KR100370773B1 - Method for an anticorrosive of rice bran - Google Patents

Abstract

The present invention relates to a method for producing a rice bran-adding anticorrosive and to the anticorrosive.

The present invention for this purpose 62.3 ~ 63.3% by weight, rice bran 26-27% by weight, soda ash 6.5-6.6% by weight, sodium benzoate 0.5-0.8% by weight, EDTA 1.0-1.3% by weight, borax 1.5-1.7% by weight, polyacrylic acid Soda is provided in a 0.2 to 0.3% by weight ratio, the mixing step of mixing and stirring for about 1 hour 10 minutes while putting the ingredients in order in a conventional stirrer, and put the material subjected to the mixing process in a heatable thermal insulation tank at room temperature 28 ~ It is characterized in that the reaction is made by aging for 210 to 230 hours at 31 ℃.

The present invention configured as described above prevents foreign matters such as corrosion or capillary (SCALE) in various water pipes through which water flows, thereby smoothing the water flow inside the pipes, preventing waste of energy, and reducing equipment repair and replacement construction costs. In particular, it does not use phosphoric acid (PO ₄ ), which is the main cause of eutrophication of river water, to prevent environmental pollution.

Description

Manufacturing method of rice bran anticorrosive and its anticorrosive {METHOD FOR AN ANTICORROSIVE OF RICE BRAN}

The present invention is to prevent the foreign matter such as corrosion or capillary (SCALE) in the various kinds of water pipe flowing water to smooth the water flow inside the pipe to prevent waste of energy and to reduce the cost of repair and replacement construction equipment In particular, the present invention relates to a method for producing a rice bran anticorrosive and a method for preventing the environmental pollution by not using phosphoric acid (PO ₄ ) which is the main culprit of eutrophication of river water.

In general, as a conventional rust inhibitor composition, a rust inhibitor manufactured by mixing calcium with phosphoric acid as a main component is used.In order to suppress corrosion due to the characteristics of the material, a large amount of phosphoric acid should be mixed. It causes the problem of polluting the rivers, calcium is deposited inside the water pipe to form the capstone to prevent water flow and heat conductivity to reduce the waste of energy, which is a corrosion protection effect for one month after the input, but after one month There was a problem that the corrosion by phosphoric acid proceeds.

In addition, the use of rust inhibitors for water supply containing phosphoric acid and calcium in the plate heat exchanger of factories, apartments, and buildings produced a large amount of capstone, which caused many problems for workers to manage.

Currently, phosphate rust inhibitors are the only ones distributed, but they do not play a role in preventing corrosion and are being pointed out as a problem of generating scale inside pipes such as cooling and heating equipment.

In addition, the conventional technology is a silicate (SiO ₂ ) rust preventive agent made by mixing silica sand, sodium carbonate and calcium to dissolve in fire. There is a problem that scale is generated inside the water pipe.

The present invention has been made to solve all the problems of the prior art as described above, by preventing the foreign matter, such as corrosion or decay (SCALE) inside the various water pipe (water pipe) flowing water to smooth the flow of water inside the pipe The first purpose is to prevent waste of energy and to reduce the cost of repair and replacement of the facility. The second purpose is not to use phosphoric acid (PO ₄ ), which is the main cause of eutrophication of the river, but instead to use rice bran. In order to prevent environmental pollution, the third object is to provide a method for preparing a rice bran additive anticorrosive and a method for preventing the environmental pollution.

In order to achieve the above object, the present invention provides water 62.3-64.3 wt%, rice bran 26-27 wt%, soda ash 6.5-6.6 wt%, sodium benzoate 0.5-0.8 wt%, EDTA 1.0-1.3 wt%, borax 1.5-1.7 wt% Sodium polyacrylate is provided in a 0.2 to 0.3% by weight ratio, the mixing process of mixing and stirring for about 1 hour and 10 minutes while putting the ingredients in order in a conventional stirrer, and put the material subjected to the mixing process in the heatable thermal tank It provides a method for producing a rice bran anticorrosive agent and the anticorrosive material characterized in that the reaction is aged at room temperature 28 ~ 31 ℃ for 210 ~ 230 hours.

Hereinafter, described in detail with reference to the accompanying drawings a preferred embodiment of the present invention for achieving this purpose are as follows.

Method for producing a rice bran anticorrosive agent applied to the present invention and the anticorrosive agent is configured as follows.

That is, 62.3 ~ 64.3% by weight of water, 26 ~ 27% by weight of rice bran, 6.5 ~ 6.6% by weight of soda ash (sodium carbonate), 0.5-0.8% by weight of sodium benzoate (sodium benzoate), EDTA (standard solution of chelating agent) ) 1.0-1.3 wt%, Borax 1.5-1.7 wt%, Polyacrylacidsoda 0.2-0.3 wt% ratio to obtain a scale and anti-corrosion composition inside the metal water pipe.

At this time, the mixing method is to put the ingredients in a conventional stirrer for about 1 hour and 10 minutes after mixing and stirring, if the mixture is well mixed, put the material in a heatable insulating tank and the reaction is aged at room temperature 28 ~ 31 ℃ 210 ~ 230 hours Let 576 When the aging temperature is 33 ℃ or more, the rice bran is too mature to kill, so the desired amount of extraction falls and the product is suspended and the value drops, so the aging temperature should not exceed 33 ℃.

In addition, when the aging temperature is less than 26 ℃, less aging, the color becomes cloudy like rice water, the quantity is reduced, so the value is reduced as a product, so the aging temperature should not be below 26 ℃.

What is important in extracting the extract from the rice bran of the present invention is that the mixing ratio, the ripening temperature, the ripening time is important, it is necessary to make a good environment to obtain a product that can be satisfied.

In the present invention, corn bran, sorghum bran, etc. may be used in addition to rice bran, but it is preferable to use rice bran.

At this time, if the rice bran is used in more than 27% of the total content ratio, the resulting stock solution is suspended and filtered or purified. However, it takes a lot of filtration cost and time, so it is preferable to use it below 26 ~ 27%. It should be noted that it is easy and effective in preventing the internal scale and corrosion of the metal water pipe, and does not damage the surface of the piping material, and the lower the content ratio below 25%, the lower the scale or the anti-corrosion effect.

In addition, in the case of soda ash, it converts hard water of industrial water quality into soft water to soften the water and reacts with the ingredients of rice bran to facilitate the extraction, preventing scale and corrosion, thereby preventing the formation of scale and thereby preventing corrosion. And it is preferable to have a content ratio of 6.5 ~ 6.6%.

In the case of sodium benzoate applied to the present invention, the bacteria in the water are extinguished to prevent the decay of the water, thereby improving the iron corrosion resistance, and at present, since it is not the object of wastewater regulation, it is expensive but effective to use. It is preferable to have a content ratio of%.

In addition, EDTA is a harmful metal ion blocking agent that controls the hardness in water, removes harmful metals from living organisms, solidifies and precipitates the minerals contained in the water, preventing scale formation and controlling the hardness of the harmful metal minerals to prevent corrosion. It serves to make a role and the amount used is preferably to have a content ratio of 1.0 ~ 1.3%.

And borax applied to the present invention is to reduce the hard water by softening the water by reducing the hard water to soft water to form a corrosion-resistant coating on the metal surface to suppress corrosion, it is preferable to have a content ratio of 1.5 ~ 1.7%. .

In addition, it is preferable that the sodium polyacrylate serves as a dispersion precipitation role and performs a catalyst role by combining with the composition described above, and the amount used is preferably 0.2 to 0.3%.

Looking at the bar about the removal of minerals and foreign substances in the equipment or pipes using the capstone removal and corrosion protection agent configured as described above through the examples and comparative examples are as follows.

Example 1

The rice bran additive is applied to the present invention used to scale and prevent corrosion of metal water pipes,

64.3 weight% of water

Rice bran 26.0 wt%

6.5% by weight of soda ash

0.5% by weight sodium benzoate

EDTA 1.0 wt%

Borax 1.5 wt%

Sodium Polyacrylate 0.2% by weight

The composition was mixed with cooling and heating circulating water in a building of approximately 8,000 pyeong in Jeongwoo Building (Yeouido). After 1 month of use, the resultant was opened after using for 1 month. As a result, the green water turned out to be clear water after 6 days of adding the composition, and the inside of the water pipe was markedly clean and there was no corrosion progress after the use of the composition.

Example 2

The rice bran additive is applied to the present invention used to scale and prevent corrosion of metal water pipes,

62.3 weight% of water

Rice bran 27.0 wt%

6.6% by weight of soda ash

0.8 wt% sodium benzoate

EDTA 1.3 wt%

Borax 1.7 wt%

0.3% by weight of sodium polyacrylate

The composition was mixed with cooling and heating circulating water of approximately 20,000 pyeong of Kia Motors (Sohari Research Institute). After opening for 1 month and using it, red rust came out from the 7th day after the composition was turned into clear water, and the inside of the water pipe was found to be remarkably clean and corrosion-free after using the composition, and maintained in good condition. It was.

Example 3

The rice bran additive is applied to the present invention used to scale and prevent corrosion of metal water pipes,

64.3 weight% of water

Rice bran 26.0 wt%

6.5% by weight of soda ash

0.5% by weight sodium benzoate

EDTA 1.0 wt%

Borax 1.5 wt%

Sodium Polyacrylate 0.2% by weight

The composition was mixed with cooling and heating circulating water in a building of approximately 5,200 pyeong in Kia Motors (Asan Dormitory). After 1 month of use and open after use, red rust appeared to be clear from 7 days after the composition was added, and the inside of the water pipe was cleaner and there was no corrosion progress and the maintenance state was good.

Hereinafter, the compositions used for the iron-based pipes and the copper alloy pipes as the existing capstone removal composition are prepared, respectively, and used in the same form as the perfusion boiler used in Example 1 and the practical example 3 in the same capillary thickness pipe. The result of removing the capstone was shown as Comparative Example 1 and Comparative Example 2.

Comparative Example 1

Existing phosphate-based composition as an example used to prevent corrosion of iron-based piping cooling and heating water pipes,

80% by weight of water

Phosphate 11.2 wt%

Alkali 5.6 wt%

Calcium 3.2 wt%

The mixed composition was not corroded until 9 days after the iron-based steel pieces were put in a beaker and the composition 1.5g was added to 100 g of water, but the color of the water changed to brown, but after 19 days, the iron-based steel pieces were corroded visually. After 30 days of opening, weight loss after opening was found to be -1.40mg / ㎠ corrosion loss.

Comparative Example 2

Existing silicate-based composition as an example used to prevent corrosion of iron-based piping cooling and heating water pipes,

75 wt% water

Silicate 13.2 wt%

Phosphate 5.3% by weight

Alkali 3.2 wt%

Calcium 3.3 wt%

After the mixed composition, the iron-based steel piece was placed in a beaker, and the composition 1.5g was added to 100 g of water. There was no corrosion until 3 days, but black spots occurred on the steel piece after 4 days, and the black spots gradually increased after 8 days. After 15 days, the entire steel sheet changed to black, and foreign matters were accumulated at the bottom of the beaker, and the corrosion condition was observed. After 30 days, the weight was opened and the weight loss resulted in a lot of -1.75mg / ㎠ corrosion loss. .

Next, the present invention was tested for the weight change by the metal corrosion test of the existing rice bran additive anticorrosive composition, the results were obtained as shown in Table 1.

Table 1 Change in weight of rice bran additives by metal corrosion test of existing composition

Composition Rice Bran Additive Example 1 Example 2 Example 3 Comparative Example 1 Silicate Additive Comparative Example 2 River 0.01 -1.40 -1.75 Appearance none Corrosion Corrosion

As shown in Table 1, the present invention, which was used in Examples 1 and 2 and 3, shows that the composition used in Comparative Example 1 is about 14 times more severe than the composition. Furthermore, in the case of the rice bran-containing anticorrosive agent of the present invention, as shown in the above experiments, even in the state of 30 days of immersion, it was determined that there was no corrosion in the appearance due to the extremely small amount of corrosion phenomenon, and thus it was judged that there was no problem as the corrosion inhibitor inside the cooling and heating metal water pipes. can do.

In addition, as described above, red rust due to metal corrosion of the cooling / heating circulating water turns into clear water within one week after adding the composition of Example 1, as in Examples 1 to 3, and it is determined that corrosion of the metal water pipe is stopped. .

The method of manufacturing a rice bran anticorrosive agent according to the present invention and the anticorrosive agent according to the present invention, as of July 24, 2000, was commissioned by the Korean Institute of Emulsification and Testing, a national accredited testing and inspection organization, with the application number 2000-1413. The test results were informed on August 30, 2000.

The test report of the above result is as follows.

* Sample name: ① Anti-corrosive additives of rice ② Anti-corrosive additive of phosphate ③ Anti-corrosive additive of silicate

Test Items Test Test Methods ① ② ③ Corrosive to metals [1.5% aqueous solution 30 days] Metal test piece Weight change (mg / ㎠) River -0.01 -1.40 -1.75 KS M 2142 (97) and presented standards Outward appearance none Corrosion Corrosion

According to the test report as described above, the present invention, rice bran-added anticorrosive material has no heavy metal components or toxicity during use, does not harm the human body without contaminating the environment and at the same time obtained a result of no metal corrosion.

As described above, the present invention prevents foreign matters such as corrosion or capillary (SCALE) in various water pipes through which water flows, thereby smoothing the water flow inside the pipes, preventing waste of energy, and reducing facility repair and replacement construction costs. It does not use phosphoric acid (PO ₄ ), which is the main culprit of eutrophication of rivers, but instead uses natural materials extracted from rice bran to prevent environmental pollution. It is a very useful invention that can greatly improve the.

Claims (2)

Water 62.3 ~ 64.3 wt%, Rice bran 26 ~ 27 wt%, Soda ash 6.5 ~ 6.6 wt%, Sodium benzoate 0.5 ~ 0.8 wt%, EDTA 1.0 ~ 1.3 wt%, Borax 1.5 ~ 1.7 wt%, Sodium polyacrylate 0.2 ~ 0.3 wt% Equipped with a% rate; A mixing step of mixing and stirring the materials in a conventional stirrer for about 1 hour and 10 minutes; The method of producing a rice bran-adding anticorrosive agent, characterized in that the material is subjected to the mixing process in the heat insulating tank and the reaction aging for 210 to 230 hours at room temperature 28 ~ 31 ℃. Rice bran anticorrosive prepared by the method of claim 1.