JPWO2020058403A5 - - Google Patents
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- JPWO2020058403A5 JPWO2020058403A5 JP2021514403A JP2021514403A JPWO2020058403A5 JP WO2020058403 A5 JPWO2020058403 A5 JP WO2020058403A5 JP 2021514403 A JP2021514403 A JP 2021514403A JP 2021514403 A JP2021514403 A JP 2021514403A JP WO2020058403 A5 JPWO2020058403 A5 JP WO2020058403A5
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- 239000002131 composite material Substances 0.000 claims 37
- 239000002033 PVDF binder Substances 0.000 claims 21
- 229920002981 polyvinylidene fluoride Polymers 0.000 claims 21
- 239000010410 layer Substances 0.000 claims 17
- 239000000835 fiber Substances 0.000 claims 16
- 239000012778 molding material Substances 0.000 claims 16
- 239000004952 Polyamide Substances 0.000 claims 15
- 229920002647 polyamide Polymers 0.000 claims 15
- 229920001577 copolymer Polymers 0.000 claims 11
- 239000011159 matrix material Substances 0.000 claims 10
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 10
- 239000000203 mixture Substances 0.000 claims 9
- 239000007789 gas Substances 0.000 claims 8
- 229920001169 thermoplastic Polymers 0.000 claims 8
- 239000004416 thermosoftening plastic Substances 0.000 claims 8
- 229910052739 hydrogen Inorganic materials 0.000 claims 7
- 239000001257 hydrogen Substances 0.000 claims 7
- 239000003921 oil Substances 0.000 claims 6
- 229920000642 polymer Polymers 0.000 claims 6
- 230000003014 reinforcing effect Effects 0.000 claims 6
- 239000007924 injection Substances 0.000 claims 5
- 238000002347 injection Methods 0.000 claims 5
- 125000004432 carbon atom Chemical group C* 0.000 claims 4
- 239000008188 pellet Substances 0.000 claims 4
- 125000001931 aliphatic group Chemical group 0.000 claims 3
- 239000010779 crude oil Substances 0.000 claims 3
- 239000003502 gasoline Substances 0.000 claims 3
- 239000010720 hydraulic oil Substances 0.000 claims 3
- 150000002431 hydrogen Chemical class 0.000 claims 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 2
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims 2
- 150000001244 carboxylic acid anhydrides Chemical group 0.000 claims 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims 2
- 239000000463 material Substances 0.000 claims 2
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims 2
- 239000002253 acid Substances 0.000 claims 1
- 150000008065 acid anhydrides Chemical group 0.000 claims 1
- 125000004185 ester group Chemical group 0.000 claims 1
- 229920001519 homopolymer Polymers 0.000 claims 1
- 125000005462 imide group Chemical group 0.000 claims 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims 1
- 239000002356 single layer Substances 0.000 claims 1
Claims (20)
前記ポリマーマトリックスが、以下の成分：
ａ）主成分としての、すなわち少なくとも５０重量部程度の低粘度ＰＶＤＦ、および
ｂ）１重量部～５０重量部のアクリレートコポリマーであり、無水カルボン酸単位を有する単位を１重量％～３０重量％含むアクリレートコポリマーを含み、前記成分ａ）および成分ｂ）の重量部の合計が１００である混合物を、少なくとも８０重量％程度含み、
前記複合材料中の前記連続繊維の体積比率が１０重量％～８０重量％であり、前記ポリマーマトリックスと前記連続繊維の百分率が、それぞれ、前記複合材料の総質量または総体積に対するものである、複合材料。 A composite material consisting of a polymer matrix and continuous fibers embedded therein.
The polymer matrix has the following components:
a) Low-viscosity PVDF as a main component, that is, at least about 50 parts by weight, and b) 1 part by weight to 50 parts by weight of an acrylate copolymer containing 1% by weight to 30% by weight of a unit having an carboxylic acid anhydride unit. It contains at least about 80% by weight of a mixture containing an acrylate copolymer and having a total of 100 parts by weight of the components a) and b).
The composite in which the volume ratio of the continuous fibers in the composite is 10% to 80% by weight and the proportions of the polymer matrix and the continuous fibers are relative to the total mass or volume of the composite, respectively. material.
Ｉ．１４重量％～８０重量％の下記式のエステル単位、
（式中、Ｒはメチル、エチル、プロピルまたはブチルであり、Ｒ１は水素またはメチルである。）
ＩＩ．１０重量％～７５重量％の下記式のイミド単位、
（式中、Ｒ４は、独立して、１～８個の炭素原子を有する、好ましくは１～４個の炭素原子を有する、より好ましく水素またはメチルを有する脂肪族または脂環式ラジカルであり、Ｒ３は、独立して、メチル、エチル、プロピル、ブチルまたはフェニルであり、ｍは０または１である。）
ＩＩＩ．１重量％～２０重量％の下記式の酸単位、
（式中、Ｒ２は水素またはメチルである。）
ＩＶ．１重量％～３０重量％の下記式の酸無水物単位
（式中、Ｒ５は、独立して、１～８個の炭素原子を有する脂肪族または脂環式ラジカルであり、ｎは０または１である。）
を含み、
前記単位Ｉ、ＩＩ、ＩＩＩおよびＩＶは、合計で１００重量％になることを特徴とする、請求項１記載の複合材料。 The acrylate copolymer has the following units:
I. 14% by weight to 80% by weight of the ester unit of the following formula,
(In the formula, R is methyl, ethyl, propyl or butyl and R1 is hydrogen or methyl.)
II. 10% by weight to 75% by weight of the imide unit of the following formula,
(In the formula, R4 is an aliphatic or alicyclic radical independently having 1 to 8 carbon atoms, preferably 1 to 4 carbon atoms, more preferably hydrogen or methyl. , R 3 are independently methyl, ethyl, propyl, butyl or phenyl, and m is 0 or 1.)
III. 1% by weight to 20% by weight of the acid unit of the following formula,
(In the formula, R2 is hydrogen or methyl.)
IV. 1% by weight to 30% by weight of the acid anhydride unit of the following formula
(In the formula, R5 is an aliphatic or alicyclic radical having 1 to 8 carbon atoms independently, and n is 0 or 1.)
Including
The composite material according to claim 1 , wherein the units I, II, III and IV are 100% by weight in total.
Ｉ．外面がポリアミド成形材料またはＰＶＤＦ成形材料で構成される、単層または複数層の管状ライナーと、
ＩＩ．ポリマーマトリックスとその中に埋め込まれた連続繊維からなる複合材料で構成される補強プライであり、前記ポリマーマトリックスが、以下の成分：
ａ）５０重量部～９９重量部のＰＶＤＦ、および
ｂ）１重量部～５０重量部のアクリレートコポリマーであり、カルボン酸無水物基を有する単位を１重量％～３０重量％含むアクリレートコポリマー
を含み、かつ前記成分ａ）および成分ｂ）の重量部の合計が１００である混合物を、少なくとも８０重量％程度含み、前記複合材料中の前記連続繊維の体積比率が１０重量％～８０重量％であり、前記ポリマーマトリックスと前記連続繊維の百分率が、それぞれ、前記補強プライの総質量または総体積に対するものである補強プライとを含み、
ＩＩＩ．任意で、ポリアミドマトリックスとその中に埋め込まれた連続繊維からなる複合材料で構成されるさらなる補強プライであり、前記ポリアミドマトリックスがポリアミドを少なくとも８０重量％程度含み、前記複合材料中の前記連続繊維の体積比率がさらに１０％～８０％であり、前記ポリアミドマトリックスと前記連続繊維の百分率が、それぞれ、前記補強プライの総質量または総体積に対するものである補強プライを含んでよく、
ＩＶ．任意で、ポリマー材料からなる外側カバー層を含んでよい
熱可塑性複合パイプ（ＴＣＰ）。 From the inside to the outside, the following components:
I. A single-layer or multi-layer tubular liner with an outer surface made of polyamide molding material or PVDF molding material,
II. It is a reinforcing ply composed of a composite material consisting of a polymer matrix and continuous fibers embedded therein, and the polymer matrix has the following components:
a) 50 parts by weight to 99 parts by weight of PVDF, and b) 1 part by weight to 50 parts by weight of an acrylate copolymer containing 1% by weight to 30% by weight of a unit having a carboxylic acid anhydride group. Moreover, the mixture containing at least about 80% by weight of the mixture in which the total of the parts by weight of the components a) and b) is 100, and the volume ratio of the continuous fibers in the composite material is 10% by weight to 80% by weight. The polymer matrix and the continuous fiber percentages include a reinforcing ply that is relative to the total weight or volume of the reinforcing ply, respectively.
III. Optionally, a further reinforcing ply composed of a composite material consisting of a polyamide matrix and continuous fibers embedded therein, wherein the polyamide matrix contains at least about 80% by weight of polyamide and the continuous fibers in the composite material. It may further include a reinforcing ply having a volume ratio of 10% to 80% and the percentage of the polyamide matrix and the continuous fiber being relative to the total mass or volume of the reinforcing ply, respectively.
IV. Optionally, a thermoplastic composite pipe (TCP) may include an outer cover layer made of a polymeric material.
ａ）ポリアミド成形材料のライナー／本発明のＰＶＤＦ複合層／ポリアミド成形材料のカバープライ、
ｂ）ＰＶＤＦ成形材料のライナー／本発明のＰＶＤＦ複合層／ＰＶＤＦ成形材料のカバープライ、
ｃ）ＰＶＤＦ成形材料のライナー／本発明のＰＶＤＦ複合層／ポリアミド成形材料のカバープライ、
ｄ）ポリアミド成形材料のライナー／本発明のＰＶＤＦ複合層／ＰＶＤＦ成形材料のカバープライ、
ｅ）ポリアミド成形材料の内層とＰＶＤＦの外層を有する２層ライナー／アクリレートコポリマーブレンド／本発明のＰＶＤＦ複合層／ＰＶＤＦ層／アクリレートコポリマーブレンド／ポリアミド成形材料のカバープライ
ｆ）ポリアミド成形材料の内層とＰＶＤＦの外層を有する２層ライナー／アクリレートコポリマーブレンド／本発明のＰＶＤＦ複合層／ＰＶＤＦ成形材料のカバープライ、
ｇ）ＰＶＤＦまたはポリアミド成形材料のライナー／本発明のＰＶＤＦ複合層／ポリアミドマトリックスを有する複合層／ＰＶＤＦまたはポリアミド成形材料のカバープライ
から選択されることを特徴とする、請求項６記載の熱可塑性複合パイプ。 The TCP structure is as follows:
a) Liner of polyamide molding material / PVDF composite layer of the present invention / cover ply of polyamide molding material,
b) PVDF molding material liner / PVDF composite layer of the present invention / PVDF molding material cover ply,
c) PVDF molding material liner / PVDF composite layer of the present invention / polyamide molding material cover ply,
d) Liner of polyamide molding material / PVDF composite layer of the present invention / cover ply of PVDF molding material,
e) Two-layer liner having an inner layer of polyamide molding material and an outer layer of PVDF / acrylate copolymer blend / PVDF composite layer of the present invention / PVDF layer / acrylate copolymer blend / cover ply of polyamide molding material f) Inner layer of polyamide molding material and PVDF Two-layer liner with outer layer / acrylate copolymer blend / PVDF composite layer of the present invention / cover ply of PVDF molding material,
g) The thermoplastic composite according to claim 6, wherein the thermoplastic composite is selected from a liner of PVDF or a polyamide molding material / a PVDF composite layer of the present invention / a composite layer having a polyamide matrix / a cover ply of PVDF or a polyamide molding material. pipe.
Ｒはメチル、Ｒ R is methyl, R １1 は水素であり、Is hydrogen,
Ｒ R ４4 は、独立して、１～４個の炭素原子を有する脂肪族または脂環式ラジカルである請求項３に記載の複合材料。3 is the composite material of claim 3, which is an aliphatic or alicyclic radical independently having 1 to 4 carbon atoms.
Ｒはメチル、Ｒ R is methyl, R １1 はメチルであり、Is methyl
Ｒ R ４4 は、水素又はメチルである請求項３に記載の複合材料。Is the composite material of claim 3, wherein is hydrogen or methyl.
Ｒはメチル、Ｒ R is methyl, R １1 は水素であり、Is hydrogen,
Ｒ R ４4 は、水素である請求項３に記載の複合材料。Is hydrogen, the composite material according to claim 3.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP18195870.3A EP3626764B1 (en) | 2018-09-21 | 2018-09-21 | Composite with thermoplastic matrix |
| EP18195870.3 | 2018-09-21 | ||
| PCT/EP2019/075171 WO2020058403A1 (en) | 2018-09-21 | 2019-09-19 | Composites having a thermoplastic matrix |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2022500538A JP2022500538A (en) | 2022-01-04 |
| JPWO2020058403A5 true JPWO2020058403A5 (en) | 2022-06-09 |
| JP7395573B2 JP7395573B2 (en) | 2023-12-11 |
Family
ID=63798776
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2021514403A Active JP7395573B2 (en) | 2018-09-21 | 2019-09-19 | Composite material with thermoplastic matrix |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US20220041849A1 (en) |
| EP (1) | EP3626764B1 (en) |
| JP (1) | JP7395573B2 (en) |
| KR (1) | KR20210065129A (en) |
| CN (1) | CN112739751A (en) |
| BR (1) | BR112021004961B1 (en) |
| CA (1) | CA3112965C (en) |
| MX (1) | MX2021003211A (en) |
| TW (1) | TWI826528B (en) |
| WO (1) | WO2020058403A1 (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP3477176A1 (en) | 2017-10-25 | 2019-05-01 | Evonik Degussa GmbH | Method for manufacturing a tube clad with an inner liner |
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| DE4326130A1 (en) * | 1993-08-04 | 1995-02-09 | Huels Chemische Werke Ag | Thermoplastic multilayer composites |
| FI933877A (en) | 1993-09-06 | 1995-03-07 | Neste Oy | Haollfast composite tubes on a thermoplastic basis |
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| NO314958B1 (en) | 1998-06-24 | 2003-06-16 | Wellstream Int Ltd | Flexible, polymeric, composite rudder such as a flexible riser |
| DK200100832A (en) | 2001-05-23 | 2001-05-23 | Nkt Flexibles Is | Method of manufacturing a reinforcing element for a flexible pipeline |
| DE102004048777A1 (en) | 2004-10-07 | 2006-04-13 | Degussa Ag | Multi-layer composite with polyester layer and protective layer |
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| FR2918082B1 (en) * | 2007-06-27 | 2011-07-01 | Arkema France | PROCESS FOR IMPREGNATING FIBERS CONTINUOUS BY A COMPOSITE POLYMERIC MATRIX COMPRISING A FLUORINATED GRAFT POLYMER |
| FR2945549B1 (en) * | 2009-05-12 | 2012-07-27 | Arkema France | FIBROUS SUBSTRATE, METHOD FOR MANUFACTURING AND USE OF SUCH A FIBROUS SUBSTRATE |
| NL2006335C2 (en) | 2011-03-03 | 2012-09-04 | Airborne Composites Tubulars B V | Method for manufacturing continuous composite tube, apparatus for manufacturing continuous composite tube. |
| JP6141259B2 (en) | 2011-04-29 | 2017-06-07 | ティコナ・エルエルシー | Impregnation section with tension adjusting device and method for impregnating fiber roving |
| WO2013188644A1 (en) | 2012-06-15 | 2013-12-19 | Ticona Llc | Subsea pipe section with reinforcement layer |
| FR3003195B1 (en) | 2013-03-15 | 2015-07-31 | Faurecia Automotive Composites | METHOD AND DEVICE FOR MAKING A PROFILE OF FIBER-REINFORCED THERMOPLASTIC MATERIAL COMPRISING A FIBER TENSIONING STEP DURING THEIR IMPREGNATION |
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| FR3033573B1 (en) * | 2015-03-10 | 2018-03-23 | Arkema France | THERMOPLASTIC COMPOSITION AND PRE-IMPREGNE, COMPOSITE MATERIAL BASED ON SAID PRE-IMPREGN AND USES OF SAID COMPOSITE MATERIAL |
| EP3069875B1 (en) * | 2015-03-17 | 2017-07-05 | Evonik Degussa GmbH | Multilayer compound with one fluoropolymer layer |
| US10836136B2 (en) * | 2015-04-02 | 2020-11-17 | Evonik Operations Gmbh | Process and device for producing a fibre composite material |
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| EP3345749B1 (en) * | 2017-01-10 | 2019-05-22 | Evonik Degussa GmbH | Thermoplastic composite pipe with multilayered intermediate layer |
| CN110603284B (en) | 2017-05-10 | 2022-04-19 | 大金工业株式会社 | Sheet, laminate, pipe, riser pipe, and flow pipe |
| CN108214980B (en) * | 2017-12-12 | 2021-08-03 | 华东理工大学 | Equipment and method for preparing continuous fiber reinforced thermoplastic prepreg tape |
-
2018
- 2018-09-21 EP EP18195870.3A patent/EP3626764B1/en active Active
-
2019
- 2019-09-18 TW TW108133604A patent/TWI826528B/en active
- 2019-09-19 CA CA3112965A patent/CA3112965C/en active Active
- 2019-09-19 WO PCT/EP2019/075171 patent/WO2020058403A1/en active Application Filing
- 2019-09-19 CN CN201980061459.3A patent/CN112739751A/en active Pending
- 2019-09-19 KR KR1020217011367A patent/KR20210065129A/en unknown
- 2019-09-19 MX MX2021003211A patent/MX2021003211A/en unknown
- 2019-09-19 US US17/275,274 patent/US20220041849A1/en active Pending
- 2019-09-19 JP JP2021514403A patent/JP7395573B2/en active Active
- 2019-09-19 BR BR112021004961-4A patent/BR112021004961B1/en active IP Right Grant
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