KR100398025B1 - Dry manufacturing method for polyurethane gloves coated by water soluble polyurethane - Google Patents

Dry manufacturing method for polyurethane gloves coated by water soluble polyurethane Download PDF

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KR100398025B1
KR100398025B1 KR20010044223A KR20010044223A KR100398025B1 KR 100398025 B1 KR100398025 B1 KR 100398025B1 KR 20010044223 A KR20010044223 A KR 20010044223A KR 20010044223 A KR20010044223 A KR 20010044223A KR 100398025 B1 KR100398025 B1 KR 100398025B1
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parts
weight
water
polyurethane
gloves
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KR20010044223A
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KR20030009667A (en )
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변홍식
김기목
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변홍식
김기목
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PURPOSE: A process for preparing polyurethane gloves is provided to prevent the generation of waster water, to reduce production time, and to obtain various properties including water/moisture penetration and water-proof property, anti-sliding property and discoloration resistance by coating the water soluble polyurethane resin the gloves. CONSTITUTION: The process comprises (M101) mixing 100 parts by weight of water-soluble polyurethane, 50-60 parts by weight of water, 10-150 parts by weight of MEK and 50-100 parts by weight of toner to form a coating composition; (M102) coating a pair of gloves with the prepared composition; then (M103,M104) conducting a first and a second drying processes. The first drying process is carried out at 40-60deg.C for 10-30 minutes while the second drying process is performed at 100-150deg.C for 20-40 minutes. The composition may comprise 50-100 parts of emulsifying agent, 50-100 parts by weight of solvent, 10-50 parts by weight of toner and 10-50 parts by weight of HP-2000.

Description

수용성 폴리우레탄이 코팅된 폴리우레탄 장갑의 건식 제조방법{Dry manufacturing method for polyurethane gloves coated by water soluble polyurethane} The dry method of producing a waterborne polyurethane coated polyurethane gloves {Dry manufacturing method for polyurethane gloves coated by water soluble polyurethane}

본 발명은 산업용, 또는 농업용 및 가정용으로 널리 사용되고 있는 폴리우레탄 장갑의 제조에 있어서 산업폐수의 발생을 방지하고, 또한 장갑의 표면에 미세한 기공과 거친표면을 형성할 수 있는 수용성 폴리우레탄이 코팅된 폴리우레탄 장갑의 건식 제조방법에 관한 것이다. The present invention is industrial use, or in the manufacture of polyurethane gloves which are widely used in agricultural, domestic and preventing generation of industrial waste water, and further a water-soluble polyurethane that is capable of forming fine pores and a rough surface on the surface of the gloves coated with poly It relates to a dry production method of polyurethane gloves.

일반적으로, 폴리우레탄 장갑은 내구성과 우수한 착용감으로 산업용과 가정용으로 널리 활용되고 있는 장갑이다. In general, polyurethane glove is a glove that is widely used in industrial and household durable and a good fit. 이러한 장갑을 제조하는 방법으로 종래의 방법은 습식폴리우레탄 제조방법이 있다. Conventional methods as a way of making such gloves is the method of producing liquid polyurethane.

그러나, 종래의 습식 제조방법은 폴리우레탄수지에 유화제와 표백용토너를 혼합한 용액에 폴리에틸렌사로 제조된 장갑을 함침하여 코팅함으로써 제조된다. However, conventional wet production method is produced by coating polyethylene was impregnated with the prepared gloves captured in a mixed solution of an emulsifier and a bleach toner for the polyurethane resin. 이때 코팅된 장갑은 약 10 o C 이하의 냉각수에 15분, 그리고 온수(50-60 o C)에 15분 함침하여 용제의 제거작업 및 폴리우레탄의 고형화작업을 진행하게 된다. The coated glove by 15 minutes impregnation for 15 minutes up to about 10 o C water, and hot water (50-60 o C) to proceed to solidification operation of removal of the solvent action and polyurethane.

이와 같이 종래의 습식폴리우레탄 장갑의 제조방식은 고형화작업을 피할 수 없게 되고, 따라서 폐수의 발생으로 인한 환경오염을 유발하게 되는 단점이 있다. Thus, manufacturing method of the conventional wet polyurethane gloves are inevitable action for solidification, and therefore has the disadvantage that it causes environmental pollution due to the generation of waste water.

이러한 단점을 개선하고자 또 다른 습식폴리우레탄 장갑의 제조방법이 개발되었다. To improve this disadvantage is also another method for producing a liquid polyurethane gloves have been developed. 국내특허 293055호(출원번호:1998-031815 출원일:1998년 08월 03일), "습식폴리우레탄 장갑 및 그 제조방법"이 환경오염을 방지하기 위하여 개발된 제조방식이나, 이 방법도 냉각수와 온수를 이용한 폴리우레탄의 고형화 작업이 포함되므로 환경폐수의 발생이 필연적임을 알 수 있다. Korean Patent No. 293055 (Patent Application No. 1998-031815 filed Aug. 03, 1998), the manufacturing method developed for the "wet polyurethane gloves and a manufacturing method thereof" is to prevent environmental pollution and this method is also cooling and hot water because the operation includes the solidification of the polyurethane using it can be seen that the generation of environmental waste water necessarily. 종래의 단점을 개선하기 위하여 개발된 이러한 방법도 발포촉진 유화제(상품명: s-153) 130-150 중량%에 폴리우레탄 수지(100중량%), 항변제를 교반시킨 용액을 코팅하여 장갑을 제조한 뒤 냉각수에 15분, 온수에 15분 함침하여 발포촉진유화제를 제거시킴으로 환경폐수가 발생한다는 것을 명확히 알 수 있다. The development of such a method to improve the conventional drawbacks also promote foaming emulsifier (trade name: s-153) 130-150 by coating a solution obtained by stirring the polyurethane resin (100% by weight), to protest the% by weight to prepare a glove 15 minutes after the cooling water, sikimeuro by 15 minutes impregnation with warm water to remove the emulsifier to promote the foaming can be clearly seen that the environmental wastewater. 또한 습식폴리우레탄 제조방법으로 제조될 경우 미세한 기공이 형성된다고 하였으나, 실제 습식폴리우레탄 제조방법으로 제조되어 시판되고 있는 장갑의 확대사진을 볼 경우 미세한 기공은 확인되지 않았다(fig 1참조). In addition, when prepared by a wet production method, but that the polyurethane fine pores formed, in the case see enlarged version of the actual liquid poly gloves in the market is made of a method for producing polyurethane fine pores was observed (see fig 1). 다만 표면의 매끄러움으로 인하여 장갑의 미끄럼 방지가 현저히 떨어질 것으로 예상되었다. However, due to the smoothness of the surface was expected to significantly reduce the slip of the gloves.

<fig 1> <Fig 1>

이와같이, 종래의 폴리우레탄 제조방법과 이의 단점을 개선하기 위하여 개발된 습식폴리우레탄 제조방법은 폐수발생이 필연적이며, 공정이 복잡하고, 고형화 및 용제 제거작업으로 인하여 제조시간이 길어지는 문제점이 있다. In this way, the conventional polyurethane production process and method of manufacturing the development in order to improve its disadvantages liquid polyurethane has a problem that the manufacturing time increases due to an inevitably waste water generated, the process is complex, and solidifying and removing the solvent action.

본 발명은 상기와 같은 문제점을 해결하기 위해 안출한 것으로서, 산업용, 또는 농업용 및 가정용으로 널리 사용되고 있는 폴리우레탄 장갑의 제조에 있어서 종래의 습식방법을 지양하고 건식방법을 발명함으로써 산업폐수가 발생하지 않으며, 장갑의 표면에 미세한 기공(pore)을 주어 투습성과 통기성을 우수하게 하고, 거친표면을 형성하여 미끄럼방지가 현저히 좋아지도록 한 수용성 폴리우레탄이 코팅된 폴리우레탄 장갑의 건식 제조방법을 제공하는데 그 목적이 있다. The present invention is one made in view the above problems, avoiding the conventional wet method in the manufacture of industrial, or agricultural and polyurethane gloves are widely used for home use and does not have industrial wastewater generated by invention the drying method , given a pore (pore) minute to the surface of the glove and the excellent moisture permeability and air permeability, by forming a rough surface to provide a dry production method of the waterborne polyurethane which such that slip is remarkably like coating of polyurethane gloves that purpose there is.

상기 목적은 본 발명에 따라, 폐수발생을 방지하기 위하여 냉수와 온수에 함침하는 공정을 삭제할 필요가 있으며, 이 경우 수용성 폴리우레탄을 이용하면 가능하다는 것을 다년간의 연구 끝에 개발하게 되었다. The above object has been developed that in accordance with the present invention, in order to prevent the waste water generated it is necessary to delete the step of impregnating the cold and hot water, and in this case can, using the aqueous polyurethane at the end of many years of research. 그러나 건식공정에서는 수용성폴리우레탄의 고형화 및 용제의 제거작업이 냉수와 온수를 사용하지 않고 열로써 건조하므로 이때 온도의 선택은 최종 장갑의 물성과 표면구조에 상당한 영향이 있음을 알게 되었다. However, because the dry process is removal of the solvent and solidification of the aqueous polyurethane as a heat drying operation without using the cold and hot water temperature is selected at this time has been found that there is a significant effect on the physical properties and the surface structure of the final glove. 또한 수용성 폴리우레탄의 농도는 최종장갑의 미세한 기공의 크기에도 영향이 있다는 것을 다년간의 연구결과로 밝혀졌다. Also been found that the concentration of the water-soluble polyurethane is that the effect on the size of the fine pores of the final glove with many years of study. 따라서 본 발명의 기술적 과제는 산업용, 또는 농업용 및 가정용으로 널리 사용되고 있는 폴리우레탄 장갑의 제조에 있어서 종래의 습식방법을 지양하고 건식방법을 발명함으로써 산업폐수를 발생하지 않으며, 장갑의 표면에 미세한 기공을 주어 투습성과 통기성을 우수하게 하고, 표면을 거칠게 형성하여 미끄럼방지가 현저히 좋아지도록 건식공정을 개발하는 데에 있다. Therefore, object of the present invention is avoiding the conventional wet method in the manufacture of industrial, or agricultural and polyurethane gloves are widely used for home use and do not cause the industrial waste water by invention the drying method, the fine pores on the surface of the glove It was given and the excellent moisture permeability and air permeability, to form a rough surface so that slip is remarkably like it to develop a dry process. 상기와 같은 목적을 달성하기 위하여 수용성 폴리우레탄 수지 100 중량%에 소량의 물과 용제(Methylethylketone, MEK)를 혼합하여 용액을 제조한 후 폴리에틸렌사 또는 그 외의 섬유로 제조된 장갑을 함침하면 폴리우레탄이 코팅된 장갑이 일차 제조된다. If then a mixture of a small amount of water and solvent (Methylethylketone, MEK) to 100 wt% water-soluble polyurethane resin in order to accomplish the above object, the production of solutions impregnating a glove made of a polyethylene yarn or another fiber is a polyurethane the coated gloves are made primary. 코팅된 장갑은 40-60 o C의 건조실에서 약 10-30분 정도 건조시키면 용제가 증발되고 우레탄 도막이 형성된다. The coated gloves are the solvent is evaporated and the polyurethane coating film formation when drying for about 10-30 minutes at 40-60 o C in a drying chamber. 이때 우레탄 도막은 막힌 기공을 형성하여 거칠은 표면을 제공하게 된다. The urethane coating film to form a blocked pore roughness will provide the surface. 그 다음 2차 건조실(100-150 o C)에서 약 20-40분 정도 건조되면 장갑에 남아있던 물과 1차 건조에서 남아있던 용제가 함께 증발하면서 미세한 기공(열린기공)을 장갑의 표면에 발생시키게 된다. Then the secondary drying chamber (100-150 o C) in the generation of about 20-40 minutes when dried and the solvent remaining in the water and primary drying was left to evaporate gloves with fine pores (open pores) in the surface of the glove thereby. 이때 MEK와 물의 량(또는 수용성 폴리우레탄의 농도) 및 건조시간에 따라 미세한 기공의 크기차이를 조절할 수 있는 것이 본 발명의 특징이며, 습식폴리우레탄 제조공법과 달리냉수와 온수공정을 제거하여 공정이 간편하고, 제조시간도 단축되는 효과도 있다. The MEK and water amounts are characterized in the present invention, which (or the concentration of the water-soluble polyurethane) and can adjust the size difference between the fine pores according to the drying time, the process to remove the cold and hot water process, unlike the manufacturing process liquid polyurethane It has an effect that is simple, and also shortening the production time. 특히 폐수는 전혀 발생하지 않으면서 종래의 장갑과 동일한 물성을 보여주며(표 1참조), 표면의 구조에서는 열린기공과 거친 표면(닫힌 기공, 그림 2참조)을 동시에 갖고 있는 독특한 구조로써 종래의 장갑보다 더 우수한 구조를 가질 수 있다는 장점이 있다. In particular, the waste water without any occurrence shows a prior art gloves the same physical properties (see Table 1), the structure of the surface open porosity and rough surface (closed pores, see figure 2) at the same time, the conventional glove as a unique structure, with It has the advantage of being able to have a better structure than.

fig 2 fig 2

도 1은 본 발명인 수용성 폴리우레탄이 코팅된 폴리우레탄 장갑의 건식 제조방법에 관한 공정도이다. Figure 1 is a process diagram about the method of manufacturing the dry polyurethane gloves of the present inventors the waterborne polyurethane coating.

이하, 첨부한 도면을 참조하여 본 발명인 수용성 폴리우레탄이 코팅된 폴리우레탄 장갑의 건식 제조방법에 관해 좀더 상세하게 설명하면 다음과 같다. Hereinafter, more detailed description about the method of manufacturing the dry-the present inventors with reference to the accompanying drawings, the waterborne polyurethane coating polyurethane gloves as follows.

본 발명의 수용성 폴리우레탄이 코팅된 폴리우레탄 장갑의 건식 제조방법에 따르면 수용성폴리우레탄 수지와 물, 그리고 수용성 용제(MEK)의 혼합액(M101)에 폴리에틸렌사, 또는 그 외의 섬유로 직조된 장갑을 함침하여 코팅(M102)한 후 건조실에서 건조(M103,M104)시키면 거칠은 표면과 미세한 기공을 동시에 형성하는 장갑이 제조되게 된다. According to the dry method of manufacturing a waterborne polyurethane coated polyurethane gloves of the present invention the water-soluble polyurethane resin and water, and a mixed solution (M101) of the water-soluble solvent (MEK) impregnating a woven glove of a polyethylene yarn or other fiber and if after coating (M102) dried in the drying chamber (M103, M104) is a rough surface and the glove to form the fine pores at the same time is to be prepared. 이때 수용성폴리우레탄의 농도(물과 MEK의 중량)의 조절로써 도막의 미세한 기공구조를 조절할 수 있으며, 건조실에서의 온도와 시간의 조절로써 거친 표면의 구조를 발생시킬 수 있다. The waterborne polyurethane can adjust the fine pore structure of the coating film, and by adjustment of the concentration (by weight of water and MEK), and may cause the structure of the rough surface as the adjustment of temperature and time in the drying chamber. 상기와 같은 건식 제조방법은 냉수와 온수 공정이 제거되어 폐수발생이 없으며, 공정의 간단화로 인하여 제조시간이 절약되고, 따라서 장갑의 제조단가도 저감시키는 장점이 있다. Dry method as described above is removed the chilled water and the hot water there is no process wastewater, the manufacturing time is saved due to easy furnace of the process, and therefore has the advantage of also reducing the manufacturing cost of the glove. 본 발명의 실시예는 다음과 같다. Embodiment of the present invention is as follows.

[실시예 1] 100중량%의 수용성폴리우레탄 수지에 50-60중량%의 물과 100-200중량%의 MEK, 50-100중량%의 토너(Toner)를 혼합하여 교반시킨 다음 직조된 장갑을 손 모양의 금형에 끼운 후 디핑(Deeping)처리하여 코팅한 다음 40-60 o C의 건조실에서 10-30분 1차 건조시키면 용제가 증발하면서 도막이 거칠은 표면으로 형성된다. [Example 1] Next woven glove was stirred a mixture of a toner (Toner) of MEK, 50-100% by weight of 50-60% by weight of water and 100-200% by weight of the aqueous polyurethane resin of 100% by weight If after inserting a hand-shaped dipping mold (Deeping) treatment by coating, and then dried o 40-60 10-30 minutes in from the drying chamber of the coating film C, while the solvent is evaporated rough it is formed on the surface. 그 다음 100-150 o C의 건조실에서 20-40분 동안 2차 건조시키면 물과 남아있던 용제가 함께 증발하면서 도막에 미세한 기공이 형성되게 된다. When the next secondary drying 100-150 o for 20-40 minutes in a drying chamber of C is to be the fine pores in the coating film evaporates with the solvent remaining with the water formed. 이 과정을 거치면 투습성과 통기성이 있으며 방수성이 있는 폴리우레탄 장갑이 제조되게 된다. Geochimyeon this process, the water vapor permeability and air permeability, and is a polyurethane gloves with a waterproof be prepared.

[실시예 2] 100중량%의 수용성폴리우레탄 수지에 50-100중량%의 유화제와 100-200중량%의 MEK, 50-100중량%의 토너(Toner), 10-50중량%의 HP-2000을 혼합하여 교반시킨 다음 직조된 장갑을 손 모양의 금형에 끼운 후 디핑(Deeping)처리하여 코팅한 다음 40-60 o C의 건조실에서 10-30분 1차 건조시키면 용제가 증발하면서 도막이 거칠은 표면으로 형성된다. Example 2 Toner (Toner) of MEK, 50 to 100% by weight of 50 to 100% by weight of emulsifier and 100-200% by weight of the aqueous polyurethane resin of 100% by weight, of 10-50% by weight of HP-2000 the mixture was stirred and then after a woven glove fitted in a hand-shaped dipping mold (Deeping) when treated by coating, and then dried o 40-60 10-30 minutes in from the drying chamber of the coating film C, while the solvent is evaporated rough surface It is formed. 그 다음 100-150 o C의 건조실에서 20-40분 동안 2차건조시키면 물과 남아있던 용제가 함께 증발하면서 도막에 미세한 기공이 형성되게 된다. When the next secondary drying 100-150 o for 20-40 minutes in a drying chamber of C is to be the fine pores in the coating film evaporates with the solvent remaining with the water formed. 이때 미세한 기공의 크기는 실시예 1보다 작게 된다. The size of the fine pores is smaller than the first embodiment. 이 과정을 거치면 투습성과 통기성이 있으며 방수성이 있는 폴리우레탄 장갑이 제조되게 된다. Geochimyeon this process, the water vapor permeability and air permeability, and is a polyurethane gloves with a waterproof be prepared. 제조된 장갑은 전자산업의 산업용으로 활용된다. Manufactured gloves are utilized in industrial applications in the electronics industry.

[실시예 3] 100중량%의 수용성폴리우레탄 수지에 50-60중량%의 물과 100-200중량%의 MEK, 50-100중량%의 토너(Toner), 10-50중량%의 HP-2000, 10-50중량%의 HN-100을 혼합하여 교반시킨 다음 직조된 장갑을 손 모양의 금형에 끼운 후 디핑(Deeping)처리하여 코팅한 다음 80-100 o C의 건조실에서 10-30분 1차 건조시키면 용제가 증발하면서 도막이 거칠은 표면으로 형성된다. Example 3 Toner (Toner) of MEK, 50-100% by weight of 50 to 60% by weight of water and 100-200% by weight of the aqueous polyurethane resin of 100% by weight, of 10-50% by weight of HP-2000 , was stirred a mixture of HN-100 of 10-50% by weight, and then after a woven glove fitted in the hand-shaped mold was coated by dipping (Deeping) processing, and then 80-100 o 10-30 minutes in from the drying chamber of a C when dried and solvent is evaporated rough coat is formed in a surface. 그 다음 100-150 o C의 건조실에서 20-40분 동안 2차 건조시키면 1차 건조에서 남아있던 물이 증발하면서 최종적인 폴리우레탄 장갑이 제조되게 된다. When the next secondary drying 100-150 o for 20-40 minutes in a drying chamber of C is to be the final polyurethane gloves are manufactured with the water remaining in the primary drying evaporation. 이 과정을 거치면 도막에 미세한 기공이 형성되지 않으며, 따라서 장갑은 과수용이나 낙농용 등의 농업용으로 사용하게된다. Geochimyeon this process is not the fine pores formed in the film, and thus the glove is used for agriculture, such as for receiving or dairy.

[실시예 4] 100중량%의 수용성폴리우레탄 수지에 50-60중량%의 물과 100-200중량%의 MEK, 50-100중량%의 토너(Toner), 50-100중량%의 HP-2000, 1-5중량%의 가교제를 혼합하여 교반시킨 다음 직조된 장갑을 손 모양의 금형에 끼운 후 디핑(Deeping)처리하여 코팅한 다음 80-100 o C의 건조실에서 10-30분 1차 건조시키면 용제가 증발하면서 도막이 형성된다. Example 4 Toner (Toner) of MEK, 50-100% by weight of 50 to 60% by weight of water and 100-200% by weight of the aqueous polyurethane resin of 100 wt%, 50-100 wt% HP-2000 , when stirring a mixture of the crosslinking agent of 1-5% by weight and then drying the woven glove by inserting the hand-shaped dipping mold (Deeping) treated by coating and then drying at 80-100 o C for 10-30 minutes, the car while the solvent is evaporated it is formed coating film. 이때의 도막은 가교제의 영향으로 표면의 접착력이 향상되게 된다. At this time, the coating film is to be the adhesive force of the surface improves the effect of cross-linking agent. 그 다음 100-150 o C의 건조실에서 20-40분 동안 2차 건조시키면 1차 건조에서 남아있던 물이 증발하면서 도막에 미세한 기공을 형성하며 최종적인 폴리우레탄 장갑이 제조되게 된다. When the next secondary drying 100-150 o for 20-40 minutes in a drying chamber of the C forming the fine pores in the coating film while evaporating the water remaining in the primary drying, and are the final polyurethane gloves so produced. 상기와 같은 제조방법으로 제조된 장갑은 실시예 1보다 표면은 부드러우나 접착력이 우수하게 되어 전자산업의 산업용으로 사용하게된다. Produced by the production method as described above glove than in Example 1. The surface becomes smooth, Una adhesion is excellent is used in the electronics industry for industrial use.

(표 1) 본 발명의 실시예에 따라 제조된 폴리우레탄 장갑과 종래의 방식으로 제조된 장갑들의 물리적 특성 비교. (Table 1) compares the physical properties of the polyurethane gloves and the gloves produced by the conventional manufacturing method according to an embodiment of the invention.

물리적 특성 Physical characteristics 단위 unit 본 발명인 건식폴리우레탄장갑 The inventors dry polyurethane gloves 습식폴리우레탄 장갑 Liquid polyurethane gloves 종래의 장갑 Conventional gloves
점도 Viscosity cps/30±1℃ cps / 30 ± 1 ℃ 15,000-30,000 15000-30000 60,000-80,000 60000-80000 80,000-100,000 80000-100000
고형분 Solid % % 20-25 20-25 24-26 24-26 30-35 30-35
100% 모듈 100% module Kg f /㎠ Kg f / ㎠ 30-40 30-40 35-45 35-45 40-45 40-45
인장강도 The tensile strength Kg f /㎠ Kg f / ㎠ 500-700 500-700 700-800 700-800 800-900 800-900
연신률 Elongation % % 700-900 700-900 700-800 700-800 800-900 800-900

이상으로 살펴본 바와 같이 본 발명으로 제조된 건식 폴리우레탄 장갑은 폐수가 전혀 발생하지 않아 환경오염을 방지하며, 공정의 단순화로써 제조시간을 단축하여 장갑의 제조단가를 저감시킬 수 있다. The dry polyurethane gloves manufactured by the present invention as seen from the foregoing, and is to prevent environmental pollution does not occur at all the waste water, by reducing the production time as a simplification of the process it is possible to reduce the manufacturing cost of the glove. 또한 제조된 폴리우레탄 장갑은 투습성과 통기성, 방수성이 탁월하며, 착용감도 우수하고, 미끄럼방지 효과도 우수하고, 본 발명으로 제조된 장갑은 변색을 방지하며, 다양한 색상의 장갑을 생산 할 수 있어 사용자 및 생산자의 효율성을 극대화 하는 매우 훌륭한 발명이다. In addition, the produced polyurethane gloves and excellent in moisture-permeable and air-permeable, water-resistant, wear is also excellent, and excellent non-slip effect, and the glove made of the present invention is to prevent color fading, it is possible to produce a variety of colors glove user and a very good invention to maximize the efficiency of the producers.

Claims (3)

  1. 폴리우레탄 장갑의 제조방법에 있어서, In the production method of polyurethane gloves,
    수용성 폴리우레탄 100 중량부, 물 50-60 중량부, 용제(MEK) 100-150 중량부 및 토너(Toner) 50-100 중량부로 조성된 용액을 이용하여 코팅한 후 1차 건조(40-60 o C, 10-30분)와 2차 건조(100-150 o C, 20-40분)하는 것을 특징으로 하는 수용성 폴리우레탄이 코팅된 폴리우레탄 장갑의 건식 제조방법. Waterborne polyurethane 100 parts by weight water 50-60 parts by weight of a solvent (MEK) 100-150 parts by weight of a toner (Toner) 50-100 was coated by using a solution composition parts by weight of the primary drying (40-60 o C, 10-30 min) and the secondary drying (100-150 o C, 20-40 minutes) a dry process for producing a waterborne polyurethane coated glove polyurethane characterized in that.
  2. 제 1항에 있어서, According to claim 1,
    상기 폴리우레탄 100 중량부에 유화제 50-100 중량부, 용제 50-100 중량부, 토너(Toner) 10-50 중량부 및 제 1유화제(HP-2000) 10-50 중량부로 코팅하여 건조하는 것을 특징으로 하는 수용성 폴리우레탄이 코팅된 폴리우레탄 장갑의 건식 제조방법. The polyurethane 100 parts by weight of 50 to 100 parts by weight of an emulsifier, a solvent, 50 to 100 parts by weight of a toner (Toner) 10-50 parts by weight, and a first emulsifier (HP-2000) 10-50 wherein the coated and dried to parts by weight dry process for producing a waterborne polyurethane coated glove with a polyurethane.
  3. 제 1항에 있어서, According to claim 1,
    상기 폴리우레탄 100 중량부에 물 50-60 중량부, 용제 100-200 중량부, Toner 50-100 중량부, 제 1유화제(HP-2000) 50-100 중량부 및 가교제 1-5 중량부로 조성된 용액을 이용하여 코팅하여 건조하는 것을 특징으로 하는 수용성 폴리우레탄이 코팅된 폴리우레탄 장갑의 건식 제조방법. The polyurethane 50 to 60 parts by weight of water to 100 parts by weight of solvent 100 to 200 parts by weight of Toner 50 to 100 parts by weight of the emulsifier composition of claim 1 (HP-2000) 50 to 100 parts by weight and parts by weight of a crosslinking agent 1-5 dry method for producing a water-soluble polyurethane, characterized in that the coating dried by using a coating solution of polyurethane gloves.
KR20010044223A 2001-07-23 2001-07-23 Dry manufacturing method for polyurethane gloves coated by water soluble polyurethane KR100398025B1 (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100683897B1 (en) 2004-06-23 2007-02-15 미요시 마사오 A poly-urethane double gloves and its making method
KR100984024B1 (en) 2005-08-26 2010-09-28 두라밋 센드리안 버하드 Method and article of manufacturing a waterborne polyurethane coated glove liner
KR100988075B1 (en) 2008-07-29 2010-10-18 김용상 Foam Polyurethane Water Dispersion coated gloves those show a special water repellent quality and preparation method thereof
KR101538332B1 (en) * 2013-09-04 2015-07-23 주식회사 형제인터내셔널 Method and device for eliminating harmful substance of coated gloves

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100717975B1 (en) * 2006-08-24 2007-05-14 손국태 The glove coated polyurethane and its manufacturing method
KR100784131B1 (en) * 2006-09-29 2007-12-12 주식회사 서울세미텍 Method of manufacturing the permeable and waterproofing textiles having endurance and antibacterial and deodorization, and method of manufacturing of the permeable and waterproofing gloves

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100683897B1 (en) 2004-06-23 2007-02-15 미요시 마사오 A poly-urethane double gloves and its making method
KR100984024B1 (en) 2005-08-26 2010-09-28 두라밋 센드리안 버하드 Method and article of manufacturing a waterborne polyurethane coated glove liner
KR100988075B1 (en) 2008-07-29 2010-10-18 김용상 Foam Polyurethane Water Dispersion coated gloves those show a special water repellent quality and preparation method thereof
KR101538332B1 (en) * 2013-09-04 2015-07-23 주식회사 형제인터내셔널 Method and device for eliminating harmful substance of coated gloves

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