KR100468324B1 - A POLYMER PRODUCTS FOR RECYCLING WASTE RUBBER USING γ-RAY AND A METHOD FOR THE SAME - Google Patents
A POLYMER PRODUCTS FOR RECYCLING WASTE RUBBER USING γ-RAY AND A METHOD FOR THE SAME Download PDFInfo
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- KR100468324B1 KR100468324B1 KR10-2001-0071041A KR20010071041A KR100468324B1 KR 100468324 B1 KR100468324 B1 KR 100468324B1 KR 20010071041 A KR20010071041 A KR 20010071041A KR 100468324 B1 KR100468324 B1 KR 100468324B1
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B13/00—Conditioning or physical treatment of the material to be shaped
- B29B13/08—Conditioning or physical treatment of the material to be shaped by using wave energy or particle radiation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2021/00—Use of unspecified rubbers as moulding material
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- Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
- Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
Abstract
본 발명은 분쇄된 폐타이어 분말을 포함하는 폐고무 분말을 생고무 및/또는 플라스틱 수지에 투입한 후 성형하여 고분자 제품을 얻는 폐고무 재활용 기술에 관한 것으로서, 폐타이어 또는 폐고무 분말을 생고무 및/또는 플라스틱 수지에 투입하기 전에 상기 폐고무 분말에 감마선을 조사하는 것을 특징으로 한다.The present invention relates to a waste rubber recycling technology in which a waste rubber powder including pulverized waste tire powder is put into raw rubber and / or plastic resin and then molded to obtain a polymer product, and the waste tire or waste rubber powder is made of raw rubber and / or Gamma rays are irradiated to the waste rubber powder before being added to the plastic resin.
Description
본 발명은 폐고무 또는 폐타이어 분말을 표면 개질하여 생고무(Virgin rubber) 및/또는 플라스틱 수지에 투입함으로써 고무 제품을 얻는 방법에 관한 것이다.The present invention relates to a method of obtaining a rubber product by surface-modifying waste rubber or waste tire powder and injecting it into virgin rubber and / or plastic resin.
최근 자동차 산업의 발달로 인한 폐타이어의 발생량이 급격하게 늘어남으로써, 이에 따른 폐타이어의 처리 문제가 사회적으로 대두되고 있다. 일반적으로, 이러한 폐타이어는 소각되거나 매립되는데, 이로 인한 환경 문제가 갈수록 심각해지고 있다.Recently, the amount of waste tires rapidly increased due to the development of the automotive industry, the problem of disposal of waste tires has emerged socially. In general, these waste tires are incinerated or landfilled, and environmental problems are becoming more serious as a result.
이러한 문제를 해결하기 위해, 버려지는 폐타이어를 재활용하기 위한 시도가 다각도로 진행되고 있다. 그 중 폐고무 또는 폐타이어를 분쇄해 분쇄된 분말을 생고무 및/또는 플라스틱 수지에 다시 혼합하는 방법이 연구되어 왔는데, 좋은 품질의 고무 제품을 만들어 내기 위하여는 폐고무 분말의 표면 개질이 선행되어야 한다.In order to solve this problem, attempts are being made at various angles to recycle used tires. Among them, a method of pulverizing waste rubber or waste tire and mixing the crushed powder again with raw rubber and / or plastic resin has been studied. In order to produce good quality rubber products, surface modification of waste rubber powder must be preceded. .
이러한 표면 개질 방법 중, 유기 용매에 의한 화학 처리법과 코로나 또는 플라즈마 조사를 통한 폐고무 분말의 표면 개질 방법이 제시되었다.Among these surface modification methods, a chemical treatment method using an organic solvent and a surface modification method of waste rubber powder through corona or plasma irradiation have been proposed.
하지만, 상기 방법들로 개질된 폐고무 분말을 다른 시료와 혼합하는 경우, 그 혼합도가 매우 저하되어 재생된 제품의 물성 저하 및 표면 불량의 문제점이 있었다.However, when the waste rubber powder modified by the above methods is mixed with other samples, the mixing degree is very low, thereby deteriorating physical properties and surface defects of the recycled product.
따라서, 본 발명의 목적은 폐타이어 분말을 생고무 및/또는 플라스틱 수지와 혼합하여 고분자 제품을 제조할 때, 제조되는 고분자 제품의 물성을 크게 저하시키지 않으면서도 폐타이어 및/또는 폐고무 분말과 다른 원료와의 성형성을 증가시키도록 표면 개질하는 폐고무 재생 방법을 제공하는 것이다.Accordingly, an object of the present invention is to produce a polymer product by mixing waste tire powder with raw rubber and / or plastic resin, and thus, waste tire and / or waste rubber powder and other raw materials without significantly reducing the physical properties of the polymer product to be produced. It is to provide a waste rubber recycling method of surface modification to increase the moldability of the.
도 1은 감마선이 조사되지 않은 폐타이어 분말의 표면을 나타내는 현미경 사진.1 is a micrograph showing the surface of waste tire powder not irradiated with gamma rays.
도 2는 2M의 감마선이 조사된 폐타이어 분말의 표면을 나타내는 현미경 사진.Figure 2 is a micrograph showing the surface of the waste tire powder irradiated with 2M gamma rays.
도 3은 4M의 감마선이 조사된 폐타이어 분말의 표면을 나타내는 현미경 사진.Figure 3 is a micrograph showing the surface of the waste tire powder irradiated with 4M gamma rays.
도 4는 6M의 감마선이 조사된 폐타이어 분말의 표면을 나타내는 현미경 사진.Figure 4 is a micrograph showing the surface of the waste tire powder irradiated with gamma rays of 6M.
상기 본 발명의 목적을 달성하기 위해, 본 발명은 분쇄된 폐고무 분말에 감마선을 조사하는 것을 특징으로 하는 폐고무 재생 방법을 제공한다.In order to achieve the above object of the present invention, the present invention provides a waste rubber regeneration method characterized in that the gamma ray is irradiated to the pulverized waste rubber powder.
즉, 본 발명에 따른 폐고무 재생 방법은 수십mm ~ 수십㎛ 입도 크기로 분쇄한 후, 상기 분쇄된 폐고무 분말을 감마선 처리함으로써 상기 폐고무 분말 분자를 표면 개질하고, 이렇게 표면 개질된 폐고무 분말을 생고무 또는 플라스틱 수지에 혼합하여 새로운 고분자 제품으로 재활용하는 것을 특징으로 한다.That is, according to the waste rubber regeneration method according to the present invention, after the pulverized to a particle size of several tens of mm to several tens of micrometers, the waste rubber powder molecules are surface-modified by gamma ray treatment of the pulverized waste rubber powder, and thus the surface-modified waste rubber powder To be mixed with raw rubber or plastic resin, characterized in that to recycle into a new polymer product.
본 발명에서는 종래의 방법과 차원을 달리한 방법인 감마선 처리로 S-S 결합(S-S bond) 및 C-S(C-S bond)결합을 끊고 탈황시켜, 가교된 기존 재료의 문제점인 성형성을 향상시키고, 물리적 물성과 외관에서도 거의 동일한 고무 제품의 제조를 가능하게 한다.In the present invention, the SS bond and the CS bond are desulfurized and desulfurized by gamma ray treatment, which is a method different from the conventional method, to improve moldability, which is a problem of crosslinked conventional materials, and to improve physical properties. It is possible to produce almost identical rubber products in appearance.
<실시예><Example>
감마선 처리효과를 알아보기 위해, 160℃, 130atm의 조건에서, 파일럿 스케일(pilot scale)로 폐타이어 분말을 압축성형하고 재가황시켜 시편을 제조한 후, 상기 시편에 대해 물성을 측정하여, 그 측정 결과를 표 1에 정리하였다.In order to examine the effects of gamma ray treatment, at 160 ° C and 130 atm, waste tire powder was compressed and revulcanized on a pilot scale to prepare a specimen, and then the physical properties of the specimen were measured and measured. The results are summarized in Table 1.
감마선 처리된 폐타이어 분말은 20분 동안 압축 성형 가공하였을 경우, 미처리된 폐타이어 분말이 30분 압축성형 가공되었을 경우보다 물성은 약간 떨어짐을 나타내었으나, 미처리 분말을 혼합할 때보다 성형시간이 단축됨을 나타내어 경제성이 좋음을 알 수 있다.When the gamma ray-treated waste tire powder was subjected to compression molding for 20 minutes, the physical properties of the untreated waste tire powder were slightly lower than that of 30 minutes compression molding. It can be seen that the economy is good.
감마선 처리된 폐타이어 분말의 물성이 약간 떨어지는 이유는 감마선이 강력하여 황과 황, 탄소와 황의 결합뿐만 아니라 탄소와 탄소 사이의 결합을 끊기 때문이다.The reason why the properties of the gamma ray-treated waste tire powder are slightly lower is that the gamma ray is strong and breaks the bond between carbon and carbon as well as sulfur and sulfur, carbon and sulfur.
표 1을 참조하면, 감마선 처리에 의해 폐타이어의 물성이 크게 떨어지지 않음을 알 수 있다. 따라서, 감마선 처리는 폐타이어가 다른 고무 원료와 쉽게 성형되는 것을 가능하게 하면서도 물성이 크게 변하지 않는다는 것을 알 수 있다.Referring to Table 1, it can be seen that the physical properties of the waste tire are not significantly reduced by gamma ray treatment. Accordingly, it can be seen that the gamma ray treatment enables the waste tire to be easily molded with other rubber raw materials, but does not significantly change its physical properties.
도 1은 감마선이 조사되지 않은 폐타이어 분말의 표면을 나타내는 현미경 사진이고, 도 2 내지 도 4는 2 Mev, 4 Mev 및 6Mev의 감마선이 조사된 폐타이어 분말의 표면을 나타내는 현미경 사진이다.1 is a micrograph showing the surface of the waste tire powder irradiated with gamma rays, Figures 2 to 4 are micrographs showing the surface of the waste tire powder irradiated with gamma rays of 2 Mev, 4 Mev and 6Mev.
도 1 내지 도 4로 알 수 있는 바와 같이, 감마선이 조사되지 않은 폐타이어 분말 표면은 매끄럽지만, 감마선 처리를 2 Mev, 4 Mev 및 6Mev으로 증가할수록 표면의 거칠기(roughness)가 증가하는 것을 확인할 수 있다.As can be seen from Figures 1 to 4, the surface of the waste tire powder irradiated with gamma rays is smooth, but as the gamma ray treatment is increased to 2 Mev, 4 Mev and 6Mev, the surface roughness increases. have.
단, 6 Mev에서 물성이 특히 떨어지는 이유는 감마선이 강력하여 황과 황, 탄소와 황의 결합뿐만 아니라 탄소와 탄소 사이의 결합을 끊기 때문이며, 도 4의 사진에서도 폐타이어 표면이 도 2 및 도 3의 양상과 다름을 알 수 있다.However, the reason why the physical properties are particularly poor at 6 Mev is that the gamma ray is strong and breaks the bond between carbon and carbon as well as sulfur and sulfur and carbon and sulfur bonds. It is different from the aspect.
이를 기준으로 폐타이어 분말을 표면 개질하여 폐타이어 재활용품을 제조하면, 성형시간을 40분에서 20분으로 줄일 때, 감마선 처리에서는 약 12% 정도의 생산비가 절감이 된다.Based on this, if waste tire powder is surface-modified to manufacture waste tire recycled products, when the molding time is reduced from 40 minutes to 20 minutes, the production cost is reduced by about 12% in gamma ray treatment.
상술한 바와 같이, 본 발명은 폐고무 재생 방법에 있어서, 분쇄된 폐고무 분말에 감마선을 조사하여 표면 개질함으로써, 폐고무의 물성을 크게 변화시키지 않으면서도 생고무 및/또는 플라스틱 수지와의 성형성을 증가시키며, 그 결과 재생 폐타이어의 효율을 높이는 효과를 갖는다.As described above, the present invention is a waste rubber regeneration method, by irradiating gamma-rays to the surface of the pulverized waste rubber powder surface modification, the formability with the raw rubber and / or plastic resin without significantly changing the physical properties of the waste rubber This increases the efficiency of the recycled waste tires.
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| KR10-2001-0071041A KR100468324B1 (en) | 2001-11-15 | 2001-11-15 | A POLYMER PRODUCTS FOR RECYCLING WASTE RUBBER USING γ-RAY AND A METHOD FOR THE SAME |
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| KR10-2001-0071041A KR100468324B1 (en) | 2001-11-15 | 2001-11-15 | A POLYMER PRODUCTS FOR RECYCLING WASTE RUBBER USING γ-RAY AND A METHOD FOR THE SAME |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101772010B1 (en) * | 2017-02-22 | 2017-08-29 | 삼성의료고무주식회사 | Method for production of the reclaimed rubber with electron beam and the reclaimed rubber therefrom |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20030084427A (en) * | 2002-04-26 | 2003-11-01 | 김진국 | The manufacture of shoe outsole using NR and waste tire powder |
| CA2874248C (en) | 2012-05-30 | 2017-02-28 | Bridgestone Bandag, Llc | Tire tread and method of making the same |
| GB2560768B (en) * | 2017-03-24 | 2022-02-09 | Acell Ind Ltd | Method of shaping a cured thermosetting resin |
| KR102228463B1 (en) * | 2020-10-26 | 2021-03-15 | 금오공과대학교 산학협력단 | Plastic aggregate modified by Gamma rays irradiation |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR890001716A (en) * | 1987-07-22 | 1989-03-28 | 모또야마 가즈오 | Rubber product manufacturing method |
| JPH01193325A (en) * | 1988-01-28 | 1989-08-03 | Japan Atom Energy Res Inst | Method for accelerating vulcanization of natural rubber latex with radiation |
| JPH09104762A (en) * | 1995-10-12 | 1997-04-22 | Japan Atom Energy Res Inst | Production of easily decomposable polypropylene |
| KR20020074643A (en) * | 2001-03-21 | 2002-10-04 | 엘지전선 주식회사 | High damping polymer composites for reducing impact sound and method thereof |
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Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR890001716A (en) * | 1987-07-22 | 1989-03-28 | 모또야마 가즈오 | Rubber product manufacturing method |
| JPH01193325A (en) * | 1988-01-28 | 1989-08-03 | Japan Atom Energy Res Inst | Method for accelerating vulcanization of natural rubber latex with radiation |
| JPH09104762A (en) * | 1995-10-12 | 1997-04-22 | Japan Atom Energy Res Inst | Production of easily decomposable polypropylene |
| KR20020074643A (en) * | 2001-03-21 | 2002-10-04 | 엘지전선 주식회사 | High damping polymer composites for reducing impact sound and method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101772010B1 (en) * | 2017-02-22 | 2017-08-29 | 삼성의료고무주식회사 | Method for production of the reclaimed rubber with electron beam and the reclaimed rubber therefrom |
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