGAFL-UHFFFAOYSA-N calcium;2-hydroxypropanoic acid Chemical compound [Ca].CC(O)C(O)=O SMHNUIFHMAGAFL-UHFFFAOYSA-N 0.000 description 1
- 239000005018 casein Substances 0.000 description 1
- 235000021240 caseins Nutrition 0.000 description 1
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- 238000010494 dissociation reaction Methods 0.000 description 1
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- 239000010437 gem Substances 0.000 description 1
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- JEGUKCSWCFPDGT-UHFFFAOYSA-N h2o hydrate Chemical compound O.O JEGUKCSWCFPDGT-UHFFFAOYSA-N 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
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Classifications
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L33/00—Modifying nutritive qualities of foods; Dietetic products; Preparation or treatment thereof
- A23L33/10—Modifying nutritive qualities of foods; Dietetic products; Preparation or treatment thereof using additives
- A23L33/16—Inorganic salts, minerals or trace elements
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
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Abstract
본 발명은 칼슘강화를 위하여 식품에 첨가되는 식품첨가용 칼슘제재 액상 조성물에 있어서, 콜로이달 탄산칼슘 100 중량부(A)에 대하여; 아라비아검 1~70 중량부(B)와; 구연산염 또는 인산염 군에서 1종 또는 적어도 1종 이상을 병용하여 형성된 0.001~70 중량부(C)를; 함유시킴으로써 첨가된 식품의 PH 안정성을 향상시키는 것을 특징으로 하는 식품첨가용 칼슘제재 액상 조성물에 관한 것이다.The present invention is a food additive calcium preparation liquid composition added to food for calcium fortification, with respect to 100 parts by weight of colloidal calcium carbonate (A); Arabia gum 1 to 70 parts by weight (B); 0.001 to 70 parts by weight (C) formed by using one type or at least one type in combination with citrate or phosphate group; It relates to a food additive calcium-based liquid composition characterized by improving the PH stability of the food added by containing.
상기 본 발명에 의하여 액중에서의 재분산성 및 장기분산 안정성이 우수하며 상기 조성물 C를 첨가하므로써 pH의 변화 및 용해한 칼슘이온에 의한 단백질의 응집 등을 방지하여 제품의 품질 안정성을 향상시킬 뿐만 아니라 식품의 풍미에 영향을 주지 않는 제재이므로 고농도로 첨가가 가능한 식품첨가용 칼슘제재 액상 조성물이 제공되는 이점이 있다. According to the present invention, it is excellent in redispersibility and long-term dispersion stability in the liquid and prevents the change of pH and aggregation of protein by dissolved calcium ions by adding the composition C as well as improving the quality stability of the product Since the agent does not affect the flavor, there is an advantage in that a liquid composition for food additives, which can be added at a high concentration, is provided.
Description
본 발명은 칼슘강화를 위하여 식품에 첨가되는 식품첨가용 칼슘제재 액상 조성물에 있어서, 콜로이달 탄산칼슘 100 중량부(A)에 대하여; 아라비아검 1~70 중량부(B)와; 구연산염 또는 인산염 군에서 1종 또는 적어도 1종 이상을 병용하여 형성된 0.001~70 중량부(C)를; 함유시킴으로써 첨가된 식품의 PH 안정성을 향상시키는 것을 특징으로 하는 식품첨가용 칼슘제재 액상 조성물에 관한 것이다.The present invention is a food additive calcium preparation liquid composition added to food for calcium fortification, with respect to 100 parts by weight of colloidal calcium carbonate (A); Arabia gum 1 to 70 parts by weight (B); 0.001 to 70 parts by weight (C) formed by using one type or at least one type in combination with citrate or phosphate group; It relates to a food additive calcium-based liquid composition characterized by improving the PH stability of the food added by containing.
일반적으로 의학의 발달로 고령화 사회가 도래됨에 따라 인간의 평균수명이 연장되었으나, 골다공증, 류마티스, 관절염 등의 퇴행성 질환으로 고통받는 환자들이 급증하고 있는 실정이다. In general, the life expectancy of human beings has been prolonged with the advent of an aging society due to the development of medicine, but patients suffering from degenerative diseases such as osteoporosis, rheumatism and arthritis are rapidly increasing.
따라서, 고령화에 의한 퇴행성 질환 등의 예방, 완화 및 치료 효과가 있는 제재의 개발이 필요하다. 또한, 칼슘 섭취량의 부족이 성장기의 어린이와 노인 등에서 현저하다고 지적되고 있으며, 이러한 문제점을 해결하기 위하여 칼슘강화식품들이 개발되어 판매되고 있다. Therefore, there is a need for the development of agents that have the effect of preventing, alleviating and treating degenerative diseases such as aging. In addition, it is pointed out that the lack of calcium intake is remarkable in children and the elderly during the growth period, calcium fortified foods have been developed and sold to solve this problem.
즉, 식품의 칼슘을 강화할 목적으로 유산칼슘, 염화칼슘 등의 수용성의 무기 또는 유기산 칼슘과 탄산칼슘, 인산칼슘, 난각칼슘, 우골칼슘, 유청칼슘, 산호칼슘 및 해조칼슘 등과 같은 물에 녹지 않는 무기칼슘들이 첨가되고 있다. That is, for the purpose of strengthening the calcium of food, water-soluble inorganic calcium or lactic acid such as calcium lactic acid or calcium chloride or inorganic calcium insoluble in water such as calcium carbonate, calcium phosphate, eggshell calcium, bone calcium, whey calcium, coral calcium and seaweed calcium Are being added.
이하 상기 탄산칼슘에 대하여 살펴보면, 탄산칼슘을 주성분으로 하는 석회석(limestone), 대리석, 산석(霰石), 백암, 방해석, 빙주석(氷洲石), 산호, 패각, 골 및 난각 등에서 소성(calcination), 생석회(quick lime), 유화(slaking), 화합(chemical reaction), 탈수(dehydration), 건조(drying) 및 분쇄(pulverizing) 공정을 통하여 제조되는 탄산칼슘은 자연계에 존재하는 염중에서 가장 많으며, 석회석(limestone), 대리석, 산석(霰石), 백암, 방해석, 빙주석(氷洲石), 산호, 패각, 골 및 난각 등으로서 존재한다. Hereinafter, the calcium carbonate may include limestone, marble, calcite, white rock, calcite, ice tin, coral, shell, bone, and egg shell, which are mainly composed of calcium carbonate. Calcium carbonate, produced through quick lime, slaking, chemical reaction, dehydration, drying and pulverizing processes, is the most abundant salt in nature. It exists as limestone, marble, stone, white rock, calcite, ice tin, coral, shell, bone and eggshell.
그리고, 상기의 탄산칼슘은 무색의 결정 또는 백색고체로, 분자량이 100.09, 비중이 2.93이며, 825℃에서 분해된다. The calcium carbonate is colorless crystals or white solids, has a molecular weight of 100.09 and a specific gravity of 2.93, and decomposes at 825 ° C.
가열하면 이산화탄소를 발생하고 생석회를 얻을 수 있으며, 이 반응은 이산화탄소와 생석회를 공업적으로 얻기 위한 중요한 반응이다. When heated, carbon dioxide is generated and quicklime is obtained. This reaction is an important reaction for industrially obtaining carbon dioxide and quicklime.
또한, 상기의 탄산칼슘은 순수한 물에는 20℃에서 약 0.01%, 80℃에서 약 0.013%, 120℃에서 약 0.015% 정도 용해하며, 이산화탄소를 함유하는 물에는 용해도가 증가하여 중탄산칼슘을 생성하며, 또 탄산칼슘에 산을 작용시키면 이산화탄소를 발생하면서 용해된다. In addition, the calcium carbonate dissolves in pure water at about 0.01% at 20 ℃, about 0.013% at 80 ℃, about 0.015% at 120 ℃, solubility in water containing carbon dioxide increases to produce calcium bicarbonate, When acid is applied to calcium carbonate, it dissolves while generating carbon dioxide.
탄산칼슘을 실험실에서 얻는데는 수용성의 칼슘염에 탄산알카리를 작용시키거나, 석회수에 이산화탄소를 통과시킨다. Calcium carbonate is obtained in the laboratory by applying alkali carbonate to water-soluble calcium salt or passing carbon dioxide through lime water.
공업적으로는 석회석을 분쇄하여 가루를 만들어 체로 쳐서 가르거나 풍피(공기중에서 고체입자가 자유침강할 때 속도의 차이를 이용하여 입자를 크기 또는 비중에 따라 나누는 조작)하여 얻는데 이것을 중질(重質)탄산칼슘이라 한다. Industrially, limestone is pulverized, pulverized, sieved and sifted, or obtained by wind blowing (the operation of dividing particles according to size or specific gravity using the difference in speed when solid particles settle freely in air). It is called calcium carbonate.
또, 석회수(石灰水)에 이산화탄소를 불어 넣어 생기는 침전을 여과, 건조 및 분쇄하여 경질(輕質)탄산칼슘을 얻는다. In addition, precipitates produced by blowing carbon dioxide into lime water are filtered, dried and pulverized to obtain hard calcium carbonate.
탄산칼슘은 값이 싸고, 비중도 크지 않아 공업분야에서 널리 사용되는데 고무의 보강제, 제철 및 건축재료 등의 각종 중화제, 인쇄 및 잉크용, 제지용, 페인트용, 합성수지, 치약, 의약용 및 식품용으로 폭 넓게 사용되고 있다. Calcium carbonate is inexpensive and does not have a high specific gravity, so it is widely used in the industrial field. It is widely used in the industrial fields such as rubber reinforcement, steel and building materials, printing and ink, paper and paint, synthetic resin, toothpaste, medicine and food. It is widely used.
종래에, 탄산칼슘은 석회석 등을 원료로 하여 석회석의 주성분인 칼슘질을 탄산가스로 화학적으로 합성하여 탄산칼슘을 침전시켜서 탈수, 건조 및 분쇄하여 제조되고 있다.Conventionally, calcium carbonate is produced by using a limestone or the like as a raw material, chemically synthesizing calcium material, which is a main component of limestone, with carbonic acid gas to precipitate calcium carbonate, dehydrating, drying and grinding.
상기한 바와 같이, 칼슘 섭취량의 부족이 성장기의 어린이와 노인 등에서 현저하다고 지적되고 있으며, 이러한 문제점을 해결하기 위하여 상기 탄산칼슘을 주원료로 하는 칼슘강화식품들이 개발되어 판매되고 있다. As described above, it has been pointed out that the lack of calcium intake is remarkable in children and the elderly during the growth period, and calcium fortified foods based on the calcium carbonate are developed and sold to solve such problems.
그런데, 수용성의 유기산칼슘은 유리된 칼슘이온이 식품 특히 유제품 중의 단백질과 결합하여 망상구조로 단백질의 거대분자를 형성하여 침전하므로서 단백질의 안정성을 저해하고 아린맛 등의 이미가 발생하기 때문에 일정량 이상 첨가가 불가능하므로 다량으로 사용할 수 없다. However, the water-soluble organic calcium acid is added to a certain amount because the free calcium ions bind to proteins in foods, especially dairy products, to precipitate and form macromolecules of the protein in a network structure, thereby inhibiting the stability of the protein and generating amine taste. Can not be used in large quantities.
한편, 물에 녹지 않는 탄산칼슘, 인산칼슘, 난각칼슘, 우골칼슘, 유청칼슘, 산호칼슘 및 해조칼슘 등은 칼슘이온이 유리되지 않으므로 단백질과의 결합이 일어나지 않기 때문에 단백질의 안정성에는 문제가 없이 다량으로 첨가하는 것은 가능하나, 이 무기칼슘은 전반적으로 비중이 높아서 유제품중에 분산시킬 경우, 단시간에 침전하기 때문에 침전 등으로 식품의 미관과 제품의 특성에 악영향을 주므로서 첨가량이 제한되어 다량으로 사용할 수 없다는 문제점이 있다.On the other hand, calcium carbonate, calcium phosphate, eggshell calcium, right bone calcium, whey calcium, coral calcium and algae calcium, which are insoluble in water, are not free of calcium ions and therefore do not bind to the protein. Although it is possible to add the inorganic calcium in general, the inorganic calcium has a high specific gravity, so that when it is dispersed in dairy products, it is precipitated in a short time. There is no problem.
자세하게는 상기와 같이 탄산칼슘의 용해도에 대하여 1g중에 포화용액 1dm3에 포함된 무수화합물의 질량은 0℃에서 1.34, 25℃에서 0.82, 80℃에서 약 0.26, 100℃에서 약 0.20 정도 용해하며, 수산화칼슘은 탄산칼슘보다 용해도가 훨씬 높다.Specifically, as described above, the mass of the anhydride contained in the saturated solution 1dm 3 in 1 g of the solubility of calcium carbonate is 1.34 at 0 ° C, 0.82 at 25 ° C, about 0.26 at 80 ° C, about 0.20 at 100 ° C, Calcium hydroxide is much more soluble than calcium carbonate.
또한 탄산칼슘이 물에 함유되어 있는 상태로 장시간 방치하면 탄산가스가 이탈되어 OH기가 증가되므로서 자연적으로 액중의 pH가 상승되는데, 적어도 1% 탄산칼슘 용액을 기준으로 적어도 pH 10에서 심할 경우에는 pH 12 및 pH 13까지 상승하는 경우가 많으며, 이것은 외부의 인자 특히 공기혼입, 온도, 빛 및 물리적인 교반 등에 따라서 pH의 증가 속도가 더 빨라질 수가 있다. In addition, if the calcium carbonate is left in water for a long time, the pH of the liquid naturally rises as the carbon dioxide gas is released and the OH group is increased.If the pH is severe at least pH 10 based on at least 1% calcium carbonate solution, the pH is increased. It often rises to 12 and pH 13, which can increase the rate of increase of pH faster depending on external factors, in particular air incorporation, temperature, light and physical agitation.
pH의 상승은 결론적으로 Ca(OH)2가 액중에 증가되는 것과 같으며, 이는 pH 상승과 아울러 2가의 칼슘이온(Ca2+)이 액중으로 해리되는 양이 급격히 증가되게 된다.In conclusion, the increase in pH is equivalent to the increase of Ca (OH) 2 in the liquid, which leads to a sharp increase in the amount of dissociation of divalent calcium ions (Ca 2+ ) into the liquid.
이 탄산칼슘이 식품에 첨가되었을 경우, pH 상승으로 인하여 식품 특히 유제품중의 카제인과 같은 단백질이 용해되어 카제인염으로 변환되거나 변성 단백질로 변화게 되어 식품 본래의 단백질 발란스에 문제를 야기시킬 수 있다. When this calcium carbonate is added to foods, a rise in pH may dissolve proteins, such as casein, in foods, especially dairy products, which may be converted to casein salts or converted into denatured proteins, which may cause problems with food original protein balance.
또한, 탄산칼슘이 용해되어 2가의 칼슘이온(Ca2+)이 식품중에 해리되면 2가의 금속이온은 식품 특히 우유중의 카제인 단백질과 가교결합을 형성하여 거대한 망상구조를 형성하게 되며 이는 단백질이 서로 엉키어 점도의 증가와 같은 식품 본래의 물성에 변화를 일으키거나 커드가 형성되며, 시간이 경과함에 따라 단백질 응어리가 식품 저변에 침전물로 형성되는 문제점이 있다..In addition, when calcium carbonate is dissolved and the divalent calcium ions (Ca 2+ ) dissociate in the food, the divalent metal ions cross-link with the casein protein in the food, especially milk, to form a huge network structure. There is a problem that changes in the physical properties of the food, such as an increase in viscosity, or curd is formed, and protein cores are formed as a precipitate on the food base over time.
이런 현상들은 식품의 제조공정에 따라 그 정도가 달라지며 제조공정중에 야기되는 외부의 인자 예를 들면 투입량, 처리시간, 가열온도, 교반, 믹스, 균질, 살균, 유통 및 저장 등은 상기의 현상들을 증폭시키는 문제점이 있다.These phenomena vary depending on the manufacturing process of food, and external factors such as dosage, processing time, heating temperature, agitation, mix, homogeneity, sterilization, distribution and storage caused during the manufacturing process There is a problem to amplify.
본 발명은 상기한 문제점을 해결하기 위하여 초미립자에 아라비아검으로 표면 코팅시킨 콜로이달 탄산칼슘의 초미립자가 식품에 투여시 발생되는 pH의 변화를 중화시킴으로써 단백질의 응집 등을 방지하여 제품의 품질 안정성을 향상시킨 고분산성의 식품첨가용 칼슘제재 조성물을 제공하는 것을 목적으로 한다.The present invention to improve the quality stability of the product by preventing the aggregation of protein by neutralizing the change in pH generated when the ultrafine particles of the colloidal calcium carbonate surface-coated with gum arabic in order to solve the above problems in foods An object of the present invention is to provide a highly dispersible food additive calcium preparation composition.
따라서 고분산성으로 첨가량을 높혀 장기간 방치해도 분산안정성이 높은 식품첨가용 칼슘제재 조성물을 제공하는 것을 목적으로 한다.Accordingly, an object of the present invention is to provide a food additive calcium preparation composition having high dispersion stability even if left for a long time with high dispersion.
상기한 목적을 달성하기 위하여 본 발명은 칼슘강화를 위하여 식품에 첨가되는 식품첨가용 칼슘제재 액상 조성물에 있어서, 콜로이달 탄산칼슘 100 중량부(A)에 대하여; 아라비아검 1~70 중량부(B)와; 구연산염 또는 인산염 군에서 1종 또는 적어도 1종 이상을 병용하여 형성된 0.001~70 중량부(C)를; 함유시킴으로써 첨가된 식품의 PH 안정성을 향상시키는 것을 특징으로 하는 식품첨가용 칼슘제재 액상 조성물을 기술적 요지로 한다.In order to achieve the above object, the present invention provides a calcium-based liquid additive for food additives added to foods for calcium fortification, with respect to 100 parts by weight of colloidal calcium carbonate (A); Arabia gum 1 to 70 parts by weight (B); 0.001 to 70 parts by weight (C) formed by using one type or at least one type in combination with citrate or phosphate group; The food additive calcium-based liquid composition characterized by improving the PH stability of the added food by making it a technical subject matter.
여기서 상기 구연산염 또는 인산염은 일인산나트륨, 이인산나트륨, 삼인산나트륨, 폴리인산나트륨, 폴리메타인산나트륨, sodium tripolyphosphate, sodium trimetaphosphate, 피로인산나트륨, 일인산칼륨, 이인산칼륨, 삼인산칼륨, 폴리인산칼륨, 메타인산칼륨, 폴리메타인산칼륨, 피로인산칼륨, potassium tripolyphosphate, potassium trimetaphosphate 등에서 적어도 1종인 것을 특징으로 하는 식품첨가용 칼슘제재 액상 조성물로 되는 것이 바람직하다.Wherein the citrate or phosphate is sodium monophosphate, sodium diphosphate, sodium triphosphate, sodium polyphosphate, sodium polymethphosphate, sodium tripolyphosphate, sodium trimetaphosphate, sodium pyrophosphate, potassium monophosphate, potassium diphosphate, potassium triphosphate, potassium polyphosphate , Potassium metaphosphate, potassium polymethaphosphate, potassium pyrophosphate, potassium tripolyphosphate, potassium trimetaphosphate, and the like.
한편 본 발명은 상기 식품첨가용 칼슘제재 조성물을 건조분말화시킨 것을 특징으로 하는 식품첨가용 칼슘제재 분말 조성물을 또 다른 기술적 요지로 한다.On the other hand, the present invention is a food additive calcium preparation powder composition characterized in that the dry powdered food preparation calcium preparation composition is another technical gist.
이하 본 발명에 관하여 상세히 살펴보면, 본 발명의 상기 콜로이달 탄산칼슘(A)은 탄산칼슘 미립자를 일반적인 화학적 합성법으로 제조한 것이며, 이의 제조공정이나 그 활용은 공지의 것이므로 이하 간략한 설명만으로 대신하기로 한다.Looking in detail with respect to the present invention, the colloidal calcium carbonate (A) of the present invention is prepared by the calcium carbonate fine particles in a general chemical synthesis method, its manufacturing process or its use is well known and will be replaced by the following brief description only. .
상기 탄산칼슘이 제조 공정을 약술하면, 60mm 정도로 조분쇄한 원석(석회석)에 무연탄을 원석중량대비 8~10 중량% 정도 섞어서 800~1,200℃에서 2~20시간 정도 강하게 소성시킨 후, 물 또는 정제수를 원석중량대비 약 10~16.5 중량% 가하여 수화시킨다. When the calcium carbonate outlines the manufacturing process, anthracite coal is mixed with about 8 to 10% by weight of the raw material (limestone) roughly ground to about 60 mm, and calcined strongly at 800 to 1,200 ° C. for 2 to 20 hours, followed by water or purified water. To hydrate by adding about 10 ~ 16.5% by weight relative to the weight of the gemstone.
상기 수화액을 가는 메쉬체로 체통 또는 원심분리 등의 방법으로 수화액중의 이물질을 제거하여 수산화칼슘액을 만든다. The hydrated liquid is removed from the hydrated liquid by a sieve or centrifugation using a thin mesh body to form a calcium hydroxide liquid.
이 때, 수산화칼슘액중의 수산화칼슘 고형분은 약 5~10% 정도이다. At this time, the calcium hydroxide solid content in the calcium hydroxide liquid is about 5 to 10%.
상기에서 제조된 수산화칼슘액을 수산화칼슘 고형분으로 5.0 중량% 정도로 조절한 액(수산화칼슘 고형분 500kg, 온도 10~30℃)에 탄산가스농도 20~30 중량%의 탄산가스를 25m/min의 유속으로 통과시켜 탄산화반응을 일으키고, 반응의 종결점은 수산화칼슘액의 농도, 온도, 탄산가스농도 및 유속 등에 따라 달라지지만 상기의 조건으로 실시한 결과 반응시간은 약 30분, 전자현미경 또는 입도분석기로 원하는 탄산칼슘의 평균입자가 생성되었을 때, 탄산가스의 주입을 중단하여 반응을 정지시킨다.Carbonate gas with a carbon dioxide concentration of 20-30% by weight is passed through a liquid having a calcium hydroxide content adjusted to about 5.0% by weight as a calcium hydroxide solid (calcium hydroxide solid content 500kg, temperature 10-30 ° C) at a flow rate of 25m / min. Reaction occurs depending on the concentration of calcium hydroxide, temperature, carbon dioxide concentration and flow rate, but the reaction time is about 30 minutes and the average particle of calcium carbonate desired by electron microscope or particle size analyzer. When is produced, the injection of carbon dioxide gas is stopped to stop the reaction.
상기에서 제조된 탄산칼슘 수현탁액중의 탄산칼슘 고형분의 농도는 5.0중량% 정도이며 상이한 입자의 제조를 위하여 이하 가열처리하는 방법도 병용될 수 있다.The concentration of the calcium carbonate solids in the calcium carbonate aqueous suspension prepared above is about 5.0% by weight, and the following heat treatment may be used in combination for the production of different particles.
상기에서 제조된 탄산칼슘 수현탁액을 정치하여 탄산칼슘 미립자를 자유침강시켜서 상부에 분리된 물(정제수)를 제거하므로서 탄산칼슘 고형분의 농도를 12.0~15.0중량%까지 농축시키거나 원심분리 및 필터프레스 등으로 탈수시킨다.The calcium carbonate aqueous suspension prepared above is left to stand to freely settle the calcium carbonate fine particles to remove the separated water (purified water), thereby concentrating the concentration of the calcium carbonate solids to 12.0 to 15.0% by weight or by centrifugation and filter press. Dehydrate.
여기서, 탄산칼슘의 원료는 석회석, 대리석, 산석, 백암, 방해석, 빙주석, 산호, 패각, 골, 난각으로 구성된 그룹중 1종 이상이 포함되는 것이 바람직하다.Here, it is preferable that the raw material of calcium carbonate contains one or more of the group consisting of limestone, marble, rock, white rock, calcite, ice tin, coral, shell, bone, and egg shell.
이상 본 발명의 탄산칼슘의 제조공정에 대하여 간략히 살펴보았으며, 본 발명에 사용되는 탄산칼슘은, 칼슘질이 포함된 석회석(limestone) 등의 원료와 무연탄(coal), 가스 및 기름으로 소성(calcination)하여 생석회(CaO, quick lime)을 제조하고 물을 가하여 유화(slaking)시켜서 만든 수산화칼슘액(석회유, 石灰乳)에 탄산가스(CO2, carbonic acid gas)를 주입하여 탄산칼슘(CaCO3)으로 화학적으로 합성(chemical reaction)시키는 탄산가스법으로 대표되는 화학적 합성법에 의해 조제되는 콜로이달 탄산칼슘이 미세한 입자를 얻기 쉬운 점에서 가장 바람직하다.The manufacturing process of the calcium carbonate of the present invention has been briefly described, and the calcium carbonate used in the present invention is calcined from raw materials such as limestone, including calcium, and anthracite (coal), gas and oil. Calcium hydroxide (CaO, quick lime) to make calcium hydroxide solution (lime oil, Calcium) produced by adding water to the calcium carbonate (CO 2 , carbonic acid gas) is injected into calcium carbonate (CaCO 3 ) Colloidal calcium carbonate prepared by a chemical synthesis method represented by a carbon dioxide gas chemically synthesized is most preferred in that fine particles are easily obtained.
한편, 상기 탄산칼슘의 특성을 살펴보면 전반적으로 비중이 높아서 유제품중에 분산시킬 경우, 단시간에 침전하기 때문에 침전 등으로 식품의 미관과 제품의 특성에 악영향을 주며 pH의 변화 및 용해한 칼슘이온에 의한 단백질의 응집 등이 발생되어 다량으로 사용할 수 없는 두가지의 문제점을 가지고 있다.On the other hand, when looking at the characteristics of the calcium carbonate in general, the specific gravity is high, when dispersed in dairy products, because it precipitates in a short time, adversely affects the appearance of the food and the characteristics of the product by precipitation, etc. There are two problems that can not be used in a large amount due to the aggregation.
본 발명의 상기 아라비아검은 상기 탄산칼슘이 내포한 문제점 중 침전에 관한 문제점을 해결하기 위하여 첨가되는 것으로 공지의 기술내용이며 그 작용에 관하여 살펴보면, 상기 콜로이달 탄산칼슘이 우유 등의 식품에 첨가되었을 때, 입자의 표면에 코팅되어 분산성을 개선시킴으로써, 침전을 예방하기 위하여 첨가되는 것이다.The gum arabic of the present invention is known to be added to solve the problems related to precipitation among the problems contained in the calcium carbonate and look at the action, when the colloidal calcium carbonate is added to foods such as milk It is added to prevent precipitation by coating the surface of the particles to improve dispersibility.
자세하게는 본 발명의 상기 아라비아검은 상기에서 제조된 탄산칼슘 100 중량부(A)에 대하여 아라비아검(B)를 1~70 중량부를 가하여 탄산칼슘미립자 표면을 코팅한다.In detail, the gum arabic of the present invention adds 1 to 70 parts by weight of gum arabic (B) based on 100 parts by weight of the calcium carbonate prepared above to coat the surface of the calcium carbonate fine particles.
상기의 콜로이달 탄산칼슘(A)에 아라비아검(B)를 투입하여 탄산칼슘의 초미립자 표면에 코팅하는 방법으로는 교반, 용해, 가열, 호모믹스, 고압균질 등의 방법을 1종 이상 병행하여 완전히 용해하고 입자를 분리하여 코팅하는 것이 바람직하다. As a method of coating Arabian gum (B) into the colloidal calcium carbonate (A) and coating the surface of the ultrafine particles of calcium carbonate, one or more methods such as stirring, dissolving, heating, homomixing, and high pressure homogeneous are completely performed. It is preferable to dissolve and separate and coat the particles.
이때, 상기에서 코팅된 탄산칼슘액중에 함유되어 있는 이물질과 코팅되지 않거나 탄산칼슘의 평균입도가 큰 것을 제거하기 위하여 24시간 정도 액을 정치시켜서 침전된 이물질을 완전히 제거하는 것이 바람직하다.At this time, it is preferable to completely remove the precipitated foreign matter by standing the liquid for about 24 hours in order to remove the foreign matter contained in the coated calcium carbonate liquid and the uncoated or large average particle size of calcium carbonate.
상기 이물질의 제거된 탄산칼슘액을 탄산칼슘 고형분으로 1~60중량%가 되도록 조절하고 가열 살균하여 액상의 제품으로 포장하거나 건조분말화과정의 원료로 이용한다.The removed calcium carbonate liquid of the foreign matter is adjusted to 1 to 60% by weight as a calcium carbonate solid, heat sterilized and packaged as a liquid product or used as a raw material for dry powdering.
한편 상기 아라비아검의 첨가에도 불구하고 상기 탄산칼슘의 pH의 변화 및 상기 PH의 변화에 의하여 용해한 칼슘이온에 의한 단백질의 응집은 여전히 문제점으로 남아있다.Meanwhile, despite the addition of the gum arabic, the aggregation of the protein by calcium ions dissolved by the change of pH and the pH of the calcium carbonate still remains a problem.
본 발명은 상기 문제점을 해결하기 위하여 구연산염 및 인산염을 첨가함을 특징으로 하는데, 이 성분들은 pH 완충작용을 나타내어 식품중의 pH 상승을 억제시키고 또한 식품중에 해리된 2가의 칼슘이온(Ca2+)에 대하여 금속이온봉쇄작용을 나타내어 칼슘이온의 반응기를 봉쇄하여 단백질과의 반응성을 없애므로서 단백질의 변성, 점도의 증가, 커드의 발생 및 단백질 응어리가 식품 저변에 침전물의 형성 등의 문제점이 해결된다.The present invention is characterized in that the addition of citrate and phosphate to solve the above problems, these components exhibit a pH buffering action to suppress the rise in pH in foods and also dissociated bivalent calcium ions (Ca 2+ ) in foods By blocking the reaction of calcium ions by blocking the reaction of the metal ions by blocking the reaction of the protein with protein, the problems such as denaturation of protein, increase of viscosity, generation of curd and formation of protein cores on food base are solved. .
즉, 본 발명의 상기 인산나트륨염 및 인산칼륨염(C)은 상기 상기 탄산칼슘의 pH의 변화 및 상기 PH의 변화에 의하여 용해한 칼슘이온에 의한 단백질의 응집 문제점을 개선시키기 위하여 첨가되는 것으로서, 상기 코팅시에 발생되는 PH의 변화에 대한 완충작용과 금속이온과 식품성분 특히 단백질과의 반응성을 없애는 금속이온봉쇄제로 사용된다.That is, the sodium phosphate salt and potassium phosphate salt (C) of the present invention are added to improve the cohesion problem of the protein due to calcium ions dissolved by the change in pH of the calcium carbonate and the change in pH. It is used as a metal ion blocking agent to buffer the change of pH generated during coating and to eliminate the reactivity between metal ions and food ingredients, especially proteins.
자세하게는 상기 코팅된 탄산칼슘에 인산나트륨염 및 인산칼륨염(C) 군에서 적어도 1종 이상 또는 2종 이상을 병용하여 0.001~70 중량부 함유시켜 pH의 변화 및 용해한 칼슘이온에 의한 단백질의 응집 등을 방지하여 제품의 품질 안정성을 향상시킬 뿐만 아니라 식품의 풍미에 영향을 주지 않는 칼슘제재 액상 조성물 및 분말 조성물을 제공한다.In detail, the coated calcium carbonate contains 0.001 to 70 parts by weight of sodium phosphate salt and potassium phosphate salt (C) group in combination of at least one or two or more kinds thereof, thereby agglomeration of the protein by a change in pH and dissolved calcium ions. The present invention provides a calcium-based liquid composition and a powder composition, which prevents the product from improving the quality stability of the product and does not affect the flavor of the food.
또한 본 발명의 상기 구연산염은 모든 구연산염류를 사용할 수 있지만 특히 구연산삼나트륨 또는 구연산칼륨인 것과 인산염은 일인산나트륨, 이인산나트륨, 삼인산나트륨, 폴리인산나트륨, 폴리메타인산나트륨, sodium tripolyphosphate, sodium trimetaphosphate, 피로인산나트륨, 일인산칼륨, 이인산칼륨, 삼인산칼륨, 폴리인산칼륨, 메타인산칼륨, 폴리메타인산칼륨, 피로인산칼륨, potassium tripolyphosphate, potassium trimetaphosphate 등에서 구연산염과 인산염을 적어도 1종 이상 또는 2종 이상을 병용하여 사용하는 것이 바람직하다.In addition, the citrate of the present invention can be used for all citrates, in particular trisodium citrate or potassium citrate and phosphate is sodium monophosphate, sodium diphosphate, sodium triphosphate, sodium polyphosphate, sodium polymethphosphate, sodium tripolyphosphate, sodium trimetaphosphate At least one or two or more citrates and phosphates from sodium pyrophosphate, potassium monophosphate, potassium diphosphate, potassium triphosphate, potassium polyphosphate, potassium metaphosphate, potassium polymethphosphate, potassium pyrophosphate, potassium tripolyphosphate, potassium trimetaphosphate, etc. It is preferable to use together and use the above.
본 발명의 건조분말화는 분무건조, 동결건조, 진공건조 및 드럼건조 등의 일반적인 건조방식을 적어도 1종 또는 1종 이상인 것을 병용하여 건조분말화하여 식품첨가용 칼슘제재 분말조성물을 제공한다.The dry powderization of the present invention is to dry powderize by using at least one or more than one type of common drying methods such as spray drying, freeze drying, vacuum drying and drum drying to provide a calcium-based powder for food additives.
이상 설명한 본 발명에 의하여 녹는 유화제로 코팅하지 않고 아라비아검으로 코팅하여 가온 없이 낮은 온도에서도 응집되지 않고 잘 분산되며 그 조성물을 우유 등과 같은 제품에 첨가하여 살균공정 등과 같은 가열 처리시에 pH의 변화 및 용해한 칼슘이온에 의한 단백질의 응집 등을 방지시켜 식품 안정성을 향상시킨 고분산성의 식품첨가용 칼슘제재 조성물이 제공된다.According to the present invention described above, it is coated with arabic gum without coating with a soluble emulsifier and is not dispersed even at low temperature without heating. The composition is added to a product such as milk to change the pH during heat treatment such as sterilization process and Provided is a highly dispersible food additive calcium preparation composition which prevents aggregation of protein by dissolved calcium ions and improves food stability.
이하에 실시예를 예시하여 본 발명을 보다 상세하게 설명하나, 본 발명은 이들 실시예에만 한정되는 것은 아니다.Although an Example is given to the following and this invention is demonstrated to it in more detail, this invention is not limited only to these Examples.
실시예Example
실시예에서 사용하는 콜로이달 합성탄산칼슘의 제조는 일반적인 공지기술이므로 구체적인 제조방법은 생략할 수 있지만 그 일반적인 공지기술의 일례는 전술의 방법과 같다. Since the preparation of the colloidal synthetic calcium carbonate used in the embodiment is a general known technique, a specific manufacturing method may be omitted, but one example of the general known technique is the same as the above-described method.
실시예에서 사용하는 콜로이달 탄산칼슘의 제조방법을 이하에 예시한다.The manufacturing method of the colloidal calcium carbonate used by the Example is illustrated below.
콜로이달 탄산칼슘 제조방법 :How to prepare colloidal calcium carbonate:
80mm 정도로 조분쇄한 석회석 1톤에 무연탄을 90kg 섞어서 1,100℃에서 5시간 강하게 소성시키고 물을 10톤 가하여 수화한다. 90 kg of anthracite coal is mixed with 1 ton of limestone roughly crushed to about 80mm and calcined strongly at 1,100 ℃ for 5 hours and hydrated by adding 10 tons of water.
수화액을 325메쉬 정도의 가는 체로 체통 또는 원심분리하여 수화액중의 이물질을 제거하여 수산화칼슘액을 만든다. Calcium hydroxide is prepared by removing the foreign matter in the hydration solution by sieving or centrifuging the hydration solution with a thin sieve of about 325 mesh.
제조된 수산화칼슘액 10톤(액온도 25℃, 농도 5%)에 탄산가스농도 25 중량%의 가스를 20m/min의 유속으로 통과시켜 탄산화반응을 일으키고, 반응액은 20℃에서 pH 7.0으로 조절한다. A carbonation reaction is caused by passing a gas having a carbon dioxide concentration of 25% by weight at a flow rate of 20m / min through 10 tons of the calcium hydroxide solution (liquid temperature 25 ° C, concentration 5%), and the reaction solution is adjusted to pH 7.0 at 20 ° C. .
반응의 종결점은 반응액의 최종 pH는 7.0 부근이고 전자현미경으로 탄산칼슘의 평균입자경이 0.04㎛ 정도일 때, 탄산가스의 주입을 중단하여 반응을 정지시킨다. The end point of the reaction is to stop the reaction by stopping the injection of carbon dioxide gas when the final pH of the reaction solution is around 7.0 and the average particle diameter of calcium carbonate is about 0.04㎛ by electron microscope.
제조된 콜로이달 탄산칼슘 수현탁액중의 탄산칼슘 고형분의 농도는 5.0중량% 정도이다. The concentration of calcium carbonate solids in the prepared colloidal calcium carbonate aqueous suspension is about 5.0% by weight.
제조된 탄산칼슘 수현탁액을 정치하여 탄산칼슘 미립자를 자유침강시켜서 상부에 분리된 물(정제수)를 제거하므로서 농축시켜 콜로이달 탄산칼슘 수현탁액을 만들거나 필터프레스로 여과하여 케이크를 형성시켜 콜로이달 탄산칼슘을 얻었다.The prepared calcium carbonate aqueous suspension was left to stand, and the calcium carbonate fine particles were freely settled and concentrated by removing water (purified water) separated thereon to make a colloidal calcium carbonate aqueous suspension or filtered through a filter press to form a cake. Calcium was obtained.
실시예 1Example 1
상기에서 제조된 콜로이달 탄산칼슘 케이크를 물을 가하여 탄산칼슘의 농도가 20%되도록 조절한 액 5.0리터에 아라비아검 50g 및 구연산삼나트륨 0.1g을 서서히 투입하고 호모믹스탱크나 고속교반기를 이용하여 완전히 분산시킨 후, 12시간에서 24시간 정도 정치하여 이물질과 큰입자를 침전시키고 상층액을 취하여 제거한다. 50 g of gum arabic and 0.1 g of trisodium citrate were slowly added to a 5.0 liter solution of the colloidal calcium carbonate cake prepared above to add 20% calcium carbonate to water, and then completely mixed using a homomix tank or a high speed stirrer. After dispersion, the mixture is allowed to stand for 12 to 24 hours to precipitate foreign matter and large particles, and the supernatant is removed and removed.
이를 탄산칼슘 고형분으로 1~60 중량%가 되도록 농축하고 150～200bar로 고압균질한 후 식품의 일반적인 살균방식의 어떤 방법을 선택하여 살균한 후에 안정성을 향상시킨 식품첨가용 칼슘제재 액상 조성물을 제조하거나 분무건조기 등으로 건조하여 식품첨가용 칼슘제재 분말 조성물 975g을 얻었다. It is concentrated to 1 to 60% by weight as a calcium carbonate solid, homogenized to 150 to 200 bar, and then sterilized by selecting any method of general sterilization method of food to prepare a liquid food additive calcium composition for improved stability. It dried with the spray dryer, etc., and obtained 975 g of the calcium-based powder composition for food addition.
실시예 2Example 2
상기에서 제조된 콜로이달 탄산칼슘 케이크를 물을 가하여 탄산칼슘의 농도가 20%되도록 조절한 액 5.0리터에 아라비아검 50g 및 구연산칼륨 0.2g을 서서히 투입하고 이하는 실시예 1과 같은 방법으로 제조하여 안정성을 향상시킨 식품첨가용 칼슘제재 액상 조성물을 제조하거나 분말 조성물 979g을 얻었다. 50 g of arabic gum and 0.2 g of potassium citrate were gradually added to 5.0 liter of the colloidal calcium carbonate cake prepared above, which was added to water to adjust the concentration of calcium carbonate to 20%, and then prepared in the same manner as in Example 1. Calcium-added liquid-based liquid compositions for improving stability were prepared or 979 g of powder compositions were obtained.
실시예 3Example 3
상기에서 제조된 콜로이달 탄산칼슘 케이크를 물을 가하여 탄산칼슘의 농도가 20%되도록 조절한 액 5.0리터에 아라비아검 50g 및 일인산나트륨 0.15g을 서서히 투입하고 이하는 실시예 1과 같은 방법으로 제조하여 안정성을 향상시킨 식품첨가용 칼슘제재 액상 조성물을 제조하거나 분말 조성물 977g을 얻었다. To the colloidal calcium carbonate cake prepared above was added 50 g of arabic gum and 0.15 g of sodium monophosphate slowly to 5.0 liters of water adjusted to a concentration of 20% calcium carbonate, which was prepared in the same manner as in Example 1. To prepare a food additive calcium formulation liquid composition improved stability or to obtain a powder composition 977g.
실시예 4Example 4
상기에서 제조된 콜로이달 탄산칼슘 케이크를 물을 가하여 탄산칼슘의 농도가 20%되도록 조절한 액 5.0리터에 아라비아검 50g 및 이인산나트륨 0.15g을 서서히 투입하고 이하는 실시예 1과 같은 방법으로 제조하여 안정성을 향상시킨 식품첨가용 칼슘제재 액상 조성물을 제조하거나 분말 조성물 967g을 얻었다. To the colloidal calcium carbonate cake prepared above, 50 g of gum arabic and 0.15 g of sodium diphosphate were slowly added to 5.0 liter of a solution adjusted to 20% calcium carbonate by adding water, followed by preparing in the same manner as in Example 1. To prepare a food additive calcium formulation liquid composition improved stability or to obtain a powder composition 967g.
실시예 5Example 5
상기에서 제조된 콜로이달 탄산칼슘 케이크를 물을 가하여 탄산칼슘의 농도가 20%되도록 조절한 액 5.0리터에 아라비아검 50g 및 삼인산나트륨 0.17g을 서서히 투입하고 이하는 실시예 1과 같은 방법으로 제조하여 안정성을 향상시킨 식품첨가용 칼슘제재 액상 조성물을 제조하거나 분말 조성물 982g을 얻었다. 50 g of gum arabic and 0.17 g of sodium triphosphate were slowly added to 5.0 liter of the colloidal calcium carbonate cake prepared above to adjust the concentration of calcium carbonate to 20% by adding water, and then prepared in the same manner as in Example 1. Calcium-based liquid formulations for food additives having improved stability were prepared or 982 g of powder compositions were obtained.
실시예 6Example 6
상기에서 제조된 콜로이달 탄산칼슘 케이크를 물을 가하여 탄산칼슘의 농도가 20%되도록 조절한 액 5.0리터에 아라비아검 50g 및 폴리인산나트륨 0.1g을 서서히 투입하고 이하는 실시예 1과 같은 방법으로 제조하여 안정성을 향상시킨 식품첨가용 칼슘제재 액상 조성물을 제조하거나 분말 조성물 973g을 얻었다. 50 g of gum arabic and 0.1 g of sodium polyphosphate were slowly added to 5.0 liter of the colloidal calcium carbonate cake prepared above to adjust the concentration of calcium carbonate to 20% by adding water, followed by the same method as in Example 1. To prepare a food additive calcium formulation liquid composition improved stability or to obtain a powder composition 973g.
실시예 7Example 7
상기에서 제조된 콜로이달 탄산칼슘 케이크를 물을 가하여 탄산칼슘의 농도가 20%되도록 조절한 액 5.0리터에 아라비아검 50g 및 폴리메타인산나트륨 0.1g을 서서히 투입하고 이하는 실시예 1과 같은 방법으로 제조하여 안정성을 향상시킨 식품첨가용 칼슘제재 액상 조성물을 제조하거나 분말 조성물 965g을 얻었다. 50 g of gum arabic and 0.1 g of sodium polymethaphosphate were slowly added to 5.0 liter of the colloidal calcium carbonate cake prepared above to adjust the concentration of calcium carbonate to 20% by adding water, and then in the same manner as in Example 1 To prepare a food-added calcium-based liquid composition for improving the stability or to obtain a powder composition 965g.
실시예 8Example 8
상기에서 제조된 콜로이달 탄산칼슘 케이크를 물을 가하여 탄산칼슘의 농도가 20%되도록 조절한 액 5.0리터에 아라비아검 50g 및 sodium tripolyphosphate 0.1g을 서서히 투입하고 이하는 실시예 1과 같은 방법으로 제조하여 안정성을 향상시킨 식품첨가용 칼슘제재 액상 조성물을 제조하거나 분말 조성물 978g을 얻었다. To the colloidal calcium carbonate cake prepared above, 50 g of gum arabic and 0.1 g of sodium tripolyphosphate were slowly added to 5.0 liter of a solution adjusted to 20% calcium carbonate by adding water, followed by preparing in the same manner as in Example 1 Calcium-added liquid-based liquid compositions for improving stability were prepared or 978g of powder compositions were obtained.
실시예 9Example 9
상기에서 제조된 콜로이달 탄산칼슘 케이크를 물을 가하여 탄산칼슘의 농도가 20%되도록 조절한 액 5.0리터에 아라비아검 50g 및 sodium trimetaphosphate 0.1g을 서서히 투입하고 이하는 실시예 1과 같은 방법으로 제조하여 안정성을 향상시킨 식품첨가용 칼슘제재 액상 조성물을 제조하거나 분말 조성물 955g을 얻었다. To the colloidal calcium carbonate cake prepared above, 50 g of gum arabic and 0.1 g of sodium trimetaphosphate were slowly added to 5.0 liter of a solution adjusted to 20% calcium carbonate by adding water to prepare the same method as in Example 1 below. Calcium powder or liquid composition for food additives having improved stability was prepared or 955 g of powder composition was obtained.
실시예 10Example 10
상기에서 제조된 콜로이달 탄산칼슘 케이크를 물을 가하여 탄산칼슘의 농도가 20%되도록 조절한 액 5.0리터에 아라비아검 50g 및 피로인산나트륨 0.1g을 서서히 투입하고 이하는 실시예 1과 같은 방법으로 제조하여 안정성을 향상시킨 식품첨가용 칼슘제재 액상 조성물을 제조하거나 분말 조성물 979g을 얻었다. 50 g of gum arabic and 0.1 g of sodium pyrophosphate were slowly added to 5.0 liter of the colloidal calcium carbonate cake prepared above to adjust the concentration of calcium carbonate to 20% by adding water, followed by the same method as in Example 1. To prepare a food additive calcium formulation liquid composition improved stability or to obtain a powder composition 979g.
실시예 11Example 11
상기에서 제조된 콜로이달 탄산칼슘 케이크를 물을 가하여 탄산칼슘의 농도가 20%되도록 조절한 액 5.0리터에 아라비아검 50g 및 삼인산칼륨 0.1g을 서서히 투입하고 이하는 실시예 1과 같은 방법으로 제조하여 안정성을 향상시킨 식품첨가용 칼슘제재 액상 조성물을 제조하거나 분말 조성물 965g을 얻었다. 50 g of gum arabic and 0.1 g of potassium triphosphate were slowly added to 5.0 liter of the colloidal calcium carbonate cake prepared above to adjust the concentration of calcium carbonate to 20% by adding water, and then prepared in the same manner as in Example 1. Calcium powder or liquid composition for food additives with improved stability was prepared or 965 g of powder composition was obtained.
실시예 12Example 12
상기에서 제조된 콜로이달 탄산칼슘 케이크를 물을 가하여 탄산칼슘의 농도가 20%되도록 조절한 액 5.0리터에 아라비아검 50g 및 폴리인산칼륨 0.1g을 서서히 투입하고 이하는 실시예 1과 같은 방법으로 제조하여 안정성을 향상시킨 식품첨가용 칼슘제재 액상 조성물을 제조하거나 분말 조성물 988g을 얻었다. 50 g of gum arabic and 0.1 g of potassium polyphosphate were slowly added to 5.0 liter of the colloidal calcium carbonate cake prepared above to adjust the concentration of calcium carbonate to 20% by adding water, followed by preparing in the same manner as in Example 1. To prepare a food additive calcium formulation liquid composition improved stability or to obtain a powder composition 988g.
실시예 13Example 13
상기에서 제조된 콜로이달 탄산칼슘 케이크를 물을 가하여 탄산칼슘의 농도가 20%되도록 조절한 액 5.0리터에 아라비아검 50g 및 메타인산칼륨 0.1g을 서서히 투입하고 이하는 실시예 1과 같은 방법으로 제조하여 안정성을 향상시킨 식품첨가용 칼슘제재 액상 조성물을 제조하거나 분말 조성물 983g을 얻었다. 50 g of gum arabic and 0.1 g of potassium metaphosphate were slowly added to 5.0 liter of the colloidal calcium carbonate cake prepared above to adjust the concentration of calcium carbonate to 20% by adding water, followed by the same method as in Example 1. To prepare a food additive calcium formulation liquid composition improved stability or to obtain a powder composition 983g.
실시예 14Example 14
상기에서 제조된 콜로이달 탄산칼슘 케이크를 물을 가하여 탄산칼슘의 농도가 20%되도록 조절한 액 5.0리터에 아라비아검 50g 및 폴리메타인산칼륨 0.1g을 서서히 투입하고 이하는 실시예 1과 같은 방법으로 제조하여 안정성을 향상시킨 식품첨가용 칼슘제재 액상 조성물을 제조하거나 분말 조성물 958g을 얻었다. 50 g of gum arabic and 0.1 g of potassium polymethaphosphate were slowly added to 5.0 liter of the colloidal calcium carbonate cake prepared above, which was adjusted to 20% calcium carbonate by adding water, and then in the same manner as in Example 1 To prepare a food additive calcium formulation liquid composition improved stability or to obtain a powder composition 958g.
실시예 15Example 15
상기에서 제조된 콜로이달 탄산칼슘 케이크를 물을 가하여 탄산칼슘의 농도가 20%되도록 조절한 액 5.0리터에 아라비아검 50g 및 피로인산칼륨 0.1g을 서서히 투입하고 이하는 실시예 1과 같은 방법으로 제조하여 안정성을 향상시킨 식품첨가용 칼슘제재 액상 조성물을 제조하거나 분말 조성물 966g을 얻었다. 50 g of gum arabic and 0.1 g of potassium pyrophosphate were slowly added to 5.0 liter of the colloidal calcium carbonate cake prepared above to adjust the concentration of calcium carbonate to 20% by adding water, followed by the same method as in Example 1. To prepare a food additive calcium formulation liquid composition improved stability or to obtain a powder composition 966g.
실시예 16Example 16
상기에서 제조된 콜로이달 탄산칼슘 케이크를 물을 가하여 탄산칼슘의 농도가 20%되도록 조절한 액 5.0리터에 아라비아검 50g 및 potassium tripolyphosphate 0.1g을 서서히 투입하고 이하는 실시예 1과 같은 방법으로 제조하여 안정성을 향상시킨 식품첨가용 칼슘제재 액상 조성물을 제조하거나 분말 조성물 961g을 얻었다. To the colloidal calcium carbonate cake prepared above was added 50 g of arabic gum and 0.1 g of potassium tripolyphosphate to 5.0 liter of liquid adjusted to a concentration of 20% calcium carbonate by adding water, followed by preparing in the same manner as in Example 1 A calcium-based liquid composition for food additives having improved stability was prepared or 961 g of a powder composition was obtained.
실시예 17Example 17
상기에서 제조된 콜로이달 탄산칼슘 케이크를 물을 가하여 탄산칼슘의 농도가 20%되도록 조절한 액 5.0리터에 아라비아검 50g 및 potassium trimetaphosphate 0.1g을 서서히 투입하고 이하는 실시예 1과 같은 방법으로 제조하여 안정성을 향상시킨 식품첨가용 칼슘제재 액상 조성물을 제조하거나 분말 조성물 959g을 얻었다. 50 g of gum arabic and 0.1 g of potassium trimetaphosphate were slowly added to 5.0 liter of the colloidal calcium carbonate cake prepared above to adjust the concentration of calcium carbonate to 20% by adding water, and then prepared in the same manner as in Example 1. Calcium powder or liquid composition for food additives having improved stability was prepared or 959 g of powder composition was obtained.
실시예 18Example 18
상기에서 제조된 콜로이달 탄산칼슘 케이크를 물을 가하여 탄산칼슘의 농도가 20%되도록 조절한 액 5.0리터에 아라비아검 50g 및 구연산삼나트륨 0.07g과 폴리인산나트륨 0.1g을 병용하여 서서히 투입하고 이하는 실시예 1과 같은 방법으로 제조하여 안정성을 향상시킨 식품첨가용 칼슘제재 액상 조성물을 제조하거나 분말 조성물 970g을 얻었다. To the colloidal calcium carbonate cake prepared above was added 50 g of gum arabic, 0.07 g of trisodium citrate and 0.1 g of sodium polyphosphate to 5.0 liters of water, adjusted to 20% calcium carbonate by adding water. Prepared in the same manner as in Example 1 to prepare a food additive calcium formulation liquid composition improved stability or to obtain a powder composition 970g.
실시예 19Example 19
상기에서 제조된 콜로이달 탄산칼슘 케이크를 물을 가하여 탄산칼슘의 농도가 20%되도록 조절한 액 5.0리터에 아라비아검 50g 및 구연산칼륨 0.05g과 sodium tripolyphosphate 0.1g을 병용하여 서서히 투입하고 이하는 실시예 1과 같은 방법으로 제조하여 안정성을 향상시킨 식품첨가용 칼슘제재 액상 조성물을 제조하거나 분말 조성물 972g을 얻었다. To the colloidal calcium carbonate cake prepared above, 50 g of gum arabic, 0.05 g of potassium citrate, and 0.1 g of sodium tripolyphosphate were added slowly to 5.0 liter of the solution adjusted to 20% calcium carbonate by adding water. Prepared in the same manner as in 1 to prepare a food additive calcium formulation liquid composition improved stability or to obtain a powder composition 972g.
실시예 20Example 20
상기에서 제조된 콜로이달 탄산칼슘 케이크를 물을 가하여 탄산칼슘의 농도가 20%되도록 조절한 액 5.0리터에 아라비아검 50g 및 구연산칼륨 0.05g과 potassium tripolyphosphate 0.1g을 병용하여 서서히 투입하고 이하는 실시예 1과 같은 방법으로 제조하여 안정성을 향상시킨 식품첨가용 칼슘제재 액상 조성물을 제조하거나 분말 조성물 958g을 얻었다.To the colloidal calcium carbonate cake prepared above was added 50 g of gum arabic, 0.05 g of potassium citrate and 0.1 g of potassium tripolyphosphate in a 5.0 liter solution adjusted to a concentration of 20% calcium carbonate by adding water to the following examples. Prepared in the same manner as in 1 to prepare a food additive calcium formulation liquid composition improved stability or to obtain a powder composition 958g.
다음의 표 1은 상기 본 발명의 실시예에서 제조된 안정성을 향상시킨 고분산성의 식품첨가용 칼슘제재 조성물의 이화학적 특성에 관한 도표이다.Table 1 below shows the above It is a diagram regarding the physicochemical properties of the highly dispersible food additive calcium preparation composition prepared in the embodiment of the present invention.
[표 1]TABLE 1
다음의 표 2는 본 발명의 상기 실시예에서 제조된 안정성을 향상시킨 고분산성의 식품첨가용 칼슘제재 조성물의 분산안정성(계면의 높이와 침전물량)을 조사하여 정리한 것이다.The following Table 2 summarizes the dispersion stability (interface height and precipitate amount) of the highly dispersible food additive calcium preparation composition prepared in the above embodiment of the present invention.
표 2는 실시예 1~20에서 조제한 안정성을 향상시킨 고분산성의 식품첨가용 칼슘제재 조성물을 사용하여 각 칼슘제의 고형분 농도가 1.0 중량%가 되도록 희석하여 3,500rpm에서 10분간 호모믹스한 후에 그 희석액을 100ml의 메스실린더에 취하여 5℃로 정치하고, 탄산칼슘의 침전에 의해 생기는 투명 부분과 칼슘제 분산부분의 착색부분 계면 높이의 경시변화, 침전물량의 경시변화를 육안으로 관찰하여 판단하고 각 분산액의 장기 저장시의 분산안정성을 조사하였다. Table 2 is diluted using a highly dispersible food additive calcium preparation composition prepared in Examples 1 to 20 so that the solid content concentration of each calcium agent is 1.0% by weight, homomixed at 3,500 rpm for 10 minutes, and then the diluted solution. In a 100 ml measuring cylinder, the mixture was allowed to stand at 5 ° C. The change in the interfacial height of the transparent portion and the colored portion of the calcium-dispersed portion caused by precipitation of calcium carbonate and the change of sediment amount over time were visually judged. The dispersion stability during long-term storage was investigated.
메스실린더에 새겨진 ml 단위 표시를 읽어 그 결과를 하기 5단계의 표시에 의해 표 2에 나타낸다. The ml unit mark engraved on the measuring cylinder was read and the result is shown in Table 2 by the following five-step display.
(계면의 높이)(Height of the interface)
98 이상 100 ------------------------ 598 and over 100 ------------------------ 5
95 이상 98 미만 --------------------- 495 or more and less than 98 --------------------- 4
90 이상 95 미만 --------------------- 390 or more and less than 95 --------------------- 3
50 이상 90 미만 --------------------- 250 or more and less than 90 --------------------- 2
50 미만 ---------------------------- 1Less than 50 ---------------------------- 1
(침전물량)(Sedimentation quantity)
거의 침전이 확인되지 않음 -------------- 5Almost no precipitation confirmed -------------- 5
약간 침전이 확인됨 ------------------- 4Slight precipitation is observed ------------------- 4
0.5 미만 정도의 침전이 있음 ------------ 3Precipitation of less than 0.5 ------------ 3
0.5 이상 2.0 미만의 침전이 있음 --------- 2More than 0.5 and less than 2.0 --------- 2
2.0 이상의 침전이 있음 ---------------- 1There is more than 2.0 precipitation ---------------- 1
[표 2]TABLE 2
다음의 표 3은 본 발명에 따라 실시예에서 제조된 안정성을 향상시킨 고분산성의 식품첨가용 칼슘제재 조성물로 칼슘강화우유를 제조할 때의 침전물량과 풍미의 변화를 기록한 도표이다.The following Table 3 is a chart recording the changes in the amount of precipitate and flavor when preparing calcium fortified milk with a highly dispersible food additive calcium preparation composition prepared in Example according to the present invention.
이를 위하여 상기 실시예 1~20에서 조제한 안정성을 향상시킨 고분산성의 식품첨가용 칼슘제재 조성물 10.0g을 시유 1,000ml에 첨가하여 170bar로 균질한 후에 살균하여 칼슘강화 우유를 얻었다. To this end, 10.0 g of the highly dispersible food additive calcium preparation composition prepared in Examples 1 to 20 was added to 1,000 ml of milk powder, homogenized to 170 bar, and then sterilized to obtain calcium fortified milk.
그 칼슘강화우유를 100ml의 수개의 메스실린더에 취하여 5℃로 보존하면서 정기적으로 메스실린더중의 우유를 조용히 폐기하고, 메스실린더 저부에 잔존해 있는 침전물량의 경시변화를 육안으로 관찰하였다. The calcium-enriched milk was taken in several 100 ml measuring cylinders, and the milk in the measuring cylinders was silently discarded at regular intervals while being kept at 5 ° C.
그 결과를 하기 4단계 표시로 표 3에 나타낸다. The result is shown in Table 3 by the following four-step display.
또, 그 칼슘강화우유를 남녀 각 10명에 의해 이루어진 관능시험을 행하여 식감에 관하여 각각 5단계 판정을 하여 그 평균치를 표 3에 나타낸다.The calcium-enriched milk was subjected to a sensory test conducted by 10 men and women, and five levels were determined for the texture. The average values are shown in Table 3.
(침전물량)(Sedimentation quantity)
거의 침전이 확인되지 않음 -------------- 4Almost no precipitation found -------------- 4
약간 침전이 관찰됨 ------------------- 3Slight precipitation is observed ------------------- 3
다소 침전이 관찰됨 ------------------- 2Some precipitation is observed ------------------- 2
상당한 침전이 관찰됨 ------------------ 1Significant precipitation is observed ------------------ 1
(풍미)(zest)
풍미가 양호함 ----------------------- 5Good flavor ----------------------- 5
풍미가 약간 이상함 ------------------- 4Slightly strange flavor ------------------- 4
풍미가 다소 나쁨(약간의 불쾌감) --------- 3Slightly bad flavor (slightly unpleasant) --------- 3
풍미가 상당히 나쁨(상당한 불쾌감) --------2The flavor is considerably bad (a considerable displeasure) -------- 2
풍미가 매우 나쁨 --------------------- 1Flavor is very bad --------------------- 1
[표 3]TABLE 3
다음의 표 4는 본 발명에 따라 실시예에서 제조된 안정성을 향상시킨 고분산성의 식품첨가용 칼슘제재 조성물로 칼슘강화용 롱라이프우유를 제조할 때의 침전물량과 식감의 변화를 조사한 것이다.Table 4 is to investigate the changes in the amount of precipitate and texture when preparing a calcium-enhanced long-life milk with a highly dispersed food additive calcium preparation composition prepared in Example according to the present invention.
표 4의 작성을 위하여 실시예 1~20에서 조제한 안정성을 향상시킨 고분산성의 식품첨가용 칼슘제재 조성물 10.0g을 시유 1,000ml에 첨가하여 170bar로 균질한 후에 초고온순간살균(UHT)후 칼슘강화용 롱라이프우유를 얻었다. 10.0 g of a highly dispersible food additive calcium preparation composition prepared in Examples 1 to 20 for the preparation of Table 4 was added to 1,000 ml of milk powder and homogenized at 170 bar, followed by ultra high temperature sterilization (UHT) for calcium fortification. Obtained Long Life Milk.
그 롱라이프우유를 100ml의 수개의 메스실린더에 취하여 5℃로 보존하면서 정기적으로 메스실린더중의 우유를 조용히 폐기하고, 메스실린더 저부에 잔존해 있는 침전물량의 경시변화를 육안으로 관찰하였다. The long-life milk was taken in several 100 ml measuring cylinders, and the milk in the measuring cylinders was silently discarded at regular intervals while being kept at 5 ° C. The change over time of the amount of precipitate remaining in the bottom of the measuring cylinder was visually observed.
그 결과를 하기 4단계 표시로 표 4에 나타낸다. The results are shown in Table 4 by the following four-step display.
또, 그 칼슘강화우유를 남녀 각 10명에 의해 이루어진 관능시험을 행하여 식감에 관하여 각각 4단계 판정을 하여 그 평균치를 표 4에 나타낸다.In addition, the calcium-enriched milk was subjected to a sensory test made by 10 men and women, each of which was subjected to four stages of determination of the texture, and the average is shown in Table 4.
(침전물량)(Sedimentation quantity)
거의 침전이 확인되지 않음 -------------- 4Almost no precipitation found -------------- 4
약간 침전이 관찰됨 ------------------- 3Slight precipitation is observed ------------------- 3
다소 침전이 관찰됨 ------------------- 2Some precipitation is observed ------------------- 2
상당한 침전이 관찰됨 ------------------ 1Significant precipitation is observed ------------------ 1
(식감)(Texture)
식감이 매우 양호함 ------------------- 4Very good texture ------------------- 4
점도가 다소 높고 조금 깔끔거림 ---------- 3Viscosity is somewhat high and a little neat ---------- 3
점도가 상당히 높고 매우 깔끔거림 -------- 2Viscosity quite high and very clean -------- 2
식감이 상당히 나쁨(매우 깔끔거림) -------- 1The texture is quite bad (very neat) -------- 1
[표 4]TABLE 4
다음의 표 5는 본 발명에 따라 실시예에서 제조된 안정성을 향상시킨 고분산성의 식품첨가용 칼슘제재 조성물로 칼슘강화우유를 제조할 때의 pH와 커드생성유무의 변화를 표로 작성한 것이다. Table 5 below is a table of the change in pH and curd production when producing calcium-enhanced milk with a highly dispersible food additive calcium preparation composition prepared in Example according to the present invention.
표 5의 작성을 위하여 실시예 1~20에서 조제한 안정성을 향상시킨 고분산성의 식품첨가용 칼슘제재 조성물 10.0g을 시유 1,000ml에 첨가하여 80℃에서 15분간 가열살균하여 칼슘강화우유를 얻었다. To prepare Table 5, 10.0 g of a highly dispersible calcium food additive composition having improved stability prepared in Examples 1 to 20 was added to 1,000 ml of milk powder and sterilized by heating at 80 ° C. for 15 minutes to obtain calcium fortified milk.
그 칼슘강화우유를 100ml의 수개의 메스실린더에 취하여 5℃로 보존하면서 정기적으로 pH를 측정하고 또 용해한 칼슘이온과 pH 상승에 의해 생성되는 응어리(단백질커드)의 생성여부를 판단하기 위하여 메스실린더중의 우유를 조용히 폐기하고, 메스실린더 저부에 잔존해 있는 침전형성물을 육안으로 관찰하여 그 결과를 표 5에 나타내었다.The calcium-enriched milk is taken in several 100 ml measuring cylinders and stored at 5 ° C. to periodically measure the pH, and to determine whether or not the core (protein curd) produced by dissolved calcium ions and pH rises. The milk of was quietly discarded and the precipitate formed at the bottom of the measuring cylinder was visually observed and the results are shown in Table 5.
[표 5]TABLE 5
상기 설명한 본 발명에 의하여 화학적 합성법에 의해 제조된 콜로이달 탄산칼슘의 초미립자에 아라비아검으로 표면코팅을 하고 pH 완충작용과 금속이온 봉쇄제인 인산염류를 첨가함을 통하여 안정성을 향상시킨 고분산성의 식품첨가용 칼슘제재 조성물이 제공되는 이익이 있다. Addition of highly dispersible food added to the ultrafine particles of the colloidal calcium carbonate prepared by the chemical synthesis method described above by arabic gum and improving the stability through the addition of phosphates, pH buffering and metal ion sequestrants There is a benefit to provide a calcium formulation for use.
또한, 재분산성과 장기간의 분산안정성을 유지할 뿐만아니라 관능평가를 통하여 풍미에 있어서 극히 우수하여 고농도로 첨가가 가능하고 경제적으로도 유리한 고분산성의 식품첨가용 칼슘제재 조성물이 제공되는 이익이 있다.In addition, the redispersibility and long-term dispersion stability is maintained, as well as through the sensory evaluation, it is extremely excellent in flavor, can be added at a high concentration, and there is an advantage in providing a highly dispersible food additive calcium preparation composition economically.
그리고 pH의 변화 및 용해한 칼슘이온에 의한 단백질의 응집 등을 방지하여 제품의 품질 안정성을 향상시킨 고분산성의 식품첨가용 칼슘제재 조성물을 제조함에 의해 일반식품용, 건강보조식품 및 특수영양식품, 치약 등과 같은 생활용품, 화장품 및 의약품의 원료로 사용 가능하며, 요쿠르트, 치즈, 우유 등과 같은 유제품과 쥬스류 등의 식품에 첨가하여 칼슘을 강화하는데 이용 가능한 고분산성의 식품첨가용 칼슘제재 조성물이 제공되는 이익이 있다.In addition, by preparing a highly dispersible calcium additive composition for improving food quality by preventing pH changes and agglomeration of proteins by dissolved calcium ions, general foods, dietary supplements, special nutritional products, and toothpaste It can be used as a raw material for daily necessities, cosmetics and medicines, etc., and can be added to dairy foods such as yogurt, cheese, milk, etc., and used for foods such as juices to provide a highly dispersible food additive calcium preparation composition. There is this.
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| KR20060066009A (en) | 2006-06-15 |
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