KR100315436B1 - Multipurpose cleaning composition - Google Patents

Multipurpose cleaning composition Download PDF

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Publication number
KR100315436B1
KR100315436B1 KR1019960082676A KR19960082676A KR100315436B1 KR 100315436 B1 KR100315436 B1 KR 100315436B1 KR 1019960082676 A KR1019960082676 A KR 1019960082676A KR 19960082676 A KR19960082676 A KR 19960082676A KR 100315436 B1 KR100315436 B1 KR 100315436B1
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weight
parts
cleaning composition
composition
formula
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KR1019960082676A
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Korean (ko)
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KR19980063229A (en
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조창묵
김진호
박기만
최경욱
한순종
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조민호
에스케이케미칼주식회사
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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2003—Alcohols; Phenols
    • C11D3/2041—Dihydric alcohols
    • C11D3/2058—Dihydric alcohols aromatic
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C11D3/28—Heterocyclic compounds containing nitrogen in the ring
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0043—For use with aerosol devices
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2003—Alcohols; Phenols
    • C11D3/2006—Monohydric alcohols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2003—Alcohols; Phenols
    • C11D3/2041—Dihydric alcohols

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Detergent Compositions (AREA)

Abstract

PURPOSE: Provided is a multipurpose cleaning composition which can effectively remove dirt, stain, scrawl, and so on, and prevent damages of skin and objects to be washed, and which is safe to use and handle. CONSTITUTION: The cleaning composition comprises 5-70 parts by weight of dilimonene; 5-60 parts by weight of pyrrolidone represented by formula 1; 5-50 parts by weight of alkane monool or alkane diol; and 0.1-10 parts by weight of non-ionic surfactant. In the formula 1, R is a compound selected from the group consisting of C1-C6, linear or branched alkyl radical, allyl radical, and benzyl radical. The cleaning composition is sprayed as an aerosol.

Description

다용도 세정제 조성물Multipurpose Cleaner Composition

[산업상 이용 분야][Industrial use]

본 발명은 다용도 세정제 조성물에 관한 것으로서, 보다 상세하게는 피부 및 피세척물의 표면을 손상하거나, 부식을 유발하지 않으며, 환경 친화적인 동시에 찌든 때, 얼룩, 낙서 등을 효과적으로 제거할 수 있는 디리모넨, 피롤리돈, 알칸 모노- 또는 디-올 및 비이온성 계면 활성제로 구성되는 비수용성 다용도 액체 세정제 조성물에 관한 것이다.The present invention relates to a multi-purpose cleaner composition, more specifically, dirimonene, which does not damage or cause corrosion of the surface of the skin and the to-be-cleaned body, and which can effectively remove stains, graffiti, etc. when it is environmentally friendly and stinging, A water-insoluble, multi-purpose liquid detergent composition composed of pyrrolidone, alkanes mono- or di-ols and nonionic surfactants.

[종래기술][Private Technology]

일반 가정의 TV, 냉장고, 오디오, 비디오, 전자 렌지 등의 가전 제품과 각종 사무 기기 등의 찌든 때, 얼룩 등을 제거하거나, 볼펜, 크레용, 싸인펜, 스프레이, 페인트 등으로 인한 벽지나 장판, 타일 등의 낙서를 제거하기 위하여, 종래에는 일반 액체 세제나 연마제가 함유된 세제 혹은 아세톤, 알코올, 등유 등의 유기 용제가 사용되어 왔다.Household appliances such as TVs, refrigerators, audio, video, and microwave ovens in homes and office equipment, etc., remove stains, wallpaper, blankets, tiles, etc. from ball pens, crayons, sign pens, sprays, paints, etc. In order to remove the graffiti, conventional liquid detergents or detergents containing abrasives or organic solvents such as acetone, alcohol and kerosene have been used.

그러나 일반 액체 세제의 경우 물과 함께 사용되어야 하는 번거로움과 함께 만족스러운 효과를 기대하기가 어려운 문제점이 있었고, 연마제가 함유된 세제 역시 벽지나 장판, 타일 등의 표면의 긁힘 현상과 잔유물 발생 등의 단점을 지니고 있다. 또한 아세톤, 알코올, 등유 등의 유기 용제의 경우 인화성, 발화성, 폭발성등의 취급상의 어려움과 함께 장시간 사용할 때 피부의 손상 및 피세척물의 표면 손상을 유발하는 문제점이 있었다.However, in the case of general liquid detergents, it was difficult to expect a satisfactory effect with the trouble of using it with water, and detergents containing abrasives also had scratches and residues on surfaces such as wallpaper, floorboards and tiles. It has a downside. In addition, in the case of organic solvents such as acetone, alcohol, kerosene, there is a problem of causing damage to the skin and surface of the cleaned object when used for a long time with the difficulty of handling such as flammability, flammability, explosive.

본 발명은 상기와 같은 종래 기술의 문제점을 해결하기 위하여 안출된 것으로서, 본 발명의 목적은 찌든 때, 얼룩, 낙서 등의 미관을 저해하는 오물질을 효과적으로 제거하고, 사용 및 취급이 안전하며, 피부의 손상 및 피세척물의 표면 손상을 방지할 수 있는 세정제 조성물을 제공하는 것이다.The present invention has been made to solve the problems of the prior art as described above, the object of the present invention is to effectively remove the dirt, such as stains, graffiti, such as aesthetics, to effectively remove, safe to use and handle, skin It is to provide a cleaning composition that can prevent the damage of the surface and the surface of the object to be cleaned.

상기와 같은 본 발명의 목적을 달성하기 위하여 본 발명은 디리모넨과 화학식(1)의 피롤리돈과 알칸 모노-올 또는 알칸 디-올과 비이온성 계면 활성제를 포함하는 세정제 조성물을 가공한다.In order to achieve the object of the present invention as described above, the present invention processes a detergent composition comprising dirimonene and pyrrolidone and alkane mono-ol of formula (1) or alkane di-ol and a nonionic surfactant.

[화학식 1][Formula 1]

상기 화학식(1)에서 R은 탄소수 1 내지 6의 직쇄상 또는 분쇄상의 알킬 라디칼, 알릴 라디칼 및 벤질 라디칼로 이루어지는 군에서 선택된 화합물이다.R in the formula (1) is a compound selected from the group consisting of linear or pulverized alkyl radicals, allyl radicals and benzyl radicals having 1 to 6 carbon atoms.

여기에서, 상기한 디리모넨은 전체 조성물에 대하여 5 내지 70중량부인 것이바람직하고, 상기한 알칸 모노-올 또는 알칸 디-올은 전제 조성물에 대하여 5 내지 50중량부인 것이 바람직하고, 상기한 비이온성 계면 활성제는 전제 조성물에 대하여 0.1 내지 10중량부인 것이 바람직하다. 그리고, 상기한 세정제 조성물은 에어로졸 형태로 분사되는 것이 바람직하다.Here, it is preferable that the dirimonene is 5 to 70 parts by weight based on the total composition, and the alkane mono-ol or the alkane di-ol is preferably 5 to 50 parts by weight based on the total composition, and the aforementioned nonionic It is preferable that surfactant is 0.1-10 weight part with respect to a whole composition. In addition, the detergent composition is preferably sprayed in the form of an aerosol.

[실시예]EXAMPLE

대표적인 실시예Representative Example

디리모넨 5 내지 70중량부, 피롤리돈 5 내지 60중량부, 알칸 모노 또는 디-올 5 내지 50중량부, 비이온 계면 활성제 0.1 내지 10중량부 및 소량의 부식 방지제를 각각 혼합하여 본 발명의 세정제 조성물을 제조한다. 본 발명의 세정제 조성물은 LPG 충진제를 사용하여 용이하게 분무할 수 있도록 에어로졸(aerosol) 충진하여 제조하는 것이 바람직하다.5 to 70 parts by weight of dilimonene, 5 to 60 parts by weight of pyrrolidone, 5 to 50 parts by weight of alkane mono or di-ol, 0.1 to 10 parts by weight of nonionic surfactant and a small amount of a corrosion inhibitor, respectively, Prepare the detergent composition. The detergent composition of the present invention is preferably prepared by filling aerosol (aerosol) so that it can be easily sprayed using the LPG filler.

이하 본 발명의 각 구성 성분을 설명한다.Hereinafter, each component of this invention is demonstrated.

본 발명에 있어 용제로 사용되는 디리모넨은 천연 감귤류(citrus)껍질의 추출액으로서, 화학 구조상 터페노이드계로 오일 또는 유지 성분의 오염 제거 능력 즉, 디그리싱율(degreasing rate)에 있어 종래의 석유 용제인 퍼클로로에틸렌 (perchloroethylene)보다 상대적으로 높다(참조 : 미국특허 제4790951호, 제 5031648호). 또한, 디리모넨은 액체로서 155℃ 이상의 높은 끓는점을 갖기 때문에 화학적으로 안정할 뿐 아니라 미국 식품의약국(FDA)의 GRAS(Generally recognized as safe)에 등재된 매우 안전한 화합물이다. 사용되는 디리모넨의 함량은 5 내지 70중량부, 바람직하게는 20 내지 45 중량부이다. 디리모넨을 5중량부 미만 사용하는 경우에는 용제로서의 효과를 기대하기가 어렵고 70중량부를 초과하여 사용하는 경우에는 피세척물의 표면을 손상시킬 수 있다.Dilimonene, which is used as a solvent in the present invention, is an extract of natural citrus shells, and is a conventional petroleum solvent in terms of degreasing rate of oil or oil components by terpenoid chemical structure. Relatively higher than perchloroethylene (see US Pat. No. 4790951, 5031648). In addition, dilimonene is not only chemically stable because it has a high boiling point above 155 ° C. as a liquid, but is also a very safe compound listed in the General Recognized as Safe (GRAS) of the US Food and Drug Administration (FDA). The content of dilimonene used is 5 to 70 parts by weight, preferably 20 to 45 parts by weight. When dilimonene is used in less than 5 parts by weight, it is difficult to expect the effect as a solvent, and when used in excess of 70 parts by weight may damage the surface of the object to be cleaned.

피롤리돈은 디리모넨, 알코올, 에스테르 등과 상용성이 좋으며 낮은 독성과 높은 생분해도 등의 장점으로 인해 현재 페인트 제거제 등에서 용제로 사용되고 있는 메틸렌 클로라이드(methylene chloride)를 대체할 수 있는 용제이다(참고 : EP 0578492호). 본 발명에서 사용될 수 있는 피롤리돈은 상기의 화학식(1)으로 이루어진 화합물로, 상기 화학식(1)에서 R은 탄소수 1 내지 6의 직쇄상 또는 분쇄상의 알킬 라디칼, 알릴 라디칼, 벤질 라디칼이 될 수 있다. 이들 피롤리돈의 함량은 조성물 내에 5 내지 60중량부, 바람직하게는 10 내지 50중량부이다. 5중량부 미만과 60중량부의 범위를 벗어나서 사용할 경우에는 디리모넨과의 상승 효과를 기대하기 어려워 전체적인 조성물의 세정 효과가 감소하게 된다.Pyrrolidone is compatible with dirimonene, alcohols and esters, and is a solvent that can replace methylene chloride, which is currently used as a solvent in paint removers due to its low toxicity and high biodegradability. EP 0578492). Pyrrolidone which can be used in the present invention is a compound consisting of the above formula (1), wherein in the formula (1) R can be a linear or pulverized alkyl radical, allyl radical, benzyl radical of 1 to 6 carbon atoms have. The content of these pyrrolidones is 5 to 60 parts by weight, preferably 10 to 50 parts by weight in the composition. When used out of the range of less than 5 parts by weight and 60 parts by weight, it is difficult to expect a synergistic effect with dirimonene, reducing the cleaning effect of the overall composition.

본 발명에서 사용되는 알칸 모노 또는 디-올은 탄소수 1 내지 4의 직쇄상 또는 분쇄상의 모노 또는 디-올로서, 구체적으로 메탄올, 에탄올, 프로판올, 이소프로판올, 부탄올, 에틸렌글리콜, 프로필렐글리콜 또는 디에틸렌글리콜 등이 될 수 있으며, 이들이 단독 또는 혼합물로서 5 내지 50중량부, 바람직하게는 10 내지 40 중량부가 사용될 수 있다. 알칸 모노 또는 디-올이 5중량부 미만으로 사용될 경우는 피세척물의 표면 손상 방지 효과를 기대하기 어렵고 50중량부 초과시에는 조성물의 세정력이 감소하게 된다.Alkanes mono or di-ols used in the present invention are linear or ground mono or di-ols having 1 to 4 carbon atoms, specifically methanol, ethanol, propanol, isopropanol, butanol, ethylene glycol, propylrel glycol or diethylene Glycols and the like, and these may be used alone or as a mixture of 5 to 50 parts by weight, preferably 10 to 40 parts by weight. When the alkane mono or di-ol is used in less than 5 parts by weight, it is difficult to expect the effect of preventing damage to the surface of the object to be washed, and when it exceeds 50 parts by weight, the cleaning power of the composition is reduced.

본 발명에 사용된 비이온 계면 활성제는 고급 지방산의 에틸렌 옥사이드 부가의 폴리옥시에틸렌글리콜 형태, 지방족 아미드의 지방산 에스테르의 폴리옥시에틸렌글리콜 형태, 소르비톨 및 소르비탄의 지방산 에스테르 형태 및 알카놀아민의 지방족 아미드 형태 등으로 조성물 내에 0.1 내지 10중량부, 바람직하게는 1 내지 5중량부이다. 0.1중량부 미만의 양으로 사용할 경우에는 계면 활성 효과를 기대하기 어렵고, 10중량부 초과시에는 조성물의 점도 상승 및 세정 후의 잔유물 발생 등으로 사용이 어렵다.The nonionic surfactants used in the present invention are polyoxyethylene glycol forms of ethylene oxide addition of higher fatty acids, polyoxyethylene glycol forms of fatty acid esters of aliphatic amides, fatty acid ester forms of sorbitol and sorbitan and aliphatic amide forms of alkanolamines. And 0.1 to 10 parts by weight, preferably 1 to 5 parts by weight, in the composition. When it is used in an amount of less than 0.1 part by weight, it is difficult to expect the surfactant effect, and when it is more than 10 parts by weight, it is difficult to use due to the increase in viscosity of the composition and the generation of residue after washing.

또한, 본 발명의 세정제 조성물을 에어로졸 형태로 만들 경우 주석(tin) 캔의 부식 방지를 위해 보락스, 포스포네이트, 포스페이트, 아민, 벤조에이트, 몰리브데이트, 나이트라이트 등의 부식 방지제를 0.001∼0.10중량부를 첨가하는데, 그 사용량이 0.001중량부 미만이면 방식 처리가 불충분한 문제가 있고, 0.10중량부를 초과하면 침전이 생기는 문제가 발생한다.In addition, when the cleaning composition of the present invention is made into an aerosol form, corrosion inhibitors such as borax, phosphonate, phosphate, amine, benzoate, molybdate, and nitrite are contained in an amount of 0.001 to Although 0.10 parts by weight is added, if the amount is less than 0.001 parts by weight, the anticorrosive treatment is insufficient. If the amount is more than 0.10 parts by weight, precipitation occurs.

바람직한 실시예Preferred Embodiment

본 발명의 바람직한 실시예 및 비교예를 기재한다. 그러나 하기한 실시예는 본 발명의 구성 및 효과를 나타내는 본 발명의 일 실시예일 뿐 본 발명이 하기한 실시예에 한정되는 것은 아니다.Preferred examples and comparative examples of the present invention are described. However, the following examples are merely examples of the present invention showing the constitution and effects of the present invention, and the present invention is not limited to the following examples.

실시예 1∼4 및 비교예 1∼3Examples 1-4 and Comparative Examples 1-3

하기한 표 1의 배합 비율에 따라 각각 혼합하여 본 발명의 세정제 조성물 및 비교예의 세정제 조성물을 제조하고 LPG 충진제를 사용하여 용이하게 분사할 수 있도록 에어로졸 충진을 하였다.Mixing was carried out according to the mixing ratios of Table 1 below to prepare the cleaning composition of the present invention and the cleaning composition of the comparative example, and the aerosol filling to be easily sprayed using the LPG filler.

[표 1] (단위:중량부)[Table 1] (Unit: parts by weight)

* polyethylene SL-62(미국 Olin사 제품)* polyethylene SL-62 (manufactured by Olin, USA)

실험예 1Experimental Example 1

본 발명의 실시예 및 비교예의 제조 방법에 의하여 제조된 세정제 조성물의 시료를 다음과 같은 조건에서 세척력 시험과 표면 손상 시험을 실시하였으며, 그 결과는 표 2 및 표 3에 하기 하였다.Samples of the cleaning composition prepared by the preparation methods of Examples and Comparative Examples of the present invention were subjected to the cleaning force test and the surface damage test under the following conditions, the results are shown in Table 2 and Table 3.

* 시험편의 제조 *Preparation of Test Piece

벽지와 장판의 크기를 20cm ×20cm로 하고, 타일은 15cm ×15cm로 각각을 준비하여 볼펜, 크레용, 수성 잉크펜, 유성펜, 스프레이 페인트를 약 10cm의 길이로 오염시킨 후 상온에서 24시간 건조시켜 준비하였다.The size of the wallpaper and the floorboard are 20 cm × 20 cm, and the tiles are 15 cm × 15 cm, respectively, and the ballpoint pens, crayons, water ink pens, oil pens, and spray paints are contaminated to about 10 cm in length, and then dried at room temperature for 24 hours. It was.

* 세척과 평가방법 ** Cleaning and Evaluation Method *

오염 부분의 10cm 높이에서 조성물을 분사한 후 화장지로 오염 부분을 닦아낸 다음 세정력과 피세척물의 표면 손상을 육안으로 판별하였다.After spraying the composition at a height of 10 cm of the contaminated portion, the contaminated portion was wiped off with a toilet paper, and then the cleaning power and the surface damage of the object were visually determined.

[표 2]TABLE 2

[표 3]TABLE 3

실험예 2Experimental Example 2

상기 실시예 및 비교예에서 제조된 세정제 조성물의 시료를 주석(tin) 캔에 넣고 부식을 시험 평가하였으며, 그 결과는 다음 표 4에 나타낸 바와 같다.Samples of the detergent compositions prepared in Examples and Comparative Examples were placed in tin cans and tested for corrosion, and the results are shown in Table 4 below.

* 시험 평가 방법 ** Test evaluation method *

조성물 시료를 넣은 주석 캔을 60℃의 오븐에 넣고 1주일, 2주일, 1개월, 3개월, 6개월 후 개봉하여 육안으로 부식을 평가하였다.Tin cans containing the composition samples were placed in an oven at 60 ° C., and opened after 1 week, 2 weeks, 1 month, 3 months, and 6 months, and the corrosion was visually evaluated.

[표 4]TABLE 4

상기 표 2 내지 표 3의 비교 시험 결과에서 알 수 있듯이, 실시예의 세정제 조성물을 사용하여 각종 오염 물질을 제거한 결과 세척력이 우수하거나 탁월하고, 피세척물의 표면 손상도 거의 유발하지 않았음을 알 수 있었다. 특히, 표 4의 부식 여부의 평가 시험 결과에서 알 수 있듯이 본 발명의 세정제 조성물은 부식을 발생시키지 않는 안정된 조성물임을 확인할 수 있었다.As can be seen from the comparative test results of Tables 2 to 3, as a result of removing various contaminants using the cleaning composition of the example, it was found that the cleaning power was excellent or excellent, and the surface damage of the cleansing material was hardly induced. . In particular, as can be seen from the evaluation test results of the corrosion of Table 4 it was confirmed that the cleaning composition of the present invention is a stable composition does not cause corrosion.

Claims (2)

디리모넨 5 내지 70중량부;Dilimonene 5 to 70 parts by weight; 하기 화학식(1)의 피롤리돈 5 내지 60중량부;5 to 60 parts by weight of pyrrolidone of the formula (1); 알칸 모노-올 또는 알칸 디-올 5 내지 50중량부; 및5 to 50 parts by weight of alkane mono-ol or alkane di-ol; And 비이온성 계면 활성제 0.1 내지 10중량부를 포함하는 세정제 조성물.Cleaner composition comprising 0.1 to 10 parts by weight of the nonionic surfactant. [화학식 1][Formula 1] 상기 화학식(1)에서 R은 탄소수 1 내지 6의 직쇄상 또는 분지쇄상의 알킬 라디칼, 알릴 라디칼 및 벤질 라디칼로 이루어지는 군에서 선택된 화합물임.R in the formula (1) is a compound selected from the group consisting of linear or branched alkyl radicals having 1 to 6 carbon atoms, allyl radicals and benzyl radicals. 제1항에 있어서, 상기한 세정제 조성물은 에어로졸 형태로 분사되는 세정제 조성물.The detergent composition of claim 1, wherein the detergent composition is sprayed in an aerosol form.
KR1019960082676A 1996-12-31 1996-12-31 Multipurpose cleaning composition KR100315436B1 (en)

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JPH0428796A (en) * 1990-05-23 1992-01-31 Kawaken Fine Chem Co Ltd Liquid detergent composition

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Publication number Priority date Publication date Assignee Title
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