KR100538819B1 - Antibiotic absorption fabric - Google Patents
Antibiotic absorption fabric Download PDFInfo
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- KR100538819B1 KR100538819B1 KR10-2004-0042745A KR20040042745A KR100538819B1 KR 100538819 B1 KR100538819 B1 KR 100538819B1 KR 20040042745 A KR20040042745 A KR 20040042745A KR 100538819 B1 KR100538819 B1 KR 100538819B1
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- 239000004744 fabric Substances 0.000 title claims abstract description 19
- 238000010521 absorption reaction Methods 0.000 title 1
- 230000003115 biocidal effect Effects 0.000 title 1
- 239000002245 particle Substances 0.000 claims abstract description 23
- 229910052900 illite Inorganic materials 0.000 claims abstract description 19
- VGIBGUSAECPPNB-UHFFFAOYSA-L nonaaluminum;magnesium;tripotassium;1,3-dioxido-2,4,5-trioxa-1,3-disilabicyclo[1.1.1]pentane;iron(2+);oxygen(2-);fluoride;hydroxide Chemical compound [OH-].[O-2].[O-2].[O-2].[O-2].[O-2].[F-].[Mg+2].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[K+].[K+].[K+].[Fe+2].O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2 VGIBGUSAECPPNB-UHFFFAOYSA-L 0.000 claims abstract description 19
- 239000000843 powder Substances 0.000 claims abstract description 15
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000011248 coating agent Substances 0.000 claims abstract description 13
- 238000000576 coating method Methods 0.000 claims abstract description 13
- 238000001179 sorption measurement Methods 0.000 claims abstract description 13
- 230000000845 anti-microbial effect Effects 0.000 claims abstract description 12
- 238000001035 drying Methods 0.000 claims abstract description 10
- 239000002105 nanoparticle Substances 0.000 claims abstract description 7
- 238000002156 mixing Methods 0.000 claims abstract description 5
- 239000004925 Acrylic resin Substances 0.000 claims abstract description 4
- 229920000178 Acrylic resin Polymers 0.000 claims abstract description 4
- 230000000844 anti-bacterial effect Effects 0.000 claims description 9
- 238000000034 method Methods 0.000 claims description 7
- 239000007788 liquid Substances 0.000 claims description 5
- 238000004519 manufacturing process Methods 0.000 claims description 5
- 230000008021 deposition Effects 0.000 claims 1
- 238000005108 dry cleaning Methods 0.000 abstract description 15
- 239000004745 nonwoven fabric Substances 0.000 abstract description 6
- 235000019645 odor Nutrition 0.000 abstract description 6
- 238000000151 deposition Methods 0.000 abstract description 2
- 239000004599 antimicrobial Substances 0.000 abstract 1
- 239000000356 contaminant Substances 0.000 description 6
- 239000000428 dust Substances 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 239000003960 organic solvent Substances 0.000 description 5
- 239000002904 solvent Substances 0.000 description 5
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 4
- 229920005822 acrylic binder Polymers 0.000 description 4
- 239000000835 fiber Substances 0.000 description 4
- 238000004062 sedimentation Methods 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 230000002745 absorbent Effects 0.000 description 3
- 239000002250 absorbent Substances 0.000 description 3
- 239000003463 adsorbent Substances 0.000 description 3
- 238000013329 compounding Methods 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 238000010998 test method Methods 0.000 description 3
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 2
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 2
- CYTYCFOTNPOANT-UHFFFAOYSA-N Perchloroethylene Chemical group ClC(Cl)=C(Cl)Cl CYTYCFOTNPOANT-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000000172 allergic effect Effects 0.000 description 2
- 208000010668 atopic eczema Diseases 0.000 description 2
- 238000011109 contamination Methods 0.000 description 2
- 230000001877 deodorizing effect Effects 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 239000003205 fragrance Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000002923 metal particle Substances 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- -1 perchloroethylene copper Chemical compound 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 239000013557 residual solvent Substances 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 230000001953 sensory effect Effects 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 230000001954 sterilising effect Effects 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 229950011008 tetrachloroethylene Drugs 0.000 description 2
- NEYTXADIGVEHQD-UHFFFAOYSA-N 2-hydroxy-2-(prop-2-enoylamino)acetic acid Chemical compound OC(=O)C(O)NC(=O)C=C NEYTXADIGVEHQD-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- BRDOQYRYXNVFPS-UHFFFAOYSA-N CC(=C)C(=O)C(C(=O)OC)(N)O Chemical compound CC(=C)C(=O)C(C(=O)OC)(N)O BRDOQYRYXNVFPS-UHFFFAOYSA-N 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- 241000237536 Mytilus edulis Species 0.000 description 1
- CNCOEDDPFOAUMB-UHFFFAOYSA-N N-Methylolacrylamide Chemical compound OCNC(=O)C=C CNCOEDDPFOAUMB-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 230000000274 adsorptive effect Effects 0.000 description 1
- 244000052616 bacterial pathogen Species 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000032798 delamination Effects 0.000 description 1
- 239000002781 deodorant agent Substances 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000000873 masking effect Effects 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 235000020638 mussel Nutrition 0.000 description 1
- DNTMQTKDNSEIFO-UHFFFAOYSA-N n-(hydroxymethyl)-2-methylprop-2-enamide Chemical compound CC(=C)C(=O)NCO DNTMQTKDNSEIFO-UHFFFAOYSA-N 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- 244000052769 pathogen Species 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 229920013716 polyethylene resin Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- NHARPDSAXCBDDR-UHFFFAOYSA-N propyl 2-methylprop-2-enoate Chemical compound CCCOC(=O)C(C)=C NHARPDSAXCBDDR-UHFFFAOYSA-N 0.000 description 1
- PNXMTCDJUBJHQJ-UHFFFAOYSA-N propyl prop-2-enoate Chemical compound CCCOC(=O)C=C PNXMTCDJUBJHQJ-UHFFFAOYSA-N 0.000 description 1
- 239000013049 sediment Substances 0.000 description 1
- 230000037307 sensitive skin Effects 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
- D06M11/79—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y40/00—Manufacture or treatment of nanostructures
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/38—Oxides or hydroxides of elements of Groups 1 or 11 of the Periodic Table
- D06M11/42—Oxides or hydroxides of copper, silver or gold
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/83—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with metals; with metal-generating compounds, e.g. metal carbonyls; Reduction of metal compounds on textiles
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M23/00—Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
- D06M23/08—Processes in which the treating agent is applied in powder or granular form
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2401/00—Physical properties
- D10B2401/13—Physical properties anti-allergenic or anti-bacterial
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Nanotechnology (AREA)
- Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Manufacturing & Machinery (AREA)
- Crystallography & Structural Chemistry (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
본 발명은 세탁물의 드라이크리닝 후에 세탁물에 잔존하는 냄새를 제거하는데 사용되는 항균흡착포에 관한 것으로, 아크릴계수지 100중량부에 대하여 다공편상의 일라이트 분말 1중량부 내지 30중량부와 나노크기의 입자상태로 된 은분말 0.1 내지 5중량부를 혼합하여 코팅액을 제조하고, 상기 코팅액에 직물 또는 부직물을 침적시켜 코팅한 다음 건조시켜 제조되는 흡착포를 제공함으로서 달성될수 있다.The present invention relates to an antimicrobial adsorption cloth used to remove odors remaining in laundry after dry cleaning of laundry. 1 to 30 parts by weight of porous piece of illite powder and nano-sized particle state with respect to 100 parts by weight of acrylic resin It can be achieved by providing a coating solution by mixing 0.1 to 5 parts by weight of the silver powder, and by depositing a coating or non-woven fabric in the coating solution and then drying the coating solution.
Description
본 발명은 세탁물의 드라이크리닝 후에 세탁물에 잔존하는 냄새를 제거하는데 사용되는 항균흡착포에 관한 것으로 좀더 상세하게는 세탁물의 드라이크리닝은 오염물질을 세탁물로부터 제거하기 위하여 유기용제를 사용하고, 유기용제에 의한 드라이크리닝 세탁 후 원심분리기 등을 이용하여 유기용제를 세탁물로부터 제거후 잔존하는 드라이크리닝용 용제의 냄새를 제거하는데 사용될 수 있는 항균 흡착포에 관한 것이다.The present invention relates to an antibacterial adsorption cloth used to remove odors remaining in laundry after dry cleaning of laundry. More specifically, dry cleaning of laundry uses an organic solvent to remove contaminants from the laundry. The present invention relates to an antibacterial absorbent cloth that can be used to remove the odor of the remaining dry cleaning solvent after removing the organic solvent from the laundry by using a centrifuge after dry cleaning.
세탁물의 드라이크리닝에 사용되는 유기용제는 대부분 석유계의 유기용제가 사용되고 있으며, 주로 벤젠, 톨루엔, 키실렌등과 같은 유기용제가 단독 혼합사용되다가, 점차 의복 등을 오염시키는 오염물질이 복잡해 짐에 따라 그와 같은 오염물질을 제거하기 위하여 퍼클로로에틸렌 동과 같은 침투제를 첨가하기도 하고, 액성을 조절하기 위한 조절제 등을 첨가하여 사용되기 시작하였다.Most organic solvents used for dry cleaning of laundry are petroleum-based organic solvents, and organic solvents such as benzene, toluene, and xylene are mixed and used, and contaminants that contaminate clothing gradually become more complicated. Therefore, in order to remove such contaminants, a penetrant such as perchloroethylene copper is added, and a control agent for adjusting the liquidity, etc., has been started to be used.
그러나, 상기와 같이 특정의 오염물질을 제거하기 위하여 첨가되는 퍼클로로에틸렌 등과 같은 첨가물질 중의 일부는 직물의 내부로 침투되어 드라이크리닝의 후공정인 건조공정의 이후에도 직물에 남아 있게되어 의복을 착용하는 착용자에게 불쾌한 냄새를 풍기는 문제가 있을 뿐만 아니라, 심한 경우에는 피부와 접촉이되어 알레르기를 일으키는 경우도 발생하게 되었다.However, some of the additives, such as perchloroethylene, added to remove specific contaminants as described above, penetrate into the fabric and remain on the fabric even after the drying process, which is a post-drying process, to wear clothes. Not only does the wearer have an unpleasant odor, but in severe cases, allergic contact with the skin occurs.
이와 같은 문제로 인하여 일부의 세탁소에서는 의복에 잔류하는 드라이크리닝 용제의 냄새를 제거하기 위하여 향료성분을 함유하는 탈취제를 살포하여 냄새를 마스킹하고 있으나, 향의 성분은 대부분 오일로 이루어져 있기 때문에 대기중의 먼지 등에 의하여 용이하게 오염이 되는 또다른 오염원을 제공하게 되는 문제가 있었다.Due to these problems, some dry cleaners use masking odors by spraying deodorants containing fragrance ingredients to remove the odors of dry cleaning solvents remaining on the garments. There has been a problem of providing another source of contamination that is easily contaminated by dust or the like.
또, 드라이크리닝 후의 건조 공정에서 잔류하게 되는 퍼클로로에틸렌 등의 첨가물은 향기 성분에 의하여 잠시 가리워져 있을 뿐 근본적으로 제거된 것이 아니어서 드라이크리닝한 의복의 착용시 민감한 피부를 가진자의 피부를 자극하여 알레르기 현상을 일으키는 것은 막을 수가 없었다.Also, additives such as perchlorethylene remaining in the drying process after dry cleaning are temporarily removed by the fragrance component and are not essentially removed. Therefore, allergic to skin of sensitive skin when wearing dry-cleaned clothes. What caused the phenomenon could not be prevented.
또한, 의복등의 세탁물에는 다양한 오염물질에 의하여 오염이 되고 그중에는 그 오염물질을 영양성분으로 섭취하는 각종의 세균 등이 서식하고 있고, 그 중에는 인간에게 질병을 유발시키는 병원균 등도 포함되어 있으나, 통상의 드라이크리닝과 같은 세탁방법으로는 이와 같은 세균을 사멸시키지 못하는 문제가 있다.In addition, laundry such as clothing is contaminated by various contaminants, and among them, various bacteria and the like that consume the contaminants as nutrients contain live pathogens that cause diseases in humans. There is a problem in that the washing method such as dry cleaning does not kill such bacteria.
본 발명은 상기와 같은 문제점을 해결하기 위한 것으로, 드라이크리닝 후, 드라이크리닝에 사용된 잔류용제를 제거하기 위한 건조 공정에서 잔류용제의 흡수를 하고 또 살균을 할 수 있는 탈취 흡착포를 제공함을 목적으로 한다. The present invention has been made to solve the above problems, and after dry cleaning, to provide a deodorizing adsorbent which can absorb and sterilize the residual solvent in the drying process for removing the residual solvent used in the dry cleaning. do.
아크릴계수지 100중량부에 대하여 다공편상의 일라이트 분말 1중량부 내지 10중량부와 나노크기의 입자상태로 된 은분말 0.1 내지 5중량부를 혼합하여 코팅액을 제조하고, 상기 코팅액에 직물 또는 부직물을 침적시켜 코팅한 다음 건조시켜 제조되는 흡착포를 제공함으로서 달성될수 있다.A coating liquid was prepared by mixing 1 to 10 parts by weight of the porous piece of illite powder with 0.1 to 5 parts by weight of silver powder in the form of nanoparticles with respect to 100 parts by weight of the acrylic resin. It can be achieved by providing an adsorbent fabric which is prepared by depositing, coating and then drying.
본 발명에서 사용되는 아크릴계수지는 폴리에스테르수지, 폴리에틸렌수지, 폴리프로필렌 수지등과 같이 섬유 스테이플의 제조에 사용되는 합성수지에 친화력을 갖는 수지라면 어떠한 수지라도 상관이 없으며,대표적인 화합물로는 메틸아크릴레이트, 메틸메타크릴레이트, 에틸아크릴레이트, 에틸메타크릴레이트, 프로필아크릴레이트, 프로필메타크릴레이트, n-부틸아크릴레이트, n-부틸메타크릴레이트, 2-에틸헥실아크릴레이트, 아크릴아미노글리콜산, 메타크릴아미노글리콜산메틸에스테르, N-메틸올아크릴아마이드, N-메틸올메타크릴아마이드 등이 사용될 수 있다.The acrylic resin used in the present invention may be any resin as long as it has affinity for synthetic resins used in the manufacture of fiber staples such as polyester resins, polyethylene resins, polypropylene resins, and the like. Methyl methacrylate, ethyl acrylate, ethyl methacrylate, propyl acrylate, propyl methacrylate, n-butyl acrylate, n-butyl methacrylate, 2-ethylhexyl acrylate, acrylaminoglycolic acid, methacryl Aminoglycolic acid methyl ester, N-methylol acrylamide, N-methylol methacrylamide and the like can be used.
일라이트 분말은 자연으로부터 얻어지는 것으로 점토, 황토 등에 많이 함유되어 있으며 수비분리에 의하여 얻어지는 매우 미세한 분말로서, 250메쉬 내지 1500메쉬의 입도를 갖는 것을 사용하는 것이 바람직하며, 250메쉬보다 큰 입도를 갖는 경우에는 생산공정에서 어떠한 종류의 교반기를 사용한다 하여도 침강속도가 빨라서 섬유의 표면에 고르게 코팅을 할 수 없으며, 1500메쉬 보다 작은 입도에서는 일라이트의 입자가 코팅액의 상부에서 부유되어 역시 섬유에 고른 코팅을 할 수 없는 문제를 야기시키게 된다.The illite powder is obtained from nature and is contained in clay, loess, and the like and is a very fine powder obtained by the defensive separation, and it is preferable to use a particle having a particle size of 250 mesh to 1500 mesh, and having a particle size larger than 250 mesh. Even though any kind of stirrer is used in the production process, the sedimentation rate is high so that it is not evenly coated on the surface of the fiber.In the particle size smaller than 1500 mesh, the particles of the illite are suspended in the upper part of the coating liquid and the coating is evenly coated on the fiber. It causes problems that cannot be done.
또 일라이트 분말의 사용량은 아크릴계 바인더 100중량부에 대하여 1중량부 내지 10중량부로 사용되는데, 1중량부 이하로 첨가하게 되면 소정의 탈취효과를 얻기가 어려우며, 10중량부 이상 첨가되는 경우에는 바인더인 코팅액에 비하여 일라이트분말이 과다하여 일라이트 분말이 섬유의 표면에 견고하게 고착이되지 않고 탈락이되어 비산되는 문제를 일으켜 건조공정에서 백색계통의 의류에는 또다른 오염원으로 작용되는 문제가 있다.In addition, the amount of the illite powder is used in 1 part by weight to 10 parts by weight with respect to 100 parts by weight of the acrylic binder, it is difficult to obtain a predetermined deodorizing effect when added to less than 1 part by weight, binder is added when 10 parts by weight or more Compared to the phosphorus coating solution, the illite powder is excessive, and thus the illite powder is not firmly fixed to the surface of the fiber and is dropped off, which causes scattering, and thus, the white clothing has a problem of acting as another pollutant in the drying process.
나노상태의 은분말은 3㎚ 내지 120㎚의 입도를 갖는 것을 사용하는 것이 바람직하며, 120㎚보다 큰 입도를 갖는 경우에는 비표면적이 작아지고 또 높은 비중으로 인하여 코팅액 중에서 분산이 어려우며 또 살균력이 떨어지는 문제가 있으며, 3㎚ 보다 작은 입도에서는 금속간의 강한 화합력에 기인하여 폭발등의 위험성이 내재되어 있어 취급이 용이하지 않은 문제가 있다.It is preferable to use a nanoparticle silver powder having a particle size of 3 nm to 120 nm, and when the particle size is larger than 120 nm, the specific surface area is small and high specific gravity makes it difficult to disperse in the coating liquid and lower sterilization power. There is a problem, and at a particle size smaller than 3 nm, there is a problem in that the handling is not easy due to the inherent danger of explosion due to the strong compounding force between metals.
또 나노상태의 은 분말의 사용량은 아크릴계 바인더 100중량부에 대하여 0.1중량부 내지 5중량부로 사용되는데, 0.1중량부 이하로 첨가하게 되면 소정의 항균효과를 얻기가 어려우며, 5중량부 이상 첨가되는 경우에는 과량의 첨가로 인하여 코팅용액의 내에서 교반도중 금속입자와 금속입자의 충돌로 인하여 거대 입자를 형성하는 문제가 있다.In addition, the amount of nano-phase silver powder is used in an amount of 0.1 parts by weight to 5 parts by weight based on 100 parts by weight of an acrylic binder, and when it is added in an amount of 0.1 parts by weight or less, it is difficult to obtain a predetermined antibacterial effect. There is a problem in that large particles are formed due to collision of metal particles and metal particles during stirring in the coating solution due to the addition of excess.
본 발명에서 사용될 수 있는 직물 또는 부직물은 폴리에스테르계, 폴리비닐계가 모두 사용될 수 있으며, 긴밀한 조직을 갖는 직물보다는 공기의 유동성이 좋은 부직물 예를들어 부직포, 부직펠트 등을 사용하는 것이 바람직하다,The fabric or non-woven fabric that can be used in the present invention can be used both polyester-based, polyvinyl-based, it is preferable to use a non-woven fabric, such as non-woven fabric, non-woven felt, etc. with good air flow rather than the fabric having a tight structure ,
직물 또는 부직물에 적당한 두께로 코팅을 하기 위하여는 아크릴계바인더를 용해할 수 있는 용매의 첨가가 가능하며, 필요한 경우에는 에멀젼화시켜 수성의 상태로도 코팅을 할 수 있다.In order to coat the fabric or non-woven fabric to a suitable thickness, it is possible to add a solvent capable of dissolving the acrylic binder, and if necessary, may be emulsified and coated in an aqueous state.
이하 본 발명을 하기의 실시예를 통하여 보다 상세히 설명하기로 하나, 본 발명이 하기의 실시예에 의하여 한정되어 지는 것은 아니다.Hereinafter, the present invention will be described in more detail with reference to the following examples, but the present invention is not limited to the following examples.
<실시예 1 내지 실시예 6><Examples 1 to 6>
6개의 200㎖비이커에 메틸메타크릴레이트 105g을 넣은 다음 하기의 표1에서와 같은 입도를 갖는 일라이트 분말 1.05g씩 각각 넣은 다음 자석교반기를 이용하여 10분간 교반한 다음 교반된 일라이트 함유 메틸메타크릴레이트를 직경 20㎜ 시험관에 넣고 층분리현상을 측정하였으며, 그 결과를 표 1에 함께 나타내었다.105 g of methyl methacrylate was added to six 200 ml beakers, followed by 1.05 g of illite powder having a particle size as shown in Table 1 below, followed by stirring for 10 minutes using a magnetic stirrer. The acrylate was placed in a test tube with a diameter of 20 mm and the delamination was measured. The results are shown in Table 1 together.
상기 표1의 결과로 부터 확인이 되는 바와 같이, 입도가 250메쉬보다 큰 경우에는 빠른 침강속도로 인하여 아크릴계 바인더와 일라이트 간의 혼화성에 문제가 발생하여 균질한 홍합이 어려우며, 또 혼합액을 장기보존하는데 문제가 있으며, 실시예 6의 경우와 같이 입도가 1500메쉬 이상인 경우에는 일라이트의 상당량이 부유되어 잘 침강이 이루어지지 않아 혼합액의 제조시 균질 혼합이 어려운 문제가 있음을 확인할 수 있었다.As can be seen from the results of Table 1, when the particle size is larger than 250 mesh, a problem of miscibility between the acrylic binder and the illite occurs due to the rapid sedimentation rate, making it difficult to homogeneous mussels and to preserve the mixed solution for a long time. However, when the particle size is more than 1500 mesh as in the case of Example 6, it was confirmed that there is a problem that homogeneous mixing is difficult during the preparation of the mixed liquid because a considerable amount of illite is suspended and not well settled.
<실시예 7 내지 실시예 11><Example 7 to Example 11>
5개의 200㎖비이커에 각각 메틸메타크릴레이트 105g을 넣은 다음 하기의 표2에서와 같은 입도를 갖는 나노입자의 은분말 0.1g을 각각 넣은 다음 자석교반기를 이용하여 10분간 교반한 다음 교반된 일라이트 함유 메틸메타크릴레이트를 직경 20㎜ 시험관에 넣고 층분리현상을 관찰하였으며, 그 결과를 표 2에 함께 나타내었다.105 g of methyl methacrylate was added to five 200 ml beakers, and then silver powder of nanoparticles having a particle size as shown in Table 2 below. 0.1g was added thereto, and then stirred for 10 minutes using a magnetic stirrer. The stirred illite-containing methyl methacrylate was placed in a test tube with a diameter of 20 mm, and layer separation was observed. The results are shown in Table 2 together.
나노 상태의 은 입자별 실험에 있어서는 실시예 7과 같이 미세한 분말은 시료의 수급이 되지 않는 관계로 실험을 할 수 없었으나, 입도가 이와 같이 미세한 경우에는 금속간의 화합력에 의하여 입도가 거대해지는 문제가 예상되며, 또 화합력에 의한 결합으로 사용상에 문제를 야기시킬 수 있고, 실시예 8 내지 실시예 11로부터 확인되는 바와 같이 입도가 커짐에 따라 침강속도가 빨라지는 것을 확인할 수 있다.In the nanoparticle-specific experiments, as in Example 7, the fine powder could not be tested because it did not supply or receive the sample. However, when the particle size was thus fine, the particle size was large due to the compounding power between metals. It is expected, and may also cause problems in use by the combination of the compounding force, it can be confirmed that the settling speed is increased as the particle size increases as confirmed from Examples 8 to 11.
<실시예 12 내지 실시예 32><Example 12 to Example 32>
10리터의 용량을 갖는 23개의 비이커에 2-에틸헥실아크릴레이트 5250g을 넣은 다음 325 ~ 700메쉬의 입도를 갖는 일라이트 분말과 10 ~ 50㎚의 입도를 갖는 은 분말을 하기의 표 3과 같이 첨가하고 45g/㎡의 폴리에스테르계 부직포를 22㎝×15㎝ 크기로 절단하여 각각 4장씩 침적시킨 다음 압착로울러을 이용하여 압착후 건조하여 흡착포를 제조하고 항균시험에 1장, 퍼클로르 에틸렌에 대한 흡착시험에 2장 그리고 비산상태 확인에 1장을 사용하여 하기의 방법으로 실험을 한 후 그 결과를 표 3에 기재하였다.5250 g of 2-ethylhexyl acrylate was added to 23 beakers having a capacity of 10 liters, and then illite powder having a particle size of 325 to 700 mesh and silver powder having a particle size of 10 to 50 nm were added as shown in Table 3 below. After cutting 45g / ㎡ polyester-based nonwoven fabric into 22cm × 15㎝ size, sediment each of 4 sheets, compress them using a compression roller, compress them, and dry them to prepare an absorbent cloth. After the experiment in the following method using Chapter 2 and Chapter 1 to confirm the scattering state, the results are shown in Table 3.
<흡착효과 시험방법><Adsorption effect test method>
상기 각 실시예의 방법으로 만들어진 항균 흡착포 2매와 드라이크리닝 후 세탁물 10Kgs을 지름 37㎝, 깊이 60㎝의 원통형 회전 드럼 건조기에 넣고 송풍기를 이용하여 60℃로 가온된 공기를 30㎥/분의 속도로 불어 넣고 1시간 정도 건조후의 정상인의 관능검사에의한 측정하고 판정방법은 드라이크리닝 - 건조공정을 거친 세탁물을 3인 이상이 관능 평가 하며 판정 급수는 다음과 같이 하였다.Two antibacterial adsorption cloths made by the method of each embodiment and 10kgs of laundry after dry cleaning were put into a cylindrical rotary drum dryer having a diameter of 37 cm and a depth of 60 cm, and the air heated to 60 ° C. using a blower at a rate of 30 m 3 / min. Sensory evaluation of normal subjects after 1 hour of drying and blowing was carried out. The method of judging was sensory evaluation of three or more laundry-dried laundry after dry cleaning and drying process.
1급= 자극적이고 강렬냄새 Level 1 = Irritating and Intense Smell
2급= 강한 냄새. 2nd level = strong smell.
3급= 약하지만 쉽게 감지 할 수 있는 냄새. Level 3 = A weak but easily detectable smell.
4급= 냄새가 미미하여 판정하기 어려움 Level 4 = Inadequate smell
5급= 냄새를 거의 감지 할 수 없음Level 5 = almost no smell
6급= 냄새 없슴Level 6 = no smell
<항균효과 시험방법><Antibacterial effect test method>
FC-TM-20-2003에 준하여 필름 밀착법의 방법으로 실험하였다.It experimented by the method of the film adhesion method according to FC-TM-20-2003.
<비산상태 시험방법><Scattering test method>
상기 실시예에 의해서 제조된 항균흡착포의 초기무게를 계량하고 압축공기로 불어서 부착되지 않은 일라이트를 (제거후의 무게)제거하고 흡착포를 건조하여 초기중량과 제거후의 무게차이가 없어야 한다.The initial weight of the antimicrobial adsorption cloth prepared according to the above example was measured and blown with compressed air to remove unattached illite (weight after removal), and the adsorbent cloth should be dry so that there is no difference in initial weight and weight after removal.
상기의 실시예 12 내지 실시예 32로부터 확인되는 바와 같이 일라이트 분말이 본 발명의 수치 이내로 들어간 경우에는 흡착효과가 떨어지는 것을 확인 할 수 있으며, 또 과다하게 들어간 실시예 16 및 실시예 30 내지 실시예 32의 경우에는 일라이트 분말의 비산으로 인하여 세탁물에 또다른 오염을 일으키는 문제가 있었다.As can be seen from Examples 12 to 32 above, when the illite powder falls within the numerical value of the present invention, it can be confirmed that the adsorption effect is deteriorated. In the case of 32, there was a problem of causing another contamination to the laundry due to the scattering of the illite powder.
나노 입도를 갖는 은 분말이 적에 들어간 실시예 17, 실시예27 및 실시예 30의 경우는 항균효과가 현저히 떨어짐을 확인할 수 있으며, 동일한 량의 은 분말이 첨가된 경우에도 일라이트의 첨가에 따라 항균효과가 상승함을 실시예 24 내지 실시예 32를 통하여 확인할 수 있다.In Example 17, Example 27, and Example 30 in which the silver powder having a nanoparticle size entered the product, it was confirmed that the antimicrobial effect was remarkably decreased, and even when the same amount of silver powder was added, It can be confirmed from Examples 24 to 32 that the effect is increased.
따라서, 일라이트 분말과 은분말을 적정의 비율로 혼합하여 주면, 흡착효과 및 항균효과의 상승효과를 얻을 수 있다는 것을 확인 할 수 있다.Therefore, it can be confirmed that synergistic effect of the adsorption effect and the antimicrobial effect can be obtained by mixing the illite powder and the silver powder in an appropriate ratio.
상기에서 확인된 바와 같이, 본 발명에 의한 항균 흡착포는 드라이 크리닝후 잔존하는 용제에 대한 흡착력이 뛰어나고 또 항균효과에 있어서도 우수한 살균효과를 나타내고 있어, 드라이크리닝 후 착용자에게 용제 냄새로 인한 불쾌감을 주지 않을 뿐 만 아니라, 병원성 세균등을 살균함으로서 건강한 삶은 유지토록 하는 유용한 발명인 것이다.As confirmed above, the antimicrobial adsorption cloth according to the present invention has excellent adsorptive power to the solvent remaining after dry cleaning and also shows an excellent bactericidal effect in the antibacterial effect, and thus does not give the wearer the discomfort caused by the smell of the solvent after dry cleaning. In addition, it is a useful invention to maintain healthy life by sterilizing pathogenic bacteria.
Claims (4)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR10-2004-0042745A KR100538819B1 (en) | 2004-06-10 | 2004-06-10 | Antibiotic absorption fabric |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR10-2004-0042745A KR100538819B1 (en) | 2004-06-10 | 2004-06-10 | Antibiotic absorption fabric |
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| Publication Number | Publication Date |
|---|---|
| KR20050117435A KR20050117435A (en) | 2005-12-14 |
| KR100538819B1 true KR100538819B1 (en) | 2005-12-26 |
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| KR10-2004-0042745A KR100538819B1 (en) | 2004-06-10 | 2004-06-10 | Antibiotic absorption fabric |
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| KR (1) | KR100538819B1 (en) |
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