KR100208779B1 - Light weight aggregate and the method of producing thereof - Google Patents
Light weight aggregate and the method of producing thereof Download PDFInfo
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- KR100208779B1 KR100208779B1 KR1019960020089A KR19960020089A KR100208779B1 KR 100208779 B1 KR100208779 B1 KR 100208779B1 KR 1019960020089 A KR1019960020089 A KR 1019960020089A KR 19960020089 A KR19960020089 A KR 19960020089A KR 100208779 B1 KR100208779 B1 KR 100208779B1
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B20/00—Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
- C04B20/02—Treatment
- C04B20/04—Heat treatment
- C04B20/06—Expanding clay, perlite, vermiculite or like granular materials
- C04B20/061—Expanding clay, perlite, vermiculite or like granular materials in rotary kilns
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B14/02—Granular materials, e.g. microballoons
- C04B14/04—Silica-rich materials; Silicates
- C04B14/10—Clay
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B18/00—Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B18/04—Waste materials; Refuse
- C04B18/06—Combustion residues, e.g. purification products of smoke, fumes or exhaust gases
- C04B18/10—Burned or pyrolised refuse
- C04B18/101—Burned rice husks or other burned vegetable material
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B20/00—Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
- C04B20/10—Coating or impregnating
- C04B20/1055—Coating or impregnating with inorganic materials
- C04B20/1066—Oxides, Hydroxides
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Structural Engineering (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Environmental & Geological Engineering (AREA)
- Civil Engineering (AREA)
- Thermal Sciences (AREA)
- Physics & Mathematics (AREA)
- Inorganic Chemistry (AREA)
- Combustion & Propulsion (AREA)
- Dispersion Chemistry (AREA)
- Processing Of Solid Wastes (AREA)
- Road Paving Structures (AREA)
Abstract
본 발명은 건축물 및 도로포장시 사용되는 경량골조 및 제조방법에 관한 것으로서, 전체중량을 90로 기준하여 산화규소(SiO2)가 59, 산화 알루미늄(Al2O3) 19, 산화칼륨(CaO3) 5, 산화철(Fe2O3) 2, 조성비를 가지는 점토에 애쉬 4와 물10와 벙커C유를 1를 투입하여 내부온도가 1150∼1200℃의 온도를 가지는 로터리 키른(8)을 통과시켜 성형하여 선발명에서 발생되는 1·2차 소성공정을 1차의 소성공정으로 단축시키고 부재료의 종류를 절감하여 단시간내에 골재를 성형함으로써 생산성을 높일 수 있음은 물론 에너지 절감효과를 가져오고 양질의 경량골재를 생산할 수 있는 발명이다.BACKGROUND OF THE INVENTION 1. Field of the Invention [0001] The present invention relates to a lightweight frame used in buildings and road paving, (SiO 2 ) was 59 , Aluminum (Al 2 O 3) 19 oxide , Potassium (CaO 3) 5 oxidation , Iron oxide (Fe 2 O 3 ) 2 , And clay having a composition ratio of Ash 4 And water 10 And bunker C oil 1 Is passed through a rotary kiln (8) having an internal temperature of 1150 to 1200 ° C to shorten the primary and secondary firing processes generated in the name of the firing process to the primary firing process, It is possible to increase the productivity by molding the aggregate in a short time, and it is an invention that can produce energy saving effect and produce high quality lightweight aggregate.
Description
제1도는 본 발명의 제조공정을 나타낸 공정도.FIG. 1 is a process diagram showing a production process of the present invention. FIG.
* 도면의 주요부분에 대한 부호의 설명DESCRIPTION OF THE REFERENCE NUMERALS
1 : 공급기 2 : 믹서기1: Feeder 2: Mixer
3 : 물탱크 4 : 스크류 콘베이어3: Water tank 4: Screw conveyor
5 : 터브레이터 6 : 이송 콘베이어5: Turbler 6: Feed conveyor
7 : 연돌 8 : 로터리 키튼7: Stackable 8: Rotary Kitten
9 : 에프론 콘베이어 10 : 냉각로9: Ephron conveyor 10: Cooling furnace
본 발명은 건축물 및 도로포장시 사용되는 경량골조 및 제조방법에 관한 것으로서, 특히 대량생산이 가능하고 방수성이 우수하며 내진성을 가지도록 한 외피에 피막이 형성된 경량골조 및 그 제조방법에 관한 것이다.BACKGROUND OF THE INVENTION 1. Field of the Invention [0002] The present invention relates to a lightweight frame and a method of manufacturing the same, and more particularly, to a lightweight frame and a method of manufacturing the same.
일반적으로 건축물이나 도로포장시 사용되는 골조는 화강암이나 현무암등의 자연석을 작은 입자로 파쇄하여 이를 시멘트등과 혼합하여 사용하여 왔던바, 골조를 자연석으로 사용하기 때문에 골조를 구입하기 위하여서는 환경 파괴가 필연적으로 발생되는 문제점이 있어 최근에는 탄광 폐석을 이용한 골조(특허공고 제80-1054호)나 구상 발포 플라스틱 표면에 토양을 코팅하거나 또는 토양과 유사한 무기질 세립이나 시멘트와 경화제를 첨가 교반하여서 된 점주액을 코팅하여 형성한 경량골재(특허공고 제76-466호)석면을 이용한 경량골조(특허 공고 제81-123호), 발포 플라스틱 구상체와 중질유를 혼합 교반하여 건식 모르타르를 피착시켜 양생한 경량골조(특허공고 제80-1056호)들이 개발되었으나, 상기의 경량골조들은 비중이 1.4∼0.7로 비교적 중량이고 발포플라스틱 구상체에 토양을 코팅한 경량골재를 골재로서 사용하게되면 모르타르내의 이물질인 토양이 혼입되므로서 강도가 약해지는 결합이 발생되었고 접착매개층인 점토질 부분 때문에 단열성과 경량성이 떨어지며, 발포플라스틱 구상체에 중질유를 코팅한 것등은 중질유드의 재료비가 고가로 인하여 생산원가가 높아질 뿐 아니라 구상체 표막에 불균형한 표막층이 도포되어 콘크리이트 강도가 불균일한 폐단이 발생되었으며, 또한 석면을 이용한 경량 골재를 사용하게 되면 콘크리이트이 비중이 높아질 뿐만 아니라 콘크리이트 강도가 약해지고 생산원가가 높아지는 단점이 발생되었으며, 상기의 경량골재를 이용하여 기포 콘크리이트를 제조할 경우에는 강도가 더욱 떨어지게 됨으로써 실용적가치가 없어지게 되어 별도의기포제를 첨가하여야 하는 등의 문제점이 발생되었다.Generally, the frame used for building or road pavement is made by crushing natural stone such as granite or basalt with small particles and mixing it with cement. Since the frame is used as a natural stone, environmental destruction In recent years, it has been proposed to coat soil on the surface of a plastic foamed plastic or a spherical foamed plastic surface (Japanese Patent Publication No. 80-1054) or to add a mineral filler such as soil or cement and a curing agent to the surface, (Patent Publication No. 76-466), a lightweight frame using asbestos (Patent Publication No. 81-123), a lightweight frame obtained by mixing and agitating foamed plastic spheres and heavy oil, and drying and curing the mortar (Patent Publication No. 80-1056) have been developed. However, the above-mentioned lightweight frames have a specific gravity of 1.4 to 0.7, When the lightweight aggregate coated with the spheroids of the plastic is used as the aggregate, the soil, which is a foreign material in the mortar, is mixed, and the weak bonding is generated. The clay part, which is the adhesive medium layer, deteriorates the insulation and lightweight. In addition to the high cost of raw materials due to the high cost of heavy oil coatings such as the coating of heavy oil on the upper body, the production cost is increased, and the uneven coating layer is applied to the surface of the sphere, When the aggregate is used, not only the specific gravity of the concrete is increased but also the strength of the concrete is weakened and the production cost is increased. In the case of producing the foamed concrete by using the lightweight aggregate, the strength is lowered and there is no practical value It is necessary to add a separate foaming agent This issue was of such occurrence.
상기의 문제점 등을 해결하기 위하여 본 발명인은 특허공고 제90-5974호를 창출하였던 바, 상기의 선발명은 규소(SiO264.0∼72.96)를 갖는 점토에 산화 알루미늄(Al2O315.0∼16.95), 산화철(Fe2O35.0∼7.5), 산화칼슘(CaO30.4∼0.59), 산화 마그네슘(MgO30.41), Igloss 6.78, 중유 1.5%를 혼합하여 1150∼1200℃에서 약 2분간 소성 시킨 다음 800∼900℃로 3∼5분간 로타리 키른에서 2차 소성시켜서 된 것으로서 외피에 천이 피막되게하고 압축강도가 45kg/㎠ 이상되게 하며 열전도율이 0.06 이하와 흡음률 0.7dB 이하, 비중 0.28∼0.4 이내가 되는 방수와 내진성을 가지는 특성이 있도록 한 경량골재를 얻을 수 있도록 한 것인바, 상기의 선발명은 골재를 성형하기 위하여서는 1차 소성과 2차 소성의 공정을 필요로 하므로 단시간내에 골재의 성형이 어렵고 다수의 부재료가 투입되는 등의 단점을 가지고 있는 것이다.In order to solve the above problems, the inventor of the present invention created Patent Publication No. 90-5974, and the above-mentioned name was silicon (SiO 2 64.0 to 72.96 ) Was added to the clay having aluminum oxide (Al 2 O 3 15.0 to 16.95 ), Iron oxide (Fe 2 O 3, 5.0 to 7.5 ), Calcium oxide (CaO 3 0.4~0.59 ), Magnesium oxide (MgO 3 0.41 ), Igloss 6.78 , 1.5% of heavy oil, and fired at 1150 ~ 1200 ° C for about 2 minutes and then fired at 800-900 ° C for 3 ~ 5 minutes in a rotary kiln. It was made to have a coating on the outer shell and a compressive strength of 45 kg / A lightweight aggregate having a thermal conductivity of 0.06 or less, a sound absorption coefficient of 0.7 dB or less, a specific gravity of 0.28 to 0.4 or less and a waterproof property and an earthquake-proof property can be obtained. In order to form an aggregate, And secondary firing process, it is difficult to form an aggregate in a short time, and a large number of sub-materials are injected.
본 발명은 상기의 선발명을 개량한 것으로 산화규소와 산화칼슘 및 산화 알루미늄, 산화철을 가지는 점토에 폐제지를 태워 애쉬를 혼합한 후 물과 벙커C유로 반죽을 하여 1200℃에서 소성한 후 급냉시켜 압축강도와 열전도율 및 흡음율, 비중, 방수, 내진성이 개선된 경량골재를 제공하는데 본 발명의 목적이 있는 것이다.The present invention relates to an improvement of the above-mentioned name, which comprises burning waste paper in clay having silicon oxide, calcium oxide, aluminum oxide and iron oxide, mixing the ash with water, kneading the mixture with water and bunker C, It is an object of the present invention to provide a lightweight aggregate having improved compressive strength, thermal conductivity, sound absorption ratio, specific gravity, waterproofing and seismic resistance.
이하, 본 발명을 첨부된 도면에 의하여 상세히 설명하면 다음과 같다.DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS Hereinafter, the present invention will be described in detail with reference to the accompanying drawings.
전체중량을 90로 기준하여 약 59가량의 산화규소(SiO2)와 산화 알루미늄(Al2O3) 19, 산화칼륨(CaO3) 5, 산화철(Fe2O3) 2의 성분을 가지는 점토에 폐제지를 태워 생성된 애쉬 4%를 공급기(1)를 통해서 혼합기(2)로 공급한 후 혼합기(2)에서 혼합된 재료에 물탱크(3)를 통해서 물 10와 벙커C유 1를 투입하여 스크류 콘베어(4)로서 반죽을 하고 반죽된 재료를 터브레이터(5)로서 1∼3mm 의 크기로 선별한 후 선별된 재료를 콘베어(6)로서 일측에 연돌(7)이 형성되고 내부온도가 1150∼1200℃의 온도를 가지는 로터리 키른(8)내로 투입 시켜 5분간에 걸쳐 통과되도록 하여 로터리 키튼(8)을 통과시 성형된 중간재가 폭발되어 입자가 100∼200팽윤시키고 에프론 콘베어(9)로 튜입하면 에프론 콘베어(9)가 냉각로(10)를 통과하면서 팽윤 조성된 입자들이 고열로 연화되는 것을 방지한 상태에서 야적장에 저장되거나 포장기로 보내어 포장된후 저장이 되는 것이다.The total weight is 90 About 59 (SiO 2 ) and aluminum oxide (Al 2 O 3 ) 19 , Potassium (CaO 3) 5 oxidation , Iron oxide (Fe 2 O 3 ) 2 4% of the ash produced by burning the waste paper is supplied to the mixer 2 through the feeder 1 and then mixed with the mixed material in the mixer 2 through the water tank 3 to produce water 10 And bunker C oil 1 Is kneaded as a screw conveyor (4), the kneaded material is selected as a turbator (5) to a size of 1 to 3 mm, a selected material is conveyed as a conveyor (6) The mixture is poured into a rotary kiln (8) having a temperature of 1150 to 1200 占 폚 and allowed to pass for 5 minutes. When passing through the rotary key knob (8), the formed intermediate material is exploded, When the swollen material is swollen and fed into the Efron conveyor 9, the Efron conveyor 9 is passed through the cooling furnace 10 to prevent the swollen particles from being softened by the high temperature. .
이때, 재료를 반죽하기 위하여 투입되는 벙커 C유는 상기 로터리 키른(8)을 중간재가 통과할 때 1150∼1200℃의 온도에 의하여 점토에 함유된 산화물로부터 유리되는 산소와 결합하여 이산화 탄소로 팽윤되어서 성형재 속에서 공동을 형성함과 동시에 점토에 함유된 철은 용융되어 고열에 의하여 산소를 빼앗긴상태로 분리 배출이 되고 산화칼슘이나 산화 마그네슘등은 성형물의 표면에 자동으로 형성되어 고체화 됨으로 골재의 외피에 피막이 형성되어 내부가 공동에 의하여 가벼우면서 피막층을 형성하는 피막에 의하여 압축강도를 높여주게 되는 것이다.At this time, the bunker C oil injected for kneading the material binds the rotary kiln 8 with oxygen liberated from the oxides contained in the clay by the temperature of 1150 to 1200 占 폚 when the intermediate material passes, The iron contained in the clay is melted and separated and discharged in a state in which oxygen is deprived by high temperature, and calcium oxide, magnesium oxide, etc. are automatically formed on the surface of the molding and solidified, And the inner portion is lightened by the cavity, and the compressive strength is increased by the coating forming the coating layer.
따라서, 상기와 같이 성형된 본 발명인 골재의 특성은 압축강도가 240kg/㎠ 이상이며 열전도율이 0.3 이하이고 흡음율이 50dB이상 (1250Hz 일 때 손실율)이며, 비중이 0.1∼1.0 이내의 특성을 지니게 되는 것이다.Accordingly, the aggregate of the present invention molded as described above has a compressive strength of 240 kg / cm 2 or more, a thermal conductivity of 0.3 or less, a sound absorption rate of 50 dB or more (loss rate at 1250 Hz), and a specific gravity of 0.1 to 1.0 .
이와같이 본 발명은 선발명에서 발생되는 1·2차 소성공정을 1차의 소성공정으로 단축시키고 부재료의 종류를 절감하여 단시간내에 골재를 성형함으로써 생산성을 높일 수 있음은 물론 에너지 절감효과를 가져오고 양질의 경량골재를 생산할 수 있는 발명이다.As described above, the present invention can shorten the primary and secondary firing processes generated in the selection name to the first firing process, reduce the kinds of the sub materials, mold the aggregate in a short time, thereby improving the productivity, Of lightweight aggregate.
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KR1019960020089A KR100208779B1 (en) | 1996-06-05 | 1996-06-05 | Light weight aggregate and the method of producing thereof |
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KR1019960020089A KR100208779B1 (en) | 1996-06-05 | 1996-06-05 | Light weight aggregate and the method of producing thereof |
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KR100208779B1 true KR100208779B1 (en) | 1999-07-15 |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR101130207B1 (en) | 2010-12-02 | 2012-03-30 | (주)폴리뱅크 | Coating apparatus and method of preventing water absorption into light weight aggregate |
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1996
- 1996-06-05 KR KR1019960020089A patent/KR100208779B1/en not_active IP Right Cessation
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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KR101130207B1 (en) | 2010-12-02 | 2012-03-30 | (주)폴리뱅크 | Coating apparatus and method of preventing water absorption into light weight aggregate |
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KR980001925A (en) | 1998-03-30 |
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