KR100257300B1 - Steering wheel cover with antibiosis - Google Patents
Steering wheel cover with antibiosis Download PDFInfo
- Publication number
- KR100257300B1 KR100257300B1 KR1019970043605A KR19970043605A KR100257300B1 KR 100257300 B1 KR100257300 B1 KR 100257300B1 KR 1019970043605 A KR1019970043605 A KR 1019970043605A KR 19970043605 A KR19970043605 A KR 19970043605A KR 100257300 B1 KR100257300 B1 KR 100257300B1
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- KR
- South Korea
- Prior art keywords
- steering wheel
- foaming
- agent
- antimicrobial agent
- added
- Prior art date
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Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B62—LAND VEHICLES FOR TRAVELLING OTHERWISE THAN ON RAILS
- B62D—MOTOR VEHICLES; TRAILERS
- B62D1/00—Steering controls, i.e. means for initiating a change of direction of the vehicle
- B62D1/02—Steering controls, i.e. means for initiating a change of direction of the vehicle vehicle-mounted
- B62D1/04—Hand wheels
- B62D1/06—Rims, e.g. with heating means; Rim covers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60N—SEATS SPECIALLY ADAPTED FOR VEHICLES; VEHICLE PASSENGER ACCOMMODATION NOT OTHERWISE PROVIDED FOR
- B60N3/00—Arrangements or adaptations of other passenger fittings, not otherwise provided for
- B60N3/02—Arrangements or adaptations of other passenger fittings, not otherwise provided for of hand grips or straps
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60Y—INDEXING SCHEME RELATING TO ASPECTS CROSS-CUTTING VEHICLE TECHNOLOGY
- B60Y2410/00—Constructional features of vehicle sub-units
- B60Y2410/12—Production or manufacturing of vehicle parts
- B60Y2410/122—Plastic parts manufactured by moulding
Abstract
Description
본 발명은 항균제를 자동차핸들 제조공정중의 플라스틱 재료에 첨가하여 항균기능을 가지는 자동차핸들을 제조하는 방법에 관한 것이다. 여기서 플라스틱이란 주로 PVC, PU, PE, PP, ABS, PS, SAN, PET 등의 압출이나 사출이 가능한 것중의 하나이다. 자동차의 실내 부품중 인체가 가장 접촉이 빈번한 것이 바로 핸들부분으로써 자가운전일 경우 손에서 나는 땀이나 손에 오염되어있던 이물질이 쉽게 핸들에 접착될 수 있고, 타인의 운전시에도 땀과 오염물이 잔류하기 쉽다. 또한 자동차의 실내는 균이나 곰팡이가 성장할 수 있는 온도와 습도가 유지되기도하므로 균이나 곰팡이류는 영양분이 있을때는 쉽게 기하급수적으로 성장하여 핸들의 표면에 존재하게되고 접촉하는 손을 통해 운전자 본인은 물론 타인에게까지 이동되어 전염서질환을 유발하는 원인이 되기도하며, 자동차 실내의 불쾌한 냄새발생의 원인이 되기도 한다.The present invention relates to a method of manufacturing a car handle having an antibacterial function by adding an antimicrobial agent to a plastic material in a car handle manufacturing process. Here, plastic is one of those that can be extruded or injected mainly of PVC, PU, PE, PP, ABS, PS, SAN, PET, and the like. The most frequently contacted body part of the car's interior parts is the handle part. When self-driving, sweat from the hands or foreign substances contaminated with the hand can be easily adhered to the handle, and sweat and contaminants remain even when driving by others. easy to do. In addition, the interior of the car can maintain the temperature and humidity where germs and molds can grow, so germs and molds easily grow exponentially when there is nutrients, and are present on the surface of the steering wheel. The disease can be caused to cause infectious diseases and cause unpleasant odors in the car interior.
본 발명에서는 항균제를 상기에서 열거한 플라스틱의 성형공정중에 첨가함으로써 항균기능을 부여하도록 하는 것으로 일반적으로 사용할 수 있는 항균제로는 유기계 및 무기계항균제가 있다. 그러나 유기계항균제는 대부분 독성을 가지므로 인체안정성이 매우 낮고, 제품을 사용시 용출 및 휘발로 항균기능의 지속성이 짧고, 대부분의 플라스틱 가공온도범위에서 가공시 휘발하여 효과를 기대할 수 없는 단점을 가진다. 반면, 무기계항균제는 인체안정성이 탁월하고 사용중에 휘발 및 용출이 없어 항균기능이 반영구적이며, 고온영역 즉, 800∼1000℃까지도 안정하므로 플라스틱가공온도 범위인 150∼300℃에서는 매우 안정적이다. 또한 유기계는 여타 첨가제와 반응성이 있을 경우 기존 물성에 영향을 줄 우려도 있으나 무기계항균제의 경우 기존의 물성에 영향을 주지 않고 소량첨가로써도 항균기능을 충분히 발휘할 수 있는 장점이 있다. 본 발명에서 사용될 수 있는 무기계항균제로는 담체의 종류에 따라 다음과 같이 구분할 수 있다. 많이 사용되는 담체로는 세라믹, 인산지르코늄, 아파타이트, 제올라이트등이 있으며, 항균금속인 은, 구리, 아연등으로 담체중의 이온을 교환하거나 흡착시킨 것이다. 항균제를 수지에 적용시에는 최적의 분산을 고려하여야 하는데, 항균제를 분말형태로 공정중에 적정첨가비로 직접투입하거나, 분산을 유리하게 하기 위해 항균제를 농축시킨 마스타뱃치를 만들러나 항균컴파운드를 만들어 최종 제품의 중량대비 적정한 양이 되도록 투입할 수도 있다. 좀더 상세히 설명하면, 기존의 피브이씨(PVC)재질의 핸들을 제조하기 위해 수지 및 여타첨가제 즉, 가소제, 경도조정제, 인장강도조정제, 조색용안료, 각종 안정제 등을 혼합하게 되는데, 항균제의 투입공정은 어느 공정이라도 혼합이 쉬우며 공정 작업의 편의에 따라 수지 및 첨가제중 몇가지를 임의로 조합한 마스타뱃치 또는 컴파운드를 사용하여 고른 분산에 도움이 되도록 할 수 있다. 기존의 폴리우레탄(PU)재질의 핸들을 제조하기 위해서는 수지와 첨가제 즉, 가교제, 촉매, 발포제, 색상조절용토너, 산화 방지제등을 혼합하게 되는데, 항균제 투입방법은 피브이씨 재질의 핸들 제조시와 유사하다.In the present invention, by adding the antimicrobial agent during the molding process of the plastics listed above to give the antimicrobial function, antimicrobial agents that can be used generally include organic and inorganic antibacterial agents. However, organic antimicrobials have most of the toxicity, so the stability of the human body is very low, the durability of the antimicrobial function by the elution and volatilization when using the product is short, and the effects of volatilization during processing in most plastic processing temperature range can not be expected. On the other hand, the inorganic antimicrobial agent has excellent human stability, no volatilization and no dissolution during use, and thus is antipermanent. It is stable even in the high temperature range, that is, 800 to 1000 ° C, and thus is very stable in the plastic processing temperature range of 150 to 300 ° C. In addition, the organic system may affect the existing physical properties when reactive with other additives, but the inorganic antimicrobial agent does not affect the existing physical properties and has a merit of sufficiently exhibiting antibacterial function even with a small amount of addition. Inorganic antibacterial agents that can be used in the present invention can be classified as follows according to the type of carrier. Commonly used carriers include ceramics, zirconium phosphate, apatite, zeolites, and the like. The antimicrobial metals such as silver, copper, and zinc are used to exchange or adsorb ions in the carrier. When applying the antimicrobial agent to the resin, it is necessary to consider the optimum dispersion.The antimicrobial agent should be added directly in the form of powder in the proper additive ratio during the process, or the master batch made with the concentrated antimicrobial compound to make the dispersion advantageous, or the antimicrobial compound is made into the final product It may be added in an amount suitable for the weight of the product. In more detail, the resin and other additives, such as plasticizers, hardness modifiers, tensile strength modifiers, coloring pigments, and various stabilizers, etc., are mixed to manufacture conventional PVC handles. The process is easy to mix in any process and can be used to aid in even dispersion using a masterbatch or compound of any combination of resins and additives, depending on the convenience of the process operation. In order to manufacture a polyurethane handle, a resin and an additive, such as a crosslinking agent, a catalyst, a foaming agent, a color control toner, and an antioxidant, are mixed. similar.
[실시예 1]Example 1
피브이씨수지에 가소제, 탄산칼슘, 안료, 안정제등이 혼합된 기존의 자동차용 핸들을 제조하기 위해 50∼250℃에서 배합한 보통의 배합물(항균제 무첨가)에 항균제를 핸들의 고형분 대비 0.05 내지 10중량퍼센트의 비로 무기계항균제를 분말상태로 첨가하고 고르게 분산한 후 압출하여 펠렛상태로 만들고 이를 다시 150∼250℃의 온도로 사출 공정을 거쳐 항균기능을 가지는 핸들을 만들었다.Antimicrobial agent was added to the conventional formulation (addition of antimicrobial agent) at 50-250 ° C to manufacture a conventional automobile handle, in which plasticizer, calcium carbonate, pigment, stabilizer, etc. were mixed with FB resin, and 0.05 to 10 Inorganic antimicrobial agent was added in powder form at a weight percent ratio, uniformly dispersed and extruded into pellets, which were then injected at a temperature of 150 to 250 ° C. to make a handle having antibacterial function.
[실시예 2]Example 2
실시예 1에서 보통의 배합물에 고형분 대비 무기항균제의 첨가비가 0.05 10중량퍼센트가 되도록 항균제를 농축한 마스타뱃치를 첨가하여 항균기능을 가지는 핸들을 만들었다.In Example 1, a handle having an antimicrobial function was prepared by adding a masterbatch concentrated with an antimicrobial agent so that the ratio of the inorganic antimicrobial agent to the solid content was 0.05 to 10% by weight.
[실시예 3]Example 3
실시예 1에서 보통의 배합물에 고형분 대비 무기항균제의 첨가비가 0.05 10중량퍼센트가 되도록 항균컴파운드를 첨가하여 항균기능을 가지는 핸들을 만들었다.In Example 1, a handle having an antimicrobial function was made by adding an antimicrobial compound so that the addition ratio of the inorganic antimicrobial agent to the solid content was 0.05 to 10% by weight.
[실시예 4]Example 4
폴리우레탄수지에 가교제, 촉매, 발포제, 색상조절용토너, 산화방지제 등이 배합된 보통의 배합물에 고형분 대비 무기항균제를 분말상태로 0.05 내지 10 중량퍼센트가 되도록 첨가하여 발포온도 40∼100℃, 발포압력 2∼10kg/cm2에서 발포하여 항균기능을 가지는 핸들을 제조하였다.Foaming temperature is 40 ~ 100 ℃, foaming pressure by adding inorganic antimicrobial agent in powder form to 0.05 ~ 10% by weight to the ordinary formulation containing polyurethane resin, crosslinking agent, catalyst, foaming agent, color control toner, antioxidant, etc. A handle having an antibacterial function was prepared by foaming at 2 to 10 kg / cm 2 .
[실시예 5]Example 5
실시예 4에서 보통의 배합물에 고형분 대비 무기항균제의 첨가비가 0.05 내지 10중량퍼센트가 되도록 항균제가 농축된 마스타뱃치를 첨가하여 항균기능을 가지는 핸들을 제조하였다.In Example 4, a handle having an antimicrobial function was prepared by adding a masterbatch in which the antimicrobial agent was concentrated so that the ratio of the inorganic antimicrobial agent to the solid content was 0.05 to 10% by weight.
[실시예 6]Example 6
실시예 4에서 보통의 배합물에 고형분 대비 무기항균제의 첨기비가 0.05 내지 10중량퍼센트가 되도록 항균컴파운드를 첨가하여 항균기능을 가지는 핸들을 제조하였다.In Example 4, a handle having an antimicrobial function was prepared by adding an antibacterial compound so that the addition ratio of the inorganic antimicrobial agent to the solid content was 0.05 to 10% by weight.
실시예에 대한 균과 곰팡이에 대한 항균력 시험 결과는 다음과 같고, 균에 대한 시험방법은 가압밀착법, 시험조건은 시험균액을 25℃에서 24시간 정치배양후 균수(세균수/ml)를 측정하였으며, 시료표면적은 60cm2이다. 방미도측정에 대한 사용공시균주는 Aspergillusniger(ATCC 9642)이며, 시험조건은 28℃, 85% R.H, 4주간 배향하였다.The results of the antibacterial activity test against the bacteria and molds for the examples are as follows. The test method for the bacteria was press-contact method, and the test conditions were measured for 24 hours of incubation at 25 ° C for the test bacteria solution. The sample surface area is 60 cm 2 . The strain used was for Aspergillusniger (ATCC 9642). The test conditions were 28 ° C., 85% RH, and 4 weeks.
표시구분 3 : 시편 위 30-60% 이하로 자라남Display Classification 3: 30-60% or less on the specimen
1 : 시편 위 10% 이하로 자라남1: grow up to 10% above the specimen
0 : 자라지 못함0: can't grow
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KR1019970043605A KR100257300B1 (en) | 1997-08-30 | 1997-08-30 | Steering wheel cover with antibiosis |
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KR1019970043605A KR100257300B1 (en) | 1997-08-30 | 1997-08-30 | Steering wheel cover with antibiosis |
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KR100257300B1 true KR100257300B1 (en) | 2000-05-15 |
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KR20020056058A (en) * | 2000-12-29 | 2002-07-10 | 이계안 | Polyurethane containing inorganic antibiosis |
KR102402524B1 (en) * | 2020-09-22 | 2022-05-27 | 엘지전자 주식회사 | Refrigerator |
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