KR100200017B1 - Resin composition for floor-covering pearl chip and product of the same - Google Patents

Resin composition for floor-covering pearl chip and product of the same Download PDF

Info

Publication number
KR100200017B1
KR100200017B1 KR1019970014590A KR19970014590A KR100200017B1 KR 100200017 B1 KR100200017 B1 KR 100200017B1 KR 1019970014590 A KR1019970014590 A KR 1019970014590A KR 19970014590 A KR19970014590 A KR 19970014590A KR 100200017 B1 KR100200017 B1 KR 100200017B1
Authority
KR
South Korea
Prior art keywords
parts
weight
pearl
chip
resin composition
Prior art date
Application number
KR1019970014590A
Other languages
Korean (ko)
Other versions
KR970070091A (en
Inventor
박찬동
Original Assignee
이종학
한화종합화학주식회사
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 이종학, 한화종합화학주식회사 filed Critical 이종학
Priority to KR1019970014590A priority Critical patent/KR100200017B1/en
Publication of KR970070091A publication Critical patent/KR970070091A/en
Application granted granted Critical
Publication of KR100200017B1 publication Critical patent/KR100200017B1/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06—Homopolymers or copolymers of vinyl chloride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
    • C08K3/36—Silica
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
    • C08L25/02—Homopolymers or copolymers of hydrocarbons
    • C08L25/04—Homopolymers or copolymers of styrene
    • C08L25/08—Copolymers of styrene
    • E—FIXED CONSTRUCTIONS
    • E04—BUILDING
    • E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F15/00—Flooring
    • E04F15/02—Flooring or floor layers composed of a number of similar elements

Abstract

본 발명은 바닥장식재의 펄칩용 합성수지 조성물 및 이의 제품에 관한 것으로, 보다 상세하게는 폴리염화비닐(PVC) 수지 100중량부, 가소제 10~30중량부, 활제 1~10중량부, 안정제 1~10중량부, 펄안료 1~5중량부 및 스티렌 모노머로부터 현탁 중합된 가교구조를 갖는 비드상 스티렌 수지 1~10중량부로 이루어지는 바닥장식재의 펄칩용 합성수지 조성물 및 이의 제품에 관한 것이다.The present invention relates to a synthetic resin composition for pearl chips of flooring materials and products thereof, more specifically, 100 parts by weight of polyvinyl chloride (PVC) resin, 10 to 30 parts by weight of plasticizer, 1 to 10 parts by weight of lubricant, 1 to 10 parts by stabilizer The present invention relates to a pearl chip synthetic resin composition and a product thereof, comprising 1 to 10 parts by weight of a bead-like styrene resin having a crosslinked structure suspended from a styrene monomer by weight parts, 1 to 5 parts by weight of a pearl pigment.

본 발명에 따른 바닥장식재의 펄칩용 조성물은 펄칩표면에 미세한 돌출부를 형성하여 여러각도에서 입체효과 및 화려한 색조효과가 가능할 뿐만 아니라 불필요한 공정수를 줄여 생산공정을 단순화시키고 제조원가를 절감하며 작업능률을 향상시킬 수 있는 효과가 있다.The composition for pearl chip of the flooring material according to the present invention is to form a fine protrusion on the surface of the pearl chip to enable a three-dimensional effect and brilliant color effect at various angles, as well as to reduce the number of unnecessary processes to simplify the production process, reduce manufacturing costs and improve work efficiency It can be effected.

Description

바닥장식재의 펄칩용 합성수지 조성물 및 이의 제품Synthetic resin composition for pearl chips of flooring materials and products thereof

본 발명은 바닥장식재의 펄칩용 합성수지 조성물 및 이의 제품에 관한 것으로, 보다 상세하게는 펄칩표면에 미세한 돌출부를 형성하여 여러각도에서 입체효과 및 화려한 색조효과가 가능한 바닥장식재의 펄칩용 합성수지 조성물 및 이의 제품에 관한 것이다.The present invention relates to a synthetic resin composition for pearl chips of flooring materials and products thereof, and more specifically, to a pearl chip synthetic resin composition and floorings thereof having a three-dimensional effect and a colorful color effect at various angles by forming minute protrusions on the surface of the pearl chip. It is about.

일반적으로, 바닥장식재에 사용되는 펄칩(Pearl Chip)은 햇빛을 받으면 진주빛 색조를 나타내고 형광등과 같은 조명하에서는 은은한 색조를 나타낸어 고급 바닥장식재 내부에 많이 사용되어져 왔다.In general, pearl chips used for flooring materials have been used in high-quality flooring materials because they exhibit a pearly hue when exposed to sunlight and a light hue under lighting such as a fluorescent lamp.

그러나, 바닥장식재에 사용되는 일반적인 종래의 펄칩은 바닥장식재 내부에서 한쪽방향으로만 배열되었기 때문에 한쪽각도에서만 화려한 색조가 나타나는 문제점이 있었다.However, the conventional conventional pearl chip used in the flooring material has a problem that the colorful color tone appears only at one angle because it is arranged only in one direction inside the flooring material.

또한, 이를 보완하기 위해 펄칩의 제조시 중합도가 서로 상이한 2종류의 합성수지(예를들어, 중합도 700의 폴리염화비닐 수지인 P-700 80중량부와 중합도 1700의 폴리염화비닐 수지인 P-1700 20중량부)를 이용하여 펄칩표면에 중합도 차이에 의한 미세한 돌출부를 형성하여 여러각도에서 입체효과 및 화려한 색조효과가 가능하도록 하였으나, 이 경우 중합도가 다른 2종류의 합성수지로 펄칩을 생산하여야 하기 때문에 이에 따른 공정수가 증가될 뿐만 아니라 제조원가가 상승되는 문제점이 있었다. 또한, 중합도 차이에 의한 미세한 돌출부 형성방법은 원하는 만큼의 표면돌출효과를 얻기 위해 중합도 차이의 조절, 혼합비율의 조정 및 용융온도의 조절 등 여러조절공정을 거쳐야 하기 때문에 생산공정이 복잡하였을 뿐만 아니라 충분한 표면돌출효과를 얻기 어려웠다.In order to compensate for this, two kinds of synthetic resins having different polymerization degrees (for example, 80 parts by weight of P-700, a polyvinyl chloride resin having a polymerization degree of 700, and P-1700 20, a polyvinyl chloride resin having a polymerization degree of 1700, may be used. By weight) to form a fine protrusion on the surface of the pearl chip due to the difference in the degree of polymerization to enable a three-dimensional effect and a brilliant color effect at various angles, but in this case, the pearl chip must be produced from two kinds of synthetic resins having different polymerization degrees. In addition to the increase in the number of processes, there was a problem that the manufacturing cost is increased. In addition, the method of forming a fine protrusion by the difference in polymerization degree requires a complicated process such as controlling the difference in polymerization degree, adjusting the mixing ratio and adjusting the melting temperature in order to obtain the desired surface protruding effect. It was difficult to obtain the surface protruding effect.

상기한 바와 같은 문제점을 해결하기 위하여 고안된 본 발명의 목적은 펄칩표면에 미세한 돌출부를 형성하여 여러각도에서 입체효과 및 화려한 색조효과가 가능한 바닥장식재의 펄칩용 합성수지 조성물을 제공하는데 있다.An object of the present invention devised to solve the problems as described above is to provide a pearl chip synthetic resin composition of the flooring material capable of forming a three-dimensional protrusion on the surface of the pearl chip and a three-dimensional effect and colorful color effect at various angles.

본 발명이 다른 목적은 상기 조성물을 이용하여 제조되는 바닥장식재용 펄칩을 제공하는데 있다.Another object of the present invention to provide a pearl chip for floor decoration prepared using the composition.

상기 목적을 달성하기 위한 본 발명의 바닥장식재의 펄칩용 합성수지조성물은 폴리염화비틸(PVC) 수지 100중량부, 가소제 10~30중량부, 활제 1~10중량부, 안정제 1~10중량부, 펄안료 1~5중량부 및 스티렌 모노머로부터 현탁 중합된 가교구조를 갖는 비드상 스티렌 수지 1~10중량부로 이루어진다.Synthetic resin composition for pearl chips of the flooring material of the present invention for achieving the above object is 100 parts by weight of polyvinyl chloride (PVC) resin, 10 to 30 parts by weight of plasticizer, 1 to 10 parts by weight of lubricant, 1 to 10 parts by weight of stabilizer, pearl 1 to 5 parts by weight of the pigment and 1 to 10 parts by weight of the bead-like styrene resin having a crosslinked structure suspended from the styrene monomer.

이하, 본 발명을 보다 상세하게 설명한다.Hereinafter, the present invention will be described in more detail.

본 발명에서는 여러각도에서 입체효과 및 화려한 색조효과가 가능하도록 미세한 돌출부를 펄칩표면에 형성하기 위해서 종래의 중합도가 다른 2종류의 합성수지에 의한 펄칩생산공정 대신에 폴리염화비닐(PVC) 수지와 혼합될 경우 자체 비중(0.9~1.3)에 의해 펄칩표면에 존재할 수 있는 유기 가교 투명 고분자 물질을 사용하였다. 본 발명에 사용되는 유기 가교 투명 고분자 물질은 투명한 물질로서 기재인 폴리염화비닐(PVC) 수지와의 비중 차이에 의해 펄칩표면부에 존재한다. 또한, 가교입자가 탄성체의 성질을 보유하므로 성형 후에도 펄칩표면에 미세한 엠보스를 유지하게 된다.In the present invention, in order to form a fine protrusion on the surface of the pearl chip to enable a three-dimensional effect and a brilliant color effect at various angles, it is mixed with polyvinyl chloride (PVC) resin instead of the pearl chip production process by two kinds of synthetic resins having different polymerization degrees. In this case, an organic crosslinked transparent polymer material, which may exist on the surface of the pearl chip by specific gravity (0.9 to 1.3), was used. The organic crosslinked transparent polymer material used in the present invention is present as a transparent material on the surface of the pearl chip due to the difference in specific gravity with the polyvinyl chloride (PVC) resin as a base material. In addition, since the crosslinked particles retain the properties of the elastomer, fine embossing is maintained on the surface of the pearl chip even after molding.

본 발명에 사용되는 유기 가교 투명 고분자 물질은 스티렌 모노머로부터 현탁 중합된 가교 구조를 갖는 10~40

Figure kpo00003
입자 크기의 비드상 스티렌 수지이다.The organic crosslinked transparent polymer material used in the present invention is 10 to 40 having a crosslinked structure suspended and polymerized from a styrene monomer.
Figure kpo00003
Bead styrene resin of particle size.

상기 스티렌 수지는 페인트나 잉크에 첨가되어 부드러운 감을 향상시키는 첨가제, 필름용 차단 방지제, 화장품용 충전제 또는 의치와 같은 치과용 재료등으로 사용되어 왔으나, 본 발명과 같이 바닥장식재의 펄칩용 합성수지 조성물에 사용된 예는 없었다.The styrene resin has been used as a dental material such as additives to add a soft feeling by adding to paints or inks, film blocking agents, cosmetic fillers or dentures, etc., but is used in pearl chip synthetic resin compositions of flooring materials as in the present invention. There was no example.

상기 비드상 가교 스티렌 수지는 1) 스티렌 단량체 또는 이를 포함하는 다른 공중합 단량체 100중량부 2) 가교제 20~50중량부 및 3) 중합촉매 0.01~1중량부를 사용하여 현탁 중합에 의해 제조된다. 상기 스티렌 단량체와의 공중합 단량체로서는

Figure kpo00004
-메틸스티렌, 아클리로니트릴 또는 메틸메타아크릴레이트 등이 사용된다.The bead-shaped crosslinked styrene resin is prepared by suspension polymerization using 1) 100 parts by weight of a styrene monomer or another copolymer monomer including the same 2) 20-50 parts by weight of a crosslinking agent and 3) 0.01-1 part by weight of a polymerization catalyst. As a copolymerization monomer with the said styrene monomer,
Figure kpo00004
-Methyl styrene, acrylonitrile or methyl methacrylate is used.

상기 가교제로서는 에틸렌글리콜 디메틸아크릴레이트 또는 트리메틸롤프로판 트리메타크릴레이트 등의 사용된다. 상기 트리메틸롤프로판 트리메타크릴레이트의 구조는 하기 화학식 I 로 표시된다.As said crosslinking agent, ethylene glycol dimethyl acrylate, trimethylolpropane trimethacrylate, etc. are used. The structure of the trimethylolpropane trimethacrylate is represented by the following formula (I).

Figure kpo00001
Figure kpo00001

상기 중합촉매로는 벤조일퍼옥사이드, tert-부틸퍼벤조에이트 등의 유기과산화물이나 아조비스이소부티로니트릴의 아조화합물이 사용된다.As said polymerization catalyst, organic peroxides, such as benzoyl peroxide and tert- butyl perbenzoate, and the azo compound of azobisisobutyronitrile are used.

본 발명에서 사용되는 상기 스티렌수지는 폴리염화비닐(PVC) 수지 100중량부, 가소제 10~30중량부, 활제 1~10중량부, 안정제 1~10중량부, 펄안료 1~5중량부에 대하여 1~10중량부로 첨가되는데, 이때 1중량부 미만이면 펄칩표면에 충분한 미세 돌출부를 형성할 수 없고, 10중량부를 초과하면 미세 돌출부 효과가 없어지며 경제성도 낮아진다. 또한, 상기 스티렌 수지는 비드형태로 사용되며, 입자크기는 10~40

Figure kpo00005
이 바람직하다. 입자크기가 10
Figure kpo00006
미만이면 미세 돌출부 효과가 적으며, 40
Figure kpo00007
를 초과하면 표면 미세 돌출부가 균일하지 못한 단점이 있다.The styrene resin used in the present invention is based on 100 parts by weight of polyvinyl chloride (PVC) resin, 10 to 30 parts by weight of plasticizer, 1 to 10 parts by weight of lubricant, 1 to 10 parts by weight of stabilizer, and 1 to 5 parts by weight of pearl pigment. 1 to 10 parts by weight is added, when less than 1 part by weight can not form a sufficient micro-projection on the surface of the pearl chip, when it exceeds 10 parts by weight, the micro-projection effect is lost and economic efficiency is lowered. In addition, the styrene resin is used in the form of beads, the particle size of 10 ~ 40
Figure kpo00005
This is preferred. Particle Size 10
Figure kpo00006
If less, there is less micro protrusion effect, 40
Figure kpo00007
If it exceeds, there is a disadvantage that the surface fine protrusions are not uniform.

상기한 바닥장식재의 펄칩용 합성수지 성분들은 통상의 바닥장식쟁용 펄칩 제조방법과 동일한 방법으로 제조되어 바닥장식재에 적용된다.Synthetic resin components for the pearl chip of the flooring material is prepared in the same manner as the conventional method for manufacturing a pearl chip for floor decoration and applied to the flooring material.

이하, 실시예 및 비교예를 통해 본 발명을 보다 구체적으로 설명하지만 하기 예에 본 발명의 범주가 한정되는 것은 아니다.Hereinafter, the present invention will be described in more detail with reference to Examples and Comparative Examples, but the scope of the present invention is not limited to the following Examples.

[실시예 1]Example 1

P-700 (중합도 700의 폴리염화비닐 수지) 100중량부, 가소제(DDP) 24중량부, 활제 5중량부, 안정제 5중량부, 펄안료 3중량부 및 평균입경 30

Figure kpo00008
인 가교 스티렌 수지(한화종합화학(주), 상품명 : XS-30) 10중량부를 각각 계량한 후 라이카키 믹서(일본 타바이사)에 투입하여 10분동안 교반하여 균일하게 분산된 혼합물을 얻었다.100 parts by weight of P-700 (polyvinyl chloride resin having a degree of polymerization 700), 24 parts by weight of plasticizer (DDP), 5 parts by weight of lubricant, 5 parts by weight of stabilizer, 3 parts by weight of pearl pigment, and an average particle diameter of 30
Figure kpo00008
After weighing 10 parts by weight of phosphorus-crosslinked styrene resin (Hanhwa General Chemical Co., Ltd., product name: XS-30), respectively, the mixture was added to a Leicaki mixer (Tabai, Japan) and stirred for 10 minutes to obtain a uniformly dispersed mixture.

분산된 혼합물의 점도는 브룩필드(Brookfield)점도계를 사용하여 23

Figure kpo00009
, 20rpm에서 측정하였다. 코팅성은 평판위에 혼합물을 떨어뜨려 바 코터를 사용하여 30
Figure kpo00010
의 두께로 코팅한 후 1분동안 경화시킨 뒤 표면상태를 육안 관찰하였다.The viscosity of the dispersed mixture was measured using a Brookfield viscometer.
Figure kpo00009
It was measured at 20 rpm. The coatability is achieved by using a bar coater to drop the mixture onto the plate.
Figure kpo00010
After coating with a thickness of and cured for 1 minute, the surface condition was visually observed.

광택도는 상기 코팅성 측정시료의 평면에 45

Figure kpo00011
및 60
Figure kpo00012
의 경면광택도를 JIS Z 8741(광택도 측정방법)방법에 준하여 측정하였다.Glossiness is 45 degrees on the plane of the coating
Figure kpo00011
And 60
Figure kpo00012
The specular glossiness of was measured according to JIS Z 8741 (Measuring method of glossiness).

표면요철과 손가락 느낌은 상기 코팅성 측정시료의 표면을 5명의 각기 다른 작업자가 손가락으로 문질러서 각기 느끼는 정도로서 평가하였다. 동 마찰계수는 KSM 3053방법에 의해 마찰계수 측정기로 측정하였다(표 1 참조).Surface irregularities and finger feelings were evaluated as the degree to which five different workers rubbed the surface of the coating sample with their fingers. The dynamic coefficient of friction was measured by a coefficient of friction measurement by the KSM 3053 method (see Table 1).

[실시예 2]Example 2

상기 실시예 1의 조성에 평균입경 0.012

Figure kpo00013
의 실리카(Degusa, 상품명 : Aerosil 200) 0.3중량부를 첨가한 것을 제외하고는 동일하게 실시하였고, 그 물성치를 측정하여 하기 표 1에 기재하였다.Average particle size 0.012 in the composition of Example 1
Figure kpo00013
Except that 0.3 parts by weight of silica (Degusa, trade name: Aerosil 200) was carried out in the same manner, the physical properties were measured and listed in Table 1 below.

[비교예 1]Comparative Example 1

상기 실시예 1의 조성에서 가교 스티렌 수지 10중량부 대신에 실리카 1중량부를 사용한 것을 제외하고는 동일하게 실시하였고, 그 물성치를 측정하여 하기 표 1에 기재하였다.Except for using 10 parts by weight of silica instead of 10 parts by weight of the cross-linked styrene resin in the composition of Example 1, the physical properties were measured and listed in Table 1 below.

[비교예 2]Comparative Example 2

상기 실시예 1의 조성에서 가교 스티렌 수지 10중량부 대신에 평균입경 30

Figure kpo00014
의 유리구(Emerson Cuming, 상품명 : Ecosphere) 10중량부를 사용한 것을 제외하고는 동일하게 실시하였고, 그 물성치를 측정하여 하기 표 1에 기재하였다.In the composition of Example 1 instead of 10 parts by weight of the crosslinked styrene resin, the average particle diameter of 30
Figure kpo00014
Except for using 10 parts by weight of glass spheres (Emerson Cuming, trade name: Ecosphere) was carried out in the same manner, the physical properties were measured and listed in Table 1 below.

Figure kpo00002
Figure kpo00002

* : 수치가 작을수록 매끄럽고 클수록 까칠까칠함.*: The smaller the value, the smoother it is.

상기 표 1에서 알 수 있는 바와 같이, 본 발명에 따른 구형 가교 스티렌 수지 단독 또는 혼합 사용한 경우가 실리카 단독 또는 유리구를 사용한 경우에 비해서 점도가 낮아 작업성이 양호하고 표면돌출효과가 탁월함을 알 수 있었다.As can be seen in Table 1, the spherical crosslinked styrene resin alone or mixed according to the present invention can be seen that the workability is good and the surface protruding effect is excellent due to the low viscosity compared to the case of using silica alone or glass spheres. there was.

종래의 중합도가 다른 2종류의 합성수지에 의한 펄칩생산공정에 의해 만들어진 바닥장식재용 펄칩은 중합도차이의 조절, 혼합비율의 조정 및 용융온도의 조절 등 여러조절공정을 거쳐야 하기 때문에 생산공정이 복잡하고 충분한 표면돌출효과를 기대하기 어려운 문제점이 있었으나, 본 발명에 따른 바닥장식재의 펄칩용 합성수지 조성물은 펄칩표면에 미세한 돌출부를 형성하여 여러각도에서 입체효과 및 화려한 색조효과가 가능할 뿐만 아니라 불필요한 공정수를 줄여 생산공정을 단순화시키고 제조원가를 절감하며 작업능률을 향상시킬 수 있는 효과가 있다.Pearl chip for floor decoration material made by pearl chip production process using two kinds of synthetic resins having different degree of polymerization degree has complicated production process because it has to go through various control processes such as control of polymerization degree difference, adjustment of mixing ratio and control of melting temperature. Although there was a problem that it was difficult to expect the surface protruding effect, the synthetic resin composition for pearl chip of the flooring material according to the present invention by forming a fine protrusion on the surface of the pearl chip is possible to produce a three-dimensional effect and a brilliant color effect at various angles, as well as reducing the number of unnecessary processes The effect is to simplify the process, reduce manufacturing costs and improve work efficiency.

Claims (6)

바닥장식재의 펄칩용 합성수지 조성물에 있어서, 폴리염화비닐 수지 100중량부, 가소제 10~30중량부, 활제 1~10중량부, 안정제 1~10중량부, 펄안료 1~5중량부 및 스티렌 모노머로부터 현탁 중합된 가교구조를 갖는 비드상 스티렌 수지 1~10중량부를 포함하여 이루어지는 것을 특징으로 하는 바닥장식재의 펄칩용 합성수지 조성물.In the synthetic resin composition for pearl chip of flooring material, from 100 parts by weight of polyvinyl chloride resin, 10 to 30 parts by weight of plasticizer, 1 to 10 parts by weight of lubricant, 1 to 10 parts by weight of stabilizer, 1 to 5 parts by weight of pearl pigment and styrene monomer 1 to 10 parts by weight of a bead-like styrene resin having a suspension-polymerized crosslinked structure. 제1항에 있어서, 상기 비드상 스티렌 수지의 평균입경이 10~40
Figure kpo00015
인 것을 특징으로 하는 바닥장식재의 펄칩용 합성수지 조성물.According to claim 1, wherein the average particle diameter of the bead-like styrene resin is 10 to 40
Figure kpo00015
Pearl resin synthetic resin composition of the flooring material characterized in that. 제1항 또는 제2항에 있어서, 실리카 0.3중량부가 첨가된 것을 특징으로 하는 바닥장식재의 펄칩용 합성수지 조성물.The synthetic resin composition for pearl chip according to claim 1 or 2, wherein 0.3 parts by weight of silica is added. 폴리염화비닐 수지 100중량부, 가소제 10~30중량부, 활제 1~10중량부, 안정제 1~10중량부, 펄안료 1~5중량부 및 스티렌 모노머로부터 현탁 중합된 가교구조를 갖는 비드상 스티렌 수지 1~10중량부를 포함하여 이루어진 바닥장식재의 펄칩용 합성수지 조성물을 이용하여 제조되는 것을 특징으로 하는 바닥장식재용 펄칩.Beaded styrene having a crosslinked structure suspended from 100 parts by weight of polyvinyl chloride resin, 10 to 30 parts by weight of plasticizer, 1 to 10 parts by weight of lubricant, 1 to 10 parts by weight of stabilizer, 1 to 5 parts by weight of pearl pigment, and styrene monomer. Pearl chip for floor decoration, characterized in that the resin is manufactured using a synthetic resin composition for pearl chips of floor decoration comprising 1 to 10 parts by weight of resin. 제4항에 있어서, 상기 비드상 스티렌 수지의 평균입경이 10~40
Figure kpo00016
인 것을 특징으로 하는 바닥장식재용 펄칩.The average particle diameter of said bead-like styrene resin is 10-40.
Figure kpo00016
Pearl chip for flooring material, characterized in that. 제4항 또는 제5항에 있어서, 상기 바닥장식재의 펄칩용 합성수지 조성물에 실리카 0.3중량부가 첨가된 것을 특징으로 하는 바닥장식재용 펄칩.The pearl chip for floor decoration according to claim 4 or 5, wherein 0.3 parts by weight of silica is added to the pearl chip synthetic resin composition of the floor decoration material.
KR1019970014590A 1997-04-19 1997-04-19 Resin composition for floor-covering pearl chip and product of the same KR100200017B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
KR1019970014590A KR100200017B1 (en) 1997-04-19 1997-04-19 Resin composition for floor-covering pearl chip and product of the same

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
KR1019970014590A KR100200017B1 (en) 1997-04-19 1997-04-19 Resin composition for floor-covering pearl chip and product of the same

Publications (2)

Publication Number Publication Date
KR970070091A KR970070091A (en) 1997-11-07
KR100200017B1 true KR100200017B1 (en) 1999-06-15

Family

ID=19503319

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019970014590A KR100200017B1 (en) 1997-04-19 1997-04-19 Resin composition for floor-covering pearl chip and product of the same

Country Status (1)

Country Link
KR (1) KR100200017B1 (en)

Also Published As

Publication number Publication date
KR970070091A (en) 1997-11-07

Similar Documents

Publication Publication Date Title
JP3727658B2 (en) Acrylic sheet in which colorant and inorganic filler are uniformly distributed before and after thermoforming
US5237004A (en) Thermoplastic and thermoset polymer compositions
RU2396286C2 (en) Product moulded from plastics and method of its fabrication
US5756211A (en) Method of manufacturing high filler content plastics having a glitter appearance
TW200946583A (en) Light-scattering compositions
US5690872A (en) Method for the production of highly filled polymethyl methacrylate based plastics
CA2265496C (en) Acrylic sheet having uniform distribution of coloring and mineral filler before and after thermoforming
EP3601435B1 (en) Light scattering polymeric composition with improved scattering efficiency and improved mechanical properties
CA2233149C (en) Thermoformable acrylic sheet having uniform distribution of color and mineral filler
US20020169236A1 (en) Decorative solid surfacing materials filled with ceramic microspheres
KR100200017B1 (en) Resin composition for floor-covering pearl chip and product of the same
JPH0159297B2 (en)
KR100200016B1 (en) Resin composition for floor covering materials and the product therof
KR100200014B1 (en) Resin composition for window-flame and product of the same
KR100200013B1 (en) Resin composition for tile and product of the same
KR100200015B1 (en) Resin composition for doors and the product of the same
WO2023135544A1 (en) Composition for kitchen or bathroom furnishings, such as sinks, washbasins, worktops, tubs and sheets
JP2763558B2 (en) Stone-grain artificial stone
JPH01287161A (en) Acrylic resin composition for molded body excellent in matte property, molded product and production thereof
JP3877974B2 (en) Manufacturing method of artificial marble
JP2001064062A (en) Composition of artificial marble
JPH1192606A (en) Synthetic resin composition and products therefrom
JP2001064063A (en) Composition of artificial marble
JPH02170847A (en) Granite-like acryl resin molded article
KR19980077461A (en) Synthetic resin composition for baths and products thereof

Legal Events

Date Code Title Description
A201 Request for examination
G15R Request for early opening
E701 Decision to grant or registration of patent right
GRNT Written decision to grant
FPAY Annual fee payment

Payment date: 20080110

Year of fee payment: 10

LAPS Lapse due to unpaid annual fee