JPWO2019141568A5 - - Google Patents
Download PDFInfo
- Publication number
- JPWO2019141568A5 JPWO2019141568A5 JP2020539813A JP2020539813A JPWO2019141568A5 JP WO2019141568 A5 JPWO2019141568 A5 JP WO2019141568A5 JP 2020539813 A JP2020539813 A JP 2020539813A JP 2020539813 A JP2020539813 A JP 2020539813A JP WO2019141568 A5 JPWO2019141568 A5 JP WO2019141568A5
- Authority
- JP
- Japan
- Prior art keywords
- methyl
- bis
- methylimidazolium
- melting composition
- ice melting
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 claims description 110
- 238000002844 melting Methods 0.000 claims description 83
- -1 Tributyl Octyl Chemical group 0.000 claims description 45
- 239000002904 solvent Substances 0.000 claims description 30
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L MgCl2 Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims description 24
- 239000002608 ionic liquid Substances 0.000 claims description 21
- 230000005496 eutectics Effects 0.000 claims description 20
- LYCAIKOWRPUZTN-UHFFFAOYSA-N glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 20
- 239000010426 asphalt Substances 0.000 claims description 16
- 239000000654 additive Substances 0.000 claims description 14
- 230000000996 additive Effects 0.000 claims description 14
- XIYUIMLQTKODPS-UHFFFAOYSA-M 1-ethyl-3-methylimidazol-3-ium;acetate Chemical compound CC([O-])=O.CC[N+]=1C=CN(C)C=1 XIYUIMLQTKODPS-UHFFFAOYSA-M 0.000 claims description 12
- 239000003795 chemical substances by application Substances 0.000 claims description 12
- 150000003949 imides Chemical class 0.000 claims description 12
- 229910001629 magnesium chloride Inorganic materials 0.000 claims description 12
- 239000002270 dispersing agent Substances 0.000 claims description 11
- AKDNDOBRFDICST-UHFFFAOYSA-N methylazanium;methyl sulfate Chemical compound [NH3+]C.COS([O-])(=O)=O AKDNDOBRFDICST-UHFFFAOYSA-N 0.000 claims description 10
- 230000015572 biosynthetic process Effects 0.000 claims description 8
- RTZKZFJDLAIYFH-UHFFFAOYSA-N diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 8
- 238000005755 formation reaction Methods 0.000 claims description 8
- KFZMGEQAYNKOFK-UHFFFAOYSA-N iso-propanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 8
- DNIAPMSPPWPWGF-UHFFFAOYSA-N propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 8
- 125000001889 triflyl group Chemical group FC(F)(F)S(*)(=O)=O 0.000 claims description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
- NJMWOUFKYKNWDW-UHFFFAOYSA-N 1-ethyl-3-methylimidazolium Chemical compound CCN1C=C[N+](C)=C1 NJMWOUFKYKNWDW-UHFFFAOYSA-N 0.000 claims description 6
- XEKOWRVHYACXOJ-UHFFFAOYSA-N acetic acid ethyl ester Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 6
- CSCPPACGZOOCGX-UHFFFAOYSA-N acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 6
- BDAGIHXWWSANSR-UHFFFAOYSA-N formic acid Chemical compound OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 claims description 6
- ODGCEQLVLXJUCC-UHFFFAOYSA-N tetrafluoroborate Chemical compound F[B-](F)(F)F ODGCEQLVLXJUCC-UHFFFAOYSA-N 0.000 claims description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-M chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 5
- PXELHGDYRQLRQO-UHFFFAOYSA-N 1-butyl-1-methylpyrrolidin-1-ium Chemical compound CCCC[N+]1(C)CCCC1 PXELHGDYRQLRQO-UHFFFAOYSA-N 0.000 claims description 4
- LSBXQLQATZTAPE-UHFFFAOYSA-N 1-butyl-3-methylimidazol-3-ium;tetrafluoroborate Chemical compound F[B-](F)(F)F.CCCC[N+]=1C=CN(C)C=1 LSBXQLQATZTAPE-UHFFFAOYSA-N 0.000 claims description 4
- GXZCAMSPWNHTAE-UHFFFAOYSA-N 1-methyl-3-octylimidazol-1-ium;tetrafluoroborate Chemical compound F[B-](F)(F)F.CCCCCCCCN1C=C[N+](C)=C1 GXZCAMSPWNHTAE-UHFFFAOYSA-N 0.000 claims description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Natural products CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 4
- VZGDMQKNWNREIO-UHFFFAOYSA-N Carbon tetrachloride Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 claims description 4
- MVPPADPHJFYWMZ-UHFFFAOYSA-N Chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 claims description 4
- MTHSVFCYNBDYFN-UHFFFAOYSA-N Diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 4
- UEGPKNKPLBYCNK-UHFFFAOYSA-L Magnesium acetate Chemical compound [Mg+2].CC([O-])=O.CC([O-])=O UEGPKNKPLBYCNK-UHFFFAOYSA-L 0.000 claims description 4
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims description 4
- SCVFZCLFOSHCOH-UHFFFAOYSA-M Potassium acetate Chemical compound [K+].CC([O-])=O SCVFZCLFOSHCOH-UHFFFAOYSA-M 0.000 claims description 4
- WEVYAHXRMPXWCK-UHFFFAOYSA-N acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 claims description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 4
- 239000011449 brick Substances 0.000 claims description 4
- HEDRZPFGACZZDS-UHFFFAOYSA-N chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 claims description 4
- VLKZOEOYAKHREP-UHFFFAOYSA-N hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 claims description 4
- 239000011654 magnesium acetate Substances 0.000 claims description 4
- 235000011285 magnesium acetate Nutrition 0.000 claims description 4
- 229940069446 magnesium acetate Drugs 0.000 claims description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 4
- YMWUJEATGCHHMB-UHFFFAOYSA-N methylene dichloride Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 claims description 4
- LRHPLDYGYMQRHN-UHFFFAOYSA-N n-butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims description 4
- 229920001223 polyethylene glycol Polymers 0.000 claims description 4
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims description 4
- JUJWROOIHBZHMG-UHFFFAOYSA-N pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 claims description 4
- FAPWRFPIFSIZLT-UHFFFAOYSA-M sodium chloride Chemical group [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 4
- DKGAVHZHDRPRBM-UHFFFAOYSA-N t-BuOH Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 claims description 4
- WYURNTSHIVDZCO-UHFFFAOYSA-N tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims description 4
- YXFVVABEGXRONW-UHFFFAOYSA-N toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 4
- GCRCSLNXFKCFHB-UHFFFAOYSA-N triethyl(hexyl)azanium Chemical compound CCCCCC[N+](CC)(CC)CC GCRCSLNXFKCFHB-UHFFFAOYSA-N 0.000 claims description 4
- XSQUKJJJFZCRTK-UHFFFAOYSA-N urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 4
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 claims description 2
- GSGLHYXFTXGIAQ-UHFFFAOYSA-M 1,3-dimethylimidazol-1-ium;dimethyl phosphate Chemical compound COP([O-])(=O)OC.CN1C=C[N+](C)=C1 GSGLHYXFTXGIAQ-UHFFFAOYSA-M 0.000 claims description 2
- FBPIPPWLOCMHGR-UHFFFAOYSA-N 1,3-dimethylimidazol-1-ium;tetrafluoroborate Chemical compound F[B-](F)(F)F.CN1C=C[N+](C)=C1 FBPIPPWLOCMHGR-UHFFFAOYSA-N 0.000 claims description 2
- HVVRUQBMAZRKPJ-UHFFFAOYSA-N 1,3-dimethylimidazolium Chemical compound CN1C=C[N+](C)=C1 HVVRUQBMAZRKPJ-UHFFFAOYSA-N 0.000 claims description 2
- ARSMIBSHEYKMJT-UHFFFAOYSA-M 1,3-dimethylimidazolium iodide Chemical compound [I-].CN1C=C[N+](C)=C1 ARSMIBSHEYKMJT-UHFFFAOYSA-M 0.000 claims description 2
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 claims description 2
- IXQYBUDWDLYNMA-UHFFFAOYSA-N 1-Butyl-3-methylimidazolium hexafluorophosphate Chemical compound F[P-](F)(F)(F)(F)F.CCCCN1C=C[N+](C)=C1 IXQYBUDWDLYNMA-UHFFFAOYSA-N 0.000 claims description 2
- BMQZYMYBQZGEEY-UHFFFAOYSA-M 1-Ethyl-3-methylimidazolium chloride Chemical compound [Cl-].CCN1C=C[N+](C)=C1 BMQZYMYBQZGEEY-UHFFFAOYSA-M 0.000 claims description 2
- KAIPKTYOBMEXRR-UHFFFAOYSA-N 1-butyl-3-methyl-2H-imidazole Chemical compound CCCCN1CN(C)C=C1 KAIPKTYOBMEXRR-UHFFFAOYSA-N 0.000 claims description 2
- KYCQOKLOSUBEJK-UHFFFAOYSA-M 1-butyl-3-methylimidazol-3-ium;bromide Chemical compound [Br-].CCCCN1C=C[N+](C)=C1 KYCQOKLOSUBEJK-UHFFFAOYSA-M 0.000 claims description 2
- FHDQNOXQSTVAIC-UHFFFAOYSA-M 1-butyl-3-methylimidazol-3-ium;chloride Chemical compound [Cl-].CCCCN1C=C[N+](C)=C1 FHDQNOXQSTVAIC-UHFFFAOYSA-M 0.000 claims description 2
- ICIVTHOGIQHZRY-UHFFFAOYSA-N 1-butyl-3-methylimidazol-3-ium;cyanoiminomethylideneazanide Chemical compound [N-]=C=NC#N.CCCCN1C=C[N+](C)=C1 ICIVTHOGIQHZRY-UHFFFAOYSA-N 0.000 claims description 2
- KIDIBVPFLKLKAH-UHFFFAOYSA-M 1-butyl-3-methylimidazol-3-ium;octyl sulfate Chemical compound CCCCN1C=C[N+](C)=C1.CCCCCCCCOS([O-])(=O)=O KIDIBVPFLKLKAH-UHFFFAOYSA-M 0.000 claims description 2
- XREPTGNZZKNFQZ-UHFFFAOYSA-M 1-butyl-3-methylimidazolium iodide Chemical compound [I-].CCCCN1C=C[N+](C)=C1 XREPTGNZZKNFQZ-UHFFFAOYSA-M 0.000 claims description 2
- DADKKHHMGSWSPH-UHFFFAOYSA-N 1-butyl-3-methylpyridin-1-ium Chemical compound CCCC[N+]1=CC=CC(C)=C1 DADKKHHMGSWSPH-UHFFFAOYSA-N 0.000 claims description 2
- XUZKQHMUEBPODI-UHFFFAOYSA-N 1-butyl-3-methylpyridin-1-ium;hexafluorophosphate Chemical compound F[P-](F)(F)(F)(F)F.CCCC[N+]1=CC=CC(C)=C1 XUZKQHMUEBPODI-UHFFFAOYSA-N 0.000 claims description 2
- UQEAMJVKASNOMA-UHFFFAOYSA-N 1-butyl-3-methylpyridin-1-ium;tetrafluoroborate Chemical compound F[B-](F)(F)F.CCCC[N+]1=CC=CC(C)=C1 UQEAMJVKASNOMA-UHFFFAOYSA-N 0.000 claims description 2
- NNLHWTTWXYBJBQ-UHFFFAOYSA-N 1-butyl-4-methylpyridin-1-ium Chemical compound CCCC[N+]1=CC=C(C)C=C1 NNLHWTTWXYBJBQ-UHFFFAOYSA-N 0.000 claims description 2
- XBSZSSGZQFAUPF-UHFFFAOYSA-N 1-butyl-4-methylpyridin-1-ium;hexafluorophosphate Chemical compound F[P-](F)(F)(F)(F)F.CCCC[N+]1=CC=C(C)C=C1 XBSZSSGZQFAUPF-UHFFFAOYSA-N 0.000 claims description 2
- VISYYHYJMCAKAF-UHFFFAOYSA-N 1-butyl-4-methylpyridin-1-ium;tetrafluoroborate Chemical compound F[B-](F)(F)F.CCCC[N+]1=CC=C(C)C=C1 VISYYHYJMCAKAF-UHFFFAOYSA-N 0.000 claims description 2
- REACWASHYHDPSQ-UHFFFAOYSA-N 1-butylpyridin-1-ium Chemical compound CCCC[N+]1=CC=CC=C1 REACWASHYHDPSQ-UHFFFAOYSA-N 0.000 claims description 2
- CTMFVASPBJWPFC-UHFFFAOYSA-N 1-butylpyridin-1-ium;hexafluorophosphate Chemical compound F[P-](F)(F)(F)(F)F.CCCC[N+]1=CC=CC=C1 CTMFVASPBJWPFC-UHFFFAOYSA-N 0.000 claims description 2
- XLWDQAHXRCBPEE-UHFFFAOYSA-N 1-butylpyridin-1-ium;tetrafluoroborate Chemical compound F[B-](F)(F)F.CCCC[N+]1=CC=CC=C1 XLWDQAHXRCBPEE-UHFFFAOYSA-N 0.000 claims description 2
- FQWUDBZGMGXIAR-UHFFFAOYSA-N 1-dodecylimidazole;2-hydroxybenzoic acid Chemical compound OC(=O)C1=CC=CC=C1[O-].CCCCCCCCCCCC[NH+]1C=CN=C1 FQWUDBZGMGXIAR-UHFFFAOYSA-N 0.000 claims description 2
- GWQYPLXGJIXMMV-UHFFFAOYSA-M 1-ethyl-3-methylimidazol-3-ium;bromide Chemical compound [Br-].CCN1C=C[N+](C)=C1 GWQYPLXGJIXMMV-UHFFFAOYSA-M 0.000 claims description 2
- VRFOKYHDLYBVAL-UHFFFAOYSA-M 1-ethyl-3-methylimidazol-3-ium;ethyl sulfate Chemical compound CCOS([O-])(=O)=O.CCN1C=C[N+](C)=C1 VRFOKYHDLYBVAL-UHFFFAOYSA-M 0.000 claims description 2
- HZKDSQCZNUUQIF-UHFFFAOYSA-M 1-ethyl-3-methylimidazol-3-ium;hydrogen sulfate Chemical compound OS([O-])(=O)=O.CCN1C=C[N+](C)=C1 HZKDSQCZNUUQIF-UHFFFAOYSA-M 0.000 claims description 2
- IKQCDTXBZKMPBB-UHFFFAOYSA-M 1-ethyl-3-methylimidazol-3-ium;iodide Chemical compound [I-].CCN1C=C[N+](C)=C1 IKQCDTXBZKMPBB-UHFFFAOYSA-M 0.000 claims description 2
- CAVPTISELCJZGX-UHFFFAOYSA-N 1-ethyl-3-methylimidazol-3-ium;methanetricarbonitrile Chemical compound N#CC(C#N)C#N.CCN1C=C[N+](C)=C1 CAVPTISELCJZGX-UHFFFAOYSA-N 0.000 claims description 2
- CUNYTRQQXKCRTJ-UHFFFAOYSA-N 1-ethyl-3-methylimidazol-3-ium;tetrafluoroborate Chemical compound F[B-](F)(F)F.CC[N+]=1C=CN(C)C=1 CUNYTRQQXKCRTJ-UHFFFAOYSA-N 0.000 claims description 2
- VASPYXGQVWPGAB-UHFFFAOYSA-M 1-ethyl-3-methylimidazol-3-ium;thiocyanate Chemical compound [S-]C#N.CCN1C=C[N+](C)=C1 VASPYXGQVWPGAB-UHFFFAOYSA-M 0.000 claims description 2
- YPWSSSRXUOQNMQ-UHFFFAOYSA-N 1-hexyl-3-methylimidazol-3-ium;hexafluorophosphate Chemical compound F[P-](F)(F)(F)(F)F.CCCCCCN1C=C[N+](C)=C1 YPWSSSRXUOQNMQ-UHFFFAOYSA-N 0.000 claims description 2
- CZIUVCSYOGFUPH-UHFFFAOYSA-M 1-hexyl-3-methylimidazol-3-ium;iodide Chemical compound [I-].CCCCCC[N+]=1C=CN(C)C=1 CZIUVCSYOGFUPH-UHFFFAOYSA-M 0.000 claims description 2
- MFXLOVLEQJRXFP-UHFFFAOYSA-N 1-hexyl-3-methylimidazol-3-ium;tetrafluoroborate Chemical compound F[B-](F)(F)F.CCCCCCN1C=C[N+](C)=C1 MFXLOVLEQJRXFP-UHFFFAOYSA-N 0.000 claims description 2
- NKRASMXHSQKLHA-UHFFFAOYSA-M 1-hexyl-3-methylimidazolium chloride Chemical compound [Cl-].CCCCCCN1C=C[N+](C)=C1 NKRASMXHSQKLHA-UHFFFAOYSA-M 0.000 claims description 2
- YQFWGCSKGJMGHE-UHFFFAOYSA-N 1-methyl-1-propylpyrrolidin-1-ium Chemical compound CCC[N+]1(C)CCCC1 YQFWGCSKGJMGHE-UHFFFAOYSA-N 0.000 claims description 2
- LSFWFJFDPRFPBK-UHFFFAOYSA-N 1-methyl-3-pentylimidazol-1-ium Chemical compound CCCCCN1C=C[N+](C)=C1 LSFWFJFDPRFPBK-UHFFFAOYSA-N 0.000 claims description 2
- QVRCRKLLQYOIKY-UHFFFAOYSA-M 1-methyl-3-prop-2-enylimidazol-1-ium;chloride Chemical compound [Cl-].C[N+]=1C=CN(CC=C)C=1 QVRCRKLLQYOIKY-UHFFFAOYSA-M 0.000 claims description 2
- IPVXEUXSWNLULC-UHFFFAOYSA-M 1-methyl-3-prop-2-enylimidazol-1-ium;iodide Chemical compound [I-].C[N+]=1C=CN(CC=C)C=1 IPVXEUXSWNLULC-UHFFFAOYSA-M 0.000 claims description 2
- WVDDUSFOSWWJJH-UHFFFAOYSA-N 1-methyl-3-propylimidazol-1-ium Chemical compound CCCN1C=C[N+](C)=C1 WVDDUSFOSWWJJH-UHFFFAOYSA-N 0.000 claims description 2
- IVCMUVGRRDWTDK-UHFFFAOYSA-M 1-methyl-3-propylimidazol-1-ium;iodide Chemical compound [I-].CCCN1C=C[N+](C)=C1 IVCMUVGRRDWTDK-UHFFFAOYSA-M 0.000 claims description 2
- BTANRVKWQNVYAZ-UHFFFAOYSA-N 2-Butanol Chemical compound CCC(C)O BTANRVKWQNVYAZ-UHFFFAOYSA-N 0.000 claims description 2
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 claims description 2
- OXFHNKYFIVWAAT-UHFFFAOYSA-N 2-ethyl-1,3-dimethylimidazol-1-ium Chemical compound CCC=1N(C)C=C[N+]=1C OXFHNKYFIVWAAT-UHFFFAOYSA-N 0.000 claims description 2
- FLVCCOBLYCNTDS-UHFFFAOYSA-N 2-hydroxybenzoic acid;1-nonylimidazole Chemical compound OC(=O)C1=CC=CC=C1[O-].CCCCCCCCC[NH+]1C=CN=C1 FLVCCOBLYCNTDS-UHFFFAOYSA-N 0.000 claims description 2
- 239000001763 2-hydroxyethyl(trimethyl)azanium Substances 0.000 claims description 2
- WXMVWUBWIHZLMQ-UHFFFAOYSA-N 3-methyl-1-octylimidazolium Chemical compound CCCCCCCCN1C=C[N+](C)=C1 WXMVWUBWIHZLMQ-UHFFFAOYSA-N 0.000 claims description 2
- OXFBEEDAZHXDHB-UHFFFAOYSA-M 3-methyl-1-octylimidazolium chloride Chemical compound [Cl-].CCCCCCCCN1C=C[N+](C)=C1 OXFBEEDAZHXDHB-UHFFFAOYSA-M 0.000 claims description 2
- YMGJQBWOTAGHGX-UHFFFAOYSA-M 4-methylbenzenesulfonate;methyl(tripropyl)phosphanium Chemical compound CCC[P+](C)(CCC)CCC.CC1=CC=C(S([O-])(=O)=O)C=C1 YMGJQBWOTAGHGX-UHFFFAOYSA-M 0.000 claims description 2
- FOZHLSIBKHFJBR-UHFFFAOYSA-M 4-methylbenzenesulfonate;methyl-bis(2-methylpropyl)-octylphosphanium Chemical compound CC1=CC=C(S([O-])(=O)=O)C=C1.CCCCCCCC[P+](C)(CC(C)C)CC(C)C FOZHLSIBKHFJBR-UHFFFAOYSA-M 0.000 claims description 2
- SNXTZFCNWIVLKZ-UHFFFAOYSA-M 4-methylbenzenesulfonate;methyl-tris(2-methylpropyl)phosphanium Chemical compound CC1=CC=C(S([O-])(=O)=O)C=C1.CC(C)C[P+](C)(CC(C)C)CC(C)C SNXTZFCNWIVLKZ-UHFFFAOYSA-M 0.000 claims description 2
- ZZAZFRIZOXHKGA-UHFFFAOYSA-M 4-methylbenzenesulfonate;tritert-butyl(methyl)phosphanium Chemical compound CC1=CC=C(S([O-])(=O)=O)C=C1.CC(C)(C)[P+](C)(C(C)(C)C)C(C)(C)C ZZAZFRIZOXHKGA-UHFFFAOYSA-M 0.000 claims description 2
- DVARTQFDIMZBAA-UHFFFAOYSA-O Ammonium nitrate Chemical compound [NH4+].[O-][N+]([O-])=O DVARTQFDIMZBAA-UHFFFAOYSA-O 0.000 claims description 2
- BFNBIHQBYMNNAN-UHFFFAOYSA-N Ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 claims description 2
- IQQRAVYLUAZUGX-UHFFFAOYSA-N C4mim Chemical compound CCCCN1C=C[N+](C)=C1 IQQRAVYLUAZUGX-UHFFFAOYSA-N 0.000 claims description 2
- 229940044172 CALCIUM FORMATE Drugs 0.000 claims description 2
- KVFJTXHIACIBEQ-UHFFFAOYSA-O CCCCOC[n+]1cc[nH]c1 Chemical compound CCCCOC[n+]1cc[nH]c1 KVFJTXHIACIBEQ-UHFFFAOYSA-O 0.000 claims description 2
- VSGNNIFQASZAOI-UHFFFAOYSA-L Calcium acetate Chemical compound [Ca+2].CC([O-])=O.CC([O-])=O VSGNNIFQASZAOI-UHFFFAOYSA-L 0.000 claims description 2
- CBOCVOKPQGJKKJ-UHFFFAOYSA-L Calcium formate Chemical compound [Ca+2].[O-]C=O.[O-]C=O CBOCVOKPQGJKKJ-UHFFFAOYSA-L 0.000 claims description 2
- 229960003178 Choline Chloride Drugs 0.000 claims description 2
- SGMZJAMFUVOLNK-UHFFFAOYSA-M Choline chloride Chemical compound [Cl-].C[N+](C)(C)CCO SGMZJAMFUVOLNK-UHFFFAOYSA-M 0.000 claims description 2
- 235000019743 Choline chloride Nutrition 0.000 claims description 2
- SBZXBUIDTXKZTM-UHFFFAOYSA-N Diglyme Chemical compound COCCOCCOC SBZXBUIDTXKZTM-UHFFFAOYSA-N 0.000 claims description 2
- FKSGWCHYJXNQIO-UHFFFAOYSA-N F[P-](F)(F)(F)(F)F.CC(O)CC1C=[N+](C)C=N1 Chemical compound F[P-](F)(F)(F)(F)F.CC(O)CC1C=[N+](C)C=N1 FKSGWCHYJXNQIO-UHFFFAOYSA-N 0.000 claims description 2
- BKACLUZRLYZOAV-UHFFFAOYSA-N F[P-](F)(F)(F)(F)F.CCOCCOn1cc[n+](C)c1 Chemical compound F[P-](F)(F)(F)(F)F.CCOCCOn1cc[n+](C)c1 BKACLUZRLYZOAV-UHFFFAOYSA-N 0.000 claims description 2
- GNOIPBMMFNIUFM-UHFFFAOYSA-N Hexamethylphosphoramide Chemical compound CN(C)P(=O)(N(C)C)N(C)C GNOIPBMMFNIUFM-UHFFFAOYSA-N 0.000 claims description 2
- IVSZLXZYQVIEFR-UHFFFAOYSA-N M-Xylene Chemical group CC1=CC=CC(C)=C1 IVSZLXZYQVIEFR-UHFFFAOYSA-N 0.000 claims description 2
- BZLVMXJERCGZMT-UHFFFAOYSA-N MeOtBu Chemical compound COC(C)(C)C BZLVMXJERCGZMT-UHFFFAOYSA-N 0.000 claims description 2
- LYGJENNIWJXYER-UHFFFAOYSA-N Nitromethane Chemical compound C[N+]([O-])=O LYGJENNIWJXYER-UHFFFAOYSA-N 0.000 claims description 2
- WFIZEGIEIOHZCP-UHFFFAOYSA-M Potassium formate Chemical compound [K+].[O-]C=O WFIZEGIEIOHZCP-UHFFFAOYSA-M 0.000 claims description 2
- RUOJZAUFBMNUDX-UHFFFAOYSA-N Propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 claims description 2
- HLBBKKJFGFRGMU-UHFFFAOYSA-M Sodium formate Chemical compound [Na+].[O-]C=O HLBBKKJFGFRGMU-UHFFFAOYSA-M 0.000 claims description 2
- 239000004280 Sodium formate Substances 0.000 claims description 2
- HXJUTPCZVOIRIF-UHFFFAOYSA-N Sulfolane Chemical compound O=S1(=O)CCCC1 HXJUTPCZVOIRIF-UHFFFAOYSA-N 0.000 claims description 2
- CBXCPBUEXACCNR-UHFFFAOYSA-N Tetraethylammonium Chemical compound CC[N+](CC)(CC)CC CBXCPBUEXACCNR-UHFFFAOYSA-N 0.000 claims description 2
- LAGQNGWYNLUQRI-UHFFFAOYSA-N Trioctylmethylammonium bis(trifluoromethylsulfonyl)imide Chemical compound FC(F)(F)S(=O)(=O)[N-]S(=O)(=O)C(F)(F)F.CCCCCCCC[N+](C)(CCCCCCCC)CCCCCCCC LAGQNGWYNLUQRI-UHFFFAOYSA-N 0.000 claims description 2
- 125000000218 acetic acid group Chemical group C(C)(=O)* 0.000 claims description 2
- 229910052921 ammonium sulfate Inorganic materials 0.000 claims description 2
- 235000011130 ammonium sulphate Nutrition 0.000 claims description 2
- OMMLVGFDYVJZPD-UHFFFAOYSA-M bis(dioctylamino)methylidene-dimethylazanium;chloride Chemical compound [Cl-].CCCCCCCCN(CCCCCCCC)C(=[N+](C)C)N(CCCCCCCC)CCCCCCCC OMMLVGFDYVJZPD-UHFFFAOYSA-M 0.000 claims description 2
- XOZHIVUWCICHSQ-UHFFFAOYSA-N bis(trifluoromethylsulfonyl)azanide;1,2-dimethyl-3-propylimidazol-1-ium Chemical compound CCCN1C=C[N+](C)=C1C.FC(F)(F)S(=O)(=O)[N-]S(=O)(=O)C(F)(F)F XOZHIVUWCICHSQ-UHFFFAOYSA-N 0.000 claims description 2
- UCCKRVYTJPMHRO-UHFFFAOYSA-N bis(trifluoromethylsulfonyl)azanide;1-butyl-2,3-dimethylimidazol-3-ium Chemical compound CCCC[N+]=1C=CN(C)C=1C.FC(F)(F)S(=O)(=O)[N-]S(=O)(=O)C(F)(F)F UCCKRVYTJPMHRO-UHFFFAOYSA-N 0.000 claims description 2
- INDFXCHYORWHLQ-UHFFFAOYSA-N bis(trifluoromethylsulfonyl)azanide;1-butyl-3-methylimidazol-3-ium Chemical compound CCCCN1C=C[N+](C)=C1.FC(F)(F)S(=O)(=O)[N-]S(=O)(=O)C(F)(F)F INDFXCHYORWHLQ-UHFFFAOYSA-N 0.000 claims description 2
- LRESCJAINPKJTO-UHFFFAOYSA-N bis(trifluoromethylsulfonyl)azanide;1-ethyl-3-methylimidazol-3-ium Chemical compound CCN1C=C[N+](C)=C1.FC(F)(F)S(=O)(=O)[N-]S(=O)(=O)C(F)(F)F LRESCJAINPKJTO-UHFFFAOYSA-N 0.000 claims description 2
- IEKPEVWFUIKZFI-UHFFFAOYSA-N bis(trifluoromethylsulfonyl)azanide;1-hexadecyl-3-methylimidazol-3-ium Chemical compound FC(F)(F)S(=O)(=O)[N-]S(=O)(=O)C(F)(F)F.CCCCCCCCCCCCCCCCN1C=C[N+](C)=C1 IEKPEVWFUIKZFI-UHFFFAOYSA-N 0.000 claims description 2
- RCNFOZUBFOFJKZ-UHFFFAOYSA-N bis(trifluoromethylsulfonyl)azanide;1-hexyl-3-methylimidazol-3-ium Chemical compound CCCCCC[N+]=1C=CN(C)C=1.FC(F)(F)S(=O)(=O)[N-]S(=O)(=O)C(F)(F)F RCNFOZUBFOFJKZ-UHFFFAOYSA-N 0.000 claims description 2
- IEFUHGXOQSVRDQ-UHFFFAOYSA-N bis(trifluoromethylsulfonyl)azanide;1-methyl-1-propylpiperidin-1-ium Chemical compound CCC[N+]1(C)CCCCC1.FC(F)(F)S(=O)(=O)[N-]S(=O)(=O)C(F)(F)F IEFUHGXOQSVRDQ-UHFFFAOYSA-N 0.000 claims description 2
- DHMWATGUEVQTIY-UHFFFAOYSA-N bis(trifluoromethylsulfonyl)azanide;1-methyl-3-prop-2-enylimidazol-1-ium Chemical compound C[N+]=1C=CN(CC=C)C=1.FC(F)(F)S(=O)(=O)[N-]S(=O)(=O)C(F)(F)F DHMWATGUEVQTIY-UHFFFAOYSA-N 0.000 claims description 2
- CDWUIWLQQDTHRA-UHFFFAOYSA-N bis(trifluoromethylsulfonyl)azanide;1-methyl-3-propylimidazol-1-ium Chemical compound CCCN1C=C[N+](C)=C1.FC(F)(F)S(=O)(=O)[N-]S(=O)(=O)C(F)(F)F CDWUIWLQQDTHRA-UHFFFAOYSA-N 0.000 claims description 2
- CHJFYGKCKZENPL-UHFFFAOYSA-N bis[butyl(ethyl)amino]methylidene-dimethylazanium;tetrafluoroborate Chemical compound F[B-](F)(F)F.CCCCN(CC)C(=[N+](C)C)N(CC)CCCC CHJFYGKCKZENPL-UHFFFAOYSA-N 0.000 claims description 2
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 claims description 2
- UXVMQQNJUSDDNG-UHFFFAOYSA-L cacl2 Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims description 2
- 239000001639 calcium acetate Substances 0.000 claims description 2
- 235000011092 calcium acetate Nutrition 0.000 claims description 2
- 229960005147 calcium acetate Drugs 0.000 claims description 2
- 239000001110 calcium chloride Substances 0.000 claims description 2
- 229910001628 calcium chloride Inorganic materials 0.000 claims description 2
- 235000011148 calcium chloride Nutrition 0.000 claims description 2
- 239000004281 calcium formate Substances 0.000 claims description 2
- 235000019255 calcium formate Nutrition 0.000 claims description 2
- 239000004202 carbamide Substances 0.000 claims description 2
- MKHFCTXNDRMIDR-UHFFFAOYSA-N cyanoiminomethylideneazanide;1-ethyl-3-methylimidazol-3-ium Chemical compound [N-]=C=NC#N.CCN1C=C[N+](C)=C1 MKHFCTXNDRMIDR-UHFFFAOYSA-N 0.000 claims description 2
- XDTMQSROBMDMFD-UHFFFAOYSA-N cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 claims description 2
- RGSFGYAAUTVSQA-UHFFFAOYSA-N cyclopentane Chemical compound C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 claims description 2
- HQWOEDCLDNFWEV-UHFFFAOYSA-M diethyl phosphate;1-ethyl-3-methylimidazol-3-ium Chemical compound CC[N+]=1C=CN(C)C=1.CCOP([O-])(=O)OCC HQWOEDCLDNFWEV-UHFFFAOYSA-M 0.000 claims description 2
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 claims description 2
- AHRQMWOXLCFNAV-UHFFFAOYSA-O ethylammonium nitrate Chemical compound CC[NH3+].[O-][N+]([O-])=O AHRQMWOXLCFNAV-UHFFFAOYSA-O 0.000 claims description 2
- 235000019253 formic acid Nutrition 0.000 claims description 2
- 239000008079 hexane Substances 0.000 claims description 2
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 2
- LPPJNZJBKFSQGA-UHFFFAOYSA-M hydron;2-hydroxyethyl(trimethyl)azanium;phosphate Chemical compound OP(O)([O-])=O.C[N+](C)(C)CCO LPPJNZJBKFSQGA-UHFFFAOYSA-M 0.000 claims description 2
- 235000011147 magnesium chloride Nutrition 0.000 claims description 2
- GMDNUWQNDQDBNQ-UHFFFAOYSA-L magnesium;diformate Chemical compound [Mg+2].[O-]C=O.[O-]C=O GMDNUWQNDQDBNQ-UHFFFAOYSA-L 0.000 claims description 2
- IMNFDUFMRHMDMM-UHFFFAOYSA-N n-heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 claims description 2
- NHNBFGGVMKEFGY-UHFFFAOYSA-N nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N o-xylene Chemical group CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 2
- 229940078552 o-xylene Drugs 0.000 claims description 2
- URLKBWYHVLBVBO-UHFFFAOYSA-N p-xylene Chemical group CC1=CC=C(C)C=C1 URLKBWYHVLBVBO-UHFFFAOYSA-N 0.000 claims description 2
- WVGZZTIINNFUQS-UHFFFAOYSA-N pentamethylphosphoranuidylmethane Chemical compound C[P-](C)(C)(C)(C)C WVGZZTIINNFUQS-UHFFFAOYSA-N 0.000 claims description 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 claims description 2
- 239000003208 petroleum Substances 0.000 claims description 2
- 229920001484 poly(alkylene) Polymers 0.000 claims description 2
- 235000011056 potassium acetate Nutrition 0.000 claims description 2
- 239000001103 potassium chloride Substances 0.000 claims description 2
- 235000011164 potassium chloride Nutrition 0.000 claims description 2
- DROIHSMGGKKIJT-UHFFFAOYSA-N propane-1-sulfonamide Chemical compound CCCS(N)(=O)=O DROIHSMGGKKIJT-UHFFFAOYSA-N 0.000 claims description 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propanol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 claims description 2
- 239000004576 sand Substances 0.000 claims description 2
- VMHLLURERBWHNL-UHFFFAOYSA-M sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 claims description 2
- 239000001632 sodium acetate Substances 0.000 claims description 2
- 235000017281 sodium acetate Nutrition 0.000 claims description 2
- 239000011780 sodium chloride Substances 0.000 claims description 2
- 235000002639 sodium chloride Nutrition 0.000 claims description 2
- 235000019254 sodium formate Nutrition 0.000 claims description 2
- DZLFLBLQUQXARW-UHFFFAOYSA-N tetrabutylammonium Chemical compound CCCC[N+](CCCC)(CCCC)CCCC DZLFLBLQUQXARW-UHFFFAOYSA-N 0.000 claims description 2
- GTCDARUMAMVCRO-UHFFFAOYSA-M tetraethylazanium;acetate Chemical compound CC([O-])=O.CC[N+](CC)(CC)CC GTCDARUMAMVCRO-UHFFFAOYSA-M 0.000 claims description 2
- DTIFFPXSSXFQCJ-UHFFFAOYSA-N tetrahexylazanium Chemical compound CCCCCC[N+](CCCCCC)(CCCCCC)CCCCCC DTIFFPXSSXFQCJ-UHFFFAOYSA-N 0.000 claims description 2
- OSBSFAARYOCBHB-UHFFFAOYSA-N tetrapropylammonium Chemical compound CCC[N+](CCC)(CCC)CCC OSBSFAARYOCBHB-UHFFFAOYSA-N 0.000 claims description 2
- AQQOUVLRCMEMHI-UHFFFAOYSA-N tributyl(heptyl)azanium Chemical compound CCCCCCC[N+](CCCC)(CCCC)CCCC AQQOUVLRCMEMHI-UHFFFAOYSA-N 0.000 claims description 2
- FJAPXHMQWAFWMW-UHFFFAOYSA-N tributyl(hexyl)azanium Chemical compound CCCCCC[N+](CCCC)(CCCC)CCCC FJAPXHMQWAFWMW-UHFFFAOYSA-N 0.000 claims description 2
- YWRSPDSZBLLBPN-UHFFFAOYSA-M tributyl(octyl)azanium;trifluoromethanesulfonate Chemical compound [O-]S(=O)(=O)C(F)(F)F.CCCCCCCC[N+](CCCC)(CCCC)CCCC YWRSPDSZBLLBPN-UHFFFAOYSA-M 0.000 claims description 2
- WCZKTXKOKMXREO-UHFFFAOYSA-N triethylsulfanium Chemical compound CC[S+](CC)CC WCZKTXKOKMXREO-UHFFFAOYSA-N 0.000 claims description 2
- RJELOMHXBLDMDB-UHFFFAOYSA-M trihexyl(tetradecyl)phosphanium;bromide Chemical compound [Br-].CCCCCCCCCCCCCC[P+](CCCCCC)(CCCCCC)CCCCCC RJELOMHXBLDMDB-UHFFFAOYSA-M 0.000 claims description 2
- JCQGIZYNVAZYOH-UHFFFAOYSA-M trihexyl(tetradecyl)phosphanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCCC[P+](CCCCCC)(CCCCCC)CCCCCC JCQGIZYNVAZYOH-UHFFFAOYSA-M 0.000 claims description 2
- WCKLETBLOAOZDE-UHFFFAOYSA-N trihexyl(tetradecyl)phosphanium;hexafluorophosphate Chemical compound F[P-](F)(F)(F)(F)F.CCCCCCCCCCCCCC[P+](CCCCCC)(CCCCCC)CCCCCC WCKLETBLOAOZDE-UHFFFAOYSA-N 0.000 claims description 2
- SIKCPMYZUKIFIB-UHFFFAOYSA-N bis(dioctylamino)methylidene-dimethylazanium;tetrafluoroborate Chemical compound F[B-](F)(F)F.CCCCCCCCN(CCCCCCCC)C(=[N+](C)C)N(CCCCCCCC)CCCCCCCC SIKCPMYZUKIFIB-UHFFFAOYSA-N 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
Description
本明細書は最良の形態を含む本明細書の主題を開示するために、また、任意のデバイス又はシステムを作製及び使用すること、ならびに組み込まれた方法を実行することを含めて、当業者が本開示を実施することを可能にするために、例を使用する。主題の特許性のある範囲は、特許請求の範囲によって定義され、当業者に想起される他の例を含むことができる。構成要素が特許請求の範囲に記載のものと相違ない場合、又は特許請求の範囲に記載のものとそれほど相違ない同等の構成要素を含む場合、このような他の例は特許請求の範囲内であるものとする。
本発明は例えば以下の態様を含む。
［項１]
少なくとも１種の溶媒、
0.01～約55重量%の少なくとも1種の除氷剤、並びに
0.01～約25重量%の、イオン液体、深共晶溶媒、分散剤、及びそれらの組み合わせからなる群から選択される少なくとも1種の添加剤
を含む、融氷組成物。
［項２］
少なくとも1種の添加剤が少なくとも1種のイオン液体を含む、項1に記載の融氷組成物。
［項３］
少なくとも1種のイオン液体が、4-(2-ヒドロキシ-プロピル)-1-メチル-4H-イミダゾリウムヘキサフルオロホスファート、3-メチル-1-(プロパン-2-オール)-イミダゾリウムヘキサフルオロホスファート、3-メチル-1-(プロパン-2-オール)-イミダゾリウムクロリド、3-メチル-1-(プロパン-2-オール)-イミダゾリウムニトラート、3-メチル-1-(エトキシエトキシ)-イミダゾリウムヘキサフルオロホスファート、3-ヘキシル-1-(2-ジエチルホスホナート-エチル)-イミダゾリウムテトラフルオロボラート、3-ヘキシル-1-(3-ジエチルホスホナート-プロピル)-イミダゾリウムテトラフルオロボラート、3-オクチル-1-(2-ジエチルホスホナート-エチル)-イミダゾリウムテトラフルオロボラート、3-メチル-1-ブチル-イミダゾリウムテトラフルオロボラート、3-メチル-1-ブチル-イミダゾリウムクロリド、3-メチル-1-ブチル-イミダゾリウムオクチルスルファート、3-メチル-1-ブチル-イミダゾリウムフルオロハイドロジェネート、3-メチル-1-エチル-イミダゾリウムトリシアノメタン、3-メチル-1-エチル-イミダゾリウムフルオロハイドロジェネート、3-メチル-1-エチル-イミダゾリウムカルボラン、3-メチル-1-エチル-イミダゾリウムメチルカルボラン、3-メチル-1-エチル-イミダゾリウムエチルカルボラン、3-メチル-1-メチル-イミダゾリウムフルオロハイドロジェネート、3-メチル-1-プロピル-イミダゾリウムフルオロハイドロジェネート、3-メチル-1-ペンチル-イミダゾリウムフルオロハイドロジェネート、3-メチル-1-ヘキシル-イミダゾリウムフルオロハイドロジェネート、3-メチル-1-ヘキシル-イミダゾリウムクロリド、3-メチル-1-オクチル-イミダゾリウムクロリド、3-メチル-1-オクチル-イミダゾリウムテトラフルオロボラート、3-メチル-1-メチル-イミダゾリウムテトラフルオロボラート、3-メチル-2-エチル-1-メチル-イミダゾリウムカルボラート、テトラエチルアンモニウムトリブチルオクチルボラート、テトラエチルアンモニウムアセタート、ヘキシル-トリエチル-アンモニウムヘキシル-トリエチルボラート、ヘキシル-トリエチル-アンモニウムトリブチルオクチルボラート、テトラプロピルアンモニウムトリプロピルヘキシルボラート、テトラブチルアンモニウムトリブチルヘキシルボラート、ヘキシル-トリ-ブチルアンモニウムトリブチルヘキシルボラート、ヘキシル-トリ-ブチルアンモニウム ビス-トリフルオロメタンスルホンアミド、ヘプチル-トリ-ブチルアンモニウム ビス-トリフルオロメタンスルホンアミド、テトラペンチルアンモニウム ビス-トリフルオロメタンスルホンアミド、オクチル-トリ-ブチルアンモニウム ビス-トリフルオロメタンスルホンアミド、オクチル-トリ-ブチルアンモニウムトリフルオロメチルスルホナート、テトラヘキシルアンモニウム ビス-トリフルオロメタンスルホンアミド、テトラヘキシルアンモニウム トリブチルヘキシルボラート、テトラヘプチルアンモニウム ビス-トリフルオロメタンスルホンアミド、テトラオクチルアンモニウム ビス-トリフルオロメタンスルホンアミド、テトラドデシルアンモニウム ビス-トリフルオロメタンスルホンアミド、N-メチル-N-プロピルピロリジンジシアニミド、N-メチル-N-ブチルピロリジンジシアニミド、N-メチル-N-ヘキシルピロリジンジシアニミド、[ビス-(N-ブチル-N-エチル-アミノ)-メチレン]-ジメチル-アンモニウムテトラフルオロボラート、[ビス-(N-ヘキシル-N-ヘキシル-アミノ)-メチレン]-ジメチル-アンモニウム テトラフルオロボラート、[ビス-(N-ヘキシル-N-ヘキシル-アミノ)-メチレン]-ジメチル-アンモニウムヘキサフルオロホスファート、[ビス-(N-ヘキシル-N-ヘキシル-アミノ)-メチレン]-ジメチル-アンモニウムクロリド、[ビス-(N-ヘキシル-N-ヘキシル-アミノ)-メチレン]-ジメチル-アンモニウム ビス-トリフルオロメタンスルホンアミド、[ビス-(N-オクチル-N-オクチル-アミノ)-メチレン]-ジメチル-アンモニウムテトラフルオロボラート、[ビス-(N-オクチル-N-オクチル-アミノ)-メチレン]-ジメチル-アンモニウムヘキサフルオロホスファート、[ビス-(N-オクチル-N-オクチル-アミノ)-メチレン]-ジメチルアンモニウムクロリド、メチル-トリプロピルホスホニウムトシラート、メチル-トリ-(iso-ブチル)ホスホニウムトシラート、メチル-トリ-(tert-ブチル)ホスホニウムトシラート、メチル-ジ-(iso-ブチル)-オクチルホスホニウムトシラート、メチル-ジ-(iso-ブチル)-テトラデシルホスホニウムトシラート、テトラデシル-トリ-(ヘキシル)-ホスホニウムブロミド、テトラデシル-トリ-(ヘキシル)-ホスホニウムテトラフルオロボラート、テトラデシル-トリ-(ヘキシル)-ホスホニウムヘキサフルオロホスファート、オクチルイミダゾリウムサリチラート、ノニルイミダゾリウムサリチラート、ドデシルイミダゾリウムサリチラート、(ブチルオキシメチル)イミダゾリウムサリチラート、1-エチル-3-メチルイミダゾリウムテトラフルオロボラート、1-ブチル-3-メチルイミダゾリウムテトラフルオロボラート、1-ヘキシル-3-メチルイミダゾリウムテトラフルオロボラート、1-メチル-3-オクチルイミダゾリウムテトラフルオロボラート、1-ブチルピリジニウムテトラフルオロボラート、1-ブチル-3-メチルピリジニウムテトラフルオロボラート、1-ブチル-4-メチルピリジニウムテトラフルオロボラート、1-ブチル-3-メチルイミダゾリウムヘキサフルオロホスファート、1-ヘキシル-3-メチルイミダゾリウムヘキサフルオロホスファート、1-メチル-3-オクチルイミダゾリウム、1-ブチルピリジニウムヘキサフルオロホスファート、1-ブチル-3-メチルピリジニウムヘキサフルオロホスファート、1-ブチル-4-メチルピリジニウムヘキサフルオロホスファート、1-エチル-3-メチルイミダゾリウムジエチルホスファート、1,3-ジメチルイミダゾリウムジメチルホスファート、コリンジハイドロジェンホスファート、1-エチル-3-メチルイミダゾリウムエチルスルファート、1-エチル-3-メチルイミダゾリウムハイドロジェンスルファート、1-エチル-3-メチルイミダゾリウムアセタート、エチルアンモニウムニトラート、トリエチルスルホニウム ビス(トリフルオロメチルスルホニル)イミド、メチルトリオクチルアンモニウム ビス(トリフルオロメチルスルホニル)イミド、1-エチル-3-メチルイミダゾリウム ビス(トリフルオロメチルスルホニル)イミド、1-メチル-3-プロピルイミダゾリウム ビス(トリフルオロメチルスルホニル)イミド、1,2-ジメチル-3-プロピルイミダゾリウム ビス(トリフルオロメチルスルホニル)イミド、1-ブチル-3-メチルイミダゾリウム ビス(トリフルオロメチルスルホニル)イミド、1-ブチル-2,3-ジメチルイミダゾリウム ビス(トリフルオロメチルスルホニル)イミド、1-ヘキシル-3-メチルイミダゾリウム ビス(トリフルオロメチルスルホニル)イミド、1-ヘキサデシル-3-メチルイミダゾリウム ビス(トリフルオロメチルスルホニル)イミド、1-アリル-3-メチルイミダゾリウム ビス(トリフルオロメチルスルホニル)イミド、1-メチル-1-プロピルピロリジニウムビス(トリフルオロメチルスルホニル)イミド、1-ブチル-1-メチルピロリジニウム ビス(トリフルオロメチルスルホニル)イミド、1-メチル-1-プロピルピペリジニウム ビス(トリフルオロメチルスルホニル)イミド、1-ブチルピリジニウム ビス(トリフルオロメチルスルホニル)イミド、1-ブチル-3-メチルピリジニウム ビス(トリフルオロメチルスルホニル)イミド、1-ブチル-4-メチルピリジニウム ビス(トリフルオロメチルスルホニル)イミド、トリヘキシルテトラデシルホスホニウム ビス(トリフルオロメチルスルホニル)イミド、1-エチル-3-メチルイミダゾリウムトリフラート、1-ブチル-3-メチルイミダゾリウムトリフラート、1-ヘキシル-3-メチルイミダゾリウムトリフラート、1-メチル-3-オクチルイミダゾリウムトリフラート、1-ブチル-1-メチルピロリジニウムトリフラート、1-エチル-3-メチルイミダゾリウムチオシアナート、1-エチル-3-メチルイミダゾリウムジシアナミド、1-ブチル-3-メチルイミダゾリウムジシアナミド、1-ブチル-1-メチルピロリジニウムジシアナミド、1-エチル-3-メチルイミダゾリウムクロリド、1-ブチル-3-メチルイミダゾリウムクロリド、1-アリル-3-メチルイミダゾリウムクロリド、トリヘキシルテトラデシルホスホニウムクロリド、1-エチル-3-メチルイミダゾリウムブロミド、1-ブチル-3-メチルイミダゾリウムブロミド、1,3-ジメチルイミダゾリウムヨージド、1-エチル-3-メチルイミダゾリウムヨージド、1-メチル-3-プロピルイミダゾリウムヨージド、1-ブチル-3-メチルイミダゾリウムヨージド、1-ヘキシル-3-メチルイミダゾリウムヨージド、1-アリル-3-メチルイミダゾリウムヨージド、(トリス-2-ヒドロキシエチル)メチルアンモニウムメチルスルファート、1-エチル-3-メチルイミダゾリウムアセタート、及びそれらの組み合わせからなる群から選択される、項2に記載の融氷組成物。
［項４］
少なくとも1種のイオン液体が、(トリス-2-ヒドロキシエチル)メチルアンモニウムメチルスルファート、1-エチル-3-メチルイミダゾリウムアセタート及びそれらの組み合わせからなる群から選択される、項3に記載の融氷組成物。
［項５］
0.1～5.0重量%の少なくとも1種のイオン液体を含む、項2に記載の融氷組成物。
［項６］
少なくとも1種の添加剤が、少なくとも1種の深共晶溶媒を含む、項1に記載の融氷組成物。
［項７］
少なくとも1種の深共晶溶媒が、I型深共晶溶媒、II型深共晶溶媒、III型深共晶溶媒、IV型深共晶溶媒、及びそれらの組み合わせからなる群から選択される、項6に記載の融氷組成物。
［項８］
少なくとも1種の深共晶溶媒が、1:1の塩化コリンとグリコールである、項7に記載の融氷組成物。
［項９］
少なくとも1種の除氷剤が、塩化ナトリウム、塩化カルシウム、塩化カリウム、塩化マグネシウム、酢酸ナトリウム、酢酸カルシウム、酢酸カリウム、酢酸マグネシウム、酢酸カルシウムマグネシウム、硝酸アンモニウム、硫酸アンモニウム、ギ酸ナトリウム、ギ酸カリウム、ギ酸カルシウム、ギ酸マグネシウム、尿素、砂、及びそれらの組み合わせからなる群から選択される、項1に記載の融氷組成物。
［項１０］
少なくとも1種の除氷剤が塩化マグネシウムを含む、項9に記載の融氷組成物。
［項１１］
25～35重量%の少なくとも1種の除氷剤を含む、項10に記載の融氷組成物。
［項１２］
少なくとも1種の溶媒が、酢酸、アセトン、アセトニトリル、ベンゼン、n-ブタノール、s-ブタノール、t-ブタノール、2-ブタノン、四塩化炭素、クロロベンゼン、クロロホルム、シクロヘキサン、シクロペンタン、1,2-ジクロロエタン、ジクロロメタン、ジエチルエーテル、ジエチレングリコール、ジグリム、ジメチルホルムアミド、ジメチルスルホキシド、1,4-ジオキサン、エタノール、酢酸エチル、ギ酸、グリム、ヘプタン、ヘキサメチルホスホルアミド、ヘキサメチルリン酸トリアミド、ヘキサン、イソプロパノール、メタノール、メチルt-ブチルエーテル、ニトロメタン、ペンタン、石油エーテル、プロパノール、炭酸プロピレン、ピリジン、スルホラン、テトラヒドロフラン、トルエン、水、m-キシレン、o-キシレン、p-キシレン、及びそれらの組み合わせからなる群から選択される、項1に記載の融氷組成物。
［項１３］
少なくとも1種の溶媒が水を含む、項12に記載の融氷組成物。
［項１４］
少なくとも1種の添加剤が0.01～1.0重量%の少なくとも1種の分散剤を含む、項1に記載の融氷組成物。
［項１５］
少なくとも1種の分散剤が、ポリ(アルキレン)グリコール、(ポリ)プロピレングリコール、(ポリ)エチレングリコール、プロピレングリコール、エチレングリコール、及びそれらの組み合わせからなる群から選択される、項14に記載の融氷組成物。
［項１６］
水、
約30重量%の塩化マグネシウム、
約3.5重量%の、(トリス-2-ヒドロキシエチル)メチルアンモニウムメチルスルファート、1-エチル-3-メチルイミダゾリウムアセタート及びそれらの組み合わせからなる群から選択されるイオン液体、並びに
0.02～1.0重量%の(ポリ)エチレングリコール
を含む、項14に記載の融氷組成物。
［項１７］
少なくとも1種の添加剤を含まない同じ組成物と比較して、増大した飽和点を有する、項1に記載の融氷組成物。
［項１８］
水、
約30重量%の塩化マグネシウム、及び
0.02～1.0重量%の(ポリ)エチレングリコール
を含む、項15に記載の融氷組成物。
［項１９］
表面上の氷を溶かすための方法であって、
氷が形成された後に融氷組成物を表面に適用することを含み、
融氷組成物が、
少なくとも1種の溶媒、
0.01～約55重量%の少なくとも1種の除氷剤、並びに
0.01～約25重量%の、イオン液体、深共晶溶媒、分散剤及びそれらの組み合わせからなる群から選択される少なくとも1種の添加剤を含む、方法。
［項２０］
融氷組成物が、
約30重量%の塩化マグネシウム、
約3.5重量%の、(トリス-2-ヒドロキシエチル)メチルアンモニウムメチルスルファート、1-エチル-3-メチルイミダゾリウムアセタート及びそれらの組み合わせからなる群から選択されるイオン液体、並びに
0.02～約1.0重量%のポリ(エチレン)グリコール
を含む、項19に記載の方法。
［項２１］
表面が、建物、屋根、ガター、パイプの内部又は外部、非多孔性アスファルト道路、アスファルト道路、多孔性アスファルト道路、コンクリート道路、ビチューメン道路、れんが道路、砂利道、敷石道路、舗装されていない道路、橋、道路高架、舗装道路、窓、歩道、通路、舗装された通路、滑走路、航空機、自動車、トラック、車両及び車両フロントガラスからなる群から選択される、項19に記載の方法。
［項２２］
表面上の氷を溶かすための方法であって、
氷が形成された後に融氷組成物を表面に適用することを含み、
融氷組成物が、項1に記載の融氷組成物を含む、方法。
［項２３］
表面上の氷を溶かすための方法であって、
氷が形成された後に融氷組成物を表面に適用することを含み、
融氷組成物が、項16に記載の融氷組成物を含む、方法。
［項２４］
表面上の氷を溶かすための方法であって、
氷が形成された後に融氷組成物を表面に適用することを含み、
融氷組成物が、項18に記載の融氷組成物を含む、方法。
［項２５］
表面上の氷の形成を防止するための方法であって、
氷が形成される前に融氷組成物を表面に適用することを含み、
融氷組成物が、
少なくとも１種の溶媒、
0.01～約55重量%の少なくとも1種の除氷剤、並びに
0.01～約25重量%の、イオン液体、深共晶溶媒、分散剤、及びそれらの組み合わせからなる群から選択される少なくとも1種の添加剤を含む、方法。
［項２６］
融氷組成物が、
約30重量%の塩化マグネシウム、
約3.5重量%の、(トリス-2-ヒドロキシエチル)メチルアンモニウムメチルスルファート、1-エチル-3-メチルイミダゾリウムアセタート及びそれらの組み合わせからなる群から選択されるイオン液体、並びに
0.02～1.0重量%のポリ(エチレン)グリコール
を含む、項25に記載の方法。
［項２７］
表面が、建物、屋根、ガター、パイプの内部又は外部、非多孔性アスファルト道路、アスファルト道路、多孔性アスファルト道路、コンクリート道路、ビチューメン道路、れんが道路、砂利道、敷石道路、舗装されていない道路、橋、道路高架、舗装道路、窓、歩道、通路、舗装された通路、滑走路、航空機、自動車、トラック、車両及び車両フロントガラスからなる群から選択される、項25に記載の方法。
［項２８］
表面上の氷の形成を防止するための方法であって、
氷が形成される前に融氷組成物を表面に適用することを含み、
融氷組成物が、項1に記載の融氷組成物を含む、方法。
［項２９］
表面上の氷の形成を防止するための方法であって、
氷が形成される前に融氷組成物を表面に適用することを含み、
融氷組成物が、項16に記載の融氷組成物を含む、方法。
［項３０］
表面上の氷の形成を防止するための方法であって、
氷が形成される前に融氷組成物を表面に適用することを含み、
融氷組成物が、項18に記載の融氷組成物を含む、方法。
Those skilled in the art are skilled in the art to disclose the subject matter of this specification, including the best forms, and to make and use any device or system, as well as to carry out embedded methods. Examples are used to make it possible to implement this disclosure. The patentable scope of the subject matter is defined by the claims and may include other examples reminiscent of those skilled in the art. If the components are not different from those described in the claims, or if they contain equivalent components that are not so different from those described in the claims, such other examples are within the scope of the claims. Suppose there is.
The present invention includes, for example, the following aspects.
[Item 1]
At least one solvent,
0.01-about 55% by weight of at least one deicing agent, as well as
At least one additive selected from the group consisting of 0.01 to about 25% by weight of ionic liquids, deep eutectic solvents, dispersants, and combinations thereof.
Including an ice melting composition.
[Item 2]
Item 2. The ice melting composition according to Item 1, wherein at least one additive contains at least one ionic liquid.
[Item 3]
At least one ionic liquid is 4- (2-hydroxy-propyl) -1-methyl-4H-imidazolium hexafluorophosphate, 3-methyl-1- (propane-2-ol) -imidazolium hexafluorophos. Fert, 3-Methyl-1- (Propan-2-ol)-Imidazolium chloride, 3-Methyl-1- (Propan-2-ol)-Imidazolium nitrate, 3-Methyl-1- (ethoxyethoxy)- Imidazolium hexafluorophosphate, 3-hexyl-1- (2-diethylphosphonate-ethyl) -imidazolium tetrafluoroborate, 3-hexyl-1- (3-diethylphosphonate-propyl) -imidazolium tetrafluoro Borato, 3-octyl-1- (2-diethylphosphonate-ethyl) -imidazolium tetrafluoroborate, 3-methyl-1-butyl-imidazolium tetrafluoroborate, 3-methyl-1-butyl-imidazole Lium chloride, 3-Methyl-1-butyl-imidazolium octylsulfate, 3-methyl-1-butyl-imidazolium fluorohydrogenate, 3-methyl-1-ethyl-imidazolium tricyanomethane, 3-methyl- 1-Ethyl-Imidazolium Fluorohydrogenate, 3-Methyl-1-ethyl-Imidazolium Carborane, 3-Methyl-1-Ethyl-Imidazolium Methyl Carborane, 3-Methyl-1-Ethyl-Imidazolium EthylCarborane, 3 -Methyl-1-methyl-imidazolium fluorohydrogenate, 3-methyl-1-propyl-imidazolium fluorohydrogenate, 3-methyl-1-pentyl-imidazolium fluorohydrogenate, 3-methyl-1- Hexil-imidazolium fluorohydrogenate, 3-methyl-1-hexyl-imidazolium chloride, 3-methyl-1-octyl-imidazolium chloride, 3-methyl-1-octyl-imidazolium tetrafluoroborate, 3- Methyl-1-methyl-imidazolium tetrafluoroborate, 3-methyl-2-ethyl-1-methyl-imidazolium carborate, tetraethylammonium tributyloctylborate, tetraethylammonium acetate, hexyl-triethyl-ammonium hexyl-triethyl Borat, Hexyl-Triethyl-Ammonium Tributyl Octyl Borat, Tetrapropylammonium tripropylhexylborate, tetrabutylammonium tributylhexylborate, hexyl-tri-butylammonium tributylhexylborate, hexyl-tri-butylammonium bis-trifluoromethanesulfonamide, heptyl-tri-butylammonium bis-trifluo Propylsulfonamide, tetrapentylammonium bis-trifluoromethanesulfonamide, octyl-tri-butylammonium bis-trifluoromethanesulfonamide, octyl-tri-butylammonium trifluoromethylsulfonate, tetrahexylammonium bis-trifluoromethanesulfonamide, tetra Hexylammonium Tributylhexylborate, Tetraheptylammonium bis-trifluoromethanesulfonamide, Tetraoctylammonium bis-trifluoromethanesulfonamide, Tetradodecylammonium bis-trifluoromethanesulfonamide, N-Methyl-N-propylpyrrolidin disyanimide, N -Methyl-N-butylpyrrolidin disianimide, N-methyl-N-hexylpyrrolidin disianimide, [bis- (N-butyl-N-ethyl-amino) -methylene]-dimethyl-ammonium tetrafluoroborate, [ Bis-(N-Hexyl-N-Hexyl-Amino) -Methyl] -Dimethyl-Ammonium Tetrafluoroborate, [Bis- (N-Hexyl-N-Hexyl-Amino) -Methyl] -Dimethyl-Ammonium Hexafluorophosphate , [Bis- (N-Hexyl-N-Hexyl-Amino) -Methyl] -Dimethyl-Ammonyl chloride, [Bis- (N-Hexyl-N-Hexyl-Amino) -Methyl] -Dimethyl-Ammonium Bis-Trifluoromethanesulfon Amid, [bis- (N-octyl-N-octyl-amino) -methylene] -dimethyl-ammonium tetrafluoroborate, [bis- (N-octyl-N-octyl-amino) -methyl] -dimethyl-ammonium hexa Fluorophosphate, [bis- (N-octyl-N-octyl-amino) -methylene] -dimethylammonium chloride, methyl-tripropylphosphonium tosylate, methyl-tri- (iso-butyl) phosphonium tosylate, methyl-tri -(tert-Butyl) Phosphonium tosylate , Methyl-di- (iso-butyl) -octylphosphonium tosylate, methyl-di- (iso-butyl) -tetradecylphosphonium tocilate, tetradecyl-tri- (hexyl) -phosphonium bromide, tetradecyl-tri- (hexyl) -Phosphornium tetrafluoroborate, tetradecyl-tri- (hexyl)-phosphonium hexafluorophosphate, octyl imidazolium salicylate, nonyl imidazolium salicylate, dodecyl imidazolium salicylate, (butyloxymethyl) imidazolium sali Tirate, 1-ethyl-3-methylimidazolium tetrafluoroborate, 1-butyl-3-methylimidazolium tetrafluoroborate, 1-hexyl-3-methylimidazolium tetrafluoroborate, 1-methyl-3 -Octylimidazolium tetrafluoroborate, 1-butylpyridinium tetrafluoroborate, 1-butyl-3-methylpyridinium tetrafluoroborate, 1-butyl-4-methylpyridinium tetrafluoroborate, 1-butyl-3- Methylimidazolium hexafluorophosphate, 1-hexyl-3-methylimidazolium hexafluorophosphate, 1-methyl-3-octylimidazolium, 1-butylpyridinium hexafluorophosphate, 1-butyl-3-methylpyridinium hexa Fluorophosphate, 1-butyl-4-methylpyridinium hexafluorophosphate, 1-ethyl-3-methylimidazolium diethylphosphate, 1,3-dimethylimidazolium dimethylphosphate, cholinedihydrogenphosphate, 1-ethyl -3-Methylimidazolium ethyl sulfate, 1-ethyl-3-methylimidazolium hydrogen sulfate, 1-ethyl-3-methylimidazolium acetate, ethylammonium nitrate, triethylsulfonium bis (trifluoromethylsulfonyl) Imid, Methyltrioctylammonium bis (trifluoromethylsulfonyl) imide, 1-ethyl-3-methylimidazolium bis (trifluoromethylsulfonyl) imide, 1-methyl-3-propylimidazolium bis (trifluoromethylsulfonyl) imide , 1,2-Dimethyl-3-propylimidazolium bis (trifluoromethylsulfonyl) imide, 1-butyl-3- Methylimidazolium bis (trifluoromethylsulfonyl) imide, 1-butyl-2,3-dimethylimidazolium bis (trifluoromethylsulfonyl) imide, 1-hexyl-3-methylimidazolium bis (trifluoromethylsulfonyl) imide, 1-Hexadecyl-3-methylimidazolium bis (trifluoromethylsulfonyl) imide, 1-allyl-3-methylimidazolium bis (trifluoromethylsulfonyl) imide, 1-methyl-1-propylpyrrolidinium bis (trifluoro) Methylsulfonyl) imide, 1-butyl-1-methylpyrrolidinium bis (trifluoromethylsulfonyl) imide, 1-methyl-1-propylpiperidinium bis (trifluoromethylsulfonyl) imide, 1-butylpyridinium bis (tri) Fluoromethylsulfonyl) imide, 1-butyl-3-methylpyridinium bis (trifluoromethylsulfonyl) imide, 1-butyl-4-methylpyridinium bis (trifluoromethylsulfonyl) imide, trihexyltetradecylphosphonium bis (trifluoromethyl) Sulfonyl) imide, 1-ethyl-3-methylimidazolium trifurate, 1-butyl-3-methylimidazolium trifurate, 1-hexyl-3-methylimidazolium trifurate, 1-methyl-3-octylimidazolium trifurate, 1- Butyl-1-methylpyrrolidinium trifurate, 1-ethyl-3-methylimidazolium thiocyanate, 1-ethyl-3-methylimidazolium dicyanamide, 1-butyl-3-methylimidazolium dicyanamide, 1-butyl -1-Methylpyrrolidinium disianamide, 1-ethyl-3-methylimidazolium chloride, 1-butyl-3-methylimidazolium chloride, 1-allyl-3-methylimidazolium chloride, trihexyltetradecylphosphonium chloride, 1-Ethyl-3-methylimidazolium bromide, 1-butyl-3-methylimidazolium bromide, 1,3-dimethylimidazolium iodide, 1-ethyl-3-methylimidazolium iodide, 1-methyl-3- Propylimidazolium iodide, 1-butyl-3-methylimidazolium iodide, 1-hexyl-3-methylimidazolium iodide, 1-allyl-3-methylimidazolium iodide, (Tris-2-hydroxyethi) L) The ice melting composition according to Item 2, which is selected from the group consisting of methylammonium methylsulfate, 1-ethyl-3-methylimidazolium acetate, and combinations thereof.
[Item 4]
Item 2. The item 3 wherein at least one ionic liquid is selected from the group consisting of (Tris-2-hydroxyethyl) methylammonium methylsulfate, 1-ethyl-3-methylimidazolium acetate and combinations thereof. Ice melting composition.
[Item 5]
Item 2. The ice melting composition according to Item 2, which comprises 0.1 to 5.0% by weight of at least one ionic liquid.
[Item 6]
Item 2. The ice melting composition according to Item 1, wherein at least one additive contains at least one deep eutectic solvent.
[Item 7]
At least one deep eutectic solvent is selected from the group consisting of type I deep eutectic solvents, type II deep eutectic solvents, type III deep eutectic solvents, type IV deep eutectic solvents, and combinations thereof. Item 6. The ice melting composition according to Item 6.
[Item 8]
Item 7. The ice melting composition according to Item 7, wherein the at least one deep eutectic solvent is 1: 1 choline chloride and glycol.
[Item 9]
At least one deicing agent is sodium chloride, calcium chloride, potassium chloride, magnesium chloride, sodium acetate, calcium acetate, potassium acetate, magnesium acetate, magnesium acetate, ammonium nitrate, ammonium sulfate, sodium formate, potassium formate, calcium formate, Item 2. The ice-melting composition according to Item 1, selected from the group consisting of magnesium formate, urea, sand, and a combination thereof.
[Item 10]
Item 9. The ice melting composition according to Item 9, wherein at least one deicing agent contains magnesium chloride.
[Item 11]
Item 6. The ice melting composition according to Item 10, which comprises 25 to 35% by weight of at least one deicing agent.
[Item 12]
At least one solvent is acetic acid, acetone, acetonitrile, benzene, n-butanol, s-butanol, t-butanol, 2-butanone, carbon tetrachloride, chlorobenzene, chloroform, cyclohexane, cyclopentane, 1,2-dichloroethane, Dichloromethane, diethyl ether, diethylene glycol, diglyme, dimethylformamide, dimethylsulfoxide, 1,4-dioxane, ethanol, ethyl acetate, formic acid, grim, heptane, hexamethylphosphoramide, hexamethylphosphate triamide, hexane, isopropanol, methanol, Selected from the group consisting of methyl t-butyl ether, nitromethane, pentane, petroleum ether, propanol, propylene carbonate, pyridine, sulfolane, tetrahydrofuran, toluene, water, m-xylene, o-xylene, p-xylene, and combinations thereof. , Item 1. The ice melting composition.
[Item 13]
Item 12. The ice melting composition according to Item 12, wherein at least one solvent comprises water.
[Item 14]
Item 2. The ice melting composition according to Item 1, wherein at least one additive contains at least one dispersant in an amount of 0.01 to 1.0% by weight.
[Item 15]
Item 12. The fusion according to Item 14, wherein at least one dispersant is selected from the group consisting of poly (alkylene) glycol, (poly) propylene glycol, (poly) ethylene glycol, propylene glycol, ethylene glycol, and combinations thereof. Ice composition.
[Item 16]
water,
About 30% by weight magnesium chloride,
Approximately 3.5% by weight of an ionic liquid selected from the group consisting of (tris-2-hydroxyethyl) methylammonium methylsulfate, 1-ethyl-3-methylimidazolium acetate and combinations thereof, as well.
0.02-1.0% by weight (poly) ethylene glycol
Item 4. The ice melting composition according to Item 14.
[Item 17]
Item 2. The ice melting composition according to Item 1, which has an increased saturation point as compared with the same composition which does not contain at least one additive.
[Item 18]
water,
Approximately 30% by weight magnesium chloride, and
0.02-1.0% by weight (poly) ethylene glycol
Item 5. The ice melting composition according to Item 15.
[Item 19]
A way to melt the ice on the surface,
Including applying the ice melting composition to the surface after the ice is formed,
The ice melting composition
At least one solvent,
0.01-about 55% by weight of at least one deicing agent, as well as
A method comprising 0.01 to about 25% by weight of at least one additive selected from the group consisting of ionic liquids, deep eutectic solvents, dispersants and combinations thereof.
[Item 20]
The ice melting composition
About 30% by weight magnesium chloride,
Approximately 3.5% by weight of an ionic liquid selected from the group consisting of (tris-2-hydroxyethyl) methylammonium methylsulfate, 1-ethyl-3-methylimidazolium acetate and combinations thereof, as well.
0.02 to about 1.0% by weight of poly (ethylene) glycol
19. The method according to paragraph 19.
[Item 21]
Surfaces are buildings, roofs, gutters, inside or outside of pipes, non-porous asphalt roads, asphalt roads, porous asphalt roads, concrete roads, bitumen roads, brick roads, gravel roads, paved roads, unpaved roads, Item 19. The method of item 19, wherein the method is selected from the group consisting of bridges, elevated roads, paved roads, windows, sideways, passages, paved passages, runways, aircraft, automobiles, trucks, vehicles and vehicle windshields.
[Item 22]
A way to melt the ice on the surface,
Including applying the ice melting composition to the surface after the ice is formed,
A method, wherein the ice melting composition comprises the ice melting composition according to Item 1.
[Item 23]
A way to melt the ice on the surface,
Including applying the ice melting composition to the surface after the ice is formed,
The method, wherein the ice melting composition comprises the ice melting composition according to Item 16.
[Item 24]
A way to melt the ice on the surface,
Including applying the ice melting composition to the surface after the ice is formed,
The method, wherein the ice melting composition comprises the ice melting composition according to Item 18.
[Item 25]
A method to prevent the formation of ice on the surface,
Including applying the ice melting composition to the surface before the ice is formed,
The ice melting composition
At least one solvent,
0.01-about 55% by weight of at least one deicing agent, as well as
A method comprising 0.01 to about 25% by weight of at least one additive selected from the group consisting of ionic liquids, deep eutectic solvents, dispersants, and combinations thereof.
[Item 26]
The ice melting composition
About 30% by weight magnesium chloride,
Approximately 3.5% by weight of an ionic liquid selected from the group consisting of (tris-2-hydroxyethyl) methylammonium methylsulfate, 1-ethyl-3-methylimidazolium acetate and combinations thereof, as well.
0.02-1.0% by weight poly (ethylene) glycol
25.
[Item 27]
Surfaces are buildings, roofs, gutters, inside or outside of pipes, non-porous asphalt roads, asphalt roads, porous asphalt roads, concrete roads, bitumen roads, brick roads, gravel roads, paved roads, unpaved roads, Item 25. The method of item 25, which is selected from the group consisting of bridges, elevated roads, paved roads, windows, sideways, passages, paved passages, runways, aircraft, automobiles, trucks, vehicles and vehicle windshields.
[Item 28]
A method to prevent the formation of ice on the surface,
Including applying the ice melting composition to the surface before the ice is formed,
A method, wherein the ice melting composition comprises the ice melting composition according to Item 1.
[Item 29]
A method to prevent the formation of ice on the surface,
Including applying the ice melting composition to the surface before the ice is formed,
The method, wherein the ice melting composition comprises the ice melting composition according to Item 16.
[Item 30]
A method to prevent the formation of ice on the surface,
Including applying the ice melting composition to the surface before the ice is formed,
The method, wherein the ice melting composition comprises the ice melting composition according to Item 18.
Claims (30)
0.01～約55重量%の少なくとも1種の除氷剤、並びに
0.01～約25重量%の、イオン液体、深共晶溶媒、分散剤、及びそれらの組み合わせからなる群から選択される少なくとも1種の添加剤
を含む、融氷組成物。 At least one solvent,
0.01-about 55% by weight of at least one deicing agent, as well as
An ice melting composition comprising 0.01 to about 25 % by weight of at least one additive selected from the group consisting of ionic liquids, deep eutectic solvents, dispersants, and combinations thereof.
約30重量%の塩化マグネシウム、
約3.5重量%の、(トリス-2-ヒドロキシエチル)メチルアンモニウムメチルスルファート、1-エチル-3-メチルイミダゾリウムアセタート及びそれらの組み合わせからなる群から選択されるイオン液体、並びに
0.02～1.0重量%の(ポリ)エチレングリコール
を含む、請求項14に記載の融氷組成物。 water,
About 30% by weight magnesium chloride,
Approximately 3.5% by weight of an ionic liquid selected from the group consisting of (tris-2-hydroxyethyl) methylammonium methylsulfate, 1-ethyl-3-methylimidazolium acetate and combinations thereof, as well.
The ice melting composition according to claim 14, which comprises 0.02 to 1.0% by weight of (poly) ethylene glycol.
約30重量%の塩化マグネシウム、及び
0.02～1.0重量%の(ポリ)エチレングリコール
を含む、請求項15に記載の融氷組成物。 water,
Approximately 30% by weight magnesium chloride, and
The ice melting composition according to claim 15, which comprises 0.02 to 1.0% by weight of (poly) ethylene glycol.
氷が形成された後に融氷組成物を表面に適用することを含み、
融氷組成物が、
少なくとも1種の溶媒、
0.01～約55重量%の少なくとも1種の除氷剤、並びに
0.01～約25重量%の、イオン液体、深共晶溶媒、分散剤及びそれらの組み合わせからなる群から選択される少なくとも1種の添加剤を含む、方法。 A way to melt the ice on the surface,
Including applying the ice melting composition to the surface after the ice is formed,
The ice melting composition
At least one solvent,
0.01-about 55% by weight of at least one deicing agent, as well as
A method comprising 0.01 to about 25% by weight of at least one additive selected from the group consisting of ionic liquids, deep eutectic solvents, dispersants and combinations thereof.
約30重量%の塩化マグネシウム、
約3.5重量%の、(トリス-2-ヒドロキシエチル)メチルアンモニウムメチルスルファート、1-エチル-3-メチルイミダゾリウムアセタート及びそれらの組み合わせからなる群から選択されるイオン液体、並びに
0.02～約1.0重量%のポリ(エチレン)グリコール
を含む、請求項19に記載の方法。 The ice melting composition
About 30% by weight magnesium chloride,
Approximately 3.5% by weight of an ionic liquid selected from the group consisting of (tris-2-hydroxyethyl) methylammonium methylsulfate, 1-ethyl-3-methylimidazolium acetate and combinations thereof, as well.
19. The method of claim 19, comprising 0.02 to about 1.0% by weight of poly (ethylene) glycol.
氷が形成された後に融氷組成物を表面に適用することを含み、
融氷組成物が、請求項1に記載の融氷組成物を含む、方法。 A way to melt the ice on the surface,
Including applying the ice melting composition to the surface after the ice is formed,
A method, wherein the ice melting composition comprises the ice melting composition according to claim 1.
氷が形成された後に融氷組成物を表面に適用することを含み、
融氷組成物が、請求項16に記載の融氷組成物を含む、方法。 A way to melt the ice on the surface,
Including applying the ice melting composition to the surface after the ice is formed,
A method, wherein the ice melting composition comprises the ice melting composition of claim 16.
氷が形成された後に融氷組成物を表面に適用することを含み、
融氷組成物が、請求項18に記載の融氷組成物を含む、方法。 A way to melt the ice on the surface,
Including applying the ice melting composition to the surface after the ice is formed,
A method, wherein the ice melting composition comprises the ice melting composition of claim 18.
氷が形成される前に融氷組成物を表面に適用することを含み、
融氷組成物が、
少なくとも１種の溶媒、
0.01～約55重量%の少なくとも1種の除氷剤、並びに
0.01～約25重量%の、イオン液体、深共晶溶媒、分散剤、及びそれらの組み合わせからなる群から選択される少なくとも1種の添加剤を含む、方法。 A method to prevent the formation of ice on the surface,
Including applying the ice melting composition to the surface before the ice is formed,
The ice melting composition
At least one solvent,
0.01-about 55% by weight of at least one deicing agent, as well as
A method comprising 0.01 to about 25 % by weight of at least one additive selected from the group consisting of ionic liquids, deep eutectic solvents, dispersants, and combinations thereof.
約30重量%の塩化マグネシウム、
約3.5重量%の、(トリス-2-ヒドロキシエチル)メチルアンモニウムメチルスルファート、1-エチル-3-メチルイミダゾリウムアセタート及びそれらの組み合わせからなる群から選択されるイオン液体、並びに
0.02～1.0重量%のポリ(エチレン)グリコール
を含む、請求項25に記載の方法。 The ice melting composition
About 30% by weight magnesium chloride,
Approximately 3.5% by weight of an ionic liquid selected from the group consisting of (tris-2-hydroxyethyl) methylammonium methylsulfate, 1-ethyl-3-methylimidazolium acetate and combinations thereof, as well.
25. The method of claim 25, comprising 0.02 to 1.0 % by weight of poly (ethylene) glycol.
氷が形成される前に融氷組成物を表面に適用することを含み、
融氷組成物が、請求項1に記載の融氷組成物を含む、方法。 A method to prevent the formation of ice on the surface,
Including applying the ice melting composition to the surface before the ice is formed,
A method, wherein the ice melting composition comprises the ice melting composition according to claim 1.
氷が形成される前に融氷組成物を表面に適用することを含み、
融氷組成物が、請求項16に記載の融氷組成物を含む、方法。 A method to prevent the formation of ice on the surface,
Including applying the ice melting composition to the surface before the ice is formed,
A method, wherein the ice melting composition comprises the ice melting composition of claim 16.
氷が形成される前に融氷組成物を表面に適用することを含み、
融氷組成物が、請求項18に記載の融氷組成物を含む、方法。 A method to prevent the formation of ice on the surface,
Including applying the ice melting composition to the surface before the ice is formed,
A method, wherein the ice melting composition comprises the ice melting composition of claim 18.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201862618877P | 2018-01-18 | 2018-01-18 | |
| US62/618,877 | 2018-01-18 | ||
| PCT/EP2019/050473 WO2019141568A1 (en) | 2018-01-18 | 2019-01-10 | Increased saturation of ice melting compositions and methods of use |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2021510760A JP2021510760A (en) | 2021-04-30 |
| JPWO2019141568A5 true JPWO2019141568A5 (en) | 2022-02-07 |
Family
ID=65031044
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2020539813A Ceased JP2021510760A (en) | 2018-01-18 | 2019-01-10 | Ice melting composition with increased saturation and usage |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US11584874B2 (en) |
| EP (1) | EP3740543A1 (en) |
| JP (1) | JP2021510760A (en) |
| KR (1) | KR20200108449A (en) |
| CN (1) | CN111511871A (en) |
| AU (1) | AU2019209219A1 (en) |
| CA (1) | CA3086816A1 (en) |
| WO (1) | WO2019141568A1 (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113046026B (en) * | 2021-04-07 | 2023-03-24 | 山西大同大学 | Chlorine-free low-corrosivity coal antifreezing solution |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63117089A (en) * | 1986-11-05 | 1988-05-21 | Mototada Matsushima | Liquid snow and ice thawing agent |
| JP2013506753A (en) * | 2009-10-05 | 2013-02-28 | カーギル・インコーポレイテッド | Improved antifreeze composition |
| US8187489B1 (en) * | 2011-03-23 | 2012-05-29 | The United States Of America As Represented By The Secretary Of The Navy | Biodegradable ionic liquids for aircraft deicing |
| CN103709995B (en) * | 2013-12-04 | 2015-01-14 | 宁波保税区安德利斯机械有限公司 | Environmentally-friendly runway snow melting and deicing agent |
| CN104862709A (en) | 2015-04-28 | 2015-08-26 | 安徽不二越精工轴承有限公司 | Steel material anticorrosion conditioning fluid |
| CN105062421A (en) * | 2015-09-06 | 2015-11-18 | 温州泓呈祥科技有限公司 | Environment-friendly snow-melting agent and preparation method thereof |
| CN107129874A (en) * | 2017-05-23 | 2017-09-05 | 句容耀皮节能玻璃科技发展有限公司 | A kind of automobile glass water and preparation method thereof |
| CN107083234A (en) * | 2017-05-23 | 2017-08-22 | 句容耀皮节能玻璃科技发展有限公司 | A kind of automobile glass anti-fog antifreezing agent and preparation method thereof |
-
2019
- 2019-01-10 JP JP2020539813A patent/JP2021510760A/en not_active Ceased
- 2019-01-10 WO PCT/EP2019/050473 patent/WO2019141568A1/en unknown
- 2019-01-10 US US16/961,960 patent/US11584874B2/en active Active
- 2019-01-10 KR KR1020207023089A patent/KR20200108449A/en unknown
- 2019-01-10 EP EP19700656.2A patent/EP3740543A1/en not_active Withdrawn
- 2019-01-10 AU AU2019209219A patent/AU2019209219A1/en active Pending
- 2019-01-10 CA CA3086816A patent/CA3086816A1/en active Pending
- 2019-01-10 CN CN201980006693.6A patent/CN111511871A/en active Pending
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US8006551B2 (en) | Methods and compositions for removing residues and substances from substrates using environmentally friendly solvents | |
| US8702343B1 (en) | Method and composition for road construction and surfacing | |
| US7825074B2 (en) | Hydrolytically and hydrothermally stable consolidation or change in the wetting behavior of geological formations | |
| US8104991B2 (en) | Method and composition for road construction and surfacing | |
| KR101881049B1 (en) | Water proofing apparatus for bridge and water proofing method using reflection crack stiffner | |
| US10030483B2 (en) | Carbon dioxide and hydrocarbon assisted enhanced oil recovery | |
| US8915671B2 (en) | System and method of forming a roadway comprising polyurethane | |
| KR101953381B1 (en) | Melting fiber coat for tack coating and method of manufacturing the same and asphalt pavement method using the same | |
| JPWO2019141568A5 (en) | ||
| JP2002524645A (en) | Aqueous fluorinated polymer dispersion capable of protecting asphalt material | |
| CN110484230A (en) | Fat-soluble dissolution nanometer displacement agent of viscous crude cold water injection and its preparation method and application | |
| WO2015171596A1 (en) | Flash point adjustment of wettability alteration chemicals in hydrocarbon solvents | |
| US11584874B2 (en) | Increased saturation of ice melting compositions and methods of use | |
| US3344721A (en) | Pneumatic compaction of asphalt compositions | |
| JPH08127761A (en) | Abherent | |
| KR20190133222A (en) | Sand solidification with petroleum products | |
| CN100427568C (en) | Ion liquid solvent for dissolving and removing asphaltene deposit and preparing method thereof, and method for removing asphaltene and regeneration method of the ion liquid solvent | |
| RU143147U1 (en) | WATERPROOF TAPE | |
| US1455010A (en) | Method of drilling wells | |
| RU2015129711A (en) | COMPOSITION OF BITUMINOUS BINDER FOR PRODUCING BITUMINOMERAL MIXTURES AT LOW TEMPERATURES | |
| JP2017088672A (en) | Liquid antifreezing agent | |
| FR2641806A1 (en) | METHOD FOR STABILIZING A FURNISHED LAND AREA | |
| FR2484492A1 (en) | Regenerator surfacer for old bituminous carriageway - has automatic binder regenerator additive dosage by linkage to surfacer vehicle speed | |
| US11987747B2 (en) | Sand consolidation using asphaltene/tar with solvents and adsorption system | |
| KR102439716B1 (en) | Asphalt concrete coating emulsions for asphalt repair and asphalt pavement method using thereof |