KR100509679B1 - Stone-based spray-painting composition - Google Patents

Stone-based spray-painting composition Download PDF

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KR100509679B1
KR100509679B1 KR1020050019888A KR20050019888A KR100509679B1 KR 100509679 B1 KR100509679 B1 KR 100509679B1 KR 1020050019888 A KR1020050019888 A KR 1020050019888A KR 20050019888 A KR20050019888 A KR 20050019888A KR 100509679 B1 KR100509679 B1 KR 100509679B1
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weight
stone
acrylic
calcite
material composition
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KR1020050019888A
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이건신
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대보페인트 주식회사
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04—Homopolymers or copolymers of esters
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Paints Or Removers (AREA)
  • Finishing Walls (AREA)

Abstract

본 발명은 석재 뿜칠재 조성물에 관한 것으로, 아크릴 에멀젼 10 내지 20 중량%, 아크릴 칼라칩 1 내지 10 중량%, 맥반석 10 내지 30 중량%, 방해석(80 mesh) 20 내지 30 중량%, 방해석(60 mesh) 10 내지 20 중량%, 방해석(40 mesh) 5 내지 15 중량%, 산화아연(ZnO) 1 내지 3 중량% 및 물 1 내지 15 중량%를 포함하는 석재 뿜칠재 조성물을 제공한다.The present invention relates to a stone fuming material composition, acrylic emulsion 10 to 20% by weight, acrylic color chip 1 to 10% by weight, ganban stone 10 to 30% by weight, calcite (80 mesh) 20 to 30% by weight, calcite (60 mesh) ) 10 to 20% by weight, 5 to 15% by weight of calcite (40 mesh), 1 to 3% by weight of zinc oxide (ZnO), and 1 to 15% by weight of the water to provide a stone fuming material composition.

본 발명에 따른 석재 뿜칠재 조성물은 아크릴 칼라칩을 포함하여 입체감이 뛰어나고, 순수한 아크릴 에멀젼을 사용하여 표면강도가 우수하고 투명도가 뛰어나며, 방해석(calcite)을 사용하여 은폐력과 백색도 및 내변색성 등이 우수하고, 맥반석을 다량으로 함유하고 있어 인체에 이로우며, 특히 스프레이 작업이 가능하도록 설계된 제품이다.The stone-splashing material composition according to the present invention is excellent in three-dimensional feeling, including acrylic color chips, excellent surface strength and excellent transparency using pure acrylic emulsion, and using calcite to conceal and whiteness and discoloration resistance, etc. It is excellent, and contains a large amount of elvan, which is good for the human body. Especially, it is designed to be sprayed.

Description

석재 뿜칠재 조성물{Stone-based spray-painting composition}Stone-based spray-painting composition

본 발명은 석재 뿜칠재 조성물에 관한 것으로, 더욱 상세하게는 입체감이 뛰어나고 표면강도가 우수하고 투명도가 뛰어나며 은폐력과 백색도 및 내변색성 등이 우수하고 인체에 이로우며 특히 스프레이 작업이 가능하도록 설계된 석재 뿜칠재 조성물에 관한 것이다.The present invention relates to a stone fuming material composition, more specifically, three-dimensional, excellent surface strength, excellent transparency, excellent hiding power and whiteness and discoloration resistance, such as good for the human body, in particular designed for spraying It relates to a lacquer composition.

석재 뿜칠재는 벽면, 천장 등에 스프레이로 도장한 후 건조시키면 석재상으로 형성되는 건축 마감용 뿜칠재이다.Stone spraying material is a building finishing spraying material that is formed into stone when it is sprayed on walls, ceilings, etc. and dried.

종래의 석재 뿜칠재는 표면의 강도를 높여주는 촉매 등을 포함하고 있지 않기 때문에 강도와 투명도가 떨어지는 문제점이 있었으며, 원재료로 사용되는 돌로마이트(dolomite)는 은폐력과 백색도가 떨어지고 고온(600℃)과 자외선에 의한 고유 색상의 변화가 발생하는 단점이 있었다. 또한 원적외선 방사 등의 건강을 고려한 제품이 없었고, 특히 0.8 내지 3 mm의 골재들을 사용하여 질감과 색상을 표현하는 제품들이었기 때문에 원거리에서는 석재 고유의 질감을 표현하는데 한계가 있었다.Conventional stone spraying materials do not contain catalysts to increase the strength of the surface, so the strength and transparency was inferior. Dolomite, which is used as a raw material, has a low hiding power and whiteness and high temperature (600 ° C) and ultraviolet rays. There was a disadvantage that occurs due to the change in intrinsic color. In addition, there were no products considering health such as far-infrared radiation, and in particular, since they were products expressing texture and color using aggregates of 0.8 to 3 mm, there was a limit in expressing a texture unique to stones at a distance.

따라서, 본 발명의 목적은 표면강도와 투명도가 뛰어나고, 은폐력과 백색도 및 내변색성 등이 우수하고, 인체에 이로우며, 특히 입체감이 뛰어나면서도 스프레이 작업이 가능하도록 설계된 석재 뿜칠재 조성물을 제공하는 것이다.Accordingly, it is an object of the present invention to provide a stone spray material composition excellent in surface strength and transparency, excellent hiding power, whiteness, discoloration resistance, and the like, which is beneficial to the human body, and in particular, is excellent in three-dimensional appearance and can be sprayed. .

본 발명은 상기한 목적을 달성하기 위하여, 아크릴 에멀젼 10 내지 20 중량%, 아크릴 칼라칩 1 내지 10 중량%, 맥반석 10 내지 30 중량%, 방해석(80 mesh) 20 내지 30 중량%, 방해석(60 mesh) 10 내지 20 중량%, 방해석(40 mesh) 5 내지 15 중량%, 산화아연(ZnO) 1 내지 3 중량% 및 물 1 내지 15 중량%를 포함하는 석재 뿜칠재 조성물을 제공한다.The present invention to achieve the above object, 10 to 20% by weight of acrylic emulsion, 1 to 10% by weight of acrylic color chip, 10 to 30% by weight of ganbanite, 20 to 30% by weight of calcite (80 mesh), calcite (60 mesh) ) 10 to 20% by weight, 5 to 15% by weight of calcite (40 mesh), 1 to 3% by weight of zinc oxide (ZnO), and 1 to 15% by weight of the water to provide a stone fuming material composition.

본 발명에서 사용되는 아크릴 칼라칩은 아크릴 에멀젼 20 내지 40 중량%, 이산화 티타늄 10 내지 20 중량%, 탄산칼슘 10 내지 30 중량%, 아크릴 폴리머 10 내지 20 중량%, 물 10 내지 20 중량%를 포함하는 아크릴 필름을 분쇄한 것이다.The acrylic color chip used in the present invention includes 20 to 40% by weight of acrylic emulsion, 10 to 20% by weight of titanium dioxide, 10 to 30% by weight of calcium carbonate, 10 to 20% by weight of acrylic polymer, and 10 to 20% by weight of water. The acrylic film is pulverized.

첫째, 본 발명의 조성물은 순수한 아크릴 에멀젼을 사용하므로 표면 강도가 우수하고 투명도가 뛰어나다. 상기 아크릴 에멀젼에 사용되는 아크릴 수지로서 순수 아크릴 공중합체는 통상적으로 본 발명의 기술분야에서 사용되는 화학물질이라면 어떠한 것을 사용해도 무방하나, 도막의 점착성(tackiness)과 도막의 경도를 고려하여 유리전이온도(Tg)의 값이 -15 내지 -10℃인 것을 사용하는 것이 바람직하다.First, since the composition of the present invention uses a pure acrylic emulsion, the surface strength is excellent and the transparency is excellent. As the acrylic resin used in the acrylic emulsion, a pure acrylic copolymer may be used as long as it is a chemical substance used in the technical field of the present invention, but the glass transition temperature in consideration of the tackiness of the coating film and the hardness of the coating film It is preferable to use the thing whose value of (Tg) is -15--10 degreeC.

둘째, 본 발명의 조성물은 기존의 석재 뿜칠재가 돌로마이트를 사용하던 것과는 달리, CaCO3의 결정체로서 안정화되어 있는 방해석(calcite)을 사용함으로써, 은폐력과 백색도 그리고 내변색성이 우수하다.Second, the composition of the present invention is excellent in hiding power, whiteness, and discoloration resistance by using calcite stabilized as a crystal of CaCO 3 , unlike the conventional stone fuming material used dolomite.

방해석은 돌로마이트에 비하여 백색도가 우수하며, 고온(약 600℃)과 자외선에 의한 고유 색상의 변화가 없어서, 석재 뿜칠재에 사용시 은폐력과 백색도가 향상되며, 내자외선성과 내변색성을 우수하게 만드는 효과가 있다.Compared to dolomite, calcite has better whiteness, no change in intrinsic color by high temperature (about 600 ℃) and ultraviolet rays, which improves hiding power and whiteness when used in stone spraying materials, and makes it excellent in UV and UV resistance. There is.

또한, 촉매로써 산화아연(ZnO)을 사용하여 제품의 물성 중 내구성과 내자외선성을 향상시켰다.In addition, zinc oxide (ZnO) was used as a catalyst to improve durability and UV resistance in the physical properties of the product.

셋째, 본 발명의 조성물은 아크릴 공중합체를 이용한 필름상의 칩을 첨가하여 기존의 석재 뿜칠재보다 뛰어난 입체감을 나타낸다. 특히, 종래 제품이 3 mm 이하의 작은 골재를 사용하였던 것과는 달리, 본 발명품은 최대 15 mm의 아크릴 칼라칩을 이용함으로써 입체효과를 극대화시켰다.Third, the composition of the present invention by adding a film-like chip using the acrylic copolymer exhibits a three-dimensional feeling superior to the conventional stone-coated material. In particular, unlike conventional products used small aggregates of 3 mm or less, the present invention maximizes the steric effect by using acrylic color chips of up to 15 mm.

본 발명에서는 석재 뿜칠재에 입체감을 부여하기 위하여 칼라칩을 사용하였으나, 다음과 같은 문제가 발생할 수 있다.In the present invention, the color chip is used to give a three-dimensional appearance to the stone-coated material, the following problems may occur.

일반적인 석재 뿜칠재의 스프레이 작업에 사용되는 스톤건(stone gun: 본타일건)은 노즐의 구경은 3 내지 7 mm 정도이다. 그러나 본 발명의 조성물에 사용되는 칼라칩의 크기는 두께 0.25 내지 0.3 mm, 지름 10 내지 15 mm 정도이다. 따라서, 칩의 지름이 노즐의 구경보다 크기 때문에 칩이 노즐에서 막혀서 분사되지 않을 수 있다.Stone guns (bone guns), which are used for spraying general stone fumes, have a nozzle diameter of about 3 to 7 mm. However, the size of the color chip used in the composition of the present invention is 0.25 to 0.3 mm in thickness, 10 to 15 mm in diameter. Therefore, since the diameter of the chip is larger than the diameter of the nozzle, the chip may be blocked by the nozzle and not ejected.

본 발명은 상술한 노즐의 막힘 문제를 해결하기 위하여, 아크릴 에멀젼에 습윤되었을 때(제품에 혼입된 상태) 부러지거나 분쇄되지 않고 녹지 않는 성질을 가진 아크릴 칩을 사용함으로써, 막힘없이 스프레이 작업이 가능하도록 설계된 것을 특징으로 한다. 즉 아크릴 에멀젼에 이와 유사한 물성 및 조성을 갖는 아크릴 칼라칩을 적용함으로써, 이 아크릴 칼라칩이 아크릴 에멀젼에 습윤되어 유연성을 갖되, 부러지거나 분쇄되지 않고 녹지 않는 성질을 가지며, 이에 따라 아크릴 칼라칩이 스톤건 내에서 유연하게 구부러지거나 접히면서 분사되어, 막힘없는 스프레이 작업이 가능한 것이다.The present invention is to solve the problem of clogging of the nozzle, by using an acrylic chip that has a property that does not break, crush, and melt when wet in the acrylic emulsion (mixed in the product), so that spraying can be performed without clogging. It is characterized by the design. That is, by applying an acrylic color chip having similar properties and composition to the acrylic emulsion, the acrylic color chip is wetted in the acrylic emulsion and has flexibility, but does not break or break without melting, and thus the acrylic color chip is a stone gun. It can be sprayed while flexing or bending in the inside, so that it can be sprayed without clogging.

넷째, 본 발명의 조성물은 기존의 석재 뿜칠재와는 차별화하여 원적외선 방사와 흡착의 기능이 강한 맥반석을 다량 함유하고 있어서, 인체에 이로운 건강 도료로서 설계되어진 제품이다. 맥반석의 작용 및 효과는 다음과 같다.Fourth, the composition of the present invention is a product designed as a health paint that is beneficial to the human body, because it contains a large amount of elvan rock strong in the function of far-infrared radiation and adsorption, different from the existing stone spraying material. The action and effect of elvan is as follows.

맥반석은 유해물질 제거 및 중금속 분해작용을 한다. 맥반석은 1 ㎤당 3만 내지 15만개의 다층 다공질로 구성되어 있고 비표면적이 넓어서 오염물질, 중금속 등을 흡착분해하는 작용을 하며, 또한 시멘트 독성중화, 항균, 방충 및 강한 탈취력을 보이고 있다. 최근에는 다이옥신 제거기술을 선보이고 있는 상황이다.Elvan stone removes harmful substances and decomposes heavy metals. Elvanite is composed of 30,000 to 150,000 multi-layered porous materials per cm 3 and has a large specific surface area to adsorb and decompose contaminants and heavy metals. Recently, dioxin removal technology has been introduced.

또한, 맥반석은 미네랄 용출작용을 한다. 맥반석으로부터 인체에 활력을 주는 40여종 이상의 미네랄이 용출되어 신진대사와 피부건강관리에 효과가 있다.In addition, elvan has a mineral eluting effect. More than 40 minerals that elevate the human body from elvan are effective for metabolism and skin health management.

또한, 맥반석은 수질조절 및 정수작용을 한다. 맥반석은 산성이나 강한 알칼리성 물을 약알칼리성(pH 7.2 내지 7.4)으로 조절하며, 수질을 활성화시켜 정수작용을 한다.In addition, elvan has water quality control and water purification. Elvanite controls acidic or strong alkaline water to weak alkaline (pH 7.2 to 7.4) and activates water quality to purify water.

또한, 맥반석은 풍부한 산소함유량을 갖는다. 맥반석을 물에 담그면 COD(화학적 산소요구량), BOD(생물학적 산소요구량)가 낮아져 방부작용은 물론 활성화에 따른 생체에 활력을 준다.In addition, elvan has abundant oxygen content. Soaking elvan in water lowers COD (chemical oxygen demand) and BOD (biological oxygen demand), thereby providing vitality to the living body as well as antiseptic action.

또한, 맥반석은 원적외선 방사작용을 한다. 맥반석은 원적외선 방사에 의한 공명, 공진, 흡수작용 등으로 식품의 신선도 유지, 맛의 증가, 혈액순환 및 신진대사 촉진 등에 탁월한 효과가 있다.In addition, elvan has far-infrared radiation. Elvan stones have excellent effects on maintaining food freshness, increasing taste, promoting blood circulation and metabolism by resonance, resonance, and absorption by far-infrared radiation.

[실시예]EXAMPLE

하기 표 1의 조성 및 표 3의 제조공정에 따라 본 발명의 석재 뿜칠재를 제조하였다. 이때 사용된 아크릴 칼라칩의 조성은 표 2와 같다.According to the composition of Table 1 and the manufacturing process of Table 3 was prepared stone blowing material of the present invention. The composition of the acrylic color chip used at this time is shown in Table 2.

표 4는 상기 실시예에 따라 제조한 본 발명에 따른 석재 뿜칠재의 물성을 나타낸 것으로, 강도 등 전반적인 물성이 우수하며, 특히 높은 원적외선 방사성능을 발휘함을 확인할 수 있다.Table 4 shows the physical properties of the stone blowing material according to the present invention prepared according to the embodiment, it can be confirmed that the overall physical properties such as strength is excellent, especially high far-infrared radiation performance.

도 1 내지 도 7은 종래와 본 발명에 따른 석재 뿜칠재의 제품 사진을 비교한 것으로, 도 1(종래 제품) 및 도 2(본 발명 제품), 도 4(종래 제품) 및 도 5(본 발명 제품), 도 6(종래 제품) 및 도 7(본 발명 제품)를 각각 비교하면, 본 발명에 따른 석재 뿜칠재 제품의 경우 최대 15 mm의 아크릴 칼라칩을 이용함으로써, 입체효과가 종래 제품보다 우수함을 확인할 수 있다.1 to 7 is a comparison of the product picture of the stone fuming material according to the prior art and the present invention, Figure 1 (primary product) and Figure 2 (present product), Figure 4 (conventional product) and Figure 5 (present invention) Product), Figure 6 (conventional product) and Figure 7 (product of the present invention), respectively, in the case of stone fuming material according to the present invention by using an acrylic color chip of up to 15 mm, the stereoscopic effect is superior to the conventional products can confirm.

본 발명에 따른 석재 뿜칠재 조성물은 아크릴 칼라칩을 포함하여 입체감이 뛰어나고, 순수한 아크릴 에멀젼을 사용하여 표면강도가 우수하고 투명도가 뛰어나며, 방해석을 사용하여 은폐력과 백색도 및 내변색성 등이 우수하고, 맥반석을 다량으로 함유하고 있어 인체에 이로우며, 특히 스프레이 작업이 가능하도록 설계된 제품이다.Stone spraying material composition according to the present invention is excellent in three-dimensional feeling, including acrylic color chips, excellent surface strength and excellent transparency using pure acrylic emulsion, excellent hiding power and whiteness and discoloration resistance using calcite, It contains a large amount of elvan, which is good for the human body. Especially, it is designed to be sprayed.

도 1은 종래의 석재 뿜칠재 제품 사진이다.1 is a photograph of a conventional stone blowing material.

도 2는 본 발명의 일 실시예에 따른 석재 뿜칠재의 제품 사진이다.Figure 2 is a product picture of the stone blowing material according to an embodiment of the present invention.

도 3은 본 발명의 다른 실시예에 따른 석재 뿜칠재의 제품 사진이다.Figure 3 is a product picture of the stone blowing material according to another embodiment of the present invention.

도 4는 종래의 다른 석재 뿜칠재의 제품 사진이다.Figure 4 is a product photograph of another conventional stone blowing material.

도 5는 본 발명의 또 다른 실시예에 따른 석재 뿜칠재의 제품 사진이다.Figure 5 is a product picture of the stone spraying material according to another embodiment of the present invention.

도 6은 종래의 또 다른 실시예에 따른 석재 뿜칠재의 제품 사진이다.Figure 6 is a product picture of the stone blowing material according to another embodiment of the prior art.

도 7은 본 발명의 또 다른 실시예에 따른 석재 뿜칠재의 제품 사진이다.Figure 7 is a product picture of the stone blowing material according to another embodiment of the present invention.

Claims (4)

아크릴 에멀젼 10 내지 20 중량%, 아크릴 칼라칩 1 내지 10 중량%, 맥반석 10 내지 30 중량%, 방해석(80 mesh) 20 내지 30 중량%, 방해석(60 mesh) 10 내지 20 중량%, 방해석(40 mesh) 5 내지 15 중량%, 산화아연(ZnO) 1 내지 3 중량% 및 물 1 내지 15 중량%를 포함하는 석재 뿜칠재 조성물.10 to 20% by weight of acrylic emulsion, 1 to 10% by weight of acrylic color chip, 10 to 30% by weight of ganbanite, 20 to 30% by weight of calcite (80 mesh), 10 to 20% by weight of calcite (60 mesh), calcite (40 mesh) ) 5 to 15% by weight, zinc oxide (ZnO) 1 to 3% by weight and 1 to 15% by weight of the stone fumes material composition. 제1항에 있어서, 상기 아크릴 칼라칩은 아크릴 에멀젼 20 내지 40 중량%, 이산화 티타늄 10 내지 20 중량%, 탄산칼슘 10 내지 30 중량%, 아크릴 폴리머 10 내지 20 중량%, 물 10 내지 20 중량%를 포함하는 아크릴 필름을 분쇄한 것임을 특징으로 하는 석재 뿜칠재 조성물.According to claim 1, wherein the acrylic color chip is 20 to 40% by weight acrylic emulsion, 10 to 20% by weight titanium dioxide, 10 to 30% by weight calcium carbonate, 10 to 20% by weight acrylic polymer, 10 to 20% by weight water Stone-splashing material composition, characterized in that the pulverized acrylic film comprising. 제1항 또는 제2항에 있어서, 상기 아크릴 칼라칩의 크기가 10 내지 15 mm인 것을 특징으로 하는 석재 뿜칠재 조성물.The stone fumed material composition according to claim 1 or 2, wherein the acrylic color chip has a size of 10 to 15 mm. 제1항 또는 제2항에 있어서, 상기 아크릴 에멀젼에 사용되는 아크릴 수지가 -15 내지 -10℃의 유리전이온도(Tg)를 갖는 아크릴 공중합체인 것을 특징으로 하는 석재 뿜칠재 조성물.The stone fuming material composition according to claim 1 or 2, wherein the acrylic resin used in the acrylic emulsion is an acrylic copolymer having a glass transition temperature (Tg) of -15 to -10 ° C.
KR1020050019888A 2005-03-10 2005-03-10 Stone-based spray-painting composition KR100509679B1 (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100912924B1 (en) * 2009-02-05 2009-08-20 최성필 Stone-like spray-painting composition, method for preparing and using the same
KR101519404B1 (en) * 2014-11-03 2015-05-13 유지씨 주식회사 Building coating method using the composition and the composition born tile paint to prevent flow down
CN105838175A (en) * 2016-04-25 2016-08-10 金华市佳丽涂料有限公司 Pure acrylic mercerized external wall paint and preparation technique thereof
KR101667252B1 (en) 2015-12-16 2016-10-18 박창래 Stone based paint composition

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100912924B1 (en) * 2009-02-05 2009-08-20 최성필 Stone-like spray-painting composition, method for preparing and using the same
KR101519404B1 (en) * 2014-11-03 2015-05-13 유지씨 주식회사 Building coating method using the composition and the composition born tile paint to prevent flow down
KR101667252B1 (en) 2015-12-16 2016-10-18 박창래 Stone based paint composition
CN105838175A (en) * 2016-04-25 2016-08-10 金华市佳丽涂料有限公司 Pure acrylic mercerized external wall paint and preparation technique thereof

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