KR100345804B1 - Electromagnetic Shelter Mortar - Google Patents

Electromagnetic Shelter Mortar Download PDF

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KR100345804B1
KR100345804B1 KR1020000000371A KR20000000371A KR100345804B1 KR 100345804 B1 KR100345804 B1 KR 100345804B1 KR 1020000000371 A KR1020000000371 A KR 1020000000371A KR 20000000371 A KR20000000371 A KR 20000000371A KR 100345804 B1 KR100345804 B1 KR 100345804B1
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weight
composition
electromagnetic
surfactant
electromagnetic shielding
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KR20010068447A (en
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신항철
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신항철
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B18/00Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B18/04Waste materials; Refuse
    • C04B18/14Waste materials; Refuse from metallurgical processes
    • C04B18/141Slags
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B14/00Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B14/02Granular materials, e.g. microballoons
    • C04B14/04Silica-rich materials; Silicates
    • C04B14/20Mica; Vermiculite
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B22/00Use of inorganic materials as active ingredients for mortars, concrete or artificial stone, e.g. accelerators, shrinkage compensating agents
    • C04B22/08Acids or salts thereof
    • C04B22/14Acids or salts thereof containing sulfur in the anion, e.g. sulfides
    • C04B22/142Sulfates
    • C04B22/143Calcium-sulfate
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K9/00Screening of apparatus or components against electric or magnetic fields
    • H05K9/0073Shielding materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2103/00Function or property of ingredients for mortars, concrete or artificial stone
    • C04B2103/40Surface-active agents, dispersants
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Civil Engineering (AREA)
  • Environmental & Geological Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Shielding Devices Or Components To Electric Or Magnetic Fields (AREA)
  • Building Environments (AREA)

Abstract

본 발명은 슬래그 10∼20중량%와, 운모석 5∼15중량%, 분산제 0.1∼ 5중량%, 코우크스 1 ∼ 5중량% 및보조제 0.1∼ 2중량%g을 물에 충분히 교반한후 상기 혼합물에 황산칼슘 30∼70중량%으로 조성됨을 특징으로 하는 전자파차폐용 조성물The present invention is a mixture of 10 to 20% by weight of slag, 5 to 15% by weight of mica stone, 0.1 to 5% by weight of dispersant, 1 to 5% by weight of coke and 0.1 to 2% by weight of adjuvants after sufficiently stirring the mixture. The composition for electromagnetic shielding, characterized in that the composition is composed of calcium sulfate 30 to 70% by weight

Description

전자파차폐용 조성물{Electromagnetic Shelter Mortar}Electromagnetic shielding composition {Electromagnetic Shelter Mortar}

본 발명은 전자파차폐용 조성물에 관한 것이다. 상세히 설명하면 몰탈을 이용하여 각종 건축자재를 제작하거나 건축물 및 건축자재에 도포하여 전자파를 차단하는 전자파 차폐용 조성물에 관한 것이다.The present invention relates to a composition for shielding electromagnetic waves. In detail, the present invention relates to a composition for shielding electromagnetic waves by manufacturing various building materials using mortar or by applying them to buildings and building materials to block electromagnetic waves.

전자, 통신산업의 발달과 더불어 현대인은 각종 전기, 전자 기기 들의 이용이 많아짐에 따라 각종 전자파의 노출이 증가되어 전자파로 인한 폐해를 연구하기 시작하며 그에 따른 대책을 강구하기 시작하였다.With the development of the electronics and telecommunications industry, as the use of various electric and electronic devices increases, the exposure of various kinds of electromagnetic waves increases.

전자파는 매질을 지나면서 투과, 흡수 및 반사가 일어나며, 이러한 현상들은 매질의 종류와 형상 등에 영향을 받으며, 매질의 전자기적 성질에 따라 흡수체와 반사체로 구분될 수 있으며 이러한 성질을 이용하여, 세계의 각 나라에서는 레이더의 허상제거나 레이더 교란등 주로 군사적 목적으로 전자파흡수체를 개발해왔다. 최근 군사적 목적뿐만 아니라 전자파장애방지용 플라스틱이나 유리제품, 고주파 흡수용 석고보드 등 일상생활에 사용되는 제품의 개발이 활발하였고,Electromagnetic waves are transmitted, absorbed, and reflected as they pass through the medium. These phenomena are affected by the type and shape of the medium, and can be classified into absorbers and reflectors according to the electromagnetic properties of the medium. Each country has developed electromagnetic wave absorbers mainly for military purposes, such as radar imagery or radar disturbances. Recently, the development of products used in daily life such as plastic or glass products for preventing electromagnetic interference, gypsum board for high frequency absorption, as well as military purposes has been active.

최근에는 고전압 송전선에서 유도된 초극저주파 등과 같은 다양한 전자파가 인체에 미치는 영향 및 차례기술에 대한 연구가 있어왔다.Recently, there have been studies on the effects of various electromagnetic waves on the human body, such as ultra-low frequency induced in high-voltage transmission lines, and a turn technology.

일본특허공개공보 공개번호 평6-209180호는 전자파 흡수내벽재에 석고보드, 석면시멘트보드 또는 규산칼슘판으로 되어 있는 판재에 탄소, 페라이트, 금속분말 또는 이들의 혼합물을 포함시켜 전자파를 흡수, 차폐하는 기술이 기재되어 있고,Japanese Patent Application Laid-open No. Hei 6-209180 absorbs and shields electromagnetic waves by including carbon, ferrite, metal powder, or mixtures thereof in a plate made of gypsum board, asbestos cement board, or calcium silicate plate in the electromagnetic wave absorbing inner wall material. The technique to say is described,

일본 공개특허공보 공개번호 평 1-148738호에는 수경성물질, 도전성 물질 및 물을 혼합한 수경성물질 및 도전성 물질 등이 공개되어 있으며,Japanese Laid-Open Patent Publication No. Hei 1-148738 discloses a hydraulic material, a conductive material and a conductive material mixed with water, a conductive material and water,

일본 공개특허공보 공개번호 제61-21956호에는 탄소섬유 복합강화석고보드 및 그 제조방법이 기재되어 있으나,Japanese Laid-Open Patent Publication No. 61-21956 describes a carbon fiber composite reinforced gypsum board and a manufacturing method thereof.

상기 종래의 기술들은 물리적 특성과, 석고보드의 불순물함유 등으로 전자파차폐의 효과는 어느 정도 인정되나 물리적 특성을 저하시키는 문제점이 있어 왔다.The conventional technologies have a problem in that the effect of electromagnetic shielding is recognized to some extent due to physical properties and the impurity content of the gypsum board, but it has a problem of lowering the physical properties.

본원 발명은 상기 문제점을 해결하고자, 본원 발명은 황산칼슘, 분산제, 슬래그, 코우크스, 운모석의 몰탈을 이용하여 각종 건축자재를 제작하거나 건축물 및 건축자재에 도포하여 전자파를 차단하는 전자파차폐용 조성물의 제공을 그 목적으로 하는 것이다.The present invention is to solve the above problems, the present invention is to produce a variety of building materials using calcium sulfate, dispersant, slag, coke, mica stone or applied to buildings and building materials of the composition for electromagnetic shielding to block electromagnetic waves The purpose is to provide.

상기한 바와 같은 목적을 달성하기 위하여, 본원 발명은 황산칼슘, 분산제, 슬래그, 코우크스, 운모석 및 기타 보조제로 조성된 전자파차폐용 조성물에 관한 것이다.In order to achieve the above object, the present invention relates to a composition for shielding electromagnetic waves, which is composed of calcium sulfate, dispersant, slag, coke, mica stone and other auxiliaries.

상기에서 사용되는 분산제는 상기 물질들이 서로 잘 혼합되도록 하는 기능을 하여, 서로 고르게 분산될 수 있도록 하는 것으로서, 상기 분산제로는 아민염, 제4급암모늄염, 피리미디늄염등의 양이온계면활성제와 음이온계면활성제 및 알킬아릴에테르, 알킬에테르, 알킬아민등의 산화에틸렌계 계면활성세, 다가 알콜지방산글리세린에스테르, 다가알콜지방산에스테르계 계면활성제, 폴리에틸렌아민계 계면활성제 및 지방산 알킬졸아미드계 계면활성제 등과 같은 비이온성 계면활성제에서 선택된 어느하나의 화합물 또는 이들 중 2이상의 혼합물로 이루어진 그룹으로부터 선택된 것이 사용 될 수 있다.The dispersant used in the above is to make the materials to be mixed well with each other, so that they can be uniformly dispersed with each other, the dispersant and anionic surface such as amine salt, quaternary ammonium salt, pyrimidinium salt, etc. Activators, such as ethylene oxide surfactants such as alkylaryl ethers, alkyl ethers, and alkylamines, polyhydric alcohol fatty acid glycerin esters, polyhydric alcohol fatty acid ester surfactants, polyethylene amine surfactants, and fatty acid alkyl solamide surfactants. Any compound selected from the ionic surfactants or those selected from the group consisting of two or more thereof may be used.

상기 보조제는 상기 혼합물의 흐름성을 놓게 하여 유동성을 유지하도록하여 몰탈의 성형성을 극대화시키는 역할을 하며, 벤즈알데히드 등과 같은 방향족 알데히드가 사용된다.The auxiliary agent serves to maximize flowability of the mortar by releasing the flowability of the mixture to maintain fluidity, and aromatic aldehydes such as benzaldehyde and the like are used.

상기 슬래그 및 운모석의 직경은 1∼30㎛이 가장 혼합이 잘되고, 유동성이 좋다.The diameter of the slag and mica is 1 to 30㎛ is best mixed, the fluidity is good.

상기 전자파 차폐용 조성물은 건축물의 주변 벽면에 직접 타설, 살포 또는 미장하거나, 벽돌, 타일 또는 플레이트의 형태로 제작한 건축자재를 건축물의 벽면에 조립 설비함으로써 전자파 차폐기능을 갖는 광물합제에 관한 것이다.The electromagnetic wave shielding composition relates to a mineral mixture having an electromagnetic shielding function by directly placing, spraying or plastering on a peripheral wall of a building, or assembling a building material manufactured in the form of a brick, a tile, or a plate on a wall of a building.

상기 전자파차단 조성물의 선택은 구체적인 건축시설의 이용 조건에 따라 달라진다.The choice of electromagnetic shielding composition depends on the specific conditions of use of the building facility.

대개의 경우에 있어서 전자파 차단 설비에 적합한 건축물은 작업자에게 알맞는 온도, 습도를 갖춘 건축물로서 전자파 차단에 사용되는 전자파차폐 조성물은 시멘트 등과 같은 모든 종류의 접합제와 함께 사용할 수 있으며, 예외적으로 상대 습도에 따라 또는 동절기 외부의 온도에 따라 내한성을 고려하여, 특별히 외부 벽면재 패널의 제작이 필요할 경우 본 발명의 전자파차폐 조성물을 사용할 수 있다.In most cases, a building suitable for electromagnetic wave shielding facilities has a temperature and humidity suitable for workers, and the electromagnetic shielding composition used for shielding electromagnetic waves can be used with all kinds of binders such as cement, with the exception of relative humidity. In consideration of cold resistance according to the temperature of the winter or outside, in particular when the manufacture of the external wall panel can be used the electromagnetic shielding composition of the present invention.

이하 본 발명을 실시예를 통하여 상세히 설명하기로 한다.Hereinafter, the present invention will be described in detail through examples.

실시예1Example 1

슬래그 2Kg와, 운모석 1kg, 알파올레핀설포네이트 8.6g, 코우크스50g 및 나프틸포름알데히드 247.7g을 물에 충분히 교반한후 상기 혼합물에 황산칼슘 2.88kg을 혼합하여 페이스트상으로 준비하고 상기 페이스트상의 전자파차폐용 조성물을 제조하였다필요시적당량의 시멘트를 섞어서 사용하거나, 기타 물질을 혼합하여 사용할 수 있다.2 kg of slag, 1 kg of mica stone, 8.6 g of alpha olefinsulfonate, 50 g of coke and 247.7 g of naphthylformaldehyde were sufficiently stirred in water, and then 2.88 kg of calcium sulfate was mixed with the mixture to prepare a paste. Electromagnetic shielding composition was prepared. If necessary, an appropriate amount of cement may be mixed or other materials may be mixed.

전자파흡수성 측정은 RF법(Adventest사의 TR-1730/A에 의한 측정법)에 따라 측정하였으며, 그 결과는 표1과 같이 나타내었다.Electromagnetic absorptivity was measured according to the RF method (Measurement method by TR-1730 / A of Adventest), and the results are shown in Table 1.

실시예2Example 2

슬래그 3Kg와, 운모석 1.5kg, 알파올레핀설포네이트 8.6g, 코우크스 50g 및 나프틸포름알데히드 247.7g을 물에 충분히 교반한 후, 상기 혼합물에 황산칼슘 2.88kg을 혼합하여 페이스트상으로 준비하고 상기 페이스트상의 전자파차폐용 조성물을 제조하였다.필요시 적당량의 시멘트를 섞어서 사용하거나, 기타 물질을 혼합하여 사용할 수 있다.After 3 kg of slag, 1.5 kg of mica stone, 8.6 g of alpha olefin sulfonate, 50 g of coke and 247.7 g of naphthylformaldehyde were sufficiently stirred in water, 2.88 kg of calcium sulfate was mixed with the mixture to prepare a paste. A paste-like composition for shielding electromagnetic waves was prepared. If necessary, an appropriate amount of cement may be mixed or other materials may be mixed.

전자파흡수성 측정은 RF법(Adventest사의 TR-1730/A에 의한 측정법)에 따라 측정하였으며, 그 결과는 표1과 같이 나타내었다.Electromagnetic absorptivity was measured according to the RF method (Measurement method by TR-1730 / A of Adventest), and the results are shown in Table 1.

실시예3Example 3

슬래그 3Kg와, 운모석 1kg, 알파올레핀설포네이트 8.6g, 코우크스50g 및 나프틸포름알데히드 247.7g을 물에 충분히 교반한후 상기 혼합물에 황산칼슘 5.76kg을 혼합하여 페이스트상으로 준비하고 상기 페이스트상의 전자파차례용 조성물을 제조하였다.필요시 적당량의 시멘트를 섞어서 사용하거나, 기타 물질을 혼합하여 사용할 수 있다.3 kg of slag, 1 kg of mica stone, 8.6 g of alpha olefinsulfonate, 50 g of coke and 247.7 g of naphthylformaldehyde were sufficiently stirred in water, and 5.76 kg of calcium sulfate was mixed with the mixture to prepare a paste. An electromagnetic wave turnover composition was prepared. If necessary, an appropriate amount of cement may be mixed or other materials may be mixed.

전자파흡수성 측정은 RF법(Adventest사의 TR-1730/A에 의한 측정법)에 따라 측정하였으며, 그 결과는 표1과 같이 나타내었다.Electromagnetic absorptivity was measured according to the RF method (Measurement method by TR-1730 / A of Adventest), and the results are shown in Table 1.

표 1 Table 1

시험방법은 Adventest사의 TR-1730/A(공진특성에 의한 신호 변율 약 3db)로 측정하였다.The test method was measured by Adventest TR-1730 / A (signal variation of about 3db due to the resonance characteristics).

상기와 같은 본 발명은, 물리적 특성이 우수한 전자파차례용 조성물을 제공하며, 직접 타설, 살포 또는 미장하거나, 벽돌, 타일 또는 플레이트의 형태로 제작한 건축자재를 건축물의 벽면에 조립 설비할 수 있어 시공이 편리하며, 소비자가 원하는 건축자재로 사용할 수 있고, 인체에 유해한 전자파를 차폐하는 효과가 있는 것이다.The present invention as described above, provides a composition for electromagnetic wave with excellent physical properties, can be directly installed, sprayed or plastered, or the building material manufactured in the form of bricks, tiles or plates can be installed on the wall of the building construction This is convenient, can be used as a building material desired by the consumer, it is effective to shield the electromagnetic waves harmful to the human body.

Claims (4)

전자파차폐용 조성물에 있어서, 직경은 1∼30㎛인 슬래그 10∼20중량%와, 직경은 1∼30㎛인 운모석 5∼15중량%, 분산제 0.1∼ 5중량%, 코우크스 1 ∼ 5중량%, 보조제로 벤즈알데히드 0.1∼ 2중량%, 물 약간량과 황산칼슘 30∼70중량%으로 조성됨을 특징으로 하는 전자파차폐용 조성물In the composition for electromagnetic shielding, 10 to 20% by weight of slag having a diameter of 1 to 30 µm, 5 to 15% by weight of mica stone having a diameter of 1 to 30 µm, 0.1 to 5% by weight of a dispersant, and 1 to 5% of coke %, Benzaldehyde 0.1 to 2% by weight, a slight amount of water and 30 to 70% by weight of calcium sulfate composition for electromagnetic shielding 삭제delete 제1항에 있어서, 상기 분산제는 아민염, 제4급암모늄염, 피리미디늄염등의 양이온계면활성제와 알파올레핀설페이트등의 음이온계면활성제 및 알킬아릴에테르, 알킬에테르, 알킬아민등의 산화에틸렌계 계면활성세, 다가알콜지방산글리세린에스테르, 다가알콜지방산에스테르계 계면활성제, 폴리에틸렌아민계 계면활성제 및 지방산 알킬졸아미드계 계면활성제 등과 같은 비이온성 계면활성제에서 선택된 어느하나의 화합물 또는 이들 중 2이상의 화합물로 이루어진 그룹으로부터 선택된 것임을 특징으로 하는 전자파 차폐용 조성물.The dispersing agent is an anionic surfactant such as an amine salt, a quaternary ammonium salt, a pyrimidinium salt, an anionic surfactant such as alpha olefin sulfate, and an ethylene oxide-based interface such as alkyl aryl ether, alkyl ether, or alkyl amine. It consists of any one compound selected from nonionic surfactants such as active tax, polyhydric alcohol fatty acid glycerin ester, polyhydric alcohol fatty acid ester surfactant, polyethyleneamine surfactant and fatty acid alkylzolamide surfactant, or two or more of these compounds. Electromagnetic shielding composition, characterized in that selected from the group. 삭제delete
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Publication number Priority date Publication date Assignee Title
KR101217738B1 (en) * 2010-02-17 2013-01-02 송종혁 Composition and preparation method of hydraulic setting tile with EMI shielding properties

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KR19990053103A (en) * 1997-12-23 1999-07-15 정몽선 Frequency-blocking concrete by frequency and its composition calculation method

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR19990053103A (en) * 1997-12-23 1999-07-15 정몽선 Frequency-blocking concrete by frequency and its composition calculation method

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101217738B1 (en) * 2010-02-17 2013-01-02 송종혁 Composition and preparation method of hydraulic setting tile with EMI shielding properties

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