KR100504081B1 - Composition of Waterproof and Operation method - Google Patents

Composition of Waterproof and Operation method Download PDF

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KR100504081B1
KR100504081B1 KR10-2002-0027994A KR20020027994A KR100504081B1 KR 100504081 B1 KR100504081 B1 KR 100504081B1 KR 20020027994 A KR20020027994 A KR 20020027994A KR 100504081 B1 KR100504081 B1 KR 100504081B1
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parts
waterproofing agent
water
agent
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KR20020054280A (en
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정인규
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주식회사 대화 정밀화학
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16Antifouling paints; Underwater paints
    • C09D5/1687Use of special additives
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/46Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with organic materials
    • C04B41/48Macromolecular compounds
    • C04B41/4857Other macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K3/00Materials not provided for elsewhere
    • C09K3/18Materials not provided for elsewhere for application to surfaces to minimize adherence of ice, mist or water thereto; Thawing or antifreeze materials for application to surfaces
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2103/00Function or property of ingredients for mortars, concrete or artificial stone
    • C04B2103/60Agents for protection against chemical, physical or biological attack
    • C04B2103/65Water proofers or repellants
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00482Coating or impregnation materials
    • C04B2111/00577Coating or impregnation materials applied by spraying
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • C04B2111/27Water resistance, i.e. waterproof or water-repellent materials

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Ceramic Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Structural Engineering (AREA)
  • Materials Applied To Surfaces To Minimize Adherence Of Mist Or Water (AREA)
  • Paints Or Removers (AREA)

Abstract

본 발명은 스프레이용 초속경화형 수용성 도막 방수제의 조성물과 고무화 아스팔트의 특성을 가진 방수제를 특수 에어레스 스프레이기와 정밀 정량펌프로 구성된 도장기기를 이용한 방수도막의 시공방법에 관한 것이다.The present invention relates to a method of constructing a waterproof coating using a coating device composed of a composition of a super fast-curing water-soluble coating waterproofing agent for spraying and rubberized asphalt with a special airless sprayer and a precise metering pump.

본 발명은 수직벽, 천장과 같이 후도막 방수제의 작업이 어려운 곳에도 도막 두께와 이음부분이 없는 방수층의 시공이 용이하며 다소의 습기가 있는 곳에도 시공이 가능하고 소지면의 전처리도 용이하다The present invention is easy to install the waterproof layer without the coating thickness and the joint part even in the difficult work of the thick film waterproofing agent such as the vertical wall, the ceiling, and can be installed even in the presence of some moisture and the pretreatment of the small surface is also easy.

특히, 인건비 절감, 공기단축 및 우수한 방수층이 확보되고 수용성이므로 작업자의 안전과 주의 환경에도 영향이 없다. 이와 같은 본 발명은 초속경화형 수용성 고무화 아스팔트에 스틸렌부타디엔 공중합 에멀젼수지를 가교화시키고 특수합성된 무기염류를 경화제로하여 2액형 분사에어레스기에 멀티헤드스프레이건을 이용, 소지면에 분사 도착 시킬 수 있게 한 지하구조물 및 대형 토목구조물의 방수제로 적합한 방수제를 제공한 것이다.In particular, labor cost savings, air shortening and excellent waterproof layer is secured and water-soluble, so there is no impact on the safety of the worker and the environment. The present invention crosslinks the styrene-butadiene copolymer emulsion resin to the super-curable water-soluble rubberized asphalt, and uses a specially synthesized inorganic salt as a curing agent to use a multi-head spray gun in a two-component spray airless device to make it spray on the surface of the paper. To provide a waterproofing agent suitable for the waterproofing of underground structures and large civil structures.

본 발명의 방수제 조성물은 다음과 같이 제조된다.The waterproofing agent composition of the present invention is prepared as follows.

혼합용기에 정수 5중량부와 유화제 0.5중량부를 혼합하여 투입하고 pH와 온도가 조절된 스틸렌부타디엔 공중합수지 40중량부를 교반, 45℃ 이하로 유지하며 pH를 검사하여 pH 조절제를 5부정도 투입하여 pH를 규격에 일치시키고, 유화 아스팔트 안정제 5중량부 소포제 1.5중량부, 흐름방지제 3중량부로 혼합하여 된 도막 방수제와 그 시공방법에 관한 발명이다5 parts by weight of purified water and 0.5 parts by weight of an emulsifier are mixed, and 40 parts by weight of styrene-butadiene copolymer resin having a pH and temperature controlled is stirred and maintained at 45 ° C. or lower. The invention relates to a coating film waterproofing agent and a method for constructing the same according to the standard, and mixed with 5 parts by weight of an emulsified asphalt stabilizer, 1.5 parts by weight of an antifoaming agent, and 3 parts by weight of a flow inhibitor.

Description

수용성 방수제의 조성물과 시공방법{Composition of Waterproof and Operation method}Composition and Waterproofing Method of Water-Soluble Waterproofing Agent

본 발명은 스프레이용 초속경화 수용성 도막 방수제의 조성물과 시공방법에 관한 것으로 유화 아스팔트에 스틸렌부타디엔 공중합을 매체로 하여 소포제, 안정제, 흐름제방지제 등을 배합하여 제조한 수용성 고무화 아스팔트 방수제의 조성물과 특수제조된 무기염류를 용기에 주입하여 경화제로 한 것과 본 발명을 실시할 수 있게 제작된 에어레스 스프레이기에 결합하여 정밀 정량펌프를 이용한 기계적 방법으로 방수제와 경화제를 분사하여 소지면에 도포할 수 있게 한 발명이다.The present invention relates to a composition of a super fast-curing water-soluble coating waterproofing agent for spraying and a construction method. The composition of water-soluble rubberized asphalt waterproofing agent prepared by mixing styrene butadiene copolymerization with emulsified asphalt as a medium, antifoaming agent, stabilizer, anti-flowing agent, etc. Invented by injecting the prepared inorganic salt into a container as a curing agent and combined with an airless sprayer manufactured to implement the present invention by spraying a waterproofing agent and a curing agent by a mechanical method using a precise metering pump to apply to the surface to be.

본 발명은 부정형의 토목구조물인 암벽, 흙벽, 천장 수직벽 교량 상판 등과 같이 기존의 방수제로 시공하기가 곤란한 곳에 단 1회의 도포로서 완벽한 방수층을 형성 할 수 있고 습기가 있는 곳에도 시공이 가능할 뿐 아니라 작업자의 안전 및 주변환경에도 유해한 영향을 주지 않는 환경친화적인 방수제를 제공하고자 한다.The present invention can form a perfect waterproof layer by only one application where it is difficult to install with existing waterproofing agents such as rock walls, soil walls, ceiling vertical wall bridge tops, etc., which are irregular civil structures, and can be constructed even where there is moisture. It is intended to provide environmentally friendly waterproofing agents that do not adversely affect worker safety and the surrounding environment.

종래의 도막 방수제는 유기용제 타입의 경우 습기가 있는 소지면에는 적용이 불가능하였고 화재위험, 작업자의 안전성 결여, 밀폐된 곳의 시공이 불가능한 결함이 많았다. 특히, 수용성 방수제인 경우 수직벽의 시공시 여러번 도포해도 도막두께를 얻기 힘들며 습기가 있을 경우 경화가 되지 않았고 벤토나이트 및 시이트 방수의 경우 이음부분의 하자가 많으나 본 발명은 종래의 유기용제 타입, 수용성 도막 방수제, 시이트 방수, 벤토나이트 방수 등의 결함을 해결할 수 있는 이점이 있다.Conventional coating waterproofing agent was not applicable to the wet surface of the organic solvent type, there were a lot of defects such as fire risk, lack of safety of the worker, impossible to install in a closed place. Particularly, in the case of water-soluble waterproofing agent, it is difficult to obtain the coating thickness even when applied several times during the construction of the vertical wall, and when there is moisture, it is not cured. In the case of bentonite and sheet waterproofing, there are many defects in the joints. There is an advantage that can solve the defects such as waterproofing, sheet waterproofing, bentonite waterproofing.

본 발명은 경화시간이 분사후 4~5초 이내에 경화되므로써 단 1회의 도포로 종래의 도막 방수제로서 시공이 어려웠던 천장부위, 수직벽, 부정형의 토목구조물 대규모 교량상판 부위에 짧은 기간 내에 간편하게 소요되는 도막두께를 얻음으로써 우수한 방수층을 형성할 수 있고 시공비 절감, 공기단축, 수용성으로서 안전도 제고 등을 구현하고자 한다.In the present invention, since the curing time is cured within 4 to 5 seconds after the spraying, the coating film is easily used in a short period of time on the ceiling, vertical walls, and large-scale bridge tops of irregular structures, which were difficult to install as a conventional coating film waterproofing agent with only one coating. By obtaining the thickness, an excellent waterproof layer can be formed, and construction cost reduction, air shortening, and water solubility will be realized.

상기 목적을 달성하기 위하여, 본 발명은 수용성 방수제 조성물이 첨가된 멀티헤드스프레이건에 정밀 정량펌프를 결합하여 1회에 2-5mm의 분사도막이 도포되도록 하며, 상기 수용성 방수제 조성물은 정수 3-10 중량부, 유화제 0.1-1.0 중량부, 스틸렌부타디엔 공중합 수지 20-40 중량부, 아스팔트 40-60 중량부, pH 조절제 2-8 중량부, 유화아스팔트 안정제 2-8 중량부, 소포제 0.5-2 중량부, 흐름방지제 1-5 중량부로 이루어진 조성물 100 중량부에 대해 무기염류 경화제 0.2 내지 0.5 중량부를 포함하는 것인 수용성 방수제의 시공방법을 제공한다.이하 본 발명은 스프레이용 초속경화 수용성도막 방수제의 조성물과 시공방법을 실시예에 따라 상술하면 다음과 같다.In order to achieve the above object, the present invention is to combine the precision metering pump to the multi-head spray gun to which the water-soluble waterproofing agent composition is added so that a spray coating film of 2-5mm at a time, the water-soluble waterproofing agent composition is an integer of 3-10 weight Parts, 0.1-1.0 parts by weight of emulsifier, 20-40 parts by weight of styrene-butadiene copolymer resin, 40-60 parts by weight of asphalt, 2-8 parts by weight of pH adjuster, 2-8 parts by weight of emulsion stabilizer, 0.5-2 parts by weight of antifoaming agent, It provides a method for the construction of a water-soluble waterproofing agent comprising 0.2 to 0.5 parts by weight of an inorganic salt curing agent with respect to 100 parts by weight of the composition consisting of 1-5 parts by weight of the flow preventing agent. The method will be described in detail according to an embodiment as follows.

[실시 예][Example]

작업온도를 120℃에서 60℃ 사이에서 임의로 조절할 수 있도록 제작된 혼합기를 사용하여 정수 5 중량부와 유화제 0.5중량부를 혼합기에 투입하여 pH와 온도가 조절된 스틸렌부타디엔 공중합수지 40중량부를 투입 교반하면서 45℃ 이하로 유지한다.Using a mixer designed to adjust the working temperature arbitrarily between 120 ° C and 60 ° C, 5 parts by weight of purified water and 0.5 parts by weight of an emulsifier were added to the mixer, and 40 parts by weight of styrene-butadiene copolymer resin having a pH and temperature controlled was added while stirring 45 Keep below ℃.

120℃ 이하로 온도가 조절된 아스팔트 40중량부를 투입하여 지정된 회전속도로 30분간 교반하면서 온도를 70℃ 이하로 유지하며 pH를 검사하여 pH 조절제를 5 중량부로 투입하여 pH를 규격에 일치시키고 안정제 5 중량부를 투입하여 10분간 혼합하고 소포제 1.5 중량부, 흐름방지제 3 중량부를 투입하고 충분히 혼합하여 흐름성을 검사한다.40 parts by weight of asphalt with temperature controlled below 120 ° C. was added, and the temperature was maintained at 70 ° C. or lower while stirring for 30 minutes at a specified rotational speed. Add weight part and mix for 10 minutes, add 1.5 weight part of antifoams, and 3 weight part of flow inhibitors, and mix thoroughly, and check flowability.

흐름성은 흐름방지제 0.5중량부 이내 또는 정수 2중량부 이내에서 추가하여 조정하여야 하고 적정 흐름성이 확보된 제품은 점도를 2500cps 이하로 조정하여 pH, 고형분 등을 확인한 후 지정 용기에 포장한다.The flowability should be adjusted by adding within 0.5 parts by weight of flow inhibitor or within 2 parts by weight of purified water. For products with proper flowability, adjust the viscosity to 2500 cps or less and check the pH, solid content, etc., and pack them in designated containers.

경화제인 무기염류는 저장성을 고려하여 별도 용기에 포장한다. 시공시 기온, 습도 등을 감안하여 주제와 경화제를 조절하여 특수제작된 멀티헤드스프레이건을 사용하여 1회에 2~5mm가 분사 도막이 되도록 반복 도포하여 소요 도막두께에 도달 되도록 주제와 경화제를 지정 비율로 혼합하여 분사 도포한다.Inorganic salts, which are curing agents, are packaged in separate containers in consideration of shelf life. Using the specially designed multihead spray gun by adjusting the main material and hardener in consideration of the temperature and humidity during construction, the main material and hardener are designated to reach the required coating thickness by repeatedly applying 2 ~ 5mm spray coating film at once. Mix by spraying and apply.

본 발명에서 사용된 소포제는 미네랄 오일타입의 소포제를 사용하였으며, 유화아스팔트 안정제는 폴리올 계열의 유화제를 사용하였다. 특히 흐름방지제는 유화아스팔트 안정제와의 상용성을 고려하여 다가알콜 계열의 제품을 사용하였다. 경화제인 무기염류는 극소량만 사용할 수 있도록 하면서도 혼합이 용이하도록 특수조제품을 사용하였다.The defoaming agent used in the present invention used a mineral oil type defoaming agent, and the emulsion asphalt stabilizer used a polyol emulsifier. In particular, the flow inhibitor was used a polyalcohol-based product in consideration of compatibility with the emulsion asphalt stabilizer. Inorganic salts, which are curing agents, were used in special preparations for easy mixing even though very small amounts could be used.

다음표는 본 발명과 종래 공법의 장. 단점을 비교한 것이다.The following table shows the chapters of the present invention and conventional methods. The disadvantages are compared.

(표) 스프레이용 초속경화형 수용성 고무화 아스팔트 방수제와 기존 공법의 장. 단점비교(Table) Ultra-fast curing water-soluble rubberized asphalt waterproofing agent for spraying and chapters of existing methods. Comparison of disadvantages

상기 (표)에서 알 수 있는바와 같이 종래의 도막방수 시공에 비하여 본 발명품은 대규모 토목공사의구조물에 간단히 시공이 가능하며 공기단축, 시공원가절감, 부정형의 구조물에 원하는 만큼의 방수층을 형성하여 대규모공사의 비용을 절감할 수 있고, 또 고무화 아스팔트를 주로 사용하여 저렴한 가격으로 시공이 가능한 스프레이용 초속경화 고무화 아스팔트 방수제의 발명이다.As can be seen in the above table, the present invention can be easily installed on the structure of large-scale civil engineering construction as compared to the conventional coating waterproofing construction, and a large scale by forming the desired waterproof layer on the structure of air shortening, city park reduction, and irregular structure. It is an invention of a super fast curing rubberized asphalt waterproofing agent for spraying, which can reduce the cost of construction and can be installed at a low price by using rubberized asphalt mainly.

Claims (3)

삭제delete 수용성 방수제 조성물이 첨가된 멀티헤드스프레이건에 정밀 정량펌프를 결합하여 1회에 2-5mm의 분사도막이 도포되도록 하며,Combine the precision metering pump with the multi-head spray gun to which the water-soluble waterproofing agent composition is added so that a spray coating film of 2-5 mm is applied at a time. 상기 수용성 방수제 조성물은 정수 3-10 중량부, 유화제 0.1-1.0 중량부, 스틸렌부타디엔 공중합 수지 20-40 중량부, 아스팔트 40-60 중량부, pH 조절제 2-8 중량부, 유화아스팔트 안정제 2-8 중량부, 소포제 0.5-2 중량부, 흐름방지제 1-5 중량부로 이루어진 조성물 100 중량부에 대해 무기염류 경화제 0.2 내지 0.5 중량부를 포함하는 것인 수용성 방수제의 시공방법.The water-soluble waterproofing agent composition is an integer of 3-10 parts by weight, 0.1-1.0 parts by weight of an emulsifier, 20-40 parts by weight of styrene-butadiene copolymer resin, 40-60 parts by weight of asphalt, pH regulator 2-8 parts by weight, emulsion stabilizer 2-8 A method of constructing a water-soluble waterproofing agent comprising 0.2 to 0.5 parts by weight of an inorganic salt curing agent based on 100 parts by weight of the composition consisting of parts by weight, antifoaming agent 0.5-2 parts by weight, and flow inhibitor 1-5 parts by weight. 삭제delete
KR10-2002-0027994A 2002-05-20 2002-05-20 Composition of Waterproof and Operation method KR100504081B1 (en)

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JPS59129260A (en) * 1983-01-14 1984-07-25 Daiwa Kobunshi Kogyo Kk Production of waterproof sheet
JPS62212489A (en) * 1986-03-14 1987-09-18 Idemitsu Petrochem Co Ltd Waterproof layer of construction
JPH04323215A (en) * 1991-04-23 1992-11-12 Toa Doro Kogyo Kk Curable composition
KR960041317A (en) * 1995-05-13 1996-12-19 이일쇄 Coating waterproofing agent and manufacturing method
KR19980062000A (en) * 1996-12-26 1998-10-07 강철구 Paint repellent
KR20010068964A (en) * 2000-01-11 2001-07-23 박찬구 Method of rubberized asphalt emulsion by using styrene-butadiene block copolymer
KR20010110252A (en) * 2001-11-06 2001-12-12 정인규 Compistion of water proofing material for reaction curing waterborn-rubber asphalt

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JPS59129260A (en) * 1983-01-14 1984-07-25 Daiwa Kobunshi Kogyo Kk Production of waterproof sheet
JPS62212489A (en) * 1986-03-14 1987-09-18 Idemitsu Petrochem Co Ltd Waterproof layer of construction
JPH04323215A (en) * 1991-04-23 1992-11-12 Toa Doro Kogyo Kk Curable composition
KR960041317A (en) * 1995-05-13 1996-12-19 이일쇄 Coating waterproofing agent and manufacturing method
KR19980062000A (en) * 1996-12-26 1998-10-07 강철구 Paint repellent
KR20010068964A (en) * 2000-01-11 2001-07-23 박찬구 Method of rubberized asphalt emulsion by using styrene-butadiene block copolymer
KR20010110252A (en) * 2001-11-06 2001-12-12 정인규 Compistion of water proofing material for reaction curing waterborn-rubber asphalt

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