KR100425796B1 - Manufacture Method of Stone Textured Clay by Addition Jeju Scoria - Google Patents

Manufacture Method of Stone Textured Clay by Addition Jeju Scoria Download PDF

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KR100425796B1
KR100425796B1 KR10-2001-0023494A KR20010023494A KR100425796B1 KR 100425796 B1 KR100425796 B1 KR 100425796B1 KR 20010023494 A KR20010023494 A KR 20010023494A KR 100425796 B1 KR100425796 B1 KR 100425796B1
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volcanic rock
jeju
rock material
mixed
mixing ratio
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KR10-2001-0023494A
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Korean (ko)
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KR20020083834A (en
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정인수
허민자
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정인수
허민자
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    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00—Clay-wares
    • C04B33/02—Preparing or treating the raw materials individually or as batches
    • C04B33/13—Compounding ingredients
    • C04B33/132—Waste materials; Refuse; Residues
    • C04B33/135—Combustion residues, e.g. fly ash, incineration waste
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00—Clay-wares
    • C04B33/02—Preparing or treating the raw materials individually or as batches
    • C04B33/04—Clay; Kaolin
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B20/00—Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
    • C04B20/02—Treatment
    • C04B20/026—Comminuting, e.g. by grinding or breaking; Defibrillating fibres other than asbestos
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
    • C04B2103/0068—Ingredients with a function or property not provided for elsewhere in C04B2103/00
    • C04B2103/0097—Anion- and far-infrared-emitting materials
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00948—Uses not provided for elsewhere in C04B2111/00 for the fabrication of containers
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00965—Uses not provided for elsewhere in C04B2111/00 for household applications, e.g. use of materials as cooking ware

Abstract

본 발명은 제주 화산암재가 첨가된 배합소지의 제조방법에 관한 것으로, 그 제조공정은 화산암재를 80目 ~ 100目으로 분쇄하고 체가름하는 1공정(2)과; 상기 1공정(2)을 거친 화산암재를 청자소지나 내열점토와 같은 기존의 점토에 10%, 20%, 30%, 40%, 50%, 60%, 70%, 80%의 혼합비율로 혼합시키는 2공정(4)으로; 이루어짐을 특징으로 하는 것으로, 일정 입도와 일정 혼합비율로 제주 화산암재가 혼합되어 된 배합소지로 제주의 독특한 질감을 갖는 민속 토산품이나 주방용품들을 제작하여 고부가가치의 제품을 제작할 수 있고 건축자재를 제작시공함으로써 제주 건축의 향토성과 지역성을 제고할 수 있으며, 또한 화산암재가 다량의 철분과 염기성 물질을 포함하고 있어서 유약을 시유하지 않아도 자연미를 갖게 돼 무유의 제품을 생산할 수 있어 청정산업으로 발전시킬 수 있는 유용한 효과가 제공되는 것이다.The present invention relates to a method for manufacturing a blended body with added Jeju volcanic rock material, the manufacturing process is one step (2) of pulverizing and sifting the volcanic rock material to 80 目 ~ 100 目; The volcanic rock material, which has undergone the first step (2), is mixed with existing clays such as celadon porcelain or heat-resistant clay at a mixing ratio of 10%, 20%, 30%, 40%, 50%, 60%, 70%, and 80%. In step 2 (4) to make; It is characterized by the fact that it is a compounded material mixed with Jeju volcanic rock material at a certain granularity and a certain mixing ratio to produce high value-added products by producing folk souvenirs or kitchen utensils with Jeju's unique texture and manufacturing construction materials. By improving the locality and locality of Jeju's architecture, volcanic rocks contain a large amount of iron and basic substances, and they have natural beauty without glazing. The effect is provided.

Description

제주 화산암재가 첨가된 배합소지의 제조방법 { Manufacture Method of Stone Textured Clay by Addition Jeju Scoria }Manufacture Method of Stone Textured Clay by Addition Jeju Scoria}

본 발명은 제주 화산암재가 첨가된 배합소지의 제조방법에 관한 것으로, 더욱 상세하게는 80 ~ 100目의 입도로 분쇄된 제주산 화산암재(송이, scoria)를 청자소지나 내열점토와 같은 기존의 점토에 10 ~ 80% 혼합하여 된 배합소지를 제공할 수 있는 제주 화산암재가 첨가된 배합소지의 제조방법에 관한 것이다.The present invention relates to a method for manufacturing a blended body added with Jeju volcanic rock material, more specifically, Jeju mountain volcanic rock material (Song, scoria) pulverized to a particle size of 80 ~ 100 grains, such as celadon porcelain or heat-resistant clay The present invention relates to a method for preparing a compounded body, wherein Jeju volcanic rock material is added, which can provide a compounded body mixed with 10 to 80%.

일반적으로 제주 화산암재(scoria)는 화산이 폭발할 때 급속히 기포를 발생하며 용암이 잘게 부수어진 다공질의 암재로서 유기불순물의 함량이 적고 철분이 다량 함유되어 있어 상기 철분의 혼합비에 따라 아이보리색상에서 어두운 갈색에이르기까지 다양한 색상 표현이 가능하고 흡습, 흡취, 원적외선 방사의 기능이 있는 것이다.In general, Jeju volcanic rock (scoria) is a porous rock material that generates bubbles rapidly when a volcano erupts, and has a low content of organic impurities and a large amount of iron. It is possible to express various colors up to brown color, and it has the function of moisture absorption, absorption, and far infrared radiation.

또한 화학적 성분이 일정하고 고른 입도분포를 보이며 중량이 가볍고 다공질이어서 점토에 혼합하였을 때 공기의 유통을 좋게하고 평균내화도는 1160℃ 로 보고 되고 있다.In addition, the chemical composition is uniform, the particle size distribution is uniform, the weight is light and porous, and when mixed with clay, it improves the air circulation and the average fire resistance is reported to be 1160 ℃.

특히 상기 제주 화산암재는 마모율이 높아 분쇄가 용이하고 일단 구워진 재료로써 소지의 휨이나 균열을 방지시킬 수 있음으로 이를 기존의 소지에 혼합함으로써 제주의 독특한 미감을 갖는 다양한 색상의 배합소지를 개발할 수 있는 것이다.In particular, the volcanic rock material of Jeju is easy to be crushed due to high abrasion rate and can be prevented from bending or cracking of the material as it is once baked. .

본 발명은 색상이 다양하지 못하고 안료나 산화물 첨가시 자연미를 도출시키기 어려운 종래 점토의 문제점을 해소하기 위한 것으로, 상기 종래 점토에 일정 입도를 갖는 제주 화산암재를 일정한 혼합비율로 혼합함으로써 자연석의 느낌을 주며 그로그(grog)의 역할을 하여 소지의 휨이나 균열을 방지시킬 수 있고 소성온도를 낮춰 생산비를 절감시키고, 저렴한 비용으로 원적외선 방사 용기나 건축자재를 생산할 수 있도록 한 제주 화산암재가 첨가된 배합소지를 제공하는 데 그 목적이 있다.The present invention is to solve the problem of the conventional clay is difficult to derive natural beauty when the color is not varied and the addition of pigments and oxides, by mixing the Jeju volcanic rock material having a certain particle size in the conventional clay at a constant mixing ratio to feel the feeling of natural stone Jeju volcanic rock is added to prevent the warpage or crack of the body by reducing the firing temperature, reduce the production cost, and to produce far-infrared radiation container or building materials at low cost. The purpose is to provide.

도 1은 본 발명에 따른 제주 화산암재가 첨가된 배합소지의 제조공정을 보여주는 흐름도1 is a flow chart showing the manufacturing process of the blended body is added Jeju volcanic rock material according to the present invention

* 도면의 주요 부분에 대한 부호의 설명 *Explanation of symbols on the main parts of the drawings

2 : 1공정 4 : 2공정2: 1 step 4: 2 step

상기한 본 발명에 따른 제주 화산암재가 첨가된 배합소지의 제조방법(1)은 화산암재를 80目 ~ 100目으로 분쇄하고 체가름하는 1공정(2)과; 상기 1공정(2)을 거친 화산암재를 청자소지나 내열점토와 같은 기존의 점토에 10%, 20%, 30%, 40%, 50%, 60%, 70%, 80%의 혼합비율로 혼합시키는 2공정(4)으로; 이루어짐을 특징으로 하는 것이다.The manufacturing method of the blended body (1) added to Jeju volcanic rock material according to the present invention described above is one step (2) of pulverizing the volcanic rock material to 80 目 ~ 100 目 and sift; The volcanic rock material, which has undergone the first step (2), is mixed with existing clays such as celadon porcelain or heat-resistant clay at a mixing ratio of 10%, 20%, 30%, 40%, 50%, 60%, 70%, and 80%. In step 2 (4) to make; It is characterized by consisting of.

이때, 10 ~ 50%의 혼합비율로 화산암재가 혼합된 배합소지는 1200℃ 소성용이며, 60 ~ 80%의 혼합비율로 화산암재가 혼합된 배합소지는 1150℃ 소성용이다.At this time, the blended material mixed with volcanic rock material at a mixing ratio of 10 to 50% is for firing at 1200 ° C., and the blended material mixed with volcanic rock material at a mixing ratio of 60 to 80% is for firing at 1150 ° C.

이하 본 발명의 바른 실시예를 첨부된 도면을 토대로 상세히 설명하면 다음과 같다.Hereinafter, a preferred embodiment of the present invention will be described in detail with reference to the accompanying drawings.

도 1은 본 발명에 따른 제주 화산암재가 첨가된 배합소지의 제조공정을 보여주는 흐름도이다.1 is a flow chart showing a manufacturing process of the blended body is added Jeju volcanic rock material according to the present invention.

도 1에 도시된 바와 같이, 본 발명에 따른 제주 화산암재가 첨가된 배합소지의 제조방법(1)은 화산암재를 80目 ~ 100目으로 분쇄하고 체가름하는 1공정(2)과; 상기 1공정(2)을 거친 화산암재를 청자소지나 내열점토와 같은 기존의 점토에 10%, 20%, 30%, 40%, 50%, 60%, 70%, 80%의 혼합비율로 혼합시키는 2공정(4)으로; 이루어짐을 특징으로 하는 것이다.As shown in Figure 1, the manufacturing method (1) of the composite body added with Jeju volcanic rock material according to the present invention is one step (2) of grinding and sieving the volcanic rock material to 80 目 ~ 100 目; The volcanic rock material, which has undergone the first step (2), is mixed with existing clays such as celadon porcelain or heat-resistant clay at a mixing ratio of 10%, 20%, 30%, 40%, 50%, 60%, 70%, and 80%. In step 2 (4) to make; It is characterized by consisting of.

이때, 상기 화산암재의 혼합비율에 따라 배합소지의 소성 후 색상이 변하게 되는 것이다.At this time, the color changes after firing of the blended material according to the mixing ratio of the volcanic rock material.

상기 혼합비율에 따른 배합소지의 소성후 색상의 실시예는 다음과 같다.Examples of the color after firing of the blended body according to the mixing ratio are as follows.

실시예1. 화산암재가 10% 혼합된 배합소지 : 아이보리 색상의 사암(砂巖)의 느낌Example 1 10% mixed volcanic rock material: Ivory sandstone

실시예2. 화산암재가 20% 혼합된 배합소지 : 짙은 아이보리 색상의 사암(砂巖)의 느낌Example 2. 20% mixed volcanic rock material: dark ivory sandstone

실시예3. 화산암재가 30% 혼합된 배합소지 : 옅은 갈색의 화산암의 느낌Example 3. 30% mixed volcanic rock material: pale brown volcanic rock

실시예4. 화산암재가 40% 혼합된 배합소지 : 짙은 갈색의 현무암의 느낌Example 4. 40% mixed volcanic rock material: dark brown basalt

실시예5. 화산암재가 50% 혼합된 배합소지 : 검은색의 현무암의 느낌Example 5. 50% mixed volcanic rock material: black basalt

또한, 화산암재 첨가량의 50%를 200目, 50%를 100目으로 혼합할 경우 암석의 질감이 강하게 도출되며, 첨가량의 30%를 80目, 30%를 100目, 40%를 150目으로 혼합하면 더욱 거친 암석의 느낌이 도출된다.In addition, when 50% of volcanic rock is added to 200 items and 50% to 100 items, the texture of the rock is strongly derived, and 30% of the amount added is 80 items, 30% is 100 items, and 40% is 150 items. This results in a rougher rock feel.

본 발명에 따른 제주 화산암재가 첨가된 배합소지로 9 5× 95 ×10(㎜), 100× 100 ×13(㎜)의 시편을 제작하고 1200℃ 로 소성한 결과 타일이나 기물로써 충분한 꺽임 강도(80이상)를 가진다.Jeju Island volcanic rock material added according to the present invention prepared 9 5 × 95 × 10 (㎜), 100 × 100 × 13 (㎜) specimens and baked at 1200 ℃ resulted in sufficient bending strength (80) Above)

또한 본 발명에 따른 제주 화산암재가 첨가된 배합소지의 건조 수축율은 5% ~ 6%, 소성수축율은 5% ~ 6.5%로써 기존 소지의 건조 수축률 8% ~ 10%, 소성수축율 8% ~ 10%보다 현저히 적음으로써 건조나 소성시 소지의 휨현상이 방지되는 것이다.In addition, the dry shrinkage of 5% to 6%, the plastic shrinkage of 5% to 6.5% of the blended base material added to Jeju volcanic rock material according to the present invention than the dry shrinkage of 8% ~ 10%, plastic shrinkage of 8% ~ 10% Significantly less, the bending of the body during drying or firing is prevented.

이하, 표 1은 화산암재(scoria)의 색상에 따른 화학적 성분의 비교를 보여주는 것이고, 표 2는 KICM 한국건자재 시험연구원 시험 성적서이며, 표 3은 시편의 꺽임강도에 대한 시험결과를 보여주는 것이다.Hereinafter, Table 1 shows a comparison of the chemical composition according to the color of the scoria, Table 2 is a test report of KICM Korea Building Materials Testing Institute, Table 3 shows the test results for the bending strength of the specimen.

표 1. 화산암재(scoria)의 색상에 따른 화학적 성분의 비교Table 1. Comparison of Chemical Compositions by Colors of Scoria

CompsampCompsamp SiO2 SiO 2 Al2O3 Al 2 O 3 Fe2O3 Fe 2 O 3 TiO2 TiO 2 CaOCaO MgOMgO Na2O+ K2ONa 2 O + K 2 O 마모율(%)Wear rate (%) 단위무게 (g/㎤)Unit weight (g / cm 3) 절대건조비중Absolute Dry Weight 온도(℃)Temperature (℃) sample Asample A 45.4045.40 16.8716.87 14.9214.92 3.973.97 6.956.95 6.136.13 4.064.06 57.8257.82 0.690.69 1.701.70 11411141 sampleBsampleB 46.2246.22 16.2616.26 11.6611.66 2.352.35 8.098.09 7.917.91 4.284.28 47.2547.25 0.680.68 1.801.80 11201120

표 2는 KICM 한국건자재 시험연구원 시험 성적서Table 2 shows KICM Korea Construction Materials Testing Institute test report

시료명Sample Name 방사율(5 ~ 20㎛)Emissivity (5 ~ 20㎛) 방사에너지(W/㎡·㎛,40 ℃ )Radiation energy (W / ㎡ · ㎛, 40 ℃) 화산암재(송이)Volcanic Rock Ash 0.920.92 3.70 ×102 3.70 × 10 2

표 3은 시편의 꺽임강도에 대한 시험결과Table 3 shows the test results for the bending strength of the specimen.

시 편Psalm 화산암재 첨가량Volcanic Rock Addition 시편의 두께 (㎝)Specimen Thickness (cm) 시험편의 폭 (㎝)Width of test piece (cm) 파괴하중(㎏f)Breaking load (㎏f) 꺽임강도(㎏f/㎠)Bending strength (㎏f / ㎠) 1-11-1 10%10% 1.01.0 9.59.5 84.084.0 100.77100.77 1-21-2 1.31.3 10.010.0 148.2148.2 102.08102.08 2-12-1 20%20% 1.01.0 9.59.5 125.4125.4 150.44150.44 2-22-2 1.31.3 10.010.0 115.4115.4 92.1892.18 3-13-1 30%30% 1.01.0 9.59.5 142.2142.2 167.00167.00 3-23-2 1.31.3 10.010.0 178.6178.6 142.67142.67 4-14-1 40%40% 1.01.0 9.59.5 113.0113.0 135.56135.56 4-24-2 1.31.3 10.010.0 189.8189.8 151.62151.62 5-15-1 50%50% 1.01.0 9.59.5 100.8100.8 146.32146.32 5-25-2 1.31.3 10.010.0 157.0157.0 125.41125.41

이상에서 설명한 바와 같이, 본 발명에 의한 일정 입도와 일정 혼합비율로 제주 화산암재가 혼합되어 된 배합소지로 제주의 독특한 질감을 갖는 민속 토산품이나 주방용품들을 제작하여 고부가가치의 제품을 제작할 수 있고 건축자재를 제작시공함으로써 제주 건축의 향토성과 지역성을 제고할 수 있으며, 또한 화산암재가 다량의 철분과 염기성 물질을 포함하고 있어서 유약을 시유하지 않아도 자연미를 갖게 돼 무유의 제품을 생산할 수 있어 청정산업으로 발전시킬 수 있는 유용한 효과가 제공되는 것이다.As described above, Jeju volcanic rock material is mixed at a certain granularity and constant mixing ratio according to the present invention to produce folk souvenirs or kitchen utensils having a unique texture of Jeju, and to produce high value-added products. It can improve the locality and locality of Jeju's architecture by making and constructing it.In addition, volcanic rock material contains a large amount of iron and basic materials, so it has natural beauty without applying glaze, so it can produce non-oil-free products and develop it into a clean industry. A useful effect can be provided.

Claims (1)

원적외선 방사 용기나 건축자재를 생산할 수 있도록 한 청자소지나 내열점토에 있어서;In celadon or heat-resistant clays capable of producing far-infrared radiation containers or building materials; 제주산 화산암재를 80目 ~ 200目의 입도로 분쇄하고 체가름하는 1공정(2)과; 상기 1공정(2)을 거친 화산암재를 상기 청자소지나 내열점토와 같은 기존의 점토에 10% ~ 80%의 혼합비율로 첨가하여 혼합시키는 2공정(4)으로; 이루어짐을 특징으로 하는 제주 화산암재가 첨가된 배합소지의 제조방법.1 step (2) of crushing and sieving Jeju volcanic rock to a grain size of 80 to 200 grains; A two-step (4) of adding the volcanic rock material that passed through the first step (2) to an existing clay such as celadon porcelain or heat-resistant clay at a mixing ratio of 10% to 80%; Jeju volcanic rock material is characterized in that the production method of the compound added.
KR10-2001-0023494A 2001-04-30 2001-04-30 Manufacture Method of Stone Textured Clay by Addition Jeju Scoria KR100425796B1 (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100673791B1 (en) 2005-05-17 2007-01-24 김영수 Ceramic Composition with Scoria
KR101706776B1 (en) * 2015-12-08 2017-02-15 주식회사 아일랜드 Fabrication of scoria coffee cup

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20040016755A (en) * 2002-08-19 2004-02-25 최명부 The magative ion antibvacterial yellow soit paints
KR100688874B1 (en) * 2005-05-09 2007-03-02 김영수 Glaze Prepared with Scoria, and Method of Preparing and Using Same

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100673791B1 (en) 2005-05-17 2007-01-24 김영수 Ceramic Composition with Scoria
KR101706776B1 (en) * 2015-12-08 2017-02-15 주식회사 아일랜드 Fabrication of scoria coffee cup

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