KR100192829B1 - Method of painting a car body - Google Patents

Method of painting a car body Download PDF

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KR100192829B1
KR100192829B1 KR1019960070854A KR19960070854A KR100192829B1 KR 100192829 B1 KR100192829 B1 KR 100192829B1 KR 1019960070854 A KR1019960070854 A KR 1019960070854A KR 19960070854 A KR19960070854 A KR 19960070854A KR 100192829 B1 KR100192829 B1 KR 100192829B1
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coating
electrodeposition
temperature
improved
vehicle body
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KR1019960070854A
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Korean (ko)
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KR19980051929A (en
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조용래
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양재신
대우자동차주식회사
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Abstract

본 발명은 자동차 제조과정중의 도장방법에 관한 것으로, 차체에 화성피막을 형성하는 표면처리단계와 프라이머 도료가 들어있는 반응조에 차체를 담궈 전착하는 전착도장단계를 포함하여 구성되는 자동차 도장방법에 있어서, 상기 전착도장단계가, 상기 반응조내의 온도를 약 35℃로 유지하며 차체를 전착하는 것을 특징으로 하는 방법으로, 도막두께 편차를 상당히 줄일 수 있고, 부가적으로 전착 수세성이 좋아지며, 작업성이 향상되는 효과를 가진다.The present invention relates to a coating method during the automobile manufacturing process, comprising a surface treatment step of forming a chemical coating on the vehicle body and an electrodeposition coating step of electrodeposition by dipping the vehicle body in a reaction tank containing a primer paint. The electrodeposition coating step is characterized in that the electrode body is electrodeposited while maintaining the temperature in the reaction vessel at about 35 ° C., which can significantly reduce the film thickness deviation, and additionally, the electrodeposition flushing property is improved, and the workability is improved. This has the effect of being improved.

Description

자동차 도장방법(Method of painting a car body)Method of painting a car body

본 발명은 자동차 제조과정중의 도장방법에 관한 것으로, 특히 도장공정의 표면처리단계 후의 전착도장단계에서의 도막두께를 균일하게 형성하는 방법에 관한 것이다.BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a coating method during a vehicle manufacturing process, and more particularly, to a method for uniformly forming a coating film thickness in an electrodeposition coating step after a surface treatment step of a painting process.

일반적으로 자동차 도막은 직사광선, 비, 먼지, 기타 각종의 오염물질 등에 대하여 내구력이 있어야 하며, 움직이는 물체로서의 진동, 마찰 등의 대단히 가혹한 조건에 대하여 내성이 있어야 할 뿐 아니라 최초의 마감도장 당시의 미관이 최대한 그대로 유지되지 않으면 안된다는 고도의 성능이 요구되는 바, 자동차 도막은 색상 및 광택의 유지, 부착성의 유지, 내수성 및 내약품성 등의 내후성이 우수하여야 하므로, 내식성을 갖게 하는 하도도막, 전체도막의 내구성을 향상시키는 중도도막, 외관을 부여하는 상도도막으로 구성된다.In general, automotive coatings must be durable against direct sunlight, rain, dust, and other contaminants, and must be resistant to extremely harsh conditions such as vibration and friction as moving objects. As high performance is required to be maintained as it is, automotive coatings must be excellent in weatherability such as maintaining color and gloss, maintaining adhesion, water resistance and chemical resistance, so that the durability of the undercoat and the overall coating that provides corrosion resistance It consists of an intermediate coating film which improves the quality, and a top coating film which gives an external appearance.

이러한 자동차 도막을 형성하는 대표적인 자동차 도장공정은 도 1에 도시된 바와 같이, 하도도장 전단계인 표면처리단계(S100)와 표면처리한 차체에 프라이머로서 하도도장하는 전착도장단계(S200), 열경화성 전착도료를 160-170℃에서 25-35분정도 가열하여 경화하는 제 1 가열건조단계(S300), 하도도막을 평활하게 하는 공연마단계(S400), 중도도료로 정전도장하는 중도도장단계(S500), 중도도막을 130-140℃에서 20-30분정도 가열하는 제 2 가열건조단계(S600), 중도도막을 평활하게 하는 수연마단계(S700), 도장의 마지막 마무리단계인 상도도장단계(S800), 열경화성 상도도료를 140-150℃에서 약30분 정도 가열하여 경화하는 제 3 가열건조단계(S900) 및 마감상태의 이상유무를 체크하는 검사단계(S1000)로 구성된다.Representative automotive coating process for forming such automotive coating film is, as shown in Figure 1, the surface treatment step (S100) that is the pre-painting step and the electrodeposition coating step (S200) to coat the primer as a primer on the surface-treated car body, thermosetting electrodeposition paint The first heating and drying step (S300) for curing by heating for about 25-35 minutes at 160-170 ℃, performing performance step (S400) to smooth the coating film, medium coating step (S500), electrostatic coating with a medium paint, The second heating and drying step (S600) of heating the intermediate coating film at 130-140 ° C. for 20-30 minutes, the water polishing step of smoothing the coating film (S700), the top coating step (S800), which is the final finishing step of the coating, It consists of a third heat drying step (S900) for curing by curing about 30 minutes at 140-150 ° C thermosetting top paint and an inspection step (S1000) for checking the abnormality of the finished state.

이중 상기 전착도장단계(S200)는 표면처리 한 차체를 약 30℃로 유지되는 반응조내의 전착용의 도료속에 담궈, 차체를 양극으로 하고 도료를 음극으로 하여 전기화학적으로 도막을 형성시킨 후, 수세를 하는 공정으로 이루어져 있다. 이때 수세를 하고난 오염된 물은 유에프(UF,Ultra Filton)를 사용하여 처리한다.In the electrodeposition coating step (S200), the surface treated car body is immersed in the electrodeposition paint in a reaction tank maintained at about 30 ° C., and the water body is used as an anode and the paint is used as a cathode to form an electrochemical film, followed by water washing. It consists of a process. At this time, the contaminated water after washing with water is treated with EU (Ultra Filton).

그러나, 도막두께의 편차가 차체 부위별로 상존하는 문제점이 있는데, 특히 바디의 수평과 수직부의 도막편차가 심해 도막의 품질이 저하되고, 이로 인해 생산성이 떨어지는 문제점이 있었다.However, there is a problem that the variation in the thickness of the coating film exists for each vehicle body part. In particular, the coating film is deteriorated in the horizontal and vertical portions of the body so that the quality of the coating film is deteriorated.

이에 본 발명은 상기한 문제점을 해결하기 위한 것으로, 전착도장단계에서 형성된 도막의 편차를 최소화할 수 있는 자동차 도장방법을 제공함에 그 목적이 있다.Accordingly, an object of the present invention is to provide an automobile coating method capable of minimizing the deviation of the coating film formed in the electrodeposition coating step.

상기한 목적을 이루기 위한 본 발명의 자동차 도장방법은,Automotive coating method of the present invention for achieving the above object,

차체에 화성피막을 형성하는 표면처리단계와 프라이머 도료가 들어있는 반응조에 차체를 담궈 전착하는 전착도장단계를 포함하여 구성되는 자동차 도장방법에 있어서, 상기 전착도장단계가, 상기 반응조내의 온도를 약 35℃로 유지하며 차체를 전착하는 것을 특징으로 한다.In the automobile coating method comprising a surface treatment step of forming a chemical film on the vehicle body and an electrodeposition coating step of electrodepositing the vehicle body in a reaction tank containing a primer paint, the electrodeposition coating step is a temperature of about 35 It is characterized in that the electrode body is deposited while maintaining at ℃.

본 발명의 핵심적인 내용인 반응조내의 온도변화는 종래의 약 30℃로 유지되는 반응조내에서 도료를 전착하는 것보다 약 35℃로 하여 도료를 전착하였을 때 도막 두께 편차가 현저히 줄어든 것을 알아내었다.The temperature change in the reaction tank, which is the core content of the present invention, was found to significantly reduce the film thickness variation when the paint was electrodeposited to about 35 ° C. rather than electrodepositing the paint in the conventional reaction tank maintained at about 30 ° C.

도 1은 종래의 자동차 도장방법의 공정도이다.1 is a process chart of a conventional automobile coating method.

이하 본 발명의 실시예를 첨부된 도면을 참조하여 상세하게 설명한다.Hereinafter, exemplary embodiments of the present invention will be described in detail with reference to the accompanying drawings.

본 실시예는 종래의 전착도장설비의 보완 없이도 전착도장에 영향을 주는 반응인자의 값을 조절하여 도막편차를 줄일 수 있는 지에 대한 실험이다.This embodiment is an experiment to determine whether the coating film deviation can be reduced by adjusting the value of the reaction factors affecting the electrodeposition coating without supplementing the conventional electrodeposition coating equipment.

이 실험은 고형분이 20.9%이고, P/B(Pigment/Binder)은 0.35, pH는 6.1, 콘덕턴스는 1490μS 인 도료를 시료로 하여 반응조 온도 변화에 따른 영향 및 효과를 분석한 것으로, 실험기준온도로서 28℃, 30℃, 32℃, 35℃를 택하였고, 이 온도 변화에 따라 도막두께와 도막두께 편차, 쓰로우파워(THROWPOWER), 가스핀홀 럽쳐(gas pinhole rupture) 전압, UF 투과량(flux), 표면 조도(roughness) 및 수세성을 실험하였다.This experiment analyzed the effects and effects of the reaction tank temperature with 20.9% solids, 0.35 P / B (Pigment / Binder), 6.1 pH, and 1490μS conductance. 28 ℃, 30 ℃, 32 ℃, and 35 ℃ were selected as the temperature change, and the film thickness and film thickness variation, THROWPOWER, gas pinhole rupture voltage, UF flux , Surface roughness and flushing were tested.

상기한 실험의 결과는 하기 표와 같다.The results of the above experiments are shown in the table below.

반응조 온도변화에 따른 도막두께Coating thickness depending on reactor temperature 온도(℃)Temperature (℃) 도막두께(μm )Coating thickness (μm) 2828 26.526.5 3030 34.434.4 3232 41.741.7 3535 47.047.0

반응조 온도변화에 따른 도막두께 편차Coating thickness variation with reactor temperature change 온도(℃)Temperature (℃) 코팅전압(V)Coating voltage (V) 도막두께(μm)Coating thickness (μm) MAX.MAX. MIN.MIN. 평균Average 표준편차Standard Deviation 2828 280280 36.336.3 25.425.4 29.229.2 2.52.5 3030 250250 34.634.6 27.227.2 29.829.8 1.61.6 3232 220220 33.233.2 28.728.7 29.129.1 0.90.9 3535 190190 31.931.9 29.029.0 29.829.8 0.70.7

반응조 온도변화에 따른 쓰로우파워Throw power according to temperature change of reactor 온도(℃)Temperature (℃) 쓰로우파워(cm)Throw power (cm) 2828 20.920.9 3030 19.519.5 3232 19.319.3 3535 19.019.0

반응조 온도 변화에 따른 가스핀홀럽쳐전압Gas pinhole voltage due to reactor temperature change 온도(℃)Temperature (℃) 럽쳐 전압(V)Rupture voltage (V) LEGEND G.A.LEGEND G.A. PPG 3/2 G.A.PPG 3/2 G.A. 2828 230230 220220 3030 280280 240240 3232 300300 280280 3535 320320 320320

반응조 온도 변화에 따른 유에프 투과량EU permeation rate according to the change of reactor temperature 온도(℃)Temperature (℃) 투과량(ml/min)Permeation amount (ml / min) 2828 130130 3030 139139 3232 152152 3535 171171

반응조 온도 변화에 따른 표면 조도Surface Roughness with Reactor Temperature Change 온도(℃)Temperature (℃) 조도(μm)Roughness (μm) 2828 0.2040.204 3030 0.1840.184 3232 0.1840.184 3535 0.1820.182

상기한 표 1에서의 표면두께 값은 극간거리를 16cm로 하고, 260V의 전압을 2분간 통전시킨 결과이며, 표 2는 7회 측정하여 도막두께 30μm를 기준으로 한 결과이고, 표 3은 지름 1.75mm인 파이프로서 실험하는 파이프법으로 측정하였으며, 상기 표 4에서 LEGEND G.A.와 PPG 3/2 G.A.는 실험 강종이고 통전시간을 2분으로하며 극간거리를 16cm로 한 결과이며, 표 5는 로미콘(ROMICON) UF 장치로 실험한 결과이고, 표 6은 도막두께 30μm를 기준으로 측정한 것이다.The surface thickness value in Table 1 above is a result of applying a distance of 16 cm to a pole and energizing a voltage of 260 V for 2 minutes. Table 2 is a result of measuring 7 times and a thickness of 30 μm as a reference. It was measured by the pipe method to test as a pipe of mm, in Table 4 LEGEND GA and PPG 3/2 GA is the experimental steel grade, the conduction time is 2 minutes and the distance between the poles to 16cm, Table 5 is the Lomicon ( ROMICON) results of the experiment with the UF device, Table 6 is measured based on the coating film thickness 30μm.

그리고, 각 온도별로 전착시편을 만든후, 수세하기전 2분, 5분씩 각각 방치시킨 후 수세한 결과 전착 외관 상태 모두 양호하다는 결과를 얻었다.After the electrodeposition specimens were prepared for each temperature, the specimens were left for 2 minutes and 5 minutes before washing with water, followed by washing with water.

따라서 종래의 전착반응조 관리온도인 30℃에서 35℃로 상향관리할 경우, 도막두께 편차가 현저히 줄어들게 되고, 유에프 투과량이 증가하게 되어 전착 수세성이 좋아지며, 아연도 강판의 가스핀홀럽쳐전압이 상승함에 따라 작업성이 향상되게 됨을 알 수 있었다.Therefore, when the upward management from the conventional electrodeposition reaction temperature of 30 ℃ to 35 ℃, the film thickness variation is significantly reduced, the permeation of the UPF increases, the electrodeposition flushing ability is improved, the gas pin hole voltage of the galvanized steel sheet is increased As the workability was improved.

또한 온도를 상향시킬 경우 쓰로우파워가 다소 감소하지만 전착 품질에 영향을 미칠 수준은 아님을 알 수 있었다.In addition, when the temperature is increased, the throw power is slightly reduced but it does not affect the electrodeposition quality.

본 발명에 따라 전착도장 반응조의 온도를 상향 조정할 경우, 도막두께 편차를 상당히 줄일 수 있고, 부가적으로 전착 수세성이 좋아지며, 작업성이 향상되는 효과가 있다.According to the present invention, when the temperature of the electrodeposition coating reactor is adjusted upward, the film thickness variation can be considerably reduced, and in addition, the electrodeposition water washing property is improved, and the workability is improved.

Claims (1)

차체에 화성피막을 형성하는 표면처리단계와 프라이머 도료가 들어있는 반응조에 차체를 담궈 전착하는 전착도장단계를 포함하여 구성되는 자동차 도장방법에 있어서,In the automotive coating method comprising a surface treatment step of forming a chemical film on the vehicle body and electrodeposition coating step of electrodepositing the vehicle body in a reaction tank containing a primer paint, 상기 전착도장단계가, 상기 반응조내의 온도를 약 35℃로 유지하며 차체를 전착하는 것을 특징으로 하는 자동차 도장방법.The electrodeposition coating step, the vehicle coating method characterized in that the electrode body is maintained while maintaining the temperature in the reaction tank to about 35 ℃.
KR1019960070854A 1996-12-24 1996-12-24 Method of painting a car body KR100192829B1 (en)

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KR100395148B1 (en) * 2000-11-27 2003-08-21 동부제강주식회사 Environment Affinitive Color Clear Coated Steel Sheet
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