KR100318497B1 - Sliding plate refractory for flow controling of molten metal - Google Patents
Sliding plate refractory for flow controling of molten metal Download PDFInfo
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- KR100318497B1 KR100318497B1 KR1019990012816A KR19990012816A KR100318497B1 KR 100318497 B1 KR100318497 B1 KR 100318497B1 KR 1019990012816 A KR1019990012816 A KR 1019990012816A KR 19990012816 A KR19990012816 A KR 19990012816A KR 100318497 B1 KR100318497 B1 KR 100318497B1
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- sliding plate
- refractory material
- molten
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- 229910052751 metal Inorganic materials 0.000 title claims abstract description 15
- 239000002184 metal Substances 0.000 title claims abstract description 15
- 239000011819 refractory material Substances 0.000 claims abstract description 15
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 13
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 11
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 10
- 239000002245 particle Substances 0.000 claims abstract description 10
- 229910018072 Al 2 O 3 Inorganic materials 0.000 claims abstract description 9
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 7
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 7
- 229910052863 mullite Inorganic materials 0.000 claims abstract description 7
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 7
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000010703 silicon Substances 0.000 claims abstract description 6
- 238000000034 method Methods 0.000 claims abstract description 4
- 239000000203 mixture Substances 0.000 claims description 5
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 4
- 229910000831 Steel Inorganic materials 0.000 abstract description 14
- 239000010959 steel Substances 0.000 abstract description 14
- 230000035939 shock Effects 0.000 abstract description 10
- 230000003647 oxidation Effects 0.000 abstract description 9
- 238000007254 oxidation reaction Methods 0.000 abstract description 9
- 229910052755 nonmetal Inorganic materials 0.000 abstract description 5
- 239000002904 solvent Substances 0.000 abstract description 3
- 238000005336 cracking Methods 0.000 description 5
- 230000006866 deterioration Effects 0.000 description 4
- 150000002739 metals Chemical class 0.000 description 3
- 238000005245 sintering Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 238000005266 casting Methods 0.000 description 2
- 229910052593 corundum Inorganic materials 0.000 description 2
- 239000010431 corundum Substances 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 150000004706 metal oxides Chemical class 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 238000004901 spalling Methods 0.000 description 2
- 230000003313 weakening effect Effects 0.000 description 2
- 229910018134 Al-Mg Inorganic materials 0.000 description 1
- 229910018125 Al-Si Inorganic materials 0.000 description 1
- 229910017109 AlON Inorganic materials 0.000 description 1
- 229910018467 Al—Mg Inorganic materials 0.000 description 1
- 229910018520 Al—Si Inorganic materials 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- RHZUVFJBSILHOK-UHFFFAOYSA-N anthracen-1-ylmethanolate Chemical compound C1=CC=C2C=C3C(C[O-])=CC=CC3=CC2=C1 RHZUVFJBSILHOK-UHFFFAOYSA-N 0.000 description 1
- 239000003830 anthracite Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000009749 continuous casting Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000000593 degrading effect Effects 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 150000001247 metal acetylides Chemical class 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 150000004767 nitrides Chemical class 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000009628 steelmaking Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 230000003685 thermal hair damage Effects 0.000 description 1
- 239000011882 ultra-fine particle Substances 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
- C04B35/10—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on aluminium oxide
- C04B35/101—Refractories from grain sized mixtures
- C04B35/106—Refractories from grain sized mixtures containing zirconium oxide or zircon (ZrSiO4)
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D41/00—Casting melt-holding vessels, e.g. ladles, tundishes, cups or the like
- B22D41/14—Closures
- B22D41/22—Closures sliding-gate type, i.e. having a fixed plate and a movable plate in sliding contact with each other for selective registry of their openings
- B22D41/28—Plates therefor
- B22D41/30—Manufacturing or repairing thereof
- B22D41/32—Manufacturing or repairing thereof characterised by the materials used therefor
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
- C04B35/16—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silicates other than clay
- C04B35/18—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silicates other than clay rich in aluminium oxide
- C04B35/185—Mullite 3Al2O3-2SiO2
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/66—Monolithic refractories or refractory mortars, including those whether or not containing clay
Abstract
본 발명은 용융금속 흐름을 제어하는 장치에 이용되는 슬라이딩 플레이트의 내화재에 대하여 용강류 및 비금속 산화물에 대해 내용손, 열충격 및 산화에 따른 균열을 방지하는데 적합한 슬라이딩 플레이트(Sliding plate) 내화재질에 관한 것이다.The present invention relates to a sliding plate refractory material suitable for preventing cracks due to solvent loss, thermal shock and oxidation for molten steel and nonmetal oxides with respect to the refractory material of a sliding plate used in an apparatus for controlling molten metal flow. .
이에 따른 구성은 소결 또는 전융 알루미나(Al2O3) 60∼110 중량부, 50㎛이하의 입경을 갖는 가소 알루미나 10∼20중량부, 소결 또는 전융 지르코니아(ZrO2)-멀라이트 15∼40 중량부, 금속 실리콘(Si) 1∼3 중량부, 탄소(C) 1∼8 중량부, 산화방지제 0.5∼4.0 중량부로 조성됨을 특징으로 하는 용융금속 흐름 제어용 슬라이딩 플레이트의 내화재에 관한 기술이다.The constitution according to the present invention is 60 to 110 parts by weight of sintered or molten alumina (Al 2 O 3 ), 10 to 20 parts by weight of calcined alumina having a particle diameter of 50 μm or less, and 15 to 40 parts by weight of sintered or molten zirconia (ZrO 2 ) -mullite. It is a technique regarding the refractory material of the sliding plate for molten metal flow control characterized by consisting of 1 to 3 parts by weight of metal silicon (Si), 1 to 8 parts by weight of carbon (C), and 0.5 to 4.0 parts by weight of antioxidant.
Description
본 발명은 용융금속의 흐름을 제어하는 장치에 이용되고 있는 슬라이딩 플레이트(Sliding plate)의 내화재에 관한 것으로, 보다 상세하게는 용강류 및 비금속 산화물에 대한 내용손, 열충격 및 산화에 따른 균열을 방지하는데 적합한 슬라이딩 플레이트 내화재질에 관한 것이다.The present invention relates to a refractory material of a sliding plate used in an apparatus for controlling the flow of molten metal, and more particularly, to prevent cracking due to loss of contents, thermal shock and oxidation of molten steel and nonmetal oxides. It relates to a suitable sliding plate refractory material.
일반적으로 레들(Ladle) 및 턴디쉬(Tundish) 하부에는 용강의 배출 및 그 배출량을 제어하기 위한 슬라이딩 플레이트가 장착된다.In general, a sliding plate for controlling the discharge of molten steel and the discharge of the lower portion of the ladle and tundish is mounted.
즉, 도 1과 같이 상부노즐(1)과 하부노즐(2)이 장착되고 그들 사이에는 내화 재질로된 상부 슬라이딩 플레이트(3)와 하부 슬라이딩 플레이트(4)가 설치된다.That is, as shown in FIG. 1, the upper nozzle 1 and the lower nozzle 2 are mounted, and between them, an upper sliding plate 3 and a lower sliding plate 4 made of a refractory material are installed.
이와 같은 슬라이딩 플레이트는 주조시간 및 사용회수, 주조후 산소세척, 강종등에 따라 그 수명이 결정되는데, 이들 내화재는 주조초 열충격, 카세트 변형, 면압유지불량, 플레이트의 지지방식, 형상, 레들 또는 턴디쉬의 바닥 평탄도에 등에 따른 구속응력의 편차 발생으로 균열이 일어나게 된다.Such sliding plates have a lifespan determined by casting time and the number of times of use, oxygen cleaning after casting, and steel grades. These refractory materials have a thermal shock, cassette deformation, surface pressure maintenance failure, plate support, shape, ladle or tundish The cracking occurs due to the deviation of restraint stress due to the bottom flatness.
상기 발생된 균열은 용강류에 질소나 산소의 유입을 초래하여 용강의 품질을 저하시키며, 사용중 슬라이딩 플레이트 내화재의 탈락을 일으켜 제강, 연속주조 조업시 용강유출의 문제를 야기시킬 수 있다.The cracks may cause inflow of nitrogen or oxygen into the molten steel, thereby degrading the quality of the molten steel and causing the sliding plate refractory to fall off during use, which may cause problems of molten steel during steelmaking and continuous casting operations.
또한 용강류에 의한 마모나 비금속 산화물에 의한 용손, 산화 및 황폐화 현상이 일어나게 되는데 이러한 현상은 내용성 향상을 위해 첨가한 탄소(carbon)가 사용중 산화에 의해 탈탄되어 이들 성분에 의한 조직 결합력이 약화되고 이에 따른 공극현상과 비금속 산화물에 의한 부착이 용이하게 이루어져 슬라이딩되는 부위의 내화재 구성부분 일부가 용손되는 것이다.In addition, wear caused by molten steel, melt loss, oxidation and deterioration caused by non-metal oxides occur. This phenomenon is that carbon added to improve the contents is decarburized by oxidation during use, thereby weakening tissue binding force by these components. Accordingly, the part of the refractory material of the sliding portion is easily melted due to the pore phenomena and the adhesion by the nonmetal oxide.
상기와 같은 문제점을 해결하기 위한 일환으로서 종래의 슬라이딩 플레이트 내화재의 조성은 소결 또는 전융 알루미나(Al2O3)를 각 입도 분포로 구획하여 주성분으로한 80∼85 중량부, 입도가 50㎛ 이하인 가소 알루미나 5∼10 중량부, 금속실리콘(Si) 3∼5 중량부, 탄소(C) 4∼6 중량부이고, 산화방지제 금속 0.1∼0.5 중량부로 구성되어 있다.As a part of solving the above problems, the composition of the conventional sliding plate refractory material is 80 to 85 parts by weight of the main component by dividing the sintered or electrolytic alumina (Al 2 O 3 ) into each particle size distribution, and the particle size of 50㎛ or less 5-10 weight part of alumina, 3-5 weight part of metal silicon (Si), 4-6 weight part of carbon (C), and 0.1-0.5 weight part of antioxidant metals.
그러나 상기한 내화재질로된 슬라이딩 플레이트는 미세조직의 치밀화가 적기 때문에 황폐화 및 용강류에 의한 마모가 심하여 장기간 사용이 곤란하는 등의 문제점이 있다.However, the sliding plate made of the refractory material has a problem that it is difficult to use for a long time due to severe deterioration and abrasion due to molten steel due to the small density of the microstructure.
본 발명은 상기한 종래의 문제점을 해결하기 위한 것으로, 극초미분의 알루미나 사용량을 증대시켜 미세조직의 개선으로 강도를 향상시킴과 함께 지르코니아 (ZrO2)-멀라이트를 적절히 배합시켜 내열 스폴리성 향상과 내열 충격성 및 화학적 내용성을 향상시키는데 적합한 내화재 원료를 제공하고자 하는데 그 목적이 있다.The present invention is to solve the above-mentioned problems, and to increase the amount of ultra-fine alumina to improve the microstructure, and to improve the strength, and to combine the zirconia (ZrO 2 ) -melite appropriately to improve the heat-resistant poly- and It is an object of the present invention to provide a refractory material suitable for improving thermal shock resistance and chemical resistance.
도 1 은 슬라이딩 플레이트 구조의 단면도1 is a cross-sectional view of a sliding plate structure
도 2 는 중앙에 내삽 되는 슬라이딩 플레이트 구조의 단면도2 is a cross-sectional view of the sliding plate structure interpolated in the center
도면의 주요부분에 대한 부호 설명Explanation of symbols for the main parts of the drawings
3 : 상부 슬라이딩 플레이트3: upper sliding plate
4 : 하부 슬라이딩 플레이트4: lower sliding plate
상기한 목적을 달성하기 위한 본 발명은 각 입경분포를 갖는 소결 또는 전융 알루미나(Al2O3)가 60∼110 중량부, 50㎛ 이하의 입경을 갖는 가소 알루미나가 10∼20 중량부, 소결 또는 전융 지르코니아(ZrO2)-멀라이드(mullite)가 15∼40 중량부, 금속실리콘(Si) 1∼3 중량부, 탄소(C) 1∼8 중량부, 산화방지제 0.5∼4.0 중량부로 조성된 슬라이딩 플레이트로 이루어진다.상기 소결 또는 전융 알루미나가 상한치 이상이면 내열스폴링성의 저하로 인해 사용중 균열에 의해 제품에 용강의 침윤이 이루어지고, 하한치 이하에서는 용강및 비금속 성분에 의한 내용성이 저하하게 된다.The present invention for achieving the above object is 60 to 110 parts by weight of sintered or molten alumina (Al 2 O 3 ) having a particle size distribution, 10 to 20 parts by weight of plasticized alumina having a particle diameter of 50㎛ or less, sintering or Sliding composed of 15 to 40 parts by weight of molten zirconia (ZrO 2 ) -mullite, 1 to 3 parts by weight of metal silicon (Si), 1 to 8 parts by weight of carbon (C), and 0.5 to 4.0 parts by weight of antioxidant If the sintered or molten alumina is above the upper limit, the molten steel is infiltrated into the product due to cracking during use due to the deterioration of heat spalling resistance, and below the lower limit, the contents due to the molten steel and the nonmetallic component are lowered.
또한 상기한 소결 또는 전융 알루미나는 압축강도를 발현하기 위한 것으로, 입경이 4∼1㎜인 경우는 15∼25 중량부이고, 1∼0.22㎜인 경우는 25∼45 중량부이고, 0.2㎜ 이하인 경우는 10∼20 중량부, 0.04㎜ 이하인 경우는 10∼20 중량부 로한 합을 60∼110중량부로 하여 사용함이 바람직하다.또한 본 발명은 50㎛ 이하의 극초미분을 갖는 가소 알루미나를 종래 보다 증대시켜 사용함으로서 미세조직의 개선으로 열간 결합력을 개선하여(소결성 향상)기계적 강도의 향상과 화학적 내용성을 증가시킨다.상기 가소 알루미나가 상한치 이상에서는 제품 제조시 성형 불량의 원인이 되며, 하한치 이하에서는 제품의 미세 조직의 개선이 이루어지지 않아 내용성 개선이 미약하다.그리고 소결 또는 전융 지르코니아-멀라이트를 포함시킴으로서 내열 스폴링성 향상으로 장기간 사용시 균열 발생을 완화시킨다.상기 소결 또는 전융 지르코니아-멀라이트에서 ZrO2가 27∼39wt% Al2O3가 40∼46wt%, SiO2가 15∼20wt% 포함되고 있는 것을 15∼40 중량부 조성시킴이 바람직하다.In addition, the above-mentioned sintered or molten alumina is for expressing compressive strength, and when the particle size is 4 to 1 mm, it is 15 to 25 parts by weight, and when it is 1 to 0.22 mm, it is 25 to 45 parts by weight and 0.2 mm or less. In the case of 10 to 20 parts by weight and 0.04 mm or less, the sum of 10 to 20 parts by weight is preferably used in an amount of 60 to 110 parts by weight. By improving the microstructure by improving the hot bonding force (improving the sintering), the mechanical strength and the chemical content is increased.If the plastic alumina is above the upper limit, it causes the molding failure during the manufacturing of the product. Improvement of the contents is insignificant due to no improvement of microstructure, and long-term improvement due to heat resistance spalling resistance by including sintering or electrolytic zirconia-mullite Mitigate cracking of the sintered using jeonyung or zirconia-mullite in light ZrO 2 is 15 to 40 that contained the 27~39 wt% Al 2 O 3 40~46wt %, SiO 2 is 15~20wt% parts by weight Composition is preferred.
본 발명의 금속실리콘(Si)은 제품의 결합강도를 높이고 내열충격성 개선을 위한 것으로 상한치 이상에서는 내용성이 저하되며, 하한치 이하에서는 강도 및 내열충격성 개선이 이루어지지 않는다, 따라서 1∼3중량부 범위로 한다. 이때 Si의 입경은 0.02㎜ 이하로 함이 바람직하다.탄소(C)는 내열충격성 및 내용성을 개선하기 위한 것으로, 8중량부 이상에서는 산화에 의한 조직의 황폐화가 발생되고, 1중량부 이하에서는 내열충격성 및 내용성 개선이 감소하게 된다. 따라서 1∼8중량부 범위로 한다.Metallic silicon (Si) of the present invention is to improve the bonding strength of the product and to improve the thermal shock resistance, and the lowering of the solvent content is above the upper limit, the strength and thermal shock resistance is not improved below the lower limit, therefore 1 to 3 parts by weight Shall be. At this time, the particle size of Si is preferably 0.02 mm or less. Carbon (C) is used to improve the thermal shock resistance and the solvent resistance. At 8 parts by weight or more, deterioration of the tissue due to oxidation occurs and at 1 part by weight or less The thermal shock resistance and the improvement of the contents are reduced. Therefore, the range is 1 to 8 parts by weight.
상기 탄소(C)는 무정형(Carbon black, 무연탄 등)이나 결정형(흑연)이 첨가되며 경우에 따라서는 0.2㎜ 보다 큰 입경의 것이 사용될 수도 있으나, 바람직하게는 0.2㎜ 이하의 것을 사용한다.As the carbon (C), amorphous (Carbon black, anthracite, etc.) or crystalline (graphite) is added, and in some cases, a particle size larger than 0.2 mm may be used, but preferably 0.2 mm or less.
또한 본 발명은 탄소가 사용중 산화에 의해 탈락됨에 따라 조직결합력 약화로 인해 공극 형성과 비금속 산화물에 의한 부착이 용이하게 이루어져 슬라이딩되는 부위의 내화재 일부가 용손되는 산화 및 황폐화 현상이 일어나므로 이를 개선하기 위해 저온 및 고온에서 산화방지가 가능한 카바이트(Carbides), 붕화물 (Borides) 산탄화물(Oxycarbides), 산질화물((Oxynitrides), 유리질상 형성이 가능한 SiO2계, B2O3계, P2O3계, V2O5계의 산화물 또는 비산화물계, 각종 금속류 (Al, Iug, Si, Al-Mg, Al-Si 등)와 질화물(BN, ZrN, AlON) 중에서 1종 이상을 0.5∼4.0 중량부 첨가시켜 사용할 수 있다.상기 산화방지제가 4.0중량부 이상이면 용강 및 비금속 개재물에 대한 내용성이 저하되고, 0.5중량부 이하애서는 탄소의 내산화성이 발현되지 않는다.In addition, according to the present invention, as the carbon is eliminated by oxidation during use, the formation of pore and adhesion by the non-metal oxide are easily performed due to the weakening of the tissue binding force, so that the oxidation and degradation of the refractory material of the sliding part occurs, so as to improve this problem. Carbides, Borides Oxycarbides, Oxynitrides, SiO 2 based on glassy form, B 2 O 3 based, P 2 O 3 type, V 2 O 5, based on an oxide or a non-storage type, and various metals (Al, Iug, Si, Al-Mg, Al-Si, etc.) and the nitride (BN, ZrN, AlON) one or more of 0.5 to 4.0 wt. When the said antioxidant is 4.0 weight part or more, the resistance to molten steel and a nonmetallic inclusion will fall, and the oxidation resistance of carbon is not expressed in 0.5 weight part or less.
이상과 같은 재질을 슬라이딩 플레이트 전체에 대하여 적용될수 있으나 슬라이딩 플레이트 형상이 큰 경우는 그 중심에 도 2a∼2d와 같은 구조로 하여 내삽시켜 사용할 수도 있다.The above materials can be applied to the entire sliding plate, but when the sliding plate shape is large, it may be interpolated and used as a structure as shown in FIGS. 2A to 2D at the center thereof.
상기 제품 제조는 통상의 조건인 1000-1400℃ 범위에서 산화 또는 환원 분위기 하에서 소성한다.The production of the product is fired under an oxidizing or reducing atmosphere in the usual range of 1000-1400 ° C.
(표 1)∼(표 2)는 본 발명에 대한 실시예를 나타낸 것이다.Tables 1 to 2 show examples of the present invention.
이상에서와 같이 본 발명은 알루미나를 주성분으로 하는 원료에 대하여 극세 입경의 양을 증대시킴과 함께 여기에 지르코니아-멀라이트계를 적절히 배합하고, 금속규소, 탄소 및 산화방지제를 첨가하여 조성시킴으로서 강도가 증대되고, 열충격 및 산화에 따른 균열의 방지와 내용손이 우수한 슬라이딩 플레이트를 얻게 된다.As described above, the present invention increases the amount of the ultrafine particle diameter with respect to the raw material mainly composed of alumina, zirconia-mullite is appropriately blended therein, and the strength is increased by adding metal silicon, carbon, and antioxidant. The sliding plate is increased, and the sliding plate excellent in the prevention of cracking and thermal damage due to thermal shock and oxidation is obtained.
Claims (11)
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| Application Number | Priority Date | Filing Date | Title |
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| KR1019990012816A KR100318497B1 (en) | 1999-04-12 | 1999-04-12 | Sliding plate refractory for flow controling of molten metal |
| KR1020010044104A KR100318494B1 (en) | 1999-04-12 | 2001-07-23 | Sliding plate refractory for flow controling of molten metal |
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| KR1019990012816A KR100318497B1 (en) | 1999-04-12 | 1999-04-12 | Sliding plate refractory for flow controling of molten metal |
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| KR1020010044104A Division KR100318494B1 (en) | 1999-04-12 | 2001-07-23 | Sliding plate refractory for flow controling of molten metal |
| KR1020010044102A Division KR100318492B1 (en) | 2001-07-23 | 2001-07-23 | Sliding plate refractory for flow controling of molten metal |
| KR1020010044101A Division KR100318491B1 (en) | 2001-07-23 | 2001-07-23 | Sliding plate refractory for flow controling of molten metal |
| KR1020010044103A Division KR100318493B1 (en) | 2001-07-23 | 2001-07-23 | Sliding plate refractory for flow controling of molten metal |
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| KR100411295B1 (en) * | 2001-07-06 | 2003-12-18 | 조선내화 주식회사 | Sliding plate |
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| KR100384619B1 (en) * | 2000-09-06 | 2003-05-22 | 조선내화 주식회사 | sliding plate refractory for flow controling of molten metal |
| KR20020019702A (en) * | 2000-09-06 | 2002-03-13 | 한종웅 | Fireproof material |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0298860A1 (en) * | 1987-07-07 | 1989-01-11 | Vesuvius France S.A. | Refractory composition for sliding gate plate and process for manufacturing it |
| JPS6424069A (en) * | 1987-07-15 | 1989-01-26 | Kurosaki Refractories Co | Brick of sliding nozzle plate for special steel |
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1999
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0298860A1 (en) * | 1987-07-07 | 1989-01-11 | Vesuvius France S.A. | Refractory composition for sliding gate plate and process for manufacturing it |
| JPS6424069A (en) * | 1987-07-15 | 1989-01-26 | Kurosaki Refractories Co | Brick of sliding nozzle plate for special steel |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100411295B1 (en) * | 2001-07-06 | 2003-12-18 | 조선내화 주식회사 | Sliding plate |
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