KR0151291B1 - Phosphor forming method of color braun tube - Google Patents

Phosphor forming method of color braun tube

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Publication number
KR0151291B1
KR0151291B1 KR1019950005636A KR19950005636A KR0151291B1 KR 0151291 B1 KR0151291 B1 KR 0151291B1 KR 1019950005636 A KR1019950005636 A KR 1019950005636A KR 19950005636 A KR19950005636 A KR 19950005636A KR 0151291 B1 KR0151291 B1 KR 0151291B1
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South Korea
Prior art keywords
color
film
pigment
forming
phosphor
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KR1019950005636A
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Korean (ko)
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KR960035712A (en
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김대황
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구자홍
엘지전자주식회사
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Priority to KR1019950005636A priority Critical patent/KR0151291B1/en
Publication of KR960035712A publication Critical patent/KR960035712A/en
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Publication of KR0151291B1 publication Critical patent/KR0151291B1/en

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J9/00Apparatus or processes specially adapted for the manufacture, installation, removal, maintenance of electric discharge tubes, discharge lamps, or parts thereof; Recovery of material from discharge tubes or lamps
    • H01J9/20Manufacture of screens on or from which an image or pattern is formed, picked up, converted or stored; Applying coatings to the vessel
    • H01J9/22Applying luminescent coatings
    • H01J9/227Applying luminescent coatings with luminescent material discontinuously arranged, e.g. in dots or lines

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  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Formation Of Various Coating Films On Cathode Ray Tubes And Lamps (AREA)
  • Cathode-Ray Tubes And Fluorescent Screens For Display (AREA)

Abstract

본 발명은 칼라 브라운관의 형광면 형성방법에 관한 것으로, 특히 R, G, B 안료필터층 아래에 안료잔사 방지막을 사용하여 상기 R, G, B 안료입자가 타색위치에 남지 못하게하여 칼라 브라운관의 콘트라스트 및 휘도를 향상시키는데 적당하도록 한 칼라 브라운관의 형광면 형성방법에 관한 것이다.The present invention relates to a method for forming a fluorescent surface of a color CRT, in particular, by using a pigment residue prevention layer under the R, G, B pigment filter layer to prevent the R, G, B pigment particles from remaining in the other color position, and thus the contrast and luminance of the CRT. The present invention relates to a method for forming a fluorescent surface of a color CRT that is suitable for improving the efficiency of the CRT.

본 발명의 상기 목적을 달성하기 위한 칼라브라운관의 형광면 형성방법은 패널내면에 형광면을 포함하는 칼라음극선관에 있어서, 상기 패널상에 블랙 매트릭스를 형성하는 제1공정과, 상기 패널전면에 제1프리코트막과 제1색안료막을 차례로 도포하고 제1칼라화소영역에만 남도록 제1프리코트막 및 제1색안료막을 패터닝하는 제2공정과, 상기 전면에 제2프리코트막과 제2색안료막을 차례로 도포하고 제2칼라화소영역에만 남도록 제2프리코트막 및 제2색안료막을 패터닝하는 제3공정과, 상기 전면에 제3프리코트막과 제3색안료막을 차례로 도포하고 제3칼라화소영역에만 남도록 제3프리코트막 및 제3색안료막을 패터닝하는 제4공정과, 상기 제1칼라화소영역에 제1형광체막을 형성하는 제5공정과, 상기 제2칼라화소영역에 제2형광체막을 형성하는 제6공정과, 상기 제3칼라화소영역에 제3형광체막을 형성하는 제7공정을 포함하여 이루어짐을 특징으로 한다.In order to achieve the above object of the present invention, a fluorescent surface forming method of a color brown tube includes a first step of forming a black matrix on the panel in a color cathode ray tube including a fluorescent surface on an inner surface of the panel, and a first free surface on the front surface of the panel. A second step of coating the coating film and the first color pigment film in sequence and patterning the first precoat film and the first color pigment film so as to remain only in the first color pixel region; and a second precoat film and a second color pigment film on the entire surface. A third step of patterning the second precoat film and the second color pigment film so as to be applied in sequence and remaining only in the second color pixel area, and then applying a third precoat film and a third color pigment film on the entire surface, and then applying a third color pixel area. A fourth process of patterning a third precoat film and a third color pigment film so as to remain only, a fifth process of forming a first phosphor film in the first color pixel region, and a second phosphor film in the second color pixel region 6th process Characterized the yirueojim including a seventh step of forming the first film a third color phosphor in the third pixel region.

Description

칼라브라운관의 형광면 형성방법How to Form Fluorescent Surface of Color Brown Tube

제1도는 종래의 칼라 브라운관의 형광면 구조도.1 is a fluorescent surface structure diagram of a conventional color CRT.

제2도는 종래의 안료부착 형광표면을 도시한 도면대용사진.2 is a drawing substitute photograph showing a conventional fluorescent surface with pigments.

제3도는 본 발명의 칼라 브라운관의 형광면 공정단면도.Figure 3 is a cross-sectional view of the fluorescent surface process of the color CRT of the present invention.

제4도는 종래와 본 발명에 따른 칼라 브라운관의 형광면 휘도 특성비교도.Figure 4 is a comparison of the fluorescent surface luminance characteristics of the color CRT according to the prior art and the present invention.

제5도는 종래와 본 발명에 따른 칼라 브라운관의 형광면 휘도 콘트라스트 특성 비교도.5 is a comparison of fluorescent surface luminance contrast characteristics of color CRT tubes according to the prior art and the present invention.

* 도면의 주요부분에 대한 부호의 설명* Explanation of symbols for main parts of the drawings

31 : 패널면 32 : 블랙 매트릭스31: panel surface 32: black matrix

33R,33G,33B : 제1,제2,제3프리코트막33R, 33G, 33B: 1st, 2nd, 3rd precoat film

34R,34G,34B : 제1,제2,제3안료박막34R, 34G, 34B: 1st, 2nd, 3rd pigment thin film

35 : 새도우 마스크 36R,36G,36B : 제1,제2,제3형광체막35: shadow mask 36R, 36G, 36B: first, second, third phosphor film

본 발명은 칼라 브라운관의 형광면 형성방법에 관한 것으로, 특히 R, G, B 안료 필터층 아래에 안료잔사 방지막을 사용하여 상기 R, G, B 안료입자가 타색위치에 남지 못하게하여 칼라 브라운관의 콘트라스트 및 휘도를 향상시키는데 적당하도록 한 칼라 브라운관의 형광면 형성방벙법에 관한 것이다.The present invention relates to a method for forming a fluorescent surface of a color CRT, in particular, by using a pigment residue prevention layer under the R, G, B pigment filter layer so that the R, G, B pigment particles do not remain in the other color position, and thus the contrast and luminance of the CRT. It relates to a method for forming a fluorescent surface of a color CRT tube to be suitable for improving the efficiency.

제1도는 종래의 칼라 브라운관의 형광면 구조를 나타낸 도면으로써, 블랙 매트릭스(2)가 형성된 패널(1)의 각 칼라 화소영역에 해당 R, G, B 3색 형광체막을 형성시킨다.FIG. 1 is a diagram showing a fluorescent surface structure of a conventional color CRT, in which corresponding R, G, and B three-color phosphor films are formed in each color pixel region of the panel 1 on which the black matrix 2 is formed.

이때, 상기 R, G, B 3색 형광체중에서, 소정의 형광체를 폴리비닐알코올-중크롬산, 나트륨계 감광제 및 기타 첨가약품으로 구성된 슬러리를 상기 패널에 도포하고 새도우 마스크(5)를 이용하여 노광한 뒤 소정의 원하는 형광체막을 얻는다. 상기 공정을 반복하여 R, G, B 3색의 형광체막을 형성한다. 여기서, 상기 3색 형광체중에서 R, B 형광체는 콘트라스트 향상을 위해서 제2도에 나타낸 바와 같이 안료가 부착된 형광체막을 사용한다.At this time, in the R, G, B tri-color phosphor, a predetermined phosphor is applied to the panel a slurry composed of polyvinyl alcohol-dichromic acid, sodium photosensitizer and other additives and exposed using a shadow mask (5). A desired desired phosphor film is obtained. The above process is repeated to form phosphor films of three colors R, G and B. In the above three-color phosphors, R and B phosphors use a phosphor film with a pigment as shown in FIG. 2 to improve contrast.

이와같이 제조된 종래의 칼라 브라운관의 형광면에 있어서는 형광체(6R, 6B)표면에 안료입자(4R, 4B)들이 부착된 안료부착 형광체를 패널의 각 칼라화소영역에 형성하므로써, 패널을 통과한 외부 입사광이 형광체 입자표면에 부착된 안료에 의해 흡수되므로 콘트라스트가 향상된다. 그러나 이와같은 종래의 칼라 브라운관의 형광면 형성방법에 있어서는 다음과 같은 문제점이 있었다.In the fluorescent surface of the conventional color CRT manufactured as described above, by forming a pigmented phosphor having pigment particles 4R and 4B attached to surfaces of phosphors 6R and 6B in each color pixel area of the panel, external incident light passing through the panel It is absorbed by the pigment attached to the surface of the phosphor particles, so that the contrast is improved. However, in the conventional fluorescent film forming method of the color CRT, there are the following problems.

첫째, 안료부착 형광체를 해당 화소영역에 도포하여 형광면을 형성하므로 형광체 고유의 발광세기를 감소시켜 휘도를 저하시킨다. 즉, 해당 화소영역에 형성되는 형광체 표면에 안료가 부착된 형광체 입자가 보통 3∼4개 정도로 중첩되어 형성되므로, 형광체 고유의 발광세기가 감소되고, 더불어 칼라 음극선관의 휘도가 저하된다.First, since a fluorescent substance with a pigment is applied to a corresponding pixel region to form a fluorescent surface, the luminance inherent in the phosphor is reduced to lower luminance. That is, since the phosphor particles with pigments are usually overlapped with each other on the surface of the phosphor formed in the pixel region, about 3 to 4 particles are formed, the emission intensity inherent in the phosphor is reduced, and the luminance of the color cathode ray tube is also reduced.

둘째, 형광체 입자 표면에 안료부착시 안료를 균일하게 부착하기가 어렵고, 안료간의 응집에 의하여 안료가 외부 입사광을 미약하게 흡수하므로 본래 목적하고자 하는 콘트라스트 향상을 실현하기 어렵다. 본 발명은 상기 상술한 문제점을 해결하기 위해 안출된 것으로, 프리코트막을 형성하여 R, G, B 안료입자가 타색위치에 남지못하게 함으로써 칼라 브라운관의 콘트라스트 및 휘도를 향상시키는데 그 목적이 있다.Second, when the pigment is attached to the surface of the phosphor particles, it is difficult to uniformly attach the pigment, and since the pigment slightly absorbs external incident light by aggregation between the pigments, it is difficult to realize the intended contrast enhancement. SUMMARY OF THE INVENTION The present invention has been made to solve the above-mentioned problems, and an object thereof is to improve the contrast and brightness of color CRTs by forming a precoat film so that R, G and B pigment particles do not remain in other color positions.

이와같은 목적을 달성하기 위한 본 발명의 칼라 브라운관 형광면 형성방법은 패널내면에 형광면을 포함하는 칼라음극선관에 있어서, 상기 패널상에 블랙 매트릭스를 형성하는 제1공정과, 상기 패널 전면에 제1프리코트막과 제1색 안료막을 차례로 도포하고 제1칼라 화소영역에만 남도록 제1프리코트막 및 제1색안료막을 패터닝하는 제2공정과, 상기 전면에 제2프리코트막과 제2색안료막을 차례로 도포하고 제2칼라화소영역에만 남도록 제2프리코트막 및 제2색안료막을 패터닝하는 제3공정과, 상기 전면에 제3프리코트막과 제3색안료막을 차례로 도포하고 제3칼라화소영역에만 남도록 제3프리코트막 및 제3색안료막을 패터닝하는 제4공정과, 상기 제1칼라화소영역에 제1형광체막을 형성하는 제5공정과, 상기 제2칼라화소영역에 제2형광체막을 형성하는 제6공정과, 상기 제3칼라화소영역에 제3형광체막을 형성하는 제7공정을 포함하여 이루어짐을 그 특징으로 한다.The color CRT fluorescent surface forming method of the present invention for achieving the above object comprises a first step of forming a black matrix on the panel in a color cathode ray tube including a fluorescent surface on an inner surface of the panel, and a first free surface on the front surface of the panel; A second step of coating the coating film and the first color pigment film sequentially and patterning the first precoat film and the first color pigment film so as to remain only in the first color pixel region; and a second precoat film and a second color pigment film on the entire surface. A third step of patterning the second precoat film and the second color pigment film so as to be applied in sequence and remaining only in the second color pixel area, and then applying a third precoat film and a third color pigment film on the entire surface, and then applying a third color pixel area. A fourth process of patterning a third precoat film and a third color pigment film so as to remain only, a fifth process of forming a first phosphor film in the first color pixel region, and a second phosphor film in the second color pixel region The sixth to say And a seventh step of forming a third phosphor film in the third color pixel region.

상기와 같은 본 발명의 칼라 브라운관 형광면 형성방법은 첨부된 도면을 참조하여 보다 상세히 설명하면 다음과 같다.Color fluorescent tube fluorescent surface forming method of the present invention as described above will be described in more detail with reference to the accompanying drawings.

제3도는 본 발명의 칼라 브라운관 형광면 공정단면도로써, 제3도 (a)에서와 같이 패널상에 블랙 매트릭스(32)를 형성한 후 제3도 (b)에서와 같이 상기 전면에 제1프리코트액(33R)을 도포한다. 이때, 상기 제1프리코트액(33R)은 폴리스틸렌 라텍스 및 naphthalene sulfornic acid와 formalin의 중합물을 주성분으로 하며, 역할은 미립자인 안료의 입자들이 원하는 소정의 위치가 아닌 다른 위치에 접착하여 남는 것을 방지하기 위해 사용한다. 이어서, 제3도 (c)에서와 같이 상기 제1프리코트막(33R)위에 제1색안료층(34R)을 형성시키고, 상기 제1안료층(34R)위에 새도우 마스크(35)를 끼워서 노광 및 현상한다. 이때, 현상시, 상기 노광된 부분은 광경화반응에 의해, 상기 노광된 안료층과 상기 노광된 안료층 아래에 있는 제1프리코트막만 남고, 노광되지 않은 부분은 모두 제거되어 제3도 (d)에서와 같이 제1프리코트막(33R)과 제1색안료박막(34R)을 제1화소칼라영역에만 남도록 패터닝된다. 여기서, 안료현탁액은 폴리비닐 알코올-중크롬산나트륨계 감광액으로 분산된 현탁액으로 구성되어 있다.FIG. 3 is a cross-sectional view of a color CRT fluorescent surface of the present invention, in which a black matrix 32 is formed on a panel as shown in FIG. 3 (a), followed by a first precoat on the front surface as shown in FIG. The liquid 33R is applied. At this time, the first precoat liquid 33R is mainly composed of a polymer of polystyrene latex, naphthalene sulfornic acid and formalin, and serves to prevent the particles of pigments, which are fine particles, from adhering to a position other than a desired predetermined position. To use. Subsequently, as shown in FIG. 3 (c), a first color pigment layer 34R is formed on the first precoat layer 33R, and a shadow mask 35 is sandwiched and exposed on the first pigment layer 34R. And develop. At this time, during the development, the exposed portion is left by the photocuring reaction, leaving only the first precoat layer under the exposed pigment layer and the exposed pigment layer, and all of the unexposed portions are removed to remove the portion of FIG. As in d), the first precoat film 33R and the first color pigment thin film 34R are patterned so as to remain only in the first pixel color region. Here, the pigment suspension is composed of a suspension dispersed in a polyvinyl alcohol-sodium dichromate photosensitive liquid.

이어서, 제3도 (e)에서와 같이 상기 전면에 제2프리코트액(33G)을 전면에 도포하고, 상기 제2프리코트막(33G)위에 제2색안료층(34G)을 형성시킨다. 상기 제2안료층(34G)위에 새도우 마스크(35)를 끼워서 노광 및 현상한다. 상기 노광된 제2색안료층과 상기 노광된 안료층 아래에 있는 제2프리코트막이 제2화소칼라영역에만 남도록 제3도 (f)에서와 같이 패터닝된다.Subsequently, as shown in FIG. 3E, the second precoat liquid 33G is applied to the entire surface, and the second color pigment layer 34G is formed on the second precoat film 33G. A shadow mask 35 is sandwiched on the second pigment layer 34G to expose and develop. The exposed second color pigment layer and the second precoat film under the exposed pigment layer are patterned as in FIG. 3 (f) so that only the second pixel color region remains.

이어서 제3도 (g)에서와 같이 상기 전면에 제3프리코트액(33B)을 전면에 도포하고, 상기 제3프리코트막(33B)위에 제3색안료층(34B)을 형성시킨다. 상기 제3안료층(34G)위에 새도우 마스크(35)를 끼워서 노광 및 현상하여 노광된 제3색안료층과 상기 노광된 안료층 아래에 있는 제3프리코트막이 제3화소칼라영역에만 남도록 패터닝된다.Subsequently, a third precoat liquid 33B is applied to the entire surface as shown in FIG. 3 (g), and a third color pigment layer 34B is formed on the third precoat film 33B. The third color pigment layer exposed by inserting and shadowing the shadow mask 35 on the third pigment layer 34G and the third precoat layer under the exposed pigment layer are patterned so as to remain only in the third pixel color region. .

그 다음 제3도 (i)에서와 같이 상기 전면에 제1색형광체를 도포하고, 상기 제1색형광체위에 새도우 마스크를 끼워서 노광 및 현상하여 제1색 형광체막(36R)을 제1색안료박막(34R)위에 형성함으로써 제1화소칼라영역이 형성된다.Then, as shown in FIG. 3 (i), a first color phosphor is coated on the entire surface, and a shadow mask is placed on the first color phosphor to expose and develop the first color phosphor film 36R. The first pixel color region is formed by forming over 34R.

이어서, 상기 전면에 제2색 형광체를 도포하고, 상기 제2색형광체위에 새도우 마스크를 끼워서 노광 및 현상하여 제2색형광체막(36G)을 제2색안료박막(34G)위에 형성함으로써 제2화소칼라영역이 형성된다.Subsequently, a second color phosphor is coated on the entire surface, and a shadow mask is placed on the second color phosphor to expose and develop a second color phosphor film 36G on the second color pigment thin film 34G. A collar region is formed.

상기 전면에 제3색형광체를 도포하고, 상기 제3색형광체 위에 새도우 마스크를 끼워서 노광 및 현상하여 제3색형광체막(36B)을 제3색안료박막(34B)위에 형성함으로써 제3화소칼라영역이 형성된다.A third color phosphor is coated on the entire surface, and a third mask is formed on the third color pigment film 34B by exposing and developing a shadow mask on the third color phosphor to form the third color phosphor film 36B on the third color pigment film 34B. Is formed.

상기에서와 같이 형성된 본 발명의 칼라 브라운관의 형광면 형성방법에 있어서는 다음과 같은 효과가 있다.The fluorescent surface forming method of the color CRT tube of the present invention formed as described above has the following effects.

제4도는 종래와 본 발명에 의한 형광면의 휘도특성 비교도이고, 제5도는 종래와 본 발명에 의한 콘트라스트 특성 비교도로써, 프리코트막과 안료박막을 패널내면과 형광체막 사이에 차례로 형성하여 안료부착 형광체를 사용한 형광체막으로 형성된 종래의 칼라 음극선보다 제4도 및 제5도에서와 같이 휘도와 콘트라스트가 향상된다.4 is a comparison of luminance characteristics of the fluorescent surface according to the conventional art and the present invention, and FIG. 5 is a comparison of the contrast characteristic according to the conventional art and the present invention. The luminance and contrast are improved as in Figs.

Claims (1)

패널내면에 형광면을 포함하는 칼라음극선관에 있어서, 상기 패널상에 블랙 매트릭스를 형성하는 제1공정과, 상기 패널전면에 제1프리코트막과 제1색안료막을 차례로 도포하고 제1칼라화소 영역에만 남도록 제1프리코트막 및 제1색안료막을 패터닝하는 제2공정과, 상기 전면에 제2프리코트막과 제2색안료막을 차례로 도포하고 제2칼라 화소영역에만 남도록 제2프리코트막 및 제2색안료막을 패터닝하는 제3공정과, 상기 전면에 제3프리코트막과 제3색안료막을 차례로 도포하고 제3칼라화소영역에만 남도록 제3프리코트막 및 제3색안료막을 패터닝하는 제4공정과, 상기 제1칼라화소영역에 제1형광체막을 형성하는 제5공정과, 상기 제2칼라화소영역에 제2형광체막을 형성하는 제6공정과, 상기 제3칼라화소영역에 제3형광체막을 형성하는 제7공정을 포함하여 이루어짐을 특징으로 하는 칼라 브라운관의 형광면 형성방법.In a color cathode ray tube including a fluorescent surface on an inner surface of a panel, a first process of forming a black matrix on the panel, and a first precoat film and a first color pigment film are sequentially applied on the front surface of the panel, and then the first color pixel region. And a second step of patterning the first precoat film and the first color pigment film so as to remain only, the second precoat film and the second color pigment film are sequentially applied to the entire surface, and the second precoat film is left only in the second color pixel region. A third step of patterning the second color pigment film, and a third precoat film and a third color pigment film are sequentially applied to the entire surface, and the third precoat film and the third color pigment film are patterned so as to remain only in the third color pixel region. A fourth step of forming a first phosphor film in the first color pixel region, a sixth step of forming a second phosphor film in the second color pixel region, and a third phosphor in the third color pixel region Including the seventh step of forming a film Method for forming a fluorescent surface of a color CRT, characterized in that made.
KR1019950005636A 1995-03-17 1995-03-17 Phosphor forming method of color braun tube KR0151291B1 (en)

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