JPWO2020208474A5 - - Google Patents
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- JPWO2020208474A5 JPWO2020208474A5 JP2021513026A JP2021513026A JPWO2020208474A5 JP WO2020208474 A5 JPWO2020208474 A5 JP WO2020208474A5 JP 2021513026 A JP2021513026 A JP 2021513026A JP 2021513026 A JP2021513026 A JP 2021513026A JP WO2020208474 A5 JPWO2020208474 A5 JP WO2020208474A5
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- light
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- compound
- emitting device
- organic compound
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- 150000001875 compounds Chemical class 0.000 claims 18
- 150000002894 organic compounds Chemical class 0.000 claims 15
- 239000000463 material Substances 0.000 claims 13
- 238000004770 highest occupied molecular orbital Methods 0.000 claims 8
- 239000000126 substance Substances 0.000 claims 8
- 229910052783 alkali metal Inorganic materials 0.000 claims 4
- 150000001340 alkali metals Chemical class 0.000 claims 4
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims 4
- 150000001342 alkaline earth metals Chemical class 0.000 claims 4
- 230000005525 hole transport Effects 0.000 claims 4
- 125000002524 organometallic group Chemical group 0.000 claims 4
- 238000002347 injection Methods 0.000 claims 3
- 239000007924 injection Substances 0.000 claims 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims 2
- 125000005577 anthracene group Chemical group 0.000 claims 2
- 125000000609 carbazolyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3NC12)* 0.000 claims 2
- TXCDCPKCNAJMEE-UHFFFAOYSA-N dibenzofuran Chemical group C1=CC=C2C3=CC=CC=C3OC2=C1 TXCDCPKCNAJMEE-UHFFFAOYSA-N 0.000 claims 2
- IYYZUPMFVPLQIF-ALWQSETLSA-N dibenzothiophene Chemical group C1=CC=CC=2[34S]C3=C(C=21)C=CC=C3 IYYZUPMFVPLQIF-ALWQSETLSA-N 0.000 claims 2
- 239000003446 ligand Substances 0.000 claims 2
- 229910052751 metal Inorganic materials 0.000 claims 2
- 239000002184 metal Substances 0.000 claims 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims 1
- 239000002585 base Substances 0.000 claims 1
- 230000005684 electric field Effects 0.000 claims 1
- 229910044991 metal oxide Inorganic materials 0.000 claims 1
- 150000004706 metal oxides Chemical class 0.000 claims 1
- 229910052757 nitrogen Inorganic materials 0.000 claims 1
- 239000001301 oxygen Substances 0.000 claims 1
- 229910052760 oxygen Inorganic materials 0.000 claims 1
- LISFMEBWQUVKPJ-UHFFFAOYSA-N quinolin-2-ol Chemical compound C1=CC=C2NC(=O)C=CC2=C1 LISFMEBWQUVKPJ-UHFFFAOYSA-N 0.000 claims 1
- 229910052761 rare earth metal Inorganic materials 0.000 claims 1
- 150000002910 rare earth metals Chemical class 0.000 claims 1
- 150000003839 salts Chemical class 0.000 claims 1
- 239000000758 substrate Substances 0.000 claims 1
Claims (23)
前記第1の層は、第1の有機化合物と、第1の物質と、を有し、
前記第2の層は、第2の有機化合物を有し、
前記第3の層は、第2の物質を有し、
前記第1の有機化合物は、電子輸送性材料であり、
前記第1の物質は、金属、金属塩、金属酸化物、または有機金属塩であり、
前記第2の有機化合物は、電子輸送性材料であり、
前記第2の物質は、電子注入性材料であり、
前記第2の層は、前記第1の層に比べて、前記第1の物質の濃度が低く、
前記第1の物質と前記第2の物質は、異なる物質である、発光デバイス。 Having a first electrode, a first light emitting layer, a first layer, a second layer, a third layer, a second light emitting layer, and a second electrode stacked in this order,
the first layer includes a first organic compound and a first substance;
The second layer has a second organic compound,
the third layer comprises a second material;
the first organic compound is an electron-transporting material,
the first substance is a metal, a metal salt, a metal oxide, or an organometallic salt;
the second organic compound is an electron-transporting material,
the second substance is an electron-injecting material;
the second layer has a lower concentration of the first substance than the first layer;
A light emitting device , wherein the first material and the second material are different materials .
前記第2の層は、前記第1の物質を含まない、発光デバイス。 In claim 1,
A light-emitting device, wherein the second layer does not include the first material.
前記第1の有機化合物と前記第2の有機化合物とは、同一の有機化合物である、発光デバイス。 In claim 1 or 2,
The light-emitting device, wherein the first organic compound and the second organic compound are the same organic compound.
前記第3の層は、さらに、第3の有機化合物を有し、
前記第3の有機化合物は、電子輸送性材料である、発光デバイス。 In any one of claims 1 to 3,
The third layer further comprises a third organic compound,
The light-emitting device, wherein the third organic compound is an electron-transporting material.
前記第3の有機化合物は、前記第1の有機化合物及び前記第2の有機化合物の少なくとも一方と同一の有機化合物である、発光デバイス。 In claim 4,
The light-emitting device, wherein the third organic compound is the same organic compound as at least one of the first organic compound and the second organic compound.
前記第1の物質は、アルカリ金属またはアルカリ土類金属を有する、有機金属錯体である、発光デバイス。 In any one of claims 1 to 5,
The light emitting device, wherein the first substance is an organometallic complex comprising an alkali metal or an alkaline earth metal.
前記第1の物質は、窒素及び酸素を有する配位子と、アルカリ金属またはアルカリ土類金属と、を有する有機金属錯体である、発光デバイス。 In any one of claims 1 to 6,
The light-emitting device, wherein the first substance is an organometallic complex having a ligand having nitrogen and oxygen and an alkali metal or alkaline earth metal.
前記第1の物質は、キノリノール配位子と、アルカリ金属またはアルカリ土類金属と、を有する有機金属錯体である、発光デバイス。 In any one of claims 1 to 7,
The light-emitting device, wherein the first substance is an organometallic complex having a quinolinol ligand and an alkali metal or alkaline earth metal.
前記第2の物質は、アルカリ金属、アルカリ土類金属、または希土類金属を有する、発光デバイス。 In any one of claims 1 to 8,
A light emitting device, wherein the second material comprises an alkali metal, an alkaline earth metal, or a rare earth metal.
前記第1の有機化合物は、HOMO準位が-6.0eV以上であり、かつ電界強度[V/cm]の平方根が600における電子移動度が1×10-7cm2/Vs以上5×10-5cm2/Vs以下である、発光デバイス。 In any one of claims 1 to 9,
The first organic compound has a HOMO level of −6.0 eV or more and an electron mobility of 1×10 −7 cm 2 /Vs or more at a square root of an electric field intensity [V/cm] of 600. -5 cm 2 /Vs or less, a light emitting device.
前記第1の層は、前記第1の発光層側の第1の領域と、前記第2の発光層側の第2の領域と、を有し、
前記第1の領域と前記第2の領域とは、前記第1の有機化合物と前記第1の物質の濃度比が異なる、発光デバイス。 In any one of claims 1 to 10,
the first layer has a first region on the first light-emitting layer side and a second region on the second light-emitting layer side;
The light-emitting device, wherein the first region and the second region have different concentration ratios of the first organic compound and the first substance.
前記第1の層は、前記第1の発光層側の第1の領域と、前記第2の発光層側の第2の領域と、を有し、
前記第2の領域は、前記第1の領域よりも、前記第1の物質の濃度が低い、発光デバイス。 In any one of claims 1 to 10,
the first layer has a first region on the first light-emitting layer side and a second region on the second light-emitting layer side;
The light emitting device, wherein the second region has a lower concentration of the first material than the first region.
さらに、正孔注入層を有し、
前記正孔注入層は、前記第1の電極と前記第1の発光層との間に位置し、
前記正孔注入層は、第1の化合物及び第2の化合物を有し、
前記第1の化合物は、前記第2の化合物に対する電子受容性を有し、
前記第2の化合物のHOMO準位は、-5.7eV以上-5.4eV以下である、発光デバイス。 In any one of claims 1 to 12,
Furthermore, having a hole injection layer,
the hole injection layer is located between the first electrode and the first light-emitting layer;
The hole injection layer has a first compound and a second compound,
The first compound has an electron-accepting property with respect to the second compound,
The light-emitting device, wherein the second compound has a HOMO level of −5.7 eV or more and −5.4 eV or less.
さらに、第1の正孔輸送層を有し、
前記第1の正孔輸送層は、前記正孔注入層と前記第1の発光層との間に位置し、
前記第1の正孔輸送層は、第3の化合物を有し、
前記第3の化合物のHOMO準位は、前記第2の化合物のHOMO準位以下の値であり、
前記第3の化合物のHOMO準位と前記第2の化合物のHOMO準位との差は、0.2eV以内である、発光デバイス。 In claim 13,
Furthermore, having a first hole transport layer,
the first hole-transporting layer is located between the hole-injecting layer and the first light-emitting layer;
The first hole transport layer has a third compound,
The HOMO level of the third compound is a value equal to or lower than the HOMO level of the second compound,
The light-emitting device, wherein the difference between the HOMO level of the third compound and the HOMO level of the second compound is within 0.2 eV.
前記第2の化合物及び前記第3の化合物は、それぞれ、カルバゾール骨格、ジベンゾフラン骨格、ジベンゾチオフェン骨格、及びアントラセン骨格のうち少なくとも一つを有する、発光デバイス。 In claim 14,
A light-emitting device, wherein the second compound and the third compound each have at least one of a carbazole skeleton, a dibenzofuran skeleton, a dibenzothiophene skeleton, and an anthracene skeleton.
さらに、第2の正孔輸送層を有し、
前記第2の正孔輸送層は、前記第1の正孔輸送層と前記第1の発光層との間に位置し、
前記第2の正孔輸送層は、第4の化合物を有し、
前記第4の化合物のHOMO準位は、前記第3の化合物のHOMO準位よりも低い、発光デバイス。 In claim 14,
Furthermore, having a second hole transport layer,
the second hole-transporting layer is located between the first hole-transporting layer and the first light-emitting layer;
The second hole transport layer has a fourth compound,
A light-emitting device, wherein the HOMO level of the fourth compound is lower than the HOMO level of the third compound.
前記第2の化合物、前記第3の化合物、及び前記第4の化合物は、それぞれ、カルバゾール骨格、ジベンゾフラン骨格、ジベンゾチオフェン骨格、及びアントラセン骨格のうち少なくとも一つを有する、発光デバイス。 In claim 16,
A light-emitting device, wherein the second compound, the third compound, and the fourth compound each have at least one of a carbazole skeleton, a dibenzofuran skeleton, a dibenzothiophene skeleton, and an anthracene skeleton.
前記第1の発光層は、青色の光を発する発光物質を有する、発光デバイス。 In any one of claims 1 to 17,
A light-emitting device, wherein the first light-emitting layer comprises a light-emitting material that emits blue light.
前記第1の発光層は、青色の光を発する蛍光発光物質を有する、発光デバイス。 In any one of claims 1 to 18,
A light-emitting device, wherein the first light-emitting layer comprises a fluorescent light-emitting material that emits blue light.
トランジスタ及び基板のうち少なくとも一つと、を有する、発光装置。 A light emitting device according to any one of claims 1 to 19;
A light emitting device, comprising at least one of a transistor and a substrate.
コネクタ及び集積回路のうち少なくとも一つと、を有する、発光モジュール。 a light emitting device according to claim 20;
A light emitting module, comprising at least one of a connector and an integrated circuit.
アンテナ、バッテリ、筐体、カメラ、スピーカ、マイク、及び操作ボタンのうち少なくとも一つと、を有する、電子機器。 a light emitting module according to claim 21;
An electronic device, comprising at least one of an antenna, a battery, a housing, a camera, a speaker, a microphone, and an operation button.
筐体、カバー、及び支持台のうち少なくとも一つと、を有する、照明装置。 A light emitting device according to any one of claims 1 to 19;
A lighting device comprising at least one of a housing, a cover, and a support base.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2019076244 | 2019-04-12 | ||
JP2019076244 | 2019-04-12 | ||
PCT/IB2020/053071 WO2020208474A1 (en) | 2019-04-12 | 2020-04-01 | Light emission device, light emission apparatus, light emission module, electronic equipment, and illumination apparatus |
Publications (3)
Publication Number | Publication Date |
---|---|
JPWO2020208474A1 JPWO2020208474A1 (en) | 2020-10-15 |
JPWO2020208474A5 true JPWO2020208474A5 (en) | 2023-03-14 |
JP7494165B2 JP7494165B2 (en) | 2024-06-03 |
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