KR100330512B1 - Animal protein fiber having affinity for skin - Google Patents
Animal protein fiber having affinity for skin Download PDFInfo
- Publication number
- KR100330512B1 KR100330512B1 KR1020000036926A KR20000036926A KR100330512B1 KR 100330512 B1 KR100330512 B1 KR 100330512B1 KR 1020000036926 A KR1020000036926 A KR 1020000036926A KR 20000036926 A KR20000036926 A KR 20000036926A KR 100330512 B1 KR100330512 B1 KR 100330512B1
- Authority
- KR
- South Korea
- Prior art keywords
- skin
- leather
- protein fiber
- friendly
- animal protein
- Prior art date
Links
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F4/00—Monocomponent artificial filaments or the like of proteins; Manufacture thereof
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2211/00—Protein-based fibres, e.g. animal fibres
- D10B2211/01—Natural animal fibres, e.g. keratin fibres
- D10B2211/06—Collagen fibres
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Treatment And Processing Of Natural Fur Or Leather (AREA)
Abstract
본 발명은 콜라겐과 단백질을 수산화 지르코늄과 규소계 화합물 및 산화 인산염 오일 제제로 축합시킨 피부 친화성 동물성 단백질 섬유에 관한 것이다. 본 발명의 피부 친화성 동물성 단백질 섬유의 섬유 조직은 다음과 같은 분자구조를 갖는다.The present invention relates to skin-friendly animal protein fibers obtained by condensing collagen and protein with zirconium hydroxide, silicon-based compounds and oxidized phosphate oil formulations. The fibrous tissue of the skin-friendly animal protein fibers of the present invention has the following molecular structure.
Description
본 발명은 콜라겐과 단백질을 수산화 지르코늄과 규소계 화합물 및 산화 인산염 오일제제로 축합시킨 피부 친화성 동물성 단백질 섬유에 관한 것이다.The present invention relates to skin-friendly animal protein fibers obtained by condensing collagen and protein with zirconium hydroxide, silicon-based compounds and oxidized phosphate oils.
종래의 동물성 단백질 섬유 조직은 콜라겐과 단백질을 황산화 크롬과 황산화 오일로 축합시킨 것으로 인체에 유해한 중금속과 흡습으로 인한 오염 및 가죽 형체가 변형되는 결점이 있었다. 기존의 가죽 제품은 진녹회색인 크롬으로 인하여 검정색 등 탁색 원단만을 생산할 수 있었고 염색이 불량하여 습하거나 우천시에는 염색물이 빠져나와 와이셔츠 등의 흰옷에 오염될 우려가 있었다. 또한 기존의 가죽 제품은 피부 친화성이 없고 환경 친화적인 가죽원단이 아니며 중금속으로 인하여 가죽의 부산물과 폐기물을 처리하는데도 비용이 많이 든다.Conventional animal protein fiber tissues are condensed with collagen and protein with chromium sulfate and sulfated oil, which has the disadvantages of deterioration of leather shape and contamination due to heavy metals and moisture absorption, which are harmful to the human body. Existing leather products were able to produce only black fabrics such as black due to dark green chromium, and there was a risk of staining due to poor dyeing or staining of white clothes such as shirts when wet. In addition, existing leather products are not skin-friendly and environmentally friendly leather fabrics, and heavy metals are also expensive to treat leather by-products and wastes.
최근 위와 같은 문제를 해결하고자 황산화 오일 대신 각종 워셔블 및 방수 가지제와 각종 조제된 탄닝제가 나왔으나 값도 비싸고 용도에 적합하지도 않았다.Recently, in order to solve the above problems, various washable and waterproof eggplants and various prepared tanning agents were used instead of sulfated oils, but they were expensive and not suitable for use.
본 발명의 목적은 피부 친화성 오일 및 무공해 세라믹을 이용한 탄닝 공정과가지 공정에서의 축합 반응에 의해 피부 친화성이 향상된 동물성 단백질 섬유조직을 제공하는 것이다.SUMMARY OF THE INVENTION An object of the present invention is to provide an animal protein fiber tissue having improved skin affinity by a condensation reaction in a tanning process and an eggplant process using skin-friendly oils and pollution-free ceramics.
본 발명은 황산화 오일과 황산화 크롬을 사용한 지금까지의 방법과 달리 무공해 세라믹계인 수산화 지르코늄과 규소 화합물 및 인산염 오일을 사용하는 것으로 이루어진 피부 친화성 섬유를 제공한다. 본 발명의 피부 친화성 섬유는 오일과 무공해 세라믹계인 지르코늄과 규소의 결합, 즉 탄닝 공정과 가지 공정에서 축합반응이 일어나서 완전한 동물성 단백질 섬유조직이 형성되는 것으로 이루어진다.The present invention provides a skin-friendly fiber consisting of using a non-polluting zirconium hydroxide, a silicon compound, and a phosphate oil, which are non-polluting ceramics, unlike conventional methods using sulfated oil and chromium sulfate. The skin-friendly fibers of the present invention consist of the condensation reaction between the oil and the pollution-free ceramic-based zirconium and silicon, that is, the tanning process and the eggplant process, thereby forming a complete animal protein fiber tissue.
본 발명의 가죽제품의 단백질 섬유 조직은 탄닝 공정에서 피부 친화성 무독성 세라믹인 지르코늄과 규소가 결합된 동물성 단백질 섬유조직이 형성되며, 가지 공정에서 산화 인산염 오일제제와 재차 축합반응하여 완전한 피부 친화성 동물성 단백질 섬유조직이 형성된다. 본 발명의 탄닝 공정과 가지 공정은 다음과 같이 실시된다.The protein fiber tissue of the leather product of the present invention forms animal protein fiber tissues in which zirconium and silicon, which are skin-friendly non-toxic ceramics, are combined in the tanning process, and are condensed again with oxidized phosphate oil in the eggplant process to completely skin-friendly animal nature. Protein fibrous tissue is formed. The tanning process and the branch process of the present invention are carried out as follows.
지르코늄 탄닝을 드럼내의 가죽과 물의 비율을 1:1로 하여 실시한다. 그 물에 염화나트륨을 투입하여 염도를 12 보오메로 맞추고 산을 첨가하여 pH를 1.0으로 맞춘다. 그 후, 지르코늄을 투입한 다음 10 시간에 걸쳐 규소 화합물을 사용하여 최종 pH를 3.5로 조절한다. -OH기가 증가하여 단백질 섬유의 카르복실산과 지르코늄과 규소 화합물과 축합 반응하여 단백질 섬유가 되고 그 후에 산성도를 pH 3.5 에서 pH 6.0으로 중화 염색한다. 그 후, 산화 인산염 오일을 투입하고 중화시 pH를 6.0에서 4 ~ 5시간에 걸쳐 최종 pH를 4.0으로 조절함으로써 지르코늄 단백질 섬유의 Zr-OH와 산화 인산염 오일 P-OH의 축합반응이 일어난 후 건조하여 청정 가죽을 제조한다.Zirconium tanning is carried out with a 1: 1 ratio of leather to water in the drum. Sodium chloride is added to the water, the salinity is adjusted to 12 boomeres, and acid is added to adjust the pH to 1.0. Thereafter, zirconium is added and the final pH is adjusted to 3.5 using a silicon compound over 10 hours. The -OH group is increased to condense the carboxylic acid, zirconium, and silicon compound of the protein fiber to become a protein fiber, and then neutralize and dye the acidity from pH 3.5 to pH 6.0. Thereafter, oxidized phosphate oil was added and the pH was neutralized at 6.0 to adjust the final pH to 4.0 over 4 to 5 hours, followed by condensation of Zr-OH of the zirconium protein fiber and oxidized phosphate oil P-OH, followed by drying. Manufactures clean leather.
본 발명에 사용되는 산화 인산염 오일은 에틸렌 옥사이드계로 반응된 산화 인산염 오일 또는 일반 알콜계로 반응된 산화 인산염 오일이 사용된다. 예를 들어 본 발명에서 사용된 산화 인산염 오일은 다음과 같이 제조되었다.As the oxidized phosphate oil used in the present invention, oxidized phosphate oil reacted with ethylene oxide or oxidized phosphate oil reacted with general alcohol is used. For example, the oxidized phosphate oil used in the present invention was prepared as follows.
알콜 탄화수소계를 80 ℃로 용해된 질소가스 용기에 당량으로 알콜계와 산화 인산계를 4:1로 혼합하고 2시간에 걸쳐 축합반응을 실시한다. 그 후, 수산화나트륨으로 중화하여 산성도를 pH 6 ~ 7로 맞춘다. 산화 인산염 오일에 1:1의 비율로 물을 첨가하여 산화 인산화 오일을 완성한다.The alcohol-hydrocarbon system is mixed in a nitrogen gas container dissolved at 80 ° C. in an equivalent amount, and the alcohol-based and phosphoric-acid-based compounds are mixed at 4: 1 and condensation reaction is carried out over 2 hours. Then, neutralize with sodium hydroxide to adjust the acidity to pH 6-7. Oxidized phosphate oil is added in a ratio of 1: 1 to complete the oxidized phosphate oil.
피부 친화성 동물성 단백질 섬유 조직은 사용되는 산화 인산염 오일제제의 종류에 따라 다음과 같은 분자구조를 갖는 2 종류로 형성된다.Skin-friendly animal protein fiber tissues are formed into two types having the following molecular structure depending on the type of oxidized phosphate oil formulation used.
첫째, 에틸렌 옥사이드계로 반응된 산화 인산염 오일제제인 경우에는 다음과 같이 축합반응이 일어나고First, in the case of oxidized phosphate oil preparation reacted with ethylene oxide, condensation reaction occurs as follows.
그 결과 다음식의 피부 친화성 동물성 단백질 섬유 조직이 형성된다.As a result, a skin-friendly animal protein fiber tissue of the following formula is formed.
둘째, 일반 알콜계로 반응된 산화 인산염 오일제제의 경우에는 다음과 같은 축합반응이 일어나고,Second, in the case of the oxidized phosphate oil preparation reacted with a general alcohol type, the condensation reaction occurs as follows.
그 결과 다음식의 피부 친화성 동물성 단백질 섬유 조직이 형성된다.As a result, a skin-friendly animal protein fiber tissue of the following formula is formed.
본 발명의 가죽 제품을 기존의 가죽 제품과 비교하여 그 결과를 표 1에 나타내었다.The leather products of the present invention are compared with conventional leather products and the results are shown in Table 1.
본 발명의 동물성 단백질 섬유 조직은 흰색을 비롯한 모든 색의 가죽 원단이 생산 가능하고 세탁 후에도 변하지 않으며 피부 친화성이 향상된 제품이다. 또한 탄닝 공정의 경우 가죽원단의 내열온도가 기존의 80 ℃에서 100 ℃로 향상되었다.The animal protein fiber tissue of the present invention is a product which can produce leather fabrics of all colors including white and does not change even after washing and improves skin affinity. In the tanning process, the heat resistance temperature of the leather fabric was improved from 80 ℃ to 100 ℃.
Claims (2)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR1020000036926A KR100330512B1 (en) | 2000-06-30 | 2000-06-30 | Animal protein fiber having affinity for skin |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR1020000036926A KR100330512B1 (en) | 2000-06-30 | 2000-06-30 | Animal protein fiber having affinity for skin |
Publications (2)
Publication Number | Publication Date |
---|---|
KR20010000148A KR20010000148A (en) | 2001-01-05 |
KR100330512B1 true KR100330512B1 (en) | 2002-04-03 |
Family
ID=19675222
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1020000036926A KR100330512B1 (en) | 2000-06-30 | 2000-06-30 | Animal protein fiber having affinity for skin |
Country Status (1)
Country | Link |
---|---|
KR (1) | KR100330512B1 (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US9403984B2 (en) | 2013-02-28 | 2016-08-02 | Kaneka Corporation | Water-resistant regenerated collagen fiber containing zirconium salt and phosphorus compound, method for producing the same, and fiber bundle for hair containing the same |
-
2000
- 2000-06-30 KR KR1020000036926A patent/KR100330512B1/en not_active IP Right Cessation
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US9403984B2 (en) | 2013-02-28 | 2016-08-02 | Kaneka Corporation | Water-resistant regenerated collagen fiber containing zirconium salt and phosphorus compound, method for producing the same, and fiber bundle for hair containing the same |
Also Published As
Publication number | Publication date |
---|---|
KR20010000148A (en) | 2001-01-05 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
KR19990007624A (en) | How to dye natural dyes | |
GB2217731A (en) | Process for producing semifinished leather goods | |
KR101431990B1 (en) | The characteristics of Gardenia yellow color to textiles in the presence of natural illites | |
WO2012053783A2 (en) | Functional leather and method for manufacturing thereof | |
CN102703619B (en) | A kind of energy saving and environment friendly standard mink skin process for tanning | |
Saleh et al. | Dyeing of cationized cotton fabrics with natural dye extracted from acacia | |
KR20120039808A (en) | Natural dyeing method for ecotextiles | |
He et al. | A natural dye extract from lotus seedpod for dyeability and functional property of tussah silk fabric | |
KR100330512B1 (en) | Animal protein fiber having affinity for skin | |
Gülümser | Comparison between naturally colored cotton fabric and white cotton fabric in manner of processes in the dyehouse | |
CN107828539A (en) | Medical cloth grass cleaning solution | |
KR100194826B1 (en) | Leather modifiers, leather methods and modified tanned leather | |
KR101235547B1 (en) | Method for producing flounder leather used flounder skin | |
KR100352240B1 (en) | A dyeing method of fiber using mugwort | |
KR20100137899A (en) | Method for producing eco-friendly salmon leather used salmon skin and salmon leather produced thereof | |
KR101748005B1 (en) | Dyeing method using Natural dye extracted from Chestnuts shell | |
KR20040000112A (en) | The processing method of natural leather | |
CN116289191A (en) | Tea extract modified silk floss and preparation method thereof | |
EP0711842B1 (en) | Leather tanning agents and actuator for dyes | |
DE1028077B (en) | Stable aqueous solutions of siliconates for waterproofing all kinds of solid objects | |
Onal et al. | Use of fermented dough extract in the dyeing of wool fabrics | |
KR100445639B1 (en) | Method for producing washable dyed leather | |
DE1085492B (en) | Process for improving the grip of organic fiber and film material (A) | |
CN1014801B (en) | The preparation method of goose down skin | |
Madhu et al. | Sustainable environment friendly approach for Psilocybe zapotecorumcolour dyeing integrated with anti-microbial finish |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A201 | Request for examination | ||
G15R | Request for early opening | ||
E701 | Decision to grant or registration of patent right | ||
GRNT | Written decision to grant | ||
FPAY | Annual fee payment |
Payment date: 20060303 Year of fee payment: 5 |
|
LAPS | Lapse due to unpaid annual fee |