JPWO2019156097A1 - Potato starch - Google Patents

Potato starch Download PDF

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JPWO2019156097A1
JPWO2019156097A1 JP2019570764A JP2019570764A JPWO2019156097A1 JP WO2019156097 A1 JPWO2019156097 A1 JP WO2019156097A1 JP 2019570764 A JP2019570764 A JP 2019570764A JP 2019570764 A JP2019570764 A JP 2019570764A JP WO2019156097 A1 JPWO2019156097 A1 JP WO2019156097A1
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potato starch
starch
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JP7258780B2 (en
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明香 桑原
明香 桑原
周平 山崎
周平 山崎
馨子 衞藤
馨子 衞藤
榊原 通宏
通宏 榊原
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Nisshin Foods Inc
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    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L19/00Products from fruits or vegetables; Preparation or treatment thereof
    • A23L19/10Products from fruits or vegetables; Preparation or treatment thereof of tuberous or like starch containing root crops
    • A23L19/12Products from fruits or vegetables; Preparation or treatment thereof of tuberous or like starch containing root crops of potatoes
    • A23L19/15Unshaped dry products, e.g. powders, flakes, granules or agglomerates
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L29/00Foods or foodstuffs containing additives; Preparation or treatment thereof
    • A23L29/20Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents
    • A23L29/206Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents of vegetable origin
    • A23L29/212Starch; Modified starch; Starch derivatives, e.g. esters or ethers
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L5/00Preparation or treatment of foods or foodstuffs, in general; Food or foodstuffs obtained thereby; Materials therefor
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L5/00Preparation or treatment of foods or foodstuffs, in general; Food or foodstuffs obtained thereby; Materials therefor
    • A23L5/10General methods of cooking foods, e.g. by roasting or frying
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L7/00Cereal-derived products; Malt products; Preparation or treatment thereof
    • A23L7/10Cereal-derived products
    • A23L7/157Farinaceous granules for dressing meat, fish or the like

Abstract

水溶きせずにとろみ付け材として使用でき、かつ揚げ物の衣材としても好適な馬鈴薯澱粉の提供。D10が18μm以上かつD90が900μm未満であり、D90/D10が4.0〜17.0である馬鈴薯澱粉。Providing potato starch that can be used as a thickening material without being water-soluble and is also suitable as a batter for deep-fried foods. Potato starch having a D10 of 18 μm or more and a D90 of less than 900 μm, and a D90 / D10 of 4.0 to 17.0.

Description

本発明は、料理のとろみ付け材や揚げ物の衣材として使用できる馬鈴薯澱粉に関する。 The present invention relates to potato starch that can be used as a thickening material for cooking and a batter for fried foods.

馬鈴薯澱粉は、調理や食品製造において、スープやソース等の液状食品のとろみ付け、から揚げ等の揚げ物の衣材として、または麺や練り物の粘性付与などに広く使用されている。しかし、馬鈴薯澱粉は、飛散して周辺に散らばりやすく、一方で粒子同士が凝集しやすいため、操作性に難点がある。例えば、馬鈴薯澱粉を温めた食品に直接添加すると、澱粉の粉末が食品中に均等に分散せずに凝集して、いわゆるダマが生じる。そのため、従来、馬鈴薯澱粉を液状食品のとろみ付け材として使用する場合には、一旦少量の水に分散させて(いわゆる「水溶き」して)から、液状食品に添加するという手間を要していた。 In cooking and food production, potato starch is widely used for thickening liquid foods such as soups and sauces, as a batter for fried foods such as fried chicken, and for imparting viscosity to noodles and pastes. However, potato starch is liable to scatter and scatter around, while particles are liable to aggregate with each other, which is difficult to operate. For example, when potato starch is added directly to warm food, the starch powder is not evenly dispersed in the food and aggregates, resulting in so-called lumps. Therefore, conventionally, when potato starch is used as a thickening material for liquid foods, it has been necessary to disperse it in a small amount of water (so-called "water-soluble") and then add it to the liquid foods. ..

特許文献1には、馬鈴薯澱粉を脱水、造粒、整粒、乾燥、篩分けすることで製造した顆粒馬鈴薯澱粉が、水にすぐ溶けてダマにならず、料理に直接添加することでとろみ付けに使用できること、また35〜60メッシュの比率が高い粒度のものがより効果が期待できることが記載されている。特許文献2には、顆粒状α化澱粉と粉末状α化澱粉とを所定の割合で含む混合物に熱湯を注ぐことでダマのできにくい滑らかなペースト状ソースが得られることが記載されている。 In Patent Document 1, the granulated potato starch produced by dehydrating, granulating, sizing, drying, and sieving the potato starch does not immediately dissolve in water and becomes lumpy, and is thickened by adding it directly to the dish. It is described that it can be used in the above, and that a grain size having a high ratio of 35 to 60 mesh can be expected to be more effective. Patent Document 2 describes that a smooth paste-like sauce that is less likely to be lumped can be obtained by pouring boiling water into a mixture containing granular pregelatinized starch and powdered pregelatinized starch in a predetermined ratio.

一方、馬鈴薯澱粉を揚げ物の衣材に使用した場合でも、その飛散性、凝集性のために具材にムラなく付着させることは難しく、その結果、得られる揚げ物は色ムラのある見劣りする外観になりやすかった。また、具材への衣づけの際に馬鈴薯澱粉が調理場に飛散して、調理場を汚したり、無駄遣いしてしまうことも多かった。さらに、馬鈴薯澱粉を具材にまぶして得られるから揚げは、表面が白く粉をふいたような外観(いわゆる「粉吹き」)を有するものが好まれる。しかし、粉吹きを良好にしようとして衣材を厚めに付着させた場合、油ちょう中に衣の一部が脱落して、素揚げのような外観となったり具材が直接揚げ油と触れることで硬くなったりすることがあり、さらに油ちょう後にも、盛付けや喫食しようとから揚げを掴んだ際に衣、特に粉吹きの部分が剥がれてしまうことが少なくなかった。そのため、従来の馬鈴薯澱粉でそのような見栄えよく粉吹きしたから揚げを得ることは、必ずしも容易ではなかった。 On the other hand, even when potato starch is used as a batter for fried foods, it is difficult to evenly adhere it to the ingredients due to its scattering and cohesiveness, and as a result, the resulting fried foods have an uneven color and an inferior appearance. It was easy to become. In addition, potato starch was often scattered in the kitchen when dressing the ingredients, polluting the kitchen and wasting it. Further, since the fried chicken is obtained by sprinkling potato starch on the ingredients, it is preferable that the fried chicken has a white surface and a dusty appearance (so-called “powder blowing”). However, if the batter is thickly attached in an attempt to improve powder blowing, part of the batter may fall off in the oil pan, giving the appearance of deep-fried food or the ingredients coming into direct contact with the frying oil. It may become hard, and even after oiling, the batter, especially the powder-blown part, often peeled off when the fried chicken was grabbed for serving or eating. Therefore, it was not always easy to obtain fried chicken because it was powdered with such a good-looking potato starch with conventional potato starch.

特許文献3には、95重量%以上が粒径20μm以上である馬鈴薯澱粉を主体とするから揚げ粉により、サクミがあり、口溶けの良いから揚げが得られることが記載されている。特許文献4には、粉砕され平均粒子径が20μm以下である穀粉または澱粉を含む打ち粉またはバッター液を用いて、衣がサクサクとし、具材がジューシーな油ちょう食品が得られることが記載されている。特許文献5には、実質的に粒子径が50μm以下の馬鈴薯澱粉を含有する衣材を用いることで、衣の透明性のあるフライ類が得られることが記載されている。特許文献6には、澱粉を含む材料をエクストルーダー等で押出し膨化させて得られる粒子径が0.1〜4mmの粒状澱粉組成物を衣材に用いると、サックリとして着色の良い揚げ物が得られることが記載されている。一方で、これらの文献では、衣材の操作性やから揚げの衣の剥がれにくさについては着目されていない。 Patent Document 3 describes that since 95% by weight or more is mainly composed of potato starch having a particle size of 20 μm or more, the fried chicken has crispy texture and is easily melted in the mouth, so that fried chicken can be obtained. Patent Document 4 describes that a flour or batter liquid containing flour or starch having an average particle size of 20 μm or less, which has been crushed, can be used to obtain an oily food with a crispy garment and juicy ingredients. ing. Patent Document 5 describes that a transparent fried batter can be obtained by using a batter containing potato starch having a particle size of 50 μm or less. According to Patent Document 6, when a granular starch composition having a particle size of 0.1 to 4 mm obtained by extruding and swelling a material containing starch with an extruder or the like is used as a batter, a fried food having good coloring can be obtained. It is stated that. On the other hand, these documents do not pay attention to the operability of the batter and the difficulty of peeling the fried batter.

特開平5−97901号公報Japanese Unexamined Patent Publication No. 5-97901 特開2014−57530号公報Japanese Unexamined Patent Publication No. 2014-57530 特開2000−350561号公報Japanese Unexamined Patent Publication No. 2000-350561 特開2003−265130号公報Japanese Unexamined Patent Publication No. 2003-265130 特開2004−329093号公報Japanese Unexamined Patent Publication No. 2004-329093 国際公開公報第2014/087730号International Publication No. 2014/087730

本発明は、食品のとろみ付け材や揚げ物の衣材として好適な馬鈴薯澱粉を提供する。より詳細には、とろみ付け材として使用した場合、予め水溶きせずとも、液状食品に直接添加すれば、ダマを生じることなく食品をとろみ付けでき、また衣材として使用すれば、衣が剥がれにくく、表面の粉吹きした部分を保った良好な外観を有するから揚げを製造することができる、馬鈴薯澱粉を提供する。 The present invention provides potato starch suitable as a thickening material for foods and a battering material for fried foods. More specifically, when used as a thickening material, the food can be thickened without causing lumps by adding it directly to the liquid food without being water-soluble in advance, and when used as a clothing material, the clothes are hard to peel off. Provided is potato starch, which can produce fried chicken because it has a good appearance while preserving the powdered portion of the surface.

本発明者らは、馬鈴薯澱粉の粒度分布を特定の範囲に調整することで、上記のような性質を有し、とろみ付け材や揚げ物の衣材として好適に使用できる馬鈴薯澱粉が得られることを見出した。さらに本発明者らは、この馬鈴薯澱粉が、振出し容器から振り出して使用することにも適していること、これを振出し容器から振り出して使用することで、馬鈴薯澱粉を使用した調理の操作を一層容易にすることを見出した。 By adjusting the particle size distribution of potato starch to a specific range, the present inventors have determined that potato starch having the above-mentioned properties and can be suitably used as a thickening material or a batter for deep-fried foods can be obtained. I found it. Furthermore, the present inventors have said that the potato starch is also suitable for being used by shaking it out of a drawing container, and by using it by shaking it out of a drawing container, the operation of cooking using potato starch is further facilitated. I found that

したがって、本発明は、D10が18μm以上かつD90が900μm未満であり、D90/D10が4.0〜17.0である馬鈴薯澱粉を提供する。
また本発明は、前記馬鈴薯澱粉を70質量%以上含有する、馬鈴薯澱粉組成物を提供する。
また本発明は、前記馬鈴薯澱粉または前記馬鈴薯澱粉組成物を、とろみ付けする対象食品に直接添加して混合することを含む、食品のとろみ付け方法を提供する。
また本発明は、前記馬鈴薯澱粉または前記馬鈴薯澱粉組成物を具材にまぶして付着させることを含む、から揚げの製造方法を提供する。
また本発明は、食品のとろみ付け材またはから揚げ用衣材としての、前記馬鈴薯澱粉または前記馬鈴薯澱粉組成物の使用を提供する。
Therefore, the present invention provides potato starch having a D10 of 18 μm or more, a D90 of less than 900 μm, and a D90 / D10 of 4.0 to 17.0.
The present invention also provides a potato starch composition containing 70% by mass or more of the potato starch.
The present invention also provides a method for thickening foods, which comprises directly adding and mixing the potato starch or the potato starch composition to the target food to be thickened.
The present invention also provides a method for producing fried chicken, which comprises sprinkling the potato starch or the potato starch composition on an ingredient and adhering the starch.
The present invention also provides the use of the potato starch or the potato starch composition as a thickening material for foods or a batter for deep-fried chicken.

本発明の馬鈴薯澱粉は、とろみ付け材として使用した場合、予め水溶きせずとも、液状食品に直接添加するだけで、ダマを生じることなく食品をとろみ付けできる。また本発明の馬鈴薯澱粉を衣材として使用すれば、衣が剥がれにくく、表面の粉吹きした部分を保った良好な外観を有するから揚げを製造することができる。さらに、本発明の馬鈴薯澱粉は、振出し容器から少量ずつ振り出して使用することにも適しているため、調理での操作性、および経済性に優れている。 When the potato starch of the present invention is used as a thickening material, the food can be thickened without causing lumps by simply adding it directly to the liquid food without preliminarily dissolving it in water. Further, if the potato starch of the present invention is used as a batter material, the batter does not easily come off and has a good appearance while maintaining the powdered portion of the surface, so that fried chicken can be produced. Further, since the potato starch of the present invention is also suitable for being used by shaking it out from a drawing container little by little, it is excellent in operability and economy in cooking.

本発明の馬鈴薯澱粉は、特定の粒度分布を有する。より詳細には、本発明の馬鈴薯澱粉は、10%粒径(D10)が18μm以上かつ90%粒径(D90)が900μm未満であり、D90とD10の比(D90/D10)が4.0〜17.0である。好ましくは、本発明の馬鈴薯澱粉は、D10が20μm以上かつD90が800μm未満であり、より好ましくはD10が25μm以上かつD90が620μm未満である。また、本発明の馬鈴薯澱粉のD90/D10は、好ましくは5.0〜12.0、より好ましくは6.0〜10.0である。さらに好ましくは、本発明の馬鈴薯澱粉は、D10が18〜100μmかつD90が72〜900μmであって、D90/D10が4.0〜17.0である。さらに好ましくは、本発明の馬鈴薯澱粉は、D10が20〜90μmかつD90が100〜800μmであって、かつD90/D10が5.0〜12.0である。さらに好ましくは、本発明の馬鈴薯澱粉は、D10が25〜80μmかつD90が150〜620μmであって、かつD90/D10が6.0〜10.0である。 The potato starch of the present invention has a specific particle size distribution. More specifically, the potato starch of the present invention has a 10% particle size (D10) of 18 μm or more and a 90% particle size (D90) of less than 900 μm, and has a ratio of D90 to D10 (D90 / D10) of 4.0. It is ~ 17.0. Preferably, the potato starch of the present invention has a D10 of 20 μm or more and a D90 of less than 800 μm, and more preferably a D10 of 25 μm or more and a D90 of less than 620 μm. The D90 / D10 of the potato starch of the present invention is preferably 5.0 to 12.0, more preferably 6.0 to 10.0. More preferably, the potato starch of the present invention has a D10 of 18 to 100 μm, a D90 of 72 to 900 μm, and a D90 / D10 of 4.0 to 17.0. More preferably, the potato starch of the present invention has a D10 of 20 to 90 μm, a D90 of 100 to 800 μm, and a D90 / D10 of 5.0 to 12.0. More preferably, the potato starch of the present invention has a D10 of 25 to 80 μm, a D90 of 150 to 620 μm, and a D90 / D10 of 6.0 to 10.0.

好適には、本発明の馬鈴薯澱粉は、粒径10〜900μmの粒子を体積基準で99%以上含有するような粒度分布を有する。粒度分布がこの範囲であると、調理に使用したときの操作性がより向上する。さらに、本発明の馬鈴薯澱粉は、その体積平均径(MV)が、好ましくは40〜700μm、より好ましくは60〜500μm、さらに好ましくは80〜300μm、さらに好ましくは80〜220μmである。一般的な馬鈴薯澱粉は、植物としての馬鈴薯が生産する澱粉結晶の大きさや特性から、そのほとんどが粒径5〜120μmの範囲であり、またMVは30〜40μm程度である。本発明の馬鈴薯澱粉は、一般的な馬鈴薯澱粉に比べて、より大きな粒径の粒子の含有率が高い。 Preferably, the potato starch of the present invention has a particle size distribution such that it contains 99% or more of particles having a particle size of 10 to 900 μm on a volume basis. When the particle size distribution is in this range, the operability when used for cooking is further improved. Further, the potato starch of the present invention has a volume mean diameter (MV) of preferably 40 to 700 μm, more preferably 60 to 500 μm, still more preferably 80 to 300 μm, still more preferably 80 to 220 μm. Most of the general potato starch has a particle size in the range of 5 to 120 μm and an MV of about 30 to 40 μm due to the size and characteristics of the starch crystals produced by the potato as a plant. The potato starch of the present invention has a higher content of particles having a larger particle size than general potato starch.

本明細書において、「10%粒径」または「D10」とは、乾式のレーザー回折・散乱法により算出された、粒子径分布の累積10%の値をいい、同様に「90%粒径」または「D90」とは、乾式のレーザー回折・散乱法により算出された、粒子径分布の累積90%の値をいう。また本明細書において、粒子の「粒径」および「体積平均径」(MV)とは、乾式のレーザー回折・散乱法により測定される値をいう。また、粒子の含有量に関する「体積基準」とは、乾式のレーザー回折・散乱法により測定される体積基準をいう。粒子の粒径、体積平均径、D10、D90、および所定の粒子の体積基準での含有量は、市販のレーザー回折式粒度分布測定装置(例えば、日機装株式会社製、マイクロトラックMT3000II)を用いて常法に従って測定することができる。 In the present specification, "10% particle size" or "D10" means a cumulative 10% value of the particle size distribution calculated by a dry laser diffraction / scattering method, and similarly, "90% particle size". Alternatively, "D90" refers to a cumulative 90% value of the particle size distribution calculated by a dry laser diffraction / scattering method. Further, in the present specification, the "particle size" and the "volume mean diameter" (MV) of particles refer to values measured by a dry laser diffraction / scattering method. Further, the "volume standard" regarding the content of particles means a volume standard measured by a dry laser diffraction / scattering method. The particle size, volume average diameter, D10, D90, and the volume-based content of a predetermined particle are determined by using a commercially available laser diffraction type particle size distribution measuring device (for example, Microtrac MT3000II manufactured by Nikkiso Co., Ltd.). It can be measured according to a conventional method.

本発明の馬鈴薯澱粉の原料となる馬鈴薯(ジャガイモ)の品種は、特に限定されないが、澱粉製造用に栽培されている品種が好ましい。そのような馬鈴薯品種の例としては、紅丸、コナユタカ、コナフブキ、ナツフブキ、サクラフブキ、アスタルテ、アーリースターチ、エニワ等が挙げられる。上記の馬鈴薯品種のいずれか1種または2種以上を、本発明の馬鈴薯澱粉の原料として使用することができる。本発明の馬鈴薯澱粉は、未加工の澱粉であっても、加工澱粉であっても、またはそれらの組み合わせであってもよい。加工澱粉としては、例えばα化澱粉、エーテル化澱粉、エステル化澱粉、アセチル化澱粉、架橋処理澱粉等、およびこれらのいずれかの組み合わせが挙げられる。 The variety of potato starch used as a raw material for the starch of the present invention is not particularly limited, but a variety cultivated for starch production is preferable. Examples of such potato varieties include Benimaru, Konayutaka, Konafubuki, Natsufubuki, Sakurafubuki, Astarte, Early Starch, Eniwa and the like. Any one or more of the above potato varieties can be used as a raw material for the potato starch of the present invention. The potato starch of the present invention may be unprocessed starch, modified starch, or a combination thereof. Modified starch includes, for example, pregelatinized starch, etherified starch, esterified starch, acetylated starch, crosslinked starch, and any combination thereof.

本発明の馬鈴薯澱粉は、原料馬鈴薯から澱粉を製造する過程で、澱粉粒の粉砕工程を調整して比較的粒子径の大きな澱粉粒子を製造し、それを分級することで製造してもよく、または、一般的な馬鈴薯澱粉を造粒して粒径の大きな澱粉粒子を調製し、これを必要に応じて分級することによって製造してもよい。あるいは、これらの造粒澱粉および非造粒澱粉を混合して使用してもよい。好ましくは、本発明の馬鈴薯澱粉は造粒澱粉を含む。より好ましくは、本発明の馬鈴薯澱粉は造粒澱粉である。造粒澱粉を含むことにより、本発明の馬鈴薯澱粉の水への分散性が向上する。 The potato starch of the present invention may be produced by adjusting the crushing process of starch granules to produce starch particles having a relatively large particle size in the process of producing starch from the raw material potato starch, and classifying the starch particles. Alternatively, general potato starch may be granulated to prepare starch particles having a large particle size, which may be classified as necessary. Alternatively, these granulated starch and non-granulated starch may be mixed and used. Preferably, the potato starch of the present invention comprises granulated starch. More preferably, the potato starch of the present invention is a granulated starch. By including the granulated starch, the dispersibility of the potato starch of the present invention in water is improved.

本発明の馬鈴薯澱粉を製造する際の分級や造粒処理には、公知の手法を用いることができる。分級の手法としては、例えば、篩を用いた分級や気流式分級機を用いた分級などが挙げられる。造粒の手法としては、例えば、馬鈴薯澱粉を、必要に応じて他の成分とともに水やバインダーを加えて混合し、乾燥させる方法;馬鈴薯澱粉を、必要に応じて他の成分とともにそのまま圧縮し、次いで破砕する方法、などが挙げられる。また造粒の手法としては、転動造粒、流動層造粒、攪拌造粒、噴霧乾燥造粒などを用いることができ、特に限定されないが、簡便性の点からは攪拌造粒が好ましい。上記に挙げた造粒の手法は、いずれも市販の造粒装置を用いることで実施することができる。さらに造粒後に、必要に応じて、整粒処理や乾燥処理を行うこともできる。本発明の馬鈴薯澱粉の製造に用いられる造粒の手法の好ましい例としては、例えば、特開2015−200207号公報、および特開2015−200208号公報(これらの全体が本明細書において参照により援用される)に開示されるものを挙げることができる。 A known method can be used for the classification and granulation treatment in producing the potato starch of the present invention. Examples of the classification method include classification using a sieve and classification using an air flow type classifier. As a granulation method, for example, potato starch is mixed with other components by adding water or a binder and dried; the potato starch is compressed as it is with other components as needed. Then, a method of crushing and the like can be mentioned. Further, as the granulation method, rolling granulation, fluidized bed granulation, stirring granulation, spray drying granulation and the like can be used, and the method is not particularly limited, but stirring granulation is preferable from the viewpoint of convenience. All of the above-mentioned granulation methods can be carried out by using a commercially available granulator. Further, after granulation, if necessary, granulation treatment or drying treatment can be performed. Preferred examples of the granulation method used for producing the potato starch of the present invention include, for example, JP-A-2015-200207 and JP-A-2015-200208 (all of which are incorporated by reference in the present specification). ) Can be mentioned.

本発明の馬鈴薯澱粉は、馬鈴薯澱粉組成物の形態で提供されてもよい。該本発明の馬鈴薯澱粉組成物は、本発明の馬鈴薯澱粉と、それ以外の他の成分、例えば、馬鈴薯以外に由来する澱粉、穀粉、またはその他の原料を含有する。当該馬鈴薯以外に由来する澱粉としては、タピオカ澱粉、コーンスターチ、ワキシーコーンスターチ、小麦澱粉などの澱粉、およびこれらのα化澱粉、エーテル化澱粉、エステル化澱粉、アセチル化澱粉、架橋処理澱粉などの加工澱粉が挙げられる。当該穀粉としては、小麦粉、大麦粉、ライ麦粉、米粉、トウモロコシ粉、ソルガム粉、豆粉などが挙げられる。当該その他の原料としては、活性グルテン等の蛋白質;デキストリン、水飴、糖アルコール等の糖類;塩等の調味料;増粘剤;乳化剤;膨張剤;酵素等が挙げられる。本発明の馬鈴薯澱粉組成物は、上記に挙げた馬鈴薯以外に由来する澱粉、穀粉およびその他の原料から選択される成分のいずれか1種を単独で含有していてもよく、またはいずれか2種以上を含有していてもよい。本発明の馬鈴薯澱粉組成物における当該他の成分の種類および含有量は、該組成物の用途に応じて適宜設定することができる。また本発明の馬鈴薯澱粉組成物において、当該他の成分は、本発明の馬鈴薯澱粉とは別個の粉体として含有されていてもよく、または本発明の馬鈴薯澱粉とともに造粒されていてもよい。本発明の馬鈴薯澱粉組成物における当該他の成分の含有量は、該組成物全量中、好ましくは30質量%以下、より好ましくは15質量%以下、さらに好ましくは8質量%以下である。該馬鈴薯澱粉組成物が衣材である場合、好ましくは、当該他の成分のうち50質量%〜100質量%が上述した穀粉または馬鈴薯以外に由来する澱粉である。したがって、本発明の馬鈴薯澱粉組成物における本発明の馬鈴薯澱粉の含有量は、該組成物全量中、好ましくは70質量%以上、より好ましくは85質量%以上、さらに好ましくは92質量%以上である。 The potato starch of the present invention may be provided in the form of a potato starch composition. The potato starch composition of the present invention contains the potato starch of the present invention and other components, for example, starch, starch, or other raw materials derived from other than potato starch. Examples of starch derived from other than the horse bell sardine include starches such as tapioca starch, corn starch, waxy corn starch, and wheat starch, and processed starches such as pregelatinized starch, etherified starch, esterified starch, acetylated starch, and crosslinked starch. Can be mentioned. Examples of the flour include wheat flour, barley flour, rye flour, rice flour, corn flour, sorghum flour, and soybean flour. Examples of the other raw materials include proteins such as active gluten; sugars such as dextrin, starch syrup, and sugar alcohols; seasonings such as salts; thickeners; emulsifiers; leavening agents; enzymes and the like. The potato starch composition of the present invention may alone contain any one of the components selected from starch, flour and other raw materials derived from other than the potatoes listed above, or any two of them. The above may be contained. The type and content of the other component in the potato starch composition of the present invention can be appropriately set according to the use of the composition. Further, in the potato starch composition of the present invention, the other component may be contained as a powder separate from the potato starch of the present invention, or may be granulated together with the potato starch of the present invention. The content of the other component in the potato starch composition of the present invention is preferably 30% by mass or less, more preferably 15% by mass or less, still more preferably 8% by mass or less, based on the total amount of the composition. When the potato starch composition is a clothing material, preferably 50% by mass to 100% by mass of the other components are starch derived from the above-mentioned grain flour or potatoes other than potato starch. Therefore, the content of the potato starch of the present invention in the potato starch composition of the present invention is preferably 70% by mass or more, more preferably 85% by mass or more, still more preferably 92% by mass or more, based on the total amount of the composition. ..

好ましくは、本発明の馬鈴薯澱粉組成物は、D10が18μm以上かつD90が900μm未満であり、D90/D10が4.0〜17.0である。好ましくは、本発明の馬鈴薯澱粉組成物は、D10が20μm以上かつD90が800μm未満であり、さらに好ましくはD10が25μm以上かつD90が620μm未満である。また、本発明の馬鈴薯澱粉組成物のD90/D10は、好ましくは5.0〜12.0、さらに好ましくは6.0〜10.0である。さらに好ましくは、本発明の馬鈴薯澱粉組成物は、D10が18〜100μmかつD90が72〜900μmであって、D90/D10が4.0〜17.0である。さらに好ましくは、本発明の馬鈴薯澱粉組成物は、D10が20〜90μmかつD90が100〜800μmであって、かつD90/D10が5.0〜12.0である。さらに好ましくは、本発明の馬鈴薯澱粉組成物は、D10が25〜80μmかつD90が150〜620μmであって、かつD90/D10が6.0〜10.0である。 Preferably, the potato starch composition of the present invention has a D10 of 18 μm or more and a D90 of less than 900 μm, and a D90 / D10 of 4.0 to 17.0. Preferably, the potato starch composition of the present invention has a D10 of 20 μm or more and a D90 of less than 800 μm, and more preferably a D10 of 25 μm or more and a D90 of less than 620 μm. The potato starch composition of the present invention has a D90 / D10 of preferably 5.0 to 12.0, more preferably 6.0 to 10.0. More preferably, the potato starch composition of the present invention has a D10 of 18 to 100 μm, a D90 of 72 to 900 μm, and a D90 / D10 of 4.0 to 17.0. More preferably, the potato starch composition of the present invention has a D10 of 20 to 90 μm, a D90 of 100 to 800 μm, and a D90 / D10 of 5.0 to 12.0. More preferably, the potato starch composition of the present invention has a D10 of 25 to 80 μm, a D90 of 150 to 620 μm, and a D90 / D10 of 6.0 to 10.0.

また好ましくは、本発明の馬鈴薯澱粉組成物は、粒径10〜900μmの粒子を体積基準で99%以上含有する。本発明の馬鈴薯澱粉組成物の体積平均径(MV)は、好ましくは40〜700μm、より好ましくは60〜500μm、さらに好ましくは80〜300μm、さらに好ましくは80〜220μmである。 Further, preferably, the potato starch composition of the present invention contains 99% or more of particles having a particle size of 10 to 900 μm on a volume basis. The volume mean diameter (MV) of the potato starch composition of the present invention is preferably 40 to 700 μm, more preferably 60 to 500 μm, still more preferably 80 to 300 μm, still more preferably 80 to 220 μm.

本発明の馬鈴薯澱粉またはそれを含む馬鈴薯澱粉組成物(まとめて、本発明の馬鈴薯澱粉または組成物と称する)は、調理用の澱粉として使用され得る。例えば、本発明の馬鈴薯澱粉または組成物は、食品のとろみ付け材として、例えばスープやソースの製造等に使用することができる。また本発明の馬鈴薯澱粉または組成物は、ムニエル等の焼き物もしくはから揚げやフライ等の揚げ物の衣材として、揚げ物の具材の打ち粉として、または加熱調理前の食材のコーティング材として使用することができる。しかし、これらの用途に限定されることなく、本発明の馬鈴薯澱粉または組成物は、調理用の澱粉の一般的な用途に使用することができる。好ましくは、本発明の馬鈴薯澱粉または組成物は、食品のとろみ付け材または揚げ物(好ましくはから揚げ)用の衣材として使用される。 The potato starch of the present invention or a potato starch composition containing the same (collectively referred to as the potato starch or composition of the present invention) can be used as a starch for cooking. For example, the potato starch or composition of the present invention can be used as a thickening material for foods, for example, in the production of soups and sauces. Further, the horse roast starch or composition of the present invention shall be used as a batter for roasted foods such as Meuniere or fried foods such as fried chicken and fried foods, as dusting ingredients for fried foods, or as a coating material for ingredients before cooking. Can be done. However, without being limited to these uses, the potato starch or composition of the present invention can be used for general uses of starch for cooking. Preferably, the potato starch or composition of the present invention is used as a batter for a food thickener or fried food (preferably fried chicken).

本発明の馬鈴薯澱粉または組成物を用いて食品をとろみ付けする場合、本発明の馬鈴薯澱粉または組成物をとろみ付けする対象食品に直接添加し、混合すればよい。とろみ付けする対象食品に対する該馬鈴薯澱粉または組成物の添加量は、好ましくは対象食品100質量部に対して0.5〜10質量部程度である。とろみ付けの際、該対象食品に添加する本発明の馬鈴薯澱粉または組成物を予め水に分散させておく(水溶きする)必要はない。とろみ付けする対象食品の例としては、特に限定されないが、スープ、ソースなどの液状食品が挙げられる。好ましくは、該対象食品は、本発明の馬鈴薯澱粉または組成物を添加する前に加熱されている。この熱せられた食品に直接本発明の馬鈴薯澱粉または組成物を添加し、混合すれば、ダマを生じることなく該食品をとろみ付けすることができる。 When a food is thickened using the potato starch or composition of the present invention, the potato starch or composition of the present invention may be added directly to the target food to be thickened and mixed. The amount of the potato starch or composition added to the target food to be thickened is preferably about 0.5 to 10 parts by mass with respect to 100 parts by mass of the target food. At the time of thickening, it is not necessary to disperse (water-soluble) the potato starch or composition of the present invention to be added to the target food in water in advance. Examples of the target food to be thickened include, but are not limited to, liquid foods such as soups and sauces. Preferably, the subject food is heated prior to the addition of the potato starch or composition of the present invention. If the potato starch or composition of the present invention is added directly to the heated food and mixed, the food can be thickened without causing lumps.

本発明の馬鈴薯澱粉または組成物を用いてから揚げを製造する場合、本発明の馬鈴薯澱粉または組成物を、具材に直接または打ち粉した具材にまぶして付着させ、次いで、本発明の馬鈴薯澱粉または組成物が付着した具材を油ちょうすればよい。本発明の馬鈴薯澱粉または組成物の具材に対する付着量は、具材100質量部に対して、好ましくは3〜30質量部程度である。本発明の馬鈴薯澱粉または組成物は、まぶしタイプの衣材(から揚げ粉)として使用される。衣材として本発明の馬鈴薯澱粉または組成物を用いることで、衣が剥がれにくく、表面の粉吹きした部分を保った良好な外観を有するから揚げを製造することができる。本明細書において、から揚げの「粉吹き」とは、揚げ上がったから揚げの表面に白く粉をふいたような部位がある状態をいう。粉吹きしたから揚げは、表面における粉吹きした部位の白っぽい色とそれ以外の部位の色(暗灰色、キツネ色、濃茶色、褐色、黒色等)とのコントラストのためにより立体的に見え、また粉吹きにより表面の色が艶消し状になって油っぽくないように見えることから、より食欲をそそる外観となる。 When fried chicken is produced using the potato starch or composition of the present invention, the potato starch or composition of the present invention is directly attached to the ingredient or sprinkled on the dusted ingredient, and then the potato starch of the present invention is used. Ingredients to which starch or composition is attached may be oiled. The amount of the potato starch or composition of the present invention adhered to the ingredients is preferably about 3 to 30 parts by mass with respect to 100 parts by mass of the ingredients. The potato starch or composition of the present invention is used as a batter-type batter (fried chicken powder). By using the potato starch or composition of the present invention as the batter material, the batter is hard to peel off and has a good appearance while maintaining the powdered portion of the surface, so that fried chicken can be produced. As used herein, the term "powder-blown" of deep-fried chicken refers to a state in which the surface of deep-fried deep-fried chicken has a white powder-like portion. The powdered fried food looks more three-dimensional due to the contrast between the whitish color of the powdered part on the surface and the color of other parts (dark gray, fox color, dark brown, brown, black, etc.). The powder spray makes the surface color matte and looks non-greasy, giving it a more appetizing appearance.

本発明の馬鈴薯澱粉または組成物は、従来の澱粉と同様に包装袋などの容器から取り出して使用することができる。さらに、本発明の馬鈴薯澱粉または組成物を振出し容器に充填し、そこから振り出して使用すると、必要な分量を簡便に容器から取り出して食品に適用することができるため、調理での操作性がさらに向上する。本発明の馬鈴薯澱粉または組成物は、容器から取り出すときに粉の飛散が少なく、また振出し容器の振出し孔を目詰まりさせることもないため、振出し容器から少量ずつ振り出して使用することに適している。 The potato starch or composition of the present invention can be taken out from a container such as a packaging bag and used in the same manner as conventional starch. Furthermore, when the potato starch or composition of the present invention is filled in a shaker container and then shaken out and used, the required amount can be easily taken out of the container and applied to food, so that operability in cooking is further improved. improves. The potato starch or composition of the present invention is suitable for use by squeezing out the powder little by little from the squeezing container because the powder is less scattered when taken out from the container and the squeezing holes of the squeezing container are not clogged. ..

本発明の馬鈴薯澱粉または組成物を充填する振出し容器としては、振出し孔を1つ以上有する振出し容器を例示することができる。当該振出し容器は、片手で持ち上げて内部の馬鈴薯澱粉の振出し操作を行うことのできる大きさおよび形状の容器であればよく、例えば、一般的な調味料容器や香辛料容器のような大きさおよび形状の容器が好ましい。より詳細には、直径または一辺の長さが20〜100mm、高さ80〜200mm程度の円柱状、楕円柱状、角柱状、またはそれらを組み合わせた形状で、50〜500g程度の本発明の馬鈴薯澱粉または組成物を充填できる大きさを有する自立型の容器であることが好ましい。容器の素材としては、粉体を保存可能であって、かつ振出し操作の際に変形しない素材であれば特に限定されず、例えばプラスチック、金属、紙などが挙げられる。 As a drawing container for filling the potato starch or the composition of the present invention, a drawing container having one or more drawing holes can be exemplified. The drawing container may be a container having a size and shape that can be lifted with one hand to shake out the potato starch inside. For example, the size and shape of a general seasoning container or spice container can be used. Container is preferable. More specifically, the potato starch of the present invention having a diameter or a side length of about 20 to 100 mm, a height of about 80 to 200 mm, a columnar shape, an elliptical columnar shape, a prismatic shape, or a combination thereof, and about 50 to 500 g. Alternatively, it is preferably a self-standing container having a size capable of filling the composition. The material of the container is not particularly limited as long as it can store powder and does not deform during the drawing operation, and examples thereof include plastic, metal, and paper.

当該振出し容器の1つ以上の振出し孔の形状は、特に限定されないが、円形、三角形、四角形、多角形などが挙げられる。該1つ以上の振出し孔の各々の大きさは、最大幅として、好ましくは2〜20mm、より好ましくは3〜12mm、さらに好ましくは4〜8mmであり、また該振出し孔の数は、好ましくは2〜9個、より好ましくは4〜7個である。該振出し孔の大きさが小さすぎる場合や孔の数が少ない場合、振出し量が過少になりやすいか、または孔が粉体で詰まりやすくなり、逆に該振出し孔の大きさが多すぎる場合や孔の数が多い場合、一度の振出し操作で多量の粉体が振り出されて、粉体が対象に過剰に振りかかるかまたは必要以上に使用されて経済性が低下するだけでなく、粉体が飛散して周辺を汚損しやすくなる。 The shape of one or more drawing holes of the drawing container is not particularly limited, and examples thereof include a circle, a triangle, a quadrangle, and a polygon. The size of each of the one or more outlet holes is preferably 2 to 20 mm, more preferably 3 to 12 mm, still more preferably 4 to 8 mm as the maximum width, and the number of the outlet holes is preferably. The number is 2 to 9, more preferably 4 to 7. If the size of the drawing holes is too small or the number of holes is small, the amount of drawing is likely to be too small, or the holes are likely to be clogged with powder, and conversely, the size of the drawing holes is too large. When the number of holes is large, a large amount of powder is shaken out by one shaking operation, and the powder is not only sprinkled excessively on the target or used more than necessary, which not only reduces the economic efficiency but also the powder. Is scattered and the surrounding area is easily soiled.

好適な例において、当該振出し容器は、直径2〜20mmの円形の振出し孔を2〜9個、好ましくは4〜7個有し、より好ましくは直径3〜12mmの円形の振出し孔を2〜9個、さらに好ましくは4〜7個有し、なお好ましくは直径4〜8mmの円形の振出し孔を4〜7個有する。別の好適な例において、本発明に使用される振出し容器は、対角線長さ2〜20mmの略四角形もしくは略多角形の振出し孔を2〜9個、好ましくは4〜7個有し、より好ましくは対角線長さ3〜12mmの略四角形もしくは略多角形の振出し孔を2〜9個、さらに好ましくは4〜7個有し、なお好ましくは対角線長さ4〜8mmの略四角形もしくは略多角形の振出し孔を4〜7個有する。 In a preferred example, the drawing vessel has 2-9, preferably 4-7 circular drawing holes with a diameter of 2-20 mm, more preferably 2-9 circular drawing holes with a diameter of 3-12 mm. It has, more preferably 4 to 7, and even more preferably 4 to 7 circular swing holes having a diameter of 4 to 8 mm. In another preferred example, the drawing vessel used in the present invention has 2-9, preferably 4-7, substantially quadrangular or substantially polygonal drawing holes with a diagonal length of 2 to 20 mm, more preferably. Has 2 to 9, more preferably 4 to 7, substantially quadrangular or approximately polygonal swing holes with a diagonal length of 3 to 12 mm, and more preferably a substantially quadrangular or approximately polygonal diagonal length of 4 to 8 mm. It has 4 to 7 swing holes.

さらに、当該振出し容器は、上記1つ以上の振出し孔とは別に、スプーン取出し部を備えていてもよい。当該スプーン取出し部は、該容器から計量スプーンや茶さじなどにより内部の粉体を取出す際に、あるいはまとまった量の粉体を該容器から振り出す際の取出し口として使用され得る。好ましくは、当該振出し容器において、該スプーン取出し部は、該1つ以上の振出し孔とは離れた位置に配置される。例えば、振出し容器の天面上で、一端に振出し孔を配置し、そこから90〜180°ずれた側にスプーン取出し部を設けることができる。 Further, the drawing container may be provided with a spoon taking-out portion in addition to the one or more drawing holes. The spoon take-out portion can be used as a take-out port when taking out the powder inside from the container with a measuring spoon, a tea spoon, or the like, or when drawing out a large amount of powder from the container. Preferably, in the drawing container, the spoon take-out portion is arranged at a position away from the one or more drawing holes. For example, on the top surface of the drawing container, a drawing hole can be arranged at one end, and a spoon take-out portion can be provided on the side deviated from the drawing hole by 90 to 180 °.

当該振出し容器の1つ以上の振出し孔およびスプーン取出し部は、好ましくは開閉可能である。好ましくは、該振出し孔およびスプーン取出し部は、開閉可能な蓋を備えている。当該蓋は、該振出し容器に充填された粉体の吸湿を防止することができ、また昆虫などの異物が容器内に侵入することを防止することができる。当該蓋の種類は特に限定されないが、片手で簡便に開閉可能な蓋、例えば、スライド蓋やフラップ蓋が好ましい。また好ましくは、該振出し孔の蓋は、複数の振出し孔を一度に開閉することができる1つの蓋である。該1つ以上の振出し孔の蓋と該スプーン取出し部の蓋とは、共通の蓋であっても独立した別々の蓋であってもよいが、いずれの場合も、該1つ以上の振出し孔と該スプーン取出し部とが同時に開口しないようにできる構造であることが好ましい。例えば、該1つ以上の振出し孔の蓋と該スプーン取出し部の蓋とは、独立して開閉可能な2つのフラップ蓋である。またあるいは、該1つ以上の振出し孔の蓋と該スプーン取出し部の蓋は、該振出し孔と該スプーン取出し部の少なくとも一方が閉じるように動く1つの共通したスライド蓋である。 One or more drawing holes and spoon take-out portions of the drawing container are preferably openable and closable. Preferably, the swing hole and the spoon take-out portion are provided with a lid that can be opened and closed. The lid can prevent the powder filled in the drawing container from absorbing moisture, and can prevent foreign substances such as insects from entering the container. The type of the lid is not particularly limited, but a lid that can be easily opened and closed with one hand, for example, a slide lid or a flap lid is preferable. Also preferably, the lid of the drawing hole is one lid that can open and close a plurality of drawing holes at once. The lid of the one or more swing holes and the lid of the spoon take-out portion may be a common lid or an independent lid, but in either case, the one or more swing holes. It is preferable that the structure is such that the spoon take-out portion and the spoon take-out portion do not open at the same time. For example, the lid of the one or more swing holes and the lid of the spoon take-out portion are two flap lids that can be opened and closed independently. Alternatively, the lid of the one or more swing holes and the lid of the spoon take-out portion are one common slide lid that moves so that at least one of the swing hole and the spoon take-out portion is closed.

好ましくは、本発明の馬鈴薯澱粉または組成物を当該振出し容器から振り出した場合、容器を振り下ろすことなく容器を180度回転させてその振出し孔のある面を真上から真下に向ける1回の振出し操作で、振出し孔より15cm直下の食品に本発明の馬鈴薯澱粉または組成物を適用するのに丁度よい範囲と量で、例えば直径約10cmの円の範囲内に約1.5〜4g程度、振り出すことができる。より多くの量でまたはより広範囲に本発明の馬鈴薯澱粉または組成物を容器から振り出す場合は、振出し操作を繰り返したり、より強く振出し操作を行えばよい。 Preferably, when the potato starch or composition of the present invention is shaken out from the drawing container, the container is rotated 180 degrees without swinging down the container, and the surface having the drawing hole is directed from directly above to directly below. By operation, shake the potato starch or composition of the present invention in a range and amount just right for applying the potato starch or composition of the present invention to a food product 15 cm below the drawing hole, for example, about 1.5 to 4 g within a circle having a diameter of about 10 cm. Can be put out. When the potato starch or composition of the present invention is shaken out of the container in a larger amount or in a wider range, the shaking operation may be repeated or the shaking operation may be performed more strongly.

次に本発明をさらに具体的に説明するために実施例を掲げるが、本発明は以下の実施例のみに限定されるものではない。なお、以下の実施例において、粉体のD10、D90およびMVはマイクロトラックMT3000II(日機装株式会社)を用いた乾式のレーザー回折・散乱法により算出された値である。 Next, examples will be given to more specifically explain the present invention, but the present invention is not limited to the following examples. In the following examples, the powders D10, D90 and MV are values calculated by a dry laser diffraction / scattering method using Microtrack MT3000II (Nikkiso Co., Ltd.).

〔製造例〕
(馬鈴薯澱粉の調製:製造例1〜13)
原料の馬鈴薯澱粉(市販品、D10;19μm、D90;55μm、体積平均径(MV);37μm)1kgを容器に入れ、ハンドミキサーで攪拌しながら霧吹きで加水し、その後恒温槽で乾燥して、以下の造粒馬鈴薯澱粉A〜Eを製造した。
_________________________________
D10 D90 体積平均径(MV)
造粒馬鈴薯澱粉A:19μm 195μm 85μm
造粒馬鈴薯澱粉B:20μm 273μm 148μm
造粒馬鈴薯澱粉C:24μm 392μm 231μm
造粒馬鈴薯澱粉D:41μm 538μm 288μm
造粒馬鈴薯澱粉E:55μm 1020μm 802μm

これらの造粒馬鈴薯澱粉粉A〜Eと原料の馬鈴薯澱粉とを混合して、表1に記載の粒度分布を有する馬鈴薯澱粉を調製した(製造例1〜13)。
[Manufacturing example]
(Preparation of potato starch: Production Examples 1 to 13)
1 kg of raw material potato starch (commercially available, D10; 19 μm, D90; 55 μm, volume average diameter (MV); 37 μm) was placed in a container, watered by spraying with stirring with a hand mixer, and then dried in a constant temperature bath. The following granulated potato starches A to E were produced.
______________________________
D10 D90 Volume Mean Free Path (MV)
Granulated potato starch A: 19 μm 195 μm 85 μm
Granulated potato starch B: 20 μm 273 μm 148 μm
Granulated potato starch C: 24 μm 392 μm 231 μm
Granulated potato starch D: 41 μm 538 μm 288 μm
Granulated potato starch E: 55 μm 1020 μm 802 μm

These granulated potato starches A to E and the raw material potato starch were mixed to prepare potato starch having the particle size distribution shown in Table 1 (Production Examples 1 to 13).

(馬鈴薯澱粉組成物の調製:製造例14〜18)
製造例5の馬鈴薯澱粉と表2に記載の原料を混合して馬鈴薯澱粉組成物を調製した(製造例14〜18)。
(Preparation of potato starch composition: Production Examples 14-18)
The potato starch composition of Production Example 5 was mixed with the raw materials shown in Table 2 to prepare a potato starch composition (Production Examples 14 to 18).

〔試験例〕
下記試験例1および2により、製造例1〜18の馬鈴薯澱粉および馬鈴薯澱粉組成物を評価した。
(試験例1:食品のとろみ付けにおける性能評価)
直径15cmの鍋に200mLの水を張り、ガスコンロで沸騰するまで加熱した後、弱火にして軽く煮立った状態を維持した。この鍋に、製造例1〜18の馬鈴薯澱粉または馬鈴薯澱粉組成物を大さじ1杯、水面全体に万遍なく散らばるように投入し、すぐに菜箸で2回/秒で20回転撹拌した。参考例として、製造例で用いた原料の馬鈴薯澱粉または造粒馬鈴薯澱粉Eを用いて同様の操作を行った。得られたとろみの状態を下記基準に従って評価した。とろみの製造および評価は、10名の専門パネラーが行った。10名の専門パネラーによる評価結果の平均点を、表1および2に示す。
[Test example]
The potato starch and potato starch compositions of Production Examples 1 to 18 were evaluated according to Test Examples 1 and 2 below.
(Test Example 1: Performance evaluation in thickening of food)
A pot with a diameter of 15 cm was filled with 200 mL of water, heated on a gas stove until it boiled, and then reduced to low heat to maintain a lightly boiled state. One tablespoon of potato starch or potato starch composition of Production Examples 1 to 18 was put into this pan so as to be evenly scattered over the entire water surface, and immediately stirred with chopsticks twice / second for 20 rotations. As a reference example, the same operation was carried out using the raw material potato starch or granulated potato starch E used in the production example. The state of thickening obtained was evaluated according to the following criteria. Thickening was manufactured and evaluated by 10 professional panelists. Tables 1 and 2 show the average score of the evaluation results by 10 specialized panelists.

(とろみの状態の評価基準)
5点:ダマが生じることなく、あんかけ状のとろみが付く。極めて良好。
4点:ダマがほとんど生じず、あんかけ状のとろみが付く。良好。
3点:部分的にダマが溶けずに残るが、あんかけ状のとろみはある。やや良好。
2点:溶けないダマが多く残り、とろみは緩い。やや不良。
1点:投入した澱粉のほとんどがダマや塊になり、とろみはほとんど付かない。不良。
(Evaluation criteria for thickening condition)
5 points: Ankake-like thickening without lumps. Very good.
4 points: Almost no lumps occur, and ankake-like thickening is added. Good.
3 points: The lumps remain partially unmelted, but there is ankake-like thickening. Somewhat good.
2 points: A lot of unmelted lumps remain, and the thickening is loose. Somewhat bad.
1 point: Most of the starch added becomes lumps and lumps, and there is almost no thickening. Bad.

(試験例2:揚げ物の衣材としての性能評価)
鶏もも肉を1個20gとなるよう切り分けて具材とした。この具材に、製造例1〜18の馬鈴薯澱粉または馬鈴薯澱粉組成物を肉100gあたりの付着量が15gになるよう振り掛けて付着させ、次いで170℃に熱したサラダ油で3分間油ちょうしてから揚げを製造した。参考例として、製造例で用いた原料の馬鈴薯澱粉を用いて同様の手順でから揚げを製造した。得られたから揚げを皿に盛り付けて喫食し、油ちょうから喫食までの間の衣の外観を評価した。評価は、10名の専門パネラーにより下記評価基準で行った。10名の専門パネラーによる評価結果の平均点を、表1および2に示す。
(Test Example 2: Performance evaluation of fried food as batter)
Each chicken thigh was cut into 20g pieces and used as ingredients. The potato starch or potato starch composition of Production Examples 1 to 18 is sprinkled on this ingredient so that the amount of adhesion per 100 g of meat is 15 g, and then oiled with salad oil heated to 170 ° C. for 3 minutes and then fried. Manufactured. As a reference example, fried chicken was produced by the same procedure using potato starch as a raw material used in the production example. The obtained fried food was served on a plate and eaten, and the appearance of the batter from the oil bowl to the eating was evaluated. The evaluation was carried out by 10 specialized panelists according to the following evaluation criteria. Tables 1 and 2 show the average score of the evaluation results by 10 specialized panelists.

(から揚げ衣の外観の評価基準)
5点:油ちょうにより表面全体に粉吹きのある衣が得られ、盛り付けおよび喫食の際に衣と粉吹き部分の脱落がない。極めて良好。
4点:油ちょうにより表面全体に粉吹きのある衣が得られたが、盛付け中に衣の一部が具材とずれる。良好。
3点:油ちょうにより表面全体に粉吹きのある衣が得られたが、盛付け中に衣の一部が具材から剥がれる。やや良好。
2点:油ちょう中に粉吹きした部位が一部脱落し、やや不良な外観。
1点:油ちょう中に粉吹きした部位の多くが脱落し、不良な外観。
(Evaluation criteria for the appearance of karaage batter)
5 points: The batter with powder blown on the entire surface is obtained by oiling, and the batter and powder blown part do not come off during serving and eating. Very good.
4 points: A batter with powder spray on the entire surface was obtained by oiling, but a part of the batter was misaligned with the ingredients during serving. Good.
3 points: A batter with powder spray on the entire surface was obtained by oiling, but a part of the batter peeled off from the ingredients during serving. Somewhat good.
2 points: Part of the powder sprayed part fell off in the oil pan, giving a slightly poor appearance.
1 point: Most of the powder-blown parts in the oil pan have fallen off, resulting in a poor appearance.

Figure 2019156097
Figure 2019156097

Figure 2019156097
Figure 2019156097

(試験例3:振出し容器入り馬鈴薯澱粉)
製造例7の馬鈴薯澱粉を、直径50mm、高さ120mmの上部が開放した円筒容器に100g充填した後、該容器の天面に表3に記載の直径と振出し孔数を有する直径50mm、厚さ0.2mmの円形プラスチック板をはめ込み、振出し容器入り馬鈴薯澱粉を製造した。この振出し容器入り馬鈴薯澱粉を用いて、試験例1と同様の手順でとろみを製造し、その際の操作性を下記基準に従って評価した。とろみの製造では、鍋に大さじ1杯の馬鈴薯澱粉を投入する代わりに、鍋の15cm上で振出し容器からの振出し操作(容器を180度回転させて振出し孔を下に向ける操作)を5回行って馬鈴薯澱粉を投入した。参考例として、製造例で用いた原料の馬鈴薯澱粉を用いて同様の評価を行った。とろみの製造および評価は、10名の専門パネラーが行った。10名の専門パネラーによる評価結果の平均点を、表3に示す。
(Test Example 3: Potato starch in a drawing container)
After filling 100 g of potato starch of Production Example 7 in a cylindrical container having a diameter of 50 mm and a height of 120 mm and an open top, the top surface of the container has the diameter and the number of drawing holes shown in Table 3 and has a diameter of 50 mm and a thickness. A 0.2 mm circular plastic plate was fitted to produce potato starch in a drawing container. Using this potato starch in a drawing container, a thickened product was produced in the same procedure as in Test Example 1, and the operability at that time was evaluated according to the following criteria. In the production of thickening, instead of putting 1 tablespoon of potato starch into the pot, the operation of shaking from the drawing container (the operation of rotating the container 180 degrees and turning the drawing hole downward) is performed 5 times on 15 cm of the pot. The potato starch was added. As a reference example, the same evaluation was carried out using potato starch as a raw material used in the production example. Thickening was manufactured and evaluated by 10 professional panelists. Table 3 shows the average score of the evaluation results by 10 specialized panelists.

(とろみ製造時の操作性の評価基準)
5点:振り出された粉が鍋内の直径10cm程度の範囲に散らばり、ダマのないあんかけ状のとろみが得られた。極めて良好。
4点:振り出された粉が鍋内に散らばり、ダマのないほぼあんかけ状のとろみが得られた。良好。
3点:振り出された粉がやや狭い範囲に散らばるか、またはわずかに鍋の外に飛散する。とろみはやや緩いもしくはやや強いか、またはわずかにダマがある。やや良好。
2点:振り出された粉が狭い範囲に散らばるか、または鍋の外に飛散する。とろみは緩いもしくは強いか、またはダマがある。やや不良。
1点:振り出された粉が狭い範囲に集中して大きなダマになるか、または鍋の外に広く飛散する。とろみはほとんど付かない。不良。
(Evaluation criteria for operability during thick manufacturing)
5 points: The powder that was shaken out was scattered in a pot with a diameter of about 10 cm, and an ankake-like thickening without lumps was obtained. Very good.
4 points: The powder that was sprinkled out was scattered in the pan, and an almost lump-free thickening was obtained. Good.
3 points: The powder that has been sprinkled out is scattered in a slightly narrow area or slightly scattered out of the pan. Thickness is slightly loose or slightly strong, or slightly lumpy. Somewhat good.
2 points: The sprinkled powder is scattered in a narrow area or scattered out of the pot. Thick is loose or strong, or lumpy. Somewhat bad.
1 point: The powder that has been sprinkled is concentrated in a narrow area and becomes a large lump, or it is widely scattered outside the pot. There is almost no thickening. Bad.

Figure 2019156097
Figure 2019156097

Claims (15)

D10が18μm以上かつD90が900μm未満であり、D90/D10が4.0〜17.0である馬鈴薯澱粉。 Potato starch having a D10 of 18 μm or more and a D90 of less than 900 μm, and a D90 / D10 of 4.0 to 17.0. 造粒澱粉を含む、請求項1記載の馬鈴薯澱粉。 The potato starch according to claim 1, which comprises granulated starch. 体積平均径が40〜700μmである、請求項1又は2記載の馬鈴薯澱粉。 The potato starch according to claim 1 or 2, wherein the volume average diameter is 40 to 700 μm. 振出し容器に充填されている、請求項1〜3のいずれか1項記載の馬鈴薯澱粉。 The potato starch according to any one of claims 1 to 3, which is filled in a drawing container. 前記振出し容器が最大幅2〜20mmの振出し孔を2〜9個有する、請求項4記載の馬鈴薯澱粉。 The potato starch according to claim 4, wherein the drawing container has 2 to 9 drawing holes having a maximum width of 2 to 20 mm. 請求項1〜3のいずれか1項記載の馬鈴薯澱粉を70質量%以上含有する、馬鈴薯澱粉組成物。 A potato starch composition containing 70% by mass or more of the potato starch according to any one of claims 1 to 3. 振出し容器に充填されている、請求項6記載の馬鈴薯澱粉組成物。 The potato starch composition according to claim 6, which is filled in a drawing container. 前記振出し容器が最大幅2〜20mmの振出し孔を2〜9個有する、請求項7記載の馬鈴薯澱粉組成物。 The potato starch composition according to claim 7, wherein the drawing container has 2 to 9 drawing holes having a maximum width of 2 to 20 mm. 請求項1〜3のいずれか1項記載の馬鈴薯澱粉又は請求項6記載の馬鈴薯澱粉組成物を対象食品に直接添加して混合することを含む、食品のとろみ付け方法。 A method for thickening a food, which comprises directly adding and mixing the potato starch according to any one of claims 1 to 3 or the potato starch composition according to claim 6 to the target food. 請求項1〜3のいずれか1項記載の馬鈴薯澱粉又は請求項6記載の馬鈴薯澱粉組成物を具材にまぶして付着させることを含む、から揚げの製造方法。 A method for producing fried chicken, which comprises sprinkling and adhering the potato starch according to any one of claims 1 to 3 or the potato starch composition according to claim 6 to the ingredients. 前記馬鈴薯澱粉または馬鈴薯澱粉組成物を振出し容器から振出して使用する、請求項9又は10記載の方法。 The method according to claim 9 or 10, wherein the potato starch or the potato starch composition is shaken out from a drawing container and used. 前記振出し容器が最大幅2〜20mmの振出し孔を2〜9個有する、請求項11記載の方法。 The method according to claim 11, wherein the drawing container has 2 to 9 drawing holes having a maximum width of 2 to 20 mm. 食品のとろみ付け材またはから揚げ用衣材としての、請求項1〜3のいずれか1項記載の馬鈴薯澱粉または請求項6記載の馬鈴薯澱粉組成物の使用。 Use of the potato starch according to any one of claims 1 to 3 or the potato starch composition according to claim 6 as a thickening material for food or a batter for deep-fried chicken. 前記馬鈴薯澱粉または馬鈴薯澱粉組成物を振出し容器から振出して使用する、請求項13記載の使用。 The use according to claim 13, wherein the potato starch or the potato starch composition is shaken out from a drawing container and used. 前記振出し容器が最大幅2〜20mmの振出し孔を2〜9個有する、請求項14記載の使用。
The use according to claim 14, wherein the drawing container has 2 to 9 drawing holes having a maximum width of 2 to 20 mm.
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JPS57144952A (en) * 1981-02-28 1982-09-07 Hokuren Nogyo Kyodo Kumiai Rengokai Preparation of granular potato starch
JPH0597901A (en) * 1991-10-02 1993-04-20 Marusan Yoshidasaneo Shoten:Kk Production of granular potato starch and producing machine
JP2000350561A (en) * 1999-06-11 2000-12-19 Nisshin Flour Milling Co Ltd Powder for deep-fried food
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