KR100257084B1 - Manufacturing method of resistance mushroom bath - Google Patents

Manufacturing method of resistance mushroom bath Download PDF

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Publication number
KR100257084B1
KR100257084B1 KR1019970051393A KR19970051393A KR100257084B1 KR 100257084 B1 KR100257084 B1 KR 100257084B1 KR 1019970051393 A KR1019970051393 A KR 1019970051393A KR 19970051393 A KR19970051393 A KR 19970051393A KR 100257084 B1 KR100257084 B1 KR 100257084B1
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South Korea
Prior art keywords
bath
resin
resin composition
bacterial
agent
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KR1019970051393A
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Korean (ko)
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KR19990030921A (en
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박봉환
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박봉환
주식회사대성
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D167/00Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
    • C09D167/06Unsaturated polyesters having carbon-to-carbon unsaturation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/14Paints containing biocides, e.g. fungicides, insecticides or pesticides
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/41Organic pigments; Organic dyes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/80Processes for incorporating ingredients

Abstract

PURPOSE: A method for preparing anti-bacterial inorganic bath is provided to continuously exhibit its anti-bacterial ability by forming gel coat resin anti-bacterial coating agent added with anti-bacterial inorganic powders and spreading the coating agent over inner surface of the bath. CONSTITUTION: A method for preparing anti-bacterial inorganic bath comprises a first process of preparing a first resin composition including 92% of unsaturated polyester iso-type resin and 8% of aerosil; a second process of mixing 65% of white pigment to 35% of unsaturated polyester iso-type resin and adding organic pigment and dispersing agent to form a second pigment dispersed resin composition; a third process of blending 25% of the first resin composition with 54% of unsaturated polyester iso-type resin and adding 15% of the second resin composition, introducing a cross-linking agent, a hardening agent and/or a defoaming agent, following by providing 0.5-1% of anti-bacterial inorganic powder and agitating for 20-30 minutes to form a gel coat resin anti-bacterial coating agent; and a fourth process of applying the coating agent over inner surface of general bath and curing at less than 60 deg.C.

Description

항균 욕조의 제조방법Manufacturing method of antibacterial bath

본 발명은 겔코트수지 조성물에 무기항균제 분말을 일정량 혼입하여 항균코팅제를 얻고 이를 욕조내표면에 도포하여 60℃이하에서 경화시켜서 욕조와 일체가 되게 제조되는 무기항균욕조의 제조방법에 관한 것이다.The present invention relates to a method for producing an inorganic antibacterial bath which is manufactured to be integrated with a bath by incorporating a certain amount of inorganic antimicrobial powder into a gel coat resin composition to obtain an antimicrobial coating agent and applying it to the surface of the bath to cure at 60 ° C. or less.

종래의 욕조는 마블옥조(인조대리석) 또는 FRP 욕조 등이 사용되고 있으나 그 원료에 항균기능이 없어 제품을 장기간 사용할 때 수분과의 접촉면에서 세균이 증식되어 비위생적이 되는 결점이 있었다.Conventional baths are used marble jade (artificial marble) or FRP baths, but there is a defect that the raw material does not have an antibacterial function, the bacteria are multiplying on the contact surface with moisture when using the product for a long time is unsanitary.

본 발명은 이점을 개선하기 위해 장기간의 연구개발을 통해 특별히 일정량의 무기항균제 분말을 겔코트수지에 혼합하여 겔코트수지 항균 코팅제를 조성하고 이를 욕조내 표면에 도포하여 60℃이하의 온도에서 경화시킬 수 있게 만들어 이를 욕조내 표면(세면기 표면도 포함)에 도포하여 경화시키므로서 항균욕조를 제조하는데 성공한 것이다.In order to improve the advantages of the present invention, a special amount of inorganic antimicrobial powder is mixed with a gel coat resin through long-term research and development to form a gel coat resin antimicrobial coating, which is applied to the surface of the bath and cured at a temperature of 60 ° C. or less. It has been successful in manufacturing an antibacterial bath by making it harden by applying it to the surface of the bathtub (including the washbasin surface).

이를 보다 상세히 설명하면 다음과 같다.This will be described in more detail as follows.

[제1공정][Step 1]

불포화 폴리에스텔 이소타잎수지 92%에 에로실(Aerosil 200)8%를 투입하여 저속믹서(RPM 200회)로 15분간 믹싱한다.…(1차 수지조성물)8% Aerosil 200 is added to 92% of unsaturated polyester isotype resin and mixed for 15 minutes with a low speed mixer (200 RPM). (Primary resin composition)

[제2공정][Step 2]

불포화 폴리에스텔 이소타잎수지 35%에 백색안료(TiO2) 65%를 혼합하고 유기안료 소량(0.01-0.8%)와 분산제 0.2-0.4%를 혼합하여 저속믹서로 20분정도 믹싱한다. …(안료 분산수지조성물)The white pigment (TiO 2 ) 65% is mixed with 35% of unsaturated polyester isotype resin, and a small amount of organic pigment (0.01-0.8%) and 0.2-0.4% of a dispersant are mixed and mixed for about 20 minutes using a low speed mixer. … Pigment Dispersion Resin Composition

[제3공정][Step 3]

불포화 폴리에스텔 이소타잎수지 54%에 제1공정에서 만든 1차 수지조성물 25%를 혼합하고 제2공정에서 만든 안료분산수지 조성물 15%를 혼합하여 가교제 6%를 넣고 제올라이트 담체에 항균금속을 치환시킨 무독성 무기항균제 분말 0.5-1.0%를 혼합하고 코발트 8%로된 경화제 0.4%, 소포제 0.2%이하, Levelling제 0.2%를 혼합하여 중속믹서(RPH700정도)로 20-30분간 믹싱하여 겔코트수지 항균성 코팅제를 제조한다.54% of the unsaturated polyester isophthalate resin was mixed with 25% of the primary resin composition made in the first step, 15% of the pigment dispersion resin composition made in the second step was added, 6% of the crosslinking agent was added, and the antimicrobial metal was substituted for the zeolite carrier. Gel coat resin antimicrobial coating agent by mixing 0.5-1.0% of non-toxic inorganic antibacterial powder, 0.4% of cobalt curing agent, 0.4% of antifoaming agent, 0.2% or less of leveling agent, and 0.2% of leveling agent. To prepare.

[제4공정][Step 4]

제3공정에서 제조된 겔코트수지 항균성 코팅제를 마불욕조나 FRP수지제 욕조의 내표면에 1-1.5mm정도로 도포하여 60℃이하에서 경화시켜서 항균욕조를 제조한다.The antimicrobial bath prepared in the third step is applied to the inner surface of the horsepower bath or the FRP resin bath with a thickness of about 1-1.5 mm and cured at 60 ° C. or less to prepare an antibacterial bath.

이와 같이 제조된 본 발명은 겔코트수지코팅제에 제올라이트담체에 항균금속을 치환시킨 무독성 항균제인 무기항균제(상품명 ANBIGENT)분말을 혼합하였기 때문에 욕조본체와 친화력이 있어 일체로 제조가 되어 이질감이 없게 되고 욕조내면에 항균제가 혼합된 코팅층이 형성되어서 욕조에 물을 담아 사용하게 될 경우 무기항균제의 작용으로 욕조표면에 접하는 세균의 증식을 억제하거나 사멸하는 효과를 얻을 수 있었다.The present invention prepared as described above is a non-toxic antimicrobial agent (brand name ANBIGENT) powder, which is a non-toxic antimicrobial agent substituted with an antimicrobial metal in a gel coat resin coating agent, has affinity with the bath body, so it is manufactured integrally and has no heterogeneity. When the antimicrobial agent was mixed on the inner surface of the bath, water was added to the bath, and the effect of inorganic antimicrobial agents on the surface of the bath could inhibit or kill the growth of bacteria.

Figure kpo00001
Figure kpo00001

특히 본 발명에 사용한 무기항균제는 고온에서 안정되고 휘발성 및 용출성이 없기 때문에 항균력이 장시간 지속되므로 욕조에 세균이 서식하는 것을 막아 장기사용에도 불구하고 위생적인 욕조를 얻을수 있게되며 사람의 피부와 접촉되어도 부작용이 없기 때문에 안심하고 사용할수 있는 등의 장점이 있으며 가공이 용이하여 생산에 어려움이 없게되는 등의 이점을 얻게 되는 것이다.In particular, the inorganic antimicrobial agent used in the present invention is stable at high temperatures and has no volatility and dissolution ability, so that the antibacterial activity lasts for a long time, thus preventing the bacteria from incubating in the bathtub, so that a hygienic bathtub can be obtained in spite of long-term use and in contact with human skin. There are no side effects, so you can use it with confidence, and you will get advantages such as easy processing and no difficulty in production.

Claims (1)

불포화 폴리에스텔 이소타입수지 92%에 에로실8%를 투입하여 저속믹서로 약 15분간 믹서하여 1차 수지조성물을 만드는 제1공정과 ; 불포화 폴리에스텔 이소타입수지 약 35%에 백색안료(TiO2) 약 65%를 혼합하고 유기안료와 분산제를 혼합하여 저속믹서기로 약 20분정도 믹서하여 안료분산수지조성물을 만드는 제2공정과 ;A first step of adding 8% of erosil to 92% of unsaturated polyester isotype resin and mixing the mixture for about 15 minutes with a low speed mixer to form a primary resin composition; A second step of preparing a pigment dispersion resin composition by mixing about 35% of unsaturated polyester isotype resin with about 65% of white pigment (TiO 2 ), mixing organic pigment and dispersant, and mixing the mixture for about 20 minutes with a low speed mixer; 불포화 폴리에스텔 이소타입수지 약 54%에 제1공정에서 만든 수지조성물 약 25%를 혼합하고 제2공정에서 만든 안료분산수지조성물 15%를 혼합하여 가교제와 경화제 소포제를 넣으면서 제올라이트 담체에 항균금속을 치환시킨 무기항균제 분말을 총량에 대하여 0.5-1%를 넣어 중속믹서로 20-30분간 믹서하여 겔코트수지 항균성 코팅제를 얻는 제3공정과 ;About 54% of the unsaturated polyester isotype resin is mixed with about 25% of the resin composition made in the first step, and 15% of the pigment dispersion resin composition made in the second step is mixed with the crosslinking agent and the curing agent antifoaming agent. A third step of preparing the gel coat resin antimicrobial coating agent by mixing 0.5-1% of the prepared inorganic antimicrobial powder with a medium speed mixer for 20-30 minutes; 제3공정에서 얻어진 코팅제를 공지의 욕조 내면에 일정두께로 도포하여 60℃이하에서 경화시켜서 도는 제4공정을 순차실시하여 얻어지는 항균 욕조의 제조방법.A method for producing an antibacterial bath, obtained by sequentially applying a coating obtained in the third step to a known thickness inside a bath and curing at 60 ° C. or lower.
KR1019970051393A 1997-10-04 1997-10-04 Manufacturing method of resistance mushroom bath KR100257084B1 (en)

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