JPWO2021198843A5 - - Google Patents
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- JPWO2021198843A5 JPWO2021198843A5 JP2022559537A JP2022559537A JPWO2021198843A5 JP WO2021198843 A5 JPWO2021198843 A5 JP WO2021198843A5 JP 2022559537 A JP2022559537 A JP 2022559537A JP 2022559537 A JP2022559537 A JP 2022559537A JP WO2021198843 A5 JPWO2021198843 A5 JP WO2021198843A5
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- 239000000758 substrate Substances 0.000 claims 54
- 239000002001 electrolyte material Substances 0.000 claims 25
- 238000002844 melting Methods 0.000 claims 15
- 239000011521 glass Substances 0.000 claims 14
- 229910010293 ceramic material Inorganic materials 0.000 claims 13
- 239000003792 electrolyte Substances 0.000 claims 11
- 239000011888 foil Substances 0.000 claims 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims 8
- 239000012777 electrically insulating material Substances 0.000 claims 6
- 239000008393 encapsulating agent Substances 0.000 claims 6
- 230000008018 melting Effects 0.000 claims 6
- 239000003566 sealing material Substances 0.000 claims 6
- 239000000463 material Substances 0.000 claims 5
- 239000002245 particle Substances 0.000 claims 5
- GUHKMHMGKKRFDT-UHFFFAOYSA-N 1785-64-4 Chemical compound C1CC(=C(F)C=2F)C(F)=C(F)C=2CCC2=C(F)C(F)=C1C(F)=C2F GUHKMHMGKKRFDT-UHFFFAOYSA-N 0.000 claims 4
- 239000004952 Polyamide Substances 0.000 claims 4
- 239000004642 Polyimide Substances 0.000 claims 4
- 238000000231 atomic layer deposition Methods 0.000 claims 4
- 239000003822 epoxy resin Substances 0.000 claims 4
- 238000004519 manufacturing process Methods 0.000 claims 4
- 238000000034 method Methods 0.000 claims 4
- 239000000203 mixture Substances 0.000 claims 4
- 229920000052 poly(p-xylylene) Polymers 0.000 claims 4
- 229920002647 polyamide Polymers 0.000 claims 4
- 229920000647 polyepoxide Polymers 0.000 claims 4
- 229920001721 polyimide Polymers 0.000 claims 4
- 229920001296 polysiloxane Polymers 0.000 claims 4
- 239000000377 silicon dioxide Substances 0.000 claims 4
- 230000005540 biological transmission Effects 0.000 claims 3
- 238000005520 cutting process Methods 0.000 claims 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 3
- 238000000151 deposition Methods 0.000 claims 2
- 229910052751 metal Inorganic materials 0.000 claims 2
- 239000002184 metal Substances 0.000 claims 2
- 239000002952 polymeric resin Substances 0.000 claims 2
- 239000000565 sealant Substances 0.000 claims 2
- 229920003002 synthetic resin Polymers 0.000 claims 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 1
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 claims 1
- 239000000853 adhesive Substances 0.000 claims 1
- 230000001070 adhesive effect Effects 0.000 claims 1
- 229910002804 graphite Inorganic materials 0.000 claims 1
- 239000010439 graphite Substances 0.000 claims 1
- 239000002608 ionic liquid Substances 0.000 claims 1
- 238000000608 laser ablation Methods 0.000 claims 1
- 239000011244 liquid electrolyte Substances 0.000 claims 1
- 229910001416 lithium ion Inorganic materials 0.000 claims 1
- 229910003002 lithium salt Inorganic materials 0.000 claims 1
- 159000000002 lithium salts Chemical class 0.000 claims 1
Claims (26)
各単位セル（１００）は、陽極集電基板（１０）、陽極層（２０）、少なくとも１つの電解質材料層（３０）および／または電解質を含浸している少なくとも１つのセパレータ層（３１）、陰極層（５０）および陰極集電基板（４０）を連続的に含み、
前記電池が複数の単位セル（１００、１００’、１００’’）を含む場合、前記単位セル（１００、１００’、１００’’）の１つが他の下に配置され、すなわち前記電池の主面に対する正面方向（ＺＺ）に従って重ね合わされ、
ｏ前記陽極集電基板（１０）は、２つの隣接する単位セル（１００、１００’、１００’’）の陽極集電基板（１０）であり、かつ、
ｏ前記陰極集電基板（４０）は、２つの隣接する単位セル（１００、１００’、１００’’）の陰極集電基板（４０）であるように配置され、
前記少なくとも１つの単位セルまたは前記単位セル（１００、１００’、１００’’）は、スタック（Ｉ）を画定し、
前記スタック（Ｉ）および前記電池は、６つの面、すなわち、
－互いに対向する、特に互いに平行な２つのいわゆる端面（Ｆ１、Ｆ２）であって、前記１つまたは複数の陽極集電基板（１０）、前記１つまたは複数の陽極層（２０）、前記１つもしくは複数の電解質材料層（３０）または電解質を含浸している前記１つもしくは複数のセパレータ層（３１）、前記１つまたは複数の陰極層（５０）、および前記１つまたは複数の陰極集電基板（４０）に概して平行な２つの端面（Ｆ１、Ｆ２）と、
－互いに対向する、特に互いに平行な２つのいわゆる横方向面（Ｆ３、Ｆ５）と、
－互いに対向する、特に互いに平行な２つのいわゆる縦方向面（Ｆ４、Ｆ６）とを有し、
前記電池の第１の縦方向面（Ｆ６）が少なくとも１つの陽極接続ゾーン（１００２）を含み、前記電池の第２の縦方向面（Ｆ４）が少なくとも１つの陰極接続ゾーン（１００６）を含み、前記陽極接続ゾーン（１００２）と陰極接続ゾーン（１００６）とが横方向に互いに対向しており、
－前記電池の第１の縦方向（ＸＸ’）において、各陽極層（２０）、各電解質材料層（３０）または電解質を含浸している各セパレータ層（３１）、各陰極層（５０）および各陰極集電基板層（４０）から各陽極集電基板（１０）が突出し、かつ、
－前記第１の縦方向（ＸＸ’）とは反対の、前記電池の第２の縦方向（ＸＸ’’）において、各陽極層（２０）、各電解質材料層（３０）または電解質を含浸している各セパレータ層（３１）、各陰極層（５０）および各陽極集電基板層（１０）から各陰極集電基板（４０）が突出していることを特徴とする、電池。 A battery (1000) including at least one unit cell (100),
Each unit cell (100) successively comprises an anode current collecting substrate (10), an anode layer (20), at least one electrolyte material layer (30) and/or at least one separator layer (31) impregnated with an electrolyte, a cathode layer (50) and a cathode current collecting substrate (40);
When the battery includes a plurality of unit cells (100, 100', 100''), the unit cells (100, 100', 100'') are arranged one below the other, i.e., stacked according to a front direction (ZZ) with respect to a main surface of the battery ;
o the anode current collecting substrate (10) is the anode current collecting substrate (10) of two adjacent unit cells (100, 100', 100''); and
o said cathode current collecting substrates (40) are arranged such that they are the cathode current collecting substrates (40) of two adjacent unit cells (100, 100', 100'');
The or said at least one unit cell (100, 100', 100'') defines a stack (I),
The stack (I) and the cell have six faces, namely:
- two mutually opposing, in particular mutually parallel, so-called end faces (F1, F2) which are generally parallel to the one or more anode current collecting substrates (10), the one or more anode layers (20), the one or more electrolyte material layers (30) or the one or more separator layers (31) impregnated with an electrolyte, the one or more cathode layers (50) and the one or more cathode current collecting substrates (40);
- two so-called lateral faces (F3, F5) which are opposite each other, in particular parallel to each other,
- has two so-called longitudinal faces (F4, F6) which are opposite each other, in particular parallel to each other,
a first longitudinal face (F6) of the cell comprises at least one anode connection zone (1002) and a second longitudinal face (F4) of the cell comprises at least one cathode connection zone (1006), the anode connection zone (1002) and the cathode connection zone (1006) being laterally opposite each other,
in a first longitudinal direction (XX') of the battery, each anode current collecting substrate (10) protrudes from each anode layer (20), each electrolyte material layer (30) or each separator layer (31) impregnated with an electrolyte, each cathode layer (50) and each cathode current collecting substrate layer (40); and
a battery, characterized in that in a second longitudinal direction (XX'') of the battery, opposite to said first longitudinal direction (XX'), each cathode current collecting substrate (40) protrudes from each anode layer (20), each electrolyte material layer (30) or each separator layer (31) impregnated with an electrolyte, each cathode layer (50) and each anode current collecting substrate layer (10).
－前記電池の第１の縦方向（ＸＸ’）において、各陽極層（２０）、各電解質材料層（３０）または各セパレータ層（３１）、各陰極層（５０）および各陰極集電基板層（４０）から突出している各陽極集電基板（１０）の各陽極端（１００２’）のみが第１の縦方向面（Ｆ６）と同一平面上にあり、かつ、
－前記電池の第２の縦方向（ＸＸ’’）において、各陽極層（２０）、各電解質材料層（３０）または各セパレータ層（３１）、各陰極層（５０）および各陽極集電基板層（２０）から突出している各陰極集電基板（４０）の各陰極端（１００６’）のみが第２の縦方向面（Ｆ４）と同一平面上にあり、前記第２の縦方向面（Ｆ４）が前記第１の縦方向面（Ｆ６）と対向かつ平行しており、
各陽極端（１００２’）が陽極接続ゾーン（１００２）を画定し、各陰極端（１００６’）が陰極接続ゾーン（１００６）を画定していることを特徴とする、請求項４に記載の電池。 the sealing material (95) covers at least a portion of the end faces (F1, F2), the lateral faces (F3, F5) and the longitudinal faces (F4, F6) of the stack;
In the first longitudinal direction (XX') of the battery, only the anode ends (1002') of each anode current collecting substrate (10) protruding from each anode layer (20), each electrolyte material layer (30) or each separator layer (31), each cathode layer (50) and each cathode current collecting substrate layer (40) are flush with the first longitudinal surface (F6); and
in a second longitudinal direction (XX'') of the battery, only each anode layer (20), each electrolyte material layer (30) or each separator layer (31), each cathode layer (50) and each cathode end (1006') of each cathode current collecting substrate (40) protruding from each anode current collecting substrate layer (20) are flush with a second longitudinal surface (F4), and said second longitudinal surface (F4) is opposite and parallel to said first longitudinal surface (F6);
5. The battery of claim 4 , wherein each anode end (1002') defines an anode connection zone (1002) and each cathode end (1006') defines a cathode connection zone (1006).
セラミック材料および／または低融点ガラスから成る、少なくとも１つの不浸透性カバー層を含む、
または、
－パリレン、パリレンＦ、ポリイミド、エポキシ樹脂、シリコン、ポリアミド、ゾルゲルシリカ、有機シリカおよび／またはそれらの混合物の中から選択され、前記スタック（Ｉ）の外周部の少なくとも一部上に堆積されているカバー層と、
－セラミック材料および／または低融点ガラスから成る、前記第１のカバー層上に堆積されている少なくとも１つの不浸透性カバー層と、を含む、
または、
－前記スタック（Ｉ）の外周部の少なくとも一部上に原子層堆積法により堆積されている、電気的絶縁材料からなるカバー層と、
－セラミック材料および／または低融点ガラスから成る、前記スタック（Ｉ）の外周部の少なくとも一部上に堆積されている少なくとも１つの不浸透性カバー層と、を含み、
電気的絶縁材料からなる前記カバー層が存在する場合に、
－前記カバー層と前記不浸透性カバー層との連続をｚ回繰り返し、ここでｚ≧１であり、少なくとも前記不浸透性カバー層の外周部上に堆積させることができ、かつ、
－前記封止材の最後の層が、不浸透性カバー層であり、セラミック材料および／または低融点ガラスから成る、
または、
－パリレン、パリレンＦ、ポリイミド、エポキシ樹脂、シリコン、ポリアミド、ゾルゲルシリカ、有機シリカおよび／またはそれらの混合物の中から選択され、前記スタック（Ｉ）の外周部の少なくとも一部上に堆積されている第１のカバー層と、
－前記スタック（Ｉ）の外周部の少なくとも一部上または前記第１のカバー層上に原子層堆積法により堆積されている、電気的絶縁材料からなる第２のカバー層と、
－セラミック材料および／または低融点ガラスから成り、前記スタック（Ｉ）の外周部の少なくとも一部上または前記第１のカバー層上に堆積されている少なくとも１つの第３の不浸透性カバー層と、を含み、
前記第２のカバー層が存在する場合に、
－前記第２のカバー層と前記第３のカバー層との連続をｚ回繰り返し、ここでｚ≧１であり、少なくとも前記第３のカバー層の外周部上に堆積させることができ、
－前記封止材の最後の層が、不浸透性カバー層であり、セラミック材料および／または低融点ガラスから成る、ことを特徴とする、請求項４に記載の電池。 The sealing material (95) is
at least one impermeable cover layer made of a ceramic material and/or a low melting glass;
or
a cover layer selected from among parylene, parylene F, polyimide, epoxy resin, silicone, polyamide, sol-gel silica, organosilica and/or mixtures thereof, deposited on at least a portion of the periphery of said stack (I);
at least one impermeable cover layer, deposited on said first cover layer, made of a ceramic material and/or a low-melting glass,
or
a cover layer made of an electrically insulating material deposited by atomic layer deposition on at least a portion of the periphery of said stack (I);
at least one impermeable cover layer, deposited on at least a portion of the periphery of said stack (I), consisting of a ceramic material and/or a low-melting glass,
When the cover layer of electrically insulating material is present,
- the sequence of said cover layer and said impermeable cover layer is repeated z times, where z≧1, and can be deposited at least on the outer periphery of said impermeable cover layer; and
the last layer of the sealant is an impermeable cover layer and consists of a ceramic material and/or a low-melting glass;
or
a first cover layer selected from among parylene , parylene F, polyimide, epoxy resin, silicone, polyamide, sol-gel silica, organosilica and/or mixtures thereof, deposited on at least a portion of the periphery of said stack (I);
a second cover layer made of an electrically insulating material, deposited by atomic layer deposition on at least a portion of the periphery of said stack (I) or on said first cover layer,
at least one third impermeable cover layer, made of a ceramic material and/or a low-melting glass , deposited on at least a portion of the periphery of said stack (I) or on said first cover layer,
When the second cover layer is present,
- the sequence of the second cover layer and the third cover layer is repeated z times, where z≧1, and can be deposited at least on the outer periphery of the third cover layer,
A battery according to claim 4 , characterized in that the last layer of the sealant is an impermeable cover layer , made of a ceramic material and/or a low-melting glass .
少なくとも前記陽極接続ゾーン（１００２）を含む前記第１の縦方向面（Ｆ６）が前記陽極コンタクト部材（９７’）によって覆われ、かつ、
少なくとも前記陰極接続ゾーン（１００６）を含む前記第２の縦方向面（Ｆ４）が前記陰極コンタクト部材（９７’’）によって覆われていることを特徴とする、請求項１に記載の電池。 Anode contact members (97') and cathode contact members (97'') provide electrical contact between the stack (I) and external conductive elements;
said first longitudinal face (F6) including at least said anode connection zone (1002) is covered by said anode contact member (97'); and
2. The battery according to claim 1 , characterized in that at least said second longitudinal face (F4) including said cathode connection zone (1006) is covered by said cathode contact member (97'').
－少なくとも前記陽極接続ゾーン（１００２）を含む前記第１の縦方向面（Ｆ６）上および少なくとも前記陰極接続ゾーン（１００６）を含む前記第２の縦方向面（Ｆ４）上に配置され、導電性粒子を充填した材料を含む第１の電気接続層と、
－導電性粒子を充填した前記材料を含む前記第１の層上に配置されている金属箔を含む第２の電気接続層と、を含むことを特徴とする請求項９に記載の電池。 Each of the anode contact member (97') and the cathode contact member (97'')
a first electrical connection layer arranged on said first longitudinal face (F6) comprising at least said anode connection zone (1002) and on said second longitudinal face (F4) comprising at least said cathode connection zone (1006), said first electrical connection layer comprising a material filled with electrically conductive particles;
a second electrical connection layer comprising a metal foil disposed on said first layer comprising said material loaded with conductive particles.
少なくとも１つの陰極接続ゾーン（１００６）を含む前記第２の縦方向面（Ｆ４）と、各陽極層（２０）、各電解質材料層（３０）および／または各セパレータ層（３１）、各陰極層（５０）および各陽極集電基板層（１０）の前記第２の縦方向端部によって画定される前記第２の端面（ＤＹ’ａ）との間の最小距離（Ｄｃｃ）が０．０１ｍｍと０．５ｍｍとの間に含まれていることを特徴とする、請求項１に記載の電池。 the minimum distance (Dca) between said first longitudinal face (F6) including at least one anode connection zone (1002) and said first end face (DY a ) defined by said first longitudinal end of each anode layer (20), each electrolyte material layer (30) and/or each separator layer (31), each cathode layer ( 50 ) and each cathode current collecting substrate layer (40) is comprised between 0.01 mm and 0.5 mm; and/or
2. The battery according to claim 1, characterized in that the minimum distance (Dcc) between the second longitudinal face (F4) including at least one cathode connection zone (1006) and the second end face (DY' a ) defined by the second longitudinal end of each anode layer (20), each electrolyte material layer (30) and/or each separator layer (31), each cathode layer (50) and each anode current collecting substrate layer ( 10 ) is comprised between 0.01 mm and 0.5 mm.
各電池は、少なくとも１つの単位セル（１００）を含み、
各単位セル（１００）は、陽極集電基板（１０）、陽極層（２０）、少なくとも１つの電解質材料層（３０）および／または電解質を含浸している少なくとも１つのセパレータ層（３１）、陰極層（５０）および陰極集電基板（４０）を連続的に含み、
前記電池（１０００）が複数の単位セル（１００、１００’、１００’’）を含む場合、前記単位セル（１００、１００’、１００’’）の１つが他の下に配置され、すなわち前記電池の主面に対する正面方向（ＺＺ）に従って重ね合わされ、
ｏ前記陽極集電基板（１０）は、２つの隣接する単位セル（１００、１００’）の陽極集電基板（１０）であり、かつ、
ｏ前記陰極集電基板（４０）は、２つの隣接する単位セル（１００、１００’）の陰極集電基板（４０）であるように配置され、
前記少なくとも１つの単位セル（１００）または前記単位セル（１００、１００’、１００’’）は、スタック（Ｉ）を画定し、
前記スタック（Ｉ）および前記電池（１０００）は、６つの面、すなわち、
－互いに対向する、特に互いに平行な２つのいわゆる端面（Ｆ１、Ｆ２）であって、前記１つまたは複数の陽極集電基板（１０）、前記１つまたは複数の陽極層（２０）、前記１つもしくは複数の電解質材料層（３０）または電解質を含浸している前記１つもしくは複数のセパレータ層（３１）、前記１つまたは複数の陰極層（５０）、および前記１つまたは複数の陰極集電基板（４０）に概して平行な２つの端面（Ｆ１、Ｆ２）と、
－互いに対向する、特に互いに平行な２つのいわゆる横方向面（Ｆ３、Ｆ５）と、
－互いに対向する、特に互いに平行な２つのいわゆる縦方向面（Ｆ４、Ｆ６）とを有し、
前記電池の第１の縦方向面（Ｆ６）が少なくとも１つの陽極接続ゾーン（１００２）を含み、前記電池の第２の縦方向面（Ｆ４）が少なくとも１つの陰極接続ゾーン（１００６）を含み、前記陽極接続ゾーン（１００２）と陰極接続ゾーン（１００６）とが横方向に互いに対向しており、
－前記電池の第１の縦方向（ＸＸ’）において、各陽極層（２０）、各電解質材料層（３０）または電解質を含浸している各セパレータ層（３１）、各陰極層（５０）および各陰極集電基板層（４０）から各陽極集電基板（１０）が突出し、かつ、
－前記第１の縦方向（ＸＸ’）とは反対の、前記電池の第２の縦方向（ＸＸ’’）において、各陽極層（２０）、各電解質材料層（３０）または電解質を含浸している各セパレータ層（３１）、各陰極層（５０）および各陽極集電基板層（１０）から各陰極集電基板（４０）が突出している電池において、
（ｉ）溝（８０）、非被覆ゾーン（８２）、および陽極層（２０）による被覆ゾーン（８１）を有する少なくとも１つの陽極集電基板箔（１０）（以下、陽極箔（２ｅ）と称する）を供給するステップであって、該陽極層は、電解質材料層（３０）またはセパレータ層（３１）で被覆されるもしくはされないステップと、
（ｉｉ）溝（７０）、非被覆ゾーン（７２）、および陰極層（５０）による被覆ゾーン（７１）を有する少なくとも１つの陰極集電基板箔（４０）（以下、陰極箔（５ｅ）と称する）を供給するステップであって、該陰極層は、電解質材料層（３０）またはセパレータ層（３１）で被覆されるもしくはされないステップと、
（ｉｉｉ）溝（８０）、非被覆ゾーン（８２）および被覆ゾーン（８１）を有する少なくとも１つの陽極箔（２ｅ）と、溝（７０）、非被覆ゾーン（７２）および被覆ゾーン（７１）を有する少なくとも１つの陰極箔（５ｅ）とを交互に積層しているスタック（Ｉ）を製造するステップであって、陽極集電基板（１０）、陽極層（２０）、少なくとも１つの電解質材料層（３０）またはセパレータ層（３１）、陰極層（５０）、および陰極集電基板（４０）を連続的に含む少なくとも１つの単位セルを得るように、
ｏ前記電池の第１の縦方向（ＸＸ’）において、各陽極層（２０）、各電解質材料層（３０）および／または各セパレータ層（３１）、各陰極層（５０）および各陰極集電基板層（４０）から各陽極集電基板（１０）が突出し、かつ、
ｏ前記第１の縦方向（ＸＸ’）とは反対の、前記電池の第２の縦方向（ＸＸ’’）において、各陽極層（２０）、各電解質材料層（３１）および／または各セパレータ層（３１）、各陰極層（５０）および各陽極集電基板層（１０）から各陰極集電基板（４０）が突出しているようにスタック（Ｉ）を製造するステップと、
（ｉｖ）連結スタックを形成するように、ステップ（ｉｉｉ）で得られた交互の箔である前記スタック（Ｉ）を熱処理および／または機械的圧縮するステップと、
（ｖ）任意選択で、前記連結スタックから形成された電池（１０００）の所定の行（Ｌｎ）を、少なくとも１つの他の行（Ｌｎ－１、Ｌｎ＋１）から分離させる第１の対の切断（ＤＸｎ、ＤＸ’ｎ）を行うステップと、
（ｖｉ）任意選択で、ステップ（ｉｖ）で得られた前記連結スタック、またはステップ（ｖ）を実施した場合のステップ（ｖ）で得られた電池（１０００）の前記行（Ｌｎ）に、リチウム塩を含む液体電解質またはイオン液体などのリチウムイオンを運ぶ相を含浸させ、前記セパレータ層（３１）が電解質により含浸されるようにするステップと、
（ｖｉｉ）第２の対の切断（ＤＹｎ、ＤＹ’ｎ）を行うステップであって、
－前記電池の前記第１の縦方向（ＸＸ’）において、各陽極層（２０）、各電解質材料層（３０）または各セパレータ層（３１）、各陰極層（５０）および各陰極集電基板層（４０）から突出し、少なくとも１つの陽極接続ゾーン（１００２）を画定している各陽極端（１００２’）と、
－前記電池の前記第２の縦方向（ＸＸ’’）において、各陽極層（２０）、各電解質材料層（３０）または各セパレータ層（３１）、各陰極層（５０）および各陽極集電基板層（１０）から突出し、少なくとも１つの陰極接続ゾーン（１００６）を画定している各陰極端（１００６’）とを露出させ、
前記第２の対の切断（ＤＹｎ、ＤＹ’ｎ）により、ステップ（ｖ）を実施した場合、電池（１０００）の前記行（Ｌｎ）から形成される少なくとも１つの他の電池から、所定の電池を分離することができるステップと、を含む電池製造方法。 A method for manufacturing at least one battery (1000), comprising:
Each battery includes at least one unit cell (100);
Each unit cell (100) successively comprises an anode current collecting substrate (10), an anode layer (20), at least one electrolyte material layer (30) and/or at least one separator layer (31) impregnated with an electrolyte, a cathode layer (50) and a cathode current collecting substrate (40);
When the battery (1000) includes a plurality of unit cells (100, 100', 100''), the unit cells (100, 100', 100'') are arranged one below the other, i.e., stacked according to a front direction (ZZ) with respect to a main surface of the battery ;
o the anode current collecting substrate (10) is the anode current collecting substrate (10) of two adjacent unit cells (100, 100'), and
o said cathode current collecting substrates (40) are arranged such that they are the cathode current collecting substrates (40) of two adjacent unit cells (100, 100');
said at least one unit cell (100) or said unit cells (100, 100', 100'') define a stack (I),
The stack (I) and the cell (1000) have six faces, namely:
- two mutually opposing, in particular mutually parallel so-called end faces (F1, F2) which are generally parallel to the one or more anode current collecting substrates (10), the one or more anode layers (20), the one or more electrolyte material layers (30) or the one or more separator layers (31) impregnated with an electrolyte, the one or more cathode layers (50) and the one or more cathode current collecting substrates (40);
- two so-called lateral faces (F3, F5) which are opposite each other, in particular parallel to each other,
- has two so-called longitudinal faces (F4, F6) which are opposite each other, in particular parallel to each other,
a first longitudinal face (F6) of the cell comprises at least one anode connection zone (1002) and a second longitudinal face (F4) of the cell comprises at least one cathode connection zone (1006), the anode connection zone (1002) and the cathode connection zone (1006) being laterally opposite each other,
in a first longitudinal direction (XX') of the battery, each anode current collecting substrate (10) protrudes from each anode layer (20), each electrolyte material layer (30) or each separator layer (31) impregnated with an electrolyte, each cathode layer (50) and each cathode current collecting substrate layer (40); and
in a second longitudinal direction (XX'') of the cell opposite to said first longitudinal direction (XX'), each cathode current collecting substrate (40) protruding from each anode layer (20), each electrolyte material layer (30) or each separator layer (31) impregnated with an electrolyte, each cathode layer (50) and each anode current collecting substrate layer (10),
(i) providing at least one anode current collector substrate foil (10) (hereinafter referred to as anode foil (2e)) having a groove (80), a non-coated zone (82) and a zone (81) covered by an anode layer (20), said anode layer being either coated or not with an electrolyte material layer (30) or a separator layer (31) ;
(ii) providing at least one cathode current collector substrate foil (40) (hereinafter referred to as cathode foil (5e)) having a groove (70), a non-coated zone (72) and a zone (71) covered by a cathode layer (50), said cathode layer being either coated or not with an electrolyte material layer (30) or a separator layer (31) ;
(iii) manufacturing a stack (I) of at least one anode foil (2e) having a groove (80), a non-coated zone (82) and a coated zone (81) and at least one cathode foil (5e) having a groove (70), a non-coated zone (72) and a coated zone (71) alternately stacked together to obtain at least one unit cell comprising in succession an anode current collecting substrate (10), an anode layer (20), at least one electrolyte material layer (30) or separator layer (31), a cathode layer (50) and a cathode current collecting substrate (40);
In a first longitudinal direction (XX') of the battery, each anode current collecting substrate (10) protrudes from each anode layer (20), each electrolyte material layer (30) and/or each separator layer (31), each cathode layer (50) and each cathode current collecting substrate layer (40), and
o manufacturing the stack (I) such that in a second longitudinal direction (XX'') of the cell, opposite to said first longitudinal direction (XX'), each anode layer (20), each electrolyte material layer (31) and/or each separator layer (31), each cathode layer (50) and each anode current collecting substrate layer (10) protrude from each cathode current collecting substrate layer (40);
(iv) heat treating and/or mechanically compressing said stack (I) of alternating foils obtained in step (iii) so as to form a connected stack;
(v) optionally performing a first pair of cuts (DXn, DX'n) separating a given row ( Ln ) of cells (1000) formed from said interconnected stack from at least one other row (Ln -1 , Ln +1 );
(vi) optionally, impregnating the connected stack obtained in step (iv) or, if step (v) is carried out, the rows (L n ) of the cells (1000) obtained in step (v) with a phase carrying lithium ions, such as a liquid electrolyte containing a lithium salt or an ionic liquid, so that the separator layer (31) is impregnated with the electrolyte;
(vii) performing a second pair of cuts (DY n , DY′ n ),
- each anode end (1002') protruding from each anode layer (20), each electrolyte material layer (30) or each separator layer (31), each cathode layer (50) and each cathode current collecting substrate layer (40) in said first longitudinal direction (XX') of said battery, and defining at least one anode connection zone (1002);
- exposing, in the second longitudinal direction (XX'') of the battery, each anode layer (20), each electrolyte material layer (30) or each separator layer (31), each cathode layer (50) and each cathode end (1006') protruding from each anode current collecting substrate layer (10) and defining at least one cathode connection zone (1006);
and cutting the second pair (DY n , DY′ n ) when step (v) is performed, thereby isolating a given battery from at least one other battery formed from the row (L n ) of batteries (1000).
ステップ（ｖｉ）を実施せず、ステップ（ｖ）を実施する場合はステップ（ｖ）の後に、または、
ステップ（ｖｉ）および（ｖ）を実施しない場合、ステップ（ｉｖ）の後、かつ、ステップ（ｖｉｉ）の前に、
前記連結スタックまたは電池の前記行（Ｌｎ）を封止化するステップ（ｖｉｉｉ）を実施し、前記スタックの前記端面（Ｆ１、Ｆ２）または電池の前記行（Ｌｎ）の前記端面（ＦＦ１、ＦＦ２）、横方向面（Ｆ３、Ｆ５、ＦＦ３、ＦＦ５）および縦方向面（Ｆ４、Ｆ６、ＦＦ４、ＦＦ６）の少なくとも一部を、封止材（９５）によって覆い、
ｏ前記電池の第１の縦方向（ＸＸ’）において、各陽極層（２０）、各電解質材料層（３０）または各セパレータ層（３１）、各陰極層（５０）および各陰極集電基板層（４０）から突出している各陽極集電基板（１０）の各陽極端（１００２’）のみが第１の縦方向面（Ｆ６、ＦＦ６）と同一平面上にあり、かつ、
ｏ前記電池の第２の縦方向（ＸＸ’’）において、各陽極層（２０）、各電解質材料層（３０）または各セパレータ層（３１）、各陰極層（５０）および各陽極集電基板層（２０）から突出している各陰極集電基板（４０）の各陰極端（１００６’）のみが第２の縦方向面（Ｆ４、ＦＦ４）と同一平面上にあり、前記第２の縦方向面（Ｆ４、ＦＦ４）が前記第１の縦方向面（Ｆ６、ＦＦ６）と対向かつ平行しており、
各陽極端（１００２’）が陽極接続ゾーン（１００２）を画定し、各陰極端（１００６’）が陰極接続ゾーン（１００６）を画定することを特徴とする、請求項１２に記載の電池製造方法。 after step (vi) if step (vi) is carried out, or
if step (vi) is not performed and step (v) is performed, then after step (v), or
If steps (vi) and (v) are not performed, after step (iv) and before step (vii),
carrying out a step (viii) of encapsulating said connected stack or said row (L n ) of cells , covering at least a part of said end faces (F1, F2) of said stack or said row (L n ) of cells, said end faces (FF1, FF2), said lateral faces (F3, F5, FF3, FF5) and said longitudinal faces (F4, F6, FF4, FF6) with an encapsulant (95);
In the first longitudinal direction (XX') of the battery, only the anode ends (1002') of each anode current collecting substrate (10) protruding from each anode layer (20), each electrolyte material layer (30) or each separator layer (31), each cathode layer (50) and each cathode current collecting substrate layer (40) are flush with the first longitudinal surface (F6, FF6), and
In a second longitudinal direction (XX'') of the battery, only each anode layer (20), each electrolyte material layer (30) or each separator layer (31), each cathode layer (50) and each cathode end (1006') of each cathode current collecting substrate (40) protruding from each anode current collecting substrate layer (20) are flush with a second longitudinal surface (F4, FF4), and the second longitudinal surface (F4, FF4) is opposite and parallel to the first longitudinal surface (F6, FF6);
13. The method of claim 12 , wherein each anode end (1002') defines an anode connection zone (1002) and each cathode end (1006') defines a cathode connection zone (1006).
セラミック材料および／または低融点ガラスから成る、前記スタック（Ｉ）または電池（１０００）の前記行（ＬThe rows (L) of the stack (I) or the cells (1000) are made of ceramic material and/or low melting glass. ｎn ）の外周部の少なくとも一部上に堆積されている少なくとも１つの不浸透性カバー層を含む、at least one impermeable cover layer disposed on at least a portion of the periphery of the
または、or
－パリレン、パリレンＦ、ポリイミド、エポキシ樹脂、シリコン、ポリアミド、ゾルゲルシリカ、有機シリカおよび／またはそれらの混合物の中から選択され、前記スタック（Ｉ）または電池（１０００）の前記行（Ｌ- selected from among parylene, parylene F, polyimide, epoxy resin, silicone, polyamide, sol-gel silica, organosilica and/or mixtures thereof, and ｎn ）の外周部の少なくとも一部上に堆積されている少なくとも１つのカバー層と、At least one cover layer disposed on at least a portion of the outer periphery of the
－セラミック材料および／または低融点ガラスから成る、前記第１のカバー層上に堆積されている少なくとも１つの不浸透性カバー層と、を含む、at least one impermeable cover layer deposited on said first cover layer, said cover layer consisting of a ceramic material and/or a low-melting glass,
または、or
－前記スタック（Ｉ）の外周部の少なくとも一部上に原子層堆積法により堆積されている、電気的絶縁材料からなるカバー層と、a cover layer made of an electrically insulating material deposited by atomic layer deposition on at least a portion of the periphery of said stack (I);
－セラミック材料および／または低融点ガラスから成る、前記スタック（Ｉ）の外周部の少なくとも一部上に堆積されている少なくとも１つの不浸透性カバー層と、を含み、at least one impermeable cover layer, deposited on at least a portion of the periphery of said stack (I), consisting of a ceramic material and/or a low-melting glass,
電気的絶縁材料からなる少なくとも１つのカバー層と少なくとも１つの不浸透性カバー層との連続をｚ回繰り返し、ここでｚ≧１であり、少なくとも前記不浸透性カバー層の外周部上に堆積させることができ、かつ、前記封止材の最後の層が、不浸透性カバー層であり、セラミック材料および／または低融点ガラスから成る、a sequence of at least one cover layer of an electrically insulating material and at least one impermeable cover layer repeated z times, where z≧1, can be deposited at least on the outer periphery of the impermeable cover layer, and the last layer of the sealing material is an impermeable cover layer and is made of a ceramic material and/or a low melting glass;
または、or
－パリレン、パリレンＦ、ポリイミド、エポキシ樹脂、シリコン、ポリアミド、ゾルゲルシリカ、有機シリカおよび／またはそれらの混合物の中から選択され、前記スタック（Ｉ）の外周部の少なくとも一部上に堆積されている少なくとも１つの第１のカバー層と、at least one first cover layer selected from among parylene, parylene F, polyimide, epoxy resin, silicone, polyamide, sol-gel silica, organosilica and/or mixtures thereof, deposited on at least a portion of the periphery of said stack (I);
－前記第１のカバー層上に原子層堆積法により堆積されている、電気的絶縁材料からなる第２のカバー層と、a second cover layer made of an electrically insulating material, deposited by atomic layer deposition on said first cover layer;
－セラミック材料および／または低融点ガラスから成る少なくとも１つの第３の不浸透性カバー層と、を含み、at least one third impermeable cover layer made of a ceramic material and/or a low-melting glass,
前記第２のカバー層が存在する場合に、When the second cover layer is present,
－前記第２のカバー層と前記第３のカバー層との連続をｚ回繰り返し、ここでｚ≧１であり、少なくとも前記第３のカバー層の外周部上に堆積させることができ、- the sequence of the second cover layer and the third cover layer is repeated z times, where z≧1, and can be deposited at least on the outer periphery of the third cover layer,
－前記封止材の最後の層が、不浸透性カバー層であり、セラミック材料および／または低融点ガラスから成る、ことを特徴とする、請求項１３に記載の方法。A method according to claim 13, characterized in that the last layer of the sealing material is an impermeable cover layer, made of a ceramic material and/or a low-melting glass.
少なくとも前記陰極接続ゾーン（１００６）を含む前記第２の縦方向面（Ｆ４）が前記スタック（Ｉ）と外部導電性要素との間の電気的接触を生じさせることができる陰極コンタクト部材（９７’’）によって覆われており、
前記陽極コンタクト部材（９７’）および陰極コンタクト部材（９７’’）の前記製造は、
－少なくとも前記陽極接続ゾーン（１００２）を含む前記第１の縦方向面（Ｆ６）上および少なくとも前記陰極接続ゾーン（１００６）を含む前記第２の縦方向面（Ｆ４）上に、導電性粒子を充填した材料でできた第１の電気接続層を堆積させるステップであって、前記第１の層が好ましくは導電性粒子を充填した高分子樹脂および／またはゾルゲル法で得られた材料からなるステップと、
－前記第１の層上に、前記第１の電気接続層上に配置される金属箔を含む第２の電気接続層を堆積させるステップと、を含むことを特徴とする、請求項１２から１４のいずれか一項に記載の電池製造方法。 After step (vii) , at least said first longitudinal face (F6), including at least said anode connection zone (1002), is covered by an anode contact member (97') capable of making an electrical contact between said stack (I) and an external conductive element, and
said second longitudinal face (F4) including at least said cathode connection zone (1006) is covered by a cathode contact member (97'') capable of making an electrical contact between said stack (I) and an external conductive element,
The manufacturing of the anode contact member (97') and the cathode contact member (97'') comprises:
- depositing, on said first longitudinal face (F6) comprising at least said anode connection zone (1002) and on said second longitudinal face (F4) comprising at least said cathode connection zone (1006), a first electrical connection layer made of a material filled with conductive particles, said first layer preferably consisting of a polymeric resin and/or a sol-gel derived material filled with conductive particles ;
- depositing on said first layer a second electrical connection layer comprising a metal foil , said second electrical connection layer being arranged on said first electrical connection layer.
前記スタックおよび前記電池は、６つの面、すなわち、
－前記層および前記集電基板に対して概して平行で、互いに対向する２つのいわゆる端面（Ｆ１、Ｆ２）と、
－陽極および陰極接続ゾーンをそれぞれ含む、互いに対向する２つのいわゆる縦方向面（Ｆ４、Ｆ６）と、
－互いに対向する２つのいわゆる横方向面と、を有し、
－前記スタックの反対側の端面に設けられた２つの電気的接続部材（５６０、５７０）をさらに含み、各電気的接続部材の第１の端部（５６２、５７２）が前記縦方向（ＸＸ）において前記スタックのそれぞれの縦方向面（Ｆ４、Ｆ６）を超えて突出していることを特徴とする電池。 A battery (1500) comprising a stack formed by at least one unit cell, in particular a single unit cell (600), each unit cell comprising successively an anode current collecting substrate (510), an anode layer (520), at least one electrolyte material layer (530) and/or at least one separator layer (531) impregnated with an electrolyte, a cathode layer (550) and a cathode current collecting substrate (540),
The stack and the cells have six faces, namely:
- two so-called end faces (F1, F2) facing each other and generally parallel to said layer and to said current collecting substrate,
- two mutually opposing so-called longitudinal faces (F4, F6) which respectively comprise the anode and cathode connection zones;
- has two so-called lateral faces opposite each other,
- a battery further comprising two electrical connection members (560, 570) provided on opposite end faces of said stack, a first end (562, 572) of each electrical connection member protruding in said longitudinal direction (XX) beyond a respective longitudinal face (F4, F6) of said stack.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP20166569.2 | 2020-03-30 | ||
| EP20166569.2A EP3890077A1 (en) | 2020-03-30 | 2020-03-30 | Lithium-ion battery and manufacturing method thereof |
| PCT/IB2021/052375 WO2021198843A1 (en) | 2020-03-30 | 2021-03-23 | Lithium-ion battery and method for the manufacture thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2023519702A JP2023519702A (en) | 2023-05-12 |
| JPWO2021198843A5 true JPWO2021198843A5 (en) | 2024-05-10 |
Family
ID=70058135
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2022559537A Pending JP2023519702A (en) | 2020-03-30 | 2021-03-23 | Lithium ion secondary battery and manufacturing method thereof |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US20230122314A1 (en) |
| EP (2) | EP3890077A1 (en) |
| JP (1) | JP2023519702A (en) |
| KR (1) | KR20220160672A (en) |
| CN (1) | CN115885403A (en) |
| CA (1) | CA3173247A1 (en) |
| IL (1) | IL296779A (en) |
| TW (1) | TW202141837A (en) |
| WO (1) | WO2021198843A1 (en) |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4238645B2 (en) * | 2003-06-12 | 2009-03-18 | 日産自動車株式会社 | Bipolar battery |
| JP5165843B2 (en) * | 2004-12-13 | 2013-03-21 | パナソニック株式会社 | Laminated body including active material layer and solid electrolyte layer, and all-solid lithium secondary battery using the same |
| FR2897434B1 (en) | 2006-02-15 | 2014-07-11 | Commissariat Energie Atomique | METHOD AND DEVICE FOR PERMEATION MEASUREMENT |
| JP4301286B2 (en) * | 2006-12-21 | 2009-07-22 | トヨタ自動車株式会社 | Power storage device |
| FR3023418B1 (en) | 2014-07-01 | 2016-07-15 | I Ten | COMPLETELY SOLID BATTERY COMPRISING AN ELECTROLYTE IN RETICULATED SOLID POLYMERIC MATERIAL |
| CN110140251A (en) * | 2016-12-29 | 2019-08-16 | 株式会社村田制作所 | All-solid-state battery, electronic equipment, electronic card, wearable device and electric vehicle |
| JP6772855B2 (en) * | 2017-01-20 | 2020-10-21 | トヨタ自動車株式会社 | All solid state battery |
| JP6933250B2 (en) * | 2017-03-28 | 2021-09-08 | 株式会社村田製作所 | All-solid-state batteries, electronic devices, electronic cards, wearable devices and electric vehicles |
-
2020
- 2020-03-30 EP EP20166569.2A patent/EP3890077A1/en not_active Withdrawn
-
2021
- 2021-03-23 WO PCT/IB2021/052375 patent/WO2021198843A1/en unknown
- 2021-03-23 IL IL296779A patent/IL296779A/en unknown
- 2021-03-23 JP JP2022559537A patent/JP2023519702A/en active Pending
- 2021-03-23 US US17/907,437 patent/US20230122314A1/en active Pending
- 2021-03-23 KR KR1020227037934A patent/KR20220160672A/en active Search and Examination
- 2021-03-23 EP EP21713766.0A patent/EP4128410A1/en active Pending
- 2021-03-23 CA CA3173247A patent/CA3173247A1/en active Pending
- 2021-03-23 CN CN202180038646.7A patent/CN115885403A/en active Pending
- 2021-03-26 TW TW110111103A patent/TW202141837A/en unknown
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