JPWO2019188779A1 - Polarizers, polarizing films, laminated polarizing films, image display panels, and image display devices - Google Patents
Polarizers, polarizing films, laminated polarizing films, image display panels, and image display devices Download PDFInfo
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- JPWO2019188779A1 JPWO2019188779A1 JP2020509959A JP2020509959A JPWO2019188779A1 JP WO2019188779 A1 JPWO2019188779 A1 JP WO2019188779A1 JP 2020509959 A JP2020509959 A JP 2020509959A JP 2020509959 A JP2020509959 A JP 2020509959A JP WO2019188779 A1 JPWO2019188779 A1 JP WO2019188779A1
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- polarizer
- film
- image display
- polarizing film
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Classifications
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K59/00—Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
- H10K59/50—OLEDs integrated with light modulating elements, e.g. with electrochromic elements, photochromic elements or liquid crystal elements
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- G02B5/00—Optical elements other than lenses
- G02B5/30—Polarising elements
- G02B5/3025—Polarisers, i.e. arrangements capable of producing a definite output polarisation state from an unpolarised input state
- G02B5/3033—Polarisers, i.e. arrangements capable of producing a definite output polarisation state from an unpolarised input state in the form of a thin sheet or foil, e.g. Polaroid
- G02B5/3041—Polarisers, i.e. arrangements capable of producing a definite output polarisation state from an unpolarised input state in the form of a thin sheet or foil, e.g. Polaroid comprising multiple thin layers, e.g. multilayer stacks
- G02B5/305—Polarisers, i.e. arrangements capable of producing a definite output polarisation state from an unpolarised input state in the form of a thin sheet or foil, e.g. Polaroid comprising multiple thin layers, e.g. multilayer stacks including organic materials, e.g. polymeric layers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
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- G—PHYSICS
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- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/30—Polarising elements
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- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
- G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
- G02F1/1333—Constructional arrangements; Manufacturing methods
- G02F1/1335—Structural association of cells with optical devices, e.g. polarisers or reflectors
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- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
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Abstract
ポリビニルアルコール系フィルムから形成される偏光子であって、前記偏光子は、ホウ素およびカリウムを含み、前記偏光子中、前記ホウ素の含有量が４重量％以上６重量％以下であり、かつ前記ホウ素の含有量（重量％）に前記カリウムの含有量（重量％）を乗じた値が１．２以上である偏光子。当該偏光子は、高温環境下において、光学特性の低下の抑制効果に優れる。A polarizing element formed from a polyvinyl alcohol-based film, wherein the polarizer contains boron and potassium, and the content of the boron in the polarizer is 4% by weight or more and 6% by weight or less, and the boron. Polarizer having a value obtained by multiplying the content (% by weight) of the above potassium content (% by weight) by 1.2 or more. The polarizer is excellent in the effect of suppressing deterioration of optical characteristics in a high temperature environment.
Description
本発明は、偏光子、偏光フィルム、積層偏光フィルム、画像表示パネル、および画像表示装置に関する。 The present invention relates to a polarizer, a polarizing film, a laminated polarizing film, an image display panel, and an image display device.
従来、液晶表示装置や有機ＥＬ表示装置等の各種画像表示装置に用いる偏光子としては、高透過率と高偏光度を兼ね備えていることから、染色処理された（二色性物質を含有する）ポリビニルアルコール系フィルムが用いられている。当該偏光子は、ポリビニルアルコール系フィルムに、浴中にて、例えば、膨潤、染色、架橋、延伸等の各処理を施した後に、洗浄処理を施してから、乾燥することにより製造される。また前記偏光子は、通常、その片面または両面にトリアセチルセルロース等の保護フィルムが接着剤を用いて貼合された偏光フィルム（偏光板）として用いられている。 Conventionally, a polarizer used in various image display devices such as a liquid crystal display device and an organic EL display device has high transmittance and high degree of polarization, and thus has been dyed (contains a dichroic substance). A polyvinyl alcohol-based film is used. The polarizer is produced by subjecting a polyvinyl alcohol-based film to various treatments such as swelling, dyeing, cross-linking, and stretching in a bath, washing treatment, and then drying. Further, the polarizing element is usually used as a polarizing film (polarizing plate) in which a protective film such as triacetyl cellulose is bonded to one side or both sides thereof using an adhesive.
前記偏光フィルムは、必要に応じ、他の光学層を積層して積層偏光フィルム（光学積層体）として用いられ、前記偏光フィルムあるいは前記積層偏光フィルム（光学積層体）は、液晶セルや有機ＥＬ素子等の画像表示セルと、視認側における前面板やタッチパネル等の透明板との間に粘着剤層を介して貼合されて、上記の各種画像表示装置として用いられる。 The polarizing film is used as a laminated polarizing film (optical laminate) by laminating other optical layers as needed, and the polarizing film or the laminated polarizing film (optical laminate) is a liquid crystal cell or an organic EL element. Etc., and a transparent plate such as a front plate or a touch panel on the visual side are bonded to each other via an adhesive layer, and are used as the above-mentioned various image display devices.
近年、このような各種画像表示装置は、携帯電話やタブレット端末等のモバイル機器に加えて、カーナビゲーション装置やバックモニター等の車載用の画像表示装置としても使用される等、その用途は広がっている。これに伴い、前記偏光フィルムや前記積層偏光フィルムには、従来要求されてきたよりも、より過酷な環境下（例えば、高温環境下）における高い耐久性が求められており、そのような耐久性を確保することを目的とした偏光フィルムが提案されている（特許文献１）。 In recent years, such various image display devices have been widely used, such as being used as in-vehicle image display devices such as car navigation devices and back monitors in addition to mobile devices such as mobile phones and tablet terminals. There is. Along with this, the polarizing film and the laminated polarizing film are required to have higher durability in a harsher environment (for example, in a high temperature environment) than conventionally required, and such durability is required. A polarizing film for the purpose of securing has been proposed (Patent Document 1).
上記のような従前の偏光フィルムや積層偏光フィルムは、高温環境下に曝された場合に、ポリビニルアルコールのポリエン化が進行することにより、偏光子に着色が生じ、その光学特性が低下する問題があった。とくに、上記の偏光フィルムや積層偏光フィルムを、画像表示セルと透明板との間に粘着剤層を介して貼合することにより構成される画像表示装置は、偏光子の着色が著しく、その光学特性の低下が顕著になる問題があった。 When the conventional polarizing film or laminated polarizing film as described above is exposed to a high temperature environment, there is a problem that the polyene of polyvinyl alcohol progresses, so that the polarizer is colored and its optical characteristics are deteriorated. there were. In particular, an image display device configured by laminating the above-mentioned polarizing film or laminated polarizing film between an image display cell and a transparent plate via an adhesive layer has remarkable coloring of a polarizer, and its optics There was a problem that the deterioration of the characteristics became remarkable.
以上のような事情に鑑み、本発明は、高温環境下において、光学特性の低下の抑制効果に優れる偏光子を提供することを目的とする。 In view of the above circumstances, it is an object of the present invention to provide a polarizer having an excellent effect of suppressing deterioration of optical characteristics in a high temperature environment.
また、本発明は、上記の光学特性の低下の抑制効果に優れる偏光子を用いた偏光フィルム、積層偏光フィルム、画像表示パネル、および画像表示装置を提供することを目的とする。 Another object of the present invention is to provide a polarizing film, a laminated polarizing film, an image display panel, and an image display device using a polarizing element having an excellent effect of suppressing the deterioration of optical characteristics.
すなわち、本発明は、ポリビニルアルコール系フィルムから形成される偏光子であって、前記偏光子は、ホウ素およびカリウムを含み、前記偏光子中、前記ホウ素の含有量が４重量％以上６重量％以下であり、かつ前記ホウ素の含有量（重量％）に前記カリウムの含有量（重量％）を乗じた値が１．２以上である偏光子に関する。 That is, the present invention is a polarizing element formed from a polyvinyl alcohol-based film, wherein the polarizer contains boron and potassium, and the content of the boron in the polarizer is 4% by weight or more and 6% by weight or less. And the value obtained by multiplying the boron content (% by weight) by the potassium content (% by weight) is 1.2 or more.
また、本発明は、前記偏光子の少なくとも一方の面に透明保護フィルムが貼り合わされている偏光フィルムに関する。 The present invention also relates to a polarizing film in which a transparent protective film is bonded to at least one surface of the polarizing element.
また、本発明は、前記偏光フィルムが光学層に貼り合わされている積層偏光フィルムに関する。 The present invention also relates to a laminated polarizing film in which the polarizing film is bonded to an optical layer.
また、本発明は、画像表示セルに、前記偏光フィルム、または前記積層偏光フィルムが貼り合わされている画像表示パネルに関する。 The present invention also relates to an image display panel in which the polarizing film or the laminated polarizing film is attached to an image display cell.
また、本発明は、前記画像表示パネルの偏光フィルムまたは積層偏光フィルム側に、透明板を備える画像表示装置に関する。 The present invention also relates to an image display device provided with a transparent plate on the polarizing film or laminated polarizing film side of the image display panel.
本発明の偏光子、該偏光子を有する偏光フィルム、積層偏光フィルム、画像表示パネル、および画像表示装置における効果の作用メカニズムの詳細は不明な部分があるが、以下のように推定される。ただし、本発明は、この作用メカニズムに限定して解釈されなくてもよい。 The details of the working mechanism of the effect in the polarizing element of the present invention, the polarizing film having the polarizing element, the laminated polarizing film, the image display panel, and the image display device are unknown, but are estimated as follows. However, the present invention does not have to be construed as being limited to this mechanism of action.
本発明の偏光子は、ポリビニルアルコール系フィルムから形成され、ホウ素およびカリウムを含む。前記偏光子中、前記ホウ素の含有量は４重量％以上６重量％以下であり、かつ前記ホウ素の含有量（重量％）に前記カリウムの含有量（重量％）を乗じた値は１．２以上である。従前の偏光子がホウ素およびカリウムを含むことは知られているが、本発明の偏光子は、上記の特定量のホウ素およびカリウムを含むことにより、従前の偏光子よりも、耐熱性をより向上させることができる。とくに、本発明の偏光子ように、前記ホウ素の含有量（重量％）に前記カリウムの含有量（重量％）を乗じた値が１．２以上である偏光子が、それ未満の偏光子よりも、優れた耐熱性を奏することは知られていない。 The polarizer of the present invention is formed from a polyvinyl alcohol-based film and contains boron and potassium. The boron content in the polarizer is 4% by weight or more and 6% by weight or less, and the value obtained by multiplying the boron content (% by weight) by the potassium content (% by weight) is 1.2. That is all. Although it is known that the conventional polarizer contains boron and potassium, the polarizer of the present invention has higher heat resistance than the conventional polarizer by containing the above-mentioned specific amounts of boron and potassium. Can be made to. In particular, like the polarizer of the present invention, a polarizer having a value obtained by multiplying the boron content (% by weight) by the potassium content (% by weight) of 1.2 or more is more than a polarizer having less than that. However, it is not known to exhibit excellent heat resistance.
従来、偏光フィルムや積層偏光フィルムを、画像表示セルと透明板との間に粘着剤層を介して貼合することにより構成される画像表示装置が、高温環境下に曝された場合、偏光子や粘着剤層等に含まれる水分等が当該画像表示装置内に閉じ込められることにより、偏光子中のポリビニルアルコールの劣化（ポリエン化）が促進されるため、その光学特性の低下が顕著になる問題があったが、本発明の偏光子を用いれば、従前の偏光子よりも、ホウ素の含有量が多く、カリウムの含有量が少ないため、ホウ酸架橋により偏光子中のポリビニルアルコールの水酸基末端が保護（安定化）されていること、また、適量なカリウム含有率によって、偏光子中で対イオンとなるヨウ素イオンが安定化されていることから、上記のようなポリエン化を抑制できるものと推定される。 Conventionally, when an image display device configured by laminating a polarizing film or a laminated polarizing film between an image display cell and a transparent plate via an adhesive layer is exposed to a high temperature environment, a polarizing element is used. The problem is that the deterioration (polyene formation) of polyvinyl alcohol in the polarizer is promoted by confining moisture and the like contained in the pressure-sensitive adhesive layer and the like in the image display device, so that the optical characteristics thereof are significantly deteriorated. However, when the polarizer of the present invention is used, the content of boron is higher and the content of potassium is lower than that of the conventional polarizer. Therefore, the hydroxyl end of polyvinyl alcohol in the polarizer is formed by borate cross-linking. It is presumed that the above-mentioned polyene formation can be suppressed because it is protected (stabilized) and the iodine ion, which is the counter ion in the polarizer, is stabilized by the appropriate amount of potassium content. Will be done.
また、上記のような高温環境下に曝された画像表示装置では、偏光子がポリエン化によって劣化するほか、偏光子にクラックが発生する問題があった。当該クラックは、通常、偏光フィルム端部がベゼルで隠れるため、端部の外観不良は許容されるが、最近の画像表示装置では、デザイン性の観点から、ベゼルが薄型化さらにはベゼルレスのものまで製品化されている。よって、偏光フィルムの少しの端部不具合でも外観性を損なわせてしまうため、当該クラックを防止できることは、画像表示装置の製品化において非常に重要である。一方、本発明の偏光子は、上記の偏光子中の特定量のホウ素の含有量の上限値を、５．２重量％以下に調整することにより、上記のようなクラックの発生を防止できる効果を奏することができる。 Further, in the image display device exposed to the high temperature environment as described above, there is a problem that the polarizer is deteriorated by polyene formation and cracks are generated in the polarizer. Since the edge of the polarizing film is usually hidden by the bezel in the crack, poor appearance of the edge is tolerated. However, in recent image display devices, the bezel is thinned or even bezel-less from the viewpoint of design. It has been commercialized. Therefore, even a slight defect at the edge of the polarizing film impairs the appearance, and it is very important to prevent the cracks in the commercialization of the image display device. On the other hand, the polarizer of the present invention has the effect of preventing the occurrence of cracks as described above by adjusting the upper limit of the content of a specific amount of boron in the above-mentioned polarizer to 5.2% by weight or less. Can be played.
さらに、上記の画像表示装置において、透湿度の低い（例えば、透湿度が２００ｇ／（ｍ２・２４ｈ）以下である）透明保護フィルムが貼り合わせている偏光子を用いた場合、当該偏光子中の水分が透明保護フィルムを透過し難いため、当該水分が偏光子中により閉じ込められる結果、上記のようなポリエン化がより促進されることが推定される。よって、本発明の偏光子は、とくに、当該偏光子の少なくとも一方の面に透湿度の低い透明保護フィルムが貼り合わされている態様に有用である。Further, in the image display apparatus described above, a low moisture permeability in the case of using the (e.g., moisture permeability 200g / (m 2 · 24h) or less) polarizer transparent protective film is bonded, the polarizer in Since it is difficult for the moisture in the transparent protective film to permeate the transparent protective film, it is presumed that the moisture is trapped in the polarizer, and as a result, the above-mentioned polyene formation is further promoted. Therefore, the polarizer of the present invention is particularly useful in an embodiment in which a transparent protective film having low moisture permeability is attached to at least one surface of the polarizer.
＜偏光子＞
本発明の偏光子は、ポリビニルアルコール系フィルムから形成され、ホウ素およびカリウムを含み、前記偏光子中、前記ホウ素の含有量は４重量％以上６重量％以下であり、かつ前記ホウ素の含有量（重量％）に前記カリウムの含有量（重量％）を乗じた値は１．２以上である。<Polarizer>
The polarizer of the present invention is formed from a polyvinyl alcohol-based film, contains boron and potassium, and the content of the boron in the polarizer is 4% by weight or more and 6% by weight or less, and the content of the boron ( The value obtained by multiplying (% by weight) the content of potassium (% by weight) is 1.2 or more.
前記ポリビニルアルコール（ＰＶＡ）系フィルムは、可視光領域において透光性を有し、ヨウ素や二色性染料等の二色性物質を分散吸着するものを特に制限なく使用できる。また、通常、原反として用いる、ＰＶＡ系フィルムは、厚さが１０〜１００μｍ程度であることが好ましく、２０〜７５μｍ程度であることがより好ましく、幅が１００〜５０００ｍｍ程度であることが好ましい。 As the polyvinyl alcohol (PVA) -based film, a film having translucency in the visible light region and dispersing and adsorbing a dichroic substance such as iodine or a dichroic dye can be used without particular limitation. Further, the PVA-based film usually used as a raw material preferably has a thickness of about 10 to 100 μm, more preferably about 20 to 75 μm, and preferably a width of about 100 to 5000 mm.
前記ポリビニルアルコール系フィルムの材料としては、ポリビニルアルコールまたはその誘導体が挙げられる。前記ポリビニルアルコールの誘導体としては、例えば、ポリビニルホルマール、ポリビニルアセタール；エチレン、プロピレン等のオレフィン；アクリル酸、メタクリル酸、クロトン酸等の不飽和カルボン酸、およびそのアルキルエステル、アクリルアミド等で変性したもの等が挙げられる。前記ポリビニルアルコールは、平均重合度が１００〜１０，０００程度であることが好ましく、１，０００〜１０，０００程度であることがより好ましく、１，５００〜４，５００程度であることがさらに好ましい。また、前記ポリビニルアルコールは、ケン化度が８０〜１００モル％程度であることが好ましく、９５モル％〜９９．９５モル程度であることがより好ましい。なお、前記平均重合度および前記ケン化度は、ＪＩＳ Ｋ ６７２６に準じて求めることができる。 Examples of the material of the polyvinyl alcohol-based film include polyvinyl alcohol or a derivative thereof. Examples of the polyvinyl alcohol derivative include polyvinyl formal, polyvinyl acetal; olefins such as ethylene and propylene; unsaturated carboxylic acids such as acrylic acid, methacrylic acid and crotonic acid, and alkyl esters and acrylamides thereof. Can be mentioned. The polyvinyl alcohol preferably has an average degree of polymerization of about 100 to 10,000, more preferably about 1,000 to 10,000, and even more preferably about 1,500 to 4,500. .. Further, the polyvinyl alcohol preferably has a saponification degree of about 80 to 100 mol%, more preferably about 95 mol% to 99.95 mol%. The average degree of polymerization and the degree of saponification can be determined according to JIS K 6726.
前記ポリビニルアルコール系フィルムには、可塑剤や界面活性剤等の添加剤を含有していてもよい。前記可塑剤としては、例えば、グリセリン、ジグリセリン、トリグリセリン、エチレングリコール、プロピレングリコール、ポリエチレングリコール等の、ポリオールおよびその縮合物等が挙げられる。前記添加剤の使用量は、特に制限はないが、例えば、ポリビニルアルコール系フィルム中、２０重量％以下程度が好適である。 The polyvinyl alcohol-based film may contain additives such as a plasticizer and a surfactant. Examples of the plasticizer include polyols such as glycerin, diglycerin, triglycerin, ethylene glycol, propylene glycol, and polyethylene glycol, and condensates thereof. The amount of the additive used is not particularly limited, but is preferably about 20% by weight or less in the polyvinyl alcohol-based film, for example.
前記偏光子は、ホウ素およびカリウムを含み、前記偏光子中、前記ホウ素の含有量が４重量％以上６重量％以下であり、かつ前記ホウ素の含有量（重量％）に前記カリウムの含有量（重量％）を乗じた値が１．２以上である。なお、前記ホウ素の含有量（重量％）を「Ｂ」と定義し、前記カリウムの含有量（重量％）を「Ｋ」と定義した場合、前記ホウ素の含有量（重量％）に前記カリウムの含有量（重量％）を乗じた値が１．２以上は、「Ｂ×Ｋ≧１．２」と定義することもできる。 The polarizer contains boron and potassium, and the content of the boron in the polarizer is 4% by weight or more and 6% by weight or less, and the content of the potassium (% by weight) is added to the content of the potassium (% by weight). The value multiplied by (% by weight) is 1.2 or more. When the boron content (% by weight) is defined as "B" and the potassium content (% by weight) is defined as "K", the boron content (% by weight) of the potassium is defined as "K". A value multiplied by the content (% by weight) of 1.2 or more can also be defined as “B × K ≧ 1.2”.
前記偏光子中、前記ホウ素の含有量は、高温環境下における偏光子の光学特性の低下を抑制する観点から、４．０重量％以上であることが好ましく、４．２重量％以上であることがより好ましく、そして、高温環境下における偏光子のクラックの発生を抑制する観点から、５．２重量％以下であることが好ましく、５．０重量％以下であることがより好ましい。 The content of boron in the polarizer is preferably 4.0% by weight or more, preferably 4.2% by weight or more, from the viewpoint of suppressing deterioration of the optical characteristics of the polarizer in a high temperature environment. Is more preferable, and from the viewpoint of suppressing the occurrence of cracks in the polarizer in a high temperature environment, it is preferably 5.2% by weight or less, and more preferably 5.0% by weight or less.
前記偏光子中、前記カリウムの含有量は、高温環境下における偏光子の光学特性の低下を抑制する観点から、０．２８重量％以上であることが好ましく、０．３２重量％以上であることがより好ましく、０．３４重量％以上であることがさらに好ましく、そして、高温環境下における色相変化を抑制する観点から、０．６０重量％以下であることが好ましく、０．５５重量％以下であることがより好ましく、０．５０重量％以下であることがさらに好ましい。 The content of potassium in the polarizer is preferably 0.28% by weight or more, preferably 0.32% by weight or more, from the viewpoint of suppressing deterioration of the optical characteristics of the polarizer in a high temperature environment. Is more preferably 0.34% by weight or more, and from the viewpoint of suppressing a hue change in a high temperature environment, it is preferably 0.60% by weight or less, and 0.55% by weight or less. More preferably, it is more preferably 0.50% by weight or less.
前記偏光子中、前記ホウ素の含有量（重量％）に前記カリウムの含有量（重量％）を乗じた値（ホウ素の含有量（重量％）×カリウムの含有量（重量％））は高温環境下における偏光子の光学特性の低下を抑制する観点から、１．２以上であることが好ましく、１．３以上であることがより好ましく、１．４以上であることがさらに好ましく、そして、高温環境下における色相変化を抑制する観点から、３．５以下であることが好ましく、３．０以下であることがより好ましく、２．５以下であることがさらに好ましい。 In the polarizer, the value obtained by multiplying the boron content (% by weight) by the potassium content (% by weight) (boron content (% by weight) × potassium content (% by weight)) is a high temperature environment. From the viewpoint of suppressing the deterioration of the optical characteristics of the polarizer underneath, it is preferably 1.2 or more, more preferably 1.3 or more, further preferably 1.4 or more, and high temperature. From the viewpoint of suppressing the change in hue in the environment, it is preferably 3.5 or less, more preferably 3.0 or less, and further preferably 2.5 or less.
前記偏光子中、前記ホウ素の含有量（重量％）を前記カリウムの含有量（重量％）で除した値（ホウ素の含有量（重量％）÷カリウムの含有量（重量％））は、高温環境下における偏光子の光学特性の低下を抑制する観点から、５以上であることが好ましく、８以上であることがより好ましく、１０以上であることがさらに好ましく、そして、偏光子の初期色相を良好にする観点から、３０以下であることが好ましく、２５以下であることがより好ましく、２０以下であることがさらに好ましい。 In the polarizer, the value obtained by dividing the boron content (% by weight) by the potassium content (% by weight) (boron content (% by weight) ÷ potassium content (% by weight)) is a high temperature. From the viewpoint of suppressing deterioration of the optical properties of the polarizer in an environment, it is preferably 5 or more, more preferably 8 or more, further preferably 10 or more, and the initial hue of the polarizer. From the viewpoint of making it good, it is preferably 30 or less, more preferably 25 or less, and even more preferably 20 or less.
＜偏光子の製造方法＞
前記偏光子は、前記ポリビニルアルコール系フィルムに、染色工程、架橋工程、および延伸工程が施され、また、任意の工程として、膨潤工程、洗浄工程、および乾燥工程の少なくとも１つの処理工程が施されることにより得られる。前記偏光子中に含まれる前記ホウ素の含有量および前記カリウムの含有量は、膨潤工程、染色工程、架橋工程、延伸工程および洗浄工程における各処理浴のいずれかに含まれるホウ酸、ホウ酸塩、ホウ砂等のホウ素化合物等のホウ素成分供与物質の濃度およびヨウ化カリウム等のハロゲン化カリウム等のカリウム成分供与物質の濃度、上記の各処理浴による処理温度および処理時間によって制御できる。とくに、架橋工程および延伸工程は、ホウ素成分供与物質の濃度等の処理条件により、前記ホウ素の含有量の含有量を所望の範囲に調整し易い。また、洗浄工程は、染色工程、架橋工程、または延伸工程等で使用したホウ素成分供与物質やカリウム成分供与物質の使用量等の処理条件を考慮したうえで、ホウ素、カリウム等の成分をポリビニルアルコール系フィルムから溶出、あるいはポリビニルアルコール系フィルムに吸着させることができる観点から、前記ホウ素の含有量および前記カリウムの含有量を所望の範囲に調整し易い。<Manufacturing method of polarizer>
The polyvinyl alcohol-based film is subjected to a dyeing step, a crosslinking step, and a stretching step, and is optionally subjected to at least one treatment step of a swelling step, a washing step, and a drying step. Obtained by The content of the boron and the content of the potassium contained in the polarizer are the boric acid and the borate contained in any of the treatment baths in the swelling step, the dyeing step, the cross-linking step, the stretching step and the washing step. , Concentration of boron component donor such as boron compound such as borax, concentration of potassium component donor such as potassium iodide such as potassium iodide, treatment temperature and treatment time in each of the above treatment baths. In particular, in the cross-linking step and the stretching step, the content of the boron component can be easily adjusted to a desired range depending on the treatment conditions such as the concentration of the boron component donor substance. In the cleaning step, the components such as boron and potassium are made of polyvinyl alcohol in consideration of the treatment conditions such as the amount of the boron component donor and the potassium component donor used in the dyeing step, the crosslinking step, the stretching step, and the like. From the viewpoint that it can be eluted from the system film or adsorbed on the polyvinyl alcohol system film, it is easy to adjust the boron content and the potassium content to a desired range.
前記膨潤工程は、ポリビニルアルコール系フィルムを、膨潤浴中に浸漬する処理工程であり、ポリビニルアルコール系フィルムの表面の汚れやブロッキング剤等を除去でき、また、ポリビニルアルコール系フィルムを膨潤させることで染色ムラを抑制できる。前記膨潤浴は、通常、水、蒸留水、純水等の水を主成分とする媒体が用いられる。前記膨潤浴は、常法に従って、界面活性剤、アルコール等が適宜に添加されていてもよい。また、前記偏光子中の前記カリウムの含有量を制御する観点から、前記膨潤浴にヨウ化カリウムを使用してもよく、この場合、前記膨潤浴中、ヨウ化カリウムの濃度は、１．５重量％以下であることが好ましく、１．０重量％以下であることがより好ましく、０．５重量％以下であることがさらに好ましい。 The swelling step is a treatment step of immersing the polyvinyl alcohol-based film in a swelling bath, and can remove stains and blocking agents on the surface of the polyvinyl alcohol-based film, and dyes by swelling the polyvinyl alcohol-based film. Unevenness can be suppressed. As the swelling bath, a medium containing water as a main component, such as water, distilled water, and pure water, is usually used. A surfactant, alcohol, or the like may be appropriately added to the swelling bath according to a conventional method. Further, from the viewpoint of controlling the content of the potassium in the polarizer, potassium iodide may be used in the swelling bath, and in this case, the concentration of potassium iodide in the swelling bath is 1.5. It is preferably 0% by weight or less, more preferably 1.0% by weight or less, and further preferably 0.5% by weight or less.
前記膨潤浴の温度は、１０〜６０℃程度であることが好ましく、１５〜４５℃程度であることがより好ましく、１８〜３０℃程度であることがさらに好ましい。また、前記膨潤浴への浸漬時間は、ポリビニルアルコール系フィルムの膨潤の程度が膨潤浴の温度の影響を受けるため一概に決定できないが、５〜３００秒間程度であることが好ましく、１０〜２００秒間程度であることがより好ましく、２０〜１００秒間程度であることがさらに好ましい。前記膨潤工程は１回だけ実施されてもよく、必要に応じて複数回実施されてもよい。 The temperature of the swelling bath is preferably about 10 to 60 ° C, more preferably about 15 to 45 ° C, and even more preferably about 18 to 30 ° C. The immersion time in the swelling bath cannot be unconditionally determined because the degree of swelling of the polyvinyl alcohol-based film is affected by the temperature of the swelling bath, but is preferably about 5 to 300 seconds, preferably 10 to 200 seconds. It is more preferably about 20 to 100 seconds. The swelling step may be carried out only once, or may be carried out a plurality of times as needed.
前記染色工程は、ポリビニルアルコール系フィルムを、染色浴（ヨウ素溶液）に浸漬する処理工程であり、ポリビニルアルコール系フィルムに、ヨウ素または二色性染料等の二色性物質を吸着・配向させることができる。前記ヨウ素溶液は、通常、ヨウ素水溶液であることが好ましく、ヨウ素および溶解助剤としてヨウ化物を含有する。なお、前記ヨウ化物としては、ヨウ化カリウム、ヨウ化リチウム、ヨウ化ナトリウム、ヨウ化亜鉛、ヨウ化アルミニウム、ヨウ化鉛、ヨウ化銅、ヨウ化バリウム、ヨウ化カルシウム、ヨウ化錫、ヨウ化チタン等が挙げられる。これらの中でも、前記偏光子中の前記カリウムの含有量を制御する観点から、ヨウ化カリウムが好適である。 The dyeing step is a treatment step of immersing the polyvinyl alcohol-based film in a dyeing bath (iodine solution), and adsorbing and orienting a dichroic substance such as iodine or a dichroic dye on the polyvinyl alcohol-based film. it can. The iodine solution is usually preferably an aqueous iodine solution and contains iodine and iodide as a solubilizing agent. The iodide includes potassium iodide, lithium iodide, sodium iodide, zinc iodide, aluminum iodide, lead iodide, copper iodide, barium iodide, calcium iodide, tin iodide, and iodide. Examples include titanium. Among these, potassium iodide is preferable from the viewpoint of controlling the content of the potassium in the polarizer.
前記染色浴中、ヨウ素の濃度は、０．０１〜１重量％程度であることが好ましく、０．０２〜０．５重量％程度であることがより好ましい。前記染色浴中、前記ヨウ化物の濃度は、０．０１〜１０重量％程度であることが好ましく、０．０５〜５重量％程度であることがより好ましく、０．１〜３重量％程度であることがさらに好ましい。 In the dyeing bath, the iodine concentration is preferably about 0.01 to 1% by weight, more preferably about 0.02 to 0.5% by weight. In the dyeing bath, the concentration of the iodide is preferably about 0.01 to 10% by weight, more preferably about 0.05 to 5% by weight, and about 0.1 to 3% by weight. It is more preferable to have.
前記染色浴の温度は、１０〜５０℃程度であることが好ましく、１５〜４５℃程度であることがより好ましく、１８〜３０℃程度であることがさらに好ましい。また、前記染色浴への浸漬時間は、ポリビニルアルコール系フィルムの染色の程度が染色浴の温度の影響を受けるため一概に決定できないが、１０〜３００秒間程度であることが好ましく、２０〜２４０秒間程度であることがより好ましい。前記染色工程は１回だけ実施されてもよく、必要に応じて複数回実施されてもよい。 The temperature of the dyeing bath is preferably about 10 to 50 ° C., more preferably about 15 to 45 ° C., and even more preferably about 18 to 30 ° C. The immersion time in the dyeing bath cannot be unconditionally determined because the degree of dyeing of the polyvinyl alcohol-based film is affected by the temperature of the dyeing bath, but is preferably about 10 to 300 seconds, preferably about 20 to 240 seconds. More preferably. The dyeing step may be carried out only once, or may be carried out a plurality of times as needed.
前記架橋工程は、前記染色工程にて染色されたポリビニルアルコール系フィルムを、ホウ素化合物を含む処理浴（架橋浴）中に浸漬する処理工程であり、ホウ素化合物によりポリビニルアルコール系フィルムが架橋して、ヨウ素分子または染料分子が当該架橋構造に吸着できる。前記ホウ素化合物としては、例えば、ホウ酸、ホウ酸塩、ホウ砂等が挙げられる。前記架橋浴は、水溶液が一般的であるが、例えば、水との混和性のある有機溶媒および水の混合溶液であってもよい。また、前記架橋浴は、前記偏光子中の前記カリウムの含有量を制御する観点から、ヨウ化カリウムを含むことが好ましい。 The cross-linking step is a treatment step of immersing the polyvinyl alcohol-based film dyed in the dyeing step in a treatment bath (cross-linking bath) containing a boron compound, and the polyvinyl alcohol-based film is cross-linked by the boron compound. Iodine molecules or dye molecules can be adsorbed on the crosslinked structure. Examples of the boron compound include boric acid, borate, borax and the like. The cross-linked bath is generally an aqueous solution, but may be, for example, a mixed solution of an organic solvent and water that is miscible with water. Further, the crosslinked bath preferably contains potassium iodide from the viewpoint of controlling the content of the potassium in the polarizer.
前記架橋浴中、前記ホウ素化合物の濃度は、１〜１５重量％程度であることが好ましく、１．５〜１０重量％程度であることがより好ましく、２〜５重量％程度であることがより好ましい。また、前記架橋浴にヨウ化カリウムを使用する場合、前記架橋浴中、ヨウ化カリウムの濃度は、１〜１５重量％程度であることが好ましく、１．５〜１０重量％程度であることがより好ましく、２〜５重量％程度であることがより好ましい。 In the crosslinked bath, the concentration of the boron compound is preferably about 1 to 15% by weight, more preferably about 1.5 to 10% by weight, and more preferably about 2 to 5% by weight. preferable. When potassium iodide is used in the cross-linking bath, the concentration of potassium iodide in the cross-linking bath is preferably about 1 to 15% by weight, preferably about 1.5 to 10% by weight. More preferably, it is about 2 to 5% by weight.
前記架橋浴の温度は、２０〜７０℃程度であることが好ましく、３０〜６０℃程度であることがより好ましい。また、前記架橋浴への浸漬時間は、ポリビニルアルコール系フィルムの架橋の程度が架橋浴の温度の影響を受けるため一概に決定できないが、５〜３００秒間程度であることが好ましく、１０〜２００秒間程度であることがより好ましい。前記架橋工程は１回だけ実施されてもよく、必要に応じて複数回実施されてもよい。 The temperature of the cross-linking bath is preferably about 20 to 70 ° C, more preferably about 30 to 60 ° C. The immersion time in the cross-linking bath cannot be unconditionally determined because the degree of cross-linking of the polyvinyl alcohol-based film is affected by the temperature of the cross-linking bath, but is preferably about 5 to 300 seconds, preferably 10 to 200 seconds. More preferably. The cross-linking step may be carried out only once, or may be carried out a plurality of times as needed.
前記延伸工程は、ポリビニルアルコール系フィルムを、少なくとも一方向に所定の倍率に延伸する処理工程である。一般には、ポリビニルアルコール系フィルムを、搬送方向（長手方向）に１軸延伸する。前記延伸の方法は特に制限されず、湿潤延伸法と乾式延伸法のいずれも採用できる。前記延伸工程は１回だけ実施されてもよく、必要に応じて複数回実施されてもよい。前記延伸工程は、偏光子の製造において、いずれの段階で行われてもよい。 The stretching step is a treatment step of stretching a polyvinyl alcohol-based film to a predetermined magnification in at least one direction. Generally, the polyvinyl alcohol-based film is uniaxially stretched in the transport direction (longitudinal direction). The stretching method is not particularly limited, and either a wet stretching method or a dry stretching method can be adopted. The stretching step may be carried out only once, or may be carried out a plurality of times as needed. The stretching step may be performed at any stage in the production of the polarizer.
前記湿潤延伸法における処理浴（延伸浴）は、通常、水、または水との混和性のある有機溶媒および水の混合溶液等の溶媒を用いることができる。前記延伸浴は、前記偏光子中の前記カリウムの含有量を制御する観点から、ヨウ化カリウムを含むことが好ましい。前記延伸浴にヨウ化カリウムを使用する場合、当該延伸浴中、ヨウ化カリウムの濃度は、１〜１５重量％程度であることが好ましく、２〜１０重量％程度であることがより好ましく、３〜６重量％程度であることがより好ましい。また、前記処理浴（延伸浴）には、延伸中のフィルム破断を抑制する観点から、前記ホウ素化合物を含むことができ、この場合、当該延伸浴中、前記ホウ素化合物の濃度は、１〜１５重量％程度であることが好ましく、１．５〜１０重量％程度であることがより好ましく、２〜５重量％程度であることがより好ましい。 As the treatment bath (stretching bath) in the wet stretching method, a solvent such as water or a mixed solution of water and an organic solvent miscible with water can be usually used. The stretching bath preferably contains potassium iodide from the viewpoint of controlling the content of the potassium in the polarizer. When potassium iodide is used in the stretching bath, the concentration of potassium iodide in the stretching bath is preferably about 1 to 15% by weight, more preferably about 2 to 10% by weight, and 3 More preferably, it is about 6% by weight. Further, the treatment bath (stretching bath) can contain the boron compound from the viewpoint of suppressing film breakage during stretching. In this case, the concentration of the boron compound in the stretching bath is 1 to 15. It is preferably about% by weight, more preferably about 1.5 to 10% by weight, and even more preferably about 2 to 5% by weight.
前記延伸浴の温度は、２５〜８０℃程度であることが好ましく、４０〜７５℃程度であることがより好ましく、５０〜７０℃程度であることがさらに好ましい。また、前記延伸浴への浸漬時間は、ポリビニルアルコール系フィルムの延伸の程度が延伸浴の温度の影響を受けるため一概に決定できないが、１０〜８００秒間程度であることが好ましく、３０〜５００秒間程度であることがより好ましい。なお、前記湿潤延伸法における延伸処理は、前記膨潤工程、前記染色工程、前記架橋工程、および前記洗浄工程のいずれか１つ以上の処理工程とともに施してもよい。 The temperature of the stretching bath is preferably about 25 to 80 ° C, more preferably about 40 to 75 ° C, and even more preferably about 50 to 70 ° C. The immersion time in the stretching bath cannot be unconditionally determined because the degree of stretching of the polyvinyl alcohol-based film is affected by the temperature of the stretching bath, but is preferably about 10 to 800 seconds, preferably about 30 to 500 seconds. More preferably. The stretching treatment in the wet stretching method may be performed together with any one or more of the swelling step, the dyeing step, the cross-linking step, and the washing step.
前記乾式延伸法としては、例えば、ロール間延伸方法、加熱ロール延伸方法、圧縮延伸方法等が挙げられる。なお、前記乾式延伸法は、前記乾燥工程とともに施してもよい。 Examples of the dry stretching method include an inter-roll stretching method, a heating roll stretching method, and a compression stretching method. The dry stretching method may be performed together with the drying step.
前記ポリビニルアルコール系フィルムに施される総延伸倍率（累積の延伸倍率）は、目的に応じ適宜設定できるが、２〜７倍程度であることが好ましく、３〜６．８倍程度であることがより好ましく、３．５〜６．５倍程度であることがさらに好ましい。 The total draw ratio (cumulative draw ratio) applied to the polyvinyl alcohol-based film can be appropriately set depending on the intended purpose, but is preferably about 2 to 7 times, and preferably about 3 to 6.8 times. More preferably, it is about 3.5 to 6.5 times.
前記洗浄工程は、ポリビニルアルコール系フィルムを、洗浄浴中に浸漬する処理工程であり、ポリビニルアルコール系フィルムの表面等に残存する異物を除去できる。前記洗浄浴は、通常、水、蒸留水、純水等の水を主成分とする媒体が用いられる。また、前記偏光子中の前記カリウムの含有量を制御する観点から、前記洗浄浴にヨウ化カリウムを使用することが好ましく、この場合、前記洗浄浴中、ヨウ化カリウムの濃度は、１〜１０重量％程度であることが好ましく、１．５〜４重量％程度であることがより好ましく、１．８〜３．８重量％程度であることがさらに好ましい。 The cleaning step is a treatment step of immersing the polyvinyl alcohol-based film in a washing bath, and can remove foreign substances remaining on the surface of the polyvinyl alcohol-based film or the like. As the washing bath, a medium containing water as a main component, such as water, distilled water, and pure water, is usually used. Further, from the viewpoint of controlling the content of the potassium in the polarizer, it is preferable to use potassium iodide in the washing bath. In this case, the concentration of potassium iodide in the washing bath is 1 to 10. It is preferably about% by weight, more preferably about 1.5 to 4% by weight, and even more preferably about 1.8 to 3.8% by weight.
前記洗浄浴の温度は、５〜５０℃程度であることが好ましく、１０〜４０℃程度であることがより好ましく、１５〜３０℃程度であることがさらに好ましい。また、前記洗浄浴への浸漬時間は、ポリビニルアルコール系フィルムの洗浄の程度が洗浄浴の温度の影響を受けるため一概に決定できないが、１〜１００秒間程度であることが好ましく、２〜５０秒間程度であることがより好ましく、３〜２０秒間程度であることがさらに好ましい。前記膨潤工程は１回だけ実施されてもよく、必要に応じて複数回実施されてもよい。 The temperature of the washing bath is preferably about 5 to 50 ° C., more preferably about 10 to 40 ° C., and even more preferably about 15 to 30 ° C. The immersion time in the washing bath cannot be unconditionally determined because the degree of washing of the polyvinyl alcohol-based film is affected by the temperature of the washing bath, but is preferably about 1 to 100 seconds, preferably 2 to 50 seconds. It is more preferably about 3 to 20 seconds. The swelling step may be carried out only once, or may be carried out a plurality of times as needed.
前記乾燥工程は、前記洗浄工程にて洗浄されたポリビニルアルコール系フィルムを、乾燥して偏光子を得る工程であり、乾燥により所望の水分率を有する偏光子が得られる。前記乾燥は、任意の適切な方法で行われ、例えば、自然乾燥、送風乾燥、加熱乾燥が挙げられる。前記偏光子は、水分率が８〜２５重量％程度であることが好ましく、１２〜２０重量％程度であることがより好ましい。なお、偏光子の水分率は、１００ｍｍ角のサイズに切り出された試料の、初期重量、および１２０℃で２時間乾燥後の乾燥重量に基づいて、下記式により算出される。
水分率（重量％）＝｛（初期重量−乾燥重量）／初期重量｝×１００The drying step is a step of drying the polyvinyl alcohol-based film washed in the washing step to obtain a polarizer, and drying obtains a polarizer having a desired moisture content. The drying is carried out by any suitable method, and examples thereof include natural drying, blast drying, and heat drying. The polarizer preferably has a water content of about 8 to 25% by weight, more preferably about 12 to 20% by weight. The water content of the polarizer is calculated by the following formula based on the initial weight of the sample cut into a size of 100 mm square and the dry weight after drying at 120 ° C. for 2 hours.
Moisture content (% by weight) = {(initial weight-dry weight) / initial weight} x 100
前記乾燥の温度は、２０〜１５０℃程度であることが好ましく、２５〜１００℃程度であることがより好ましい。また、前記乾燥の時間は、偏光子の乾燥の程度が乾燥の温度の影響を受けるため一概に決定できないが、３０〜６００秒間程度であることが好ましく、６０〜３００秒間程度であることがより好ましい。前記乾燥工程は１回だけ実施されてもよく、必要に応じて複数回実施されてもよい。 The drying temperature is preferably about 20 to 150 ° C, more preferably about 25 to 100 ° C. The drying time cannot be unconditionally determined because the degree of drying of the polarizer is affected by the drying temperature, but is preferably about 30 to 600 seconds, more preferably about 60 to 300 seconds. preferable. The drying step may be carried out only once, or may be carried out a plurality of times as needed.
前記偏光子は、厚みが、１０〜３０μｍ程度であることが好ましく、１２〜２０μｍ程度であることがより好ましい。 The polarizer preferably has a thickness of about 10 to 30 μm, and more preferably about 12 to 20 μm.
＜偏光フィルム＞
本発明の偏光フィルムは、前記偏光子の少なくとも一方の面に透明保護フィルムが貼り合わされているものである。<Polarizing film>
The polarizing film of the present invention is one in which a transparent protective film is bonded to at least one surface of the polarizing element.
前記透明保護フィルムは、特に制限されず、従来より偏光フィルムに用いられている各種の透明保護フィルムを用いることができる。前記透明保護フィルムを構成する材料としては、例えば、透明性、機械的強度、熱安定性、水分遮断性、等方性等に優れる熱可塑性樹脂が用いられる。前記熱可塑性樹脂としては、例えば、トリアセチルセルロール等のセルロールエステル系樹脂、ポリエチレンテレフタレートやポリエチレンナフタレート等のポリエステル系樹脂、ポリエーテルスルホン系樹脂、ポリスルホン系樹脂、ポリカーボネート系樹脂、ナイロンや芳香族ポリアミド等のポリアミド系樹脂、ポリイミド系樹脂、ポリエチレン、ポリプロピレン、エチレン・プロピレン共重合体の如きポリオレフィン系樹脂、（メタ）アクリル系樹脂、シクロ系ないしはノルボルネン構造を有する環状ポリオレフィン系樹脂（ノルボルネン系樹脂）、ポリアリレート系樹脂、ポリスチレン系樹脂、ポリビニルアルコール系樹脂、およびこれらの混合物があげられる。また、前記透明保護フィルムは、（メタ）アクリル系、ウレタン系、アクリルウレタン系、エポキシ系、シリコーン系等の熱硬化性樹脂または紫外線硬化型樹脂から形成される硬化層を用いることができる。これらの中でも、セルロールエステル系樹脂、ポリカーボネート系樹脂、（メタ）アクリル系樹脂、環状ポリオレフィン系樹脂、ポリエステル系樹脂が好適である。 The transparent protective film is not particularly limited, and various transparent protective films conventionally used for polarizing films can be used. As the material constituting the transparent protective film, for example, a thermoplastic resin having excellent transparency, mechanical strength, thermal stability, moisture blocking property, isotropic property and the like is used. Examples of the thermoplastic resin include cell roll ester resins such as triacetyl cell rolls, polyester resins such as polyethylene terephthalate and polyethylene naphthalate, polyether sulfone resins, polysulfone resins, polycarbonate resins, nylon and fragrances. Polyamide-based resin such as group polyamide, polyimide-based resin, polyethylene, polypropylene, polyolefin-based resin such as ethylene / propylene copolymer, (meth) acrylic-based resin, cyclic polyolefin-based resin having cyclo-based or norbornene structure (norbornene-based resin) ), Polyallylate-based resin, polystyrene-based resin, polyvinyl alcohol-based resin, and mixtures thereof. Further, as the transparent protective film, a cured layer formed of a thermosetting resin such as (meth) acrylic, urethane, acrylic urethane, epoxy, silicone or the like or an ultraviolet curable resin can be used. Among these, cell roll ester-based resins, polycarbonate-based resins, (meth) acrylic-based resins, cyclic polyolefin-based resins, and polyester-based resins are preferable.
前記透明保護フィルムの厚さは、適宜に決定しうるが、一般には強度や取扱性等の作業性、薄層性等の観点から、１〜５００μｍ程度であることが好ましく、１〜３００μｍ程度あることがより好ましく、５〜１００μｍ程度であることがさらに好ましい。また、前記透明保護フィルムの厚さは、当該透明保護フィルムの透湿度を低下させる観点から、１０〜１００μｍ程度であることが好ましく、２０〜１００μｍ程度あることがより好ましく、３０〜１００μｍ程度であることがさらに好ましい。 The thickness of the transparent protective film can be appropriately determined, but in general, it is preferably about 1 to 500 μm, preferably about 1 to 300 μm, from the viewpoint of workability such as strength and handleability, and thin layer property. More preferably, it is more preferably about 5 to 100 μm. The thickness of the transparent protective film is preferably about 10 to 100 μm, more preferably about 20 to 100 μm, and more preferably about 30 to 100 μm from the viewpoint of reducing the moisture permeability of the transparent protective film. Is even more preferable.
前記透明保護フィルムは、高温多湿環境下での偏光性能の低下を抑制する観点から、透湿度が８００ｇ／（ｍ２・２４ｈ）以下であることが好ましく、４００ｇ／（ｍ２・２４ｈ）以下であることがより好ましく、２００ｇ／（ｍ２・２４ｈ）以下であることがさらに好ましく、１５０ｇ／（ｍ２・２４ｈ）以下であることがよりさらに好ましい。前記偏光子の片面の透明保護フィルムは、透湿度が２００ｇ／（ｍ２・２４ｈ）以下であることが好ましく、１５０ｇ／（ｍ２・２４ｈ）以下であることがより好ましい。なお、透湿度は、ＪＩＳ Ｚ０２０８の透湿度試験（カップ法）に準じ、直径６０ｍｍに切断したサンプルを約１５ｇの塩化カルシウムを入れた透湿カップにセットし、温度４０℃、湿度９０％Ｒ．Ｈ．の恒温機に入れ、２４時間放置した前後の塩化カルシウムの重量増加を測定することで算出できる。The transparent protective film, from the viewpoint of suppressing the deterioration of polarization performance under high temperature and high humidity environment, moisture is preferably humidity is 800g / (m 2 · 24h) or less, 400g / (m 2 · 24h ) or less more preferably in, still more preferably 200g / (m 2 · 24h) or less, and still further preferably at 150g / (m 2 · 24h) or less. The transparent protective film of the one surface of the polarizer is preferably moisture permeability is 200g / (m 2 · 24h) or less, more preferably 150g / (m 2 · 24h) or less. For the humidity permeability, according to the moisture permeability test (cup method) of JIS Z0208, a sample cut to a diameter of 60 mm was set in a moisture permeability cup containing about 15 g of calcium chloride, and the temperature was 40 ° C. and the humidity was 90%. H. It can be calculated by measuring the weight increase of calcium chloride before and after being placed in a constant temperature machine and left for 24 hours.
前記透明保護フィルムを、前記偏光子の両面に貼り合わせる場合、その両面の透明保護フィルムは、同じものであってもよく、異なっていてもよい。 When the transparent protective film is attached to both sides of the polarizer, the transparent protective films on both sides may be the same or different.
前記透明保護フィルムは、正面位相差が４０ｎｍ以上および／または、厚み方向位相差が８０ｎｍ以上の位相差を有する位相差板を用いることができる。正面位相差は、通常、４０〜２００ｎｍの範囲に、厚み方向位相差は、通常、８０〜３００ｎｍの範囲に制御される。前記透明保護フィルムとして位相差板を用いる場合には、当該位相差板が透明保護フィルムとしても機能するため、薄型化を図ることができる。 As the transparent protective film, a retardation plate having a front retardation of 40 nm or more and / or a thickness direction retardation of 80 nm or more can be used. The front phase difference is usually controlled in the range of 40 to 200 nm, and the thickness direction phase difference is usually controlled in the range of 80 to 300 nm. When a retardation plate is used as the transparent protective film, the retardation plate also functions as a transparent protective film, so that the thickness can be reduced.
前記位相差板としては、例えば、高分子素材を一軸または二軸延伸処理してなる複屈折性フィルム、液晶ポリマーの配向フィルム、液晶ポリマーの配向層をフィルムにて支持したもの等が挙げられる。位相差板の厚さは特に制限されないが、２０〜１５０μｍ程度が一般的である。なお、位相差を有しない透明保護フィルムに前記位相板を貼り合わせて使用してもよい。 Examples of the retardation plate include a birefringent film formed by uniaxially or biaxially stretching a polymer material, an alignment film of a liquid crystal polymer, and a film in which an alignment layer of a liquid crystal polymer is supported by a film. The thickness of the retardation plate is not particularly limited, but is generally about 20 to 150 μm. The phase plate may be attached to a transparent protective film having no phase difference.
前記透明保護フィルムは、表面改質処理が施されていてもよい。前記表面改質処理としては、例えば、コロナ処理、プラズマ処理、プライマー処理、ケン化処理等が挙げられる。 The transparent protective film may be subjected to a surface modification treatment. Examples of the surface modification treatment include corona treatment, plasma treatment, primer treatment, saponification treatment and the like.
前記透明保護フィルムの偏光子を貼り合わせない面には、ハードコート処理や反射防止処理、スティッキング防止や、拡散ないしアンチグレアを目的とした処理を施したものであってもよい。なお、ハードコート処理や反射防止層、スティッキング防止層、拡散層ないしアンチグレアを目的とした処理等は、透明保護フィルムそのものに設けることができるほか、別途光学層として透明保護フィルムとは別体のものとして設けることもできる。 The surface of the transparent protective film to which the polarizer is not bonded may be subjected to a hard coat treatment, an antireflection treatment, a sticking prevention treatment, and a treatment for the purpose of diffusion or antiglare. The hard coat treatment, antireflection layer, sticking prevention layer, diffusion layer, antiglare treatment, etc. can be provided on the transparent protective film itself, or as an optical layer separate from the transparent protective film. It can also be provided as.
前記透明保護フィルムには、紫外線吸収剤、酸化防止剤、滑剤、可塑剤、離型剤、着色防止剤、難燃剤、帯電防止剤、顔料、着色剤等の任意の適切な添加剤を含んでいてもよい。 The transparent protective film contains any suitable additives such as UV absorbers, antioxidants, lubricants, plasticizers, mold release agents, color inhibitors, flame retardants, antistatic agents, pigments, colorants and the like. You may.
前記偏光子と前記透明保護フィルムとの貼り合わせるためには、通常、接着剤が用いられる。前記接着剤としては、例えば、イソシアネート系接着剤、ポリビニルアルコール系接着剤、ゼラチン系接着剤、ビニル系ラテックス系、水系ポリエステル等が挙げられる。前記接着剤は、通常、水溶液からなる接着剤として用いられ、通常、０．５〜６０重量％の固形分を含有してなる。前記接着剤としては、上記の他、紫外線硬化型接着剤、電子線硬化型接着剤等が挙げられる。また、前記接着剤には、金属化合物フィラー等を含有させることができる。 An adhesive is usually used to bond the polarizer to the transparent protective film. Examples of the adhesive include isocyanate-based adhesives, polyvinyl alcohol-based adhesives, gelatin-based adhesives, vinyl-based latex-based adhesives, and water-based polyesters. The adhesive is usually used as an adhesive consisting of an aqueous solution, and usually contains 0.5 to 60% by weight of a solid content. In addition to the above, examples of the adhesive include an ultraviolet curable adhesive, an electron beam curable adhesive, and the like. Further, the adhesive may contain a metal compound filler or the like.
前記接着剤の塗布は、前記透明保護フィルム、前記偏光子のいずれに行ってもよく、両者に行ってもよい。貼り合わせ後には、乾燥工程を施し、塗布乾燥層からなる接着剤層を形成する。前記偏光子と前記透明保護フィルムの貼り合わせは、ロールラミネーター等により行うことができる。前記乾燥工程の後には、必要に応じ、紫外線や電子線を照射することができる。前記接着剤層の厚さは、特に制限されないが、３０〜５０００ｎｍ程度であることが好ましく、１００〜１０００ｎｍ程度であることがより好ましい。 The application of the adhesive may be applied to either the transparent protective film or the polarizer, or both. After bonding, a drying step is performed to form an adhesive layer composed of a coating and drying layer. The polarizing element and the transparent protective film can be bonded to each other by a roll laminator or the like. After the drying step, ultraviolet rays or electron beams can be irradiated if necessary. The thickness of the adhesive layer is not particularly limited, but is preferably about 30 to 5000 nm, and more preferably about 100 to 1000 nm.
＜積層偏光フィルム＞
本発明の積層偏光フィルム（光学積層体）は、前記偏光フィルムが光学層に貼り合わされているものである。前記光学層は特に限定はないが、例えば、反射板や半透過板、位相差板（１／２や１／４等の波長板を含む）、視角補償フィルム等の液晶表示装置等の形成に用いられることのある光学層を１層または２層以上用いることができる。前記積層偏光フィルムとしては、特に、前記偏光フィルムに更に反射板または半透過反射板が積層されてなる反射型偏光フィルムまたは半透過型偏光フィルム、前記偏光フィルムに更に位相差板が積層されてなる楕円偏光フィルムまたは円偏光フィルム、前記偏光フィルムに更に視角補償フィルムが積層されてなる広視野角偏光フィルム、あるいは前記偏光フィルムに更に輝度向上フィルムが積層されてなる偏光フィルムが挙げられる。<Laminated polarizing film>
The laminated polarizing film (optical laminate) of the present invention is one in which the polarizing film is bonded to an optical layer. The optical layer is not particularly limited, but is used for forming, for example, a reflector, a transflective plate, a retardation plate (including a wave plate such as 1/2 or 1/4), a liquid crystal display device such as a viewing angle compensation film, or the like. One or two or more optical layers that may be used can be used. The laminated polarizing film is particularly a reflective polarizing film or a semi-transmissive polarizing film in which a reflecting plate or a semi-transmissive reflecting plate is further laminated on the polarizing film, and a retardation plate is further laminated on the polarizing film. Examples thereof include an elliptically polarizing film or a circularly polarizing film, a wide viewing angle polarizing film in which a viewing angle compensating film is further laminated on the polarizing film, and a polarizing film in which a brightness improving film is further laminated on the polarizing film.
前記偏光フィルム、あるいは前記積層偏光フィルムの一方の面あるいは両方の面には、液晶セルや有機ＥＬ素子等の画像表示セルと、視認側における前面透明板やタッチパネル等の透明板等の他の部材を貼り合わせるための接着剤層が付設されてもよい。当該接着剤層としては、粘着剤層が好適である。前記粘着剤層を形成する粘着剤は特に制限されないが、例えば、アクリル系重合体、シリコーン系ポリマー、ポリエステル、ポリウレタン、ポリアミド、ポリエーテル、フッ素系やゴム系等のポリマーをベースポリマーとするものを適宜に選択して用いることができる。特に、アクリル系重合体を含む粘着剤のように、光学的透明性に優れ、適度な濡れ性と凝集性と接着性を示し、耐候性や耐熱性等に優れるものが好ましく用いられる。 On one surface or both surfaces of the polarizing film or the laminated polarizing film, an image display cell such as a liquid crystal cell or an organic EL element and another member such as a front transparent plate or a transparent plate such as a touch panel on the viewing side An adhesive layer for bonding the two may be attached. As the adhesive layer, an adhesive layer is suitable. The pressure-sensitive adhesive forming the pressure-sensitive adhesive layer is not particularly limited, and for example, those using a polymer such as an acrylic polymer, a silicone-based polymer, a polyester, a polyurethane, a polyamide, a polyether, a fluorine-based polymer, or a rubber-based polymer as a base polymer are used. It can be appropriately selected and used. In particular, a pressure-sensitive adhesive containing an acrylic polymer, which has excellent optical transparency, exhibits appropriate wettability, cohesiveness, and adhesiveness, and has excellent weather resistance, heat resistance, and the like is preferably used.
前記粘着剤層は、アクリル酸等の有機酸モノマーの含有量が低いことが好ましい。粘着剤層中の有機酸モノマー含有量を低くすることで、画像表示装置が高温環境に曝された場合でも、ポリビニルアルコールのポリエン化による透過率の低下が抑制される。 The pressure-sensitive adhesive layer preferably has a low content of an organic acid monomer such as acrylic acid. By lowering the content of the organic acid monomer in the pressure-sensitive adhesive layer, the decrease in transmittance due to polyeneization of polyvinyl alcohol is suppressed even when the image display device is exposed to a high temperature environment.
前記偏光フィルムや前記積層偏光フィルムの片面又は両面への粘着剤層の付設は、適宜な方式で行いうる。粘着剤層の付設としては、例えば、粘着剤溶液を調製し、それを流延方式や塗布方式等の適宜な展開方式で前記偏光フィルムや前記積層偏光フィルム上に直接付設する方式、あるいは、セパレータ上に粘着剤層を形成して、それを前記偏光フィルムや前記積層偏光フィルム上に移着する方式等が挙げられる。前記粘着剤層の厚さは、使用目的や接着力等に応じて適宜に決定でき、一般には１〜５００μｍであり、５〜２００μｍであることが好ましく、１０〜１００μｍであることがより好ましい。 The pressure-sensitive adhesive layer may be attached to one side or both sides of the polarizing film or the laminated polarizing film by an appropriate method. As the attachment of the pressure-sensitive adhesive layer, for example, a method of preparing a pressure-sensitive adhesive solution and directly attaching the pressure-sensitive adhesive solution onto the polarizing film or the laminated polarizing film by an appropriate development method such as a casting method or a coating method, or a separator. Examples thereof include a method in which an adhesive layer is formed on the polarizing film and the adhesive layer is transferred onto the polarizing film or the laminated polarizing film. The thickness of the pressure-sensitive adhesive layer can be appropriately determined according to the purpose of use, adhesive strength, etc., and is generally 1 to 500 μm, preferably 5 to 200 μm, and more preferably 10 to 100 μm.
前記粘着剤層の露出面に対しては、実用に供するまでの間、その汚染防止等を目的にセパレータが仮着されてカバーされることが好ましい。これにより、通例の取扱状態で粘着剤層の汚染等が防止できる。前記セパレータとしては、例えば、プラスチックフィルム、ゴムシート、紙、布、不織布、ネット、発泡シートや金属箔、それらのラミネート体等の適宜な薄葉体を、必要に応じシリコーン系や長鎖アルキル系、フッ素系や硫化モリブデン等の適宜な剥離剤でコート処理したもの等が用いられる。 It is preferable that the exposed surface of the pressure-sensitive adhesive layer is temporarily covered with a separator for the purpose of preventing contamination or the like until it is put into practical use. As a result, contamination of the adhesive layer can be prevented under normal handling conditions. As the separator, for example, an appropriate thin leaf such as a plastic film, a rubber sheet, a paper, a cloth, a non-woven fabric, a net, a foam sheet or a metal foil, or a laminate thereof, and if necessary, a silicone-based or long-chain alkyl-based separator. Those coated with an appropriate release agent such as fluorine-based or molybdenum sulfide are used.
＜画像表示パネルおよび画像表示装置＞
本発明の画像表示パネルは、画像表示セルに、前記偏光フィルム、または前記積層偏光フィルムが貼り合わされているものである。また、本発明の画像表示装置は、前記画像表示パネルの偏光フィルムまたは積層偏光フィルム側（視認側）に、透明板を備えるものである。<Image display panel and image display device>
In the image display panel of the present invention, the polarizing film or the laminated polarizing film is attached to the image display cell. Further, the image display device of the present invention is provided with a transparent plate on the polarizing film or laminated polarizing film side (visual side) of the image display panel.
前記画像表示セルとしては、例えば、液晶セルや有機ＥＬセル等が挙げられる。前記液晶セルとしては、例えば、外光を利用する反射型液晶セル、バックライト等の光源からの光を利用する透過型液晶セル、外部からの光と光源からの光の両者を利用する半透過半反射型液晶セルのいずれを用いてもよい。前記液晶セルが光源からの光を利用するものである場合、画像表示装置（液晶表示装置）は、画像表示セル（液晶セル）の視認側と反対側にも偏光フィルムが配置され、さらに光源が配置される。当該光源側の偏光フィルムと液晶セルとは、適宜の接着剤層を介して貼り合せられていることが好ましい。前記液晶セルの駆動方式としては、例えば、ＶＡモード、ＩＰＳモード、ＴＮモード、ＳＴＮモードやベンド配向（π型）等の任意なタイプのものを用いうる。 Examples of the image display cell include a liquid crystal cell and an organic EL cell. Examples of the liquid crystal cell include a reflective liquid crystal cell that uses external light, a transmissive liquid crystal cell that uses light from a light source such as a backlight, and a semitransmissive liquid cell that uses both external light and light from a light source. Any of the semi-reflective liquid crystal cells may be used. When the liquid crystal cell uses light from a light source, in the image display device (liquid crystal display device), a polarizing film is also arranged on the side opposite to the viewing side of the image display cell (liquid crystal cell), and the light source is further arranged. Be placed. It is preferable that the polarizing film on the light source side and the liquid crystal cell are bonded to each other via an appropriate adhesive layer. As the driving method of the liquid crystal cell, for example, any type such as VA mode, IPS mode, TN mode, STN mode and bend orientation (π type) can be used.
前記有機ＥＬセルとしては、例えば、透明基板上に透明電極と有機発光層と金属電極とを順に積層して発光体（有機エレクトロルミネセンス発光体）を形成したもの等が好適に用いられる。前記有機発光層は、種々の有機薄膜の積層体であり、例えば、トリフェニルアミン誘導体等からなる正孔注入層と、アントラセン等の蛍光性の有機固体からなる発光層との積層体や、これらの発光層とペリレン誘導体等からなる電子注入層の積層体、あるいは正孔注入層、発光層、および電子注入層の積層体等、種々層構成が採用され得る。 As the organic EL cell, for example, a cell in which a transparent electrode, an organic light emitting layer, and a metal electrode are sequentially laminated on a transparent substrate to form a light emitting body (organic electroluminescence light emitting body) is preferably used. The organic light emitting layer is a laminate of various organic thin films, for example, a laminate of a hole injection layer made of a triphenylamine derivative or the like and a light emitting layer made of a fluorescent organic solid such as anthracene, or these. Various layer configurations can be adopted, such as a laminate of an electron injection layer composed of the light emitting layer and a perylene derivative, or a laminate of a hole injection layer, a light emitting layer, and an electron injection layer.
前記画像表示セルの視認側に配置される透明板としては、例えば、前面透明板（ウインドウ層）やタッチパネル等が挙げられる。前記前面透明板としては、適宜の機械強度および厚みを有する透明板が用いられる。このような透明板としては、例えば、アクリル系樹脂やポリカーボネート系樹脂のような透明樹脂板、あるいはガラス板等が用いられる。前記タッチパネルとしては、例えば、抵抗膜方式、静電容量方式、光学方式、超音波方式等の各種タッチパネルや、タッチセンサー機能を備えるガラス板や透明樹脂板等が用いられる。前記透明板として静電容量方式のタッチパネルが用いられる場合、タッチパネルよりもさらに視認側に、ガラスや透明樹脂板からなる前面透明板が設けられることが好ましい。 Examples of the transparent plate arranged on the visual side of the image display cell include a front transparent plate (window layer) and a touch panel. As the front transparent plate, a transparent plate having appropriate mechanical strength and thickness is used. As such a transparent plate, for example, a transparent resin plate such as an acrylic resin or a polycarbonate resin, a glass plate, or the like is used. As the touch panel, for example, various touch panels such as a resistive film method, a capacitance method, an optical method, and an ultrasonic method, a glass plate having a touch sensor function, a transparent resin plate, and the like are used. When a capacitance type touch panel is used as the transparent plate, it is preferable to provide a front transparent plate made of glass or a transparent resin plate on the visual side of the touch panel.
以下に実施例を挙げて本発明をさらに詳細に説明するが、本発明はこれらの実施例のみに限定されるものではない。 The present invention will be described in more detail with reference to Examples below, but the present invention is not limited to these Examples.
＜実施例１＞
＜偏光子の作製＞
平均重合度が２，４００、ケン化度が９９．９モル％、厚みが４５μｍであるポリビニルアルコールフィルムを用意した。ポリビニルアルコールフィルムを、周速比の異なるロール間で、２０℃の膨潤浴（水浴）中に３０秒間浸漬して膨潤しながら搬送方向に２．４倍に延伸し（膨潤工程）、続いて、２０℃の染色浴（ヨウ素濃度が０．０３重量％、ヨウ化カリウム濃度が０．３重量％である水溶液）中で４５秒間浸漬して染色しながら元のポリビニルアルコールフィルム（搬送方向に全く延伸していないポリビニルアルコールフィルム）を基準にして搬送方向に３．７倍に延伸した（染色工程）。次いで、染色したポリビニルアルコールフィルムを、４０℃の架橋浴（ホウ酸濃度が３．０重量％、ヨウ化カリウム濃度が３．０重量％である水溶液）中で２０秒間浸漬して元のポリビニルアルコールフィルムを基準にして搬送方向に４．２倍まで延伸した（架橋工程）。さらに、得られたポリビニルアルコールフィルムを、６５℃の延伸浴（ホウ酸濃度が４．０重量％、ヨウ化カリウム濃度が５．０重量％である水溶液）中で５０秒間浸漬して元のポリビニルアルコールフィルムを基準にして搬送方向に６．０倍まで延伸した（延伸工程）後、１８℃の洗浄浴（ヨウ化カリウム濃度が２．５重量％である水溶液）中で５秒間浸漬した（洗浄工程）。洗浄したポリビニルアルコールフィルムを、３０℃で２分間乾燥して偏光子を作製した。以下の測定方法にて求めた、偏光子中のホウ素含有量は４．２重量％であり、偏光子中のカリウム含有量は０．３２重量％であった。また、偏光子の厚みは１８μｍであり、偏光子の水分率は１６重量％であった。<Example 1>
<Making a polarizer>
A polyvinyl alcohol film having an average degree of polymerization of 2,400, a saponification degree of 99.9 mol%, and a thickness of 45 μm was prepared. The polyvinyl alcohol film was immersed in a swelling bath (water bath) at 20 ° C. for 30 seconds between rolls having different peripheral speed ratios and stretched 2.4 times in the transport direction while swelling (swelling step). The original polyvinyl alcohol film (extremely stretched in the transport direction) while being dyed by immersing it in a dyeing bath at 20 ° C. (an aqueous solution having an iodine concentration of 0.03% by weight and a potassium iodide concentration of 0.3% by weight) for 45 seconds. It was stretched 3.7 times in the transport direction with reference to the uncoated polyvinyl alcohol film (dyeing step). Next, the dyed polyvinyl alcohol film is immersed in a cross-linked bath at 40 ° C. (an aqueous solution having a boric acid concentration of 3.0% by weight and a potassium iodide concentration of 3.0% by weight) for 20 seconds to obtain the original polyvinyl alcohol. It was stretched up to 4.2 times in the transport direction with respect to the film (crosslinking step). Further, the obtained polyvinyl alcohol film is immersed in a stretching bath at 65 ° C. (an aqueous solution having a boric acid concentration of 4.0% by weight and a potassium iodide concentration of 5.0% by weight) for 50 seconds to obtain the original polyvinyl alcohol film. After stretching up to 6.0 times in the transport direction with reference to the alcohol film (stretching step), it was immersed in a washing bath at 18 ° C. (an aqueous solution having a potassium iodide concentration of 2.5% by weight) for 5 seconds (washing). Process). The washed polyvinyl alcohol film was dried at 30 ° C. for 2 minutes to prepare a polarizer. The boron content in the polarizer, which was determined by the following measuring method, was 4.2% by weight, and the potassium content in the polarizer was 0.32% by weight. The thickness of the polarizer was 18 μm, and the water content of the polarizer was 16% by weight.
［偏光子中のホウ素含有量（重量％）の測定方法］
１２０℃で２時間乾燥させた偏光子（約０．２ｇ）を水に溶かし、マンニトールおよびＢＴＢ溶液を少量滴下した水溶液に、０．１ｍｏｌ／ＬのＮａＯＨ水溶液をビュレットを用いて中和滴定し、偏光子のホウ素含有率を下記式に基づき算出した。
偏光子のホウ素含有量（重量％）＝Ｃ×Ｖ×Ｍｗ／Ｍ×１００
Ｃ：ＮａＯＨ水溶液の濃度（ｍｏｌ／Ｌ）
Ｖ：ＮａＯＨ水溶液の滴下量（Ｌ）
Ｍｗ：ホウ素の分子量（ｇ／ｍｏｌ）
Ｍ：１２０℃、２時間乾燥後の偏光子重量（ｇ）[Method for measuring boron content (% by weight) in polarizer]
A polarizer (about 0.2 g) dried at 120 ° C. for 2 hours was dissolved in water, and a 0.1 mol / L NaOH aqueous solution was neutralized and titrated using a burette in an aqueous solution in which a small amount of mannitol and BTB solution was added dropwise. The boron content of the polarizer was calculated based on the following formula.
Boron content (% by weight) of polarizer = C × V × Mw / M × 100
C: Concentration of aqueous NaOH solution (mol / L)
V: Amount of dropping of NaOH aqueous solution (L)
Mw: Molecular weight of boron (g / mol)
M: Polarizer weight (g) after drying at 120 ° C. for 2 hours
［偏光子中のカリウム含有量（重量％）の測定方法］
偏光子について、蛍光Ｘ線分析装置（リガク社製、商品名「ＺＳＸ１００Ｅ」、測定径：ψ１０ｍｍ）を用いて、カリウム元素の蛍光Ｘ線強度（ｋｃｐｓ）を測定した。一方、当該偏光子の厚み（μｍ）を、分光膜厚計（ＰＥＡＣＯＣＫ社製、商品名「ＤＧ−２０５」）を用いて測定した。得られた蛍光Ｘ線強度と厚みから下記式を用いてカリウム含有量（重量％）を求めた。なお、下記の「２．９９」は、厚み（μｍ）およびカリウム濃度（重量％）が既知の試料（例えば、一定量のＫＩを添加したＰＶＡ系樹脂フィルム）の蛍光Ｘ線強度（ｋｃｐｓ）を測定し、導き出された検量線の係数である。
偏光中のカリウム含有量（重量％）＝２．９９×（カリウム元素の蛍光Ｘ線強度）／（偏光子の厚み）[Measurement method of potassium content (% by weight) in polarizer]
For the polarizer, the fluorescent X-ray intensity (kcps) of the potassium element was measured using a fluorescent X-ray analyzer (manufactured by Rigaku Corporation, trade name "ZSX100E", measurement diameter: ψ10 mm). On the other hand, the thickness (μm) of the polarizer was measured using a spectroscopic film thickness meter (manufactured by PEACOCK, trade name “DG-205”). From the obtained fluorescent X-ray intensity and thickness, the potassium content (% by weight) was determined using the following formula. In addition, the following "2.99" is the fluorescent X-ray intensity (kcps) of a sample having a known thickness (μm) and potassium concentration (% by weight) (for example, a PVA-based resin film to which a certain amount of KI is added). It is the coefficient of the calibration curve measured and derived.
Potassium content in polarized light (% by weight) = 2.99 x (fluorescent X-ray intensity of potassium element) / (thickness of polarizer)
＜偏光フィルムの作製＞
接着剤として、アセトアセチル基を含有するポリビニルアルコール樹脂（平均重合度が１，２００、ケン化度が９８．５モル％、アセトアセチル化度が５モル％）とメチロールメラミンとを重量比３：１で含有する水溶液を用いた。この接着剤を用いて、第２透明保護フィルムとして、上記で得られた偏光子の一方の面（画像表示セル側表面）に、（メタ）アクリル系樹脂（ラクトン環構造を有する変性アクリル系ポリマー）からなる厚み３０μｍの透明保護フィルム（飽和吸水量が０．２ｇ／ｍ２、透湿度が１２５ｇ／（ｍ２・２４ｈ））、（以下、このフィルムを「透明フィルムＡ」と称する）、また、第１透明保護フィルムとして、他方の面（視認側）に、ハードコート層を有する厚み４０μｍのトリアセチルセルロースフィルム（透湿度が３４２ｇ／（ｍ２・２４ｈ）、コニカミノルタ製、商品名「ＫＣ４ＵＹＷ」）（以下、このフィルムを「透明フィルムＢ」と称する）をロール貼合機で貼り合わせた後、引き続きオーブン内で加熱乾燥（温度が８８℃、時間が１０分間）させて、偏光子の両面に透明保護フィルムが貼り合わせられた偏光フィルムを作製した。<Manufacturing of polarizing film>
As an adhesive, a polyvinyl alcohol resin containing an acetoacetyl group (average degree of polymerization of 1,200, saponification degree of 98.5 mol%, acetoacetylation degree of 5 mol%) and methylol melamine in a weight ratio of 3: The aqueous solution contained in 1 was used. Using this adhesive, as a second transparent protective film, a (meth) acrylic resin (modified acrylic polymer having a lactone ring structure) was applied to one surface (the surface on the image display cell side) of the polarizer obtained above. transparent protective film having a thickness of 30μm consisting of) (saturated water absorption 0.2 g / m 2, moisture permeability 125g / (m 2 · 24h) ), ( hereinafter, this film is referred to as "transparent film a"), also , as the first transparent protective film, on the other surface (viewing side), triacetyl cellulose film having a thickness of 40μm with a hard coat layer (moisture permeability 342g / (m 2 · 24h) , manufactured by Konica Minolta, trade name "KC4UYW ”) (Hereinafter, this film is referred to as“ transparent film B ”) is bonded with a roll bonding machine, and then heat-dried in an oven (temperature is 88 ° C., time is 10 minutes) to obtain a polarizer. A polarizing film in which a transparent protective film was bonded to both sides was produced.
＜疑似画像表示装置の作製＞
上記で得られた偏光フィルムを、偏光子の吸収軸が長辺となるように１５０×５０ｃｍのサイズに切断し、偏光フィルムの一方の面（透明フィルムＡ側の面）に、厚み２０μｍのアクリル系粘着剤層を介してガラス板（疑似画像表示セル）を貼り合わせ、偏光フィルムの他方の面（透明フィルムＢ側の面）に厚み２００μｍのアクリル酸モノマーフリー粘着剤（日東電工（株）製、商品名「ＬＵＣＩＡＣＳ ＣＳ９８６８」）を介して別のガラス板を貼り合わせて、疑似画像表示装置を作製した。<Manufacturing a pseudo image display device>
The polarizing film obtained above is cut into a size of 150 × 50 cm so that the absorption axis of the polarizer is the long side, and acrylic having a thickness of 20 μm is formed on one surface of the polarizing film (the surface on the transparent film A side). A glass plate (pseudo-image display cell) is attached via an adhesive layer, and a 200 μm-thick acrylic acid monomer-free adhesive (manufactured by Nitto Denko Co., Ltd.) is attached to the other surface (transparent film B side) of the polarizing film. , A pseudo-image display device was produced by laminating another glass plate via the trade name "LUCIACS CS9868").
［高温環境下における光学特性の評価］
上記で得られた疑似画像表示装置を、温度９５℃の熱風オーブン内に５００時間静置し、投入（加熱）前後の単体透過率（ΔＴｓ）および偏光度（ΔＰ）を測定した。単体透過率および偏光度は、分光光度計（村上色彩技術研究所（株）製、製品名「ＤＯＴ−３」）を用いて測定した。当該単体透過率は、ＪｌＳ Ｚ ８７０１−１９８２の２度視野（Ｃ光源）により、視感度補正を行ったＹ値である。なお、測定波長は、３８０〜７００ｎｍ（１０ｎｍ毎）である。
ΔＴｓ（％）＝Ｔｓ５００−Ｔｓ０
ΔＰ（％）＝Ｐ５００−Ｐ０
ここで、Ｔｓ０およびＰ０は加熱前の単体透過率および偏光度であり、Ｔｓ５００およびＰ５００は５００時間加熱後の単体透過率および偏光度である。結果を表１に示す。[Evaluation of optical characteristics in high temperature environment]
The pseudo image display device obtained above was allowed to stand in a hot air oven at a temperature of 95 ° C. for 500 hours, and the single transmittance (ΔTs) and the degree of polarization (ΔP) before and after charging (heating) were measured. The single transmittance and the degree of polarization were measured using a spectrophotometer (manufactured by Murakami Color Technology Laboratory Co., Ltd., product name "DOT-3"). The simple substance transmittance is a Y value obtained by correcting the luminosity factor with a 2 degree field of view (C light source) of JlS Z 8701-1982. The measurement wavelength is 380 to 700 nm (every 10 nm).
ΔTs (%) = Ts 500 −Ts 0
ΔP (%) = P 500 −P 0
Here, Ts 0 and P 0 are the simple substance transmittance and the degree of polarization before heating, and Ts 500 and P 500 are the simple substance transmittance and the degree of polarization after heating for 500 hours. The results are shown in Table 1.
上記の偏光度は、疑似画像表示装置と基準偏光フィルム（日東電工（株）製、商品名「ＣＷＱ１４６３ＣＵ」）を吸収軸が平行な状態に配置した場合に得られる平行透過率（Ｔｐ）と、吸収軸が９０゜となるように互いに直交させた後に得られる直交透過率（Ｔｃ）によって、下記式で定義される。
Ｐ（％）＝［（Ｔｐ−Ｔｃ）／（Ｔｐ＋Ｔｃ）］１／２×１００The above degree of polarization is the parallel transmittance (Tp) obtained when the pseudo image display device and the reference polarizing film (manufactured by Nitto Denko Co., Ltd., trade name "CWQ1463CU") are arranged in a state where the absorption axes are parallel. It is defined by the following equation by the orthogonal transmittance (Tc) obtained after making the absorption axes orthogonal to each other so as to be 90 °.
P (%) = [(Tp-Tc) / (Tp + Tc)] 1/2 x 100
前記ΔＴｓ（％）は、−１．０〜１．０であることが好ましく、−０．５〜０．５であることがより好ましい。また、前記ΔＰ（％）は、−０．０１０〜０．０００であることが好ましく、−０．００５〜０．０００であることがより好ましい。 The ΔTs (%) is preferably −1.0 to 1.0, and more preferably −0.5 to 0.5. Further, the ΔP (%) is preferably −0.01 to 0.000, and more preferably −0.005 to 0.000.
［高温環境下における外観の評価］
上記で得られた疑似画像表示装置を、温度９５℃の熱風オーブン内に５００時間静置し、投入（加熱）後の外観を目視で以下の基準で評価した。結果を表１に示す。
○：外観に異常なし、あるいは偏光フィルムの端部に１００μｍ未満のクラックが発生する。
×：外観に異常（ポリエン化）あり、あるいは偏光フィルムの端部に１００μｍ以上のクラックが発生する。[Evaluation of appearance in high temperature environment]
The pseudo image display device obtained above was allowed to stand in a hot air oven at a temperature of 95 ° C. for 500 hours, and the appearance after charging (heating) was visually evaluated according to the following criteria. The results are shown in Table 1.
◯: There is no abnormality in appearance, or cracks of less than 100 μm occur at the edge of the polarizing film.
X: There is an abnormality (polyene formation) in appearance, or cracks of 100 μm or more occur at the edge of the polarizing film.
＜実施例２＞
＜偏光子、偏光フィルム、疑似画像表示装置の作製＞
偏光子の作製において、架橋工程で架橋浴（ホウ酸濃度が３．５重量％、ヨウ化カリウム濃度が２．５重量％である水溶液）を用いたこと、また、延伸工程で延伸浴（ホウ酸濃度が４．５重量％、ヨウ化カリウム濃度が５．０重量％である水溶液）を用いたこと、さらに、洗浄工程で洗浄浴（ヨウ化カリウム濃度が１．８重量％である水溶液）を用いたこと以外は、実施例１と同様の操作にて、偏光子を作製した。得られた偏光子中のホウ素含有量は５．２重量％であり、カリウム含有量は０．２８重量％であった。また、得られた偏光子を用い、実施例１と同様な操作にて、偏光フィルム、疑似画像表示装置を作製した。<Example 2>
<Manufacturing of polarizer, polarizing film, pseudo image display device>
In the preparation of the polarizer, a cross-linking bath (an aqueous solution having a boric acid concentration of 3.5% by weight and a potassium iodide concentration of 2.5% by weight) was used in the cross-linking step, and a stretching bath (how) was used in the stretching step. An aqueous solution having an acid concentration of 4.5% by weight and a potassium iodide concentration of 5.0% by weight) was used, and a washing bath (an aqueous solution having a potassium iodide concentration of 1.8% by weight) was used in the washing step. A polarizer was prepared by the same operation as in Example 1 except that the above was used. The boron content in the obtained polarizer was 5.2% by weight, and the potassium content was 0.28% by weight. Further, using the obtained polarizing element, a polarizing film and a pseudo image display device were produced by the same operation as in Example 1.
＜実施例３＞
＜偏光子、偏光フィルム、疑似画像表示装置の作製＞
偏光子の作製において、延伸工程で延伸浴（ホウ酸濃度が３．５重量％、ヨウ化カリウム濃度が５．０重量％である水溶液）を用いたこと、さらに、洗浄工程で洗浄浴（ヨウ化カリウム濃度が３．０重量％である水溶液）を用いたこと以外は、実施例１と同様の操作にて、偏光子を作製した。得られた偏光子中のホウ素含有量は４．０重量％であり、カリウム含有量は０．３４重量％であった。また、得られた偏光子を用い、実施例１と同様な操作にて、偏光フィルム、疑似画像表示装置を作製した。<Example 3>
<Manufacturing of polarizer, polarizing film, pseudo image display device>
In the production of the polarizer, a stretching bath (an aqueous solution having a boric acid concentration of 3.5% by weight and a potassium iodide concentration of 5.0% by weight) was used in the stretching step, and a washing bath (yo) was used in the washing step. A polarizer was prepared by the same operation as in Example 1 except that an aqueous solution having a potassium iodide concentration of 3.0% by weight was used. The boron content in the obtained polarizer was 4.0% by weight, and the potassium content was 0.34% by weight. Further, using the obtained polarizing element, a polarizing film and a pseudo image display device were produced by the same operation as in Example 1.
＜実施例４＞
＜偏光子、偏光フィルム、疑似画像表示装置の作製＞
偏光子として、実施例３で得られた偏光子を用意した。偏光フィルムの作製において、第２透明保護フィルムとして、偏光子の一方の面（画像表示セル側表面）に、厚み８０μｍのトリアセチルセルロースフィルム（透湿度が５６０ｇ／（ｍ２・２４ｈ）、コニカミノルタ社製、商品名「ＫＣ８ＵＹＷ」）（以下、このフィルムを「透明フィルムＣ」と称する）を用いたこと以外は、実施例１と同様な操作にて、偏光フィルムおよび疑似画像表示装置を作製した。<Example 4>
<Manufacturing of polarizer, polarizing film, pseudo image display device>
As the polarizer, the polarizer obtained in Example 3 was prepared. In the preparation of the polarizing film, a second transparent protective film on one surface of the polarizer (image display cell surface), triacetyl cellulose film having a thickness of 80 [mu] m (moisture permeability 560 g / (m 2 · 24h), Konica Minolta A polarizing film and a pseudo image display device were produced by the same operation as in Example 1 except that a trade name “KC8UYW” manufactured by the same company was used (hereinafter, this film is referred to as “transparent film C”). ..
＜実施例５＞
＜偏光子、偏光フィルム、疑似画像表示装置の作製＞
偏光子の作製において、架橋工程で架橋浴（ホウ酸濃度が３．５重量％、ヨウ化カリウム濃度が２．５重量％である水溶液）を用いたこと、また、延伸工程で延伸浴（ホウ酸濃度が５．０重量％、ヨウ化カリウム濃度が５．０重量％である水溶液）を用いたこと、さらに、洗浄工程で洗浄浴（ヨウ化カリウム濃度が１．８重量％である水溶液）を用いたこと以外は、実施例１と同様の操作にて、偏光子を作製した。得られた偏光子中のホウ素含有量は５．３重量％であり、カリウム含有量は０．２８重量％であった。また、得られた偏光子を用い、実施例１と同様な操作にて、偏光フィルム、疑似画像表示装置を作製した。<Example 5>
<Manufacturing of polarizer, polarizing film, pseudo image display device>
In the preparation of the polarizer, a cross-linking bath (an aqueous solution having a boric acid concentration of 3.5% by weight and a potassium iodide concentration of 2.5% by weight) was used in the cross-linking step, and a stretching bath (how) was used in the stretching step. An aqueous solution having an acid concentration of 5.0% by weight and a potassium iodide concentration of 5.0% by weight) was used, and a washing bath (an aqueous solution having a potassium iodide concentration of 1.8% by weight) was used in the washing step. A polarizer was prepared by the same operation as in Example 1 except that the above was used. The boron content in the obtained polarizer was 5.3% by weight, and the potassium content was 0.28% by weight. Further, using the obtained polarizing element, a polarizing film and a pseudo image display device were produced by the same operation as in Example 1.
＜比較例１＞
＜偏光子、偏光フィルム、疑似画像表示装置の作製＞
偏光子の作製において、架橋工程で架橋浴（ホウ酸濃度が２．５重量％、ヨウ化カリウム濃度が２．５重量％である水溶液）を用いたこと、また、延伸工程で延伸浴（ホウ酸濃度が３．０重量％、ヨウ化カリウム濃度が５．０重量％である水溶液）を用いたこと、さらに、洗浄工程で洗浄浴（ヨウ化カリウム濃度が４．０重量％である水溶液）を用いたこと以外は、実施例１と同様の操作にて、偏光子を作製した。得られた偏光子中のホウ素含有量は３．９重量％であり、カリウム含有量は０．３６重量％であった。また、得られた偏光子を用い、実施例１と同様な操作にて、偏光フィルム、疑似画像表示装置を作製した。<Comparative example 1>
<Manufacturing of polarizer, polarizing film, pseudo image display device>
In the preparation of the polarizer, a cross-linking bath (an aqueous solution having a boric acid concentration of 2.5% by weight and a potassium iodide concentration of 2.5% by weight) was used in the cross-linking step, and a stretching bath (how) was used in the stretching step. An aqueous solution having an acid concentration of 3.0% by weight and a potassium iodide concentration of 5.0% by weight) was used, and a washing bath (an aqueous solution having a potassium iodide concentration of 4.0% by weight) was used in the washing step. A polarizer was prepared by the same operation as in Example 1 except that the above was used. The boron content in the obtained polarizer was 3.9% by weight, and the potassium content was 0.36% by weight. Further, using the obtained polarizing element, a polarizing film and a pseudo image display device were produced by the same operation as in Example 1.
＜比較例２＞
＜偏光子、偏光フィルム、疑似画像表示装置の作製＞
偏光子の作製において、洗浄工程で洗浄浴（ヨウ化カリウム濃度が１．３重量％である水溶液）を用いたこと以外は、実施例１と同様の操作にて、偏光子を作製した。得られた偏光子中のホウ素含有量は４．１重量％であり、カリウム含有量は０．２７重量％であった。また、得られた偏光子を用い、実施例１と同様な操作にて、偏光フィルム、疑似画像表示装置を作製した。<Comparative example 2>
<Manufacturing of polarizer, polarizing film, pseudo image display device>
In the preparation of the polarizer, the polarizer was prepared by the same operation as in Example 1 except that a washing bath (an aqueous solution having a potassium iodide concentration of 1.3% by weight) was used in the washing step. The boron content in the obtained polarizer was 4.1% by weight, and the potassium content was 0.27% by weight. Further, using the obtained polarizing element, a polarizing film and a pseudo image display device were produced by the same operation as in Example 1.
＜比較例３＞
＜偏光子、偏光フィルム、疑似画像表示装置の作製＞
偏光子の作製において、延伸工程で延伸浴（ホウ酸濃度が３．５重量％、ヨウ化カリウム濃度が５．０重量％である水溶液）を用いたこと、さらに、洗浄工程で洗浄浴（ヨウ化カリウム濃度が１．５重量％である水溶液）を用いたこと以外は、実施例１と同様の操作にて、偏光子を作製した。得られた偏光子中のホウ素含有量は４．０重量％であり、カリウム含有量は０．２８重量％であった。また、得られた偏光子を用い、実施例１と同様な操作にて、偏光フィルム、疑似画像表示装置を作製した。<Comparative example 3>
<Manufacturing of polarizer, polarizing film, pseudo image display device>
In the production of the polarizer, a stretching bath (an aqueous solution having a boric acid concentration of 3.5% by weight and a potassium iodide concentration of 5.0% by weight) was used in the stretching step, and a washing bath (yo) was used in the washing step. A polarizer was prepared by the same operation as in Example 1 except that an aqueous solution having a potassium iodide concentration of 1.5% by weight was used. The boron content in the obtained polarizer was 4.0% by weight, and the potassium content was 0.28% by weight. Further, using the obtained polarizing element, a polarizing film and a pseudo image display device were produced by the same operation as in Example 1.
＜比較例４＞
＜偏光子、偏光フィルム、疑似画像表示装置の作製＞
偏光子の作製において、架橋工程で架橋浴（ホウ酸濃度が１．５重量％、ヨウ化カリウム濃度が２．５重量％である水溶液）を用いたこと、また、延伸工程で延伸浴（ホウ酸濃度が１．５重量％、ヨウ化カリウム濃度が５．０重量％である水溶液）を用いたこと、さらに、洗浄工程で洗浄浴（ヨウ化カリウム濃度が１０．０重量％である水溶液）を用いたこと以外は、実施例１と同様の操作にて、偏光子を作製した。得られた偏光子中のホウ素含有量は２．４重量％であり、カリウム含有量は０．６５重量％であった。また、得られた偏光子を用い、実施例１と同様な操作にて、偏光フィルム、疑似画像表示装置を作製した。<Comparative example 4>
<Manufacturing of polarizer, polarizing film, pseudo image display device>
In the preparation of the polarizer, a cross-linking bath (an aqueous solution having a boric acid concentration of 1.5% by weight and a potassium iodide concentration of 2.5% by weight) was used in the cross-linking step, and a stretching bath (how) was used in the stretching step. An aqueous solution having an acid concentration of 1.5% by weight and a potassium iodide concentration of 5.0% by weight) was used, and a washing bath (an aqueous solution having a potassium iodide concentration of 10.0% by weight) was used in the washing step. A polarizer was prepared by the same operation as in Example 1 except that the above was used. The boron content in the obtained polarizer was 2.4% by weight, and the potassium content was 0.65% by weight. Further, using the obtained polarizing element, a polarizing film and a pseudo image display device were produced by the same operation as in Example 1.
上記で得られた実施例２〜５および比較例１〜４の疑似画像表示装置を用い、上記の［高温環境下における光学特性の評価］および［高温環境下における外観の評価］における評価を行った。結果を表１に示す。 Using the pseudo-image display devices of Examples 2 to 5 and Comparative Examples 1 to 4 obtained above, the above-mentioned [evaluation of optical characteristics in a high temperature environment] and [evaluation of appearance in a high temperature environment] are performed. It was. The results are shown in Table 1.
Claims (8)
前記偏光子は、ホウ素およびカリウムを含み、
前記偏光子中、前記ホウ素の含有量が４重量％以上６重量％以下であり、かつ前記ホウ素の含有量（重量％）に前記カリウムの含有量（重量％）を乗じた値が１．２以上であることを特徴とする偏光子。A polarizer formed from a polyvinyl alcohol-based film.
The polarizer contains boron and potassium and contains
In the polarizer, the boron content is 4% by weight or more and 6% by weight or less, and the value obtained by multiplying the boron content (% by weight) by the potassium content (% by weight) is 1.2. A polarizer characterized by the above.
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| JP2021118875A JP6985556B2 (en) | 2018-03-28 | 2021-07-19 | Polarizers, polarizing films, laminated polarizing films, image display panels, and image display devices |
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| JP2021118874A Active JP6985555B2 (en) | 2018-03-28 | 2021-07-19 | Polarizers, polarizing films, laminated polarizing films, image display panels, and image display devices |
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| KR (4) | KR102496903B1 (en) |
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| JP2021162858A (en) * | 2020-03-30 | 2021-10-11 | 日東電工株式会社 | Polarization film, laminated polarization film, image display panel and image display unit |
| JP2021165826A (en) * | 2020-04-01 | 2021-10-14 | 住友化学株式会社 | Polarizer and image display unit using the polarizer |
| KR20230023610A (en) * | 2020-06-12 | 2023-02-17 | 스미또모 가가꾸 가부시끼가이샤 | Polarizing film and ellipsoidal polarizer |
| JP7089093B2 (en) * | 2020-10-15 | 2022-06-21 | 住友化学株式会社 | Polarizing plate and image display device |
| TW202221366A (en) * | 2020-10-15 | 2022-06-01 | 日商住友化學股份有限公司 | Polarizing plate and image display device |
| JP7005803B1 (en) | 2020-10-26 | 2022-01-24 | 住友化学株式会社 | Laminate |
| JP7524032B2 (en) | 2020-11-04 | 2024-07-29 | 住友化学株式会社 | Polarizing plate and image display device |
| KR20230148329A (en) | 2021-03-01 | 2023-10-24 | 닛토덴코 가부시키가이샤 | Polarizing film, polarizing film, image display panel, and image display device |
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- 2019-03-22 KR KR1020237030536A patent/KR20230131971A/en not_active Application Discontinuation
- 2019-03-22 CN CN202310236094.1A patent/CN118091813A/en active Pending
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- 2019-03-22 CN CN201980022317.6A patent/CN111919149A/en active Pending
- 2019-03-22 KR KR1020227002276A patent/KR102565143B1/en active IP Right Grant
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- 2019-03-22 JP JP2020509959A patent/JP6917521B2/en active Active
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Also Published As
| Publication number | Publication date |
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| KR102600802B1 (en) | 2023-11-10 |
| KR20220015509A (en) | 2022-02-08 |
| CN117518324A (en) | 2024-02-06 |
| JP6985556B2 (en) | 2021-12-22 |
| WO2019188779A1 (en) | 2019-10-03 |
| JP2021185415A (en) | 2021-12-09 |
| JP6917521B2 (en) | 2021-08-11 |
| JP6985555B2 (en) | 2021-12-22 |
| KR20220015508A (en) | 2022-02-08 |
| JP2021185414A (en) | 2021-12-09 |
| KR102565143B1 (en) | 2023-08-09 |
| CN111919149A (en) | 2020-11-10 |
| KR102496903B1 (en) | 2023-02-08 |
| KR20200139665A (en) | 2020-12-14 |
| CN118091813A (en) | 2024-05-28 |
| KR20230131971A (en) | 2023-09-14 |
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