KR100325985B1 - hair color composition of matter including a material increasing color penentration - Google Patents

hair color composition of matter including a material increasing color penentration Download PDF

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KR100325985B1
KR100325985B1 KR1020000002294A KR20000002294A KR100325985B1 KR 100325985 B1 KR100325985 B1 KR 100325985B1 KR 1020000002294 A KR1020000002294 A KR 1020000002294A KR 20000002294 A KR20000002294 A KR 20000002294A KR 100325985 B1 KR100325985 B1 KR 100325985B1
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hair
dye
oat
composition
color
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KR1020000002294A
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Korean (ko)
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KR20010078530A (en
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조봉림
신경아
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이긍구
동성제약주식회사
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    • AHUMAN NECESSITIES
    • A41WEARING APPAREL
    • A41BSHIRTS; UNDERWEAR; BABY LINEN; HANDKERCHIEFS
    • A41B13/00Baby linen
    • A41B13/10Bibs
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00Preparations for care of the hair
    • A61Q5/10Preparations for permanently dyeing the hair
    • AHUMAN NECESSITIES
    • A41WEARING APPAREL
    • A41BSHIRTS; UNDERWEAR; BABY LINEN; HANDKERCHIEFS
    • A41B13/00Baby linen
    • A41B13/10Bibs
    • A41B13/103Bibs with a pocket
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34Alcohols
    • A61K8/342Alcohols having more than seven atoms in an unbroken chain
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/64Proteins; Peptides; Derivatives or degradation products thereof
    • A61K8/645Proteins of vegetable origin; Derivatives or degradation products thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/96Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
    • A61K8/97Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
    • A61K8/9783Angiosperms [Magnoliophyta]
    • A61K8/9789Magnoliopsida [dicotyledons]

Abstract

본 발명은 염료 침투증강제를 포함하는 모발염색제 조성물에 관한 것으로, 더욱 자세하게는 귀리단백추출물이 함유되어 있는 모발염색제 조성물에 관한 것이다.The present invention relates to a hair colorant composition comprising a dye penetration enhancer, and more particularly to a hair colorant composition containing oat protein extract.

본 발명의 목적은 종래의 모발 염색제에 귀리단백추출물울 사용하여 염료를 모피질(cortex) 내에 깊숙히 침투시킴으로서 염색된 모발의 퇴색을 방지하고 염색된 색상을 오래 유지하는 모발염색제 조성물을 제공하는데 있다.SUMMARY OF THE INVENTION An object of the present invention is to provide a hair dye composition which prevents fading of dyed hair and maintains dyed color by penetrating the dye deeply into the cortex by using oat protein extract in a conventional hair dye.

본 발명의 모발염색제 조성물은 귀리단백추출물을 조성물 전체 중량 대비 0.1∼10.0%가 배합됨을 특징으로 한다.The hair dye composition of the present invention is characterized in that the oat protein extract is formulated with 0.1 to 10.0% of the total weight of the composition.

Description

염료 침투 증강제를 포함하는 모발염색제 조성물{hair color composition of matter including a material increasing color penentration}Hair color composition of matter including a material increasing color penentration}

본 발명은 염료 침투 증강제를 포함하는 염색제 조성물에 관한 것으로 더욱 자세하게는 통상의 염색제 조성물에 염료의 모발 침투 증강제로 귀리단백추출물을 사용하여 염료를 모피질(cortex) 층에 깊숙히 침투시켜 색상 발현이 우수하고 퇴색속도를 지연시켜 염색된 색상을 오래 유지하는 염색제 조성물에 관한 것이다.The present invention relates to a dye composition comprising a dye penetration enhancer, and more particularly, using an oat protein extract as a hair penetration enhancer of a dye in a conventional dye composition to penetrate the dye deep into the cortex layer to excellent color expression. And it relates to a dye composition for maintaining the dyed color for a long time by delaying the fading rate.

일반적으로 모발염색은 노화한 흰머리를 원래의 색으로 되찾고자 할 때, 원래의 모발색을 보다 매력적인 색조,명암으로 바꾸고자 할 때, 염색실시후 원래의 자연색을 되찾고자 할 때 실시한다.In general, hair dyeing is performed to restore the aged hair to its original color, to change the original hair color to a more attractive color tone and contrast, and to restore the original natural color after dyeing.

모발의 염색은 크게 3가지 종류로 나눌수 있는데, 일시적 염색, 반영구적 염색 그리고 영구적 염색이다. 이러한 분류는 일차적으로 염료가 모발에 정착(fastness)되는 정도에 따른 것이다.Hair dyeing can be divided into three types: temporary dyeing, semi-permanent dyeing and permanent dyeing. This classification is primarily based on the degree to which the dye fastens to the hair.

본 발명이 속하는 영구적 염색제는 색소가 모표피(cuticle)를 침투하여 모피질(cortex) 안에 색소 분자를 침전시키도록 만들어졌다. 침투와 산화제의 추가작용에 의해 이들 염색제는 탈색도 시키고 착색도 시킨다.Permanent dyeing agents to which the present invention pertains are made so that the pigment penetrates the cuticle and precipitates pigment molecules in the cortex. By penetrating and adding the oxidant, these dyes decolorize and color.

영구적 모발염색은 식물성 염료, 금속성 염료, 혼합성 염료, 산화성 염료(유기합성 염료)로 나눈다. 현재 가장 많이 쓰이는 것은 산화형 염료로 본 발명있어서도 산화형 염료를 이용한다.Permanent hair dye is divided into vegetable dyes, metallic dyes, mixed dyes and oxidative dyes (organic dyes). At present, the most commonly used oxidative dye is also used in the present invention.

산화성 염료(oxidation tints)는 아닐린(aniline)에서 유도된 염료, 합성 유기체 염료, 그리고 아미노 염료(aminotint)라고도 알려져 있다. 이것은 영구적 모발 염색의 방법으로 잘 알려져 있다. 처음 개발이 시작된 이래 지속적으로 개발되어 현재 약 60,000가지 이상의 색조를 만들 수 있다.Oxidation tints are also known as aniline-derived dyes, synthetic organic dyes, and aminotints. This is well known as a method of permanent hair dyeing. Since its inception, it has been continuously developed and can now produce more than 60,000 shades.

산화성 염색제는 알칼리제와 산화제로 구성되어 있다.Oxidative dyes are composed of alkali and oxidizing agents.

암모니아(ammonia)와 모노에탄올아민(monoethanol amine)등이 주로 사용되는 알칼리제는 모간을 부풀리고 작은 염료가 모간 표모피 (cuticle)을 통하여 모피질(cortex) 안에 정착하는 것을 도우며 산화제의 과산화물에 의해 생성된 산소분자와 함께 반응하기 시작한다.Alkali, which is mainly used as ammonia and monoethanol amine, swells the hair shaft and helps small dyes settle in the cortex through the hair cuticle and is produced by the peroxide of the oxidant. It starts to react with oxygen molecules.

상기 일칼리성 염색제는 염료의 모발 침투를 용이하게 하기 위하여 암모니아 또는 모노에탄올아민 등 강한 알칼리제로 모발을 팽윤시켜 염료를 모발의 모피질 속으로 침투시키는데 이 염료가 균질하고 깊숙히 침투되지 않아 퇴색시 얼룩이 지는 등의 문제점이 있다.The monochromic dye swells the hair with a strong alkaline agent such as ammonia or monoethanolamine to facilitate the penetration of the dye into the hair and penetrates the dye into the hair of the hair. There is a problem such as losing.

본 발명은 상기 문제점을 해결하기 위하여 염료침투증강재로 귀리추출단백질을 사용하여 염료를 모발의 모피질(cortex)내로 깊이 균질하게 침투시킴으로써, 退色이 적고 색상 발현이 우수한 염색제를 제조한다. 하나의 예로 본 발명의 염색제는 스테아릴알콜( stearyl alcohol)과 세탄올(cetyl alcohol)과 올레일알콜(oleyl alcohol)등으로 이루어진 지방알코올 2.0∼25.0%와, 폴리옥시에칠렌 세틸에텔(polyoxyethylene cetylether) 등으로 이루어진 계면활성제 0.5∼20.0%와, P-아미노페놀(P-aminophenol)과 P-아미노-o-크레졸(p-amino-ocresol)과, o-아미노페놀(o-aminophenol)과, 레소르신(resorcine)과, 황산톨루엔2,5디아민(toluene2,5diamine sulfate)등으로 이루어진 산화염료중간체 0.1∼10.0% 및 정제수 등을 포함하는 원료에 귀리 단백추출물을 추가로 배합하는 방법에 의하여 크림상의 염색제 칼라베이스를 제조한다. 산화제는 35.0%의 과산화수소를 사용하여 통상적인 산화제를 사용하였다.The present invention to solve the above problems by using the oat extraction protein as a dye penetrant enhancer deeply and uniformly penetrates the dye into the cortex of the hair, thereby producing a dye with less color and excellent color expression. As an example, the dyeing agent of the present invention is 2.0 to 25.0% fatty alcohol consisting of stearyl alcohol (cetyl alcohol) and cetanol (cetyl alcohol) and oleyl alcohol, and polyoxyethylene cetylether (polyoxyethylene cetylether) 0.5 to 20.0% of surfactant, P-aminophenol, P-amino-o-cresol, o-aminophenol, and resor Creamy coloring agent by the method of additionally combining oat protein extract with a raw material containing 0.1-10.0% of an oxidized dye intermediate composed of resorcine, toluene 2,5 diamine sulfate, purified water, and the like. Manufacture a color base. The oxidant used a conventional oxidant with 35.0% hydrogen peroxide.

따라서 본 발명의 목적은 모발의 염색된 색상을 오래 유지하는 모발염색제 조성물을 제공하는데 있다.It is therefore an object of the present invention to provide a hair dye composition which maintains the dyed color of the hair for a long time.

도 1, 도 2는 본 발명의 모발염색제 조성물의 제조방법을 설명하기 위한 공정도이고,1 and 2 is a process chart for explaining the manufacturing method of the hair dye composition of the present invention,

도 3a는 종래의 모발염색제를 이용하여 모발을 염색하였을 때 모발에 염료가 침투한 상태를 나타내는 상태확대도이고,Figure 3a is an enlarged state showing the state where the dye penetrates the hair when the hair is dyed using a conventional hair dye,

도 3b는 본 발명의 모발염색제를 이용하여 모발을 염색하였을 때 모발에 염료가 침투한 상태를 나타내는 상태확대도이다.Figure 3b is an enlarged state showing a state in which the dye penetrates the hair when the hair dye using the hair dye of the present invention.

본 발명의 모발염색제 조성물은 산화형 염료 (oxidation tints)를 사용하는 영구염색제 조성물에 있어서, 귀리단백추출물을 조성물 전체 중량 대비 0.1∼10.0%가 배합됨을 특징으로 한다.The hair colorant composition of the present invention is characterized in that in the permanent colorant composition using oxidation dyes (oxidation tints), the oat protein extract is 0.1 to 10.0% of the total weight of the composition.

특히, 상기 귀리단백추출물은 귀리추출물 (CTFA Name ; OAT EXTRACT), 귀리분말 (CTFA Name ; OAT FLOUR), 오트밀추출물 (CTFA Name ; OATMEAL EXTRACT), 귀리단백 (CTFA Name ; OAT PROTEIN), 귀리전분 (CTFA Name ; OAT STARCH)을 포함하는 분말 및 액상의 원료로 이루어진다.In particular, the oat protein extract may be oat extract (CTFA Name; OAT EXTRACT), oat powder (CTFA Name; OAT FLOUR), oatmeal extract (CTFA Name; OATMEAL EXTRACT), oat protein (CTFA Name; OAT PROTEIN), oat starch ( It consists of powder and liquid raw materials containing CTFA Name (OAT STARCH).

상기와 같은 특징을 갖는 본 발명의 모발염색제 조성물에 있어서, 염료 침투 증강제로 사용한 귀리단백추출물은 손상되거나 거칠은 피부에 대한 외용제로 유아 및 성인 모두에게 목욕제, 로션 및 노인병 치료를 위한 찜질용으로 꾸준히 이용되어 왔다. 귀리추출단백질의 단백질 함량은 13.0%∼50.0%까지의 범위가 있으며, 그 형태도 분말, 액상 등 다양하게 있다.In the hair dye composition of the present invention having the above characteristics, the oat protein extract used as a dye penetration enhancer is a topical agent for damaged or rough skin, and is steadily used for the treatment of baths, lotions and geriatrics for both infants and adults. Has been used. The protein content of oat extract protein is in the range of 13.0% to 50.0%, and the form is also varied in powder, liquid and the like.

본 발명은 염료 침투 증강제로 귀리추출단백질을 사용하여 염료를 모발의 모피질(cortex)내로 깊이 균질하게 침투시킴으로서 종래의 염색제와 비교, 퇴색이 적고 색상 발현이 우수한 염색제를 제조하였다.The present invention uses a oat extract protein as a dye penetration enhancer to infiltrate the dye deeply and homogeneously into the cortex of the hair to prepare a dye having less color fading and excellent color expression as compared with a conventional dye.

실시예 1Example 1

도 1의 공정도에서와 같이 스테아릴알콜( stearyl alcohol)과 세탄올(cetyl alcohol)과 올레일알콜(oleyl alcohol)등으로 이루어진 지방알코올 2.0∼25.0%와, 폴리옥시에칠렌 세틸에텔(polyoxyethylene cetylether) 등으로 이루어진 계면활성제 0.5∼20.0%를 75℃∼85℃에서 용해하고, P-아미노페놀(P-aminophenol)과 P-아미노-o-크레졸(p-amino-ocresol)과, o-아미노페놀(o-aminophenol)과, 레소르신(resorcine)과, 황산톨루엔2,5디아민(toluene2,5diamine sulfate)등으로 이루어진 산화염료중간체 0.1∼10.0%와 정제수를 혼합하여 용해한다. 상기 용해된 물질을 충분히 교반한 후 그 교반물을 50℃∼60℃로 냉각시킨 후 귀리단백추출물을 추가로 배합교반하여 크림상의 염색제 칼라베이스를 제조하였다.본 실시예의 크림狀의 염색제 칼라베이스의 바람직한 예는 계면 활성제인 폴리옥시에칠렌 세틸에텔(polyoxyethylene cetylether) 12.00%와,지방알콜인 스테아릴알콜( stearyl alcohol) 4.00%, 세탄올(cetyl alcohol) 2.00%, 올레일알콜(oleyl alcohol) 7.00%와,모발보호제인 염화스테아릴트리메칠암모늄(stearyltrimethyl ammonium chloride) 3.57%와,항상화제인 치오글리콜산 (thioglycolic acid) 0.30%와,모발 팽창제인 모노에탄올아민(monoethanol amine) 4.00%, 강암모니아수(strong ammonia water) 4.00%와,염료 침투 증강제인 귀리추출물(oat protein) 1.00%와,색소인 P-아미노페놀(P-aminophenol) 0.59%, P-아미노-o-크레졸(p-amino-ocresol) 0.25%, o-아미노페놀(o-aminophenol) 0.10%, 레소르신(resorcine)0.20%,황산톨루엔2,5디아민(toluene2,5diamine sulfate) 0.38%와,정제수 60.61%의 중량 비율로 조성하였다.As shown in the process diagram of FIG. 1, fatty alcohols consisting of stearyl alcohol, cetanol, ceilol, oleyl alcohol, etc., 2.0 to 25.0%, polyoxyethylene cetyl ether, etc. 0.5-20.0% of the surfactant was dissolved at 75 ° C. to 85 ° C., and P-aminophenol (P-aminophenol), P-amino-o-cresol (p-amino-ocresol), and o-aminophenol (o 0.1 to 10.0% of an oxidized dye intermediate composed of -aminophenol, resorcine, toluene 2,5 diamine sulfate and the like and mixed water are dissolved. After sufficiently stirring the dissolved material, the mixture was cooled to 50 ° C. to 60 ° C., and the oat protein extract was further mixed and stirred to prepare a creamy colorant color base. Preferred examples include 12.00% polyoxyethylene cetylether surfactant, 4.00% stearyl alcohol fatty acid, 2.00% cetyl alcohol, 7.00% oleyl alcohol And, 3.57% of stearyltrimethyl ammonium chloride, a hair protector, 0.30% of thioglycolic acid, and 4.00% of monoethanol amine, a hair swelling agent, and strong ammonia water ( strong ammonia water) 4.00%, oat protein as a dye penetration enhancer, 0.59% as a pigment, P-aminophenol, p-amino-o-cresol (p-amino-ocresol) 0.25%, o-aminophenol 0.10%, resorcine (0.20%), toluene sulfate 2,5 diamine sulfate (0.38%) and purified water 60.61% by weight ratio.

산화제는 35.0%의 과산화수소를 사용하여 통상적인 산화제를 사용하였다.The oxidant used a conventional oxidant with 35.0% hydrogen peroxide.

실시예 2Example 2

도 2의 공정도에서와 같이 폴리옥시에칠렌라우릴에텔황산나트륨액(polyoxyethylene laurylether sodium sulfate solution) 등으로 이루어진 계면활성제 2.0∼25.0%,올레인산(oleic acid)등으로 이루어진 지방산 0.5∼20.0% 및 정제수를 혼합하여 용해하고 교반한다. 前記 교반물에 P-아미노페놀(P-aminophenol)과 P-아미노-o-크레졸(p-amino-ocresol)과, o-아미노페놀(o-aminophenol)과, 레소르신(resorcine)과, 황산톨루엔2,5디아민(toluene2,5diamine sulfate)등으로 이루어진 산화염료중간체 0.1∼10.0%를 용해시켜 재차 교반한 후, 귀리단백추출물을 추가로 배합교반하여 크림상의 염색제 칼라베이스를 제조하였다.본 실시예의 크림상의 염색제 칼라베이스의 바람직한 예는 계면 활성제인 폴리옥시에칠렌라우릴에텔황산나트륨액(polyoxyethylene laurylether sodium sulfate solution) 25.00%와,지방산으로서 점도 조정제인 올레인산(oleic acid) 6.00%와,용해보조제인 프로필렌글리콜(propylene glycol) 6.00%와모발보호제인 염화스테아릴트리메칠암모늄(stearyltrimethyl ammonium chloride) 3.57%와,항상화제인 치오글리콜산 (thioglycolic acid) 0.40%와,모발 팽창제인 모노에탄올아민(monoethanol amine) 4.00%, 강암모니아수(strong ammonia water) 4.00%와,용해보존제인 이소프로필알콜(iso propyl alcohol) 11.00%와,염료 침투 증강제인 귀리추출물(oat protein) 1.00%와,색소인 P-아미노페놀(P-aminophenol) 0.59%, P-아미노-o-크레졸(p-amino-ocresol) 0.25%, o-아미노페놀(o-aminophenol) 0.10%, 레소르신(resorcine)0.20%, 황산톨루엔2,5디아민(toluene2,5diamine sulfate) 0.38%와,정제수 37.51%의 중량 비율로 조성하였다.As shown in the process of FIG. 2, by mixing 2.0-25.0% of a surfactant consisting of polyoxyethylene laurylether sodium sulfate solution, 0.5-20.0% of a fatty acid consisting of oleic acid and the like, and purified water Dissolve and stir. P-aminophenol (P-aminophenol) and P-amino-o-cresol (o-aminophenol), resorcine and sulfuric acid After dissolving 0.1-10.0% of an oxidized dye intermediate composed of toluene 2,5 diamine sulfate and the like again, the oat protein extract was further stirred and mixed to prepare a creamy colorant color base. Preferred examples of the creamy colorant color base are 25.00% of a polyoxyethylene laurylether sodium sulfate solution as a surfactant, 6.00% of an oleic acid as a viscosity modifier and a propylene glycol as a dissolution aid. (propylene glycol) 6.00%, hair protecting agent stearyltrimethyl ammonium chloride, 3.57%, thioglycolic acid (0.40%) and monoethanolamine (monoet) hanol amine) 4.00%, strong ammonia water 4.00%, soluble isopropyl alcohol 11.00%, dye oat protein 1.00% dye penetration enhancer, pigment P- 0.59% P-aminophenol, 0.25% P-amino-o-cresol, 0.10% o-aminophenol, 0.20% resorcine, toluene sulfate 2,5 diamine (toluene 2,5 diamine sulfate) and 0.38% of purified water, the composition ratio of 37.51%.

상기 귀리단백추출물의 모발내 염료 침투 증가 효과를 확인하기 위하여 동일한 처방의 염색제에 귀리단백추출물을 투입하여 염색 후 모발의 단면을 편광현미경(모델명 OLYMPUS BX60, U-SPT, JAPAN ; x500)을 이용하였다.In order to confirm the effect of the oat protein extracts in the hair dye penetration increased by adding the oat protein extract to the dye of the same prescription, the cross-section of the hair after dyeing using a polarizing microscope (model name OLYMPUS BX60, U-SPT, JAPAN; x500) .

귀리추출단백질을 사용하지 않은 종래의 염색제는 도 3a와 같이 염료가 불균일하게 침투하였으나 귀리추출단백질을 사용한 본 발명의 염색제는 도 3b와 같이 염료가 모발의 중앙부분까지 균질하게 침투하였다.Conventional dyes that do not use oat extract proteins are inhomogeneously penetrated as shown in FIG. 3a, but dyes of the present invention using oat extract proteins penetrate homogeneously to the center of hair as shown in FIG. 3b.

본 발명은 모발염색제에 귀리추출단백질을 첨가함으로써, 모발의 모피질(cortex)내로 염료가 깊이 균질하게 침투되도록 하여 퇴색이 적고 색상 발현이 우수한 염색제를 얻을 수 있다.According to the present invention, by adding oat extraction protein to the hair colorant, the dye can penetrate deeply and homogeneously into the cortex of the hair so that a colorant with less discoloration and excellent color expression can be obtained.

Claims (2)

산화형 염료 (oxidation tints)를 사용하는 모발염색제 조성물에 있어서, 귀리단백추출물을 조성물 전체 중량 대비 0.1∼10.0%가 배합됨을 특징으로 하는 모발염색제 조성물.A hair dye composition using oxidative dyes, wherein the oat protein extract comprises 0.1 to 10.0% of the total weight of the composition. 제1항에 있어서, 상기 귀리단백추출물은 귀리추출물 (CTFA Name ; OAT EXTRACT), 귀리분말 (CTFA Name ; OAT FLOUR), 오트밀추출물 (CTFA Name ; OATMEAL EXTRACT), 귀리단백 (CTFA Name ; OAT PROTEIN), 귀리전분 (CTFA Name ; OAT STARCH)을 포함하는 원료로 구성되는 것을 특징으로 하는 모발염색제 조성물.According to claim 1, wherein the oat protein extract is oat extract (CTFA Name; OAT EXTRACT), oat powder (CTFA Name; OAT FLOUR), oatmeal extract (CTFA Name; OATMEAL EXTRACT), oat protein (CTFA Name; OAT PROTEIN) Hair dye composition comprising oat starch (CTFA Name; OAT STARCH) comprising a raw material.
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