KR0182600B1 - A fluoro carbon resin containing composition for ironing in a household - Google Patents
A fluoro carbon resin containing composition for ironing in a household Download PDFInfo
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- KR0182600B1 KR0182600B1 KR1019960017978A KR19960017978A KR0182600B1 KR 0182600 B1 KR0182600 B1 KR 0182600B1 KR 1019960017978 A KR1019960017978 A KR 1019960017978A KR 19960017978 A KR19960017978 A KR 19960017978A KR 0182600 B1 KR0182600 B1 KR 0182600B1
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
- D06M15/277—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof containing fluorine
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/53—Polyethers
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
Abstract
1. 특허 청구의 범위에 기재된 발명이 속하는 기술분야1. The technical field to which the invention described in the claims belongs
다림질 용이제 조성물Ironing Agonist Composition
2. 발명이 해결하고자 하는 기술적 과제2. Technical problem to be solved by the invention
의류를 다림질 할 때 다리미와 의류와의 마찰을 적게끔 하게 하여 다림질시 다림질이 쉽게 될 수 있게 하고, 인체에서 발생되는 오염 및 외부로 부터 발생되는 오염이 의류에 부착되어 의류가 오염 되는 것을 방지하는 기능을 가진 다림질 용이제 조성물.When ironing clothes, the iron and the friction between clothes can be reduced so that ironing can be done easily when ironing, and the pollution generated from the human body and the pollution from outside are attached to the clothes to prevent the clothing from being contaminated. Iron agonist composition having a function.
3. 발명이 해결방법 요지3. Invention Solution Summary
유용한 다림질 용이제 조성물이 말레인산과 아크릴산염의 공중합체인 수용성폴리머와 폴리에틸렌글리콜, 실리콘오일 에멀젼을 주성분으로 한 조성에 불소수지를 수용성으로 만든 것을 1 내지 10중량%를 함유하는 것을 특징으로 한다.The useful ironing agent composition contains 1 to 10% by weight of a water-soluble polymer which is a copolymer of maleic acid and an acrylate, and made of water-soluble fluorine resin in a composition mainly composed of polyethylene glycol and silicone oil emulsion.
4. 발명의 중요한 용도4. Important uses of the invention
다림질 용이제Ironing agents
Description
본 발명은 의류의 오염 부착을 방지하는 효과를 갖고 있는 다림질 용이제에 관한 것으로서 더욱 상세하게는 방수, 방유 효과를 낼 수 있는 불소수지를 수용성으로 변환시켜 함유시킨 다림질 용이제의 조성물에 관한것이다.The present invention relates to an ironing agent having an effect of preventing fouling of clothing, and more particularly, to a composition of an ironing agent containing a fluorine resin capable of producing a waterproofing and oilproofing effect by converting it into a water-soluble.
일반적으로 다림질 용이제는 옷을 다림질할 때 다림질이 쉽게 되게 하고, 세탁, 건조 후 옷에 남아있는 주름을 쉽게 펴지게 하는 기능과, 겨울철 건조한 기후에 발생되는 정전기 발생을 예방하는 기능을 가진 제품을 말한다. 다림질 용이제가 나오기 전에는 다림질 풀을 주로 사용하였는데 최근에는 그 수요가 줄어들고 있는 추세이다. 다림질 풀의 수요가 줄어드는 이유는 다림질풀의 주성분으로 전분과 실리콘 에멀젼을 사용하고 있는데 전분은 옷에 빴빳한 강도를 주기 위해서는 4 내지 10중량%를 사용해야 하는데 전분의 함량을 4중량% 이상 사용시에는 다림질풀을 의류에 분무하고 난 다음 다림질을 하면 다리미에 눌러 붙는 현상이 있고, 다림질 후에 전분이 옷에 흰 잔유물을 생성시키기 때문에 유색옷에는 사용이 힘들었다. 이런 문제점이 있기에 최근에는 전분대신 건조 후에도 흰잔유물 생성이 적고, 조금만 첨가하여도 섬유에 빳빳한 강도를 줄 수 있는 수용성 폴리머를 사용한다.In general, the ironing agent is a product having a function of making ironing easier when ironing clothes, easily unfolding wrinkles remaining in clothes after washing and drying, and preventing static electricity generated in a dry climate in winter. . Prior to ironing agents, ironing pools were used. Recently, the demand is decreasing. The reason why the demand for ironing paste is decreased is that starch and silicone emulsion are used as the main ingredients of ironing paste. Starch should be used in an amount of 4 to 10% by weight in order to give a strong strength to clothes. Spraying the grass onto clothing and then ironing causes the iron to squeeze out, and after ironing, starch creates white residue on clothes, making it difficult to use on colored clothes. Due to this problem, recently, instead of starch, a small amount of white residue is produced even after drying, and a little water is added to the water-soluble polymer that gives strength to the fiber.
다림질 용이제의 주성분은 섬유에 빳빳한 강도를 부여하는 수용성 폴리머와 다림질시 다림질이 쉽게 되게끔하는 윤활제, 다림질시 섬유에서 정전기 및 분무시 발생되는 기포를 예방하는 실리콘 에멀젼, 조성물의 부패를 방지하는 방부제, 향료 등으로 이루어져 있다.The main components of the ironing agent are water-soluble polymers that give strength to the fibers, lubricants that make ironing easier when ironing, silicone emulsions that prevent bubbles from occurring during electrostatic and spraying of the fibers during ironing, and preservatives that prevent rotting of the composition. , Spices and so on.
본 발명의 목적은 일반 다림질 풀이나 다림질 용이제의 기능에 없는 방수, 방유 기능을 첨가하여 다림질 용이성과 피세정율이 우수한 다림질 용이제 조성물을 개발하는데 있다.It is an object of the present invention to develop an ironing agent composition having excellent ironing ease and cleanability by adding a waterproofing and oilproofing function which is not in the function of an ordinary ironing iron or an ironing agent.
특히 본 발명에서는 말레인산과 아크릴산염의 공중합체 1 내지 10 중량%, 폴리에틸렌글리콜 0.1 내지 1.0중량%, 실리콘 에멀젼 0.1 내지 1.0중량% 및 불소수지 에멀젼 1 내지 10중량%를 함유하고 기타 첨가제를 가하여 이루어진 다림질 용이제 조성물을 제공한다.In particular, in the present invention, iron containing 1 to 10% by weight of copolymer of maleic acid and acrylate, 0.1 to 1.0% by weight of polyethylene glycol, 0.1 to 1.0% by weight of silicone emulsion, and 1 to 10% by weight of fluororesin emulsion and adding other additives Provides an easy agent composition.
본 발명에서 다림질 용이제의 주원료에 대한 구성 및 특성에 관하여 하기에 상세히 설명한다.The constitution and properties of the main raw material of the ironing agent in the present invention will be described in detail below.
폴리머는 그 종류가 상당히 많이 있으나, 본 발명에서는 세탁 세제에 사용하는 폴리머인 말레인산 또는 그의 염과 아크릴산 또는 그의 염의 공중합체를 사용하며 바람직하게는 말레인산과 아크릴산의 반응 몰비율이 3:7로 이루어진 공중합체를 사용한다. 말레인산 또는 그의 염과 아크릴산 또는 그의 염의 공중합체인 폴리머는 분말세제에서 오염이 의류에 부착되는 것을 방지를 해주는 역할을 하고, 다림질 건조 후에 흰잔유물 생성이 적다.Although there are many kinds of polymers, in the present invention, maleic acid or a salt thereof and a copolymer of acrylic acid or a salt thereof, which is a polymer used in laundry detergent, are used. Preferably, the reaction molar ratio of maleic acid and acrylic acid is 3: 7. Use coalescing The polymer, which is a copolymer of maleic acid or a salt thereof and acrylic acid or a salt thereof, serves to prevent the adhesion of dirt to clothing in the powder detergent, and produces less white residue after ironing and drying.
폴리머는 그 함량이 1 내지 10중량%를, 바람직하게는 2 내지 5중량%를 사용한다. 본 발명에서는 사용된 폴리머는 그 분자량이 약 70,000 정도인 BASF사의 CP-5 라는 제품을 사용하였다. 폴리머의 함량이 너무 높을 경우 다리미에 눌어붙는 현상이 발생되거나, 흰잔유물이 생성된다. 폴리머의 함량이 낮으면 섬유의 강도가 떨어지므로 최소 2중량% 이상 사용하는 것이 바람직하다.The polymer is used in an amount of 1 to 10% by weight, preferably 2 to 5% by weight. In the present invention, the polymer used was a BASF CP-5 product having a molecular weight of about 70,000. If the content of the polymer is too high, it will stick to the iron or produce white residue. If the polymer content is low, the strength of the fiber is lowered, so it is preferable to use at least 2% by weight or more.
섬유와 다리미 사이에 부착을 방지해주는 부착 방지제로는 가장 많이 사용되고 있는 폴리에틸렌글리콜을 사용하였다. 폴리에틸렌글리콜은 그 분자량에 따라 성상이 변하는데 본 발명에서는 분자량이 300 이하인 것을 사용하였다. 분자량이 1000 이상인 것을 사용하면 제품이 저온에서 뿌옇게 되는 현상이 발생되기 때문에 본 발명에서는 저온에서도 그 형태가 변하지 않는 분자량이 300정도인 것을 0.1 내지 1.0중량%을 사용하였다. 폴리에틸렌글리콜은 그 함량이 높아지면 다림질 용이성은 좋아지나 섬유의 빳빳한 강도를 떨어뜨리므로 적당량을 사용해야한다. 폴리에틸렌 글리콜은 그 함량이 0.2 내지 0.5중량%를 사용할 때 섬유의 빳빳한 강도에 영향이 적고 0.5중량% 이상 사용할 때는 다림질 용이성이 동일하게 나타난다.Polyethylene glycol, which is used most often, is used as an anti-sticking agent to prevent adhesion between fibers and irons. Polyethylene glycol has a change in properties depending on its molecular weight, but in the present invention, a molecular weight of 300 or less was used. When the molecular weight of 1000 or more is used, the phenomenon that the product becomes cloudy at low temperature occurs, so in the present invention, 0.1 to 1.0% by weight was used, which has a molecular weight of about 300 which does not change its shape even at low temperature. The higher the polyethyleneglycol content, the better the ironing ease, but the lower the strength of the fiber, the appropriate amount should be used. Polyethylene glycol is less affected by the strength of the fiber when the content is used 0.2 to 0.5% by weight, and the same ease of ironing when using more than 0.5% by weight.
실리콘 에멀젼은 일반적으로 섬유의 유연 및 정전기 방지, 소포제 등의 원료로 많이 사용되고 있는 원료로서 본 발명에서도 적당량 사용하였을 경우 동절기 기후에서 발생될 수 있는 정전기 발생을 예방해주고 조성물을 분무 시켰을 경우 발생되는 기포를 억제 해주는 작용을 한다. 본 발명에서 사용된 실리콘은 폴리디메칠실록산이 주성분이며 에멀젼 형태는 비이온계로서 물에 쉽게 용해되고, 온도 및 pH 조건에 안정하여 산업적으로 매우 광범위하게 사용되고 있는 소포제이다.Silicone emulsion is generally used as a raw material for the softness of the fabric, antistatic, antifoaming agent, and the like, and when used in the present invention, an appropriate amount prevents the generation of static electricity that may occur in the winter climate and prevents bubbles generated when the composition is sprayed. It acts to suppress. The silicone used in the present invention is an antifoaming agent, which is mainly composed of polydimethylsiloxane and the emulsion form is a nonionic, easily soluble in water, stable to temperature and pH conditions, and widely used industrially.
본 발명에서는 기존에 나와 있는 다림질 용이제와 차별화된 기능이 있는데 바로 방수, 방유 기능이다. 방수, 방유기능은 일상생활에서 의류에 부착되기 쉬운오염으로 부터 의류를 보호할 수 있기 때문에 비오는 날이나, 음식점에서 음식물이 튀었을 경우 김치국물이나 케찹, 커피 등 잘 지워지지 않는 오염으로 부터 의류를 보호할 수 있고, 성장기의 어린아이들이 활동중에 외부로부터의 오염이 의류에 부착되는 것을 방지 해주기 때문에 세탁시 절수, 절전할 수 있고 오염을 쉽게 분리할 수 있는 장점이 있기 때문에 본 조성물로 다림질한 의류를 입었을 경우 빨래하는 사람이 힘이 적게 들고 잦은 세탁으로 인한 의류의 손상을 최소화할 수 있는 장점이 있다.In the present invention, there is a function that is different from the conventional ironing agent, which is waterproof and oil proof function. The waterproof and oil-proof function protects clothing from contamination that is easily attached to clothing in everyday life, so it protects clothing from contamination that is hard to remove such as kimchi soup, ketchup, coffee, etc. in case of food splashing on rainy days or restaurants. It is possible to save children's clothes during the growing season and prevent contamination from attaching to clothing during activities. When worn, there is an advantage that the person who washes less power and can minimize the damage of clothing due to frequent washing.
본 발명에서 사용된 불소수지는 퍼플루오루알킬아크릴레이트 공중합체로서 방수, 방유 기능을 주는데 사용되었고 1 내지 10중량%를, 바람직하게는 2 내지 5중량%를 사용한다. 그 함량이 2% 이하일 경우 합성섬유는 방수, 방유기능을 할 수 있으나, 면 섬유의 경우에는 방수, 방유 기능이 떨어져 그 효과를 기대하기 어렵다. 불소수지 함량이 5중량% 이상 일때는 방수, 방유 효과는 뛰어나지만 다림질 용이제의 섬유에 대한 빳빳한 강도를 저하 시키므로 그 함량을 적절히 사용하는 것이 바람직하다. 본 발명에서 사용된 불소수지는 퍼플루오루알킬아크릴레이트 공중합체로서 공업적으로는 섬유공업에서 유연, 발수, 발유재로 사용되고 있으며 본 발명에서는 물에서 녹지 않는 불소수지의 특성을 변화시켜서 물에 잘 녹게끔 수용성화 시킨 것을 사용하였고, 그 외관은 유백색이다. 또한 불소수지는 하기 일반식으로 표시되는 퍼플루오루알킬아크릴레이트 공중합체가 바람직하다.The fluororesin used in the present invention was used to give a waterproof and oil-proof function as a perfluorolucoacrylate acrylate copolymer, and used 1 to 10% by weight, preferably 2 to 5% by weight. If the content is 2% or less, synthetic fibers may function as waterproofing or oilproofing, but in the case of cotton fiber, the waterproofing and oilproofing function is difficult to expect the effect. When the fluorine resin content is more than 5% by weight, it is excellent in waterproofing and oilproofing effect, but it is preferable to use the content appropriately since it lowers the strength of the iron of the iron easily. The fluororesin used in the present invention is a perfluorolucoacrylate acrylate copolymer, which is industrially used as a flexible, water-repellent and oil-repellent material in the textile industry. Solubilized to melt was used, the appearance is milky white. In addition, the fluororesin is preferably a perfluorolukoacrylate acrylate copolymer represented by the following general formula.
상기식에서 Rf는이다.Where Rf is to be.
다림질 용이제의 조성물에는 상기에서 사용된 원료들외에 다림질 용이제의 장기간 보존을 위해서 방부제를 꼭 첨가 해야하는데, 본 발명에서는 물이 주성분인 다림질 용이제의 특성을 고려하여 수용성이 좋은 방부제를 사용하였다.In addition to the raw materials used above, iron preservatives must be added to the composition of the ironing agent for the long term preservation of the ironing agent. In the present invention, a water-soluble preservative is used in consideration of the properties of the ironing agent, the main component of water. .
또한 다림질시 사용자의 사용감을 좋게하여 소비자의 사용감을 만족시킬 수 있도록 조성물에 향을 첨가하였으며 향료는 대부분 유성이기 때문에 소량 사용하는 것이 바람직하다.In addition, it is preferable to use a small amount of the fragrance is added to the composition to improve the user's feeling when ironing to satisfy the consumer's feeling and the fragrance is mostly oily.
다음의 실시예에서 본 발명에서 조제한 조성물의 성능을 평가하였고 특별한 언급이 없는 한 조성물의 단위는 중량%로 한다.In the following examples, the performance of the compositions prepared in the present invention was evaluated and unless otherwise specified, the units of the composition are in weight percent.
[실시예]EXAMPLE
1. 방수, 방유성능 실험 방법1. Test method of waterproof and oilproof performance
상기에서 제조한 조성물을 100% 면에 분무한 후 다림질하여 면포위에 물과 식용유를 각각 1방울씩 떨어뜨린 후 약 30분 후의 면포 위의 상태를 육안으로 판단하였다.The composition prepared above was sprayed onto 100% cotton, and then ironed to drop 1 drop of water and cooking oil on the cotton cloth, and then the state on the cotton cloth was visually determined after about 30 minutes.
2. 다림질 용이성2. ease of ironing
시판중인 다림질 용이제와 본 발명 조성물을 동일한 방법으로 다림질시 다림질이 쉽게 되는가를 비교(다림질 전문 모니터 3명이 와이셔츠를 각각 3장씩 다림질한 후 평가)하였다.A commercially available ironing agent and the composition of the present invention were compared with the same method for easy ironing when ironing (three iron professional monitors were evaluated after ironing three sheets of shirts, respectively).
+3 기준품 보다 월등히 우수함Much better than the +3 standard
+2 기준품 보다 우수함Better than +2 reference
+1 기준품 보다 약간 우수함Slightly better than the +1 reference
0 기준품과 동일함0 Same as reference
-1 기준품 보다 떨어짐-1 below standard
-2 기준품 보다 월등히 떨어짐-2 far below the standard
3. 피세정율의 측정 방법3. How to measure the rate of cleaning
1) 가로20㎝ × 세로30㎝인 백면포에 기준품(시판중인 제품)과 본 개발 조성물을 일정하게 분사한 후 다림질하였다.1) A standard product (commercially available product) and the present development composition were sprayed on a white cloth having a width of 20 cm x 30 cm and then ironed.
2) 다음의 오염액에 위에서 다림질한 백포를 침적시킨 후, 1일간 자연 건조 후 인공오염포로 사용하였다.2) A white cloth ironed in the stomach was deposited in the following contaminated solution, and then dried for 1 day and used as an artificial contaminated cloth.
인공오염 조성표Artificial Pollution Composition Table
피클로로에틸렌 1000ccPychloroethylene 1000cc
카본 0.6g0.6 g of carbon
면실유 10g10 g of cottonseed oil
오레인산 2.0g2.0 g of oleic acid
팔미트산 1.6gPalmitic acid 1.6 g
유동파라핀 1.0g1.0g of liquid paraffin
시판 중질세제를 표준사용량에 맞추어서 20℃에서 terg-O-tometer를 이용하여 상기 인공오염도를 10분간 1회 세척, 3분씩 2회 행굼 후 자연건조한 다음 백도계로 포의 표면 반사율을 측정하였다.A commercially available heavy detergent was washed once with artificial terg-O-tometer at 20 ° C. for 10 minutes, twice with 3 minutes of rinsing for 3 minutes, and then air dried, and then the surface reflectance of the fabric was measured with a white scale.
실시예에서도 알 수 있듯이 불소수지인 퍼플루오루아크릴레이트 공중합체가 함유될 때 방수, 방유 기능이 나타나는데 그 함량이 높아 질수록 피세정율이 높아짐을 알 수가 있고, 다림질 용이성도 향상됨을 알 수 있다. 다림질 용이성에 있어서도 윤활제 역할을 하는 폴리에틸렌 글리콜과 실리콘에멀젼을 동시에 사용할 때 다림질 용이성이 향상되나 함량이 0.5중량% 이상일 때 동일한 효과가 나타난다. 본 발명에서는 일반 다림질 용이제가 할 수 없는 방수, 방유 기능을 첨가하여 차별화된 다림질 용이제 조성물을 조제 하였다. 본 발명자들은 이와 같이 조제된 다림질 용이제 조성물이 일반 다림질 용이제에 비하여 피세정력 및 오염부착 방지력이 월등함을 발견하였다.As can be seen from the embodiment, when the fluororesin perfluoroluacrylate copolymer is contained, the waterproofing and oilproofing functions are shown. As the content thereof increases, the cleaning rate is increased, and the ease of ironing is also improved. . The ease of ironing also improves the ease of ironing when polyethylene glycol and silicone emulsion, which act as lubricants, are simultaneously used, but the same effect occurs when the content is 0.5 wt% or more. In the present invention, by adding a waterproof, oil-proof function that can not be a general ironing agent was prepared a differentiated ironing agent composition. The present inventors have found that the iron preparation composition thus prepared has superior cleaning power and antifouling ability compared with general ironing agents.
Claims (3)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1019960017978A KR0182600B1 (en) | 1996-05-27 | 1996-05-27 | A fluoro carbon resin containing composition for ironing in a household |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1019960017978A KR0182600B1 (en) | 1996-05-27 | 1996-05-27 | A fluoro carbon resin containing composition for ironing in a household |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR970075094A KR970075094A (en) | 1997-12-10 |
| KR0182600B1 true KR0182600B1 (en) | 1999-05-01 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019960017978A KR0182600B1 (en) | 1996-05-27 | 1996-05-27 | A fluoro carbon resin containing composition for ironing in a household |
Country Status (1)
| Country | Link |
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| KR (1) | KR0182600B1 (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20010044682A (en) * | 2001-03-15 | 2001-06-05 | 박청기 | Coating agent for textile |
| KR20030090120A (en) * | 2002-05-21 | 2003-11-28 | 주식회사 에이프로스 엔터프라이즈 | Hydrophobic aid composition for ironing and method of preparing same |
| KR20210085948A (en) | 2019-12-31 | 2021-07-08 | 이강태 | Rideable compactor for attaching to cultivator |
-
1996
- 1996-05-27 KR KR1019960017978A patent/KR0182600B1/en not_active IP Right Cessation
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20010044682A (en) * | 2001-03-15 | 2001-06-05 | 박청기 | Coating agent for textile |
| KR20030090120A (en) * | 2002-05-21 | 2003-11-28 | 주식회사 에이프로스 엔터프라이즈 | Hydrophobic aid composition for ironing and method of preparing same |
| KR20210085948A (en) | 2019-12-31 | 2021-07-08 | 이강태 | Rideable compactor for attaching to cultivator |
Also Published As
| Publication number | Publication date |
|---|---|
| KR970075094A (en) | 1997-12-10 |
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