KR100216961B1 - Manufacturing method of an excellent flame retardant car's loop fabric and tent's fabric - Google Patents
Manufacturing method of an excellent flame retardant car's loop fabric and tent's fabric Download PDFInfo
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- KR100216961B1 KR100216961B1 KR1019970020534A KR19970020534A KR100216961B1 KR 100216961 B1 KR100216961 B1 KR 100216961B1 KR 1019970020534 A KR1019970020534 A KR 1019970020534A KR 19970020534 A KR19970020534 A KR 19970020534A KR 100216961 B1 KR100216961 B1 KR 100216961B1
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/244—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of halogenated hydrocarbons
- D06M15/248—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of halogenated hydrocarbons containing chlorine
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/32—Polyesters
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/10—Repellency against liquids
- D06M2200/12—Hydrophobic properties
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/30—Flame or heat resistance, fire retardancy properties
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- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
- D10B2331/04—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]
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- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2401/00—Physical properties
- D10B2401/02—Moisture-responsive characteristics
- D10B2401/021—Moisture-responsive characteristics hydrophobic
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- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2505/00—Industrial
- D10B2505/12—Vehicles
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- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2505/00—Industrial
- D10B2505/18—Outdoor fabrics, e.g. tents, tarpaulins
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
본 발명은 방염성이 우수한 차량용 루프 포지 또는 천막지의 제조 방법에 관한 것으로 폴리에스터 원착사(Dope dyed yarn)를 원사로 사용하여 제직한 포지에 브롬계 방염제가 전체 조성물의 15-40 중량부, 클로로화합물 5-10 중량부, 물 50-80 중량부로 구성된 방염수지(A)에 침지하여 방염수지를 충분히 함침시킨 다음 망글 압력 2.0-4.0톤으로 하여 스퀴즈하고 건조 및 카렌더처리를 한 다음 다시 아크릴 바인더와 안료를 함유하는 브롬계 방염제 40-80 중량부, 클로로화합물 10-35 중량부, 염화파라핀 10-25 중량부로 구성된 방염수지(B)를 사용하여 두께 0.5-2.5mm로 1차 나이프 코팅하고 110-140℃에서 30-120초간 건조시킨 다음 그 위에 방염수지(B)로 두께 1.0-3.5mm로 도포하여 2차 나이프 코팅함을 특징으로 하며 이와 같이 하여 얻은 방염포지는 경량성이 부여될 뿐 아니라 방염성이 우수하고 피코팅재와 기포간의 접착력이 우수하여 세탁 견뢰도가 뛰어나며 방수성, 발수성이 뛰어나 우천시에도 가벼워서 운반이 용이한 효과를 가진다.The present invention relates to a method for producing a vehicle roof forge or tent paper having excellent flame retardant, 15-40 parts by weight of the bromine-based flame retardant of the entire composition, chloro compounds in the woven fabric using polyester dyed yarn (Dope dyed yarn) as a yarn Immerse the flame retardant resin (A) consisting of 5-10 parts by weight and 50-80 parts by weight of water to sufficiently immerse the flame retardant resin, squeeze it with 2.0-4.0 tons of mangle pressure, dry and calendered it, and then again acrylic binder and pigment. Using a flame retardant (B) consisting of 40-80 parts by weight of bromine flame retardant containing, 10-35 parts by weight of chloro compound, 10-25 parts by weight of paraffin chloride, the first knife coating to a thickness of 0.5-2.5mm and 110-140 It is dried for 30-120 seconds at ℃ and then coated with a flame retardant resin (B) with a thickness of 1.0-3.5mm, characterized in that the second knife coating and the flame retardant obtained in this way is not only given the lightness Excellent salt and good adhesion between coated material and air bubbles, excellent washing fastness, waterproof and water repellency, light in rainy days, and easy to carry.
Description
본 발명은 방염성이 우수한 차량용 경량 루프 포지의 제조 방법에 관한 것으로, 보다 상세하게는 폴리에스터 원사로 제직한 포지에 아크릴 바인더와 안료를 함유하는 브롬계 방염제와 클로로 화합물 및/또는 염화파라핀으로 이루어진 방염수지로서 함침법과 코팅법을 적용하여 방염성이 우수한 차량용 루프 포지 및 천막지를 제조하는 방법에 관한 것이다.The present invention relates to a method for producing a lightweight roof forge for automobiles having excellent flame retardancy, and more particularly, a flame retardant comprising a bromine flame retardant containing an acrylic binder and a pigment, a chloro compound and / or paraffin chloride in a forged fabric made of polyester yarn. The present invention relates to a method for manufacturing a vehicle roof forge and tent paper having excellent flame resistance by applying an impregnation method and a coating method as a resin.
종래에 일반적으로 사용하고 있는 방염가공 방법으로는 소재를 방염수지에 함침시켜 도포하는 함침법과 소재의 표면에 방염수지를 나이프(knife)로 도포하는 건식나이프 코팅법으로 구분된다.Flame retardant processing methods generally used in the prior art are classified into an impregnation method of impregnating and applying the material to the flame retardant resin and a dry knife coating method of applying the flame retardant resin to the surface of the material with a knife.
함침법에 있어서는 방염수지의 내부침투가 용이하고 도포량의 조절이 가능하나 방염수지의 점도 조절에 세심한 주의가 필요하며 건조 속도가 느려 생산성에 문제점이 있으며, 건식 나이프 코팅법에 있어서는 직물의 경사, 위사의 골과 골 사이에 균일한 코팅과 침투가 어려워 도포량의 한계가 있으며 이로 인해 방염성의 불량과 내구성이 떨어지는 단점이 있고, 원료수지를 혼합할 때 세심한 주위를 기울여야 하며, 고가의 원료를 사용하는 과정에서 교반이 잘못되어 일정하게 분산되지 않았을 때는 그 수지를 사용할 수 없게 작업상의 어려움이 있다. 그 뿐만 아니라 코팅을 위해서 나이프를 일정수준으로 맞추어서 가공함으로써 티끌등 불순물로 인하여 불량율이 높고, 두껍게 코팅함으로써 원재료비가 비싸게 되며 가공속도가 느려 생산성의 한계가 있다.In the impregnation method, it is easy to penetrate the inside of the flame retardant resin and the amount of coating can be controlled, but it is necessary to pay close attention to the control of the viscosity of the flame retardant resin and there is a problem in productivity due to the slow drying speed. Uniform coating between the bone and the bone is difficult to penetrate, which limits the amount of coating. Due to this, there is a disadvantage of poor flame retardancy and durability, and care must be taken when mixing the raw materials, and the process of using expensive raw materials. When the agitation is incorrect and the dispersion is not uniform, there is a difficulty in working so that the resin cannot be used. In addition, by processing the knife to a certain level for the coating process, the defect rate is high due to impurities such as dust, and the thick coating, the raw material cost is expensive and the processing speed is slow, there is a limit of productivity.
또한 종래의 차량용 루프 포지 및 천막지는 천연섬유인 면을 소재로 함으로 우천시 많은 양의 수분을 흡수하여 무게가 무거워지고 중량 과중으로 운반상의 어려움이 따랐다.In addition, the conventional vehicle roof forge and tent paper is made of cotton made of natural fibers to absorb a large amount of moisture in rainy weather, resulting in heavy weight and heavy transport difficulties.
따라서 본 발명은 종래의 함침법에 의한 생산성의 저하를 개선하고, 건식 코팅법에 의한 방염성의 불량과 내구성의 불량을 완전 해결하며 중량 과중에 따른 문제점을 해소하기 위하여 예의 연구한 결과 수분율이 낮은 폴리에스터 원사로 제직된 포지를 소재로 하여 가공이 편리하고 경량성을 부여할 뿐아니라 방염효과가 큰 방염수지를 함침 시킨 후 그 위에 코팅가공 처리를 함으로서 방염성이 우수한 차량용 루프 포지 및 천막지를 개발하게 되어 본 발명을 완성하였다.Therefore, the present invention has been conducted to improve the decrease in productivity by the conventional impregnation method, to completely solve the flame retardancy and durability defects by the dry coating method and to solve the problems caused by heavy weight, low moisture content poly The fabric is made of polyester yarn, which is easy to process and gives light weight, and impregnates the flame-retardant resin with high flame-retardant effect, and then the coating process is applied to it to develop the roof-flag and tent paper for excellent flame-retardant. The present invention has been completed.
본 발명을 상세하게 설명하면 다음과 같다.The present invention will be described in detail as follows.
종래의 차량용 루프 포지 나 천막지는 소재로써 면사 10수 9합사를 사용할 경우 그 중량이 1020g/㎡이었으나, 본 발명은 폴리에스터 원착사(Dope-dyed) 20수 2합 내지 20수 9합으로 가연하여 제직함으로써 생지의 중량을 230∼350g/㎡로 경량화 시킬 수 있다.Conventional vehicle roof forge or tent paper is 1020g / ㎡ when using 10 yarns 9 cotton yarn as a material, but the present invention is flammable to 20 polyesters 2 to 20 polyesters 9 dope-dyed By weaving, the weight of the dough can be reduced to 230 to 350 g / m 2.
이와 같이 하여 얻은 생지 포지를 아크릴 바인더와 안료를 함유하는 브롬계 방염제를 전체 조성물의 15-40 중량부, 클로로 화합물을 5-10 중량부, 물 50-80 중량부로 이루어진 방염수지욕(A) 중에 침지시켜 방염수지를 함침시킨후 망글 압력 2.0-4.0톤으로 하여 스퀴즈(squeeze)하고 건조기에서 90-120℃의 온도하에서 30-120초간 건조시킨 후 1-3mm 두께로 도포한 다음 카렌더링 처리하고 다시 아크릴 바인더와 안료를 함유하는 브롬계 방염제가 40-80 중량부, 클로로 화합물 10-35 중량부 및 염화 파라핀 10-25 중량부로 구성된 방염수지(B)를 사용하여 두께 0.5-2.5mm로 1차 나이프 코팅하고 110-140℃에서 30-120초간 건조시킨 다음 방염수지(B)를 두께 1.0-3.5mm로 도포하여 2차 나이프 코팅을 실시한 후 카렌더링 처리를 실시한다.In the flame retardant bath (A) consisting of 15-40 parts by weight of the bromine flame retardant containing the acrylic binder and the pigment, 5-10 parts by weight of the chloro compound, and 50-80 parts by weight of water. Immerse the flame-resistant resin by immersion, squeeze it with mangle pressure of 2.0-4.0 ton, dry in the dryer for 30-120 seconds at a temperature of 90-120 ℃, apply 1-3mm thick, and then calendering The primary knife with a thickness of 0.5-2.5 mm using a flame retardant (B) composed of 40-80 parts by weight of bromine flame retardant containing an acrylic binder and a pigment, 10-35 parts by weight of chloro compounds and 10-25 parts by weight of paraffin chloride. After coating and drying at 110-140 ° C. for 30-120 seconds, the flame retardant resin (B) was coated with a thickness of 1.0-3.5 mm to carry out a second knife coating, and then subjected to a calendering treatment.
방염수지(A)와 방염수지(B)에 공통적으로 사용하는 브롬계 방염제는 헥사 브로모시클로 도데칸(Hexabromo cyclododecane), 테트라 브로모 에탄(Tetrabromoethan)을 사용하며 본 발명에서는 그린 토너(안료)와 아크릴 바인더가 자체내에 배합된 브롬계 방염제인 파라카본 그린 1852K(독일 쉘 자일라커 사 제품)를 사용한다. 또 방염수지(A)는 상기 브롬계 방염제에 접착성을 부여하기 위하여 염화비닐 클로라이드계의 클로로 화합물을 첨가하며 여기에 물을 50-80 중량부 첨가하므로 실제 방염제 농도는 낮아지게 된다.The bromine flame retardant commonly used for flame retardant (A) and flame retardant (B) uses hexa bromo cyclododecane, tetrabromoethan, and in the present invention, green toner (pigment) and Paracarbon Green 1852K (manufactured by German Shell Xilacker), which is a bromine flame retardant having an acrylic binder incorporated therein, is used. In addition, the flame retardant resin (A) adds a vinyl chloride chloride-based chloro compound in order to give adhesiveness to the bromine flame retardant, and since 50-80 parts by weight of water is added thereto, the actual flame retardant concentration is lowered.
그러나 물의 첨가량을 줄이고 브롬계 방염제을 전체 조성물의 40 중량부 이상으로 하는 경우 소재 내부로 스며드는 방염제의 양이 많아져 방염성은 증가하나 제품이 뻣뻣해져 사용상의 문제점이 제기될 뿐 아니라 함침된 수지가 망글에서 짜일 때 망글의 로울러에 묻어나 세정에 많은 시간과 노력이 소요되어 생산성을 저하시키게 된다. 또 브롬계 방염제가 전체 조성물의 15 중량부 이하인 경우, 방염제의농도가 낮아져 제품의 방염성이 떨어지므로 소기의 목적을 달성할 수 없게 된다. 그러나 방염수지(B)는 상기 브롬계 방염제와 클로로 화합물 이외에 유연성을 부과하기 위하여 염화 파라핀을 전체 조성물의 10-25 중량부 첨가하고 물을 사용하지 않으므로 방염수지의 농도가 높아 건식 나이프 코팅법에 알맞도록 구성된 방염수지인 것이다.However, if the amount of water is reduced and the bromine flame retardant is more than 40 parts by weight of the total composition, the amount of flame retardant that penetrates into the material increases, so that the flame retardancy increases, but the product is stiff. When it is squeezed, it is buried in the roller of the mangle and it takes a lot of time and effort to clean it, which reduces productivity. In addition, when the bromine flame retardant is 15 parts by weight or less of the total composition, the concentration of the flame retardant is lowered, so that the flame retardancy of the product is lowered, so that the intended purpose cannot be achieved. However, the flame retardant resin (B) is suitable for dry knife coating because the concentration of the flame retardant resin is high since 10-25 parts by weight of paraffin chloride is added in addition to the bromine flame retardant and the chloro compound, and water is not used. It is a flameproof resin configured to
이하 본 발명을 실시예에 의거 상세히 설명하면 다음과 같다.Hereinafter, the present invention will be described in detail with reference to Examples.
아래 실시예는 본 발명을 제한하려는 것은 아니다. 또 실시예에서 부는 중량부를 나타낸다.The following examples are not intended to limit the invention. In the examples, parts represent parts by weight.
[실시예 1]Example 1
폴리에스터 원착사 20수 5합으로 가연한 방적사를 경, 위사로 하여 평직으로 제직한 생지를 아크릴 바인더와 안료를 함유하는 브롬계 방염제인 파라카본 그린 1852K(독일 쉘 자일라커 사 제품)를 전체 조성물에 대해서 15.0 부, 염화비닐클로라이드계의 클로로 화합물 5.0 부와 물 80.0 부로 구성된 방염수지(A)에 함침시킨후 망글 압력을 2.5톤으로 하여 스퀴즈하고 1차 건조기에서 95℃×120초간 건조시킨 다음 1.5mm 두께로 나이프 코팅한 후 2차 건조기에서 115℃×120초간 건조시키고 이를 다시 파라카본 그린 1852K가 전체 조성물에 대해서 60 부 염화파라핀 25.0 부, 클로로 화합물 15.0 부로 구성된 방염수지(B)를 1차 나이프 코팅으로 두께 1.5mm로 방염수지를 도포한 다음 100℃×120초간 건조시킨 후 2차 나이프 코팅으로 두께 1.0mm로 도포한 후 100℃×120초간 건조시키고 40℃×5.0톤의 조건으로 최종 카렌더링 처리를 하여 차량용 루프 포지를 완성하였다.The whole composition of paracarbon green 1852K (product of German shell xilacker) which is a brominated flame retardant containing an acrylic binder and a pigment which was woven into a plain weave with a light and weft yarn using a spun yarn of 20 polyester yarns of 5 polyester Impregnated into a flame retardant resin (A) consisting of 15.0 parts, 5.0 parts of a vinyl chloride-based chloro compound and 80.0 parts of water, squeezed with a mangle pressure of 2.5 tons, dried in a first dryer for 95 ° C. × 120 seconds, and then dried. Knife-coated to mm thickness and dried in a secondary dryer for 115 ° C. × 120 seconds, and again, a paracarbon green 1852K was coated with a flame retardant resin (B) consisting of 60 parts of paraffin chloride 25.0 parts and 15.0 parts of chloro compounds for the whole composition. After coating the flame-resistant resin with a thickness of 1.5mm and drying it for 100 ℃ × 120 seconds, it was applied with a second knife coating to the thickness of 1.0mm and then dried for 100 ℃ × 120 seconds and 40 The final calendering process was carried out under the condition of 占 5.0 tons to complete the vehicle roof forge.
이 차량 포지의 물성 측정 결과는 방염도 잔영시간 2초, 탄화길이 8.0cm 이고 발수도 측정결과는 80이었으며 포지의 무게 측정결과는 420g/㎡로서 면을 소재로 한 천막지 보다 약 절반 정도로 가벼워 경량화 효과를 거둘 수 있었다.The measurement results of this vehicle forge were 2 seconds of flame retardancy, 8.0cm of carbonization length and water repellency of 80. The weight of the forge was 420g / m2, which is about half lighter than cotton tent. It worked.
[실시예 2]Example 2
폴리에스터 필라멘트(150/2)를 원사로 하여 직성한 생지를 브롬계 방염제인 파라카본 그린 1852K 40.0 부, 염화비닐클로라이드계의 클로로 화합물 10.0 부, 물 50.0 부로 구성된 방염수지(A)에 함침시킨 후 망글 압력을 2.0톤으로 하여 스퀴즈하고 1차 건조기에서 90℃×30초간 건조시킨 다음 2.0mm 두께로 나이프 코팅한 후 2차 건조기에서 100℃×30초간 건조시킨 후 파라카본 그린 1852K가 전체 조성물에 대해서 80 부 염화파라핀 10 부, 클로로 화합물 10 부로 구성된 방염수지(B)를 1차 나이프 코팅층의 두께를 1.0mm로 도포한 후 100℃×60초간 건조시킨 다음 다시 2차 나이프 코팅층의 두께를 1.0mm로 도포하고 건조 후 80℃×2.톤의 조건 카렌더링 처리를 하여 텐트 포지를 완성하였다.After impregnating the dough made of polyester filament (150/2) with yarn, the flame retardant (A) composed of 40.0 parts of brominated flame retardant paracarbon green 1852K, 10.0 parts of vinyl chloride-based chloro compound and 50.0 parts of water Squeeze the mangle pressure to 2.0 tons, dry at 90 ° C × 30 seconds in the primary dryer, knife-coated to 2.0 mm thickness, and dry at 100 ° C × 30 seconds in the secondary dryer, and then Paracarbon Green 1852K A flame retardant resin (B) consisting of 10 parts of 80 parts paraffin chloride and 10 parts of chloro compounds was applied with a thickness of 1.0 mm for the first knife coating layer, dried at 100 ° C. for 60 seconds, and then again to a thickness of 1.0 mm for the second knife coating layer. After application | coating and drying, it carried out the condition calendering process of 80 degreeC x 2.ton, and completed the tent forge.
이 텐트 포지의 물성 측정 결과는 방염도 잔영시간 2초이며 탄화길이 8.0으로 우수하며 발수도 측정결과는 85이며 포지의 무게 측정결과는 380g/㎡으로 면을 소재로 한 경우 보다 절반 이상 가벼워 경량화를 기할 수 있다.The properties of this tent forge are 2 seconds of flame retardancy, excellent carbonization length of 8.0, water repellency measurement of 85, and weight of the forge is 380g / m², which is more than half lighter than cotton. It can be done.
상기한 바와 같이 제조한 차량용 포지 및 천막지는 수분율이 낮은 폴리에스터 필라멘트사 또는 스펀사를 원사로 사용하였으므로 경량성을 부여할 뿐만 아니라, 방염성이 우수하고 피코팅재와 기포간의 접착력이 우수하여 세탁 견뢰가 뛰어나며 방수성, 발수서이 뛰어나 우천시에도 가벼워서 운반이 용이한 효과를 가진다.Vehicle forge and tent paper manufactured as described above are made of polyester filament yarn or spun yarn having a low moisture content as a yarn, which not only imparts lightness, but also has excellent flame retardancy and excellent adhesion between the coating material and the air bubble, thereby ensuring fast washing. It is excellent in water resistance and water repellent, so it is light even in rainy days and has easy carrying effect.
Claims (3)
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1019970020534A KR100216961B1 (en) | 1997-05-24 | 1997-05-24 | Manufacturing method of an excellent flame retardant car's loop fabric and tent's fabric |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1019970020534A KR100216961B1 (en) | 1997-05-24 | 1997-05-24 | Manufacturing method of an excellent flame retardant car's loop fabric and tent's fabric |
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| Publication Number | Publication Date |
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| KR19980084686A KR19980084686A (en) | 1998-12-05 |
| KR100216961B1 true KR100216961B1 (en) | 1999-09-01 |
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| Application Number | Title | Priority Date | Filing Date |
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| KR1019970020534A KR100216961B1 (en) | 1997-05-24 | 1997-05-24 | Manufacturing method of an excellent flame retardant car's loop fabric and tent's fabric |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101429657B1 (en) * | 2012-12-12 | 2014-08-13 | 지엘테크텍 주식회사 | Awning outstanding flame proofing, water repellent, water proofing property and manufacture method therefor |
| CN104894888A (en) * | 2015-05-19 | 2015-09-09 | 江苏工程职业技术学院 | A dyeing and finishing process of a mosquito- and fly- repelling waterproof flame-retardant tent fabric |
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1997
- 1997-05-24 KR KR1019970020534A patent/KR100216961B1/en not_active IP Right Cessation
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101429657B1 (en) * | 2012-12-12 | 2014-08-13 | 지엘테크텍 주식회사 | Awning outstanding flame proofing, water repellent, water proofing property and manufacture method therefor |
| CN104894888A (en) * | 2015-05-19 | 2015-09-09 | 江苏工程职业技术学院 | A dyeing and finishing process of a mosquito- and fly- repelling waterproof flame-retardant tent fabric |
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| Publication number | Publication date |
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| KR19980084686A (en) | 1998-12-05 |
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