KR100331604B1 - Method for reusing the polyethylene rosin of waste cable by solvent. - Google Patents

Method for reusing the polyethylene rosin of waste cable by solvent. Download PDF

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Publication number
KR100331604B1
KR100331604B1 KR1019990059304A KR19990059304A KR100331604B1 KR 100331604 B1 KR100331604 B1 KR 100331604B1 KR 1019990059304 A KR1019990059304 A KR 1019990059304A KR 19990059304 A KR19990059304 A KR 19990059304A KR 100331604 B1 KR100331604 B1 KR 100331604B1
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solvent
polyethylene resin
recycled
communication cable
pit
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KR1019990059304A
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Korean (ko)
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KR20010064892A (en
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이종열
황쌍옥
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이종열
황쌍옥
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B17/00Recovery of plastics or other constituents of waste material containing plastics
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/62Plastics recycling; Rubber recycling

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  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)

Abstract

본 발명은 폐통신케이블의 외피에 형성된 고품질의 폴리에치렌수지만을 분리수거하여 재활용할 수 있도록 한 용제를 이용한 폐통신케이블의 폴리에치렌수지 재활용 처리방법에 관한 것이다.The present invention relates to a method for recycling polyethylene resin in a waste communication cable using a solvent capable of separating and recycling only high-quality polyethylene resin formed on the outer surface of the waste communication cable.

상기 목적을 달성하기 위하여 본 발명은 폐통신케이블로부터 핏지가 접합된 폴리에치렌수지외피를 수거한 다음 일정한 크기로 절단하고, 절단된 외피를 세척탱크에 투입하여 세척용제로 처리함으로써 핏지가 용해되어 제거된 순수 폴리에치렌수지만을 얻고, 상기 수지는 압출기를 통하여 칩화한 다음 재활용케하고, 사용된 세척용제는 용제회수공정을 통하여 회수하여 재활용케 하고, 핏지와 이물질은 분리수거 한 후 핏지는 재활용되게 하여서 된 것이다.In order to achieve the above object, the present invention collects a polyetchene resin outer shell with a pitch bonded from the waste communication cable and cuts it to a predetermined size, and the sorbent is dissolved by treating the cut outer shell with a washing solvent by treating it with a washing solvent. Only the pure polyethylene resin is removed, and the resin is chipped and recycled through an extruder, and the used cleaning solvent is recovered and recycled through a solvent recovery process. It was made to be recycled.

Description

용제를 이용한 폐통신케이블의 폴리에치렌 수지 재활용처리방법{Method for reusing the polyethylene rosin of waste cable by solvent.}Method for reusing the polyethylene rosin of waste cable by solvent.

본 발명은 폐통신 케이블을 수거한 다음 통신케이블의 외피를 구성하는 폴리에치렌수지만을 분리수거하여 재활용할 수 있도록 한 용제를 이용한 폐통신 케이블의 폴리에치렌수지 재활용처리방법에 관한 것이다.The present invention relates to a method for recycling polyethylene resin in a waste communication cable using a solvent that collects waste communication cables and then separately collects and recycles only the polyethylene resin forming the outer shell of the communication cable.

통신케이블의 구성은 다음과 같이 구성되어 있다.The communication cable consists of the following:

내면중심에 여러가닥의 코팅구리전선이 있고, 그 외면에 종이테이프, 철이나 알미늄으로된 튜브, 핏지(콜탈), 그리고 폴리에치렌수지의 순서로 피복되어 있다.There are several strands of coated copper wire in the inner center, and the outer surface is covered with paper tape, iron or aluminum tube, pit paper (coltal), and polyethylene resin.

이때 외피에 피복되는 폴리에치렌수지는 노화방지, 자외선방지등의 고가의 물성이 배합되어 있어 재활용화는 매우 부가가치가 높은 재료가 된다.At this time, the poly ethylene resin coated on the outer skin is compounded with expensive physical properties such as anti-aging and anti-ultraviolet, and the recycling becomes a very high value-added material.

그러나 현재 폐통신 케이블에 피복된 폴리에치렌수지를 분리수거하여 재활용하는 방법은 분리수거시 외피층인 폴리에치렌만의 분리수거가 불가능하고, 내면에 접합된 핏지가 불순물로 혼입되므로 저급화 재료가 되고 있어 재활용에 어려움이 있는 것이었다.However, currently, the method of separating and recycling poly ethylene resin coated on the waste communication cable is impossible to separate and collect only the poly ethylene layer, which is the outer layer during the separate collection. There was a difficulty in recycling.

본 발명은 이러한 종래의 단점을 시정하고자 폐통신케이블로부터 핏지(콜탈)가 접합된 폴리에치렌 피복재를 분리수거한 다음 폴리에치렌 피복수지에 접합된 핏지를 세척 제거하여 고품질의 폴리에치렌 수지만을 수거 재활용할 수 있도록 한 것이다.The present invention is to remove the poly ethylene coating material bonded to the pit (coltal) is bonded from the waste communication cable to correct the conventional disadvantages, and then to remove the filtration paper bonded to the poly ethylene coating resin to remove the high quality poly ethylene resin To collect and recycle.

상기 목적을 달성하기 위하여 본 발명은 핏지가 접합된 폴리에치렌 수지 외피를 수거한 다음 핏지만 용해되는 용제를 이용하여 세척함으로써 핏지는 용해 제거되고, 폴리에치렌 수지만 잔존하게 한 다음 압출, 칩화하여 재활용케 하고, 세척용제는 증발 회수하여 재사용케 하고, 잔존하는 핏지는 또 다른 용도로 재활용되게 하는 것이다.In order to achieve the above object, the present invention collects the polyetchene resin sheath to which the pitch is bonded and then washes with a solvent that dissolves the pit but dissolves the leach, leaving only the poly ethylene resin and then extruding and chipping. It is recycled, and the cleaning solvent is evaporated, recovered and reused, and the remaining filtration is recycled for another use.

도 1 : 본 발명 공정의 개략구성도.1 is a schematic diagram of a process of the present invention.

도 2 : 도1의 공정구성일부를 확대한 도면.2 is an enlarged view of a part of the process configuration of FIG. 1;

도 3 : 도1의 공정구성일부를 확대한 도면.3 is an enlarged view of a part of the process configuration of FIG. 1;

<도면의 주요부분에 대한 부호의 설명><Description of the symbols for the main parts of the drawings>

(2)--수집통 (6)--펌프(2)-basket (6)-pump

(8)--콘베어 (10)--분쇄기(8)-Conveyor (10)-Crusher

(12)--송풍기 (14)--분리기(12)-Blower (14)-Separator

(16)--분쇄재료통 (20)--가고차(16)-Pulverizer (20)-Garage

(22)--세척탱크 (24)--증발기(22)-Wash Tank (24)-Evaporator

(26)--저장통 (28)--공급관(26)-Reservoir (28)-Supply Line

(30)--응축기 (32)--레시버탱크(30)-Condenser (32)-Receiver Tank

(34)--압출기 (36)--필타프레스여과기(34)-Extruder (36)-Pilta Press Filter

(44)--용제저장탱크 (46)--진공펌프(44)-Solvent Storage Tanks (46)-Vacuum Pumps

(48)--제1혼합탑 (50)--제2혼합탑(48)-First Mixing Tower (50)-Second Mixing Tower

(52)(54)--순환펌프 (56)--증류기(52) (54)-Circulation Pump (56)-Distillers

(58)--보일러 (60)--응축기(58)-Boiler (60)-Condenser

이하 본 발명의 실시예를 첨부도면에 따라 공정별로 상세히 설명하면 다음과 같다.Hereinafter, an embodiment of the present invention will be described in detail by process according to the accompanying drawings.

도1은 본 발명 공정도이고, 도2 및 도3은 도1공정도를 확대 도시한 상태로서, 본 발명의 공정을 크게 분류하면 폐통신 케이블의 절단 및 용제를 이용한 세척공정과, 용제 회수공정으로 크게 분류할 수 있고, 상기 각 공정을 상세히 설명하면 다음과 같다.Figure 1 is a process diagram of the present invention, Figures 2 and 3 is an enlarged view of the process diagram of Figure 1, the process of the present invention is largely divided into a cutting process of the waste communication cable and the cleaning process using a solvent, and a solvent recovery process If it can be classified, each process will be described in detail as follows.

제1공정 : 절단 및 세척공정Step 1: Cutting and Washing Process

본 공정은 폐통신 케이블로부터 분리한 외피를 일정한 길이로 절단함과 동시에 내면에 접합된 핏지를 제거하는 공정으로서, 핏지(콜탈)가 접합된 재활용 폴리에치렌 수지외피를 수집통(2)에 저장하고, 수집통(2)에 저장된 폴리에치렌 수지외피를 콘베어(8)를 통하여 분쇄기(10)로 공급하여 일정한 크기로 절단한 다음 송풍기(12)를 이용하여 싸이크론 분리기(14)로 이송하고, 싸이크론 분리기(14)를 통하여 절단된 폴리에치렌 수지 외피를 재료통(16)에 저장되게 한다.This process is to cut the sheath separated from the waste communication cable to a certain length and to remove the puddle bonded to the inner surface, and to store the recycled polyethylene resin sheath bonded to the pulp (coltal) in the collecting container (2). Then, the polyethylene resin sheath stored in the collecting container (2) is fed to the grinder (10) through a conveyor (8), cut into a predetermined size, and then transferred to a cyclone separator (14) using a blower (12). The polyethylene resin sheath cut through the cyclone separator 14 is stored in the material container 16.

재료통(16)에 저장된 절단재료, 즉 폴리에치렌수지 외피 약1kg을 가고차(20)에 싣고, 세척탱크(22)내에 투입한 다음 외피에 잔류하는 이물질을 용제 처리함으로써 외피가 깨끗하게 세척되게 함과 동시에 외피에 접합된 핏지도 함께 용해 제거시킨다.The cut material stored in the material container 16, that is, about 1 kg of polyethylene resin shell, was loaded on the Gacha 20, put into the washing tank 22, and the foreign matter remaining in the shell was solvent-treated to clean the outer shell. At the same time, the pit attached to the skin is also dissolved.

이때 사용되는 유기용제의 량은 약 1ℓ정도이고, 상용성이 우수한 용제를 사용함과 동시에 비등점차이 분리가 용이한 용제, 즉 톨루엔이나 제3염화 에치렌 혹은 제4염화 에치렌 등을 사용하는 것이 이상적이다.At this time, the amount of organic solvent used is about 1 L, and it is ideal to use a solvent having excellent compatibility and easy separation of boiling point difference, that is, toluene, tertiary ethylene ethylene or tertiary ethylene ethylene. to be.

세척텡크(22)의 형태로서는 일정한 용적을 갖는 가로형 개폐식탱크로서 탱크내에 레일, 가고차, 가열장치, 가고운동장치를 부착 설치하고, 세척완료된 후 증발기(24)로 액이송, 진공감압배기, 건조개방후 핏지가 용해제거된 순수한 폴리에치렌수지 외피만을 얻어낸다.The washing tank 22 is a horizontal type tank having a constant volume. The tank is equipped with a rail, a car, a heating device, and a moving device. After opening, only the pure polyethylene resin shell obtained by dissolving pit paper is obtained.

상기에서 얻어진 순수 폴리에치렌수지 외피는 별도의 저장통(26)에 저장 시켰다가 압출기(34)를 통하여 칩화한 다음 재활용하게 되고, 세척탱크에 발생한 세척용제는 공급관(28)을 통하여 증발기(24)로 이송공급되어 증발회수공정을 통하여 회수 재사용된다.The pure polyethylene resin shell thus obtained is stored in a separate storage container 26, chipped through an extruder 34, and then recycled. The cleaning solvent generated in the cleaning tank is evaporator 24 through the supply pipe 28. It is fed to the feedstock, and is recovered and reused through the evaporation recovery process.

제1공정에서 사용된 세척용제나 용해된 핏지 및 이물질등을 증발기(24)를 통하여 세척용제와 혼합 이물질로 분리한 다음 용제는 재활용하고 혼합 이물질을 잔사와 핏지로 분리하는 공정이다.The washing solvent used in the first step or the dissolved filtration and foreign matter is separated into the cleaning solvent and mixed foreign matter through the evaporator 24, and then the solvent is recycled and the mixed foreign matter is separated into residue and pit paper.

좀더 상세하게 설명하면 공급관(28)을 통하여 이물질을 함유한 세척용제가 감압상태를 유지하는 증발기(24)내로 분사되게 하면, 세척용제는 기화되어 응축기(30)로 공급되고, 응축기(30)로 공급된 기체화된 용제가스는 냉각 응축되어 레시버탱크 (32)로 수집된다.More specifically, if the cleaning solvent containing foreign matter is injected into the evaporator 24 to maintain the reduced pressure through the supply pipe 28, the cleaning solvent is vaporized and supplied to the condenser 30, the condenser 30 The gasified solvent gas supplied is cooled and condensed and collected in the receiver tank 32.

증발기(24)내에는 교반기(25)가 설치되어 있어 세척용제의 기화를 촉진시키게 될뿐 아니라 거의 완전한 용제 재활용을 기대할 수 있다.In the evaporator 24, a stirrer 25 is installed, which not only promotes vaporization of the washing solvent, but also can expect almost complete solvent recycling.

상기에서 세척용제가 기화 배기되고 나면 증발기(24) 내에는 핏지와 이물질이 잔류하게 되고, 상기 잔류혼합물을 냉각시킨 다음 필타프레스 여과기(36)를 통하여 핏지나 이물질을 분리시키고, 분리된 핏지는 재활용하게 된다.After the cleaning solvent is vaporized and exhausted in the evaporator 24, the pit and foreign matter remains, the residual mixture is cooled and then separated the pit or foreign matter through the filter filter 36, the separated filtration is recycled Done.

레시버탱크(32)에 응축된 세척용제는 용제저장탱크(44)에 저장되었다가 다시 제1공정에서 설치된 세척탱크(22)로 공급되어 재활용하게 되고, 응축기(30)에서 미응축된 잔류세척용제와 소량의 수분은 다시 진공펌프(46)를 통하여 용제 재회수장치로 공급되어 재응축되게 함으로써 용제의 회수효율을 증진시킴과 동시에 불응축가스나 수분만 외부로 배기되게 하여 대기오염을 최소화 하게 된다.The washing solvent condensed in the receiver tank 32 is stored in the solvent storage tank 44 and then supplied to the washing tank 22 installed in the first process for recycling, and the remaining condensation in the condenser 30 is not washed. The solvent and a small amount of water are supplied to the solvent reclaimer through the vacuum pump 46 to be recondensed to enhance the recovery efficiency of the solvent and to exhaust only non-condensable gas or moisture to the outside to minimize air pollution. .

용제 재회수장치는 본인이 선출원한(특허출원제94-40779호 '용제를 이용한 염화비닐 폐전선의 회수처리방법')내용에 기재된 회수장치와 동일하나 한번 더 개략적으로 설명하면 다음과 같다.Solvent recovery device is the same as the recovery device described in the contents of the application filed by the applicant (Patent Application No. 94-40779, 'Recovery Treatment Method for Waste Vinyl Chloride Using Solvent').

즉 레시버탱크(32)에서 미응축된 수분이나 가스가 제1,2혼합탑(48)(50)으로 공급되면 제1,2혼합탑(48)(50)하단 일측에 구성된 순환펌프(52)(54)로 흡입되고, 순환펌프(52)(54)에 흡입된 가스는 유제와 혼합액화되어 혼합액이 되고, 상기 혼합액 중 일부는 증류기(56)로 공급되고, 나머지는 제1,2혼합탑으로 공급분사되는 작동을 연속반복하게 된다.That is, when water or gas that is not condensed in the receiver tank 32 is supplied to the first and second mixing towers 48 and 50, the circulation pump 52 configured at one side of the lower ends of the first and second mixing towers 48 and 50. (54), the gas sucked into the circulating pumps (52) and (54) is mixed with the emulsion to form a mixed liquid, some of the mixed liquid is supplied to the distiller 56, the remainder of the first and second mixture The operation of supply injection to the tower is repeated continuously.

상기에서 증류기(56)로 공급된 혼합액은 보일러(58)의 열원에 의해 가열된 증류기(56)내에서 용제는 다시 기화되어 응축기(60)로 이송되고, 응축기(60)로 이송된 용제가스는 응축액화되어 용제저장탱크(44)로 공급되어 세척용제의 회수율을 최대로 높이게 된다.The mixed liquid supplied to the distillation unit 56 is vaporized in the distillation unit 56 heated by the heat source of the boiler 58 is transferred to the condenser 60, the solvent gas transferred to the condenser 60 is Condensation is liquefied and supplied to the solvent storage tank 44 to maximize the recovery rate of the cleaning solvent.

미 설명부호 (70)은 벙커C유 저장탱크, (72)는 써비스탱크, (74)는 팽창탱크, (76)은 열매저장탱크이다.Reference numeral 70 is a bunker C oil storage tank, 72 is a service tank, 74 is an expansion tank, and 76 is a fruit storage tank.

이상 설명한 바와 같이 통신케이블로부터 분리 수거한 외피를 일정크기로 절단한 다음 세척용제를 이용하여 폴리에치렌수지 외피의 내면에 접합된 핏지(콜탈)을 용해 제거시켜 순수한 폴리에치렌 수지만을 얻어낸 다음 압출기를 통하여 칩화하여 재활용케 하고, 세척공정에서 발생한 이물질을 혼합한 세척용제는 용제회수공정을 통하여 세척용제만 분리회수 한 다음 재사용케하고, 세척용제가 분리 추출된 혼합물은 다시 필타프레스여과기를 이용하여 압착 함으로써 핏지와 이물질을 분리수거하여 핏지는 재활용하고, 이물질은 폐기처분 함으로써 본 발명이 완성된다.As described above, the outer sheath separated from the communication cable is cut to a certain size, and then, using a cleaning solvent, dissolving and removing the spigot (coltal) bonded to the inner surface of the polyethylene resin sheath to obtain pure polyethylene resin. Chips are recycled through an extruder, and the cleaning solvent mixed with foreign substances generated in the washing process is recovered and reused only after the solvent is recovered through the solvent recovery process. The present invention is completed by separating and collecting pit paper and foreign matters by squeezing and recycling the pit paper and discarding the foreign matters.

따라서 본 발명은 다량으로 발생하는 폐통신 케이블로부터 고품질의 폴리에치렌 수지만을 수거하여 재활용케하므로 자원재활용차원에서 매우 유리할 뿐 아니라 세척공정에서 사용한 세척용제 역시 용제회수공정을 통하여 수거 재활용케 함으로써 처리비용 및 환경오염을 줄일 수 있게 되는 등의 효과가 있는 것이다.Therefore, the present invention collects and recycles only high-quality poly ethylene resin from waste communication cables generated in large quantities, which is very advantageous in terms of resource recycling, and the cleaning solvent used in the washing process is also collected and recycled through the solvent recovery process. It is effective in reducing costs and environmental pollution.

Claims (1)

폐통신 케이블로부터 핏지가 접합된 폴리에치렌수지 외피를 분리한 다음 분쇄기(10)로 일정한 크기로 절단하고, 절단된 외피를 세척탱크(22)내에 투입한 다음 핏지가 용해되는 세척용제로 세척하여 외피에 접합된 핏지를 용해 제거되게 함으로써 순수한 폴리에치렌 수지외피만을 얻고, 상기 폴리에치렌수지 외피는 압출기(34)를 통하여 칩화한 다음 재활용케 하고, 세척용제는 증발기(24)로 이송시킨 다음 증발기(24)내에서 세척용제는 기화되게 하고, 기화된 세척용제는 응축액화시켜 재활용케 하고, 잔류하는 핏지와 이물질은 냉각시킨 다음 필타프레스 여과기(36)로 처리하여 핏지와 이물질로 분리시키는 것을 특징으로 하는 용제를 이용한 폐통신 케이블의 폴리에치렌수지 재활용 처리방법.Separating the polyetchene resin sheath to which the pit is bonded from the waste communication cable, and cut into a certain size with a grinder (10), the cut outer shell is put into the washing tank 22 and washed with a washing solvent in which the pit is dissolved Only the pure polyethylene resin shell is obtained by dissolving and removing the pit paper bonded to the shell, and the polyethylene resin shell is chipped through an extruder 34 and then recycled, and the cleaning solvent is transferred to the evaporator 24. In the evaporator 24, the cleaning solvent is vaporized, the vaporized cleaning solvent is condensed and recycled, and the remaining filter paper and foreign matter is cooled and then treated with a filter press filter 36 to separate the blood and foreign material. A method for recycling polyethylene resin in waste communication cables using a solvent.
KR1019990059304A 1999-12-20 1999-12-20 Method for reusing the polyethylene rosin of waste cable by solvent. KR100331604B1 (en)

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KR910007451A (en) * 1989-10-10 1991-05-30 이종남 Manufacturing method of emulsion composition for mayonnaise
JPH06297459A (en) * 1992-09-24 1994-10-25 Masakazu Abe Regenerating method of waste agricultural polyvinyl chloride and device thereof
KR0137898B1 (en) * 1994-11-07 1998-05-01 이종열 Reclamation device using vinyl film
KR19990068471A (en) * 1999-05-24 1999-09-06 황순창 The aparatus and method of wire for plastics colleciton

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR910007451A (en) * 1989-10-10 1991-05-30 이종남 Manufacturing method of emulsion composition for mayonnaise
JPH06297459A (en) * 1992-09-24 1994-10-25 Masakazu Abe Regenerating method of waste agricultural polyvinyl chloride and device thereof
KR0137898B1 (en) * 1994-11-07 1998-05-01 이종열 Reclamation device using vinyl film
KR19990068471A (en) * 1999-05-24 1999-09-06 황순창 The aparatus and method of wire for plastics colleciton

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