JPWO2018050497A5 - - Google Patents
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- JPWO2018050497A5 JPWO2018050497A5 JP2019513916A JP2019513916A JPWO2018050497A5 JP WO2018050497 A5 JPWO2018050497 A5 JP WO2018050497A5 JP 2019513916 A JP2019513916 A JP 2019513916A JP 2019513916 A JP2019513916 A JP 2019513916A JP WO2018050497 A5 JPWO2018050497 A5 JP WO2018050497A5
- Authority
- JP
- Japan
- Prior art keywords
- flame retardant
- aluminum
- hpo
- stabilizer
- stabilizer combination
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 239000000203 mixture Substances 0.000 description 49
- 239000003381 stabilizer Substances 0.000 description 32
- 229910052782 aluminium Inorganic materials 0.000 description 16
- HJJOHHHEKFECQI-UHFFFAOYSA-N aluminum;phosphite Chemical class [Al+3].[O-]P([O-])[O-] HJJOHHHEKFECQI-UHFFFAOYSA-N 0.000 description 15
- 239000003063 flame retardant Substances 0.000 description 12
- -1 triazine compound Chemical class 0.000 description 12
- 229920000642 polymer Polymers 0.000 description 9
- JDSHMPZPIAZGSV-UHFFFAOYSA-N Melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 8
- 229920000877 Melamine resin Polymers 0.000 description 8
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminum Chemical class [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 8
- 229920000388 Polyphosphate Polymers 0.000 description 7
- 239000001205 polyphosphate Substances 0.000 description 7
- 235000011176 polyphosphates Nutrition 0.000 description 7
- 238000010137 moulding (plastic) Methods 0.000 description 6
- 239000000835 fiber Substances 0.000 description 5
- 229910052725 zinc Inorganic materials 0.000 description 5
- 239000011701 zinc Substances 0.000 description 5
- YZEZMSPGIPTEBA-UHFFFAOYSA-N 2-N-(4,6-diamino-1,3,5-triazin-2-yl)-1,3,5-triazine-2,4,6-triamine Chemical compound NC1=NC(N)=NC(NC=2N=C(N)N=C(N)N=2)=N1 YZEZMSPGIPTEBA-UHFFFAOYSA-N 0.000 description 4
- XECAHXYUAAWDEL-UHFFFAOYSA-N Acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 description 4
- 229920000122 Acrylonitrile butadiene styrene Polymers 0.000 description 4
- POJWUDADGALRAB-PVQJCKRUSA-N Allantoin Natural products NC(=O)N[C@@H]1NC(=O)NC1=O POJWUDADGALRAB-PVQJCKRUSA-N 0.000 description 4
- 125000002853 C1-C4 hydroxyalkyl group Chemical group 0.000 description 4
- 125000004648 C2-C8 alkenyl group Chemical group 0.000 description 4
- 241000219112 Cucumis Species 0.000 description 4
- 235000015510 Cucumis melo subsp melo Nutrition 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 description 4
- 239000007795 chemical reaction product Substances 0.000 description 4
- 239000007859 condensation product Substances 0.000 description 4
- 125000000524 functional group Chemical group 0.000 description 4
- 229910052739 hydrogen Inorganic materials 0.000 description 4
- 239000001257 hydrogen Substances 0.000 description 4
- 150000002431 hydrogen Chemical group 0.000 description 4
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 4
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 4
- YSRVJVDFHZYRPA-UHFFFAOYSA-N melem Chemical compound NC1=NC(N23)=NC(N)=NC2=NC(N)=NC3=N1 YSRVJVDFHZYRPA-UHFFFAOYSA-N 0.000 description 4
- XFZRQAZGUOTJCS-UHFFFAOYSA-N phosphoric acid;1,3,5-triazine-2,4,6-triamine Chemical compound OP(O)(O)=O.NC1=NC(N)=NC(N)=N1 XFZRQAZGUOTJCS-UHFFFAOYSA-N 0.000 description 4
- 229920001169 thermoplastic Polymers 0.000 description 4
- HCHKCACWOHOZIP-UHFFFAOYSA-N zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 4
- XLOMVQKBTHCTTD-UHFFFAOYSA-N zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 4
- LCANECIWPMDASZ-UHFFFAOYSA-N 2-isocyanatoethanol Chemical compound OCCN=C=O LCANECIWPMDASZ-UHFFFAOYSA-N 0.000 description 3
- ILRRQNADMUWWFW-UHFFFAOYSA-K Aluminium phosphate Chemical class O1[Al]2OP1(=O)O2 ILRRQNADMUWWFW-UHFFFAOYSA-K 0.000 description 3
- NUJOXMJBOLGQSY-UHFFFAOYSA-N Manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 description 3
- 239000004793 Polystyrene Substances 0.000 description 3
- XOLBLPGZBRYERU-UHFFFAOYSA-N Tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 3
- 239000007983 Tris buffer Substances 0.000 description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-K [O-]P([O-])([O-])=O Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 3
- 229910000468 manganese oxide Inorganic materials 0.000 description 3
- IPJKJLXEVHOKSE-UHFFFAOYSA-L manganese(2+);dihydroxide Chemical compound [OH-].[OH-].[Mn+2] IPJKJLXEVHOKSE-UHFFFAOYSA-L 0.000 description 3
- AMWRITDGCCNYAT-UHFFFAOYSA-L manganese(II,III) oxide Inorganic materials [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 description 3
- LCLMKSPTPNBUGU-UHFFFAOYSA-N oxotin;hydrate Chemical compound O.[Sn]=O LCLMKSPTPNBUGU-UHFFFAOYSA-N 0.000 description 3
- 239000010452 phosphate Substances 0.000 description 3
- 235000021317 phosphate Nutrition 0.000 description 3
- 239000004417 polycarbonate Substances 0.000 description 3
- 229920000728 polyester Polymers 0.000 description 3
- 229920001955 polyphenylene ether Polymers 0.000 description 3
- 229920002223 polystyrene Polymers 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 229910001887 tin oxide Inorganic materials 0.000 description 3
- GZVHEAJQGPRDLQ-UHFFFAOYSA-N 6-phenyl-1,3,5-triazine-2,4-diamine Chemical compound NC1=NC(N)=NC(C=2C=CC=CC=2)=N1 GZVHEAJQGPRDLQ-UHFFFAOYSA-N 0.000 description 2
- 229960000458 Allantoin Drugs 0.000 description 2
- LFVGISIMTYGQHF-UHFFFAOYSA-N Ammonium dihydrogen phosphate Chemical compound [NH4+].OP(O)([O-])=O LFVGISIMTYGQHF-UHFFFAOYSA-N 0.000 description 2
- ZRIUUUJAJJNDSS-UHFFFAOYSA-N Ammonium phosphates Chemical compound [NH4+].[NH4+].[NH4+].[O-]P([O-])([O-])=O ZRIUUUJAJJNDSS-UHFFFAOYSA-N 0.000 description 2
- 239000004114 Ammonium polyphosphate Substances 0.000 description 2
- 229920001276 Ammonium polyphosphate Polymers 0.000 description 2
- AXCZMVOFGPJBDE-UHFFFAOYSA-L Calcium hydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 2
- NAQMVNRVTILPCV-UHFFFAOYSA-N Hexamethylenediamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 2
- VTHJTEIRLNZDEV-UHFFFAOYSA-L Magnesium hydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 2
- ZQKXQUJXLSSJCH-UHFFFAOYSA-N Melamine cyanurate Chemical compound NC1=NC(N)=NC(N)=N1.O=C1NC(=O)NC(=O)N1 ZQKXQUJXLSSJCH-UHFFFAOYSA-N 0.000 description 2
- IORMLXYGTOTABZ-UHFFFAOYSA-N O.O.O.O.[Al+3].[O-]P([O-])[O-] Chemical compound O.O.O.O.[Al+3].[O-]P([O-])[O-] IORMLXYGTOTABZ-UHFFFAOYSA-N 0.000 description 2
- AQSJGOWTSHOLKH-UHFFFAOYSA-N Phosphite Chemical compound [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 2
- 239000004952 Polyamide Substances 0.000 description 2
- XPPKVPWEQAFLFU-UHFFFAOYSA-J Pyrophosphate Chemical compound [O-]P([O-])(=O)OP([O-])([O-])=O XPPKVPWEQAFLFU-UHFFFAOYSA-J 0.000 description 2
- UGZADUVQMDAIAO-UHFFFAOYSA-L Zinc hydroxide Chemical compound [OH-].[OH-].[Zn+2] UGZADUVQMDAIAO-UHFFFAOYSA-L 0.000 description 2
- 239000004110 Zinc silicate Substances 0.000 description 2
- XSMMCTCMFDWXIX-UHFFFAOYSA-N Zinc silicate Chemical compound [Zn+2].[O-][Si]([O-])=O XSMMCTCMFDWXIX-UHFFFAOYSA-N 0.000 description 2
- NCPIYHBOLXSJJR-UHFFFAOYSA-H [Al+3].[Al+3].[O-]P([O-])=O.[O-]P([O-])=O.[O-]P([O-])=O Chemical compound [Al+3].[Al+3].[O-]P([O-])=O.[O-]P([O-])=O.[O-]P([O-])=O NCPIYHBOLXSJJR-UHFFFAOYSA-H 0.000 description 2
- 229910001413 alkali metal ion Inorganic materials 0.000 description 2
- 229910000387 ammonium dihydrogen phosphate Inorganic materials 0.000 description 2
- 235000019826 ammonium polyphosphate Nutrition 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 239000000920 calcium hydroxide Substances 0.000 description 2
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 2
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium monoxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 2
- 239000003990 capacitor Substances 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- QGBSISYHAICWAH-UHFFFAOYSA-N cyanoguanidine Chemical compound NC(N)=NC#N QGBSISYHAICWAH-UHFFFAOYSA-N 0.000 description 2
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 2
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 description 2
- 235000011180 diphosphates Nutrition 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- ZRALSGWEFCBTJO-UHFFFAOYSA-N guanidine Chemical compound NC(N)=N ZRALSGWEFCBTJO-UHFFFAOYSA-N 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 239000000347 magnesium hydroxide Substances 0.000 description 2
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 2
- 239000000395 magnesium oxide Substances 0.000 description 2
- 235000019837 monoammonium phosphate Nutrition 0.000 description 2
- 125000001971 neopentyl group Chemical group [H]C([*])([H])C(C([H])([H])[H])(C([H])([H])[H])C([H])([H])[H] 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 229920002647 polyamide Polymers 0.000 description 2
- 239000011528 polyamide (building material) Substances 0.000 description 2
- 229920000515 polycarbonate Polymers 0.000 description 2
- 150000003385 sodium Chemical group 0.000 description 2
- 239000004753 textile Substances 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 229910021511 zinc hydroxide Inorganic materials 0.000 description 2
- 229940007718 zinc hydroxide Drugs 0.000 description 2
- 239000011787 zinc oxide Substances 0.000 description 2
- 235000019352 zinc silicate Nutrition 0.000 description 2
- HFBYLYCMISIEMM-FFHNEAJVSA-N (4R,4aR,7S,7aR,12bS)-9-methoxy-3-methyl-2,4,4a,5,6,7,7a,13-octahydro-1H-4,12-methanobenzofuro[3,2-e]isoquinoline-7-ol;phosphoric acid Chemical compound OP(O)(O)=O.C([C@H]1[C@H](N(CC[C@@]112)C)C3)C[C@H](O)[C@@H]1OC1=C2C3=CC=C1OC HFBYLYCMISIEMM-FFHNEAJVSA-N 0.000 description 1
- BPXVHIRIPLPOPT-UHFFFAOYSA-N 1,3,5-tris(2-hydroxyethyl)-1,3,5-triazinane-2,4,6-trione Chemical compound OCCN1C(=O)N(CCO)C(=O)N(CCO)C1=O BPXVHIRIPLPOPT-UHFFFAOYSA-N 0.000 description 1
- 125000004493 2-methylbut-1-yl group Chemical group CC(C*)CC 0.000 description 1
- CGERYHYIVJQVLJ-UHFFFAOYSA-N 2-methylbutane Chemical group CC[C](C)C CGERYHYIVJQVLJ-UHFFFAOYSA-N 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K Aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- 229960005069 Calcium Drugs 0.000 description 1
- 210000001624 Hip Anatomy 0.000 description 1
- 229920001225 Polyester resin Polymers 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N Silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 229920002803 Thermoplastic polyurethane Polymers 0.000 description 1
- 239000004433 Thermoplastic polyurethane Substances 0.000 description 1
- LRXTYHSAJDENHV-UHFFFAOYSA-H Zinc phosphate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LRXTYHSAJDENHV-UHFFFAOYSA-H 0.000 description 1
- 239000005083 Zinc sulfide Substances 0.000 description 1
- ZDVLIXBJVNYNSW-UHFFFAOYSA-J [Mg+2].C([O-])([O-])=O.[Ca+2].C([O-])([O-])=O.[Mg+2] Chemical compound [Mg+2].C([O-])([O-])=O.[Ca+2].C([O-])([O-])=O.[Mg+2] ZDVLIXBJVNYNSW-UHFFFAOYSA-J 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N al2o3 Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- STNCDALPBBWSTC-UHFFFAOYSA-K aluminum;hydroxide;sulfate Chemical compound [OH-].[Al+3].[O-]S([O-])(=O)=O STNCDALPBBWSTC-UHFFFAOYSA-K 0.000 description 1
- ZQKXOSJYJMDROL-UHFFFAOYSA-H aluminum;trisodium;diphosphate Chemical compound [Na+].[Na+].[Na+].[Al+3].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O ZQKXOSJYJMDROL-UHFFFAOYSA-H 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 229910001593 boehmite Inorganic materials 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N calcium Chemical group [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 239000000292 calcium oxide Substances 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 1
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- PWZFXELTLAQOKC-UHFFFAOYSA-A dialuminum;hexamagnesium;carbonate;hexadecahydroxide;tetrahydrate Chemical compound O.O.O.O.[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Al+3].[Al+3].[O-]C([O-])=O PWZFXELTLAQOKC-UHFFFAOYSA-A 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 229910052732 germanium Inorganic materials 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000002241 glass-ceramic Substances 0.000 description 1
- 125000003187 heptyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 229920005669 high impact polystyrene Polymers 0.000 description 1
- 239000004797 high-impact polystyrene Substances 0.000 description 1
- 229910001701 hydrotalcite Inorganic materials 0.000 description 1
- 229960001545 hydrotalcite Drugs 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 125000001972 isopentyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910000000 metal hydroxide Inorganic materials 0.000 description 1
- 150000004692 metal hydroxides Chemical class 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 150000002829 nitrogen Chemical class 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 125000003538 pentan-3-yl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 125000000286 phenylethyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])C([H])([H])* 0.000 description 1
- ACVYVLVWPXVTIT-UHFFFAOYSA-M phosphinate Chemical compound [O-][PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-M 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920002959 polymer blend Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 238000004382 potting Methods 0.000 description 1
- 230000001681 protective Effects 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N silicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 229910052712 strontium Inorganic materials 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000002195 synergetic Effects 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 239000004634 thermosetting polymer Substances 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N titanium Chemical group [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
- 229910000165 zinc phosphate Inorganic materials 0.000 description 1
- 229910052984 zinc sulfide Inorganic materials 0.000 description 1
- DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Description
Ｒ５～Ｒ７は、それぞれ水素、Ｃ１－Ｃ８－アルキル、Ｃ５－Ｃ１６－シクロアルキルもしくは－アルキルシクロアルキル（これらはヒドロキシルまたはＣ１－Ｃ４－ヒドロキシアルキル官能基で置換されていてもよい）、Ｃ２－Ｃ８－アルケニル、Ｃ１－Ｃ８－アルコキシ、－アシル、－アシルオキシ、Ｃ６－Ｃ１２－アリールもしくは－アリールアルキル、－ＯＲ８および－Ｎ（Ｒ８）Ｒ９、Ｎ－脂環式基、またはＮ－芳香族基であり、
Ｒ８は、水素、Ｃ１－Ｃ８－アルキル、Ｃ５－Ｃ１６－シクロアルキルもしくは－アルキルシクロアルキル（これらはヒドロキシルまたはＣ１－Ｃ４－ヒドロキシアルキル官能基で置換されていてもよい）、Ｃ２－Ｃ８－アルケニル、Ｃ１－Ｃ８－アルコキシ、－アシル、－アシルオキシ、またはＣ６－Ｃ１２－アリールもしくは－アリールアルキルであり、
Ｒ９～Ｒ１３は、それぞれＲ８と同一の基であり、そしてまた－Ｏ－Ｒ８であり、
ｍおよびｎは、それぞれ独立に１、２、３、または４であり、
Ｘは、トリアジン化合物（ＩＩＩ）と一緒に付加体を形成し得る酸、またはトリス（ヒドロキシエチル）イソシアヌラートの芳香族ポリカルボン酸とのオリゴマーエステルである）、
ｅ）亜リン酸アルミニウム類
を包含する。
R 5 to R 7 are substituted with hydrogen, C 1 -C 8 -alkyl, C 5 -C 16 -cycloalkyl or -alkylcycloalkyl (these are hydroxyl or C1 - C 4 -hydroxyalkyl functional groups, respectively). May be), C 2 -C 8 -alkenyl, C 1 -C 8 -alkoxy, -acyl, -acyloxy, C 6 -C 12 -aryl or -arylalkyl, -OR 8 and -N (R 8 ) R 9 , N-alicyclic group, or N-aromatic group,
R 8 is hydrogen, C 1 -C 8 -alkyl, C 5 -C 16 -cycloalkyl or -alkylcycloalkyl (these may be substituted with hydroxyl or C1 - C 4 -hydroxyalkyl functional groups). , C2 - C8 - alkenyl, C1 - C8 - alkoxy, -acyl , -acyloxy , or C6-C12-aryl or -arylalkyl.
R 9 to R 13 are the same groups as R 8 , respectively, and are also -OR 8 and
m and n are independently 1, 2, 3, or 4, respectively.
X is an acid that can form an adduct with the triazine compound (III), or an oligomer ester with the aromatic polycarboxylic acid of tris (hydroxyethyl) isocyanate),
e ) Aluminum phosphates
Including.
本発明は、
メラミンの縮合生成物ａ）が、メレム、メラム、メロン、および／またはそれらのより高度に縮合した化合物であり、
メラミンの反応生成物ｂ）が、ピロリン酸ジメラミン、ポリリン酸メラミン、ポリリン酸メレム、ポリリン酸メラム、ポリリン酸メロン、および／またはこのタイプの混合多価塩（ｍｉｘｅｄ ｐｏｌｙｓａｌｔ）であり、
リン酸塩（ｃ）が、リン酸水素アンモニウム、リン酸二水素アンモニウム、および／またはポリリン酸アンモニウムであり、
Ｎ－相乗剤ｄ）が、ベンゾグアナミン、トリス（ヒドロキシエチル）イソシアヌラート、アラントイン、グリコウリル（ｇｌｙｃｏｕｒｉｌ）、メラミン、メラミンシアヌラート、ジシアンジアミド、および／またはグアニジンであり、
亜リン酸アルミニウム類ｅ）が、式（ＩＸ）、（ＩＩ）、および／もしくは（Ｘ）
Ａｌ２（ＨＰＯ３）３・（Ｈ２Ｏ）ｑ （ＩＸ）
（式中、
ｑは、０～４である）
Ａｌ２．００ＭＺ（ＨＰＯ３）ｙ（ＯＨ）ｖ・（Ｈ２Ｏ）ｗ （ＩＩ）
（式中、
Ｍは、アルカリ金属イオンであり、
ｚは、０．０１～１．５であり、
ｙは、２．６３～３．５であり、
ｖは、０～２であり、
ｗは、０～４である）
Ａｌ２．００（ＨＰＯ３）ｕ（Ｈ２ＰＯ３）ｔ・（Ｈ２Ｏ）ｓ （Ｘ）
（式中、
ｕは、２～２．９９であり、
ｔは、２～０．０１であり、
ｓは、０～４である）
で表されるもの、ならびに／または式（ＩＸ）で表される亜リン酸アルミニウムと、難溶性アルミニウム塩および窒素不含イオンとの混合物、式（Ｘ）で表される亜リン酸アルミニウムとアルミニウム塩の混合物、亜リン酸アルミニウム［Ａｌ（Ｈ２ＰＯ３）３］、第二級亜リン酸アルミニウム［Ａｌ２（ＨＰＯ３）３］、塩基性亜リン酸アルミニウム［Ａｌ（ＯＨ）（Ｈ２ＰＯ３）２・２ａｑ］、亜リン酸アルミニウム四水和物［Ａｌ２（ＨＰＯ３）３・４ａｑ］、ホスホン酸アルミニウム、Ａｌ７（ＨＰＯ３）９（ＯＨ）６（１，６－ヘキサンジアミン）１．５・１２Ｈ２Ｏ、Ａｌ２（ＨＰＯ３）３・ｘＡｌ２Ｏ３・ｎＨ２Ｏ（式中、ｘ＝２．２７～１）、Ａｌ４Ｈ６Ｐ１６Ｏ１８、ならびに／または０～９９．９ｗｔ％のＡｌ２（ＨＰＯ３）３・ｎＨ２Ｏと０．１～１００ｗｔ％の亜リン酸アルミニウムナトリウムの混合物である、請求項５に記載の難燃剤－安定剤の組合せにも関する。
The present invention
The melamine condensation product a) is a melem, melam, melon, and / or a more highly condensed compound thereof.
The reaction product of melamine b) is dimelamine pyrophosphate, melamine polyphosphate, melem polyphosphate, melam polyphosphate, melon polyphosphate, and / or a mixed polysalt of this type.
Phosphate (c) is ammonium hydrogen phosphate, ammonium dihydrogen phosphate, and / or ammonium polyphosphate.
The N-synergizer d) is benzoguanamine, tris (hydroxyethyl) isocyanate, allantoin, glycouryl, melamine, melamine cyanurate, dicyandiamide, and / or guanidine.
Aluminum phosphites e) are of formulas (IX), (II), and / or (X).
Al 2 (HPO 3 ) 3. (H 2 O) q (IX)
(During the ceremony,
q is 0 to 4)
Al 2.00 M Z (HPO 3 ) y (OH) v · (H 2 O) w (II)
(During the ceremony,
M is an alkali metal ion,
z is 0.01 to 1.5,
y is 2.63 to 3.5,
v is 0 to 2 and
w is 0 to 4)
Al 2.00 (HPO 3 ) u (H 2 PO 3 ) t · (H 2 O) s (X)
(During the ceremony,
u is 2 to 2.99,
t is 2 to 0.01,
s is 0-4)
, And / or a mixture of aluminum phosphite represented by the formula (IX) and a sparingly soluble aluminum salt and nitrogen-free ion, aluminum phosphite and aluminum represented by the formula (X). Mix of salts, aluminum phosphite [Al (H2PO 3 ) 3 ], secondary aluminum phosphite [Al 2 (HPO 3 ) 3 ], basic aluminum phosphite [Al (OH) (H 2 PO 3 ) ) 2.2aq ], aluminum phosphite tetrahydrate [Al 2 (HPO 3 ) 3.4aq ], aluminum phosphonate, Al 7 (HPO 3 ) 9 (OH) 6 (1,6-hexanediamine) 1 .5.12H 2 O, Al 2 (HPO 3 ) 3 · xAl 2 O 3 · nH 2 O (in the formula, x = 2.27-1 ), Al 4H 6 P 16 O 18 and / or 0 ~ The flame retardant-stabilizer combination according to claim 5, which is a mixture of 99.9 wt% Al 2 (HPO 3 ) 3.nH 2 O and 0.1 to 100 wt% sodium aluminum phosphite. ..
好ましくは、亜リン酸アルミニウム類は、５０～９９ｗｔ％のＡｌ２（ＨＰＯ３）３・（Ｈ２Ｏ）ｑ（式中、ｑは、０～４である）と１～５０ｗｔ％の亜リン酸アルミニウムナトリウムの混合物である。 Preferably, the aluminum phosphites are 50 to 99 wt% Al 2 (HPO 3 ) 3. (H 2 O) q (where q is 0 to 4 in the formula) and 1 to 50 wt% phosphite. It is a mixture of sodium aluminum phosphate.
より好ましくは、亜リン酸アルミニウム類は、５０～９９ｗｔ％のＡｌ２（ＨＰＯ３）３・（Ｈ２Ｏ）ｑ（式中、ｑは、０～４である）と１～５０ｗｔ％のＡｌ２．００Ｍｚ（ＨＰＯ３）ｙ（ＯＨ）ｖ・（Ｈ２Ｏ）ｗ（ＩＩ）（式中、Ｍは、ナトリウムであり、ｚは、０．００５～０．１５であり、ｙは、２．８～３．１であり、ｖは、０～０．４であり、ｗは、０～４である）の混合物である。 More preferably, the aluminum phosphites are 50 to 99 wt% Al 2 (HPO 3 ) 3. (H 2 O) q (in the formula, q is 0 to 4) and 1 to 50 wt% Al. 2.00 M z (HPO 3 ) y (OH) v · (H 2 O) w (II) (In the formula, M is sodium, z is 0.005 to 0.15, and y is. 2.8 to 3.1, v is 0 to 0.4, and w is 0 to 4).
前述の添加剤は、難燃剤－安定剤の組合せにも添加され得る。
なお、本願は、特許請求の範囲に記載の発明に関するものであるが、他の態様として以下も包含し得る。
１．成分Ａとして、２５～９９．９重量％の、式（Ｉ）で表されるホスフィン酸塩
Ｒ１、Ｒ２は、同一であるかまたは異なり、それぞれ直鎖もしくは分岐鎖のＣ１－Ｃ１８－アルキル、Ｃ６－Ｃ１８－アリール、Ｃ７－Ｃ１８－アリールアルキルもしくはＣ７－Ｃ１８－アルキルアリールであるか、またはＲ１およびＲ２は、一つもしくは複数の環を互いと一緒に形成し、
Ｍは、Ｍｇ、Ｃａ、Ａｌ、Ｓｂ、Ｓｎ、Ｇｅ、Ｔｉ、Ｚｎ、Ｆｅ、Ｚｒ、Ｃｅ、Ｂｉ、Ｓｒ、Ｍｎ、Ｌｉ、Ｎａ、Ｋおよび／またはプロトン化窒素塩基であり、
ｍは、１～４である）、
成分Ｂとして、０～７５重量％の、相乗剤またはリン系／窒素系難燃剤、ならびに
成分Ｃとして、０．１～５０重量％の、酸化マグネシウム、酸化亜鉛、酸化マンガン、酸化スズ、ジハイドロタルサイト、ハイドロカルマイト、水酸化マグネシウム、水酸化カルシウム、水酸化亜鉛、酸化スズ水和物、水酸化マンガン、ホウ酸亜鉛、塩基性ケイ酸亜鉛、スズ酸亜鉛またはこれらの物質の混合物
を含む、熱可塑性ポリマー用の難燃剤－安定剤の組合せであって、成分の合計は常に１００重量％であり、
前記難燃剤－安定剤の組合せの安息角が、５°～４５°の間である、難燃剤－安定剤の組合せ。
２．前記難燃剤－安定剤の組合せの安息角が、２０°～４０°の間である、上記１に記載の難燃剤－安定剤の組合せ。
３．Ｒ１、Ｒ２が、同一であるかまたは異なり、それぞれメチル、エチル、ｎ－プロピル、イソプロピル、ｎ－ブチル、ｔｅｒｔ－ブチル、ｎ－ペンチル、２－ペンチル、３－ペンチル、２－メチルブチル、３－メチルブチル（イソペンチル）、３－メチルブタ－２－イル、２－メチルブタ－２－イル、２，２－ジメチルプロピル（ネオペンチル）、ヘキシル、ヘプチル、オクチル、ノニル、デシル、シクロペンチル、シクロペンチルエチル、シクロヘキシル、シクロヘキシルエチル、フェニル、フェニルエチル、メチルフェニルおよび／またはメチルフェニルエチルである、上記１または２に記載の難燃剤－安定剤の組合せ。
４．Ｍが、カルシウム、アルミニウム、亜鉛、チタンまたは鉄イオンである、上記１～３のいずれか一つに記載の難燃剤－安定剤の組合せ。
５．成分Ｂが、ａ）～ｅ）
ａ）メラミンの縮合生成物、
ｂ）メラミンとポリリン酸の反応生成物および／またはメラミンの縮合生成物とポリリン酸の反応生成物あるいはそれらの混合物、
ｃ）式（ＮＨ４）ｙＨ３－ｙＰＯ４または式（ＮＨ４ＰＯ３）ｚのリン酸塩（式中、ｙは１～３であり、ｚは１～１００００である）、
ｄ）式（ＩＩＩ）～式（ＶＩＩＩ）で表されるＮ－相乗剤またはそれらの混合物
Ｒ５～Ｒ７は、それぞれ水素、Ｃ１－Ｃ８－アルキル、Ｃ５－Ｃ１６－シクロアルキルもしくは－アルキルシクロアルキル（これらはヒドロキシルまたはＣ１－Ｃ４－ヒドロキシアルキル官能基で置換されていてもよい）、Ｃ２－Ｃ８－アルケニル、Ｃ１－Ｃ８－アルコキシ、－アシル、－アシルオキシ、Ｃ６－Ｃ１２－アリールもしくは－アリールアルキル、－ＯＲ８および－Ｎ（Ｒ８）Ｒ９、Ｎ－脂環式基またはＮ－芳香族基であり、
Ｒ８は、水素、Ｃ１－Ｃ８－アルキル、Ｃ５－Ｃ１６－シクロアルキルもしくは－アルキルシクロアルキル（これらはヒドロキシルまたはＣ１－Ｃ４－ヒドロキシアルキル官能基で置換されていてもよい）、Ｃ２－Ｃ８－アルケニル、Ｃ１－Ｃ８－アルコキシ、－アシル、－アシルオキシまたはＣ６－Ｃ１２－アリールもしくは－アリールアルキルであり、
Ｒ９～Ｒ１３は、それぞれＲ８と同一の基であり、およびまた－Ｏ－Ｒ８であり、
ｍおよびｎは、それぞれ独立に１、２、３または４であり、
Ｘは、トリアジン化合物（ＩＩＩ）と一緒に付加体を形成し得る酸、またはトリス（ヒドロキシエチル）イソシアヌラートの芳香族ポリカルボン酸とのオリゴマーエステルである）、
ｅ）亜リン酸アルミニウム類
の群の一つまたは複数を含む、上記１～４のいずれか一つに記載の難燃剤－安定剤の組合せ。
６．メラミンの縮合生成物ａ）が、メレム、メラム、メロンおよび／またはそれらのより高度に縮合した化合物であり、
メラミンの反応生成物ｂ）が、ピロリン酸ジメラミン、ポリリン酸メラミン、ポリリン酸メレム、ポリリン酸メラム、ポリリン酸メロンおよび／またはこのタイプの混合多価塩（ｍｉｘｅｄ ｐｏｌｙｓａｌｔ）であり、
リン酸塩（ｃ）が、リン酸水素アンモニウム、リン酸二水素アンモニウムおよび／またはポリリン酸アンモニウムであり、
Ｎ－相乗剤ｄ）が、ベンゾグアナミン、トリス（ヒドロキシエチル）イソシアヌラート、アラントイン、グリコウリル、メラミン、メラミンシアヌラート、ジシアンジアミドおよび／またはグアニジンであり、
亜リン酸アルミニウム類ｅ）が、式（ＩＸ）、（ＩＩ）および／もしくは（Ｘ）
Ａｌ２（ＨＰＯ３）３ ｘ（Ｈ２Ｏ）ｑ （ＩＸ）
（式中、
ｑは、０～４である）
Ａｌ２．００ＭＺ（ＨＰＯ３）ｙ（ＯＨ）ｖｘ（Ｈ２Ｏ）ｗ （ＩＩ）
（式中、
Ｍは、アルカリ金属イオンであり、
ｚは、０．０１～１．５であり、
ｙは、２．６３～３．５であり、
ｖは、０～２であり、
ｗは、０～４である）
Ａｌ２．００（ＨＰＯ３）ｕ（Ｈ２ＰＯ３）ｔｘ（Ｈ２Ｏ）ｓ （Ｘ）
（式中、
ｕは、２～２．９９であり、
ｔは、２～０．０１であり、
ｓは、０～４である）
で表されるものならびに／または式（ＩＸ）で表される亜リン酸アルミニウムと、難溶性アルミニウム塩および窒素不含イオンとの混合物、式（Ｘ）で表される亜リン酸アルミニウムとアルミニウム塩の混合物、亜リン酸アルミニウム［Ａｌ（Ｈ２ＰＯ３）３］、第二亜リン酸アルミニウム［Ａｌ２（ＨＰＯ３）３］、塩基性亜リン酸アルミニウム［Ａｌ（ＯＨ）（Ｈ２ＰＯ３）２＊２ａｑ］、亜リン酸アルミニウム四水和物［Ａｌ２（ＨＰＯ３）３＊４ａｑ］、ホスホン酸アルミニウム、Ａｌ７（ＨＰＯ３）９（ＯＨ）６（１，６－ヘキサンジアミン）１．５＊１２Ｈ２Ｏ、Ａｌ２（ＨＰＯ３）３＊ｘＡｌ２Ｏ３＊ｎＨ２Ｏ（式中、ｘ＝２．２７～１）、Ａｌ４Ｈ６Ｐ１６Ｏ１８ならびに／または０～９９．９ｗｔ％のＡｌ２（ＨＰＯ３）３＊ｎＨ２Ｏと０．１～１００ｗｔ％の亜リン酸アルミニウムナトリウムの混合物である、上記５に記載の難燃剤－安定剤の組合せ。
７．亜リン酸アルミニウム類が、５０～９９ｗｔ％のＡｌ２（ＨＰＯ３）３ｘ（Ｈ２Ｏ）ｑ（式中、ｑは、０～４である）と１～５０ｗｔ％の亜リン酸アルミニウムナトリウムの混合物である、上記１～６のいずれか一つに記載の難燃剤－安定剤の組合せ。
８．亜リン酸アルミニウム類が、５０～９９ｗｔ％のＡｌ２（ＨＰＯ３）３ｘ（Ｈ２Ｏ）ｑ（式中、ｑは、０～４である）と１～５０ｗｔ％のＡｌ２．００Ｍｚ（ＨＰＯ３）ｙ（ＯＨ）ｖｘ（Ｈ２Ｏ）ｗ（ＩＩ）（式中、Ｍは、ナトリウムであり、ｚは、０．００５～０．１５であり、ｙは、２．８～３．１であり、ｖは、０～０．４であり、ｗは、０～４である）の混合物である、上記１～６のいずれか一つに記載の難燃剤－安定剤の組合せ。
９．成分Ｂが、ポリリン酸メラミンである、上記１～６のいずれか一つに記載の難燃剤－安定剤の組合せ。
１０．成分Ｃが、塩基性もしくは両性の酸化物、金属酸化物、酸化マグネシウム、酸化亜鉛、酸化マンガン、酸化スズ、金属水酸化物、水酸化マグネシウム、ハイドロタルサイト、ハイドロカルマイト、ジハイドロタルサイト、水酸化カルシウム、水酸化亜鉛、酸化スズ水和物、水酸化マンガン、ケイ酸塩、ゼオライト、ケイ酸、ガラス粉末、ガラス－セラミック粉末もしくはセラミック粉末、炭酸マグネシウム 炭酸カルシウムマグネシウム（ドロマイト）；スズ酸亜鉛、ヒドロキシスズ酸亜鉛、リン酸亜鉛、硫化亜鉛、酸化アルミニウム、水酸化アルミニウム、ベーマイト、水酸化硫酸アルミニウム、リン酸アルミニウム、酸化カルシウム、酸化マンガン、酸化スズ、酸化スズ水和物、水酸化マンガン、塩基性ケイ酸亜鉛である、上記１～９のいずれか一つに記載の難燃剤－安定剤の組合せ。
１１．５０～９９重量％の成分Ａ、０～５０重量％の成分Ｂおよび１～２０重量％の成分Ｃが存在する、上記１～１０のいずれか一つに記載の難燃剤－安定剤の組合せ。
１２．５０～７８重量％の成分Ａ、２０～５０重量％の成分Ｂおよび２～２０重量％の成分Ｃが存在する、上記１～１１のいずれか一つに記載の難燃剤－安定剤の組合せ。
１３．６０～９８重量％の成分Ａおよび２～４０重量％の成分Ｃが存在する、上記１～１２のいずれか一つに記載の難燃剤－安定剤の組合せ。
１４．前記難燃剤－安定剤の組合せの残留水分含有量が、０．０１ｗｔ％～１０ｗｔ％の間であることを特徴とする、上記１～１３のいずれか一つに記載の難燃剤－安定剤の組合せ。
１５．前記難燃剤－安定剤の組合せの残留水分含有量が、０．１ｗｔ％～１ｗｔ％の間であることを特徴とする、上記１～１４のいずれか一つに記載の難燃剤－安定剤の組合せ。１６．前記難燃剤－安定剤の組合せの粒子径が、１μｍ～１００μｍの間であることを特徴とする、上記１～１５のいずれか一つに記載の難燃剤－安定剤の組合せ。
１７．前記難燃剤－安定剤の組合せのかさ密度が、１００ｇ／Ｌ～１０００ｇ／Ｌの間であることを特徴とする、上記１～１６のいずれか一つに記載の難燃剤－安定剤の組合せ。１８．前記難燃剤－安定剤の組合せのタップ密度が、２００ｇ／Ｌ～１２００ｇ／Ｌの間であることを特徴とする、上記１～１７のいずれか一つに記載の難燃剤－安定剤の組合せ。
１９．難燃剤としての、または、熱可塑性ポリマー用、熱硬化性ポリマー用、クリアコート用、発泡性防炎塗料用、木材および他のセルロース製品用、ポリマー成形体、フィルム、スレッドもしくは繊維用の難燃剤を製造するための、難燃性ポリマー成形用組成物を製造するための、難燃性ポリマー成形体を製造するための、ならびに／または純粋および混紡のポリエステルおよびセルロースの織物を含浸によって難燃性にするための中間体としての、上記１～１８のいずれか一つに記載の難燃剤－安定剤の組合せの使用。
２０．熱可塑性ポリマーが、ポリエステル、ポリスチレンおよび／またはポリアミドであり、熱硬化性ポリマーが、不飽和ポリエステル樹脂、エポキシ樹脂、ポリウレタンおよび／またはアクリラートである、上記１９に記載の使用。
２１．上記１～１８のいずれか一つに記載の難燃剤－安定剤の組合せを含む、難燃性プラスチック成形用組成物、ポリマー成形体、フィルム、スレッドまたは繊維。
２２．使用されるプラスチックが、耐衝撃性ポリスチレン、ポリフェニレンエーテル、ポリアミド、ポリエステル、ポリカーボナート、熱可塑性ポリウレタンのタイプ、およびＡＢＳ（アクリロニトリル－ブタジエン－スチレン）もしくはＰＣ／ＡＢＳ（ポリカーボナート／アクリロニトリル－ブタジエン－スチレン）もしくはＰＰＥ／ＨＩＰＳ（ポリフェニレンエーテル／ＨＩポリスチレン）プラスチックのタイプのブレンドまたはポリマーブレンドに属する熱可塑性ポリマーである、上記２１に記載の難燃性プラスチック成形用組成物、ポリマー成形体、フィルム、スレッドまたは繊維。
２３．プラスチック成形用組成物を基準として２～５０重量％の量で難燃剤－安定剤の組合せを含む、上記２１または２２に記載の難燃性プラスチック成形用組成物、ポリマー成形体、フィルム、スレッドまたは繊維。
２４．プラスチック成形用組成物を基準として１０～３０重量％の量で難燃剤－安定剤の組合せを含む、上記２１～２３のいずれか一つに記載の難燃性プラスチック成形用組成物、ポリマー成形体、フィルム、スレッドまたは繊維。
２５．コネクタ、電流分配装置における電流接触部品（ＲＣＣＢ）、基板、ポッティング材、電源コネクタ、回路遮断器、ランプハウジング、ＬＥＤハウジング、コンデンサハウジング、ボビンおよびファン、回路基板内／上の保護接点、コネクタ、コネクタ用筐体、ケーブル、可撓性回路基板、携帯電話用充電器、エンジンカバー、テキスタイルコーティング、電気／電子工学分野用の構成要素、特に印刷回路基板、ハウジング、フィルム、ケーブル、スイッチ、配電盤、リレー、抵抗、キャパシタ、コイル、ランプ、ダイオード、ＬＥＤ、トランジスタ、コネクタ、コントローラ、メモリおよびセンサ部品用の構成要素の形態、面積の大きな構成要素、特にキャビネット用ハウジング部品の形態、ならびに精密な構造を有する精巧に設計される構成要素の形態の成形体において、あるいはこれらのために使用するための、上記２１～２４のいずれか一つに記載の難燃性プラスチック成形用組成物、ポリマー成形体、フィルム、スレッドまたは繊維。
The aforementioned additives can also be added to flame retardant-stabilizer combinations.
Although the present application relates to the invention described in the claims, the following may be included as other aspects.
1. 1. 25-99.9% by weight of the phosphinate represented by the formula (I) as the component A
R 1 and R 2 are the same or different and are linear or branched C 1 -C 18 -alkyl, C 6 -C 18 -aryl, C 7 -C 18 -aryl alkyl or C 7 -C, respectively. 18 -Alkylaryl, or R1 and R2 form one or more rings together with each other.
M is Mg, Ca, Al, Sb, Sn, Ge, Ti, Zn, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na, K and / or a protonated nitrogen base.
m is 1 to 4),
As component B, 0 to 75% by weight, synergistic or phosphorus / nitrogen flame retardant, and as component C, 0.1 to 50% by weight, magnesium oxide, zinc oxide, manganese oxide, tin oxide, dihydro. Contains talcite, hydrocarbamite, magnesium hydroxide, calcium hydroxide, zinc hydroxide, tin oxide hydrate, manganese hydroxide, zinc borate, basic zinc silicate, zinc tinate or mixtures of these substances. , Flame retardant-stabilizer combination for thermoplastic polymers, the total of the components is always 100% by weight,
A flame retardant-stabilizer combination in which the angle of repose of the flame retardant-stabilizer combination is between 5 ° and 45 °.
2. 2. The flame retardant-stabilizer combination according to 1 above, wherein the angle of repose of the flame retardant-stabilizer combination is between 20 ° and 40 °.
3. 3. R 1 and R 2 are the same or different, methyl, ethyl, n-propyl, isopropyl, n-butyl, tert-butyl, n-pentyl, 2-pentyl, 3-pentyl, 2-methylbutyl, 3 respectively. -Methylbutyl (isopentyl), 3-methylbut-2-yl, 2-methylbut-2-yl, 2,2-dimethylpropyl (neopentyl), hexyl, heptyl, octyl, nonyl, decyl, cyclopentyl, cyclopentylethyl, cyclohexyl, cyclohexyl The flame retardant-stabilizer combination according to 1 or 2 above, which is ethyl, phenyl, phenylethyl, methylphenyl and / or methylphenylethyl.
4. The flame retardant-stabilizer combination according to any one of 1 to 3 above, wherein M is calcium, aluminum, zinc, titanium or iron ion.
5. Ingredients B are a) to e)
a) Melamine condensation product,
b) Melamine-polyphosphate reaction products and / or melamine condensation products and polyphosphate reaction products or mixtures thereof,
c) Phosphate of formula (NH 4 ) y H 3-y PO 4 or formula (NH 4 PO 3 ) z (in the formula, y is 1-3 and z is 1-10000),
d) N-synergists represented by formulas (III) to (VIII) or mixtures thereof.
R 5 to R 7 are substituted with hydrogen, C 1 -C 8 -alkyl, C 5 -C 16 -cycloalkyl or -alkylcycloalkyl (these are hydroxyl or C1 - C 4 -hydroxyalkyl functional groups, respectively). May be), C 2 -C 8 -alkenyl, C 1 -C 8 -alkoxy, -acyl, -acyloxy, C 6 -C 12 -aryl or -arylalkyl, -OR 8 and -N (R 8 ) R 9 , N-alicyclic group or N-aromatic group,
R 8 is hydrogen, C 1 -C 8 -alkyl, C 5 -C 16 -cycloalkyl or -alkylcycloalkyl (these may be substituted with hydroxyl or C1 - C 4 -hydroxyalkyl functional groups). , C 2 -C 8 -alkenyl, C 1 -C 8 -alkoxy, -acyl, -acyloxy or C 6 -C 12 -aryl or -arylalkyl.
R 9 to R 13 are the same groups as R 8 and are also -OR 8 respectively.
m and n are independently 1, 2, 3 or 4, respectively.
X is an acid that can form an adduct with the triazine compound (III), or an oligomer ester with the aromatic polycarboxylic acid of tris (hydroxyethyl) isocyanate),
e ) Aluminum phosphates
The flame retardant-stabilizer combination according to any one of 1 to 4 above, which comprises one or more of the groups of.
6. The melamine condensation product a) is a melem, melam, melon and / or a more highly condensed compound thereof.
The reaction product of melamine b) is dimelamine pyrophosphate, melamine polyphosphate, melem polyphosphate, melam polyphosphate, melon polyphosphate and / or a mixed polysalt of this type.
Phosphate (c) is ammonium hydrogen phosphate, ammonium dihydrogen phosphate and / or ammonium polyphosphate.
The N-synergizer d) is benzoguanamine, tris (hydroxyethyl) isocyanurate, allantoin, glycouryl, melamine, melamine cyanurate, dicyandiamide and / or guanidine.
Aluminum phosphites e) are of formulas (IX), (II) and / or (X).
Al 2 (HPO 3 ) 3 x (H 2 O) q (IX)
(During the ceremony,
q is 0 to 4)
Al 2.00 M Z (HPO 3 ) y (OH) v x (H 2 O) w (II)
(During the ceremony,
M is an alkali metal ion,
z is 0.01 to 1.5,
y is 2.63 to 3.5,
v is 0 to 2 and
w is 0 to 4)
Al 2.00 (HPO 3 ) u (H 2 PO 3 ) t x (H 2 O) s (X)
(During the ceremony,
u is 2 to 2.99,
t is 2 to 0.01,
s is 0-4)
A mixture of aluminum phosphite represented by and / or aluminum phosphite represented by the formula (IX), a sparingly soluble aluminum salt and a nitrogen-free ion, aluminum phosphite and an aluminum salt represented by the formula (X). , Aluminum phosphite [Al (H2PO 3 ) 3 ], Aluminum dibasic aluminum [Al 2 (HPO 3 ) 3 ], Basic aluminum phosphite [Al (OH) (H 2 PO 3 ) 2 * 2aq], aluminum phosphite tetrahydrate [Al 2 (HPO 3 ) 3 * 4aq], aluminum phosphonate, Al 7 (HPO 3 ) 9 (OH) 6 (1,6-hexanediamine) 1.5 * 12 H 2 O, Al 2 (HPO 3 ) 3 * xAl 2 O 3 * nH 2 O (in the formula, x = 2.27 to 1), Al 4 H 6 P 16 O 18 and / or 0 to 99.9 wt The flame retardant-stabilizer combination according to 5 above, which is a mixture of% Al 2 (HPO 3 ) 3 * nH 2 O and 0.1 to 100 wt% aluminum aluminum phosphite.
7. Aluminum phosphite contains 50-99 wt% Al 2 (HPO 3 ) 3 x (H 2 O) q (where q is 0-4 in the formula) and 1-50 wt% sodium aluminum phosphite. The flame retardant-stabilizer combination according to any one of 1 to 6 above, which is a mixture of the above.
8. Aluminum phosphite contains 50-99 wt% Al 2 (HPO 3 ) 3 x (H 2 O) q (in the formula, q is 0-4) and 1-50 wt% Al 2.00 M. z (HPO 3 ) y (OH) v x (H 2 O) w (II) (In the formula, M is sodium, z is 0.005 to 0.15, and y is 2.8. The flame retardant-stabilizer according to any one of 1 to 6 above, which is a mixture of (1 to 3.1, v is 0 to 0.4, and w is 0 to 4). combination.
9. The flame retardant-stabilizer combination according to any one of 1 to 6 above, wherein the component B is melamine polyphosphate.
10. Component C is a basic or amphoteric oxide, metal oxide, magnesium oxide, zinc oxide, manganese oxide, tin oxide, metal hydroxide, magnesium hydroxide, hydrotalcite, hydrocarbimite, dihydrotalcite, Calcium hydroxide, zinc hydroxide, tin oxide hydrate, manganese hydroxide, silicate, zeolite, silicic acid, glass powder, glass-ceramic powder or ceramic powder, magnesium carbonate Calcium carbonate magnesium (dromite); zinc tinate , Zinc hydroxytinate, zinc phosphate, zinc sulfide, aluminum oxide, aluminum hydroxide, boehmite, aluminum hydroxide sulfate, aluminum phosphate, calcium oxide, manganese oxide, tin oxide, tin oxide hydrate, manganese hydroxide, The flame retardant-stabilizer combination according to any one of 1 to 9 above, which is a basic zinc silicate.
11. The flame retardant-stabilizer according to any one of 1 to 10 above, wherein 50 to 99% by weight of component A, 0 to 50% by weight of component B and 1 to 20% by weight of component C are present. combination.
12. The flame retardant-stabilizer according to any one of 1 to 11 above, wherein 50 to 78% by weight of component A, 20 to 50% by weight of component B and 2 to 20% by weight of component C are present. combination.
13. The flame retardant-stabilizer combination according to any one of 1 to 12 above, wherein a component A of 60 to 98% by weight and a component C of 2 to 40% by weight are present.
14. The flame retardant-stabilizer according to any one of 1 to 13, wherein the residual water content of the flame retardant-stabilizer combination is between 0.01 wt% and 10 wt%. combination.
15. The flame retardant-stabilizer according to any one of 1 to 14, wherein the residual water content of the flame retardant-stabilizer combination is between 0.1 wt% and 1 wt%. combination. 16. The flame retardant-stabilizer combination according to any one of 1 to 15, wherein the particle size of the flame retardant-stabilizer combination is between 1 μm and 100 μm.
17. The flame retardant-stabilizer combination according to any one of 1 to 16, wherein the bulk density of the flame retardant-stabilizer combination is between 100 g / L and 1000 g / L. 18. The flame retardant-stabilizer combination according to any one of 1 to 17, wherein the tap density of the flame retardant-stabilizer combination is between 200 g / L and 1200 g / L.
19. Flame Retardants for Flame Retardants or For Thermoplastic Polymers, Thermocurable Polymers, Clear Coats, Foamable Flame Retardant Paints, Wood and Other Cellulose Products, Polymer Molds, Films, Threads or Textiles Flame Retardant for Producing Flame Retardant Polymer Molding Compositions, For Producing Flame Retardant Polymer Molds, and / or By Impregnating Pure and Blended Polyester and Cellulose Fabrics Use of the flame retardant-stabilizer combination according to any one of 1 to 18 above as an intermediate for the use of the flame retardant-stabilizer.
20. 19. The use according to 19 above, wherein the thermoplastic polymer is polyester, polystyrene and / or polyamide and the thermosetting polymer is an unsaturated polyester resin, epoxy resin, polyurethane and / or acrylate.
21. A flame retardant plastic molding composition, a polymer molded article, a film, a thread or a fiber, which comprises the flame retardant-stabilizer combination according to any one of 1 to 18 above.
22. The plastics used are impact resistant polystyrene, polyphenylene ether, polyamide, polyester, polycarbonate, thermoplastic polyurethane type, and ABS (acrylonitrile-butadiene-styrene) or PC / ABS (polycarbonate / acrylonitrile-butadiene-styrene). Alternatively, the flame-retardant plastic molding composition, polymer molded body, film, thread or fiber according to 21 above, which is a thermoplastic polymer belonging to a PPE / HIPS (polyphenylene ether / HI polystyrene) plastic type blend or polymer blend. ..
23. 21 or 22 above, wherein the flame retardant plastic molding composition, polymer molded product, film, thread or fiber.
24. The flame-retardant plastic molding composition or polymer molded product according to any one of 21 to 23 above, which comprises a flame retardant-stabilizer combination in an amount of 10 to 30% by weight based on the plastic molding composition. , Film, thread or fiber.
25. Connector, current contact component (RCCB) in current distributor, board, potting material, power connector, circuit breaker, lamp housing, LED housing, capacitor housing, bobbin and fan, protective contacts in / on circuit board, connector, connector Housings, cables, flexible circuit boards, chargers for mobile phones, engine covers, textile coatings, components for the electrical / electronic engineering field, especially printed circuit boards, housings, films, cables, switches, switchboards, relays. Has components for resistors, capacitors, coils, lamps, diodes, LEDs, transistors, connectors, controllers, memory and sensor components, large area components, especially housing components for cabinets, and precise structures. The flame-retardant plastic molding composition, polymer molded body, film according to any one of 21 to 24 above, for use in or for a molded body in the form of an elaborately designed component. , Thread or fiber.
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| PCT/EP2017/072278 WO2018050497A1 (en) | 2016-09-15 | 2017-09-06 | Flame retardant-stabilizer combination for thermoplastic polymers |
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| DE10309385B4 (en) | 2003-03-03 | 2007-01-18 | Clariant Produkte (Deutschland) Gmbh | Flame retardant stabilizer combination for thermoplastic polymers and their use as well as flameproof plastic molding compounds |
| DE10331888B4 (en) | 2003-07-14 | 2005-11-10 | Clariant Gmbh | Elastic covering material with improved flame retardancy and a method for its production |
| FR2864097B1 (en) * | 2003-12-19 | 2006-03-10 | Rhodia Enginnering Plastics | FLAME RETARDANT COMPOSITION BASED ON THERMOPLASTIC MATRIX |
| DE10359814A1 (en) * | 2003-12-19 | 2005-07-28 | Clariant Gmbh | Dialkylphosphinic salts |
| DE102004023085A1 (en) * | 2004-05-11 | 2005-12-15 | Clariant Gmbh | Dialkylphosphinic acid salts, a process for their preparation and their use |
| DE102004048876A1 (en) * | 2004-09-13 | 2006-03-30 | Bayer Ag | Halogen-free flame-retardant thermoplastic molding compounds based on polyamide with increased glow wire resistance |
| US8716378B2 (en) * | 2010-06-29 | 2014-05-06 | Sabic Innovative Plastics Ip B.V. | Flame resistant polyester compositions, method of manufacture, and articles thereof |
| DE102010026973A1 (en) * | 2010-07-13 | 2012-01-19 | Clariant International Ltd. | Flame retardant stabilizer combination for thermoplastic polymers |
| DE102011120200A1 (en) * | 2011-12-05 | 2013-06-06 | Clariant International Ltd. | Flame retardant mixtures containing flame retardants and aluminum phosphites, process for their preparation and their use |
| US20140066551A1 (en) | 2012-08-30 | 2014-03-06 | Sabic Innovative Plastics Ip B.V. | Glass-filled polyamide composition and article |
| CN104059101B (en) | 2013-02-27 | 2015-09-09 | 广州金凯新材料有限公司 | A kind of dialkylphosphinic salts with good free-running property |
| DE102014001222A1 (en) | 2014-01-29 | 2015-07-30 | Clariant lnternational Ltd | Halogen-free solid flame retardant mixture and its use |
| EP3034553A1 (en) | 2014-12-19 | 2016-06-22 | LANXESS Deutschland GmbH | Polyamide compositions |
-
2016
- 2016-10-17 CN CN201611204272.9A patent/CN107828084A/en active Pending
-
2017
- 2017-08-01 TW TW106125926A patent/TW201827503A/en unknown
- 2017-09-06 WO PCT/EP2017/072278 patent/WO2018050497A1/en unknown
- 2017-09-06 RU RU2019107404A patent/RU2019107404A/en not_active Application Discontinuation
- 2017-09-06 JP JP2019513916A patent/JP7062001B2/en active Active
- 2017-09-06 SG SG11201901476RA patent/SG11201901476RA/en unknown
- 2017-09-06 EP EP17772318.6A patent/EP3580271A1/en active Pending
- 2017-09-06 KR KR1020197010483A patent/KR102475946B1/en active IP Right Grant
- 2017-09-06 US US16/333,227 patent/US20190225773A1/en not_active Abandoned
- 2017-09-06 MX MX2019002655A patent/MX2019002655A/en unknown
- 2017-09-06 BR BR112019003509-5A patent/BR112019003509A2/en not_active Application Discontinuation
- 2017-09-06 MY MYPI2019000589A patent/MY194031A/en unknown
-
2018
- 2018-06-07 HK HK18107437.6A patent/HK1247948A1/en unknown
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