KR100216622B1 - Regeneration antibacterial nonwoven fabric and manufacturing method - Google Patents
Regeneration antibacterial nonwoven fabric and manufacturing method Download PDFInfo
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- KR100216622B1 KR100216622B1 KR1019960043617A KR19960043617A KR100216622B1 KR 100216622 B1 KR100216622 B1 KR 100216622B1 KR 1019960043617 A KR1019960043617 A KR 1019960043617A KR 19960043617 A KR19960043617 A KR 19960043617A KR 100216622 B1 KR100216622 B1 KR 100216622B1
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- nonwoven fabric
- antimicrobial
- treatment
- antibacterial
- fiber
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- 239000004745 nonwoven fabric Substances 0.000 title claims abstract description 49
- 230000000844 anti-bacterial effect Effects 0.000 title claims abstract description 20
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 5
- 230000008929 regeneration Effects 0.000 title 1
- 238000011069 regeneration method Methods 0.000 title 1
- 230000000845 anti-microbial effect Effects 0.000 claims abstract description 23
- 238000000034 method Methods 0.000 claims abstract description 16
- 239000000835 fiber Substances 0.000 claims abstract description 11
- 239000000126 substance Substances 0.000 claims abstract description 11
- 239000004902 Softening Agent Substances 0.000 claims abstract description 6
- 238000005097 cold rolling Methods 0.000 claims abstract description 6
- 229920002972 Acrylic fiber Polymers 0.000 claims abstract description 4
- 238000002347 injection Methods 0.000 claims abstract 2
- 239000007924 injection Substances 0.000 claims abstract 2
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 claims description 4
- 239000004744 fabric Substances 0.000 claims description 4
- 230000003204 osmotic effect Effects 0.000 claims description 3
- 238000004925 denaturation Methods 0.000 claims description 2
- 230000036425 denaturation Effects 0.000 claims description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims 2
- 238000006424 Flood reaction Methods 0.000 claims 1
- 238000007602 hot air drying Methods 0.000 claims 1
- 230000008595 infiltration Effects 0.000 claims 1
- 238000001764 infiltration Methods 0.000 claims 1
- 229910052742 iron Inorganic materials 0.000 claims 1
- 239000004599 antimicrobial Substances 0.000 abstract description 4
- 239000005003 food packaging material Substances 0.000 abstract description 3
- 238000007664 blowing Methods 0.000 abstract description 2
- 238000005507 spraying Methods 0.000 abstract description 2
- 230000003100 immobilizing effect Effects 0.000 abstract 1
- 239000000463 material Substances 0.000 description 12
- 241000894006 Bacteria Species 0.000 description 8
- 244000005700 microbiome Species 0.000 description 8
- 229920001817 Agar Polymers 0.000 description 5
- 239000008272 agar Substances 0.000 description 5
- 230000003115 biocidal effect Effects 0.000 description 5
- 238000004659 sterilization and disinfection Methods 0.000 description 5
- 241000588724 Escherichia coli Species 0.000 description 3
- 241000233866 Fungi Species 0.000 description 3
- 241000588747 Klebsiella pneumoniae Species 0.000 description 3
- 241000191967 Staphylococcus aureus Species 0.000 description 3
- 229910000365 copper sulfate Inorganic materials 0.000 description 3
- 238000012258 culturing Methods 0.000 description 3
- 238000007654 immersion Methods 0.000 description 3
- 208000014674 injury Diseases 0.000 description 3
- 239000002609 medium Substances 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 230000001954 sterilising effect Effects 0.000 description 3
- 230000008733 trauma Effects 0.000 description 3
- 235000014469 Bacillus subtilis Nutrition 0.000 description 2
- 241000222122 Candida albicans Species 0.000 description 2
- 206010016952 Food poisoning Diseases 0.000 description 2
- 208000019331 Foodborne disease Diseases 0.000 description 2
- 241000293869 Salmonella enterica subsp. enterica serovar Typhimurium Species 0.000 description 2
- 241001045770 Trichophyton mentagrophytes Species 0.000 description 2
- 229940095731 candida albicans Drugs 0.000 description 2
- 230000000249 desinfective effect Effects 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 244000053095 fungal pathogen Species 0.000 description 2
- 241000222120 Candida <Saccharomycetales> Species 0.000 description 1
- 241000588748 Klebsiella Species 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 241000607142 Salmonella Species 0.000 description 1
- 241000191940 Staphylococcus Species 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 244000052616 bacterial pathogen Species 0.000 description 1
- 241000385736 bacterium B Species 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 239000002274 desiccant Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000001963 growth medium Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 230000005180 public health Effects 0.000 description 1
- 238000004080 punching Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/38—Oxides or hydroxides of elements of Groups 1 or 11 of the Periodic Table
- D06M11/42—Oxides or hydroxides of copper, silver or gold
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H13/00—Other non-woven fabrics
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
- D06B1/00—Applying liquids, gases or vapours onto textile materials to effect treatment, e.g. washing, dyeing, bleaching, sizing or impregnating
- D06B1/02—Applying liquids, gases or vapours onto textile materials to effect treatment, e.g. washing, dyeing, bleaching, sizing or impregnating by spraying or projecting
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
- D06B3/00—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating
- D06B3/10—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of fabrics
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M10/00—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements
- D06M10/04—Physical treatment combined with treatment with chemical compounds or elements
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2401/00—Physical properties
- D10B2401/13—Physical properties anti-allergenic or anti-bacterial
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Absorbent Articles And Supports Therefor (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
본 발명은 양전하를 가진 항균성 화학물질을 아크릴섬유 부직포에 침지 또는 분사하여 고온처리 하므로서 양전하를 대전케한 후 변성 처리하여서 된 항균 부직포를 제공하며, 이같은 항균성 화학물질은 양전하를 섬유분자에 적재할 수 있는 황산동 등을 주재로하며 그 방법으로서 냉간압연천공과 섬유침수, 연화제 주입과 저온 열풍 공정을 특징으로 하는 부직포의 제조방빕을 아울러 제공한다. 이같은 부직포를 이용하는 제품으로는 여성용 생리대, 의료용 까운, 식품 포장재 등 각종 위생 및 병원용품을 제공한다.The present invention provides an antibacterial nonwoven fabric obtained by immobilizing and then treating a positive charge by immersing or spraying an antimicrobial chemical having a positive charge on a nonwoven fabric of acrylic fiber and treating the same at high temperature. Such antimicrobial chemical can be loaded on a fiber molecule And the manufacturing method of the nonwoven fabric characterized by the cold rolling perforation, the fiber flooding, the softening agent injection, and the low temperature hot air blowing process is provided. Products using these nonwoven fabrics include sanitary and hospital products such as feminine sanitary napkins, medical shoes, and food packaging materials.
Description
그림 제1도는 변성 처리한 항균 부직포 단면도Figure 1 shows the cross-section of the antibacterial nonwoven fabric subjected to the denaturation treatment.
제2도는 삼투처리후 형성된 그물형 항균 부직포 단면도FIG. 2 is a cross-sectional view of a net type antimicrobial nonwoven fabric formed after the osmosis treatment
제3도는 연화처리후 팽창 표변으로 회복된 항균 부직포 단변도FIG. 3 shows the antibacterial nonwoven fabric short side recovered by the expansion surface after the softening treatment
제4도는 본 발명품으로 만든 제품 중 생리대의 단면도FIG. 4 is a cross-sectional view of the sanitary napkin
사진도 제1도는 Candida albicans(ATCC 28366)Photo 1 also shows Candida albicans (ATCC 28366)
제2도는 Trichophyton mentagrophytes (ATCC 34551)The second figure shows that Trichophyton mentagrophytes (ATCC 34551)
제3도는 E.coli(ATCC 29050)The third figure shows that E. coli (ATCC 29050)
제4도는 B.subtilis (ATCC 6633)FIG. 4 is a photograph of B. subtilis (ATCC 6633)
제5도는 Salmonella typhimurium (ATCC 19214)FIG. 5 shows the results of Salmonella typhimurium (ATCC 19214)
제6도는 Staphylococcus aureus.(Hoechst 121 E)Figure 6 shows the results of Staphylococcus aureus. (Hoechst 121 E)
제7도는 Klebsiella pneumoniae (Hoechst 31660 QR)를 각각 공시 재료로 하여 실험한 본 발명 제품의 한천배지(agar plate)상에서 배양중 항균효과를 보인 것이다.FIG. 7 shows the antimicrobial effect of the present invention on an agar plate of Klebsiella pneumoniae (Hoechst 31660 QR) as a test material.
* 도면의 주요부분에 대한 부호의 설명DESCRIPTION OF THE REFERENCE NUMERALS
1 : 항균 부직포 재료 2 : 각종 서로 다른 안감 재료1: Antibacterial nonwoven material 2: Various lining materials
본 발명은 직조하지 않은 천(fabric)을 변성 처리한 항균 부직포 및 그 제조방법에 관한 것이다. 부직포는 그 사용범위가 매우 넓어 일회용 의료 위생용품으로부터 외상 치료용 병원용품에 이르기까지 다양하다.The present invention relates to an antibacterial nonwoven fabric obtained by modifying a fabric which is not woven and a method for producing the same. Non-woven fabrics have a wide range of applications, ranging from disposable medical hygiene products to trauma treatment hospital products.
현재 시장에서 제조되어 판매·사용되고 있는 상기 목적의 부직포 제품은 모두 소독·살균과정을 거쳐야만 사용할 수 있는 실정이다. 또 소독·살균 과정을 거친다 하더라도 제품의 저장, 운반 및 사용 중에 또 다른 오염을 용이하게 받는 문제점이 있었다.The above nonwoven fabric products which are currently manufactured and marketed and used in the market can be used only after being subjected to a disinfection and sterilization process. Even if the product is subjected to a disinfection / sterilization process, another contamination is easily encountered during storage, transportation and use of the product.
본 발명의 목적은 시장에서 판매·사용되는 부직포 제품이 모두 항균작용이 없어 사용범위를 제한하는 단점을 극복하는데 있다.An object of the present invention is to overcome the disadvantage that the nonwoven products sold and used in the market have no antimicrobial action and their use range is limited.
본 발명의 또 다른 목적은 삼투성과 흡습성이 강력한 부직포 제품을 제공함에 있다. 본 발명의 또 다른 목적은 재질이 유연하고도 견고한 부직포 제품을 제공함에 있다. 본 발명의 또 다른 목적은 시장에서 판매·사용중에도 계속적으로 항균작용이 있는 부직포를 제공하는데 있다.Another object of the present invention is to provide a nonwoven fabric product having high permeability and hygroscopicity. A further object of the present invention is to provide a nonwoven fabric product which is flexible and robust in material. It is another object of the present invention to provide a nonwoven fabric having an antibacterial effect continuously even during sale and use in the market.
본 발명 항균 부직포와 그 제조방법을 당업자가 이해할 수 있도록 공정별로 상세히 설명하면 다음과 같다.The antibacterial nonwoven fabric of the present invention and its preparation method will be described in detail below in order to understand those skilled in the art.
제1공정 : 항균성 화핵물질 처리공정Step 1: Process of treating antimicrobial nucleus material
양전하를 섬유분자에 적재할 수 있는 화학물질(황산동 등)을 주재로 하는 항균성 화학물질을 부직포 침지 시키거나 분사시켜 일정시간 동안 방치 한다. 이때 부직포섬유 선형고분자 사슬에 항균기단(AntiBacterial group)이접하게 된다.An antimicrobial chemical based on a chemical substance (such as copper sulfate) capable of loading a positive charge onto a fiber molecule is immersed or sprayed in a nonwoven fabric and allowed to stand for a certain period of time. At this time, the anti-bacterial group is attached to the non-woven fiber linear polymer chain.
제2공정 : 고온처리공정Second step: High temperature treatment process
항균기단이 헝성된 부직포를 고온 처리하여 양전하(Positive charge)가 섬유적층을 이탈하지 않도록 고정시킨다.The nonwoven fabric having the antibacterial base layer is treated at a high temperature to fix the positive charge so as not to deviate from the fiber laminate.
제3공정 : 삼투처리공정Third step: Osmosis treatment process
항균기단이 고정된 부직포를 기계 냉간 압연 천공한 후 침수제를 주입하여 침수처리를 수행한다. 이I렇게 기계 냉간 압연 천공한 후 침수제로 화학 처리하여된 항균 부직포는 섬유표면의 액체장력이 현저히 감소되어 삼투성과 흡수성이 크게 향상된다.The nonwoven fabric with the antimicrobial base fixed therein is subjected to mechanical cold rolling, and then the immersion fluid is injected to perform immersion treatment. In this antibacterial nonwoven fabric treated by mechanical cold treatment after cold rolling, the liquid tension on the fiber surface is remarkably reduced and the osmosis and absorbency are greatly improved.
제4공정 : 연화처리공정Step 4: Softening treatment process
삼투 처리된 항균부직포를 연화제에 침지하여 저온열퐁건조 시키거나 동 항균부직포에 공기핌프를 이용하여 연화제를 분사시킨다. 이 공정을 거친 항균 부직포는 본래의 부직포와 같이 섬유표면이 팽창되어 부직포의 유연성이 크게 향상된다.The osmotic treated nonwoven fabric is immersed in a softening agent to form a low-temperature heat-fusing drying agent, or the softening agent is sprayed on the antibacterial nonwoven fabric using air pimps. The antibacterial nonwoven fabric that has undergone this process is expanded in the same manner as the original nonwoven fabric, and the flexibility of the nonwoven fabric is greatly improved.
제1내지 제4공정을 거쳐 제조된 항균 부직포는 변성된 부직포로서 우수한 삼투성, 흡습성, 유연성이 있어서 여성용 생리대, 아기용 기저귀, 종이로 만든 속바지, 보호깔개 등 1회응 위생용품과 마스크, 침대시트, 이불보, 베개포, 수술븍, 수술용모자, 깔개, 붕대, 까운등 병원응품 및 식품 포장재를 제공할 수 있다.The antibacterial nonwoven fabric manufactured through the first to fourth steps is a denatured nonwoven fabric having superior osmosis, hygroscopicity, and flexibility, and can be used as a sanitary article for women, a diaper for baby, a shorts made of paper, , Bedclothes, pillow bags, surgical caps, surgical caps, rugs, bandages, and so on.
이와 같이 제조된 항균성부직포(Antibacterial fabric)는 양전하(Positive Charge)를 부여할 수 있는 어떠한 항균성 화학물질(Antibacterial Chemical Substance)을 사용하여도 좋다.The antimicrobial fabric thus manufactured may use any antimicrobial chemical substance capable of imparting a positive charge.
중요한 것은 부직포의 섬유분자의 배열을 변경할 수 있는 항균성 화학물질을 사용하는데 있다. 더욱 증요한 것은 항균성 물질이 처리된 섬유 고분자 사슬에 각각 양전하를 가진 항균기단을 접하게 하여 양전하가 적재되게 하는데 있다.What is important is the use of antimicrobial chemicals that can alter the arrangement of fiber molecules in the nonwoven. More importantly, the antimicrobial base having a positive charge is brought into contact with the fiber polymer chain treated with the antimicrobial substance, so that the positive charge is loaded.
일반적으로 병원성 세균은 물론 대부분의 세균들은 음전하(Negative Charge)를 띠고 있기 때문에 이러한 전기적 대전 특성에 근거하여 양이온이 대전된 부직포는 효과적이고 연속적인 세균억제 작용을 하게 된다.Generally, most bacteria, as well as pathogenic bacteria, are negatively charged. Therefore, based on such electrical charging characteristics, the cation-charged nonwoven fabric has an effective and continuous antibacterial action.
이하에는 본 발명의 구성과 효과를 나타내기 위하여 상세한 설명을 실시예를 들어 설명한다.DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS Hereinafter, the present invention will be described in detail with reference to the accompanying drawings.
[실시예 1][Example 1]
황산동(CuSO4)을 주재로한 항균성 화학물질을 아크릴 섬유(arcrylic fiber) 부직포에 스프레이로 분사하여 3시간 방치한 다음 고온 열풍 처리하였다.(제1도)An antimicrobial chemical substance based on copper sulfate (CuSO 4 ) was sprayed on an acrylic fiber nonwoven fabric by spraying and allowed to stand for 3 hours, followed by hot hot air treatment (FIG. 1)
고온처리하여 섬유 선형 고분자 사슬에 양이온 기단이 적재 고정된 부직포를 변성처리하기 위하여 냉간 압연 천공기에 넣어 직경 1mm 이하의 원형 구멍을 천공하여 그물모양의 부직포를 형성하였다.(제2도)In order to denature the nonwoven fabric having the cation radicals fixed on the fiber linear polymer chains by high temperature treatment, circular holes having a diameter of 1 mm or less were drilled in the cold-rolled perforator to form a net-like nonwoven fabric.
원형구멍이 천공된 그물 모양의 부직포를 침수제를 주입하여 침수 처리하였다. 그 다음 연화제를 주입하고 연화 처리하였다. 이를 즉시 저온 열풍 건조기를 사용하여 저온열풍을 송퐁하이 부직포 표면을 팽창시켜 변성 처리된 항균 부직포를 제조하였다.(제3도)The nonwoven fabric netted with a circular hole was immersed in a water immersion fluid. The softener was then injected and softened. This was immediately followed by a low-temperature hot air dryer to expand the surface of the ponge-up nonwoven fabric to produce a denatured antimicrobial nonwoven fabric (FIG. 3).
변성 처리된 항균 부직포로 생리대를 제조하였다.(제4도)A sanitary napkin was fabricated from a denatured antimicrobial nonwoven fabric (FIG. 4).
[실시예 2][Example 2]
황산동(CuSO4)을 주재로한 항균성 화학물질을 아크릴 섬유(arcrylic fiber) 부직포에 침지 시키고 5시간 방치한 다음 고온 열풍 처리하였다.(제1도)An antimicrobial chemical substance based on copper sulfate (CuSO 4 ) was immersed in an acrylic fiber nonwoven fabric and allowed to stand for 5 hours, followed by hot hot air treatment (Fig. 1)
이렇게 하여 양이온이 적재되어 양하전이 고정된 부직포를 변성 처리하기 위하여 냉간 압연 천공기를 사용 다변형의 구멍을 천공하므로서 그물 모양의 부직포를 형성하였다.(제2도)In order to modify the nonwoven fabric in which the positive ions were fixed and the positive charge was fixed in this way, a net-like nonwoven fabric was formed by punching holes of polystyrene using a cold-rolling perforator (FIG.
다변형 구멍이 천공된 부직포를 연화제를 주입하여 연화 처리한 다음 공기 펌프를 사용하여 저온 열퐁을 송풍하여 부직포 표면을 팽창시켜 변성 처리된 항균부직포를 제조하였다.(제3도)The nonwoven fabric having perforated multi-punched holes was softened by pouring a softening agent, followed by blowing a low-temperature thermal pond using an air pump to expand the surface of the nonwoven fabric to produce a denatured antimicrobial nonwoven fabric (FIG. 3).
변성 처리된 항균 부직포를 이용하여 보호깔개를 제조하였다.A protective mat was prepared using the denatured antimicrobial nonwoven fabric.
본 발명을 위생용품, 외상치료용, 병원용품 및 식품 포장재로의 광범위한 사용예를 위하여, 사싱균(Fungi)과 일반 세균 및 항생제 내성 세균을 공시재료로하여 실험하였다. 사상균으로는 Cand ida속과 Trichoplhyton 속균주를 사용하고, 일반세균으로는 E.coli 와 B.subtilis를 사용하였다.In order to widely use the present invention as a sanitary article, a trauma treatment article, a hospital article and a food packaging material, Fungi, a common bacterium and an antibiotic resistant bacterium were used as test materials. Candida id and Trichoplhyton strains were used as the filamentous fungi, and E. coli and B subtilis were used as general bacteria.
또한 식중독 유발 세균으로 Salmonella 속균주를 사용하였다. 항생제 내성 세균으로는 Staphylococcus속과 Klebsiella 속균주가 각각 사용되었다.Salmonella spp. Was used as food poisoning bacteria. Staphylococcus spp. And Klebsiella spp. Were used as antibiotic resistant bacteria, respectively.
[실험예 1][Experimental Example 1]
병원성 사상균 Candida albicans(ATCC 28366)를 공시 재료로하여 무균실에서 공지의 한천배지(Agar plate)에 접종한 후 본 발명제품인 변성 처리된 항균 부직포의 작은 천을 직경1.5cm 원형으로 잘라 아가배지상에 적치한 후 2일후 생육 상태를 관찰한 결과 본 발명제품이 적치된 곳에서는 공시 미생물의 성장 발육이 완전히 억제되어 있었다.(사진도 제1도)Using a virulent pathogenic fungus Candida albicans (ATCC 28366) as a starting material, the cells were inoculated into a known agar plate in a clean room and then a small fabric of the modified antimicrobial nonwoven fabric of the present invention was cut into a 1.5 cm diameter circular shape, As a result of observing the growth state two days after, the growth and development of the disclosed microorganism was completely inhibited in the place where the present invention product was placed (Fig. 1)
[실험예 2][Experimental Example 2]
병원성 사상균 Trichophyton mentagrophytes(ATCC 34551)를 공시 재료로 하여 실험예 1과 동일하게 무균실에서 작업하여 3일간 배양 결과는 사진도 제2도에서 보는바와 같이 공시 미생물의 성장발육이 완전히 억제되어 있었다.As shown in FIG. 2, the growth and development of the disclosed microorganisms were completely inhibited as shown in FIG. 2 as a result of culturing for 3 days in a clean room in the same manner as in Experimental Example 1, using the pathogenic fungus Trichophyton mentagrophytes (ATCC 34551) as a test material.
[실험예 3][Experimental Example 3]
일반세균 E.coli(ATCC 29050)를 공시 재료로하여 실험예 2와 동일하게 무균실에서 작업하여 1I일간 배양한 결과는 사진도 제3도에서 보는바와 같이 공시 미생물의 성장발육이 완전히 억제되어 있었다.As in Experimental Example 2, using the common bacterium E. coli (ATCC 29050) as a test material, the growth and development of the disclosed microorganisms were completely inhibited as shown in FIG.
[실험예 4][Experimental Example 4]
일반세균 B.subtilis(ATCC 6633)를 공시 재료로하여 실험예3과 동일하게 무균실에서 작업하여 1일간 아가배지에서 배양한 결과는 사진도 제4도에서 보는바와 같이 공시 미생물의 성장발육이 완전히 억제되어 있었다.As in Experimental Example 3, using the common bacterium B.subtilis (ATCC 6633) as a test material, the result of culturing in an aseptic culture medium for 1 day in a clean room showed that the growth and development of the disclosed microorganisms were completely inhibited .
[실험예 5][Experimental Example 5]
식중독 유발세균 Salmonella typhimurium(ATCC 19214)를 공시 재료로하여실험예 3과 동일하게 무균실에서 작업하여 1일간 한천배지에서 배양한 결과는사진도 제5도에서 보는바와 같이 공시 미생물의 성장발육이 완전히 억제되어있었다.As shown in FIG. 5, the results of culturing in an agar medium for 1 day in an aseptic chamber in the same manner as in Experimental Example 3 using the food poisoning-causing bacteria Salmonella typhimurium (ATCC 19214) as a test material showed that the growth and development of the disclosed microorganisms were completely inhibited .
[실험예 6][Experimental Example 6]
항생제 내성 세균 Staphylococcus aureus (Hoechst 121 E)를 공시 재료로하여 실험예 3과 동일하게 무균실에서 작업하여 1일간 한천배지에서 배양한 결과는 사진도 제6도에서 보는바와 같이 공시 미생물의 성장발육이 완전히 억제되어 있었다.As shown in FIG. 6, when the antibiotic-resistant bacterium Staphylococcus aureus (Hoechst 121 E) was used as a test material and incubated in a clean room for 1 day in an agar medium as in Experimental Example 3, the growth and development of the disclosed microorganisms were completely .
[실험예 7][Experimental Example 7]
항생제 내성세균 Klebsiella Pneumoniae (Hoechst 31660 QR}를 공시재료로 하여 실험예 3과 동일하게 무균실에서 작업하여 1일간 한천배지에서 배양한 결과는 사진도 제7도에서 보는바와 같이 공시 미생물의 성장발육이 완전히 억제되어 있었다.As shown in FIG. 7, when the antibiotic resistant bacterium Klebsiella pneumoniae (Hoechst 31660 QR) was used as a test material in the same manner as in Experimental Example 3 and cultured in an agar medium for 1 day, the growth and development of the disclosed microorganism were completely .
이와 같이 본 발명의 제조방법에 의하여 제조된 항균 부직포는 사상균은 물론 일반세균 특히 항생제 내성균주에 이르기까지 광범위한 미생물균주에 대하여 소독, 살균효과가 있고 나아가 항생제 내성균주인 Staphylococcus aureus 및 Klebsiella Pneumoniae에 대해서도 살균효과가 인정되어 위생용품으로부터 외상치료용 병원용품 및 식품포장재에 이르기까지 다양한 위생 제품으로 사용할 수 있으므로 국민보건 및 산업상 매우 유용한 발명이다.As described above, the antibacterial nonwoven fabric produced by the production method of the present invention has a disinfecting and disinfecting effect against a wide range of microorganism strains ranging from fungi to general bacteria, especially antibiotic resistant bacteria, and furthermore, it has sterilization effect against Staphylococcus aureus and Klebsiella pneumoniae , It can be used as a variety of sanitary products ranging from sanitary products to hospital products for trauma treatment and food packaging materials, which is a very useful invention in public health and industry.
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