KR0172144B1 - Cylindrical hearing bushing for internal combustion engine - Google Patents

Cylindrical hearing bushing for internal combustion engine Download PDF

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KR0172144B1
KR0172144B1 KR1019950017410A KR19950017410A KR0172144B1 KR 0172144 B1 KR0172144 B1 KR 0172144B1 KR 1019950017410 A KR1019950017410 A KR 1019950017410A KR 19950017410 A KR19950017410 A KR 19950017410A KR 0172144 B1 KR0172144 B1 KR 0172144B1
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weight
cast iron
internal combustion
phosphorus
boron
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KR1019950017410A
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KR960014378A (en
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뷔닝 프리트요프
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한스 귄터 보중, 슈테판 쇼버
만 베 운트 베 디젤 악티엔게젤샤프트
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C37/00Cast-iron alloys
    • C22C37/04Cast-iron alloys containing spheroidal graphite
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C37/00Cast-iron alloys
    • C22C37/06Cast-iron alloys containing chromium
    • C22C37/08Cast-iron alloys containing chromium with nickel
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C37/00Cast-iron alloys
    • C22C37/10Cast-iron alloys containing aluminium or silicon
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02BINTERNAL-COMBUSTION PISTON ENGINES; COMBUSTION ENGINES IN GENERAL
    • F02B3/00Engines characterised by air compression and subsequent fuel addition
    • F02B3/06Engines characterised by air compression and subsequent fuel addition with compression ignition
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02FCYLINDERS, PISTONS OR CASINGS, FOR COMBUSTION ENGINES; ARRANGEMENTS OF SEALINGS IN COMBUSTION ENGINES
    • F02F1/00Cylinders; Cylinder heads 
    • F02F1/02Cylinders; Cylinder heads  having cooling means
    • F02F1/10Cylinders; Cylinder heads  having cooling means for liquid cooling
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02FCYLINDERS, PISTONS OR CASINGS, FOR COMBUSTION ENGINES; ARRANGEMENTS OF SEALINGS IN COMBUSTION ENGINES
    • F02F7/00Casings, e.g. crankcases or frames
    • F02F2007/0097Casings, e.g. crankcases or frames for large diesel engines
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F05INDEXING SCHEMES RELATING TO ENGINES OR PUMPS IN VARIOUS SUBCLASSES OF CLASSES F01-F04
    • F05CINDEXING SCHEME RELATING TO MATERIALS, MATERIAL PROPERTIES OR MATERIAL CHARACTERISTICS FOR MACHINES, ENGINES OR PUMPS OTHER THAN NON-POSITIVE-DISPLACEMENT MACHINES OR ENGINES
    • F05C2201/00Metals
    • F05C2201/04Heavy metals
    • F05C2201/0469Other heavy metals
    • F05C2201/0475Copper or alloys thereof
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F05INDEXING SCHEMES RELATING TO ENGINES OR PUMPS IN VARIOUS SUBCLASSES OF CLASSES F01-F04
    • F05CINDEXING SCHEME RELATING TO MATERIALS, MATERIAL PROPERTIES OR MATERIAL CHARACTERISTICS FOR MACHINES, ENGINES OR PUMPS OTHER THAN NON-POSITIVE-DISPLACEMENT MACHINES OR ENGINES
    • F05C2203/00Non-metallic inorganic materials
    • F05C2203/04Phosphor

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Cylinder Crankcases Of Internal Combustion Engines (AREA)
  • Pistons, Piston Rings, And Cylinders (AREA)
  • Sliding-Contact Bearings (AREA)

Abstract

본 발명은 연소 동력 기관용, 특히 대형 디젤 엔진용 실린더 라이너에 관한 것으로, 이 실린더 라이너는 기조 합금으로서 구상 흑연을 가진 퍼얼라이트계 주철로 주조되며, 그 주철의 합금 조직은 명확한 경계로 그물형으로 균일하게 분포된 시멘타이트/스티어타이트 조직부를 구비하며, 기조 합금에는 합금 원소로서 붕소 및/또는 인과, 필요시 부가적으로 니켈, 몰리브덴, 크롬, 티타늄, 질소, 주석 및 바나듐이 정해진 조성으로 첨가된다.FIELD OF THE INVENTION The present invention relates to cylinder liners for combustion power engines, in particular large diesel engines, which cylinder liners have spherical graphite as a base alloy.                 Cast from cast iron, the alloy structure of the cast iron has a cementite / steerite structure that is uniformly distributed in a mesh with clear boundaries.                 As elements boron and / or phosphorus and, if necessary, additionally nickel, molybdenum, chromium, titanium, nitrogen, tin and vanadium are added in the prescribed composition.

Description

내연 기관용 실린더 라이너             Cylinder Liner for Internal Combustion Engines         

본 발명은 내연 기관, 특히 대형 디젤 엔진용 실린더 라이너(cylinder liner)에 관한 것이다.The present invention relates to a cylinder liner for an internal combustion engine, in particular a large diesel engine.

유럽 특허 출원 제0 525 540 A1호 명세서로부터 특히 대형 디젤 엔진용의 실린더 라이너가 공지되어 있으며, 이 실린더 라이너는 기저 합금으로서 퍼얼라이트계 주철(구상 흑연 주철: nodular graphite cast iron)로 주조되며, 주철의 조직은 3 내지 8%의 면적 분율을 차지하고 명확한 경계로 그물형으로 균일하게 분포된 시멘타이트/스티어타이트(cementite/steatite) 조직부를 가진다. 부가적으로, 기저 합금에는 0.01 내지 0.03 중량%의 붕소 및/또는 0.2 내지 0.4 중량%의 인 및 필요시 0.1 내지 0.3 중량%의 바나듐이 합금 원소로서 첨가된다.From the European Patent Application No. 0 525 540 A1 specification a cylinder liner is known, in particular for large diesel engines, which cylinder liner is used as a base alloy.                 Cast from cast iron cast iron (nodular graphite cast iron), the structure of cast iron occupies an area fraction of 3 to 8%                 It has a cementite / steatite tissue that is uniformly distributed in a net with clear boundaries. In addition, the base alloy                 0.01 to 0.03 wt% boron and / or 0.2 to 0.4 wt% phosphorus and, if necessary, 0.1 to 0.3 wt% vanadium as alloy elements                 Is added.

이러한 실린더 라이너는 매우 높은 강도와 매우 양호한 마모 특성 및 주행특성을 가진다. 이처럼 높은 강도는 현대의 고출력 디젤 엔진에서 균열의 방지를 위해 필수적이다.Such cylinder liners have very high strength and very good wear and running characteristics. This high strength prevents cracking in modern high power diesel engines.                 Is essential.

본 발명의 목적은 전술한 형식의 실린더 라이너에서 고온하의 내열성, 성형안정성, 내마모성과 같은 양호한 특성을 보다 우수하게 개선하는 것이다.It is an object of the present invention to further improve good properties such as heat resistance at high temperatures, molding stability and wear resistance in a cylinder liner of the type described above.

이러한 목적은 본 발명에 따라 청구 범위 제1항에 따른 합금 원소와 그 극한치(極限値)를 갖는 구상 흑연으로 이루어진 퍼얼라이트계 주철로 실린더 라이너를 주조함으로써 달성된다. 이 합금 조직은 3 내지 8%의 면적 분율을 차지하고 명확한 경계로 그물형으로 균일하게 분포된 시멘타이트/스티어타이트 조직부를 가진다.The object is to provide a cylinder liner with a ferrite-based cast iron made of an alloying element according to claim 1 and a spherical graphite having an extreme value thereof according to the present invention.                 By casting. This alloy structure accounts for an area fraction of 3 to 8% and is uniformly distributed in the shape of reticulated cementite / steerite structure.                 Have

이러한 조직의 특수성을 첨가 합금 원소에 의해 얻어진다. 즉 공지의 방식으로 Mg 또는 Mg와 Ce를 첨가함으로써 구상 흑연이 형성되며, 응고되는 용융물중에서 흑연 조직부 대신 시멘타이트/스티어타이트가 분리 석출되는 것과, 이 조직부가 공간적으로 명확한 경계를 지어 그물형으로 배열되는 것과, 그 면적 분율을 맞추는 것은 다음과 같은 조성의 퍼얼라이트계 주철에 소량의 붕소 및/또는 인 및 필요시 바나듐을 첨가함으로써 달성된다:The peculiarity of such a structure is obtained by the addition alloy element. That is, spheroidal graphite is formed by adding Mg or Mg and Ce in a known manner,                 Sedimentite / steerite is separated and precipitated instead of graphite tissue in the melt, and the tissue is arranged in a mesh with spatially clear boundaries;                 Matching the area fraction is achieved by adding a small amount of boron and / or phosphorus and, if necessary, vanadium to the ferritic cast iron of the composition:

탄소 2.8 내지 3.9 중량%,2.8 to 3.9 weight percent carbon,

규소 1.5 내지 3.0 중량%,Silicon 1.5-3.0 wt%,

망간 0.05 내지 1.0 중량%,Manganese 0.05-1.0 wt%,

황 0.02 중량% 미만,Less than 0.02% sulfur;

마그네슘 0.025 내지 0.07 중량%,Magnesium from 0.025 to 0.07% by weight,

구리 0.1 내지 2.0 중량%0.1 to 2.0 wt% copper

잔부는 기저 합금으로서 철, 특히, 첨가 합금 원소의 중량%의 비율은 다음과 같다:The balance is a base alloy of iron, in particular the proportion of the weight percent of the additive alloy element is as follows:

붕소 0.05 내지 0.03 중량% 및 필요시0.05 to 0.03 wt% boron and if necessary

인 0.01 내지 0.4 중량%,0.01 to 0.4 wt% phosphorus,

바나듐 0.05 내지 0.4 중량%.Vanadium 0.05 to 0.4 wt%.

이에 부가하여 하기의 분석 극한치를 가진 합금 원소를 추가하면, 미세 줄무늬형 퍼얼라이트의 생성, 페라이트 분율의 현저한 감소 및 특수한 탄화물/질화물의 생성에 의해 고온에서의 내열성, 성형 안정성, 높은 내마모성과 같은 보다 양호한 특성이 제공된다:In addition to this, the addition of alloying elements with the following analytical limit values leads to the production of fine stripe-type ferrites, a significant reduction in the ferrite fraction, and the special carbide / nitride                 The production provides better properties such as heat resistance at high temperatures, molding stability, high wear resistance:

니켈 0.01 내지 2.0 중량%,0.01 to 2.0 wt% nickel,

몰리브덴 0.1 내지 1.0 중량%,Molybdenum 0.1-1.0 wt%,

크롬 0.05 내지 0.5 중량%,0.05 to 0.5% by weight of chromium,

티타늄 0.01 내지 0.05 중량%,0.01-0.05% titanium,

질소 0.002 내지 0.014 중량%,0.002 to 0.014 weight percent of nitrogen,

주석 0.005 내지 0.1 중량%.0.005 to 0.1 weight percent tin.

흑연을 구상화함으로써 실린더 라이너 합금 조직의 인장 강도 및 충격 인성이 증진된다.By spheroidizing graphite, the tensile strength and impact toughness of the cylinder liner alloy structure are enhanced.

합금 조직중에 명확한 경계로 시멘타이트/스티어타이트 조직부가 특정한 공간 배열을 가짐으로써 층상 흑연을 가진 상응하는 합금 주철에서와 같이 실린더 표면이 현미경하에서 미세한 그물형 기복을 가지게 되며, 이러한 기복은 윤활유막의 양호한 부착을 보장해준다. 이에 의해, 실린더 라이너상에서 피스톤 링이 양호하게 주행하는 것을 보장한다.With a clear boundary in the alloy structure, the cementite / steerite structure has a specific spatial arrangement, thus allowing the cylinder surface to be reduced as in the corresponding alloy cast iron with layered graphite.                 It will have a fine mesh relief under the microscope, which ensures good adhesion of the lubricant film. Thereby, the piston ring on the cylinder liner                 To ensure good running.

붕소, 인, 바나듐 성분을 전술한 분석 극한치로 조절함으로써, 주조 부품에 대해 원하는 특성을 얻게 되며, 특정 용도에 따른 특정 특성으로 최적화할 수 있다. 예컨대, 인은 내마모성을 증가시키는 것은 물론 취성도 증가시키지만, 붕소, 인 또는 바나듐의 3가지 합금 원소에 의해 시멘타이트/스티어타이트 조직부의 최적의 그물형 분포가 제공된다. 붕소는 합금 조직에 최상의 내마모성을 제공하는 것은 물론 인과 마찬가지로 다소간 양호한 시멘타이트/스티어타이트 조직부의 분포를 제공하는 반면, 바나듐은 인장 간도와 내마모성을 지원하지만 시멘타이트/스티어타이트 조직부를 그물형으로 분포시키는 작용을 전혀 하지 않으므로 붕소 및/또는 인이 없다면 부가의 합금 요소로서 거의 효용이 없다.By adjusting the boron, phosphorus and vanadium components to the analytical extremes described above, the desired properties of the cast part can be obtained and optimized to specific properties for specific applications.                 have. For example, phosphorus not only increases abrasion resistance but also brittleness, but is cemented / stearite by three alloying elements of boron, phosphorus or vanadium.                 An optimal reticulated distribution of tissue is provided. Boron not only provides the best wear resistance to the alloy structure, but also somewhat good cementite / steerite like phosphorus.                 While providing a distribution of tissues, vanadium supports tensile elongation and wear resistance but does not act as a net distribution of cementite / steerite tissues.                 Thus, without boron and / or phosphorus, it is of little use as an additional alloying element.

따라서, 주조 과정중 인장 강도 및 내마모성에 관한 정해진 요건에 충족될 뿐만 아니라 동시에 충분한 윤활 작용에 필요한 표면 특성을 가지는 실린더 라이너가 제조되도록 계획하는 것이 상대적으로 유리하다.Thus, the cylinder not only meets the prescribed requirements for tensile strength and wear resistance during the casting process, but at the same time has the surface properties necessary for sufficient lubrication                 It is relatively advantageous to plan the liner to be manufactured.

Claims (2)

구상 흑연 및 이하의 분석 극한치(極限値): 탄소 2.8 내지 3.9 중량%, 규소 1.5 내지 3.0 중량%, 망간 0.05 내지 1.0 중량%, 황 0.02 중량% 미만, 마그네슘 0.025 내지 0.07 중량%, 구리 0.1 내지 2.0 중량%, 붕소 0.05 내지 0.03 중량% 또는 인 0.1 내지 0.4 중량%, 니켈 0.1 내지 2.0 중량%, 몰리브덴 0.1 내지 1.0 중량%, 크롬 0.05 내지 0.5 중량%, 티타늄 0.01 내지 0.05 중량%, 질소 0.002 내지 0.014 중량%, 주석 0.005 내지 0.1 중량%, 잔부는 철을 함유하는 퍼얼라이트계 주철로 제조된, 주철의 조직이 구상 퍼얼라이트 침전물에 3 내지 8%의 면적 분율을 차지하고 명확한 경계로 그물형으로 균일하게 분포된 시멘타이트/스티어타이트 조직부를 함유하는 것을 특징으로하는 내연 기판용 실린더 라이너.Spherical graphite and the following analysis limit values: 2.8 to 3.9 wt% carbon, 1.5 to 3.0 wt% silicon, 0.05 to 1.0 wt% manganese, sulfur                 Less than 0.02% by weight, 0.025% to 0.07% magnesium, 0.1% to 2.0% copper, 0.05% to 0.03% boron or 0.1% phosphorus                 To 0.4 wt%, nickel 0.1 to 2.0 wt%, molybdenum 0.1 to 1.0 wt%, chromium 0.05 to 0.5 wt%, titanium 0.01 to                 0.05 wt%, nitrogen 0.002 to 0.014 wt%, tin 0.005 to 0.1 wt%, the balance being made of ironite-based cast iron,                 The cast iron structure accounts for an area fraction of 3 to 8% in the spherical perlite precipitate and is uniformly distributed in a mesh with clear boundaries.                 A cylinder liner for an internal combustion substrate, comprising: 구상 흑연 및 이하의 분석 극한치(極限値): 탄소 2.8 내지 3.9 중량%, 규소 1.5 내지 3.0 중량%, 망간 0.05 내지 1.0 중량%, 황 0.02 중량% 미만, 마그네슘 0.025 내지 0.07 중량%, 구리 0.1 내지 2.0 중량%, 붕소 0.05 내지 0.03 중량% 또는 인 0.1 내지 0.4 중량%, 니켈 0.1 내지 2.0 중량%, 몰리브덴 0.1 내지 1.0 중량%, 크롬 0.05 내지 0.5 중량%, 티타늄 0.01 내지 0.05 중량%, 질소 0.002 내지 0.014 중량%, 주석 0.005 내지 0.1 중량%, 잔부는 철을 함유하는 퍼얼라이트계 주철로 제조되며, 상기 주철은 합금 원소로서 잔부의 철의 중량에 대해 0.05 내지 0.4 중량%의 바나듐을 가지고, 상기 주철의 조직이 구상 퍼얼라이트 침전물에 3 내지 8%의 면적 분율을 차지하고 명확한 경계로 그물형으로 균일하게 분포된 시멘타이트/스티어타이트 조직부를 함유하는 것을 특징으로 하는 내연 기판용 실린더 라이너.Spherical graphite and the following analysis limit values: 2.8 to 3.9 wt% carbon, 1.5 to 3.0 wt% silicon, 0.05 to 1.0 wt% manganese, sulfur                 Less than 0.02% by weight, 0.025% to 0.07% magnesium, 0.1% to 2.0% copper, 0.05% to 0.03% boron or 0.1% phosphorus                 To 0.4 wt%, nickel 0.1 to 2.0 wt%, molybdenum 0.1 to 1.0 wt%, chromium 0.05 to 0.5 wt%, titanium 0.01 to                 0.05% by weight, 0.002% to 0.014% by weight of nitrogen, 0.005% to 0.1% by weight of tin, the balance being made of ferritic cast iron containing iron,                 The cast iron has 0.05 to 0.4% by weight of vanadium with respect to the weight of the balance of iron as an alloying element, the structure of the cast iron is 3 to the spherical pearlite precipitate                 For internal combustion substrates comprising an area fraction of from 8% to 8% and containing cementite / steerite structure parts uniformly distributed in a mesh with clear boundaries                 Cylinder liner.
KR1019950017410A 1994-10-25 1995-06-26 Cylindrical hearing bushing for internal combustion engine KR0172144B1 (en)

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DE4438073A DE4438073A1 (en) 1994-10-25 1994-10-25 Cylinder liner for combustion machines, esp. large diesel engines
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FR2726035A1 (en) 1996-04-26
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DE4438073A1 (en) 1996-05-02
CN1043669C (en) 1999-06-16

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