KR100353631B1 - Heat treatment method of bearing steel casting with excellent center segregation - Google Patents

Heat treatment method of bearing steel casting with excellent center segregation Download PDF

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KR100353631B1
KR100353631B1 KR1019980062084A KR19980062084A KR100353631B1 KR 100353631 B1 KR100353631 B1 KR 100353631B1 KR 1019980062084 A KR1019980062084 A KR 1019980062084A KR 19980062084 A KR19980062084 A KR 19980062084A KR 100353631 B1 KR100353631 B1 KR 100353631B1
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cementite
bearing steel
segregation
heat treatment
slab
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KR1019980062084A
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KR20000045525A (en
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유선준
박성운
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주식회사 포스코
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    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/021Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips involving a particular fabrication or treatment of ingot or slab
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00Microstructure comprising significant phases
    • C21D2211/003Cementite

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Heat Treatment Of Articles (AREA)
  • Rolling Contact Bearings (AREA)

Abstract

본 발명은 볼베어링의 피로 수명을 감소시키는 소재 중심 편석을 감소시키기 위해 연속주조된 블룸(Bloom)의 열처리 온도 및 냉각 조건을 개선하여 블룸 주편 중심부의 편석을 감소시킴과 동시에 초석 세멘타이트(Cementite)의 두께를 감소시킨 볼베어링강 주편의 열처리 방법에 관한 것으로, 베어링강 제조시 블룸(Bloom) 상태의 주편의 중심 편석을 감소시키기 위하여 주편을 1250∼1280℃ 범위의 온도로 가열하고, 초석 세멘타이트의 두께를 미세화하도록 상변태전 850∼400℃ 온도 범위에서 냉각속도를 8∼15℃/sec로하여 냉각하는 것을 특징으로 한다.The present invention improves the heat treatment temperature and cooling conditions of continuous cast Bloom to reduce material center segregation, which reduces the fatigue life of ball bearings, thereby reducing segregation at the center of the bloom slab and at the same time of cementite cementite. The present invention relates to a heat treatment method of a ball bearing steel slab having a reduced thickness. In order to reduce the central segregation of a slab in a bloom state in the manufacture of bearing steel, the slab is heated to a temperature in the range of 1250 to 1280 ° C., and the thickness of cementite cementite is reduced. It is characterized by cooling at a cooling rate of 8 to 15 ℃ / sec in the temperature range of 850 to 400 ℃ before phase transformation.

본 발명에 의하면 볼베어링강 주편의 중심 편석이 대폭 감소되고, 초석 세멘타이트의 두께가 현저히 감소되어 베어링강 소재의 품질이 향상된다.According to the present invention, the center segregation of the ball bearing steel slab is greatly reduced, the thickness of the cementite cementite is significantly reduced, and the quality of the bearing steel material is improved.

Description

중심 편석이 우수한 베어링강 주편의 열처리 방법Heat treatment method of bearing steel casting with excellent center segregation

본 발명은 중심 편석(Central Segregation)이 우수한 볼베어링(Ball Bearing)강의 열처리 방법에 관한 것으로, 보다 상세하게는 볼베어링의 피로 수명을 저하시키는 소재 중심 편석을 감소시키기 위해 연속주조된 블룸(Bloom)의 열처리 온도 및 냉각 조건을 개선하여 블룸 주편 중심부의 편석을 감소시킴과 동시에 초석 세멘타이트(Cementite)의 두께를 감소시킨 볼베어링강 주편의 열처리 방법에 관한 것이다.The present invention relates to a heat treatment method of a ball bearing steel having excellent central segregation, and more particularly, heat treatment of a continuously cast bloom to reduce material center segregation which decreases the fatigue life of the ball bearing. The present invention relates to a method for heat treatment of a ball bearing steel slab which reduces the segregation at the center of a bloom slab by improving the temperature and cooling conditions and at the same time reduces the thickness of cementite cementite.

볼베어링강 주조시 주편 중심부에 발생하는 탄소량에 의한 편석(Segregation)은 볼베어링강의 기계적 성질에 가장 큰 악영향을 미친다.Segregation due to the amount of carbon generated in the center of cast steel during ball bearing steel casting has the greatest adverse effect on the mechanical properties of the ball bearing steel.

약 1 중량%의 탄소(C)와 1.4 중량%의 크롬(Cr)을 함유한 베어링강은 전로에서 제강후 레이들내에서 강환원성 분위기를 유지하면서 정련하여 비금속 개재물의 양을 저감시키며, 진공(RH) 탈가스 공정을 거쳐 산소 함량이 10ppm 까지 낮추어진 상태에서 정련하며, 이후 연속주조후 소재의 표면에 발생한 흠(Defects)을 제거하기 위해 핫 스카핑(Hot Scarfing) 공정을 실시하며, 이어서, 블룸(Bloom) 상태의 주편 중심부에 존재하는 편석을 제거하기 위해 균열 열처리(Soaking Heat Treatment)를 실시하고 자연 공냉을 거쳐 빌레트(Billet)로 압연된다.Bearing steel containing about 1% by weight of carbon (C) and 1.4% by weight of chromium (Cr) is refined while maintaining a strong reducing atmosphere in the ladle after steelmaking in the converter to reduce the amount of non-metallic inclusions, RH) After the degassing process, the oxygen content is lowered to 10ppm, and then hot scarfing is performed to remove defects on the surface of the material after continuous casting. Soaking Heat Treatment is performed to remove segregation at the center of the cast slab in the bloom state and is rolled to Billet through natural air cooling.

그후, 제 2, 제 3 선재 공장에서 소재를 연화시켜 주기 위하여 극서냉 조업을 실시하여 소재로 생산되며, 생산된 소재는 신선 및 구상화 열처리, 냉간 압조와 연삭을 거쳐 볼 베어링으로 가공하고, 이어서 퀀칭(Quenching) 및 템퍼링(Tempering) 공정 및 연마 공정을 거쳐 최종 제품인 볼베어링으로 생산된다.Subsequently, in order to soften the material in the second and third wire rod factories, ultra-cold operation is performed to produce the material. The produced material is processed into ball bearings through drawing and spheroidizing heat treatment, cold rolling and grinding, and then quenching. It is produced as ball bearing, the final product, through quenching, tempering and polishing processes.

상기와 같은 공정을 통해 생산된 볼베어링은 중심부에 세멘타이트가 형성되어 매우 취약하므로 피로 시험 혹은 사용중에 연속 주조시 중심 편석 발생 부위 및 선재 중심 부분의 초석 세멘타이트 부분인 소재의 중심부에서 크랙(Crack)이 빈번하게 발생한다.The ball bearing produced through the above process is very fragile due to the formation of cementite in the center, so it is cracked at the center of the material which is the center segregation part of the center segregation part and the center part of the wire rod during the continuous casting during the fatigue test or use. This happens frequently.

이러한 베어링강의 기계적 성질에 가장 큰 악영향을 미치는 주편 중심부의 편석 및 초석 세멘타이트의 형성을 저감시키기 위한 종래 기술로, 연속주조시 용강의 과열도를 20℃ 이하로 조정하고 주조속도를 약 0.63m/min으로 조정하여 연주주편에 형성되는 등축정 비율을 높여 편석을 감소시키거나, 선재 제조시 강제 송풍 냉각 구역에서 냉각 속도를 조정하여 선재 중심부에 초석 세멘타이트가 형성되는 양을 감소시킴과 동시에 퍼얼라이트(Pearlite)의 층상 간격도 작게하여 소재 품질을 개선시키는 방법이 있다.This is a conventional technique for reducing segregation in the center of cast steel and the formation of cementite cementite, which have the greatest adverse effect on the mechanical properties of the bearing steel.The superheat of molten steel is adjusted to 20 ℃ or lower and the casting speed is about 0.63m / Adjust min to reduce segregation by increasing the ratio of equiaxed crystals formed in cast steel, or adjust the cooling rate in the forced air cooling zone during wire rod manufacture to reduce the amount of cementite cementite formed in the center of wire rod and at the same time There is a method of improving material quality by making the layer thickness of (Pearlite) smaller.

또한, 일본 공개 특허 제 96-132205 호에서는 수직형 연주기에서 조업시 10∼100㎜의 경압하를 실시하여 베어링강에서의 편석을 감소시키는 방법이 개시되며, 일본 공개특허 제 94-248302호에서는 편석을 제어하기 위하여 응고 부분에 롤(Roll)을 설치하고 경압하를 실시하는 기술이 개시되는등 주로 설비에 의해 편석 발생을 제어하려는 시도가 다수 이루어져왔다.In addition, Japanese Patent Application Laid-Open No. 96-132205 discloses a method of reducing segregation in bearing steel by performing a light pressure of 10 to 100 mm when operating in a vertical player, and in Japanese Patent Application Laid-Open No. 94-248302. Attempts have been made to control segregation by means of equipment, such as the installation of rolls on the solidification part and the application of light pressure to control the pressure.

그러나, 상기 설명한 바와 같은 종래기술에 의해 생산된 베어링강 소재의 경우 여전히 중심 편석이 잔존하고 있어서, 이러한 잔존 편석에 의해 초석 세멘타이트가 발생하여 소재의 품질이 열악해지는 문제는 해소되지 못하였다.However, in the case of the bearing steel material produced by the prior art as described above, the center segregation still remains, so that the problem that the quality of the material is deteriorated due to the generation of cornerstone cementite due to such residual segregation has not been solved.

본 발명은 상기 설명한 종래기술의 문제를 해결하기 위하여 이루어진 것으로, 소재 중심부에 발생하는 중심 편석을 대폭 저감시키고 초석 세멘타이트의 두께를 감소시켜 제조된 베어링강 소재의 품질을 향상시킨 베어링강 주편의 열처리 방법을 제공함에 그 목적이 있다.The present invention has been made in order to solve the problems of the prior art described above, heat treatment of the bearing steel slab improved the quality of the bearing steel material produced by significantly reducing the center segregation generated in the center of the material and the thickness of the cementite cementite The purpose is to provide a method.

도 1 은 베어링강의 제조 공정을 도시한 도면,1 is a view showing a manufacturing process of a bearing steel,

도 2 는 본 발명과 종래 기술의 냉각 조건을 비교하여 나타낸 도면,Figure 2 is a view showing a comparison of the cooling conditions of the present invention and the prior art,

도 3 은 본 발명과 종래 기술의 편석지수를 비교하여 나타낸 도면,3 is a view showing a comparison of the segregation index of the present invention and the prior art,

도 4 는 본 발명과 종래 기술의 초석 세멘타이트 두께를 비교하여 나타낸 도면이다.Figure 4 is a view showing a comparison of the thickness of the cementite cementite of the present invention and the prior art.

상기 목적을 달성하기 위하여 본 발명에서는 베어링강 제조시 블룸(Bloom) 상태의 주편의 열처리방법에 있어서, 중심 편석을 감소시키기 위하여 주편을 1250∼1280℃ 범위의 온도로 가열하고, 초석 세멘타이트의 두께를 미세화하도록 상변태전 850∼400℃ 온도 범위에서 냉각속도를 8∼15℃/sec로하여 냉각하는 베어링강 주편의 열처리방법을 제공한다.In order to achieve the above object, in the present invention, in the method of heat-treating the cast steel in the bloom (Bloom) state in the production of bearing steel, in order to reduce the center segregation, the cast steel is heated to a temperature in the range of 1250 ~ 1280 ℃, the thickness of cementite cementite It provides a heat treatment method of the bearing steel cast for cooling to a cooling rate of 8 ~ 15 ℃ / sec in the temperature range of 850 ~ 400 ℃ before phase transformation.

이하에서는 양호한 실시예와 관련하여 본 발명을 상세하게 설명한다.Hereinafter, the present invention will be described in detail with reference to the preferred embodiments.

본 발명의 열처리 방법에서는 도 1 도시와 같이,주편에 잔존하는 중심 편석을 효과적으로 저감시키기 위하여 연속주조되고, 소재의 표면흠을 제거하기 위한 핫 스카핑(Hot Scarfing) 공정을 거친 블룸 형상의 볼베어링강 주편을 균열열처리(Soaking Heat 하는 공정에서 가열온도를 1250∼1280℃로하여 가열하는데, 1250℃ 이하로 가열하는 경우는 중심부에 편석을 발생하는 합금 원소의 확산이 늦어져 편석의 저감 효과가 거의 없기 때문이며, 1280℃ 이상으로 가열하면 오스테나이트(Austenite)의 입자 크기가 커져 후공정에서 주편의 냉각 속도를 제어하여도 입계(Grain Boundary) 주위에 두꺼운 초석 세멘타이트가 형성되어 가열 온도 변경에 의한 중심 편석의 저감 효과가 미미하여 1250∼1280℃ 범위로 가열 온도를 제한한다.In the heat treatment method of the present invention, as shown in Fig. 1, the ball-shaped ball bearing steel which is continuously cast in order to effectively reduce the center segregation remaining in the cast steel, and has undergone a hot scarping process to remove surface defects of the material. In the process of soaking heat, the cast is heated at a heating temperature of 1250 to 1280 ° C, but when heated to 1250 ° C or less, diffusion of alloying elements that cause segregation in the center is delayed and thus there is little effect of reducing segregation. If heated above 1280 ℃, the size of austenite becomes larger and thicker cementite cementite is formed around the grain boundary even though the cooling rate of the cast is controlled in the post-process. The effect of reducing the stone is negligible and the heating temperature is limited to 1250 to 1280 ° C.

또한, 도 2 도시와 같이, 본 발명에서는 종래 자연 냉각시키는 것과 달리 주편 냉각시 초석 세멘타이트의 두께를 감소시키기 위해 상변태전 850∼400℃ 온도범위에서 냉각 속도를 8∼15℃/sec로 조정하여 냉각을 실시한다.In addition, as shown in FIG. 2, in the present invention, unlike the conventional natural cooling, in order to reduce the thickness of the cementite cementite during cooling of the cast steel, the cooling rate is adjusted to 8 to 15 ° C / sec in the temperature range of 850 to 400 ° C. Cool down.

이때, 냉각 속도를 8∼15℃/sec로 조정하는 것은 압축공기를 이용하여 강제냉각시키는 방식을 취하는 것이 바람직하다.At this time, it is preferable that the cooling rate is adjusted to 8 to 15 ° C / sec by a forced cooling method using compressed air.

냉각 속도를 8∼15℃/sec로 조정하는 것은, 주편 냉각 속도가 8℃/sec 이하인 경우 가속 냉각 효과가 작아 초석 세멘타이트의 두께 감소 효과가 작을 뿐만 아니라 퍼얼라이트 층상 간격의 감소가 작기 때문이며, 냉각 속도를 15℃/sec이상으로 하는 경우 베이나이트(Bainite)나 마르텐사이트(Martensite)와 같은 유해한 저온 조직이 생성되어 표면에 크랙이 발생할 수 있기 때문에 냉각 속도를The cooling rate is adjusted to 8 to 15 ° C./sec because the accelerated cooling effect is small when the casting cooling rate is 8 ° C./sec or less, so that the thickness reduction effect of the cornerstone cementite is small, and the decrease in the layer thickness of the pearlite is small. If the cooling rate is higher than 15 ° C / sec, harmful cold tissue such as bainite or martensite may be formed, causing cracks on the surface.

8∼15℃/sec로 조정하는 것이다.It adjusts at 8-15 degreeC / sec.

이하에서는 실시예를 통하여 본 발명을 보다 상세하게 설명한다.Hereinafter, the present invention will be described in more detail with reference to Examples.

실시예Example

본 발명이 적용되는 대상 소재의 성분 조성을 표 1 에 나타내었다.Table 1 shows the component composition of the target material to which the present invention is applied.

강종Steel grade 화 학 성 분(중량%)Chemical component (wt%) CC SS O2(ppm)O 2 (ppm) N2(ppm)N 2 (ppm) SiSi PP MnMn CrCr TiTi CuCu SUJ2SUJ2 1.021.02 0.0030.003 1010 3434 0.230.23 0.0120.012 0.370.37 1.451.45 0.0030.003 미량a very small amount

본 실시예의 경우 발명재는 연속주조된 상기 조성의 블룸 형상 주편을 균열열처리시 가열온도를 1250∼1280℃ 로하여 6시간 가열하였으며, 상변태전 냉각속도를 10 ℃/sec로 조정하여 냉각하였다.In the case of the present embodiment, the inventive material was heated for 6 hours with the heating temperature of 1250 to 1280 ° C. during the crack heat treatment of the bloom-shaped slab of the above-described continuous casting, and cooled by adjusting the phase transformation cooling rate to 10 ° C./sec.

비교재는 가열온도를 종래 가열 온도 범위인 1200℃로하여 6시간 가열하였으며, 냉각속도는 동일하게 10℃/sec로 하였다.The comparative material was heated at a heating temperature of 1200 ° C. for 6 hours, and the cooling rate was the same at 10 ° C./sec.

도 3 및 도 4 는 발명재를 각각 가열온도를 1250℃, 1260℃, 1270℃,1280℃로 변화시키면서 측정하고 비교재는 4회 반복 시험하여 측정한 편석지수(Segregation Ratio)와 초석 세멘타이트의 두께를 비교하여 나타내고 있는데, 발명재의 경우 편석지수가 현저히 감소하며, 초석 세멘타이트의 두께가 현저히 감소함을 알 수 있다.3 and 4 are measured the invention materials while changing the heating temperature to 1250 ℃, 1260 ℃, 1270 ℃, 1280 ℃, and the comparative material was measured by repeated tests four times (Segregation Ratio) and the thickness of the cement cementite In comparison with the present invention, the segregation index is significantly reduced in the case of the inventive material, and the thickness of the cementite cementite is significantly reduced.

따라서, 본 발명에 의하면, 베어링강 주편의 중심 편석이 현저히 감소하며, 초석 세멘타이트가 감소하고 퍼얼라이트 층상간격이 감소하므로 제조된 베어링강의 표면 경도가 향상되고 피로 수명이 향상되는 등 기계적 성질이 개선된다.Therefore, according to the present invention, the central segregation of the bearing steel slab is significantly reduced, the cementite cementite is reduced and the ferrite layer spacing is reduced, thereby improving the mechanical properties such as improving the surface hardness of the manufactured bearing steel and improving the fatigue life. do.

Claims (1)

베어링강 제조시 블룸(Bloom) 상태의 주편의 열처리 방법에 있어서, 중심 편석을 감소시키기 위하여 주편을 1250∼1280℃ 범위의 온도로 가열하고, 초석 세멘타이트의 두께를 미세화하도록 상변태전에 850∼400℃ 온도범위에서 냉각속도를 8∼15℃/sec로하여 냉각하는 것을 특징으로 하는 베어링강 주편의 열처리방법.In the process of heat-treating the cast steel in the bloom state of bearing steel, in order to reduce the center segregation, the cast steel is heated to a temperature in the range of 1250 to 1280 ° C. and 850 to 400 ° C. before the phase transformation to refine the thickness of the cementite cementite. A heat treatment method for a bearing steel slab, characterized by cooling at a temperature ranging from 8 to 15 ° C / sec.
KR1019980062084A 1998-12-30 1998-12-30 Heat treatment method of bearing steel casting with excellent center segregation KR100353631B1 (en)

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