KR100444844B1 - Electrolytic polishing utilization radioactive contamination meatal type clear system - Google Patents

Electrolytic polishing utilization radioactive contamination meatal type clear system Download PDF

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KR100444844B1
KR100444844B1 KR10-2001-0030274A KR20010030274A KR100444844B1 KR 100444844 B1 KR100444844 B1 KR 100444844B1 KR 20010030274 A KR20010030274 A KR 20010030274A KR 100444844 B1 KR100444844 B1 KR 100444844B1
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decontamination
electrolytic polishing
radioactive
electropolishing
filter
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KR10-2001-0030274A
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KR20010070696A (en
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김장회
정원무
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대한원자력산업 주식회사
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    • GPHYSICS
    • G21NUCLEAR PHYSICS; NUCLEAR ENGINEERING
    • G21FPROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULAR RADIATION OR PARTICLE BOMBARDMENT; TREATING RADIOACTIVELY CONTAMINATED MATERIAL; DECONTAMINATION ARRANGEMENTS THEREFOR
    • G21F9/00Treating radioactively contaminated material; Decontamination arrangements therefor
    • G21F9/001Decontamination of contaminated objects, apparatus, clothes, food; Preventing contamination thereof
    • G21F9/005Decontamination of the surface of objects by ablation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D46/00Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
    • B01D46/0084Filters or filtering processes specially modified for separating dispersed particles from gases or vapours provided with safety means
    • B01D46/0091Including arrangements for environmental or personal protection
    • B01D46/0094Including arrangements for environmental or personal protection against radiation

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  • Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Food Science & Technology (AREA)
  • Physics & Mathematics (AREA)
  • General Engineering & Computer Science (AREA)
  • High Energy & Nuclear Physics (AREA)
  • Environmental & Geological Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Monitoring And Testing Of Nuclear Reactors (AREA)

Abstract

본 발명은 방사성 물질에 의해 표면이 오염된 금속성 방사성 폐기물로부터 방사성 물질을 제거하는 장치로서, 전해연마 공정을 통하여 금속의 표면을 미세하게 벗겨내어 금속표면에 고착화 된 방사성 오염물질을 대상 금속으로부터 제거하여 재활용 할 수 있도록 하거나, 일반폐기물로 처리되도록 하여 원자력발전소 등에서 발생하는 금속물질의 방사성 폐기물의 양을 줄이고, 종래 수세에 의한 제염(방사능 오염제거)시 수반되는 제염작업자의 방사선 피폭을 방지 또는 최대한 억제시키는 장치이다.The present invention is a device for removing radioactive material from the metal radioactive waste contaminated by the radioactive material, finely peel off the surface of the metal through the electropolishing process to remove the radioactive contaminants fixed on the metal surface from the target metal It can be recycled or treated as general waste to reduce the amount of radioactive waste of metals generated from nuclear power plants and to prevent or maximize the radiation exposure of decontamination workers involved in decontamination (radioactive decontamination) by conventional water washing. Device.

이를 위하여 스테인레스 계통의 합금강과 탄소강 계통의 합금강을 선택적으로 제염할 수 있는 2개의 전해연마조 및 1개의 수세로 이루어진 작업대와 전해연마를 이용한 제염 중 발생되는 기체상, 액체상 방사성 폐기물을 처리할 수 있는 기체, 액체방사성 폐기물 정화장치, 그리고 전해연마를 위한 전원공급장치, 이들 장치들을 집적화하고 방사성폐기물에서 방출되는 방사선으로부터 작업자의 피폭을 방지하기 위한 납유리로 이루어진 창이 부착된 후드가 본 발명 장치를 구성하였다.To this end, it is possible to treat gaseous and liquid radioactive wastes generated during decontamination using a work bench consisting of two electrolytic polishing tanks and one flush and the electropolishing, which can selectively decontaminate stainless steel alloy steel and carbon steel alloy steel. Gas, liquid radioactive waste purifiers, and power supplies for electropolishing, hoods with windows made of lead glass for integrating these devices and preventing worker exposure from radiation emitted from radioactive waste constitute the device of the present invention. .

Description

전해연마를 이용한 방사능 오염 금속류 오염 제거장치{ELECTROLYTIC POLISHING UTILIZATION RADIOACTIVE CONTAMINATION MEATAL TYPE CLEAR SYSTEM}ELECTROLYTIC POLISHING UTILIZATION RADIOACTIVE CONTAMINATION MEATAL TYPE CLEAR SYSTEM}

본 발명은 원자력발전소에서 발생하는 금속성 방사성 폐기물의 제염(방사능 오염제거)에 의한 연마공법을 적용하여 금속성 방사성폐기물로부터 방사성물질을 제거하여 제염하는 장치에 관한 것이다.The present invention relates to an apparatus for removing and decontaminating radioactive material from metallic radioactive waste by applying a polishing method by decontamination (radioactive decontamination) of metallic radioactive waste generated in a nuclear power plant.

일반적으로 원자력발전소에서의 금속성 방사선 오염물질의 처리는 지금까지 초음파 세척에 의하거나 브러시나 수세미 등을 통한 수세에 의한 제염에 의존하고 있는 실정이다.그러나, 이러한 제염방법으로는 금속성 방사성 폐기물 표면에 존재하는 유리성 오염물질만 제거가 가능할 뿐이고, 고착성 오염일 경우에는 마무런 효과를 기대할 수 없을 뿐만 아니라, 제염 대상물이 복잡한 형상일 경우에는 제염자체를 포기하고 있는 실정이다. 또한 수세에 의한 제염시에는 방사성 오염물질을 제염작업자가 직접 손으로 취급하기 때문에 제염에 따른 방사선 피폭도 수반되고 있는 것이다.In general, the treatment of metallic radiation pollutants in nuclear power plants has been relied on by decontamination by ultrasonic cleaning or by washing with a brush or scrubbing brush. However, these decontamination methods exist on the surface of metallic radioactive waste. It is only possible to remove the free contaminants, and in the case of sticking contamination, it is not possible to expect a smooth effect, and when the decontamination object has a complicated shape, the decontamination itself is abandoned. In addition, radiation decontamination is accompanied by decontamination because decontamination workers directly handle radioactive contaminants during decontamination by washing with water.

본 발명에 따른 장치는 종래의 문제점을 해결하기 위한 것으로서, 본 발명의 목적은 금속성 방사능 오염물질의 제염에 전해연마 공법을 적용하여 완전 제염의 효과를 얻고, 전해연마 제염시 발생하는 액체, 기체 방사성 폐기물의 처리 문제를 해결한 전해연마를 이용한 방사능 오염 금속류 오염 제거장치를 제공하는 데 있다.The device according to the present invention is to solve the conventional problems, the object of the present invention is to apply the electropolishing method to the decontamination of the metallic radioactive contaminants to obtain the effect of complete decontamination, liquid, gas radioactive generated during electrolytic decontamination It is to provide a radioactive contamination metals decontamination apparatus using electropolishing that solves the problem of waste disposal.

도 1은 본 발명에 따른 개념도이고,1 is a conceptual diagram according to the present invention,

도 2는 본 발명에 따른 조립단면도이다.2 is an assembled cross-sectional view according to the present invention.

<도면의 주요부분에 대한 부호의 설명><Description of the symbols for the main parts of the drawings>

1 : 후드 2 : 제 1전해연마조1: hood 2: first electrolytic polishing

3 : 제 2전해연마조 4 : 수세조3: second electrolytic polishing bath 4: water washing tank

5 : 순환펌프 6 : 가열 및 냉각장치5: circulation pump 6: heating and cooling device

7 : 소결금속필터 8 : 이온교환수지 탱크7: sintered metal filter 8: ion exchange resin tank

9 : 기체방사성폐기물 여과장치 9a : 전치필터9: gas radioactive waste filtration device 9a: pre-filter

9b : 활성탄필터 9c : 코트렐정화장치9b: activated carbon filter 9c: Cottrell Purifier

상기한 바와 같은 목적을 달성하기 위한 본 발명은, 방사능에 오염된 스테인레스 합금강 계열의 금속과 탄소강 계열의 금속을 선택적으로 제염할 수 있는 2개의 전해연마조 및 제염된 금속의 수세를 위한 1개의 수세조가 일렬로 형성된 작업대와, 작업대 하부에 전해연마 제염에 필요한 전해액을 공급, 회수하는 장치, 전해액의 온도를 조절하는 가열 및 냉각장치, 전해액의 증발로 인한 냄새와 기체 방사성폐기물의 처리를 위한 여과장치와 이온교환수지탱크, 전해액의 증발로 인한 냄새와 기체방사성 폐기물의 처리를 위한 여과장치를 후드에 집적화하고 전해연마시 후드에 설치된 납유리로 된 창을 닫음으로써 제염작업자의 방사선 피폭을 줄일 수 있는 것이 본 발명의 특징이다.The present invention for achieving the object as described above, two electrolytic polishing baths capable of selectively decontamination of radioactively contaminated metals and carbon steel-based metals and one water for washing the decontaminated metals A work table in which three tanks are lined up, a device for supplying and recovering an electrolyte solution for electrolytic polishing decontamination at the bottom of the work table, a heating and cooling device for controlling the temperature of the electrolyte solution, and a filtration for treating odor and gaseous radioactive waste due to evaporation of the electrolyte solution. Radiation exposure of decontamination workers can be reduced by integrating the device, ion exchange resin tank, and filtration device for the treatment of odor and gaseous radioactive waste due to evaporation of electrolyte in the hood and closing the lead glass window installed in the hood during electrolytic polishing. It is a feature of the present invention.

이하, 본 발명에 따른 실시예를 첨부된 도면을 참조로 상세히 설명하면 다음과 같다.Hereinafter, embodiments of the present invention will be described in detail with reference to the accompanying drawings.

도 1은 본 발명에 따른 개념도이고, 도 2는 본 발명에 따른 조립단면도이다. 도 1 및 도 2에 도시된 바와 같이, 후드(1) 내부 작업대 위에 스테인레스 합금강의 제염을 위한 제 1전해연마조(2)와 탄소강류의 제염을 위한 제 2전해연마조(3) 및 수세를 위한 수세조(4)가 일렬로 구비되고, 그 하부에는 전해액을 순환시키기 위한 순환펌프(5)와, 전해액의 전해조건을 맞추기 위한 가열 및 냉각장치(6)가 각각 구비된다.1 is a conceptual diagram according to the present invention, Figure 2 is an assembled cross-sectional view according to the present invention. As shown in FIGS. 1 and 2, a first electrolytic polishing bath 2 for decontamination of stainless alloy steel and a second electrolytic polishing bath 3 for decontamination of carbon steels and flushing on a work bench inside the hood 1 are mounted. A washing tank 4 is provided in a row, and a lower portion thereof includes a circulation pump 5 for circulating the electrolyte and a heating and cooling device 6 for matching the electrolyte conditions of the electrolyte.

그리고, 제 1,2전해연마조(2)(3)와 순환펌프(5) 사이에는 전해액의 회수(폐기)시 전해액 중의 방사능 오염물질을 제거하기 위한 소결금속필터(7) 및 이온교환수지탱크(8)가 각각 구비된다.한편, 후드(1) 상부에는 기체 방사성 표기물의 처리와 냄새를 제거하기 위한 기체방사성폐기물 여과장치(9)가 일체로 구비되고 후드(1) 주변에는 전해연마 제염을 위한 전원공급장치(미도시)가 구비되어 본 발명을 구성하게 된다.본 발명의 전해연마 제염 작업을 위한 후드(1)의 창을 열게 되면, 전원공급장치(미도시)는 완전히 오프상태로 전환되고, 방사능오염 금속을 양극(+)판 겸용의 이송장치의 걸쇠에 장착한 후 금속의 종류에 따라 제 1전해연마조(2)와 제 2전해연마조(3)를 선택한 다음, 전해연마 대상 금속을 전해연마조에 삽입하게 된다.그 다음으로 후드(1)의 창을 내리면 전원공급장치는 준비단계(Stand-by)로 전환되고, 후드(1) 전면의 표시창에 '준비중'의 메시지가 표시되고, 금속의 종류와 크기에 따른 고유의 전해연마 시간과 전압, 전류조건을 전압조절기, 전류조절기, 타이머를 통하여 설정할 수 있는 상태가 된다.이와 같이 모든 조건을 설정한 후 전원스위치를 온하면 후드(1) 전면 표시창에 '작업중'이라는 메세지가 표시됨과 동시에 전해연마 제염이 실시된다.이때, 전해액은 적절한 전해 조건을 갖추기 위해 가열장치(6)에 의해 가열되는 데 이 가열로 인한 전해액의 증발시 기화성 방사성 물질의 증발로 동시에 이루어지는 바, 이때의 증기(Fume)를 포함한 기체는 후드(1) 상부의 여과장치(9)를 통하여 정화되어 송풍기(Blower)에 의해 배출구로 배출된다.이러한 기체 방사성폐기물 여과장치(9)는 전치필터(Pre-Filter)(9a)와 활성탄필터(Activity Charcoal Filter)(9b), 코트렐정화장치(Cottrell Precipitator)(9c)로 구성된다.In addition, between the first and second electrolytic polishing tanks (2) (3) and the circulation pump (5), a sintered metal filter (7) and an ion exchange resin tank for removing radioactive contaminants in the electrolyte during recovery (disposal) of the electrolyte (8) are provided respectively. On the other hand, the upper part of the hood (1) is integrally provided with a gaseous radioactive waste filtration device (9) for the treatment of gaseous radioactive labeling and odor removal, and electrolytic polishing decontamination around the hood (1). A power supply device (not shown) is provided to constitute the present invention. When the window of the hood 1 for the electropolishing decontamination work of the present invention is opened, the power supply device (not shown) is completely switched off. After attaching the radioactive polluted metal to the clasp of the positive electrode (+) plate transfer device, the first electrolytic polishing bath (2) and the second electrolytic polishing bath (3) were selected according to the type of metal, and then the electropolishing target The metal is inserted into the electrolytic polishing bath. Next, the window of the hood 1 is Then, the power supply is switched to stand-by, the message 'Ready' is displayed on the display window on the front of the hood (1), and the unique electrolytic polishing time, voltage and current condition according to the type and size of metal. The voltage controller, current regulator, and timer can be set.When all the conditions are set, the power switch is turned on.The message 'working' is displayed on the front display window of the hood, and electrolytic polishing decontamination At this time, the electrolyte solution is heated by the heating device 6 so as to have appropriate electrolytic conditions, and at the same time by evaporation of the vaporizable radioactive material upon evaporation of the electrolyte solution due to this heating, the gas containing the vapor (Fume) at this time The gas is purified through a filtration device 9 above the hood 1 and discharged to a discharge port by a blower. The gaseous radioactive waste filtration device 9 is a pre-filter 9a. Consists of an activated carbon filter (Activity Charcoal Filter) (9b), Cottrell purifier (Cottrell Precipitator) (9c).

이때, 전자필터(Pre-Filter)(9a)는 활성탄필터(Activity Charcoal Filter)(9b)를 보호하기 위함이고, 활성탄필터(Activity Charcoal Filter)(8b)는 전해액의 증발시 발생하는 냄새와 1-125 등의 방사선 핵종의 오염물 제염시 발생하는 기체방사선폐기물을 흡착하고, 최종적으로 코트렐정화장치(Cottrell Precipitator)(9c)는 1,2차 여과장치를 통과한 오염된 미립자(Particle)와 잔여 오염기체를 정화하는 기능을 하게 된다.At this time, the pre-filter (9a) is to protect the activity charcoal filter (Activity Charcoal Filter) (9b), the activity charcoal filter (Activity Charcoal filter) (8b) is a smell and 1- Adsorb gaseous radioactive waste generated when decontamination of radionuclides such as 125, and finally, the Cottrell Precipitator (9c) is contaminated particles and residual contaminants passed through the first and second filtration devices. It will function to purify.

초기 가열장치에 의해 가열된 전해액은 전해연마가 진행됨에 따라 더욱 가열되는 바, 적절한 전해조건을 맞추기 위해 전해액을 냉각시킬 필요가 있으며, 각 전해연마조(2,3)에 구비된 온도센서(미도시)에 의해 검출된 온도가 적정온도 이상일 경우에는 냉각장치(6)에 의해 전해액은 적정온도로 유지되고, 전해액 순환펌프(5)에 의해 전해조로 다시 공급되어져 전해염 효과를 증대시키게 된다.The electrolyte heated by the initial heating device is further heated as the electropolishing progresses, so it is necessary to cool the electrolyte in order to meet the appropriate electrolytic conditions, and the temperature sensor (not shown) provided in each electrolytic polishing bath 2,3 When the temperature detected by c) is equal to or higher than the proper temperature, the electrolyte is maintained at the proper temperature by the cooling device 6, and is supplied back to the electrolytic cell by the electrolyte circulation pump 5 to increase the electrolytic salt effect.

전해연마제염 작업의 반복으로 인한 전해액 성분의 조성비율 변화와 방사능오염물질의 전해액 중 누적으로 인해 전해액의 폐기시에는 작업대 하부에 구비된 액체 방사성 폐기물처리장치는 방사성에 오염된 전해액을 소결금속필터(7)를 통하여 큰 입상의 방사성물질을 여과하고, 소결금속필터(7)를 통과한 전해액은 양이온 교환수지와 음이온 교환수지가 동시에 충전된 이온교환수지탱크(8)에서 이온 교환반응을 통해 전해액 중 방사능 물질을 제거하는 기능을 하게 된다.When disposing of the electrolyte due to the change in the composition ratio of the electrolyte components and the accumulation of radioactive pollutants due to the repeated electrolytic polishing salt operation, the liquid radioactive waste treatment device provided at the lower part of the work bench is used to filter the radioactively contaminated electrolyte solution into a sintered metal filter ( 7) The large granular radioactive material was filtered through the sintered metal filter (7), and the electrolyte was passed through the ion exchange reaction in the ion exchange resin tank (8) filled with the cation exchange resin and the anion exchange resin at the same time. It will function to remove radioactive material.

정해진 조건으로 전해 연마 제염이 완료되면, 부저를 통해 제염작업자에게 알림과 동시에 표시창에 '완료'를 표시하게 된다.When the electrolytic polishing decontamination is completed under the predetermined conditions, the decontamination worker is notified through the buzzer and 'complete' is displayed on the display window.

한편, 전해연마 제염이 완료된 금속의 방사능 오염물질은 수세조(4)에서 수세를 통하여 표면의 오염된 전해액을 제거하게 되고, 방사능 오염 측정에 의한 제염 완료여부를 결정하게 된다.On the other hand, the radioactive contaminants of the electropolishing decontamination is completed to remove the contaminated electrolyte solution on the surface through the water washing in the washing tank (4), it is determined whether the decontamination by radioactive contamination measurement.

이상과 같이 전해연마 제염장치는 전해연마 제염에 수반되는 문제점인 기체, 액체 방사성 폐기물의 처리를 해결하여 전해연마 공법을 방사성 폐기물 제염에 적용함으로써 금속의 방사능 오염물질을 완전히 제염 처리할 수 있게 하였다.As described above, the electropolishing decontamination apparatus solves the problem of gas and liquid radioactive waste, which is a problem associated with electrolytic polishing decontamination, and thus electrolytic polishing method is applied to radioactive waste decontamination to completely decontaminate radioactive contaminants of metals.

금속의 방사성 폐기물 완전제염은 금속성 방사성폐기물의 감량으로 인한 방사성폐기물의 저장보관과 관리에 따르는 비용의 절감 효과가와 원자력발전소에서 사용되는 특수합금 재료의 재생 및 재활용의 이득을 얻을 수 있다.Complete decontamination of radioactive waste of metals can reduce the costs associated with the storage and management of radioactive wastes due to the reduction of metallic radioactive wastes, and can also benefit from the regeneration and recycling of special alloy materials used in nuclear power plants.

원자력발전소별 자체 폐기물 저장고의 포화와 함께 원자력발전소의 노후화로 인한 기기, 탱크, 배관류 등의 교체와 해체가 더욱 증가하고 있고, 국내 최초상업운전을 개시한 고리원자력 발전소 1호기의 운전종료 예정 시점이 얼마 남지 않았고, 연구용원자로(Triga 2)의 해체가 2001년부터 시작되므로 금속성 방사성 폐기물 처리에 관한 기술의 확보가 시급한 단계에 있다고 볼 수 있어, 본 발명에 의한 전해 연마공법을 이용한 금속성 방사성폐기물 제염장치는 상기의 측면에서 적절한 효과를 갖는 것이다.With the saturation of its own waste storage facility for each nuclear power plant, the replacement and dismantling of equipment, tanks, pipes, etc., due to the aging of the nuclear power plant is increasing, and the operation time of the first Kori Nuclear Power Plant, which started its first commercial operation, is scheduled to end. Since the shortage of the research reactor (Triga 2) began in 2001, securing the technology for the treatment of metallic radioactive waste can be seen as an urgent step, and decontamination of metallic radioactive waste using the electrolytic polishing method according to the present invention. The device has an appropriate effect in view of the above.

Claims (3)

후드(1) 내부의 작업대 위에 구비되고, 스테인레스 계통의 합금강과 탄소강 계통의 합금강을 선택적으로 제염할 수 있는 제 1전해연마조(2) 및 제 2전해연마조(3);A first electrolytic polishing bath (2) and a second electrolytic polishing bath (3), which are provided on a work table inside the hood (1) and are capable of selectively decontaminating an alloy steel of a stainless steel system and an alloy steel of a carbon steel system; 상기 제 2전해연마조(3) 일측에 구비되어 상기 제 1전해연마조(2) 및 상기 제 2전해연마조(3)에서 제염된 제염대상물을 수세할 수 있는 수세조(4);A washing tank (4) provided at one side of the second electrolytic polishing bath (3) to wash the decontamination object decontaminated in the first electrolytic polishing bath (2) and the second electrolytic polishing bath (3); 상기 작업대 하부에 구비되어 전해액을 가열 및 냉각하여 적정온도로 유지시켜 전해조건을 맞추기 위한 가열 및 냉각장치(6); 및A heating and cooling device (6) provided at a lower portion of the work table to maintain an appropriate temperature by heating and cooling the electrolyte solution; And 상기 작업대 하부에 구비되어 상기 전해액을 상기 제 1,2전해연마조(2)(3)로 순환시키기 위한 순환펌프(5);A circulation pump 5 provided below the work table to circulate the electrolyte into the first and second electrolytic polishing baths (2) and (3); 로 구성된 것을 특징으로 하는 전해연마를 이용한 방사능 오염 금속류 오염 제거장치.Radioactive contamination metals decontamination apparatus using electrolytic polishing, characterized in that consisting of. 제 1항에 있어서, 상기 제 1,2전해연마조(2)(3)와 상기 순환펌프(5) 사이에는 상기 제염과정에서 생성된 슬러지를 여과할 수 있는 소결금속필터(7)와 이온교환수지탱크(8)가 구비된 것을 특징으로 하는 전해 연마를 이용한 방사능 오염 금속류 오염 제거장치.The sintered metal filter (7) and ion exchange between the first and second electrolytic polishing baths (2) and (3) and the circulation pump (5) which can filter sludge produced during the decontamination process. Radioactive contamination metals decontamination apparatus using electropolishing, characterized in that the resin tank (8) is provided. 제 1항에 있어서, 상기 후드(1) 상부에는 상기 제염과정에서 발생하는 전해액의 증발 기체와 오염물질의 기화로 인한 기체를 여과하여 처리할 수 있는 전치필터(9a), 활성탄필터(9b) 및 코트렐정화장치(9c)로 이루어진 기체방사선폐기물 제거장치(9)가 더 구비된 것을 특징으로 하는 전해 연마를 이용한 방사능 오염 금속류 오염 제거장치.2. The pre-filter 9a, the activated carbon filter 9b, and the upper portion of the hood 1, which can filter and treat the evaporated gas of the electrolyte generated during the decontamination process and the gas due to the vaporization of contaminants. The apparatus for removing radioactive contamination metals using electropolishing is characterized by further comprising a gaseous radiation waste removing device (9) comprising a coatel purifier (9c).
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