KR100198775B1 - Bleaching agent composition of oxygen series - Google Patents
Bleaching agent composition of oxygen series Download PDFInfo
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- KR100198775B1 KR100198775B1 KR1019960019645A KR19960019645A KR100198775B1 KR 100198775 B1 KR100198775 B1 KR 100198775B1 KR 1019960019645 A KR1019960019645 A KR 1019960019645A KR 19960019645 A KR19960019645 A KR 19960019645A KR 100198775 B1 KR100198775 B1 KR 100198775B1
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/395—Bleaching agents
- C11D3/3953—Inorganic bleaching agents
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
- C11D3/3905—Bleach activators or bleach catalysts
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/06—Powder; Flakes; Free-flowing mixtures; Sheets
Abstract
본 발명은 새로운 형태의 표면 활성제, 과탄산나트륨의 용해성 촉진제 및 이를 포함한 산소계 표백제 조성물에 관한 것으로서 특히 살균, 표백활성제를 함유함으로써 살균력 및 표백력을 개선한 입상 산소계 표백제 조성물에 관한 것이다. 살균표백활성제로서는 이소노나노닐옥사벤젠설폰네이트 소듐 및/또는 디옥소헥사하이드로트리아진이 사용되고, 용해도 향성을 위한 염으로는 중탄산나트륨 등을 선택한다. 각 살균표백활성제 및 연의 조성비에 따른 표백력 및 용해도를 측정하여 바람직한 표백제 조성비를 찾아내었다.The present invention relates to a new type of surface active agent, a solubility promoter for sodium percarbonate, and an oxygen bleaching composition containing the same. More particularly, the present invention relates to a granular oxygen bleaching composition having improved sterilizing power and bleaching power by containing a sterilizing and bleaching activator. As the bactericidal bleaching activator, isononanonyloxabenzenesulfonate sodium and / or dioxohexahydrotriazine are used, and as a salt for solubility-oriented salt, sodium bicarbonate or the like is selected. The bleaching power and solubility of each germicidal bleach activator and kerosene composition were measured to find the desired bleach composition ratio.
Description
본 발명은 의류 살균제, 표백제로 쓰이고 있는 과탄산나트륨69 ~99.8중량%와 과탄산나트륨의 살균력 ,표백력 및 용해성 향상을 목적으로 첨가된 살균, 표백활성제 0.1~30중량% 및 염0.1 ~10중량%로 구성된 입상 산소계 표백제 조성물에 관한 것이다.The present invention relates to a disinfectant, a bleaching activator and a disinfectant which are added for the purpose of improving the sterilizing power, bleaching power and solubility of sodium percarbonate, 69 to 99.8% by weight of sodium percarbonate used as a garment disinfectant and bleaching agent, 0.1 to 30% To a granular oxygen-based bleach composition.
일반적으로 입상 산소계 표백제는 과산화수소와 탄산나트륨을 반응시킨 입상 과탄산나트륨이 주성분으로서 이 입상 과탄산나트륨의 분해시 발생되는 활성산소의 살균력 및 표백력을 이용하여 화장실, 변기, 주방 등의 주거 환경에 기생하는 미생물의 제어 및 섬유 또는 의류의 살균,표백에 사용되고 있다.Generally, granular oxygen bleaching agent is composed of granular material and sodium carbonate which are reacted with hydrogen peroxide and sodium carbonate, and microorganisms parasitic to residential environment such as restroom, toilet bowl, and kitchen by using sterilization power and bleaching power of active oxygen generated upon decomposition of sodium carbonate and sodium carbonate Control and sterilization of textile or garments, bleaching.
그러나, 산소계 표백제의 살균력 및 표백력은 인체독성이 거의 없으면서도 상기 적용범위에 효율적으로 이용할 수 있는 장점이 있지만, 염소계 표백제에 비하여 살균력 및 표백력이 약하여 또한 과탄산나트륨이 완전히 용해되지 않는 상태에서 의류를 넣을 경우 과탄산나트륨 입자가 섬유 또는 의류에 부착되는 경우 부분적인 표백으로 인해 섬유 또는 의류에 탈색 및 손상을 일으킬 수 있다.However, the sterilizing power and the bleaching power of the oxygen bleaching agent are advantageous in that they can be efficiently used in the application range even though there is little human toxicity. However, since the sterilizing power and the bleaching power are weaker than the chlorine bleaching agent, , Sodium percarbonate particles may adhere to fibers or clothing and cause bleaching and damage to fibers or clothing due to partial bleaching.
이에 본 발명의 제1목적은 살균력 및 표백력이 보다 향상된 표백제를 제공하는 것이다. 본 발명의 제2목적은 용해성이 우수한 표백제를 제공하는 것이다.Accordingly, a first object of the present invention is to provide a bleaching agent having improved sterilizing power and bleaching power. A second object of the present invention is to provide a bleaching agent having excellent solubility.
상기 본 발명의 목적을 달성하기 위하여 본 발명의 산소계 표백제는 과탄산나트륨과 이하의 a,b의 화합물 가운데 적어도 1종 이상을 함유하는 첨가제를 혼합하여 표백력 및 살균력을 대폭 향상시키며 c , d , e , f , g ,의 화합물 가운데 적어도 1종이상을 함유하는 첨가제를 혼합하여 과탄산나트륨위 용해성을 우수하게 한 것이다.In order to accomplish the object of the present invention, the oxygen bleaching agent of the present invention is prepared by mixing sodium percarbonate with an additive containing at least one of the following compounds a and b to significantly improve bleaching power and sterilizing power, and c, d, e , f, g, and the like are mixed with each other to improve the solubility in sodium percarbonate.
(가) 「이소노나노닐옥시벤젠설폰네이트 소듐」(A) " Isononanonyloxybenzenesulfonate sodium "
(나) 「디옥소헥사하이드로트리아진」(B) " dioxohexahydrotriazine "
(다) 「중탄산나트륨」(C) "sodium bicarbonate"
NaHCO3 NaHCO 3
(라) 「탄산나트륨」(D) "Sodium carbonate"
Na2CO3 Na 2 CO 3
(마) 「황산나트륨」(E) "Sodium Sulfate"
Na2SO4 Na 2 SO 4
(바) 「구연산나트륨」(F) "Sodium citrate"
C6H5O7Na32H2OC 6 H 5 O 7 Na 3 2H 2 O
(사) 「글루콘산나트륨」(G) "Sodium gluconate"
C6H11NaO7 C 6 H 11 NaO 7
이하 본 발명을 상세하게 설명한다.Hereinafter, the present invention will be described in detail.
본 발명은 과탄산나트륨과 상기한 a , b 의 혼합물 가운데 적어도 1종 이상을 함유하는 첨가제를 혼합하여 과탄산나트륨의 살균력 및 표백력을 향상시키는고 c , d , e , f , g 의 혼합물 가운데 적어도 1종이상을 함유하는 첨가제를 혼합항 과탄산나트륨의 용해성을 획기적으로 개선시킨 입상 표백제이다.The present invention relates to a mixture of sodium cyanide and at least one of a mixture of c, d, e, f and g, which improves the sterilizing power and bleaching power of sodium percarbonate by mixing an additive containing at least one of a mixture of sodium percarbonate and a, It is a granular bleaching agent that dramatically improves the solubility of the mixing port and sodium carbonate.
본 발명에서는 제1목적을 위하여 a , b의 화합물 가운데 적어도 1종이상을 함유하는 첨가제를 혼합하여 사용할 수 있고, 이때 첨가량은 0.1 ~30 중량%가 바람직한 것으로 나타났다. 이때 첨가량이 0.1중량% 이하이면 상기 입상 표백제의 살균력 및 표백력을 향상시킬 수 없고 30 중량%를 초과하면 과탄산나트륨의 안정도가 떨어지게된다.In the present invention, it is possible to use an additive containing at least one of the compounds a and b for the first purpose, and it is preferable that the additive amount is 0.1 to 30% by weight. If the addition amount is less than 0.1% by weight, the sterilizing power and bleaching power of the granular bleaching agent can not be improved, and if it exceeds 30% by weight, the stability of sodium percarbonate is decreased.
제2목적을 위하여 c , d , e , f , g의 화합물 가운데 적어도 1종이상을 함유하는 첨가제를 혼합하여 사용할 수 있고 이때 첨가량이 0.1 내지10 중량%가 바람직한 것으로 나타났다. 이때 첨가량이 0.1중량%이하이면 상기 입상 표백제의 용해성을 개선할 수 없으며 10중량%를 초과하면 압자의 뭉침 및 분진 발생이 심화된다.For the second object, it is possible to use an additive containing at least one of the compounds c, d, e, f and g, and it is preferable that the additive amount is 0.1 to 10 wt%. If the addition amount is less than 0.1% by weight, the solubility of the granular bleaching agent can not be improved, and if the addition amount is more than 10% by weight, agglomeration of the indenter and dust generation will be intensified.
또한, 제1목적 및 제2목적을 동시에 성취하기 위해서는 과탄산나트륨에 a , b 의 화합물 가운데 적어도 1종이상을 함유하는 첨가제 0.1 내지 30 중량%와, c , d , e , f , g의 화합물 가운데 적어도 1종이상을 함유하는 첨가제 0.1 내지 10 중량%를 같이 혼합시키면 된다.In order to simultaneously achieve the first object and the second object, 0.1 to 30% by weight of an additive containing at least one compound of a and b in sodium percarbonate and 0.1 to 30% by weight of a compound of c, d, e, f and g 0.1 to 10% by weight of an additive containing at least one kind may be mixed together.
이하 본 발명을 실시예를 통하여 더욱 구체적으로 설명한다. 그러나, 본 발명이 아래의 실시예에 의하여 한정되는 것은 아니다.Hereinafter, the present invention will be described in more detail with reference to examples. However, the present invention is not limited by the following examples.
[실시예 1][Example 1]
500㎖ 비이커에 과탄산나트륨 100g과 이소노나닐옥시벤젠설폰네이트 소듐 3g 또는 5g을 넣고 시약용 스푼으로 5분간 골고루 혼합하였다. 제조한 혼합물은 살균력 시험 및 표백력 시험에 사용하기 위해 25。C증류수 1리터에 상기 혼합물 1g을 넣고 완전히 용해될 수 있도록 교반기로 5분간 교반하였다.100 g of sodium percarbonate and 3 g or 5 g of isononanyloxybenzenesulfonate sodium were added to a 500 ml beaker and mixed with a reagent spoon for 5 minutes evenly. 1 g of the mixture was added to 1 liter of distilled water at 25 ° C for use in the sterilization test and the bleaching force test, and the mixture was stirred for 5 minutes with a stirrer so that it could be completely dissolved.
실시예 1에 적용한 살균력 시험방법은 KS K0693-1990(직물항균도 시험방법) 및 ASTM E1054-85 로서 시험장치 및 균주는 상기 시험법에 준하여 사용하였다.The sterilizing power test method applied to Example 1 was KS K0693-1990 (test method for fabric antibacterial activity) and ASTM E1054-85, and the test apparatus and strain were used in accordance with the above test method.
균운 KCCM 11234(E. coli), KCCM 11335(S.aureus), KCCM 11321(P.aeruginosa), KCCM 11247(A.nigar)을 사용하였으며, 상기 혼합물과 균의 접촉시간은 10분으로 선정하였다. 시험결과 표 1 에 정리 하였다.KCCM 11234 (E. coli), KCCM 11335 (S. aureus), KCCM 11321 (P. aeruginosa) and KCCM 11247 (A. nigar) were used and the contact time of the mixture and the bacteria was selected to be 10 minutes. The test results are summarized in Table 1.
또한, 표백력 시험에 적용한 시험방법은 KS M2175(의류용 합성세제 시험방법)로서 30。C의 상기 혼합액 1리터가 담겨져 있는 교반기(Terg-O-Termeter)에 오염이 균일하게 코팅되어 있는 오염천(ENPA 114) 20장을 투입하고 10분간 교반한 후 교반 전후의 백색도를 비교하여 표백력을 측정하였다. 시험결과는 표 1에 정리하였다.The test method applied to the bleaching power test was KS M2175 (a synthetic detergent test method for clothing), and a contaminated cloth having uniformly coated with a stirrer (Terg-O-Termiter) containing 1 liter of the above- (ENPA 114) were added and stirring was performed for 10 minutes. Then, whiteness before and after stirring was compared to determine bleaching power. The test results are summarized in Table 1.
[실시예 2][Example 2]
상기 실시예 1과 같은 방법으로 하되, 이소노나노닐옥시벤젠설폰네이트 소듐 대신에 디옥소헥사하이드로트리아진을 넣고 실험하였다. 살균력 시험 및 표백력 시험 결과를 표1에 정리하였다.The procedure of Example 1 was repeated except that dioxohexahydrotriazine was added instead of sodium isononanyloxybenzenesulfonate. The sterilization test and the bleaching power test results are summarized in Table 1.
다음의 실시예 3내지 실시예 6은 과탄산나트륨에 a , b 의 첨가제와 c , d , e , f , g의 첨가제를 동시에 혼합하여 첨가했을 경우 살균력, 표백력 및 용해성을 측정하기 위한 것이다.The following Examples 3 to 6 are for measuring the sterilizing power, bleaching power and solubility of sodium percarbonate when the additives a and b and the additives c, d, e, f, and g were simultaneously mixed and added.
[실시예 3][Example 3]
상기 실시예 1과 같은 방법으로 하되, 500㎖ 의 비이커에 과탄산나트륨 100g과 이소노나노닐옥시벤젠설폰네이트 소듐 3g과 중탄산나트륨 5g을 넣고 실험하였다. 이 혼합물의 살균력, 표백력 및 용해 시간을 측정하여 그 결과를 표1에 정리하였다.The procedure of Example 1 was repeated except that 100 g of sodium percarbonate, 3 g of sodium isononanonyloxybenzenesulfonate and 5 g of sodium bicarbonate were added to a 500 ml beaker. The sterilizing power, bleaching power and dissolution time of the mixture were measured, and the results are summarized in Table 1.
[실시예 4][Example 4]
상기 실시예 3과 같은 방법으로 하되, 중산나트륨 대신에 구연산나트륨을 넣고 실험하였다. 이 혼합물 살균력, 표백력 및 용해 시간을 측정하여 그 결과를 표1에 정리하였다.The procedure of Example 3 was repeated except that sodium citrate was added instead of sodium bicarbonate. The mixture sterilizing power, bleaching power and dissolution time were measured, and the results are summarized in Table 1.
[실시예 5][Example 5]
상기 실시예 3과 같은 방법으로 하되, 이소노나노닐옥시벤젠설폰네이트 소듐대신에 디옥소헥사하이드로트리아진을 사용하고, 중탄산나트륨 대신에 구연산나트륨을 사용하여 실험하였다. 이 혼합물 살균력, 표백력 및 용해 시간을 측정하여 그 결과를 표1에 정리하였다.The procedure of Example 3 was repeated except that dioxohexahydrotriazine was used instead of isononanyloxybenzenesulfonate sodium and sodium citrate was used instead of sodium bicarbonate. The mixture sterilizing power, bleaching power and dissolution time were measured, and the results are summarized in Table 1.
[실시예 6][Example 6]
상기 실시예 5와 같은 방법으로 하되, 구연산나트륨 대신 글루콘산나트륨을 사용하여 실험하였다. 이혼합물의 살균력, 표백력 및 용해 시간을 측정하여 그 결과를 표 1에 정리하였다.The same procedure as in Example 5 was conducted except that sodium gluconate was used instead of sodium citrate. The sterilizing power, bleaching power and dissolution time of the mixture were measured, and the results are summarized in Table 1.
[비교예 1][Comparative Example 1]
첨가제 투입되지 않은 과탄산나트륨 의 살균력, 표백력 및 용해 시간을 비교하기 위하여 상기 실시예 1과 같은 방법으로 과탄산나트륨의 살균력, 표백력 및 용해 시간을 측정하여 그 결과를 표 1에 정리하였다.The sterilizing power, bleaching power and dissolution time of sodium percarbonate were measured in the same manner as in Example 1 to compare the sterilizing power, the bleaching power and the dissolution time of the sodium percarbonate not added with additives, and the results are summarized in Table 1.
표 1에 나타난 것과 같이, 과탄산나트륨에 살균표백활성제나 용해성을 향상 시키기 위한 염을 첨가하지 않은 비교예 1의 표백력과 용해도에 비해 본 발명에 의한 살균표백활성제 또는 염을 단독으로 첨가하거나 동시에 첨가하는 경우 그 표백력이 현저히 향상되고 용해 시간도 많이 단축시키는 효과를 얻을 수 있다.As shown in Table 1, the bactericidal bleaching activator or salt of the present invention alone or in combination was added to sodium percarbonate in comparison with the bleaching power and solubility of Comparative Example 1 in which no sterilizing bleaching activator or salt for improving solubility was added , The bleaching force is remarkably improved and the effect of shortening the dissolving time can be obtained.
Claims (4)
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1019960019645A KR100198775B1 (en) | 1996-06-03 | 1996-06-03 | Bleaching agent composition of oxygen series |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1019960019645A KR100198775B1 (en) | 1996-06-03 | 1996-06-03 | Bleaching agent composition of oxygen series |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR980002225A KR980002225A (en) | 1998-03-30 |
| KR100198775B1 true KR100198775B1 (en) | 1999-06-15 |
Family
ID=19460686
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019960019645A KR100198775B1 (en) | 1996-06-03 | 1996-06-03 | Bleaching agent composition of oxygen series |
Country Status (1)
| Country | Link |
|---|---|
| KR (1) | KR100198775B1 (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101139882B1 (en) * | 2006-04-17 | 2012-05-02 | 주식회사 엘지생활건강 | Bleach activator comprising a mixture of alkyloxy and diamine compound and bleach composition comprising the same |
-
1996
- 1996-06-03 KR KR1019960019645A patent/KR100198775B1/en not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| KR980002225A (en) | 1998-03-30 |
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