KR100225485B1 - Release agent and its manufacture thereof - Google Patents

Release agent and its manufacture thereof

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Publication number
KR100225485B1
KR100225485B1 KR1019970006406A KR19970006406A KR100225485B1 KR 100225485 B1 KR100225485 B1 KR 100225485B1 KR 1019970006406 A KR1019970006406 A KR 1019970006406A KR 19970006406 A KR19970006406 A KR 19970006406A KR 100225485 B1 KR100225485 B1 KR 100225485B1
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South Korea
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weight
mold
water
rust
release agent
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KR1019970006406A
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Korean (ko)
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KR19980069357A (en
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이강인
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이강인
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C33/00Moulds or cores; Details thereof or accessories therefor
    • B29C33/56Coatings, e.g. enameled or galvanised; Releasing, lubricating or separating agents
    • B29C33/60Releasing, lubricating or separating agents
    • B29C33/62Releasing, lubricating or separating agents based on polymers or oligomers

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Preventing Corrosion Or Incrustation Of Metals (AREA)

Abstract

본 발명은 디프로필렌글리콜 모노메틸 에테르와 물 및 릴리즈 블렌드로 구성된 이형제 조성물에, K2HPO4, NANO3, 소듐 실리케이트 및 물로 이루어진 방청제를 첨가한 방청수성이형제 및 그 제조방법에 관한 것으로, 1 차 산업의 각 부분의 많은 비중을 차지하는 몰드 작업에 사용되는 몰드 이형제에 있어서, 수성 용제를 사용함으로써 인체 피해를 줄이고, 방청제의 첨가로 인해 몰드의 부식이 방지되는 장점이 있다.The present invention relates to a rust-preventable mold release agent comprising a rust preventive consisting of K 2 HPO 4 , NANO 3 , sodium silicate and water, and a method for preparing the release agent composition comprising dipropylene glycol monomethyl ether and water and a release blend. In the mold releasing agent used in the mold work which occupies a large proportion of each part of the tea industry, the use of an aqueous solvent reduces the damage to the human body, there is an advantage that the corrosion of the mold due to the addition of the rust inhibitor.

Description

방청수성이형제 및 그 제조방법Antirust molding agent and its manufacturing method

본 발명은 이형제에 관한 것으로 특히 이형제의 용제를 수성으로 하고 여기에 방청제를 첨가하여 제조함으로써, 기존 이형제의 제조시 유성 용제를 사용함으로써 발생하였던 인체에의 피해를 줄이고, 또한 몰드의 부식을 방지할 수 있도록 한 방청수성이형제에 관한 것이다.The present invention relates to a mold releasing agent, in particular, by making the solvent of the releasing agent aqueous and adding a rust preventive agent, thereby reducing damage to the human body caused by using an oil-based solvent in the manufacture of a conventional mold release agent, and also prevents corrosion of the mold. The present invention relates to a rust preventive brother.

현재 날로 심화되고 있는 환경오염과 산업근로자의 건강을 보호하기 위하여 각 방면에 걸쳐 많은 노력이 진행되고 있는데, 이러한 노력은 기초 산업 부문에서도 활발히 벌어지고 있다. 한편 몰드 작업은 1 차 산업의 각 부분에서 매우 비중이 크며 몰드 작업 공정에 있어서 이형제제는 필수적으로 사용되고 있다.A lot of efforts are being made in various fields to protect the environmental pollution and the health of industrial workers, which are intensifying day by day. On the other hand, mold work is very important in each part of the primary industry, and release agents are indispensable in the mold work process.

이 때 일반적으로 이형제란 성형품 금형에서 떨어지는 것을 용이하게 하기 위해 금형에 바르는 약제를 말한다. 그런데 기존의 이형제들은 대부분 유기 용제를 베이스로 사용하기 때문에 이형성은 뛰어나나, 작업시 인체에 해를 주는 경우가 발생하게 된다. 이를 해소하기 위해서는 이형제의 용제를 물로 전환하는 것이 필요한데, 물을 베이스로 한 수성 이형제의 가장 큰 단점은 몰드가 돌과 결합하여 몰드의 부식이 일어난다는 것이다.In this case, the release agent generally refers to a drug applied to a mold in order to facilitate the falling out of the mold. By the way, the existing release agents are excellent in mold release because most of the organic solvent is used as a base, it occurs when the harm to the human body at work. In order to solve this problem, it is necessary to convert the solvent of the release agent into water. The biggest disadvantage of the water-based aqueous release agent is that the mold is combined with stones to cause corrosion of the mold.

본 발명은 상기한 문제점을 해결하기 위해 마련된 것으로 이형제의 용제를 수성으로 함과 동시에 몰드가 부식되지 않도록 방청효과를 갖도록 한 방청수성이형제를 제공하는 것을 목적으로 한다.The present invention has been made to solve the above problems, and an object of the present invention is to provide an anti-rust forming agent having an anti-rusting effect to make the solvent of the release agent aqueous and at the same time not to corrode the mold.

상기한 목적을 달성하기 위하여 본 발명은 디프로필렌글리콜 모노메틸 에테르 1 내지 10중량%, 물 85 내지 95중량% 및 릴리즈 블렌드 1 내지 5% 로 구성된 이형제 조성물에, K2HPO42 내지 5중량%, NANO32 내지 5중량%, 소듐 실리케이트 0.5 내지 2.5중량% 및 물 87 내지 95중량%로 이루어진 방청제를 20 내지 30중량% 첨가한 것임을 특징으로 하는 방청수성이형제를 제공하고 있다.In order to achieve the above object, the present invention provides a release agent composition consisting of 1 to 10% by weight of dipropylene glycol monomethyl ether, 85 to 95% by weight of water and 1 to 5% of release blend, K 2 HPO 4 2 to 5% by weight A rust-preventive molding agent is provided by adding 20 to 30% by weight of a rust-preventing agent consisting of 2 to 5% by weight of NANO 3 , 0.5 to 2.5% by weight of sodium silicate and 87 to 95% by weight of water.

또한 본 발명은 디프로필렌글리콜 모노메틸 에테르 1 내지 10중량%, 물 85 내지 95중량% 및 릴리즈 블렌드 1 내지 5 % 로 구성된 이형제 조성물에, K2HPO42 내지 5중량%, NANO32 내지 5중량%, 소듐 실리케이트 0.5 내지 2.5중량% 및 물 87 내지 95중량5로 이루어진 방청제를 20 내지 30중량% 첨가하여 10 내지 50 ℃에서 30분 이상 교반하는 것을 특징으로 하는 방청수성이형제 제조방법을 제공하고 있다.The present invention also provides a release agent composition consisting of 1 to 10% by weight of dipropylene glycol monomethyl ether, 85 to 95% by weight of water and 1 to 5% of a release blend, K 2 HPO 4 2 to 5% by weight, NANO 3 2 to 5 20 to 30% by weight of a rust preventive agent consisting of weight%, 0.5 to 2.5% by weight of sodium silicate and 87 to 95% by weight of water is added, followed by stirring at 10 to 50 ° C for at least 30 minutes. Doing.

이하 다음의 실시예를 참고로하여 본 발명의 작용효과를 살펴보기로 한다.Hereinafter, the operation and effect of the present invention will be described with reference to the following examples.

본 실시예에서는 디프로필렌글리콜 모노메틸 에테르 약 5중량%와, 물 약 92중량% 및 릴리즈 블렌드 약 3 % 로 구성된 이형제 조성물에, K2HPO4약 5중량%, NANO3약 3중량%, 소듐 실리케이트 약 1.5중량% 및 물 약 90중량%로 이루어진 방청제를 25중량% 첨가하여 30℃에서 1 시간 정도 교반하여 제조한 것을 시료로하여 다음의 시험을 행하였다.In this example, the release agent composition consisting of about 5% by weight of dipropylene glycol monomethyl ether, about 92% by weight of water and about 3% of release blend, about 5% by weight of K 2 HPO 4 , about 3% by weight of NANO 3 , sodium The following test was done using the sample manufactured by adding 25 weight% of the antirust agent which consists of about 1.5 weight% of silicates and about 90 weight% of water, stirring at 30 degreeC for about 1 hour.

[실시예 1]Example 1

본 실시예는 방청유 일반 시험방법인 KSM 2109 의 부식성 시험방법에 따라 행하였으며, 시험편인 알루미늄과 철을 상기 시료에 담그고 각각 55℃에서 7일 동안 보존한 후 시험편의 무게변화 및 겉모양으로부터 부식성을 조사하였다. 시험결과는 다음과 같다.This example was carried out according to the corrosion test method of KSM 2109, a general test method for rust-preventing oil. After immersing aluminum and iron as test pieces in the sample and storing them at 55 ° C. for 7 days, the corrosion resistance from the weight change and the appearance of the test piece was measured. Investigate. The test results are as follows.

Figure kpo00001
Figure kpo00001

[실시예 2]Example 2

본 시료를 사용하여 방청유 염수 분무 시험방법을 행하였다. (KS M 2091) 즉 시료로 피복한 시험편을 온도 35℃에서 염수를 분무하는 장치내에서 48시간 유지한 후 녹발생도를 조사하였다. 녹발생도의 시험방법은 다음과 같다. 즉 시험편 중앙부의 50 × 50 의 측정면에, 측정판(무색 투명하고 60 × 80 mm의 넓이를 가지는 평판으로서, 측정면에 닿는 부분에 나비 약 0.5 mm의 새긴 선으로 1 변이 5 mm인 정사각형 바둑판 눈 100 개를 새긴 것)을 겹쳐서 육안으로 1 점 이상의 녹이 발생되어있는 바둑판 눈의 수를 센다.This sample was used for the rust preventive salt spray test method. (KS M 2091) That is, the test piece coated with the sample was maintained for 48 hours in a device spraying brine at a temperature of 35 ℃ and then rust generation was investigated. The test method of rusting rate is as follows. In other words, a measuring board (a flat plate having a width of 60 × 80 mm, which is colorless and transparent, on a measuring surface of 50 × 50 in the center of the test piece) is a square checkerboard with a side of 5 mm inscribed with a butterfly about 0.5 mm The number of checkerboard eyes in which one or more rust has occurred with the naked eye.

이렇게 규정 시간 동안 시험편 3 매의 녹발생도의 평균치를 정수로 구하여 다음의 등급에 따라 표시한다.In this way, the average value of the rust incidence of three specimens during the specified time is determined as an integer and displayed according to the following grade.

Figure kpo00002
Figure kpo00002

이와 같은 측정 방법에 의하여 본 시료에 대하여 실시한 결과는 다음과 같다.The result of this sample by this measuring method is as follows.

Figure kpo00003
Figure kpo00003

이제까지 설명한 바와 같이 본 발명에 의한 방청수성이형제는 수성용제를 베이스로 하고 여기에 방청제를 첨가하여 방청효과를 부여한 것으로 수성용제의 사용으로 인체에 해가 없으며, 상기 실시예에서 보인 바와 같이 특히 철과 알루미늄에 대하여 방청효과가 뛰어나므로 철과 알루미늄 계통을 원료로 한 몰드를 사용하여 고무, phylon 등을 성형작업하는데 있어 탁월한 효과를 갖는다.As described above, the anti-rust forming agent according to the present invention is based on an aqueous solvent and has been added to the anti-rusting agent to impart anti-rust effect. Thus, the use of the aqueous solvent is not harmful to the human body. Excellent anti-corrosion effect against and aluminum, and has excellent effect in molding rubber, phylon, etc. by using mold based on iron and aluminum system.

Claims (2)

디프로필렌글리콜 모노메틸 에테르 1 내지 10중량%, 물 85 내지 95중량% 및 릴리즈 블렌드 1 내지 5%로 구성된 이형제 조성물에, K2HPO42 내지 5중량%, NANO32 내지 5중량%, 소듐 실리케이트 0.5 내지 2.5중량% 및 물 87 내지 95중량%로 이루어진 방청제가 20 내지 30중량% 첨가된 것임을 특징으로 하는 방청수성이형제.In a release agent composition consisting of 1 to 10% by weight of dipropylene glycol monomethyl ether, 85 to 95% by weight of water and 1 to 5% of release blend, K 2 HPO 4 2 to 5% by weight, NANO 3 2 to 5% by weight, sodium An anti-rust forming agent, characterized in that 20 to 30% by weight of a rust inhibitor consisting of 0.5 to 2.5% by weight of silicate and 87 to 95% by weight of water is added. 디프로필렌글리콜 모노메틸 에테르 1 내지 10중량%, 물 85 내지 95중량%, 및 릴리즈 블렌드 1 내지 5%로 구성된 이형제 조성물에, K2HPO42 내지 5중량%, NANO32 내지 5중량%, 소듐 실리케이트 0.5 내지 2.5중량% 및 물 87 내지 95중량%로 이루어진 방청제를 20 내지 30중량% 첨가하여 10 내지 50 ℃에서 30 분 이상 교반하는 것을 특징으로 하는 방청수성이형제 제조방법.In the release agent composition consisting of 1 to 10% by weight of dipropylene glycol monomethyl ether, 85 to 95% by weight of water, and 1 to 5% of the release blend, 2 to 5% by weight of K 2 HPO 4, 2 to 5% by weight of NANO 3 , 20 to 30% by weight of a rust inhibitor consisting of 0.5 to 2.5% by weight of sodium silicate and 87 to 95% by weight of water, followed by stirring at 10 to 50 ° C for at least 30 minutes.
KR1019970006406A 1997-02-27 1997-02-27 Release agent and its manufacture thereof KR100225485B1 (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10156931B2 (en) 2005-09-08 2018-12-18 Power2B, Inc. Displays and information input devices

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10156931B2 (en) 2005-09-08 2018-12-18 Power2B, Inc. Displays and information input devices

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