JPWO2015114915A1 - Oil composition - Google Patents

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JPWO2015114915A1
JPWO2015114915A1 JP2015513934A JP2015513934A JPWO2015114915A1 JP WO2015114915 A1 JPWO2015114915 A1 JP WO2015114915A1 JP 2015513934 A JP2015513934 A JP 2015513934A JP 2015513934 A JP2015513934 A JP 2015513934A JP WO2015114915 A1 JPWO2015114915 A1 JP WO2015114915A1
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oil
rapeseed
fat
fat composition
molting
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JP5992611B2 (en
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慎也 武波
慎也 武波
貴士 佐野
貴士 佐野
眞善 境野
眞善 境野
竜二 堀
竜二 堀
今義 潤
潤 今義
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J Oil Mills Inc
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    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23DEDIBLE OILS OR FATS, e.g. MARGARINES, SHORTENINGS, COOKING OILS
    • A23D9/00Other edible oils or fats, e.g. shortenings, cooking oils
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L5/00Preparation or treatment of foods or foodstuffs, in general; Food or foodstuffs obtained thereby; Materials therefor
    • A23L5/10General methods of cooking foods, e.g. by roasting or frying
    • A23L5/11General methods of cooking foods, e.g. by roasting or frying using oil
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11BPRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
    • C11B1/00Production of fats or fatty oils from raw materials
    • C11B1/06Production of fats or fatty oils from raw materials by pressing
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11BPRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
    • C11B3/00Refining fats or fatty oils
    • C11B3/02Refining fats or fatty oils by chemical reaction
    • C11B3/06Refining fats or fatty oils by chemical reaction with bases
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11BPRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
    • C11B3/00Refining fats or fatty oils
    • C11B3/10Refining fats or fatty oils by adsorption
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11BPRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
    • C11B3/00Refining fats or fatty oils
    • C11B3/12Refining fats or fatty oils by distillation

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Wood Science & Technology (AREA)
  • Microbiology (AREA)
  • Polymers & Plastics (AREA)
  • Food Science & Technology (AREA)
  • Nutrition Science (AREA)
  • Health & Medical Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Edible Oils And Fats (AREA)
  • Preparation Of Fruits And Vegetables (AREA)
  • Fats And Perfumes (AREA)

Abstract

【課題】本発明の目的は、食材を油脂組成物で加熱調理して得られる食品の油臭さを低減可能な油脂組成物、及びその油脂組成物で加熱調理された油臭さの低減された食品を提供することにある。【解決手段】本発明の油脂組成物は、脱皮率50%以上の菜種を搾油及び精製して得られる菜種油を15〜85重量%含む。本発明の油脂組成物は、さらに、大豆油、コーン油、及びパーム系油脂からなる群から選ばれる少なくとも一種の油脂を含むことが好ましい。【選択図】なしAn object of the present invention is to reduce an oily odor of a food obtained by cooking a food with an oily fat composition and to reduce the oily odor of the food obtained by cooking with the oily fat composition. Is to provide food. The oil and fat composition of the present invention contains 15 to 85% by weight of rapeseed oil obtained by squeezing and refining rapeseed having a molting rate of 50% or more. The oil / fat composition of the present invention preferably further contains at least one oil / fat selected from the group consisting of soybean oil, corn oil, and palm oil / fat. [Selection figure] None

Description

本発明は、油脂組成物に関し、より詳細には、食材を油脂組成物で加熱調理して得られる食品の油臭さを低減可能な前記油脂組成物に関する。   The present invention relates to an oil / fat composition, and more specifically to the oil / fat composition capable of reducing the oily odor of foods obtained by cooking food with an oil / fat composition.

菜種油、大豆油、コーン油、パーム油等の食用油を用いて食材を加熱調理すると、食用油に由来する独特の風味が食品の嗜好性を向上させる。一方で、食品の「油臭さ」は、不快臭となって食品の価値を低減する。そこで、食用油を用いて食材を加熱調理された食品の油臭さを低減したいという要望がある。   When cooking ingredients are cooked using edible oils such as rapeseed oil, soybean oil, corn oil, and palm oil, the unique flavor derived from the edible oil improves the palatability of the food. On the other hand, the “oily odor” of food becomes an unpleasant odor and reduces the value of the food. Therefore, there is a desire to reduce the oily odor of foods that have been cooked using edible oil.

従来、油脂やそれを用いた食品の油臭さを低減するために、油脂中に香料やフレーバーオイルを添加することが行なわれてきた。例えば、ドコサヘキサエン酸、エイコサペンタエン酸等のω3系多価不飽和脂肪酸を含有する油脂の前記酸に基づく油臭さを緩和するために、油脂にローレルの油溶性抽出物(特許文献1)やペパーミントオイル(特許文献2)のような香料を添加することが提案されている。食品では、魚肉練加工物を原料とする野菜入り揚げ物食品の油臭さを低減するために茶抽出物の濃縮物(特許文献3)を添加すること、油揚げ即席麺の油臭さをマスキングするために酒粕(特許文献4)を添加すること等が提案されている。   Conventionally, in order to reduce the oily odor of fats and oils and foods using the same, flavoring and flavor oils have been added to the fats and oils. For example, in order to alleviate the oily odor based on the acid of fats and oils containing ω3 polyunsaturated fatty acids such as docosahexaenoic acid and eicosapentaenoic acid, oil-soluble extracts of Laurel (Patent Document 1) and peppermint It has been proposed to add a fragrance such as oil (Patent Document 2). In foods, adding a concentrate of tea extract (Patent Document 3) to reduce the oily odor of fried vegetable foods made from processed fish meat, masking the oily odor of fried instant noodles Therefore, it has been proposed to add sake lees (Patent Document 4).

しかし、香料やフレーバーオイルのような助剤の添加は、食品の風味を変更する恐れがある。上記添加剤を使用しないでも、加熱調理食品の油臭さを低減する方法が望ましい。   However, the addition of auxiliaries such as fragrances and flavor oils may change the flavor of the food. A method for reducing the oily odor of cooked foods is desirable without using the above additives.

特開平08−242767JP 08-242767 A 特開平06−133707JP 06-133707 特開2008−212003JP2008-212003 特開2007−244217JP2007-244217

本発明の目的は、食材を油脂組成物で加熱調理して得られる食品の油臭さを低減可能な油脂組成物、及びその油脂組成物で加熱調理された油臭さの低減された食品を提供することにある。   An object of the present invention is to provide an oil / fat composition capable of reducing the oily odor of food obtained by cooking food with an oil / fat composition, and a food with reduced oily odor cooked with the oil / fat composition. It is to provide.

本発明者は、上記課題を鋭意検討した結果、以下の発明によれば課題を解決できることを見出し、本発明を完成させた。すなわち、本発明は、脱皮率50%以上の菜種を搾油及び精製して得られる菜種油を15〜80重量%含む、油脂組成物を提供する。本明細書において、「油臭さ」とは、加熱調理食品の油の臭いの強さを意味する。   As a result of intensive studies on the above problems, the present inventors have found that the problems can be solved according to the following inventions, and have completed the present invention. That is, this invention provides the oil-fat composition containing 15-80 weight% of rapeseed oil obtained by extracting and refine | purifying rapeseed with a molting rate of 50% or more. In the present specification, “oil odor” means the strength of oily odor of cooked food.

脱皮菜種に関連する技術として、特開2012−116877(植物油および植物粕の製造方法)は、菜種種子を菜種皮と脱皮菜種種子とに分離した後の該菜種皮を圧搾・抽出処理にかけて得られる脱脂菜種皮を、前記脱皮菜種種子と配合し、この混合物を圧搾・抽出にかけて得られる植物油を開示する。この発明は、菜種皮に含まれる食用油に適さない成分を除去した脱脂菜種皮を使用することで、圧搾・抽出油に溶け込む食用油に適さない成分の含有量が削減すること、その結果として、精製工程の簡素化とコストの削減を可能とする。前記特許文献の発明は、脱皮菜種を用いて植物油を得ているものの、特定の脱皮率を有する脱皮菜種の精製油を特定範囲の割合で他の食用油と配合することを特徴とする本発明の油脂組成物と相違する。そして、本発明の油脂組成物で食材を加熱調理して得られる食品の油臭さが低減することは、前記特許文献に記載の発明から全く予測できない。   As a technique related to molting rapeseed, Japanese Patent Application Laid-Open No. 2012-116877 (a method for producing vegetable oil and plant meal) is obtained by subjecting rapeseed seeds to rapeseed seeds and molting rapeseed seeds after pressing and extraction treatment. Disclosed is a vegetable oil obtained by blending defatted rapeseed with the above-described defatted rapeseed seed and pressing and extracting the mixture. This invention uses the defatted rapeseed skin from which the components unsuitable for edible oil contained in the rapeseed skin have been removed, thereby reducing the content of components unsuitable for edible oil that dissolves in the compressed / extracted oil, as a result This makes it possible to simplify the purification process and reduce costs. The invention of the above-mentioned patent document is characterized in that although a vegetable oil is obtained using molting rapeseed, a refined oil of molting rapeseed having a specific molting rate is blended with other edible oils in a specific range ratio. It is different from the oil and fat composition. And it cannot predict at all from the invention of the said patent document that the oily odor of the foodstuff obtained by heat-cooking a foodstuff with the oil-fat composition of this invention reduces.

本発明の油脂組成物は、さらに、大豆油、コーン油、及びパーム系油脂からなる群から選ばれる少なくとも一種の油脂を含むことが好ましい。   The oil / fat composition of the present invention preferably further contains at least one oil / fat selected from the group consisting of soybean oil, corn oil, and palm oil / fat.

大豆油、コーン油、及びパーム系油脂からなる群から選ばれる少なくとも一種の油脂の合計含有量は、好ましくは15〜85重量%、より好ましくは30〜70重量%である。   The total content of at least one oil selected from the group consisting of soybean oil, corn oil, and palm oil is preferably 15 to 85% by weight, more preferably 30 to 70% by weight.

本発明は、また、上記油脂組成物を用いて食材を加熱調理することを含む、食材を油脂組成物で加熱調理して得られる食品の油臭さを低減する方法を提供する。   The present invention also provides a method for reducing the oily odor of foods obtained by cooking a food with an oil / fat composition, comprising cooking the food with the oil / fat composition.

本発明は、また、上記油脂組成物を使用して加熱調理された食品を提供する。   This invention also provides the foodstuff cooked using the said oil-fat composition.

脱皮率50%以上の菜種を搾油及び精製して得られる菜種油(以下、「脱皮菜種精製油」ともいう)を他の食用油と配合することを特徴とする本発明の油脂組成物によれば、香料やフレーバーオイルが不在でも、加熱調理品の油臭さを低減することができる。後述の比較例1〜3に示すように、脱皮菜種精製油からなる油脂や脱皮菜種精製油の配合率の低い油脂組成物では、油臭さはあまり改善されない。本発明のように脱皮菜種精製油を特定の配合率で他の食用油と配合すると効果が得られることは、全く意外なことである。   According to the oil and fat composition of the present invention, rapeseed oil obtained by squeezing and refining rapeseed having a molting rate of 50% or more (hereinafter also referred to as “peeled rapeseed refined oil”) and other edible oils is blended. Even in the absence of fragrances and flavor oils, the odor of cooked foods can be reduced. As shown in Comparative Examples 1 to 3 described later, the oily odor is not improved so much in an oil / fat composition having a low blending ratio of a molted rapeseed refined oil or a molted rapeseed refined oil. It is quite surprising that an effect can be obtained by blending the molted rapeseed refined oil with other edible oils at a specific blending ratio as in the present invention.

本発明の油脂組成物を用いて食材を加熱調理すると、調理時の油特有の匂いたちも減少させることができる。   When cooking ingredients using the oil / fat composition of the present invention, the smell peculiar to oil during cooking can be reduced.

本発明の油脂組成物で食材を油脂組成物で加熱調理して得られる食品は、油臭さが低減され、食味が向上する。本発明の油脂組成物の特徴を利用して、さまざまな食材への使用が期待される。   The food obtained by cooking the food material with the oil and fat composition of the present invention with the oil and fat composition has a reduced oily odor and an improved taste. Utilizing the characteristics of the oil and fat composition of the present invention, it is expected to be used for various foods.

以下、本発明の油脂組成物の一実施の形態を説明する。本発明の油脂組成物は、脱皮率50%以上の菜種を搾油及び精製して得られる菜種油(以下、成分(A)という)を含む。   Hereinafter, one embodiment of the oil and fat composition of the present invention will be described. The oil and fat composition of the present invention contains rapeseed oil (hereinafter referred to as component (A)) obtained by squeezing and refining rapeseed having a molting rate of 50% or more.

成分(A)の原料となる菜種は、特に制限されない。菜種の例には、Brassica campestris(和種)、Brassica napus(西洋種)の他に、キャノーラ品種、キラリボシ、ななしきぶ等のエルカ酸及びグルコシノレート含量の低い品種が含まれる。   The rapeseed used as a raw material for the component (A) is not particularly limited. Examples of the rapeseed include varieties having low glucosinolate content such as canola varieties, Kirariboshi, Nanashiki, as well as Brassica campestris (Japanese varieties) and Brassica napus (Western varieties).

前記脱皮率は、式(1)により得られる。

Figure 2015114915
The molting rate is obtained by the formula (1).
Figure 2015114915

上記菜種の脱皮率の下限は、50%以上であり、好ましくは70%以上、より好ましくは85%以上、特に好ましくは90%以上である。脱皮率が50%未満であると、本発明の効果が得られない。脱皮率の上限は、特にないが、通常100%以下であり、好ましくは99%以下である。   The lower limit of the molting rate of the rapeseed is 50% or more, preferably 70% or more, more preferably 85% or more, and particularly preferably 90% or more. If the molting rate is less than 50%, the effect of the present invention cannot be obtained. The upper limit of the molting rate is not particularly limited, but is usually 100% or less, preferably 99% or less.

菜種は、粒径1〜2mm程度の球体である。菜種の約10〜20重量%を種皮が占めている。菜種を脱皮する方法は、特に制限されない。例えばフレーキングローラー(圧扁機)、エントレーター型粉砕機、ハンマーミル、ボールミル、ピンミル、ローターミル、カッティングミル、遠心粉砕機等を用いて、菜種を実と皮とに剥皮する。後で実と皮との分離が困難にならないように、微細に粉砕しすぎないことが好ましい。   The rapeseed is a sphere having a particle size of about 1 to 2 mm. The seed coat occupies about 10 to 20% by weight of the rapeseed. The method for molting rapeseed is not particularly limited. For example, the rapeseed is peeled into the fruit and the skin using a flaking roller (pressing machine), an entrator-type pulverizer, a hammer mill, a ball mill, a pin mill, a rotor mill, a cutting mill, a centrifugal pulverizer or the like. It is preferable not to pulverize too much so that separation between the fruit and the skin does not become difficult later.

剥離した菜種は、実と皮との混合物である。実と皮との分離は、風選、比重分離、篩分け等の方法で行なうことができる。   The peeled rapeseed is a mixture of fruit and skin. Separation of the fruit and the skin can be performed by methods such as wind selection, specific gravity separation, and sieving.

脱皮方法の一例を具体的に示す。
(工程1)
菜種の前処理として、菜種を風力選別機にかけて、菜種原料から、茎や鞘部分や小石等の異物を除去する。
An example of a molting method is shown concretely.
(Process 1)
As a rapeseed pretreatment, the rapeseed is subjected to a wind power sorter to remove foreign matters such as stems, sheaths and pebbles from the rapeseed raw material.

(工程2)
茎と鞘を除いた菜種をフレーキングローラーで圧扁して、種子と皮とを剥離させる。フレーキングローラーのクリアランスは、通常、0.3〜1.1mmでよい。さらに衝撃破砕機で菜種を粉砕して、実と皮との分離を促進する。
(Process 2)
The rapeseed, excluding the stem and sheath, is crushed with a flaking roller to peel the seeds and skin. The clearance of the flaking roller is usually 0.3 to 1.1 mm. Furthermore, rapeseed is pulverized with an impact crusher to promote separation of fruit and skin.

(工程3)
粉砕された菜種原料を、篩(例えば0.6mm正方網)による篩い分けにより篩上画分と篩下画分を得る。
(Process 3)
The ground rapeseed raw material is sieved with a sieve (for example, a 0.6 mm square mesh) to obtain an on-sieving fraction and an under-sieving fraction.

篩上画分は、工程2の原料に戻す。こうして得られる篩下画分を脱皮菜種とし、脱皮率は、通常、90%程度となる。   The sieving fraction is returned to the raw material of step 2. The sieving fraction thus obtained is used as molting rapeseed, and the molting rate is usually about 90%.

90%よりも緩和された脱皮率を有する脱皮菜種を得るためには、篩の目開きを調整する、上記範囲の脱皮菜種と未脱皮菜種を適当な脱皮率になるように配合する等の方法を採用すればよい。   In order to obtain a molting rapeseed having a molting rate that is less than 90%, a method of adjusting the mesh opening of the sieve, blending the molting rapeseed and the non-hulling rapeseed in the above ranges so as to obtain an appropriate molting rate, etc. Should be adopted.

上記脱皮菜種を圧搾抽出及び/又は溶剤抽出することにより粗油を得、その粗油を精製することにより、脱皮菜種精製油を製造することができる。   A crude oil can be obtained by compressing and / or solvent extracting the molting rapeseed and refining the crude oil to produce a molting rapeseed refined oil.

圧搾抽出では、脱皮菜種からなる油糧原料を圧扁し、熱処理(クッキング)後、圧搾機(連続式エキスペラーや不連続式水圧機等)で高圧を加えて細胞中の油分を搾り取る。溶剤抽出では、脱皮菜種からなる油糧原料を圧扁もしくは圧搾抽出後の残渣に溶剤を接触させ、油分を溶剤溶液として抽出し、得られる溶液から溶剤を留去して油分を得る。溶剤にはn−ヘキサン等を使用する。   In the compression extraction, an oil raw material composed of molted rapeseed is crushed, heat treated (cooked), and then pressurized with a squeezing machine (such as a continuous expeller or discontinuous hydraulic machine) to squeeze out the oil in the cells. In the solvent extraction, an oil raw material composed of molting rapeseed is brought into contact with the residue after pressing or extraction, the oil is extracted as a solvent solution, and the solvent is distilled off from the resulting solution to obtain the oil. N-hexane or the like is used as the solvent.

精製手段としては、植物油の一般的な精製工程を適用することができる。すなわち、粗油→脱ガム油→脱酸油→脱色油→脱臭油(精製油)の順に不純物が除かれる。それぞれの間に、「脱ガム処理」、「脱酸処理」、「脱色処理」、及び「脱臭処理」の操作が行われる。   As a refining means, a general refining process of vegetable oil can be applied. That is, impurities are removed in the order of crude oil → degummed oil → deoxidized oil → decolorized oil → deodorized oil (refined oil). Between each of them, operations of “degumming treatment”, “deoxidation treatment”, “decolorization treatment”, and “deodorization treatment” are performed.

脱ガム処理は、油分中に含まれるリン脂質を主成分とするガム質を水和除去する工程である。具体的には、ガム質を水和するのに必要量の水(例えば、0.5〜5重量%)の水を油に加え、50〜90℃の温度で攪拌して、ガム質を水和膨潤させる。常温へ冷却後、凝集したガム質成分を遠心分離機等で分離する。   The degumming treatment is a step of hydrating and removing the gums mainly composed of phospholipids contained in the oil. Specifically, water necessary for hydrating the gum is added to the oil in an amount of water (for example, 0.5 to 5% by weight) and stirred at a temperature of 50 to 90 ° C. to remove the gum. Swell the sum. After cooling to room temperature, the agglomerated gum component is separated with a centrifuge or the like.

脱酸処理は、アルカリ水で処理することにより、油分中に含まれる遊離脂肪酸をセッケン分として除去する工程である。具体的には、脱ガム油を、通常、40〜110℃に加熱し、0.01〜2.0重量%の酸(リン酸、酢酸、シュウ酸、クエン酸等)を添加して、撹拌する。その後、アルカリ(水酸化ナトリウム、水酸化カリウム、炭酸ナトリウム等)を添加し、油と油滓(アルカリフーツ)とに分離される。遠心分離により油滓を除去した後、温水による洗浄を行い油中のセッケン分を除去する。   A deoxidation process is a process of removing the free fatty acid contained in oil as soap by processing with alkaline water. Specifically, the degummed oil is usually heated to 40 to 110 ° C., and 0.01 to 2.0% by weight of acid (phosphoric acid, acetic acid, oxalic acid, citric acid, etc.) is added and stirred. To do. Then, alkali (sodium hydroxide, potassium hydroxide, sodium carbonate, etc.) is added, and it isolate | separates into oil and oil cake (alkali foots). After removing the oil cake by centrifugation, wash with warm water to remove soap in the oil.

脱色処理は、油分中に含まれる色素を吸着剤(活性白土、酸性白土、活性炭等)に吸着させて除去する工程である。具体的には、脱酸油に吸着剤を添加後、常圧又は減圧下、通常、40〜100℃の温度で10〜90分間攪拌する。その後、脱色油をろ過手段(加圧、減圧又は吸引濾過等)でろ過する。   The decoloring treatment is a step of removing the pigment contained in the oil by adsorbing it to an adsorbent (active clay, acidic clay, activated carbon, etc.). Specifically, after the adsorbent is added to the deoxidized oil, the mixture is stirred at a temperature of 40 to 100 ° C. for 10 to 90 minutes under normal pressure or reduced pressure. Thereafter, the decolorized oil is filtered by a filtering means (pressurization, reduced pressure, suction filtration or the like).

脱臭処理は、減圧下で水蒸気蒸留することによって油分中に含まれる有臭成分を除去する工程である。具体的には、反応容器内の脱色油へ水蒸気を連続的に吹き込み、そこから発生する臭気成分を含んだ水蒸気を除去する。   The deodorizing process is a process of removing odorous components contained in oil by steam distillation under reduced pressure. Specifically, water vapor is continuously blown into the decolorized oil in the reaction vessel, and water vapor containing odor components generated therefrom is removed.

成分(A)は、脱皮率50%以上の菜種を搾油及び精製して得られる菜種油であるが、脱皮率の高い菜種から搾油及び精製して得られる菜種油と脱皮率の低いあるいは未脱皮の菜種から搾油及び精製して得られる菜種油を混合して、脱皮率50%以上となるようにしてもよい。   Component (A) is rapeseed oil obtained by squeezing and refining rapeseed having a molting rate of 50% or more, and rapeseed oil obtained by squeezing and refining from rapeseed having a high molting rate and low molting rate or un molted rapeseed The rapeseed oil obtained by squeezing and refining can be mixed so that the molting rate is 50% or more.

本発明の組成物において、成分(A)の含有量は、15〜85重量%である必要がある。成分(A)の含有量が15重量%より低いと、油脂組成物で加熱調理して得られる食品の油臭さを低減するという効果が得られない。逆に、含有量が85重量%より高くても、本発明の効果は得られない。例えば、後述する比較例1に示すように、成分(A)のみからなる油脂を用いて加熱調理した食品の油臭さは、未脱皮菜種精製油を用いた対照と同程度となる。成分(A)の含有量は、好ましくは18〜75重量%であり、より好ましくは、20〜70重量%であり、さらに好ましくは28〜70重量%であり、最も好ましくは30〜70重量%である。   In the composition of the present invention, the content of the component (A) needs to be 15 to 85% by weight. When content of a component (A) is lower than 15 weight%, the effect of reducing the oily odor of the foodstuff obtained by cooking with an oil-fat composition is not acquired. On the contrary, even if the content is higher than 85% by weight, the effect of the present invention cannot be obtained. For example, as shown in Comparative Example 1 described later, the oily odor of food cooked using oil and fat consisting only of the component (A) is comparable to the control using unhulled rapeseed refined oil. The content of the component (A) is preferably 18 to 75% by weight, more preferably 20 to 70% by weight, further preferably 28 to 70% by weight, and most preferably 30 to 70% by weight. It is.

本発明の組成物は、成分(A)のほかに、成分(A)以外の食用油脂(以下、成分(B)という)を含む。成分(B)は、食用油として用いられているものであればよい。具体例として、大豆油、コーン油、パーム油、オリーブ油、ゴマ油、紅花油、ひまわり油、綿実油、米油、落下生油、ヤシ油等の植物油脂、牛脂、豚脂等の動物脂、並びにこれらを分別、水素添加、エステル交換等の処理を施した加工油脂が挙げられる。この食用油脂は、一種単独でも、二種類以上のブレンドでもよい。なお、菜種油の加工油脂は、成分(B)に含まれる。成分(B)は、好ましくは、大豆油、コーン油、及びパーム系油脂からなる群から選ばれる少なくとも一種を含む。ここでいうパーム系油脂とは、パーム油およびパーム油を分別、水素添加、エステル交換等の処理を施した加工油脂のことをいい、パーム油およびパームオレインが好ましい。   The composition of this invention contains edible fats and oils (henceforth a component (B)) other than a component (A) other than a component (A). A component (B) should just be used as edible oil. Specific examples include vegetable oils such as soybean oil, corn oil, palm oil, olive oil, sesame oil, safflower oil, sunflower oil, cottonseed oil, rice oil, fallen raw oil, coconut oil, animal fats such as beef tallow and pork fat, and these And processed oils and fats that have been subjected to treatments such as fractionation, hydrogenation, and transesterification. This edible oil / fat may be a single type or a blend of two or more types. In addition, the processed oil of rapeseed oil is contained in a component (B). The component (B) preferably contains at least one selected from the group consisting of soybean oil, corn oil, and palm oil. The term “palm-based oil / fat” as used herein refers to processed oil / fat obtained by subjecting palm oil and palm oil to separation, hydrogenation, transesterification and the like, and palm oil and palm olein are preferred.

本発明の組成物おいて、成分(B)の含有量は、通常、15〜85重量%であり、
好ましくは25〜82重量%であり、より好ましくは30〜80重量%であり、さらに好ましくは30〜72重量%であり、最も好ましくは30〜70重量%である。
In the composition of the present invention, the content of the component (B) is usually 15 to 85% by weight,
Preferably it is 25-82 weight%, More preferably, it is 30-80 weight%, More preferably, it is 30-72 weight%, Most preferably, it is 30-70 weight%.

特に好ましくは、成分(B)は、大豆油、コーン油、及びパーム系油脂からなる群から選ばれる少なくとも一種からなる。よって、大豆油、コーン油、及びパーム系油脂からなる群から選ばれる少なくとも一種からなる油脂の合計含有量は、組成物全体に対して、通常、15〜85重量%であり、好ましくは25〜82重量%であり、より好ましくは30〜80重量%であり、さらに好ましくは30〜72重量%であり、最も好ましくは30〜70重量%である。特に、コーン油を30〜70重量%含むことが好ましい。   Especially preferably, a component (B) consists of at least 1 type chosen from the group which consists of soybean oil, corn oil, and palm oil fat. Therefore, the total content of fats and oils consisting of at least one selected from the group consisting of soybean oil, corn oil, and palm oils and fats is usually 15 to 85% by weight, preferably 25 to 25% based on the entire composition. 82% by weight, more preferably 30-80% by weight, still more preferably 30-72% by weight, and most preferably 30-70% by weight. In particular, it is preferable to contain 30 to 70% by weight of corn oil.

本発明の油脂組成物は、成分(A)及び成分(B)のほかに、公知の食用油脂用添加剤を、本発明の効果を妨げない範囲で添加してよい。そのような添加剤の例には、トコフェロール、L−アスコルビン酸又はその誘導体(例えばアスコルビン酸ステアレートのようなエステルやエリソルビン酸のような立体異性体)、BHT(ジエチルヒドロキシトルエン)、BHA(ブチルヒドロキシアニソール)、NDGA(ノルジヒドログアヤレチック酸)、没食子酸、没食子酸プロピル、カテキン等の抗酸化剤;シリコーン樹脂等の消泡剤;クエン酸、リンゴ酸等の風味安定剤;香料;着色剤;固化防止剤;脂肪結晶調整剤;金属キレート剤;ショ糖脂肪酸エステル、有機酸モノグリセリド、ポリグリセリン脂肪酸エステル、リン脂質等の乳化剤等が挙げられる。   In addition to the component (A) and the component (B), the oil / fat composition of the present invention may be added with known edible oil / fat additives within a range that does not interfere with the effects of the present invention. Examples of such additives include tocopherol, L-ascorbic acid or derivatives thereof (eg, esters such as ascorbic acid stearate and stereoisomers such as erythorbic acid), BHT (diethylhydroxytoluene), BHA (butyl). Hydroxyanisole), NDGA (nordihydroguaiaretic acid), gallic acid, propyl gallate, catechin, and other antioxidants; antifoaming agents such as silicone resins; flavor stabilizers such as citric acid and malic acid; Agents; anti-caking agents; fat crystal modifiers; metal chelating agents; emulsifiers such as sucrose fatty acid esters, organic acid monoglycerides, polyglycerin fatty acid esters, phospholipids, and the like.

本発明の油脂組成物の形状は、液状、ペースト状、固形状のいずれでもよい。形状は、食用油脂をはじめとする必須成分、およびその他の成分を適宜選択することにより容易に調整可能である。   The shape of the oil and fat composition of the present invention may be liquid, pasty, or solid. The shape can be easily adjusted by appropriately selecting essential components including edible fats and oils and other components.

本発明は、また、上記油脂組成物を用いて食材を加熱調理することを含む、油脂を用いて加熱調理した食品の油臭さを低減する方法を提供する。本明細書において、「加熱調理」の用語は、揚げる、炒める、ソテーする、食材の表面にコーティングしてオーブン等で輻射ないし対流加熱する等の態様を含む。加熱調理の温度は、通常、100〜200℃であり、好ましくは130〜190℃である。特に、揚げ物用の調理が好ましい。   The present invention also provides a method for reducing the oily odor of food cooked using fats and oils, including cooking the food using the oil composition. In the present specification, the term “cooking” includes aspects such as frying, frying, sauteing, coating on the surface of a food material, and radiation or convection heating in an oven or the like. The temperature of cooking is usually 100 to 200 ° C, preferably 130 to 190 ° C. In particular, cooking for fried food is preferred.

上記加熱調理した食品の例には、例えば、コロッケ、とんかつ、唐揚げ、フリッター、天ぷら、魚フライ、フライドポテト、ドーナッツ等のフライ食品;さつまあげ等の魚肉練加工物の揚げ物;揚げ麺、油揚げ即席麺、薄揚げ(油揚げ)、厚揚げ、がんもどき、揚げ豆腐;ハンバーグ、ポークソテー、お好み焼き、たこ焼き、パスタ;焼飯;揚げ米菓、ポテトチップス等の揚げ菓子類;等がある。   Examples of the cooked food include fried foods such as croquettes, tonkatsu, fried chicken, fritters, tempura, fried fish, fried potatoes, donuts, etc .; There are noodles, thin fried (oil fried), thick fried, gandou, fried tofu; hamburger, pork sauté, okonomiyaki, takoyaki, pasta; baked rice;

以下、実施例及び比較例を示すことにより、本発明をさらに詳細に説明する。しかし、以下の実施例は、本発明を限定するものではない。   Hereinafter, the present invention will be described in more detail by showing examples and comparative examples. However, the following examples do not limit the present invention.

〔調製例1〕(脱皮菜種精製油の調製)
(脱皮)
菜種(品種:カナダ産キャノーラ)30kgを風力選別機(製品名:風力選別機MODEL3300 安西製作所製)にかけて、茎と鞘を除去した。得られた菜種原料を、フレーキングローラー(クリアランス0.7mm)を通過させた後、衝撃破砕機を用いて1200rpmで破砕した。破砕した菜種原料を篩(0.6mm正方網)で篩って、篩上及び篩下画分を得た。上記篩上画分は、上記フレーキングローラーへ戻した。篩下画分を脱皮菜種とした。この脱皮菜種の脱皮率は90%であった。この脱皮菜種を、「脱皮率90%菜種」という。
[Preparation Example 1] (Preparation of molting rapeseed refined oil)
(Molting)
30 kg of rapeseed (variety: Canadian canola) was applied to a wind power sorter (product name: wind power sorter MODEL3300 manufactured by Anzai Seisakusho) to remove the stem and the sheath. The obtained rapeseed raw material was passed through a flaking roller (clearance 0.7 mm) and then crushed at 1200 rpm using an impact crusher. The crushed rapeseed raw material was sieved with a sieve (0.6 mm square mesh) to obtain a fraction above and below the sieve. The sieved fraction was returned to the flaking roller. The sieving fraction was used as molting rapeseed. The molting rate of this molting rapeseed was 90%. This molting rapeseed is referred to as “rapeseed 90% rapeseed”.

上記90%脱皮菜種と通常の未脱皮菜種とを重量比で1:0.2の比率で混合することにより、脱皮率75%の脱皮菜種を調製した。この脱皮菜種を、「脱皮率75%菜種」という。同じく、90%脱皮菜種と通常の未脱皮菜種とを重量比で1:0.8の比率で混合することにより、脱皮率50%の脱皮菜種を調製した。この脱皮菜種を、「脱皮率50%菜種」という。   The 90% molting rapeseed and normal non-molting rapeseed were mixed at a weight ratio of 1: 0.2 to prepare a molting rapeseed having a molting rate of 75%. This molting rapeseed is called "rapeseed 75% rapeseed". Similarly, a molting rapeseed having a molting rate of 50% was prepared by mixing 90% molting rapeseed and normal unmolting rapeseed at a weight ratio of 1: 0.8. This molting rapeseed is called “rapeseed 50% rapeseed”.

(圧搾)
脱皮率0、50、75又は90%の菜種を、それぞれ、エキスペラーで圧搾し、圧搾油と圧搾粕を得た。得られた圧搾粕を、ヘキサン抽出により油分を抽出した。得られた抽出油を前記圧搾油と合一して、粗油を得た。
(Squeezed)
Each rapeseed having a molting rate of 0, 50, 75, or 90% was compressed with an expeller to obtain compressed oil and pressed rice cake. The oil content was extracted by hexane extraction from the obtained pressed rice cake. The obtained extracted oil was united with the compressed oil to obtain a crude oil.

(精製)
上記粗油を、常法に基づいて脱ガム、脱酸、脱色及び脱臭工程にかけることにより、精製油を得た。脱皮率90%菜種の精製油、脱皮率75%菜種の精製油、及び、脱皮率50%菜種の精製油、未脱皮菜種の精製油(従来の精製菜種油)を、それぞれ、「脱皮率90%菜種精製油」、「脱皮率75%菜種精製油」、「脱皮率50%菜種精製油」、及び「未脱皮菜種精製油」という。
(Purification)
A refined oil was obtained by subjecting the crude oil to degumming, deoxidation, decolorization and deodorization steps according to a conventional method. A refined oil of rapeseed with a molting rate of 90%, a refined oil of rapeseed with a molting rate of 75%, a refined oil of rapeseed with a molting rate of 50%, and a refined oil of rapeseed without conventional molting (conventional refined rapeseed oil), respectively, The rapeseed refined oil, the rapeseed refined oil with a molting rate of 75%, the rapeseed refined oil with a molting rate of 50%, and the unpeeled rapeseed refined oil.

未脱皮菜種精製油、及び脱皮率90%菜種精製油の物性を表1に示す。

Figure 2015114915
※色調:ロビボンド比色計(5.25インチセル使用)のR/Y値を示す。
Table 1 shows the physical properties of unpeeled rapeseed refined oil and rapeseed refined oil with a moulting rate of 90%.
Figure 2015114915
* Color tone: R / Y value of Robibond colorimeter (using 5.25 inch cell).

〔実施例1〜5〕(脱皮率の変更試験)
1.油脂組成物の調製
脱皮率を変更した菜種から得られる精製油と大豆油とのブレンドした油脂組成物を調製し、その評価を行なった。具体的には、以下に示す成分(A)及び(B)を表2に示す割合で配合し、油脂組成物を得た。
成分(A):
前記脱皮率90%菜種精製油、
前記脱皮率75%菜種精製油、
前記脱皮率50%菜種精製油、
成分(B):
大豆油(株式会社J−オイルミルズ製)、
コーン油(株式会社J−オイルミルズ製)、
パームオレイン(ヨウ素価67、株式会社J−オイルミルズ製)
[Examples 1 to 5] (Change test of molting rate)
1. Preparation of Oil and Fat Composition An oil and fat composition blended with refined oil and soybean oil obtained from rapeseed having a modified molting rate was prepared and evaluated. Specifically, the components (A) and (B) shown below were blended in the proportions shown in Table 2 to obtain an oil and fat composition.
Ingredient (A):
Rapeseed refined oil with 90% molting rate,
75% rapeseed refined oil,
50% rapeseed refined oil,
Ingredient (B):
Soybean oil (manufactured by J-Oil Mills Co., Ltd.),
Corn oil (manufactured by J-Oil Mills Co., Ltd.),
Palm olein (Iodine number 67, manufactured by J-Oil Mills Co., Ltd.)

2.油脂組成物の評価
油脂組成物を使用して冷凍食材を加熱調理して得られる食品の官能評価を行なうことによって、油脂組成物を評価した。具体的には、上記油脂組成物500gを、片手鍋に入れ、180℃まで加熱した。昇温後、冷凍食材(製品名シューストリングフライポテト、味の素冷凍食品株式会社製)75gを3分間、揚げることにより、フライドポテトを作製し、官能評価をおこなった。さらに、調理後の油が180℃に復帰したら、同様に75gの冷凍食材を揚げ、フライドポテトを作製し、官能評価を行い、計6回の官能評価を繰り返した。
2. Evaluation of oil and fat composition The oil and fat composition was evaluated by sensory evaluation of foods obtained by cooking the frozen food using the oil and fat composition. Specifically, 500 g of the oil composition was placed in a one-handed pan and heated to 180 ° C. After the temperature rise, 75 g of frozen food (product name: shoestring fried potato, Ajinomoto Frozen Foods Co., Ltd.) was fried for 3 minutes to prepare fries and sensory evaluation was performed. Furthermore, when the oil after cooking returned to 180 ° C., 75 g of frozen foods were fried in the same manner to prepare french fries, sensory evaluation was performed, and sensory evaluation was repeated a total of six times.

官能評価は、フライドポテトをホットサーバーで80℃に保温しながら、1回分で3名、計18名のパネラーにて「フライドポテトの油の臭いの強さ(油臭さ)」の評価を行った。以下、「油脂組成物を用いて加熱調理した食品の油臭さ」を、単に「油脂組成物の油臭さ」という。   For sensory evaluation, while keeping the french fries at 80 ° C with a hot server, 3 persons in a single batch, 18 panelists in total evaluated the “odor intensity of the oil of fried potatoes (oil smell)” It was. Hereinafter, “the oily odor of food cooked using the oil / fat composition” is simply referred to as “the oily odor of the oil / fat composition”.

脱皮菜種精製油の油脂組成物の油臭さを、以下に示す基準で、官能評価した。対照は、各脱皮菜種精製油に換えて同量の未脱皮菜種精製油を配合した油脂組成物である。
スコア : 指標
1 : 油臭さが対照よりもかなり弱い
2 : 油臭さが対照よりやや弱い
3 : 油臭さが対照と同程度
4 : 油臭さが対照よりやや強い
5 : 油臭さが対照よりもかなり強い
The oily odor of the oil / fat composition of the molted rapeseed refined oil was subjected to sensory evaluation according to the following criteria. The control is an oil / fat composition containing the same amount of unmolten rapeseed refined oil instead of each molted rapeseed refined oil.
Score: Indicator 1: Oil odor is considerably weaker than the control 2: Oil odor is slightly weaker than the control 3: Oil odor is about the same as the control 4: Oil odor is slightly stronger than the control 5: Oil odor is Much stronger than the control

計18名のパネラーの評価の平均値をスコアとした。このスコアが3以下であると、菜種を脱皮したことで油脂組成物の油臭さに関する性質が改善されている。逆に、スコアが3を超えると、前記性質が悪化している。   The average of the evaluations of a total of 18 panelists was used as the score. When this score is 3 or less, the properties relating to the oily odor of the oil and fat composition are improved by peeling the rapeseed. On the contrary, when the score exceeds 3, the property is deteriorated.

油臭さスコアの平均値(n数18)を、表2に示す。

Figure 2015114915
Table 2 shows the average oil odor score (n number: 18).
Figure 2015114915

表2に示すとおり、脱皮した菜種から得られる精製油を大豆油とブレンドして得られる油脂組成物の油臭さスコアは、未脱皮の菜種から得られる精製油をブレンドした対照の油脂組成物よりも、改善する。スコアの改善に必要な脱皮率は、50%以上であり、好ましくは75%以上、さらに好ましくは90%以上である。   As shown in Table 2, the oily odor score of the fat composition obtained by blending the refined oil obtained from the molted rapeseed with soybean oil is the control fat composition obtained by blending the refined oil obtained from the unpeeled rapeseed. Better than. The molting rate necessary for improving the score is 50% or more, preferably 75% or more, and more preferably 90% or more.

〔実施例6〕(脱皮菜種精製油の含有量の変更試験)
1.組成物の調製
脱皮率90%菜種精製油の含有量を変更した油脂組成物を調製し、その評価を行なった。具体的には、表3に示す成分(A)及び(B)を変更して、油脂組成物を得た。
[Example 6] (Change test of content of molted rapeseed refined oil)
1. Preparation of Composition An oil / fat composition in which the content of the rapeseed refined oil with a molting rate of 90% was changed was prepared and evaluated. Specifically, components (A) and (B) shown in Table 3 were changed to obtain an oil and fat composition.

2.油脂組成物の総揮発性成分量の測定
加熱脱着システムTDU(ゲステル社製)及びGC/MSシステム5975B(アジレント社製)を用い、フライドポテト官能評価後の油を用いて油中から揮発する成分の量を測定した。測定条件は、以下のとおりである。
(TDU条件)
サンプル採取量:10mg
初期温度、保持時間: 30℃、1分
昇温速度: 12℃/秒
最終温度、保持時間: 250℃、10分
(冷却インジェクションCIS条件)
初期温度、保持時間: −50℃、30秒
昇温速度: 12℃/秒
最終温度、保持時間: 250℃、3分
(ガスクロマトグラフ条件)
カラム: ZB−WAX Plus 60m × 250um × 0.25um
オーブン温度: 40分(10℃)→2℃/分昇温→100℃→5℃/分昇温→210℃(10分)
キャリアガス:He、1.6ml/分
(マススペクトロメトリー条件)
イオン源温度: 230℃
四重極温度: 150℃
スキャンモード: m/z 41〜400
2. Measurement of the total amount of volatile components of the oil and fat composition Components that volatilize out of the oil using the heat-desorbed system TDU (Gestel) and GC / MS system 5975B (Agilent) The amount of was measured. The measurement conditions are as follows.
(TDU conditions)
Sample collection amount: 10mg
Initial temperature, holding time: 30 ° C., 1 minute heating rate: 12 ° C./second final temperature, holding time: 250 ° C., 10 minutes (cooling injection CIS conditions)
Initial temperature, holding time: −50 ° C., 30 seconds Temperature rising rate: 12 ° C./second Final temperature, holding time: 250 ° C., 3 minutes (gas chromatographic conditions)
Column: ZB-WAX Plus 60m x 250um x 0.25um
Oven temperature: 40 minutes (10 ° C.) → 2 ° C./minute temperature increase → 100 ° C. → 5 ° C./minute temperature increase → 210 ° C. (10 minutes)
Carrier gas: He, 1.6 ml / min (mass spectrometry conditions)
Ion source temperature: 230 ° C
Quadrupole temperature: 150 ° C
Scan mode: m / z 41-400

スキャンモードで検出された全成分の面積値を合計し、総揮発性成分量とした。ここで、総揮発性成分量100%とは、未脱皮菜種精製油又は未脱皮菜種精製油を配合した油の総揮発性成分量を100としたとき、脱皮菜種精製油または未脱皮菜種精製油を配合した油の相対値が100であること、を意味する。100%よりも小さい場合は揮発性成分量が相対的に低く、100%よりも大きい場合は揮発性成分量が相対的に高いことを示す。   The area values of all components detected in the scan mode were summed to obtain the total amount of volatile components. Here, the total volatile component amount of 100% means that the total volatile component amount of the oil blended with the unpeeled rapeseed refined oil or the unpeeled rapeseed refined oil is 100, the moulted rapeseed refined oil or the unpeeled rapeseed refined oil It means that the relative value of the oil blended with is 100. When it is smaller than 100%, the amount of volatile components is relatively low, and when it is larger than 100%, the amount of volatile components is relatively high.

結果を表3に示す。脱皮菜種精製油を70重量%含む実施例1の油脂組成物は、脱皮菜種精製油からなる比較例1や脱皮菜種精製油を90重量%含む比較例2と比べて、揮発性成分が少ないことが判明した。これら揮発性成分の抑制(度)によって油から発する臭いが低減し、調理品への油臭さの付加が抑制される。   The results are shown in Table 3. The oil and fat composition of Example 1 containing 70% by weight of molting rapeseed refined oil has fewer volatile components than Comparative Example 1 consisting of molting rapeseed refined oil and Comparative Example 2 containing 90% by weight of molting rapeseed refined oil. There was found. By suppressing (degree) of these volatile components, the odor emitted from the oil is reduced, and the addition of the oily odor to the cooked product is suppressed.

3.油脂組成物の評価
上記油脂組成物の評価を、実施例1と同様にして行なった。スコアを統計処理(Wilcoxonの符号順位検定)の結果とともに表3に示す。
3. Evaluation of Oil and Fat Composition The oil and fat composition was evaluated in the same manner as in Example 1. The scores are shown in Table 3 together with the results of statistical processing (Wilcoxon sign rank test).

表3から、脱皮菜種から得られる精製油を他の油とブレンドする際に、脱皮菜種精製油の含有量が比較例3のように低いと、油脂組成物の油臭さはあまり改善されない。意外なことに、脱皮菜種精製油の含有量が比較例1及び2のように高過ぎても、油脂組成物の油臭さはあまり改善されない。したがって、脱皮菜種精製油の含有量は、15〜85重量%である必要があり、好ましくは20〜70重量%であり、より好ましくは、30〜70重量%である。一方、成分(B)の含有量は、好ましくは15〜85重量%であり、より好ましくは30〜80重量%であり、特に好ましくは30〜70重量%である。   From Table 3, when the refined oil obtained from the molting rapeseed is blended with other oils, if the content of the molting rapeseed refined oil is low as in Comparative Example 3, the oily odor of the fat composition is not significantly improved. Surprisingly, even if the content of the molted rapeseed refined oil is too high as in Comparative Examples 1 and 2, the oily odor of the oil and fat composition is not significantly improved. Therefore, the content of the molted rapeseed refined oil needs to be 15 to 85% by weight, preferably 20 to 70% by weight, and more preferably 30 to 70% by weight. On the other hand, the content of component (B) is preferably 15 to 85% by weight, more preferably 30 to 80% by weight, and particularly preferably 30 to 70% by weight.

Figure 2015114915
Figure 2015114915

〔実施例7〕(成分(B)の変更試験)
脱皮率90%菜種精製油とブレンドする油脂を変更した油脂組成物を調製し、その評価を行なった。具体的には、実施例1及び4の大豆油をコーン油又はパームオレインに変更した油脂組成物を調製した(実施例7、8、10、11)。また、実施例1の脱皮率90%菜種精製油の一部をコーン油に変更した油脂組成物を調製した(実施例9)。各例の対照として、脱皮菜種精製油を未脱皮菜種精製油に変更した油脂組成物もまた調製した。
[Example 7] (Change test of component (B))
An oil / fat composition in which the oil / fat blended with the rapeseed refined oil having a molting rate of 90% was changed was prepared and evaluated. Specifically, the oil-and-fat composition which changed the soybean oil of Examples 1 and 4 into corn oil or palm olein was prepared (Examples 7, 8, 10, and 11). Moreover, the oil-fat composition which changed some rapeseed refined oil of the molting rate 90% of Example 1 into corn oil was prepared (Example 9). As a control for each example, an oil / fat composition was also prepared in which the molted rapeseed refined oil was changed to an unmolten rapeseed refined oil.

脱皮菜種精製油と上記各種油脂とをブレンドした油脂組成物の評価を、実施例1と同様に行なった。その結果を表4に示す。

Figure 2015114915
Evaluation of the oil-fat composition which blended the molt | molting | peeling rapeseed refined oil and the said various fats and oils was performed similarly to Example 1. FIG. The results are shown in Table 4.
Figure 2015114915

脱皮菜種精製油とブレンドする油脂は、大豆油以外に、コーン油やパームオレインでも有効である。また、これらのブレンドでも有効である。油脂組成物のスコアは、脱皮菜種精製油とブレンドする油脂がコーン油である場合に効果が高く、次いで、大豆油、パームオレインに続く。したがって、本発明の油脂組成物は、脱皮菜種精製油を好ましくは大豆油、コーン油及びパームオレインからなる群から選ばれる少なくとも一種からなる油脂、より好ましくは、大豆油及び/又はコーン油とブレンドすることにより調製される。   Oils and fats blended with molting rapeseed refined oil are also effective in corn oil and palm olein in addition to soybean oil. These blends are also effective. The score of the fat composition is highly effective when the fat blended with the molted rapeseed refined oil is corn oil, followed by soybean oil and palm olein. Therefore, in the oil and fat composition of the present invention, the molted rapeseed refined oil is preferably blended with at least one oil selected from the group consisting of soybean oil, corn oil and palm olein, more preferably soybean oil and / or corn oil. To be prepared.

本発明の組成物は、成分(A)のほかに、成分(A)以外の食用油脂(以下、成分(B)という)を含む。成分(B)は、食用油として用いられている大豆油、コーン油、パーム油並びにこれらを分別、水素添加、エステル交換等の処理を施した加工油脂が挙げられる。この食用油脂は、一種単独でも、二種類以上のブレンドでもよい。なお、菜種油の加工油脂は、成分(B)に含まれる。成分(B)は、好ましくは、大豆油、コーン油、及びパーム系油脂からなる群から選ばれる少なくとも一種を含む。ここでいうパーム系油脂とは、パーム油およびパーム油を分別、水素添加、エステル交換等の処理を施した加工油脂のことをいい、パーム油およびパームオレインが好ましい。 The composition of this invention contains edible fats and oils (henceforth a component (B)) other than a component (A) other than a component (A). Component (B), soybean oil, corn oil that has been used as a cooking oil, fractionated palm oil, and these, hydrogenated, processing oils and the like which has been subjected to processing for transesterification, and the like. This edible oil / fat may be a single type or a blend of two or more types. In addition, the processed oil of rapeseed oil is contained in a component (B). The component (B) preferably contains at least one selected from the group consisting of soybean oil, corn oil, and palm oil. The term “palm-based oil / fat” as used herein refers to processed oil / fat obtained by subjecting palm oil and palm oil to separation, hydrogenation, transesterification and the like, and palm oil and palm olein are preferred.

Claims (6)

脱皮率50%以上の菜種を搾油及び精製して得られる菜種油を15〜85重量%含む、油脂組成物。   An oil and fat composition comprising 15 to 85% by weight of rapeseed oil obtained by squeezing and refining rapeseed having a molting rate of 50% or more. さらに、大豆油、コーン油、及びパーム系油脂からなる群から選ばれる少なくとも一種の油脂を含む、請求項1に記載の油脂組成物。   Furthermore, the oil-fat composition of Claim 1 containing at least 1 type of fats and oils chosen from the group which consists of soybean oil, corn oil, and palm oil fat. 大豆油、コーン油、及びパーム系油脂からなる群から選ばれる少なくとも一種の前記油脂の合計含有量が、15〜85重量%である、請求項2に記載の油脂組成物。   The fat and oil composition according to claim 2, wherein the total content of at least one fat selected from the group consisting of soybean oil, corn oil, and palm oil and fat is 15 to 85% by weight. 大豆油、コーン油、及びパーム系油脂からなる群から選ばれる少なくとも一種の前記油脂の合計含有量が、30〜70重量%である、請求項3に記載の油脂組成物。   The fat and oil composition according to claim 3, wherein a total content of at least one kind of the fat and oil selected from the group consisting of soybean oil, corn oil, and palm oil and fat is 30 to 70% by weight. 請求項1に記載の油脂組成物を用いて食材を加熱調理することを含む、食材を前記油脂組成物で加熱調理して得られる食品の油臭さを低減する方法。   The method to reduce the oily odor of the foodstuff obtained by heat-cooking a foodstuff with the said oil-fat composition including heat-cooking a foodstuff using the oil-fat composition of Claim 1. 請求項1に記載の油脂組成物を使用して加熱調理された食品。   A food cooked by using the oil and fat composition according to claim 1.
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