KR100489722B1 - Cleaning composition - Google Patents

Abstract

Anionic surfactants that impart hair cleansing, wet tangle removal properties, dry tangle removal properties, and ease of handling, and are relatively irritant and suitable for use by infants and adults with sensitive skin and eyes, There is provided a conditioning shampoo composition comprising a mixture of an amphoteric surfactant and an optional conditioner.

Description

Cleaning composition

The present invention not only imparts hair cleansing, wet tangle removal, dry tangle removal and handling properties, but also is relatively irritant and therefore suitable for use by infants and adults with sensitive skin and eyes. A conditioning cleaning composition suitable for use in the invention.

In the past, it has been considered desirable to clean hair after conditioning. Over the years, it was necessary to carry out these actions in two separate steps. However, with the development of so-called "two-in-one" conditioning shampoos, it is possible to carry out conditioning and cleansing simultaneously. Unfortunately, many of these two-in-one conditioning shampoos and body cleansers have been found to be relatively irritating to the eyes and skin, making them inconvenient for use by children or sensitive adults. Accordingly, it is an object of the present invention to develop a conditioning shampoo having excellent cleansing performance, excellent conditioning properties and low irritation to eyes and skin.

Summary of the Invention

According to the invention,

A surfactant moiety comprising a nonionic surfactant (1), an amphoteric surfactant (2) and an anionic surfactant (3),

Cationic cellulose derivatives (1), cationic guar derivatives (2) and chemical formulas Monomers of (a), wherein R is H or CH ₃ , Y is O or NH, R ₁ is an alkylene group having from about 2 to about 6 carbon atoms, and R ₂ , R ₃ and R ₄ are each independently An alkyl group or hydroxyalkyl group having about 1 to about 22 carbon atoms, X is a monovalent anion selected from halides and alkyl sulfates having about 1 to about 4 carbon atoms] and cationic monomers selected from diallyldimethylammonium chloride (b) A cleaning composition is provided comprising a conditioner portion comprising two or more cationic conditioning polymers selected from homopolymers or copolymers 3 of.

According to another aspect of the invention, based on the total weight of the composition,

Chemical formula Carboxyalkyl alkyl polyamine amphoteric surfactant (a), wherein I is an alkyl group or alkenyl group of about 8 to about 22 carbon atoms, R ₂₂ is a carboxyalkyl group of about 2 to about 3 carbon atoms, and R ₂₁ is Alkylene group of about 2 to about 3 carbon atoms, u is an integer of 1 to 4;

Alkyl sulfate of formula R'-CH ₂ OSO ₃ X '(1) and formula Alkylaryl sulfonates (2), wherein R 'is an alkyl group having from about 7 to about 14 carbon atoms, R' ₁ is an alkyl group having from about 1 to about 12 carbon atoms, and X 'is an alkali metal ion, an alkaline earth metal ion , Ammonium ions, and ammonium ions substituted by about 1 to about 3 substituents, wherein each substituent may be the same or different and has an alkyl group of 1 to 4 carbon atoms and a hydroxyalkyl group of about 2 to about 4 carbon atoms Anionic surfactant (b) except for the anionic surfactant of the group consisting of

Any nonionic surfactant (c),

If the nonionic surfactant is omitted and the anionic surfactant is an alkyl ether sulfate of the formula R '(OCH ₂ CH ₂ ) _v OSO ₃ X', a cleaning composition is provided where v is 3 or greater.

According to another aspect of the present invention,

Chemical formula Amidoalkyl sulphate amphoteric surfactant (a), wherein E is an alkyl group or alkenyl group of about 7 to about 21 carbon atoms, and R ₁₄ and R ₁₅ are each independently alkyl of about 1 to about 4 carbon atoms Group or a hydroxyalkyl group, r is an integer from about 2 to about 6, and R ₁₃ is an alkylene group or hydroxyalkylene group of about 2 to about 3 carbon atoms],

Alkyl sulfate of formula R'-CH ₂ OSO ₃ X '(1), alkyl ether sulfate of formula R' (OCH ₂ CH ₂ ) _v OSO ₃ X 'and formula Alkylaryl sulfonates (3), wherein R 'is an alkyl group having from about 7 to about 14 carbon atoms, R' ₁ is an alkyl group having from about 1 to about 12 carbon atoms, and X 'is an alkali metal ion, an alkaline earth metal ion , Ammonium ions, and ammonium ions substituted by about 1 to about 3 substituents, wherein each substituent may be the same or different and has an alkyl group of 1 to 4 carbon atoms and a hydroxyalkyl group of about 2 to about 4 carbon atoms An anionic surfactant (b) except for the anionic surfactant of the group consisting of

There is provided a cleaning composition comprising any nonionic surfactant (c).

When the composition of the present invention is used as a shampoo or body cleanser, the composition possesses one or more of the following characteristics: cleansing, wet tangle removal, dry tangle removal, ease of handling and hypoallergenicity of the eye.

In one aspect of the invention, the shampoo composition may suitably comprise, consist of or consist essentially of anionic surfactants, amphoteric surfactants, nonionic surfactants and two or more cationic conditioning polymers. have. The composition is preferably based on the total weight of the shampoo composition, preferably from about 5% to about 20%, more preferably from about 5% to about 14% of the surfactant portion and from about 0.01% to about 3.0%, preferably from about 0.01% of the conditioner portion. To about 2.0%, more preferably about 0.01 to about 1.0%, even more preferably about 0.01 to about 0.5%, most preferably about 0.01 to about 0.3%.

In such embodiments, the surfactant portion of the present invention contains nonionic, amphoteric and anionic surfactants. Preferably, the weight ratio between the amphoteric surfactant and the anionic surfactant may range from about 3: 1 to about 1: 3, preferably from about 2: 1 to about 1: 2. The weight ratio of the amphoteric surfactant / anionic surfactant blend to the nonionic surfactant can range widely, preferably from about 2: 1 to about 1: 2. The nonionic surfactant is present in an amount of about 0.1 to about 10%, preferably about 1 to about 10%, more preferably about 4 to about 8%, based on the total weight of the shampoo composition. The amphoteric surfactant is present in an amount of about 0.5 to about 10%, preferably about 1 to about 8%, more preferably about 2 to about 6%, based on the total weight of the shampoo composition. The anionic surfactant is present in the shampoo composition in an amount of about 1.0 to about 10%, preferably about 1 to about 8%, more preferably about 1 to about 6%, based on the total weight of the shampoo composition.

One class of nonionic surfactants useful in the present invention are polyoxyethylene derivatives of polyol esters, wherein the polyoxyethylene derivatives of the polyol esters are (1) fatty acids having about 8 to about 22 carbon atoms, preferably about 10 to 14 carbon atoms. derived from (a) and polyol (b) selected from sorbitol, sorbitan, glucose, α-methyl glucoside, polyglucose, glycerin, pentaerythritol and mixtures thereof having an average of about 1 to about 3 glucose residues per molecule and (2) an average of about 10 to about 120, preferably about 20 to about 80, oxyethylene units, and (3) an average of about 1 to about 3 fatty acid residues per mole of polyoxyethylene derivative of the polyol ester Have

Examples of polyoxyethylene derivatives of preferred polyol esters include, but are not limited to, PEG-80 sorbitan laurate and polysorbate 20. PEG-80 sorbitan laurate, a sorbitan monoester of lauric acid ethoxylated with an average of about 80 moles of ethylene oxide, was described by ICI Surfactants of Walmington, Delaware, "Atlas. G-4280 "is commercially available under the trade name. Polysorbate 20, a laurate monoester of a mixture of sorbitol and sorbitol anhydride condensed with about 20 moles of ethylene oxide, is commercially available under the trademark "Tween 20" from IC Eye Surfactants.

Another class of suitable nonionic surfactants include long chain alkyl glucosides or polys which are condensation products of long chain alcohols (a) with from about 6 to about 22 carbon atoms, preferably from about 8 to about 14 carbon atoms, with glucose or glucose-containing polymers (b). There is glucoside. Alkyl glucosides have from about 1 to about 6 glucose residues per alkyl glucoside molecule. Preferred glucosides are decyl glucosides, the condensation products of decyl alcohol and glucose polymers, and are marketed under the trade name "Plantaren 2000" by Henkel Corporation, Hoboken, NJ.

The composition of the present invention also contains an amphoteric surfactant. As used herein, the term "amphoteric" refers to molecules containing both acidic and basic moieties, such as amino acids containing both amino (basic) and acidic (eg carboxylic, acidic) functional groups (1 ) Or a zwitterionic molecule (2) having both positive and negative charges in the same molecule. The latter charge may or may not be dependent on the pH of the composition. Examples of zwitterionic materials include, but are not limited to, alkyl betaines and amidoalkyl betaines. Amphoteric surfactants are described herein without the use of counterions. One skilled in the art will recognize that under the pH conditions of the compositions according to the invention, the amphoteric surfactant is electrically neutral or has a counterion, such as an alkali metal, alkaline earth metal or ammonium counterion, by balancing the positive and negative charges. Can be.

Commercially available amphoteric surfactants are suitable for use in the present invention and include, for example, ampocarboxylates, alkyl betaines, amidoalkyl betaines, amidoalkyl steines, amphophosphates, phosphobetaines, pyrophosphobetaines , Carboxyalkyl alkyl polyamines and mixtures thereof, but is not limited thereto.

Suitable ampocarboxylate compounds include compounds of the formula

A-CONH (CH ₂ ) _x N ⁺ R ₅ R ₆ R ₇

In the above formula,

A is an alkyl group or alkenyl group having about 7 to about 21 carbon atoms, preferably about 10 to about 16 carbon atoms,

x is an integer from about 2 to about 6,

R ₅ is hydrogen or a carboxyalkyl group having about 2 to about 3 carbon atoms, preferably hydrogen,

R ₆ has a carbon number of about 2 to about 3 hydroxy alkyl group, or the formula _{R 8 -O- (CH 2) n} CO 2 - and the alkylene group of the group (wherein, R ₈ is having from about 2 to about 3, n Is 1 or 2),

R ₇ is a carboxyalkyl group having about 2 to about 3 carbon atoms.

Preferably, the ampocarboxylate compound is an imidazoline surfactant and more preferably sold by Mona Chemical Company, Paterson, NJ under the trade name "Monateric 949J". Disodium lauro ampodiacetate. If ampocarboxylate is used in the shampoo composition, it should be present in an amount of about 0.5 to about 10%, preferably about 0.5 to about 6%, based on the total weight of the composition.

Examples of suitable alkyl betaines are compounds of the formula

^{_{BN + R 9 R 10 (CH}} 2) p CO 2 -

In the above formula,

B is an alkyl group or alkenyl group having about 8 to about 22 carbon atoms, preferably about 8 to about 16 carbon atoms,

R ₉ and R ₁₀ are each independently an alkyl group or hydroxyalkyl group having about 1 to about 4 carbon atoms,

p is 1 or 2.

Preferred betaines for use in the present invention are lauryl betaine, marketed under the trade name "Empigen BB / J" by Albright & Wilson, Ltd., West Midlands, UK. When present, alkyl betaines should be used in amounts of about 0.25 to about 10%, preferably about 0.25 to about 8%, more preferably about 0.25 to about 5%, based on the total weight of the composition.

Examples of suitable amidoalkyl betaines include compounds of the formula

_{D-CO-NH- (CH 2} ) q -N + R 11 R 12 (CH 2) m CO 2 -

In the above formula,

D is an alkyl group or alkenyl group having about 7 to about 21 carbon atoms, preferably about 7 to about 15 carbon atoms,

R ₁₁ and R ₁₂ are each independently an alkyl group or hydroxyalkyl group having about 1 to about 4 carbon atoms,

q is an integer from about 2 to about 6,

m is 1 or 2.

Preferred amidoalkyl betaines are cocamidopropyl betaines, sold under the trade name "Tegobetaine L7" by Goldschmidt Chemical Corporation, Hopewell, Va., USA. When present in the shampoo composition of the present invention, the amidoalkyl betaine is from about 0.25 to about 10%, preferably from about 0.25 to about 8%, more preferably from about 0.25 to about 5%, based on the total weight of the composition. Should be used in

Examples of suitable amidoalkyl sulfines are compounds of the formula

In the above formula,

E is an alkyl group or alkenyl group of about 7 to about 21 carbon atoms, preferably about 7 to about 15 carbon atoms,

R ₁₄ and R ₁₅ are each independently an alkyl group or hydroxyalkyl group having about 1 to about 4 carbon atoms,

r is an integer from about 2 to about 6,

R ₁₃ is an alkylene group or hydroxyalkylene group having about 2 to about 3 carbon atoms.

Preferably, the amidoalkyl sultine is Cocamido, marketed under the trade name "Mirataine CBS" by Rhone-Poulenc Inc., Cranbury, NJ, USA. Propyl hydroxide. When present in the shampoo composition of the invention, the amidoalkyl sultine is from about 0.5 to about 10%, preferably from about 1.0 to about 6%, more preferably from about 1.5 to about 5, based on the total weight of the composition Must be used in an amount of%.

Examples of suitable ampophosphate compounds are compounds of the formula

In the above formula,

G is an alkyl group or alkenyl group of about 7 to about 21 carbon atoms, preferably about 7 to about 15 carbon atoms,

s is an integer from about 2 to about 6,

R ₁₆ is hydrogen or a carboxyalkyl group having about 2 to about 3 carbon atoms,

R ₁₇ is from about 2 to hydroxyalkyl group, or the formula of about _{3 R 19 -O- (CH 2)} t -CO 2 carbon atoms ^- a group of (wherein, R ₁₉ is a carbon number of from about 2 to about 3 alkylene group or a hydroxyl Oxyalkylene group, t is 1 or 2),

R ₁₈ is an alkylene group or hydroxyalkylene group having about 2 to about 3 carbon atoms.

Preferably, the ampophosphate compounds are sodium lauroampo PG-acetate phosphate, which is sold under the trade name "Monateric 1023" by Mona Industries, and US Pat. No. 4,380,637, which is incorporated herein by reference in its entirety. The compound described in the above, and sodium lauroampo PG-acetate phosphate is most preferred.

Examples of suitable phosphobetaines are compounds of the formula

In the above formula,

E, r, R ₁ , R ₂ and R ₃ are as defined above.

Preferably, the phosphobetaine compounds are those compounds described in US Pat. Nos. 4,215,064, 4,617,414 and 4,233,192, the entire contents of which are incorporated herein by reference.

Examples of suitable pyrophosphobetaines are compounds of the formula

In the above formula,

E, r, R ₁ , R ₂ and R ₃ are as defined above.

Preferably, the pyrophosphobetaine compounds are the compounds described in US Pat. Nos. 4,382,036, 4,372,869 and 4,617,414, which are incorporated herein by reference in their entirety.

Examples of suitable carboxyalkyl alkyl polyamines are compounds of the formula

In the above formula,

I is an alkyl group or alkenyl group of about 8 to about 22 carbon atoms, preferably about 8 to about 16 carbon atoms,

R ₂₂ is a carboxyalkyl group having about 2 to about 3 carbon atoms,

R ₂₁ is an alkylene group having from about 2 to about 3 carbon atoms,

u is an integer from about 1 to about 4.

Preferably, the carboxyalkyl alkyl polyamine is sodium carboxymethyl coco polypropylamine sold by Akzo Nobel Surface Chemistry under the trade name "Ampholak 7CX / C". When present in the shampoo composition of the present invention, it should be used in an amount of about 0.5 to about 10%, preferably about 1.0 to about 8%, more preferably about 2.0 to about 6.0%, based on the total weight of the composition do.

In a preferred embodiment, the amphoteric surfactant portion of the composition comprises a mixture of amphoteric surfactants, such as ampocarboxylates and alkyl betaines or ampocarboxylates and amidoalkyl betaines. In such embodiments, the ampocarboxylate is present in an amount of about 0.5 to about 9.5% and the alkyl betaine or amidoalkyl betaine in an amount of about 9.5 to about 0.5% based on the total weight of the shampoo composition of the shampoo composition. exist.

Compositions of this embodiment also contain one or more anionic surfactants. Preferably such anionic surfactants are selected from the following surfactant classes.

Alkyl sulfates of formula R′-CH ₂ OSO ₃ X ′, alkyl ether sulfates of formula R ′ (OCH ₂ CH ₂ ) _v OSO ₃ X ′, formula Alkyl monoglyceryl ether sulfate, chemical formula Alkyl monoglyceride sulfate, chemical formula Alkyl monoglyceride sulfonates of formula R'-SO ₃ X 'alkyl sulfonates of formula Alkylaryl sulfonates Alkyl sulfosuccinate, chemical formula Alkyl ether sulfosuccinate, chemical formula Alkyl sulfosuccinate, chemical formula Alkyl amidosulfosuccinate of formula R '-(OCH ₂ CH ₂ ) _w -OCH ₂ CO ₂ X' of alkyl carboxylate, formula Of alkyl amidoethercarboxylates, Alkyl succinate, chemical formula Fatty acyl sarcosinate, chemical formula Fatty acyl amino acid, chemical formula Fatty acyl taurate, chemical formula Of fatty alkyl sulfoacetates Alkyl phosphates and mixtures thereof

R 'is an alkyl group having about 7 to about 22 carbon atoms, preferably about 7 to about 16 carbon atoms,

R ′ ₁ is an alkyl group having about 1 to about 18 carbon atoms, preferably about 8 to about 14 carbon atoms,

R ' ₂ is a substituent of a natural or synthetic L-amino acid,

X 'is an ammonium ion substituted by an alkali metal ion, an alkaline earth metal ion, an ammonium ion, and about 1 to about 3 substituents, wherein each substituent may be the same or different and has an alkyl group having 1 to 4 carbon atoms and Selected from the group consisting of about 2 to about 4 hydroxyalkyl groups),

v is an integer from 1 to 6,

w is an integer from 0 to 20].

Preferably, the anionic surfactant comprises sodium trideset sulfate, sodium laureth sulfate, disodium lauret sulfosuccinate or mixtures thereof. Sodium tridecet sulphate is generally a sulfate of the formula C ₁₃ H ₂₇ (OCH ₂ CH ₂ ) _n OSO ₃ Na and the sodium salt of ethoxylated tridecyl alcohol, where n is 1 to 4, Northfield, Illinois, USA Stepan Company, Inc., is commercially available under the trade name "Cedapal TD-403M." Sodium laureth sulfate is marketed under the name "Empicol 0251 / 70-J" by Albright & Wilson, Limited. Disodium lauret sulfosuccinate is available from Albright & Wilson, Limited under the trade name “MPICOL SDD”.

In this embodiment, the shampoo composition of the present invention also contains a conditioner portion comprising two or more cationic conditioning polymers. Preferred cationic conditioning polymers are selected from those mentioned below.

Cationic cellulose derivatives (1),

Cationic guar derivatives (1) and

Homopolymers or copolymers (3) of cationic monomers selected from monomers (a) and diallyldimethylammonium chloride (b) of formula (I).

[Formula I]

In Formula I above,

R is H or CH ₃ ,

Y is O or NH,

R ₁ is an alkylene group having about 2 to about 6 carbon atoms, preferably about 2 to about 3 carbon atoms,

R ₂ , R ₃ and R ₄ are each independently alkyl groups of about 1 to about 22 carbon atoms, preferably about 1 to about 4 carbon atoms,

X is a monovalent anion selected from halides and alkyl sulfates.

The amount of each conditioner component may range from about 0.01 to about 1.0%, preferably from about 0.01 to about 0.5%, more preferably from about 0.01 to about 0.2%, based on the total weight of the composition.

Preferably, the cationic cellulose derivative is a polymeric quaternary ammonium salt derived from the reaction of hydroxyethyl cellulose with trimethylammonium substituted epoxide. In this regard, a material known as Polyquaternium-10, sold under the trade name "Polymer JR-400" by Amerchol Corporation, Edison, NJ, is particularly useful.

The cationic guar derivatives are preferably guar hydroxypropyltriammonium chloride, which is commercially available under the trade name "Jaguar C-17".

Another preferred cationic polymer includes Is a compound derived from acrylamidopropyltriammonium chloride, and more preferably a copolymer of these monomers with acrylamide [Allied Colloids of Suffolk, Va., Is known as "Salcare SC60. "Available under the trade name".

Other preferred cationic conditioning polymers are those derived from monomeric diallyldimethylammonium chloride. Homopolymers of such monomers are polyquaternium-6, which is commercially available from Allite Colloid under the trade name "Salcare SC30". The copolymer of diallyldimethylammonium chloride with acrylamide is known as polyquaternium-7 and Allied Colloids is commercially available under the trade name "Salcare SC10".

In a preferred embodiment, the conditioner portion is a combination of cationic cellulose derivatives and cationic guar derivatives. In such embodiments, the cationic cellulose derivative is present in the composition in an amount of about 0.01 to about 2%, preferably about 0.05 to about 1.0%, more preferably about 0.05 to about 0.3%, based on the total weight of the shampoo composition. Present and the cationic guar derivative is present in an amount of about 0.01 to about 1.0%, preferably about 0.05 to about 1.0%, more preferably about 0.05 to about 0.3% based on the total weight of the shampoo composition.

In another preferred embodiment, the conditioner portion comprises a homopolymer or copolymer of cationic cellulose derivatives or cationic guar derivatives with cationic monomers of formula (I). In such embodiments, the cationic cellulose derivative or cationic guar derivative is present in an amount of about 0.01 to about 0.5%, preferably about 0.01 to about 0.2%, based on the total weight of the composition, and the homopolymer or The copolymer is present in an amount of about 0.01 to about 0.5%, preferably about 0.01 to about 0.2%, based on the total weight of the composition.

In another preferred embodiment, the conditioner portion comprises a homopolymer or copolymer of cationic guar derivatives and diallyldimethylammonium chloride. In such embodiments, the cationic guar derivative is present in an amount of about 0.01 to about 0.5%, preferably about 0.01 to about 0.2%, based on the total weight of the shampoo composition, and is a homopolymer or airborne of diallyldimethylammonium chloride. The coalescence is present in an amount of about 0.01 to about 0.5%, preferably about 0.01 to about 0.2%, based on the total weight of the shampoo composition.

According to another aspect of the invention, suitably in a total amount of about 4 to about 20%, preferably about 4 to about 15%, more preferably about 4 to about 10%, based on the total weight of the composition There is provided a composition comprising, consisting of, or consisting essentially of an amphoteric surfactant and an anionic surfactant present. Examples of suitable amphoteric surfactants are those mentioned above, preferably the aforementioned carboxyalkyl alkylpolyamines, amidoalkyl steines and mixtures thereof. Examples of suitable anionic surfactants are those mentioned above and preferably the alkyl sulfates or alkylaryl sulfonates (1) and amphoteric surfactants mentioned above are preferably mentioned above when the amphoteric surfactant is the carboxyalkyl alkyl polyamine mentioned above. In the case of the amidoalkyl sulphates mentioned there are anionic surfactants, except for the anionic surfactant compounds of the group consisting of alkyl sulfates, alkyl ether sulfates and alkylaryl sulfonates (2).

In such embodiments, the amounts of each of the amphoteric and anionic surfactants used in the composition may range from about 2 to about 10%, preferably from about 2 to about 6%, respectively, based on the total weight of the composition. have. The weight ratio of amphoteric surfactant to anionic surfactant ranges from about 3: 1 to about 1: 3, preferably from about 2: 1 to about 1: 2, most preferably from about 1.5: 1 to about 1: 1.5. Can be. Optionally, the compositions of this aspect may contain one or more of the aforementioned nonionic surfactants and / or one or more of the aforementioned cationic conditioners. Preferably, when a nonionic surfactant is used, it is a polyoxyethylene derivative of polyol esters, more preferably polysorbate 20 and preferred cationic conditioners are polyquaternium 10, guar hydroxypropyltriammonium chloride, acrylic Amidopropyl triammonium chloride / acrylamide copolymers and mixtures thereof. The amount of nonionic surfactant used in the composition is from about 0 to about 5%, preferably from about 0.5 to about 1%, based on the total weight of the composition. If a nonionic surfactant is used, the weight ratio of the amphoteric / anionic surfactant is from about 40: 1 to about 2: 1, preferably from about 20: 1 to about 10: 1. The amount of each cationic conditioner used in the composition is about 0 to about 0.5%, preferably greater than about 0% to about 0.3%, more preferably greater than about 0% to about 0.2%, based on the total weight of the composition. It may be in the range of.

The compositions of the present invention also enhance the appearance, feel and aroma, such as, but not limited to, pearlescent or brightening agents, thickening agents, secondary conditioners, humectants, chelating agents, and coloring agents, perfumes, preservatives, pH adjusting agents, and the like. It may include one or more optional ingredients including additives. The pH of the shampoo composition according to the invention is preferably maintained within the range of about 5 to about 7.5, more preferably about 5.5 to about 7.0.

Commercial percentes or brighteners that are capable of suspending water insoluble additives such as silicones and / or instruct the consumer that the product is a conditioning shampoo are suitable for use in the present invention. The percentene or brightening agent is present in an amount of about 0 to about 3%, preferably about 0.25 to about 2.5%, more preferably about 0.5 to about 1.5%, based on the total weight of the composition. Examples of suitable percentes or milking agents include fatty acids (a) of about 16 to about 22 carbon atoms and mono or diesters of ethylene or propylene glycol (b), fatty acids (a) of about 16 to about 22 carbon atoms and the formula HO- ( JO) _a mono- or diester of polyalkylene glycol (b), wherein J is an alkylene group having from about 2 to about 3 carbon atoms, a is 2 or 3, and has about 16 to about 22 carbon atoms Fatty alcohols, fatty esters of the formula KCOOCH ₂ L, wherein K and L are independently alkyl or alkylene groups having from about 15 to about 21 carbon atoms, inorganic solids insoluble in the shampoo composition and mixtures thereof, but It is not limited.

In a preferred embodiment, the percentene or bleaching agent is preformed and stabilized, such as those sold under the trade name "Euperian PK-3000" by Henkel Corporation, Hoboken, NJ. Into the shampoo composition as an aqueous dispersion. This material is a combination of glycol distearate (diester of ethylene glycol and steanic acid), laureth-4 [CH ₃ (CH ₂ ) ₁₀ CH ₂ (OCH ₂ CH ₂ ) ₄ OH] and cocamidopropyl betaine, Preferably in a weight percent ratio of about 25 to about 30: about 3 to about 15: about 20 to about 25, respectively.

Commercial thickeners that can impart a suitable viscosity to the conditioning shampoo composition are suitable for use in the present invention. If used, the thickening agent should be present in the shampoo composition in an amount sufficient to raise the Brookfield viscosity of the composition to a value of about 500 to about 10,000 centipoise. Examples of suitable thickening agents include polyethylene glycol (1) of the formula HO- (CH ₂ CH ₂ O) _z H (where z is an integer from about 3 to about 200) and fatty acids (2) from about 16 to about 22 carbon atoms. Mono or diesters, fatty acid esters of ethoxylated polyols, ethoxylated derivatives of mono and diesters of fatty acids and glycerin, hydroxyalkyl celluloses, alkyl celluloses, hydroxyalkyl alkyl celluloses and mixtures thereof. Preferred thickening agents include polyethylene glycol esters, more preferably "PEG 6000 DS" sold by Stephen Company, Northfield, Illinois, USA or Commiel S.P., Bologna, Italy. It is PEG-150 distearate marketed by Coiel, SpA.

Commercial secondary conditioners (such as volatile silicones) that provide additional benefits such as gloss to the hair are suitable for use in the present invention. Preferably, the volatile silicone conditioning agent has an atmospheric boiling point of less than about 220 ° C. The volatile silicone conditioner is present in an amount of about 0 to about 3%, preferably about 0.25 to about 2.5%, more preferably about 0.5 to about 1.0%, based on the total weight of the composition. Non-limiting examples of suitable volatile silicones include polydimethylsiloxane, polydimethylcyclosiloxane, such as polydimethylcyclosiloxane sold by Dow Corning Corporation, Midland, Mich., Under the trade name "DC 345." , Hexamethyldisiloxane, cyclomethicone fluids and mixtures thereof, preferably cyclomethicone fluids.

Commercial moisturizers that can provide moisturizing and conditioning properties to shampoo compositions are suitable for use in the present invention. The humectant is present in an amount from about 0 to about 10%, preferably from about 0.5 to about 5%, more preferably from about 0.5 to about 3%, based on the total weight of the composition. Non-limiting examples of suitable humectants include water-soluble liquid polyols (1) selected from the group comprising glycerin, propylene glycol, hexylene glycol, butylene glycol, dipropylene glycol, and mixtures thereof, formula HO- (R "O) _b Polyalkylene glycol (2) of -H, wherein R "is an alkylene group having from about 2 to about 3 carbon atoms, b is an integer from about 2 to about 10; formula CH ₃ -C ₆ H ₁₀ O ₅ Polyethylene glycol ether (3) of methyl glucose of-(OCH ₂ CH ₂ ) _c -OH, where c is an integer from about 5 to about 25; urea (4) and mixtures thereof (5), glycerin This is a preferred moisturizer.

Examples of suitable chelating agents are those that can protect and preserve the compositions of the present invention. Preferably, the chelating agent is marketed under the trade name "Versen 100XL" by EDTA, more preferably Dow Chemical Company, and is about 0 to about 0.5% based on the total weight of the composition, preferably Is tetrasodium EDTA present in an amount from about 0.05 to about 0.25%. Examples of suitable preservatives include Quaternium-15, commercially available from Dow Chemical Company as "Dowicil 200", which is about 0 to about 0.2%, preferably about 0.05, based on the total weight of the composition. Present in the composition in an amount from about 0.10%.

The above-mentioned compositions can be prepared by combining the desired components in a suitable container and mixing them under ambient conditions with conventional mixing means well known in the art, such as mechanically stirred propellers, paddles and the like. Although the order of mixing is not critical, it is preferred to pre-blend certain ingredients, such as perfumes and nonionic surfactants, before adding them to the main mixture.

When using cationic guar conditioners, it is desirable to pre-blend the cationic guar conditioners with glycerin under ambient conditions so that the guar conditioners are wetted by the glycerin. While the time to wet may vary, generally such time may range from about 5 to about 30 minutes. Preferably, the guar conditioner: glycerine weight ratio is about 1: 100 to about 1: 1, more preferably about 1:50 to about 1: 5, most preferably about 1:15 to about 1: 7. The resulting suspension is mixed with water under ambient conditions with a weight ratio of suspension: water of about 1: 5 to about 1:20. The resulting water-suspension mixture is acidified with an amount of acid, preferably citric acid, effective to lower the pH of the overall composition to a value of about 4.

When using the thickener component, it is also preferred to preblend the desired thickener with about 5 to about 20% water, preferably at a temperature of about 60 to about 80 ° C., based on the total weight of the composition. When processing with a thickening agent, it is desirable to lower the temperature of the overall composition below about 45 ° C. before adding any preformed pearlizer to it.

The cleaning composition of the present invention is preferably used in personal cleansing applications, including but not limited to gels such as shampoos, shower gels, baths such as baby baths, and the like.

The invention described by way of example herein may suitably be carried out in the absence of any ingredient, component or step not specifically described herein. Some examples are further described below to further illustrate the nature of the invention and the manner in which it is performed. However, the present invention should not be considered as being limited to these examples.

All amounts of materials are given in parts by weight based on 100 parts of the overall formulation unless otherwise stated. The following test procedure is used in the following examples.

1. Hair Conditioning Characteristics

The conditioning properties of the shampoo are determined by measuring the average energy and the force required to comb the hair in wet and dry conditions after washing the hair with a specific shampoo formulation according to the following method.

a) hair sample preparation

Human hair bundles are prepared by weighing about 10-12 grams of natural brown hair and then bonding the epidermal ends with cable ties and hot melt glue. The epidermal end of the hair bundle is placed in a binder clip. Spread the hair evenly over the binder clean width. A hot melt glue is applied along the edge of the binder clip to join the clip with the hair. Apply glue to the inside of the clip to see the additional strength. Apply a rubber band to the outside of the clip so that the jaws of the grip do not separate Dry the glue completely. The hair bundle is immersed in methanol for 10 seconds and then the hair bundle is taken out and washed by air drying to remove contaminants such as dust and shampoo residues. Remove loose hair. Tangle is removed by combing the hair bundle with a standard comb or brush. Static static guns are used to eliminate static charge formation.

The number of trials required for the test is equal to the number of formulations (and suitable controls) under test. The formulation is randomized so that each product is applied to each hair bundle at some time point. Swallow twice with about 1 cc of shampoo composition each. Thoroughly moisten the hair bundles with 100 ° F running tap water. Approximately 1 cc of the desired shampoo composition is applied evenly from the top of the hair bundle to the bottom. Using the fingers of both hands, shampoo is rubbed into the hair for about 30 seconds to create a foam. Thoroughly rinse the hair bundle with running water at 100 ° F. The hair bundle is washed again using a second 1 cc sample of the product. The hair bundle is drip dry for 5 minutes.

The hair bundle is suspended from the test ring stand so that the hair bundle is naturally stretched and there is a clearance of several inches between the bottom of the hair bundle and the top of the bench.

b) tangle removal energy in wet state

A comb force device (CFD), a handheld electromechanical instrument that measures the amount of energy or force required to comb the hair, holds it horizontally with one hand and then moves down the CFD starting at the bottom of the hair bundle. Thus removing the tangles from the hair bundle. Each successive stroke is initiated at a point higher than the preceding stroke. This measurement continues until the CFD freely passes through the entire length of the hair bundle. Once all tangles are removed, three top to bottom strokes complete the tangle removal measurement. The energy accumulated in removing tangles of hair bundles is reported as wet tangle removal energy (g / sec).

c) combing force in wet state

After completing the tangle removal energy measurements for all hair bundles, the hair bundles are measured to determine the combing force of the wet state. Sensors attached to the curling iron measure the torsional force or twist of the hair iron as the instrument moves into the hair. The instrument passes about twenty five times of tangled hair bundles. Combing force (g) is the average force required for the comb through the entangled hair bundle.

d) tangle removal energy in dry condition

Blow dry until the hair bundle is no longer wet and then the entanglement removal procedure shown in (b) is repeated using the dry hair bundle.

e) combing power in dry condition

Blow dry until the hair bundle is no longer damp, and measure the dry tangle removal energy, and repeat the combing process shown in (c) using the dry hair bundle.

2. Eye irritation characteristics

The expected eye irritation for a given formulation is described in Intotox Protocol Number 86 (“Trans-epithelial Permeability (TEP) Assay”) as presented in Invittox Protocol Number 86 (May 1994). Therefore measure. In general, the eye stimulation potential of a particular product can be assessed by determining its effect on the permeability of the cell layer, as assessed by the leakage of fluorescein through the cell layer. Monolayers of Kidney-Darby dog kidney (MDCK) cells are grown to confluence against microporous inserts in 24-well plates containing medium or assay buffer in lower wells. The stimulation potential of a particular product is assessed by measuring damage to the permeability barrier in the cell monolayer after 15 minutes of exposure to the dilution of the product. Barrier damage is assessed by the amount of sodium fluorescein leaking through the bottom well after 30 minutes, as measured by spectrophotometer. Fluorescein leakage is plotted against the concentration of the test substance to determine the EC ₅₀ (the concentration of the test substance causing 50% of the maximum dye leakage, ie 50% damage to the permeability barrier).

Layer exposure of MDCK cells grown on microporous membranes to test samples is a model for the first event that occurs when irritation comes in contact with the eye. In vivo, the outermost layer of the comeal epithelium forms a selectively permeable barrier due to the presence of tight connections between cells. Upon exposure to the stimulant, the rigid connections are separated, thereby removing the permeability barrier. When the fluid is absorbed into the epithelium and the epidermis, the collagen lamellae separate and become opaque. TEP analysis measures the effect of stimulants on the breakage of tight connections between cells in layers of MDCK cells grown in microporous inserts. Damage is assessed using a spectrophotometer by measuring the amount of marker dye (sodium fluorescein) that leaks through the cell layer and microporous membrane into the lower wells. In general, passing scores are reflected in EC _{50 of} at least 2.2%.

Example 1 Combination of Shampoo Compositions

The following preblend is prepared.

Preblend A : 1.5 parts of PEG 6000 DS are mixed with 20 parts of deionized water at 65 ° C. in a mixing vessel until a homogeneous mixture is obtained.

Preblend B : 1.00 part of glycerin is added to a mixing container. 0.1 part of Jagua C17 is added slowly with stirring and stirring is continued for 15 minutes. 10.0 parts of water are added, 20% citric acid solution is added to adjust the pH of the blend to 4.0 and the stirring is continued for another 15 minutes.

Preblend C : 1.0 part of Atlas G-4280 is mixed with 0.25 part of fragrance.

Preblend D : 0.05 part of the Wisdom 200 blended with 0.15 part of water and the mixture is stirred until a solution is obtained.

25.75 parts of water are charged to the mixing vessel, and then 0.19 parts of polymer JR-400 is added thereto while stirring until a clean solution is obtained. 12.16 parts of Tegobetaine L7, 9.50 parts of Cedepal TD-403M, 2.85 parts of Monateric 949J and 5.5 parts of Atlas G-4280 are added in series to the solution with stirring. Preblend A maintained at a temperature of 65 ° C. is added to the solution while stirring, followed by addition of preblend C with stirring. Subsequently, 1.14 parts of tegobetaine L7 are added to this. 0.18 parts of Versene 100XL, 3.21 parts of Dye solution preblend D, 4.00 parts of Eurpean PK 3000 and 0.75 parts of DC 345 are added thereto in stirring. Citric acid solution is added in an amount to adjust the pH of the solution to 6.0. Preblend B is added while stirring. Check the pH and adjust to 6.0 using additional citric acid solution. The amount of ingredients used to make the composition of Example 1 is shown in Table 1 below.

The resulting compositions were tested for entanglement removal energy and combing force and the results are shown in Table 2 below. The irritation to the eyes of the resulting composition was measured and the data is presented in Table 3.

TABLE 1

Example 2: Combination of Shampoo Compositions Without Cyclomethicone

The procedure of Example 1 is repeated using the components shown in Table 1. The resulting compositions were tested for entanglement removal energy and combing force and the results are shown in Table 2 below.

Comparative Example 1: Combination of Shampoo Composition Without Guar Cationic Conditioner or Cyclomethicone

The procedure of Example 1 is repeated using the components shown in Table 1. The resulting compositions were tested for entanglement removal energy and combing force and the results are shown in Table 2 below.

Comparative Example 2: Combination of Shampoo Compositions Without Polyquaternium-10 or Cyclomethione

The procedure of Example 1 is repeated using the components shown in Table 1. The resulting compositions were tested for entanglement removal energy and combing force and the results are shown in Table 2 below.

TABLE 2

As indicated by the data in Table 2, the formulations of Examples 1 and 2 containing both polyquaternium-10 and guar hydroxypropyltriammonium chloride were compared to Comparative Examples 1 or 2, each of which Only one) shows a significantly improved wet state entanglement removal force (lower entanglement removal energy).

According to the previous experiments, when polyquaternium-10 is used as the sole conditioner in shampoo formulations, it is known to give the composition the manageable advantage of dry hair. Similarly, cationic guar compounds are known to confer the benefit of entanglement in the wet state. Due to the cationic nature of both of these components, when these compounds are used together, these compounds will compete for anionic sites on the hair and thus provide an improved shampoo composition with both wet and dry entanglement benefits. It was supposed to be impossible. However, the inventors have unexpectedly found that combining cationic cellulose derivatives and cationic guar derivatives in the compositions of the present invention gives the composition excellent wet and dry entanglement properties. More specifically, in the case of using the combination of the conditioner of the present invention, that is, the cationic guar derivative and polyquaternium-10, the entanglement removal energy of the wet state and the dry state uses any one of the above conditioners alone. Much lower than.

Example 1 differs from Example 2 in the presence of volatile silicones in the formulation. As can be seen from the data in Table 2, the presence of volatile silicones in Example 1 further reduces the dry tangle removal energy. Thus, it can be seen that the combination of the cationic polymer conditioner with the volatile silicone of the composition of the present invention provides both excellent wet and dry entanglement benefits.

TABLE 3

As indicated above, formulations with an average EC ₅₀ value of 2.2 or greater are believed to pass the eye irritation test, while formulations with an EC ₅₀ value of less than 2.2 are considered to have failed the test. As shown in Table 3, the formulation of Example 1 exhibits a passage value, equivalent to the use of Johnson's Baby Shampoo, a commercial shampoo known to be mild to the eye. In contrast, other commercial shampoos, such as the Pert Plus product sold by Procter & Gamble Company, failed this test.

Thus, from the above examples, it can be seen that the composition of the present invention has an excellent wet state and dry tangle removal ability while having a low irritation value for the eyes.

Examples 3-15: Preparation of Cleansing Compositions

As shown in Tables 4-7, the following preferred formulations were prepared according to the procedures described in Examples 1 and 2.

TABLE 4

TABLE 5

TABLE 6

TABLE 7

Compositions selected from Tables 4-7 are evaluated for hair and skin cleansing for human subjects, where the compositions are evaluated for their cleansing, conditioning and irritation. The selected composition is evaluated by manually cleaning and combing the hair bundles. The composition has been found to be a satisfactory conditioning personal cleansing composition.

Examples 16-54 Preparation of Cleansing Compositions

Additional compositions are prepared according to the procedures set forth in Examples 1 and 2 using the components as set forth in the following Tables 8-13.

TABLE 8

TABLE 9

TABLE 10

TABLE 11

TABLE 12

TABLE 13

Example 55 In Vitro Test

Samples of the shampoo compositions shown in Table 14 are evaluated in an in vitro test. In general, members of the test panel are provided with blind samples of each formulation in Table 14 as well as commercially available blind samples of Pert Plus ("Pert Plus") for children conditioning shampoos. These members are prescribed to use the samples independently in approximately equal amounts to shampoo and condition their hair for a period of time.

The results of the in vitro test assessed that the formulations of Examples 1 and 5 were equivalent to Pert Plus in terms of ease of conditioning of dry and wet hair. However, the formulation of Example 1 is preferred over Pert Plus for entanglement removal rate characteristics. For comparison, the formulation of Comparative Example 3 containing only a single cationic polymeric conditioner is less preferred than Pert plus in terms of these properties. These results further illustrate that the formulations of the present invention containing two or more conditioning polymers perform better than shampoos containing only a single conditioning polymer.

TABLE 14

Reference to related application

This application claims the benefit of U.S. Provisional Patent Application No. 60 / 010,784, filed Jan. 29, 1996, which is incorporated herein by reference in its entirety.

Claims (5)

Based on the total weight of the detergent personal cleansing composition, About 5 to about 20% of a surfactant portion comprising a nonionic surfactant (1), an amphoteric surfactant (2) and an anionic surfactant (3) Cationic cellulose derivatives (1), cationic guar derivatives (2) and chemical formulas Monomers of (a), wherein R is H or CH ₃ , Y is O or NH, R ₁ is an alkylene group having from about 2 to about 6 carbon atoms, and R ₂ , R ₃ and R ₄ are each independently An alkyl group or hydroxyalkyl group having about 1 to about 22 carbon atoms, X is a monovalent anion selected from halides and alkyl sulfates having about 1 to about 4 carbon atoms] and cationic monomers selected from diallyldimethylammonium chloride (b) A detergent personal cleansing composition comprising from about 0.1 to about 1.0% of a conditioner portion comprising two or more cationic conditioning polymers selected from homopolymers or copolymers (3). Conditioning detergent based on the total weight of the personal cleansing composition, Derived from a polyol selected from fatty acids having from about 8 to about 22 carbon atoms and sorbitol, sorbitan, glucose, 1-methyl glucoside, polyglucose, glycerin, pentaerythritol and mixtures thereof having an average of about 1 to about 3 glucose residues; (a) an average of about 10 to about 120 oxyethylene units, (b) an average of about 1 to about 3 fatty acid residues per molecule of polyoxyethylene derivative of the polyol ester, (c) a polyoxy of the polyol ester Ethylene Derivatives (1), nonionic surfactants comprising alkyl glucose (2) or mixtures thereof (3) having from about 6 to about 22 carbon atoms and having from about 1 to about 6 glucose residues per molecule of alkyl glucose (a) about 1 to about 10%, One or more ampocarboxylate amphoteric surfactants of formula A-CONH (CH ₂ ) _X N ⁺ R ₅ R ₆ R ₇ (b), wherein A is an alkyl group or alkenyl group having from about 7 to about 21 carbon atoms , x is an integer from about 2 to about 6, R ₅ is hydrogen or a carboxyalkyl group of about 2 or about 3 carbon atoms, R ₆ is a hydroxyalkyl group of about 2 or about 3 carbon atoms or the formula R ₈ -O- Is a group of (CH ₂ ) _n CO ₂ ^- wherein R ₈ is an alkylene group of about 2 or about 3 carbon atoms, n is 1 or 2, and R ₇ is a carboxyalkyl group of about 2 or about 3 carbon atoms About 0.5 to about 10%, Formula ^{_{BN + R 9 R 10 (CH}} 2) p CO 2 - in the alkyl beta (1) (wherein, B is from about 8 to about 22 alkyl or alkenyl group of carbon number, R ₉ and R ₁₀ are each independently And an alkyl group or a hydroxyalkyl group having about 1 to about 4 carbon atoms, p is 1 or 2) and the formula D-CO-NH- (CH ₂ ) _q -N ⁺ R ₁₁ R ₁₂ (CH ₂ ) _m CO the amido alkyl beta (2) (wherein, D is a carbon number of about 7 to an alkyl or alkenyl group of about 21, R ₁₁ and R ₁₂ are each independently having from about 1 to about 4 alkyl groups or ^- ₂ Hydroxyalkyl group, q is an integer from about 2 to about 6, m is 1 or 2) about 0.5 to about 10% of at least one betaine amphoteric surfactant (c), At least one anionic alkyl ether sulfate surfactant of formula R ′ (OCH ₂ CH ₂ ) _V OSO ₃ X ′ (d), wherein R ′ is an alkyl group or alkenyl group having from about 7 to about 22 carbon atoms, and X ′ Is an alkali metal ion, an alkaline earth metal ion, an ammonium ion, and an ammonium ion substituted by one to three substituents, wherein each substituent may be the same or different and has an alkyl group of about 1 to about 4 carbon atoms and about 2 carbon atoms To a hydroxy alkyl group from about 4 to about 4), v is an integer from 1 to 6] about 1 to about 10%, Polyquaternium-10 (e) about 0.01 to about 0.5% and Guar hydroxypropyltriammonium chloride (f) from about 0.01 to about 0.5%, wherein the surfactants of (a) to (d) are from about 5 to about 20%, based on the total weight of the detergent personal cleaning composition Conditioning detergent personal cleansing composition present in an amount of. Based on the total weight of the detergent personal cleaning composition, About 5 to about 20% of a surfactant portion comprising a nonionic surfactant (1), an amphoteric surfactant (2) and an anionic surfactant (3) Cationic cellulose derivatives (1), cationic guar derivatives (2) and chemical formulas Monomers of (a), wherein R is H or CH ₃ , Y is O or NH, R ₁ is an alkylene group having from about 2 to about 6 carbon atoms, and R ₂ , R ₃ and R ₄ are each independently An alkyl group or hydroxyalkyl group having about 1 to about 22 carbon atoms, X is a monovalent anion selected from halides and alkyl sulfates having about 1 to about 4 carbon atoms] and cationic monomers selected from diallyldimethylammonium chloride (b) A detergent personal cleansing composition comprising from about 0.01% to about 1.0% of a conditioner portion comprising at least two cationic conditioning polymers selected from homopolymers or copolymers (3). Conditioning detergent based on the total weight of the personal cleansing composition, Derived from polyol (1) and lauric acid (2) consisting of sorbitol, sorbitan and mixtures thereof, containing on average about 20 to about 80 oxyethylene units per molecule of polyoxyethylene derivative of the polyol ester, Polyoxyethylene derivatives of polyol ester nonionic surfactants having an average of about 1 to about 2 lauric acid residues per molecule of polyoxyethylene derivative of and mixtures thereof (a) about 2 to about 10%, Ampocarboxylate amphoteric surfactant of formula A-CONH (CH ₂ ) _x N ⁺ R ₅ R ₆ R ₇ , wherein A is an alkyl group of about 11 carbon atoms, x is 2, R ₅ is hydrogen, R ₆ is a group of the formula R ₈ —O— (CH ₂ ) _n CO ₂ ⁻ , wherein R ₈ is an alkylene group having 2 carbon atoms, n is 1, and R ₇ is a carboxymethyl group; and About 0.5% to about 5% of a mixture (b), The alkyl beta (1) (wherein, B is referred to us a group, R ₉ and R ₁₀ having a carbon number of 12 is a methyl group, respectively), ^- the formula ^{_{BN + R 9 R 10 CH 2}} CO 2 Formula _{DCO-NH- (CH 2) q} -N + R 11 R 12 CH 2 CO 2 - amido alkyl beta Min (2) (wherein, DCO is a fatty acid derived from coconut passage, q is 3, and , R ₁₁ and R ₁₂ are each methyl group) and About 0.5 to about 8% of a betaine surfactant (c) selected from mixtures (3) thereof, Alkyl ether sulfate anionic surfactant of the formula R '(OCH ₂ CH ₂ ) OSO ₃ X' wherein R 'is an alkyl group of about 12 or about 13 carbon atoms, X' is a sodium ion, v is 1-4 Is an integer of about 2% to about 8%) and a mixture thereof Polyquaternium-10 (e) about 0.01 to about 0.3% and Guar hydroxypropyltriammonium chloride (f) comprising about 0.01 to about 0.3%, wherein the surfactants of (a) to (d) are from about 5 to 20% based on the total weight of the detergent personal cleaning composition Conditioning detergent personal cleansing composition present in an amount. Conditioning detergent based on the total weight of the personal cleansing composition, About 2.0 to about 8% of a nonionic surfactant (1) comprising a polyoxyethylene derivative of a polyol ester, an alkyl glucoside having from about 8 to about 14 carbon atoms or a mixture thereof, Amidoalkyl steine amphoteric surfactant (2) about 1 to about 6% and About 5 to about 20% of a surfactant moiety (A) comprising about 1 to about 6% of an alkyl ether sulfate anionic surfactant (3) Cationic cellulose derivatives (1), Cationic guar derivatives (2) and Chemical formula Monomer (a) [wherein R is H or CH ₃ , Y is O or NH, R ₁ is an alkylene group having about 2 or about 3 carbon atoms, and R ₂ , R ₃ and R ₄ are each independently An alkyl group having from about 1 to about 4 carbon atoms, X is a monovalent anion selected from halides and alkyl sulfates] and a homopolymer or copolymer (3) of cationic monomers selected from diallyldimethylammonium chloride (b) A conditioning detergent personal cleansing composition comprising from about 0.01% to about 1.0% of a conditioner portion (B) comprising at least a cationic conditioning polymer.