KR100626752B1 - manufacturing method substance of fragrant resin to continue odor - Google Patents

Abstract

The present invention relates to a method for producing a fragrance resin and a composition of which the fragrance is preserved for a long time. More specifically, the present invention relates to a plastic raw material such as polyethylene (PE), polypropylene (PP), polyurethane (polyurethane), and polyethylene terephthalate ( Polyethylene Terephthalate (PET), Polybutylene Terephthalate (PBT), Polyvinyl Acetate, and any one selected from the group of oil-flavored peppermint, lavender, sol, rose, jasmine, freesia, acacia, Violet, lilac, flavono, rosemary, apple, grape, banana, orange, mango, strawberry, cherry, lemon, phytoncide, plum, quince, wormwood, pheromone, chocolate, coffee, vanilla, cola, olive, grazilia, Any one selected from the group consisting of natural and artificial flavors such as Hesslot, Ginseng and Lime, and granite, rhyolite, andesite, sandstone, sha It is made by mixing any one selected from the group consisting of work, limestone, dolomite, surrogate, talc, hard coal, zeolite, bentonite, and polyacrylic acid, and polyethylene wax, a fixing and coating agent, and polyethylene, a plastic raw material. PE), Polypropylene (PP), Polyurethane, Polyethylene Terephthalate (PET), Polybutylene Terephthalate (PBT), Polyvinyl Acetate Choose any of the oil flavored peppermint, lavender, sol, rose, jasmine, freesia, acacia, violet, lilac, flavono, rosemary, apple, grape, banana, orange, mango, strawberry, cherry, lemon, phytoncide, plum, quince Natural and artificial flavors such as mugwort, pheromone, chocolate, coffee, vanilla, cola, olive, grazilia, hazelt, ginseng and lime It is deposited on any one selected from the group consisting of to absorb the fragrance in any one of the plastic raw material, kneading and heating the polyethylene wax, which is a fixing agent to the plastic raw material absorbed by the fragrance, and coated with the impregnated plastic surface to produce a plastic raw material And any one selected from the group consisting of granite, rhyolite, andesite, sandstone, shale, limestone, dolomite, surrogate, talc, hard coal, zeolite, bentonite, polyacrylic acid and peppermint, oil flavored peppermint, lavender , Sol, rose, jasmine, freesia, acacia, violet, lilac, flavono, rosemary, apple, grape, banana, orange, mango, strawberry, cherry, lemon, phytoncide, plum, quince, mugwort, pheromone, chocolate, coffee Selected from the group consisting of natural and artificial flavors such as vanilla, cola, olive, grazilia, hazelt, ginseng and lime After immersion for one and then coating the surface aggregates hyangpo kneaded, heated by impregnating the polyethylene wax will be obtained in the present invention as the zoom continues to kneading and then added to the plastic raw material.

The present invention obtained as described above is very excellent in fragrance fragrance and durability and can maximize the effect by a simple production method, it is economical and can be extended to everyone, especially stuffed doll material, pillow material or incense or flowers By storing them in pots of ornamental trees that do not bloom, it is possible to pursue a sense of stability and high-quality products by allowing them to continuously feel the fragrance in the long term.

Polyethylene, polypropylene, fragrance aggregates, oil fragrances, fragrance resins.

Description

Manufacturing method substance of fragrant resin to continue odor}

The present invention relates to a fragrance, in more detail, a plastic raw material of polyethylene (PE), polypropylene (PP), polyurethane (Polyurethane), polyethylene terephthalate (Polyethylene Terephthalate, PET), polybutylene tere Any one selected from the group consisting of phthalate (Polybutylene Terephthalate (PBT), Polyvinyl Acetate) and oil flavored peppermint, lavender, sol, rose, jasmine, freesia, acacia, violet, lilac, flavono, rosemary, apple Natural and artificial such as grape, banana, orange, mango, strawberry, cherry, lemon, phytoncide, plum, quince, mugwort, pheromone, chocolate, coffee, vanilla, cola, olive, grazilia, hazelt, ginseng, lime Any one selected from the group consisting of incense and incense collection granite, rhyolite, andesite, sandstone, shale, limestone, dolomite, surrogate rock, talc, hard coal, zeolite , Bentonite, silica, silica gel, dextrin (Dextrin), polyacrylic acid (Polycrylic acid) any one selected from the group consisting of a mixture of polystyrene wax as a fixing and coating agent is excellent in fragrance and persistence and easy manufacturing method It can maximize the effect and is economical, so it can be extended to your field. Especially, it is stored in stuffed stuffed material or flower pots of incense or flowers that do not bloom. It relates to a method for producing a long-lasting fragrance resin.

In general, resins such as plastics generally have odorless or intrinsic odors due to the characteristics of petrochemical products. In the past, plastics have been extruded. And post-injection processing is common. At this time, the processing temperature is higher than the boiling point of the fragrance component, so it is hard to see the natural effect due to the volatility caused by the volatilization during processing or the heat of processing. You have a hard time.

The initial technology of injecting fragrance into plastics includes the method of injecting fragrance during processing and dipping plastic raw materials into oil fragrance, but first, extrusion (eg vinyl production) or injection (extrusion after deposition). ) And injection after extrusion (e.g., Patent Publication No. 2001-35366), because of the characteristics of the plastic raw material, the temperature is applied and the effect is small despite the high cost as the fragrance evaporates during processing. The fragrance emanates only from the surface of the product, which reduces the economy and durability. On the other hand, the method of immersing oil-absorbing and hygroscopic plastic raw materials in oil fragrance is cheaper than the pressure and injection method, but the effect of sustainability and product surface is inferior. There is a problem in that the value of the product decreases due to volatility during the drying itself or after processing (pressure, injection).

Therefore, looking at the prior art already filed in order to solve the above problems, Utility Model Registration No. 174010 proposes a method for producing a fragrant vinyl by administering the fragrance to the regeneration resin, but in this way There is a problem that efficiency and persistence are significantly lower than the input amount of the fragrance because the processing temperature is lower, and Patent Publication No. 1992-9267 describes the durable fragrance-dispersing method, but polyester yarn containing a silica oxide compound for maintaining durability It is not only limited to use as a method of preparing a high-cost microcapsule and to form a micro crete on the surface, there is a problem of high cost in the production.

In addition, in Korean Patent Publication No. 2001-35366, a fragrance powder is prepared, and the reaction resin is encapsulated in the addition / emulsification state of the wall resin and the surfactant, and then dried and impregnated in the fragrance powder. Although it is a method of manufacturing pellets, this also has a complicated manufacturing process and expensive raw materials such as microcapsule fragrance, which limits the use range. This is accompanied by post-processing of plastic raw materials at high temperatures such as extrusion and injection. It is a manufacturing method in consideration of the fact that the manufacturing process is long and expensive microcapsule flavor should be used to improve the sustainability slightly.

On the other hand, Patent Publication No. 2001-48771 relates to the coating composition of the microcapsule fragrance, by dispersing the microcapsule fragrance in the solvent and coating it on the surface of the product. There is a restriction to use microcapsule flavor.

In addition, Patent Publication No. 2001-70876 discloses a fragrance resin composition in which 3 to 5 parts by weight of a fragrance agent is mixed and melted in a synthetic resin raw material, but this also has problems in efficiency and durability.

The fragrance resin manufacturing method and the composition of the present invention, the fragrance is preserved for a long time is a method of producing a material that can be applied to the use that utilizes the characteristics of the raw material itself, deviating from the fixed concept of the plastic raw material, the fragrance fragrance and persistence It is very excellent and easy to make and maximize the effect. It is economical and can be extended to you. Especially, it is stored in stuffed doll material or flower pot of incense or flowers that do not bloom. The goal is to provide a fragrance resin manufacturing method that preserves the scent and maintains the fragrance for a long time.

Specific means for achieving the above object is [100 parts by weight of granite, 100 parts by weight of rhyolite, 100 parts by weight of andesite, 100 parts by weight of sandstone, 100 parts by weight of shale, 100 parts by weight of limestone, 100 parts by weight of dolomite, 100 parts by weight of surrogate rock. , 100 parts by weight of talc, 100 parts by weight hardwood, 100 parts by weight of zeolite, 100 parts by weight of bentonite, 100 parts by weight of polyacrylic acid (Polyacrylic acid) is dried at 100 ℃ any one selected from the group, oil flavored peppermint, Lavender, sol, rose, jasmine, freesia, acacia, violet, lilac, flavono, rosemary, apple, grape, banana, orange, mango, strawberry, cherry, lemon, phytoncide, plum, quince, mugwort, pheromone, chocolate, Add 1 to 50 parts by weight of any one oil selected from the group consisting of natural and artificial flavors such as coffee, vanilla, cola, olive, grazilia, hazelt, ginseng and lime, and depressurize to 20 mmHg, and then stir for 5 minutes. After the addition of 1 to 10 parts by weight of polyethylene wax and 1 to 10 parts by weight of ethylene bisamide, the mixture was stirred at 50 ° C. and 120 RPM to prepare a sachet, and then, the sachets were made of plastic (polyethylene, PE) 100. Parts by weight, 100 parts by weight of polypropylene (PP), 100 parts by weight of polyurethane, 100 parts by weight of polyethylene terephthalate (PET), 100 parts by weight of polybutylene terephthalate (PBT), poly Peppermint, lavender, sol, rose, jasmine, freesia, acacia, violet, lilac, flavono, rosemary, apple, grape, banana, orange, any one selected from the group consisting of 100 parts by weight of vinyl acetate Mango, strawberry, cherry, lemon, phytoncide, plum, quince, mugwort, pheromone, chocolate, coffee, vanilla, cola, olive, grazilia, hazelt, ginseng, lime 1-5 parts by weight of any one oil selected from the group consisting of natural and artificial flavors was immersed and mixed, reduced to 20 mmHg, stirred for 5 minutes, and then 1 to 10 parts by weight of polyethylene wax and 1 to 10 ethylene bisamide. Add any one of parts by weight to 100 parts by weight of the material obtained by stirring at 120 ℃ at 50 ℃ normal pressure and add any one of 0.1 to 10 parts by weight of the fragrance collector, 1 to 5 parts by weight of polyethylene wax, 1 to 5 parts by weight of ethylene bisamide 50 The above object can be achieved by making the fragrance resin production method of a long-lasting fragrance resin, which is made by stirring at 120 ° C. and at 120 ° C.
Hereinafter, a detailed description of the fragrance resin manufacturing method of the present invention the fragrance is preserved as follows.

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Example 1

Dry 100 parts by weight of granite at 100 ° C, add 30 parts by weight of oil, stir at 20 mmHg for 5 minutes under reduced pressure, add 10 parts by weight of polyethylene wax, stir at a heating temperature of 50 ° C, and mixer 120 RPM to obtain a fragrance aggregate. 3 parts by weight of oil flavor was added to the part and stirred for 5 minutes, and then 3 parts by weight of polyethylene wax was added and stirred at a mixer temperature of 50 ° C. for 10 minutes with a mixer 120 RPM. Then, 3 parts by weight of the fragrance aggregate was added and stirred again for 10 minutes. A composition can be obtained.

The present invention prepared as described above prepared a stuffed toy using the stuffed material of the stuffed toy, and then put it in a 50 ° C. hot air dryer for a property test. (Example 1 is a solid line, existing product 1 is a dashed line existing product 2 is a dashed line)

Table 1

Example 2

In this embodiment, polyvinylacetate was used instead of 100 parts by weight of polyethylene, compared to Example 1, and the other processes were the same.

The present invention prepared as described above prepared a stuffed toy using the stuffed material of the stuffed toy, and then placed in a 50 ° C. hot air dryer for a property test. The sensory test was performed for the fragrance persistence after a lapse of time. (Example 2 is a solid line, existing product 1 is a dashed line existing product 2 is a one-dot chain line)

TABLE 2

Example 3

In this embodiment, instead of 100 parts by weight of polystyrene compared to Example 1, the use of polyethylene terephthalate and the other processes are the same.

The present invention prepared as described above prepared the stuffed toy as a stuffed material of the stuffed toy, and then put it in a 50 ℃ hot air dryer for the property test. (Example 3 is a solid line, existing product 1 is a dashed line existing product 2 is a one-dot chain line)

TABLE 3

Example 4

This Example used a zeolite of 80 mesh passes in place of the granite compared to Example 1 and the other process is the same.

The present invention prepared as described above was prepared as a stuffed toy belly material, and then a stuffed toy was put in a 50 ° C. hot air dryer for the property test, and the sensory test was performed for the fragrance property after the lapse of time. (Example 4 is a solid line, the existing product 1 is a dotted line, and the existing product 2 is a one-dot chain line)

Table 4

Example 5

In this embodiment, ethylene bisamide was used instead of the polyethylene wax compared to Example 1, and the temperature was set from 50 ° C. to 70 ° C., and other processes were the same.

The present invention prepared as described above was prepared as a stuffed toy belly material, and then a stuffed toy was put in a 50 ° C. hot air dryer for the property test, and the sensory test was performed for the fragrance persistence after the lapse of time. (Example 5 is a solid line, existing product 1 is a dashed line existing product 2 is a dashed line)

Table 5

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Example 6

In this embodiment, 5 parts by weight of oil flavor is added to 100 parts of polyethylene in a blender and stirred for 5 minutes, 3 parts by weight of granite dried at 100 ° C., and stirred for 5 minutes, followed by 5 parts by weight of polyethylene wax at 50 ° C. The mixture was stirred at 120 RPM for 10 minutes.

After preparing the stuffed toy using the composition of the present invention prepared as described above as stuffed toy stuffing material, and put it in a 50 ℃ hot air dryer for the property test, the sensory test for the fragrance persistence after the lapse of time as shown in Table 7 (Example 7 is a solid line, the existing product 1 is a dashed line existing product 2 is a one-dot chain line)

Table 6

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Example 7

In this embodiment, 3 parts by weight of oil flavor is added to 100 parts of polyethylene in a blender and stirred for 5 minutes. Then, 3 parts by weight of polyethylene wax is added and stirred at 10 ° C. in a mixer at 120 RPM for 50 minutes.

The present invention prepared as described above was prepared as a stuffed toy of the stuffed toy, and then stuffed into a 50 ° C. hot air dryer for the property test. (Example 9 is a solid line, the existing product 1 is a dashed line existing product 2 is a one-dot chain line)

TABLE 7

The present invention obtained as described above is excellent in fragrance fragrance and persistence and can maximize the effect by a simple production method, it is economical and can be applied to everyone, especially stuffed stuffed material or incense or flowers do not bloom By storing it in the flowerpot of the ornamental tree, you can continue to feel the fragrance in the long term, so you can pursue a sense of mental stability and quality of the product.

Although the present invention has been shown and described with reference to certain preferred embodiments, the present invention is not limited to the above-described embodiments and has ordinary skill in the art to which the present invention pertains without departing from the spirit of the present invention. Many changes and modifications will be made by the user.

Claims (4)

100 parts by weight of granite, 100 parts by weight of rhyolite, 100 parts by weight of andesite, 100 parts by weight of sandstone, 100 parts by weight of shale, 100 parts by weight of limestone, 100 parts by weight of dolomite, 100 parts by weight of talc, 100 parts by weight of talc, 100 parts by weight of hard coal, After drying any one selected from the group consisting of 100 parts by weight of zeolite, 100 parts by weight of bentonite, 100 parts by weight of polyacrylic acid at 100 ℃, peppermint, lavender, sol, rose, jasmine, freesia, acacia , Violet, lilac, flavono, rosemary, apple, grape, banana, orange, mango, strawberry, cherry, lemon, phytoncide, plum, quince, wormwood, pheromone, chocolate, coffee, vanilla, cola, olive, grazilia 1 ~ 50 parts by weight of any one oil selected from the group consisting of natural and artificial flavors such as hazelt, ginseng and lime, reduced to 20mmHg and stirred for 5 minutes, and then 1 to 10 parts by weight of polyethylene wax, ethyl After adding any one of 1 to 10 parts by weight of bisamide, stirring the mixture at 50 ° C. and 120 RPM to produce a flavor collector, and then 100 parts by weight of polyethylene, PE, a raw material of plastic, and 100 weight of polypropylene (PP). By weight, 100 parts by weight of polyurethane, 100 parts by weight of polyethylene terephthalate (PET), 100 parts by weight of polybutylene terephthalate (PBT), 100 parts by weight of polyvinyl acetate Peppermint, lavender, sol, rose, jasmine, freesia, acacia, violet, lilac, flavono, rosemary, apple, grape, banana, orange, mango, strawberry, cherry, lemon, phytoncide, plum, Select from the group consisting of natural and artificial flavors such as Chinese quince, mugwort, pheromone, chocolate, coffee, vanilla, cola, olive, grazilia, hazelt, ginseng and lime 1-5 parts by weight of any one oil flavor was mixed by immersion, reduced to 20 mmHg, and then stirred for 5 minutes, followed by 1 to 10 parts by weight of polyethylene wax and 1 to 10 parts by weight of ethylene bisamide. To 100 parts by weight of the material obtained by stirring at 120 RPM, any one of 0.1 to 10 parts by weight of the fragrance collector, 1 to 5 parts by weight of polyethylene wax, and 1 to 5 parts by weight of ethylene bisamide are added, and the mixture is stirred at 50 ° C. and 120 RPM. A fragrance resin manufacturing method that preserves the fragrance for a long time. delete delete delete