JPWO2012002303A1 - Acid oil-in-water emulsified food - Google Patents

Acid oil-in-water emulsified food Download PDF

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JPWO2012002303A1
JPWO2012002303A1 JP2012522610A JP2012522610A JPWO2012002303A1 JP WO2012002303 A1 JPWO2012002303 A1 JP WO2012002303A1 JP 2012522610 A JP2012522610 A JP 2012522610A JP 2012522610 A JP2012522610 A JP 2012522610A JP WO2012002303 A1 JPWO2012002303 A1 JP WO2012002303A1
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JP5783176B2 (en
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聡 寺岡
聡 寺岡
かおり 小口
かおり 小口
茂樹 川▲崎▼
茂樹 川▲崎▼
ティ マイ リン ヒュン
ティ マイ リン ヒュン
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    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23DEDIBLE OILS OR FATS, e.g. MARGARINES, SHORTENINGS, COOKING OILS
    • A23D7/00Edible oil or fat compositions containing an aqueous phase, e.g. margarines
    • A23D7/02Edible oil or fat compositions containing an aqueous phase, e.g. margarines characterised by the production or working-up
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23DEDIBLE OILS OR FATS, e.g. MARGARINES, SHORTENINGS, COOKING OILS
    • A23D7/00Edible oil or fat compositions containing an aqueous phase, e.g. margarines
    • A23D7/005Edible oil or fat compositions containing an aqueous phase, e.g. margarines characterised by ingredients other than fatty acid triglycerides
    • A23D7/0053Compositions other than spreads
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L27/00Spices; Flavouring agents or condiments; Artificial sweetening agents; Table salts; Dietetic salt substitutes; Preparation or treatment thereof
    • A23L27/60Salad dressings; Mayonnaise; Ketchup

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Abstract

冷凍耐性が向上した酸性水中油型乳化食品を提供する。酸性水中油型乳化食品は、その水相に、非溶解状態の澱粉粒子と油滴が分散している。澱粉粒子の平均粒子径は3〜60μm、油滴の平均粒子径は1〜20μm、油滴の平均粒子径と澱粉粒子の平均粒子径との比は(5〜600)/100である。An acidic oil-in-water emulsified food with improved freezing resistance is provided. In an acidic oil-in-water emulsified food, non-dissolved starch particles and oil droplets are dispersed in the aqueous phase. The average particle size of the starch particles is 3 to 60 μm, the average particle size of the oil droplets is 1 to 20 μm, and the ratio of the average particle size of the oil droplets to the average particle size of the starch particles is (5-600) / 100.

Description

本発明は、解凍後も安定な乳化状態を有した冷凍耐性に優れた酸性水中油型乳化食品に関する。   The present invention relates to an acidic oil-in-water emulsified food having a stable emulsified state after thawing and excellent in freezing resistance.

マヨネーズや半固体状乳化ドレッシングなどの酸性水中油型乳化食品は、日常の食生活で広く親しまれている。このような酸性水中油型乳化食品の代表的な用途としてはサラダがあるが、近年、その用途が拡大され、冷凍惣菜などの冷凍食品でも利用されている。また、各家庭においても、酸性水中油型乳化食品を用いた食品を冷凍保存し、解凍あるいは温めて食することがなされている。   Acidic oil-in-water emulsified foods such as mayonnaise and semi-solid emulsified dressings are widely popular in daily eating habits. A typical application of such acidic oil-in-water emulsified foods is salad, but in recent years its use has been expanded and is also used in frozen foods such as frozen side dishes. In each household, foods using acidic oil-in-water type emulsified foods are stored frozen and thawed or warmed before eating.

このため、酸性水中油型乳化食品には、冷凍して解凍した後にも安定した乳化状態を維持すること、即ち、冷凍耐性を備えることが望まれており、冷凍耐性の向上を意図した種々の酸性水中油型乳化食品が提案されている。   Therefore, acidic oil-in-water emulsified foods are desired to maintain a stable emulsified state even after being frozen and thawed, that is, to have freezing resistance. Acidic oil-in-water emulsified foods have been proposed.

例えば、酸性水中油型乳化食品の冷凍耐性を向上させるために、脱糖処理および65℃以上の熱蔵処理が施された乾燥卵白であって、乾燥卵白水溶液(乾燥卵白1部に対し清水7部)の加熱凝固物の離水率が4%以下のものと、キサンタンガムなどのガム質を酸性水中油型乳化食品に配合すること(特許文献1)や、同様の乾燥卵白と加工澱粉等を酸性水中油型乳化食品に配合すること(特許文献2)などが提案されている。   For example, in order to improve the freezing tolerance of an acidic oil-in-water type emulsified food, it is a dried egg white that has been subjected to a desugaring process and a heat storage process of 65 ° C. or higher, Part) with a water separation rate of 4% or less and xanthan gum and other gums in acidic oil-in-water emulsion foods (Patent Document 1), and similar dry egg white and processed starch Blending in an oil-in-water emulsion food (Patent Document 2) has been proposed.

特開2009−61号公報JP 2009-61 A 特開2009−60号公報Japanese Unexamined Patent Publication No. 2009-60

本発明は、より一層冷凍耐性が向上した酸性水中油型乳化食品を提供することを目的とする。   An object of the present invention is to provide an acidic oil-in-water emulsified food having further improved freezing resistance.

本発明者は、酸性水中油型乳化食品の水相に澱粉を非溶解状態で特定の粒子径で分散させると、意外にも冷凍耐性が顕著に向上すること、また、非溶解状態の粒子が分散しているにもかかわらず食感に影響を与えないことを見いだした。   The present inventor surprisingly, when starch is dispersed in an aqueous phase of an acidic oil-in-water emulsified food with a specific particle size in a non-dissolved state, the freezing resistance is unexpectedly improved, and the particles in a non-dissolved state are Despite being dispersed, it has been found that it does not affect the texture.

即ち、本発明は、水相に、非溶解状態の澱粉粒子と油滴が分散している酸性水中油型乳化食品であって、
澱粉粒子の平均粒子径が3〜60μm、
油滴の平均粒子径が1〜20μm、
油滴の平均粒子径と澱粉粒子の平均粒子径との比が(5〜600)/100
である酸性水中油型乳化食品を提供する。
That is, the present invention is an acidic oil-in-water emulsified food in which starch particles and oil droplets in an undissolved state are dispersed in an aqueous phase,
The average particle size of the starch particles is 3-60 μm,
The average particle size of the oil droplets is 1-20 μm,
The ratio of the average particle size of oil droplets to the average particle size of starch particles is (5-600) / 100
An acidic oil-in-water emulsified food is provided.

また、この酸性水中油型乳化食品の製造方法として、澱粉粒子が分散した水相の温度を、該澱粉粒子が完全には溶解しない温度以下とする酸性水中油型乳化食品の製造方法を提供する。   In addition, as a method for producing this acidic oil-in-water emulsified food, there is provided a method for producing an acidic oil-in-water emulsified food in which the temperature of the aqueous phase in which the starch particles are dispersed is not higher than the temperature at which the starch particles are not completely dissolved. .

本発明によれば、解凍後も安定な乳化状態を有する酸性水中油型乳化食品を提供することができる。   ADVANTAGE OF THE INVENTION According to this invention, the acidic oil-in-water type emulsified food which has a stable emulsified state after thawing | decompression can be provided.

図1は、実施例1の水中油型乳化食品の顕微鏡写真である。1 is a photomicrograph of the oil-in-water emulsified food of Example 1. FIG. 図2は、比較例2の水中油型乳化食品の顕微鏡写真である。FIG. 2 is a photomicrograph of the oil-in-water emulsified food of Comparative Example 2.

以下、本発明を詳細に説明する。なお、本発明において「%」は「質量%」を、「部」は「質量部」をそれぞれ意味する。   Hereinafter, the present invention will be described in detail. In the present invention, “%” means “mass%” and “part” means “part by mass”.

本発明において酸性水中油型乳化食品とは、食用油脂が油滴として水相中に略均一に分散して水中油型の乳化状態が形成され、pHが酸性に調整されたものである。好ましくは、常温流通を可能ならしめるため、pHは4.6以下に調整される。このような酸性水中油型乳化食品であって、粘度が30Pa・s以上に調整されたものに、マヨネーズ、マヨネーズ類、半固体状乳化ドレッシング等がある。   In the present invention, the acidic oil-in-water emulsified food is one in which edible fats and oils are dispersed almost uniformly in the water phase as oil droplets to form an oil-in-water emulsified state, and the pH is adjusted to be acidic. Preferably, the pH is adjusted to 4.6 or lower in order to allow normal temperature distribution. Such acidic oil-in-water emulsified foods having a viscosity adjusted to 30 Pa · s or more include mayonnaise, mayonnaise, semi-solid emulsified dressing and the like.

本発明の酸性水中油型乳化食品では、常温において、水相に油滴が乳化分散しているだけでなく、澱粉粒子が非溶解状態で分散している。ここで、澱粉粒子を形成する澱粉としては、常温(15〜25℃)で水に不溶性又は難溶性で加熱により溶解する生澱粉もしくは架橋澱粉をあげることができる。好ましくは、その略1wt%水分散液を55℃に加熱後20℃に冷却したときの粘度が、同水分散液を90℃に加熱後20℃に冷却したときの粘度の80%未満となる粘度特性を有するものである。   In the acidic oil-in-water emulsified food of the present invention, not only oil droplets are emulsified and dispersed in the aqueous phase at normal temperature, but also starch particles are dispersed in an undissolved state. Here, as the starch forming the starch particles, raw starch or crosslinked starch which is insoluble or hardly soluble in water at room temperature (15 to 25 ° C.) and dissolves by heating can be exemplified. Preferably, the viscosity when the approximately 1 wt% aqueous dispersion is heated to 55 ° C. and then cooled to 20 ° C. is less than 80% of the viscosity when the aqueous dispersion is heated to 90 ° C. and then cooled to 20 ° C. It has viscosity characteristics.

この粘度特性は、より具体的には、澱粉の水分散液を室温で0.1〜3wt%の範囲内に調製し、それを加熱撹拌下で55℃に加熱し、55℃に達温後20℃の室内に静置し、20℃に冷却されたときに測定した粘度と、加熱温度を90℃として同様に加熱冷却後に測定した粘度とから算出される。   More specifically, this viscosity characteristic is obtained by preparing an aqueous dispersion of starch in the range of 0.1 to 3 wt% at room temperature, heating it to 55 ° C. with heating and stirring, and reaching the temperature after reaching 55 ° C. It is calculated from the viscosity measured when left in a room of 20 ° C. and cooled to 20 ° C., and the viscosity measured after heating and cooling similarly at 90 ° C.

このような粘度特性を満たす生澱粉としては、加熱溶解性の生澱粉、具体的には、米澱粉、馬鈴薯澱粉、コーンスターチ、タピオカ澱粉、サゴ澱粉、甘藷澱粉、小麦澱粉等をあげることができる。また、架橋澱粉は、澱粉分子中の水酸基のうちいくつかを架橋処理したものであり、架橋方法としては、アセチル化アジピン酸架橋や、アセチル化リン酸架橋等が挙げられる。架橋澱粉の原料となる澱粉の種類には特に限定はなく、例えば、馬鈴薯澱粉、コーンスターチ(例えば、スイートコーン由来、デントコーン由来、ワキシーコーン由来のコーンスターチ)、タピオカ澱粉、サゴ澱粉、甘藷澱粉、小麦澱粉、米澱粉等をあげることができる。本発明においては、これらの1種又は複数種を合わせて使用することができる。   Examples of raw starch satisfying such viscosity characteristics include heat-soluble raw starch, specifically, rice starch, potato starch, corn starch, tapioca starch, sago starch, sweet potato starch, and wheat starch. The crosslinked starch is obtained by crosslinking some of the hydroxyl groups in the starch molecule, and examples of the crosslinking method include acetylated adipic acid crosslinking and acetylated phosphate crosslinking. There are no particular limitations on the type of starch used as a raw material for the cross-linked starch. For example, potato starch, corn starch (for example, corn starch derived from sweet corn, dent corn, waxy corn), tapioca starch, sago starch, sweet potato starch, wheat starch , Rice starch and the like. In the present invention, one or more of these can be used in combination.

なお、上述の澱粉であっても、精製法、加工処理方法等によって冷水可溶性ないし常温可溶性を示すものは、その粒子を水相において非溶解状態で分散させることができないので好ましくない。   In addition, even if it is the above-mentioned starch, what shows cold water solubility or normal temperature solubility by a refinement | purification method, a processing method, etc. is unpreferable since the particle | grains cannot be disperse | distributed in an undissolved state in an aqueous phase.

また、本発明において水相に、非溶解状態の澱粉粒子が分散しているとは、水相に含まれている澱粉の全てが非溶解状態で粒子となっていることは必ずしも必要ではなく、一部、好ましくは全てが非溶解状態で分散していればよい。   Further, in the present invention, the non-dissolved starch particles are dispersed in the aqueous phase, and it is not always necessary that all of the starch contained in the aqueous phase is in a non-dissolved state, Some, preferably all, may be dispersed in an undissolved state.

本発明において、水相で非溶解状態で分散している澱粉粒子の平均粒子径は3〜60μmである。澱粉粒子の平均粒子径がこの範囲より小さ過ぎたり、大き過ぎたりすると冷凍耐性を十分に向上させることができず、好ましくない。   In the present invention, the average particle size of the starch particles dispersed in the water phase in an undissolved state is 3 to 60 μm. If the average particle size of the starch particles is too small or too large, the freezing resistance cannot be improved sufficiently, which is not preferable.

ここで、澱粉粒子の平均粒子径は、光学顕微鏡で酸性水中油型乳化食品を観察し、酸性水中油型乳化食品中の無作為に選択した100個の澱粉粒子について粒子径を測定し、その平均値を算出して得ることができる。   Here, the average particle size of the starch particles is measured by observing the acidic oil-in-water emulsified food with an optical microscope, measuring the particle size of 100 randomly selected starch particles in the acidic oil-in-water emulsified food, An average value can be calculated and obtained.

なお、水相に非溶解状態で分散している澱粉粒子の平均粒子径は、原料となる澱粉の種類や架橋方法、さらに架橋度の影響を受ける。即ち、糊化温度以上に加熱されることなく水相に非溶解状態で分散した澱粉粒子の平均粒子径は、主に、原料となる澱粉の由来に依存する。一方、本来の澱粉粒子の糊化温度以上に加熱されても、架橋により澱粉粒の崩壊が抑制されて粒子状態を維持する架橋澱粉の場合、その水分散液での平均粒子径は主に原料となる澱粉の粉粒の大きさと架橋度に依存する。そこで本発明においては、原料となる澱粉の種類、精製法、架橋度等により異なる種々の平均粒子径の澱粉粒子の中から、平均粒子径が前述の範囲のものを適宜選択したり、フルイにより濾別して使用する。   The average particle size of the starch particles dispersed in the water phase in an undissolved state is affected by the type of starch used as a raw material, the crosslinking method, and the degree of crosslinking. That is, the average particle diameter of starch particles dispersed in an aqueous phase in an undissolved state without being heated to the gelatinization temperature or higher mainly depends on the origin of starch as a raw material. On the other hand, in the case of cross-linked starch that maintains the particle state by suppressing starch particle disintegration by cross-linking even when heated above the gelatinization temperature of the original starch particles, the average particle size in the aqueous dispersion is mainly the raw material Depends on the size of the starch granules and the degree of crosslinking. Therefore, in the present invention, among the starch particles having various average particle sizes that differ depending on the type of starch used as a raw material, the purification method, the degree of crosslinking, etc., those having an average particle size in the above-mentioned range are appropriately selected, Used after filtering.

本発明の酸性水中油型乳化食品において、澱粉の配合割合は、当該澱粉の種類にもよるが、無水換算で0.01〜20%が好ましく、より好ましくは0.1〜10%である。澱粉の配合量が少なすぎると冷凍耐性を十分に向上させることができず、反対に多すぎると酸性水中油型乳化食品に滑らかな食感を与え難くなる。   In the acidic oil-in-water emulsified food of the present invention, the starch blending ratio is preferably 0.01 to 20%, more preferably 0.1 to 10% in terms of anhydrous, although it depends on the type of the starch. If the starch content is too small, the freezing resistance cannot be improved sufficiently, while if it is too large, it becomes difficult to give a smooth texture to the acidic oil-in-water emulsified food.

本発明の酸性水中油型乳化食品の水相には、上述のように非溶解状態の粒子として澱粉を分散させる他、DE(dextrose equivalent)12以下の澱粉分解物、加工澱粉及び湿熱処理澱粉から選ばれる1種以上の澱粉処理物を溶解状態で含有させることが好ましい。これにより水相の粘度を高め、冷凍時の油脂の結晶化を抑制することができる。   In the aqueous phase of the acidic oil-in-water emulsified food according to the present invention, starch is dispersed as non-dissolved particles as described above, and also from a starch degradation product having a DE (dextrose equivalent) of 12 or less, processed starch, and wet heat-treated starch. It is preferable to include one or more selected starch processed products in a dissolved state. Thereby, the viscosity of a water phase can be raised and the crystallization of the fats and oils at the time of freezing can be suppressed.

ここで、澱粉分解物とは、例えば、馬鈴薯澱粉、コーンスターチ、ワキシーコーンスターチ、タピオカ澱粉等の澱粉類を分解して得られるデキストリン、マルトデキストリン、水飴等と称されるものである。DEは澱粉分解物における分解の程度を表す指標であり、DEの値が大きくなるにつれ分解の程度が高くなる。本発明では、分解の程度が低いDE12以下の澱粉分解物を用いることが好ましく、より好ましくは9以下の澱粉分解物を用いる。   Here, the starch decomposition product is, for example, a dextrin obtained by decomposing starch such as potato starch, corn starch, waxy corn starch, tapioca starch, maltodextrin, starch syrup and the like. DE is an index representing the degree of decomposition in the starch decomposition product, and the degree of decomposition increases as the value of DE increases. In the present invention, it is preferable to use a starch decomposition product of DE12 or less, which has a low degree of decomposition, and more preferably a starch decomposition product of 9 or less.

また、DE12以下の澱粉分解物の配合量は、上述の非溶解状態の澱粉粒子を形成する澱粉の配合量や、他の澱粉処理物の配合量にもよるが、解凍後の乳化状態をより安定化させる点から0.1〜8%が好ましく、0.5〜6%がより好ましい。これに対し、配合量が多すぎると食感が重たくなる傾向があり好ましくない。   Moreover, the blending amount of the starch degradation product of DE12 or less depends on the blending amount of starch that forms the above-mentioned non-dissolved starch particles and the blending amount of other processed starch, but the emulsified state after thawing is more From the point of stabilization, 0.1 to 8% is preferable, and 0.5 to 6% is more preferable. On the other hand, if the amount is too large, the texture tends to be heavy, which is not preferable.

加工澱粉は、馬鈴薯澱粉、コーンスターチ、ワキシーコーンスターチ、タピオカ澱粉等の澱粉に化学的処理を施したものである。本発明において加工澱粉としては、食用として供されているものを種々使用することができる。例えば、澱粉に無水酢酸と無水アジピン酸を作用させてエステル化したアセチル化アジピン酸架橋澱粉、澱粉にオキシ塩化リン又はトリメタリン酸ナトリウムを作用させ、さらに無水酢酸又は酢酸ビニルを作用させてエステル化したアセチル化リン酸架橋澱粉、澱粉に次亜塩素酸ナトリウムと無水酢酸を作用させてエステル化したアセチル化酸化澱粉、澱粉に無水オクテニルコハク酸を作用させてエステル化したオクテニルコハク酸澱粉ナトリウム、澱粉に無水酢酸又は酢酸ビニルを作用させてエステル化した酢酸澱粉、澱粉に次亜塩素酸ナトリウムを作用させた酸化澱粉、澱粉にプロピレンオキシドを作用させてエーテル化したヒドロキシプロピル澱粉、澱粉にプロピレンオキシドを作用させてエーテル化し、さらにオキシ塩化リン又はトリメタリン酸ナトリウムを作用させてエステル化したヒドロキシプロピル化リン酸架橋澱粉、澱粉にオキシ塩化リン又はトリメタリン酸ナトリウムを作用させてエステル化し、さらにオルトリン酸又はそのカリウム塩、ナトリウム塩、トリポリリン酸ナトリウムを作用させエステル化したリン酸モノエステル化リン酸架橋澱粉、澱粉にオルトリン酸又はそのカリウム塩、ナトリウム塩、トリポリリン酸ナトリウムを作用させエステル化したリン酸化澱粉、澱粉にオキシ塩化リン又はトリメタリン酸ナトリウムを作用させエステル化したリン酸架橋澱粉などが挙げられる。   The processed starch is obtained by subjecting starch such as potato starch, corn starch, waxy corn starch, tapioca starch or the like to chemical treatment. In the present invention, various processed starches can be used as food starch. For example, acetylated adipic acid cross-linked starch esterified by the action of acetic anhydride and adipic anhydride on starch, and esterified by the action of phosphorus oxychloride or sodium trimetaphosphate on starch and the action of acetic anhydride or vinyl acetate Cross-linked acetylated phosphate starch, acetylated oxidized starch esterified with sodium hypochlorite and acetic anhydride on starch, starch octenyl succinate sodium esterified with octenyl succinic anhydride on starch, acetic anhydride on starch Or starch acetate that has been esterified by the action of vinyl acetate, oxidized starch that has been treated with sodium hypochlorite on starch, hydroxypropyl starch that has been etherified by the action of propylene oxide on starch, or propylene oxide that has been treated with starch Etherification and further phosphorus oxychloride or toluene Hydroxypropylated phosphate cross-linked starch esterified by the action of sodium metaphosphate, esterified by the action of phosphorus oxychloride or sodium trimetaphosphate on the starch, and further the action of orthophosphoric acid or its potassium salt, sodium salt, sodium tripolyphosphate Esterified phosphoric acid monoesterified phosphoric acid crosslinked starch, phosphoric acid starch esterified by the action of orthophosphoric acid or its potassium salt, sodium salt, sodium tripolyphosphate on starch, phosphorus oxychloride or sodium trimetaphosphate acting on starch And esterified phosphoric acid cross-linked starch.

湿熱処理澱粉は、澱粉を湿熱処理したもので、例えば加熱しても糊化しない程度の水分を含む澱粉粒子を密閉容器中で相対湿度100%の条件下で約100〜125℃に加熱する方法、あるいは第1段階で澱粉を容器中に入れ密閉・減圧し、第2段階で生蒸気を容器内に導入し、加湿加熱する減圧加圧加熱法などにより得ることができる。湿熱処理澱粉としては、市販のものを使用することができる。   Wet heat-treated starch is a product obtained by heat-treating starch, for example, a method in which starch particles containing water that does not gelatinize even when heated are heated to about 100 to 125 ° C. in a sealed container at a relative humidity of 100%. Alternatively, it can be obtained by a reduced pressure and pressure heating method in which starch is placed in a container in the first stage and sealed and decompressed, and live steam is introduced into the container in the second stage and humidified and heated. As the wet heat-treated starch, a commercially available product can be used.

上述のDE12以下の澱粉分解物、加工澱粉及び湿熱処理澱粉の中でもヒドロキシプロピル澱粉、ヒドロキシプロピル化リン酸架橋澱粉などの加工澱粉が冷凍耐性を向上させる点で好ましい。   Among the above-mentioned starch degradation products of DE12 or lower, modified starches and wet-heat-treated starches, modified starches such as hydroxypropyl starch and hydroxypropylated phosphoric acid crosslinked starch are preferred in terms of improving the freezing resistance.

また、澱粉処理物の配合量は、DE12以下の澱粉分解物、加工澱粉及び湿熱処理澱粉の合計として、0.3〜15%が好ましく、0.5〜12%がより好ましい。澱粉処理物の配合量が少なすぎると、前述のように非溶解状態の澱粉粒子を分散させても冷凍耐性を十分に向上させることが難しく、反対に多すぎると、食感が重たくなる。   Further, the blended amount of the processed starch product is preferably 0.3 to 15%, more preferably 0.5 to 12%, as the total of starch degradation products of DE12 or less, processed starch, and wet heat-treated starch. If the blended amount of the starch processed product is too small, it is difficult to sufficiently improve the freezing resistance even if the non-dissolved starch particles are dispersed as described above, while if too much, the texture becomes heavy.

一方、水相に分散させる油滴は常温(15〜25℃)で液状の食用油脂から形成することが好ましい。常温で液状の食用油脂としては、菜種油、コーン油、綿実油、サフラワー油、オリーブ油、紅花油、大豆油等をあげることができる。常温で液状の食用油脂を使用することにより、パーム油等の常温で固体の食用油脂を使用する場合に比して油滴の粒子径をコントロールしやすくなる。   On the other hand, the oil droplets dispersed in the aqueous phase are preferably formed from edible oils and fats that are liquid at room temperature (15 to 25 ° C.). Examples of edible oils and fats that are liquid at room temperature include rapeseed oil, corn oil, cottonseed oil, safflower oil, olive oil, safflower oil, and soybean oil. By using liquid edible fats and oils at normal temperature, it becomes easy to control the particle diameter of oil droplets compared with the case of using solid edible fats and oils such as palm oil.

本発明の酸性水中油型乳化食品における油脂の配合割合は、当該油脂の種類にもよるが、冷凍耐性を十分に向上させる点から、50%以下が好ましく、より好ましくは40%以下である。油脂の配合割合が多いほど、冷凍と解凍により油脂が分離しやすくなるためである。また、油脂の配合量が少ないと冷凍と解凍による油脂の分離は生じにくくなるが、少なすぎると酸性水中油型乳化食品のコクがなくなるため、本発明においては、油脂の配合割合は5%以上が好ましい。   The blending ratio of fats and oils in the acidic oil-in-water emulsified food of the present invention is preferably 50% or less, more preferably 40% or less, from the viewpoint of sufficiently improving freezing resistance, although depending on the type of the fats and oils. This is because as the blending ratio of fats and oils increases, the fats and oils are easily separated by freezing and thawing. Also, if the amount of fat / oil is small, separation of the oil / fat due to freezing and thawing becomes difficult to occur, but if it is too small, the richness of the acidic oil-in-water emulsified food is lost, so in the present invention, the proportion of fat / oil is 5% or more. Is preferred.

また、本発明の酸性水中油型乳化食品では、油滴の平均粒子径を1〜20μmとし、油滴の平均粒子径と前述の澱粉粒子の平均粒子径との比が(5〜600)/100、好ましくは(5〜300)/100である。ここで、油滴の平均粒子径は、光学顕微鏡で酸性水中油型乳化食品を観察し、酸性水中油型乳化食品中の無作為に選択した100個の澱粉粒子について粒子径を測定し、その平均値を算出して得ることができる。油滴の平均粒子径が20μmよりも大きく、油滴の平均粒子径と前述の澱粉粒子の平均粒子径との比が600/100より大きくなると冷凍耐性を十分に向上させ難い場合があるので好ましくない。反対に、油滴の平均粒子径が1μmよりも小さく、かつ油滴の平均粒子径と前述の澱粉粒子の平均粒子径との比が5/100より小さくなると、微細な乳化状態とするための製造コストの上昇に見合うだけの耐冷凍性の向上効果が得られ難いので好ましくない。   Moreover, in the acidic oil-in-water emulsified food of the present invention, the average particle size of oil droplets is 1 to 20 μm, and the ratio of the average particle size of oil droplets to the average particle size of the above-mentioned starch particles is (5-600) / 100, preferably (5-300) / 100. Here, the average particle diameter of the oil droplets was measured with an optical oil microscope to observe the acid oil-in-water emulsified food, and the particle diameter was measured for 100 randomly selected starch particles in the acid oil-in-water emulsified food. An average value can be calculated and obtained. If the average particle size of the oil droplets is larger than 20 μm and the ratio of the average particle size of the oil droplets to the average particle size of the aforementioned starch particles is larger than 600/100, it may be difficult to sufficiently improve the freezing resistance. Absent. On the other hand, when the average particle diameter of the oil droplets is smaller than 1 μm and the ratio of the average particle diameter of the oil droplets to the average particle diameter of the starch particles is smaller than 5/100, a fine emulsified state is obtained. This is not preferable because it is difficult to obtain the effect of improving the freezing resistance enough to meet the increase in manufacturing cost.

なお、油滴の粒子径をこのように調整する方法としては、食用油脂を乳化するときのミキサーの種類、撹拌条件、乳化材の添加順序などを調整する方法等をあげることができる。   In addition, as a method of adjusting the particle diameter of the oil droplet in this way, a method of adjusting the kind of mixer when emulsifying the edible oil and fat, the stirring conditions, the order of adding the emulsifying material, and the like can be given.

本発明の酸性水中油型乳化食品は、乳化材として、卵黄、全卵、液卵白、乾燥卵白、乳蛋白、レシチン、グリセリン脂肪酸エステル、ポリグリセリン脂肪酸エステル、ショ糖脂肪酸エステル、ソルビタン脂肪酸エステル、オクテニルコハク酸化澱粉などを含有することができる。ここで、卵黄としては、例えば、鶏卵を割卵し卵白と分離して得られた生卵黄、当該生卵黄に殺菌処理、冷凍処理、濾過処理、スプレードライ又はフリーズドライ等の乾燥処理、ホスフォリパーゼ又はプロテアーゼ等による酵素処理、酵母またはグルコースオキシダーゼ等による脱糖処理、超臨界二酸化炭素処理又は亜臨界二酸化炭素処理等の脱コレステロール処理、食塩又は糖類等の混合処理等の1種または2種以上の処理を施したもの等が挙げられる。また、本発明の酸性水中油型乳化食品に卵黄を含有させる態様としては、鶏卵を割卵して得られる全卵、もしくは卵黄と卵白とを任意の割合で混合したもの、又はこれらに上述の処理を施したもの等を含有させる態様をあげることができる。   The acidic oil-in-water emulsified food according to the present invention contains, as an emulsifier, egg yolk, whole egg, liquid egg white, dried egg white, milk protein, lecithin, glycerin fatty acid ester, polyglycerin fatty acid ester, sucrose fatty acid ester, sorbitan fatty acid ester, octenyl succinate Oxidized starch and the like can be contained. Here, as the egg yolk, for example, raw egg yolk obtained by dividing a chicken egg and separating it from egg white, the raw egg yolk is subjected to sterilization treatment, freezing treatment, filtration treatment, drying treatment such as spray drying or freeze drying, phosphor One or more kinds of enzyme treatment with lipase or protease, desugaring treatment with yeast or glucose oxidase, decholesterolization treatment such as supercritical carbon dioxide treatment or subcritical carbon dioxide treatment, mixed treatment with salt or saccharide, etc. The thing etc. which performed the process of these are mentioned. Moreover, as an aspect to contain egg yolk in the acidic oil-in-water emulsified food of the present invention, whole egg obtained by breaking chicken eggs, or a mixture of egg yolk and egg white in an arbitrary ratio, or the above-mentioned An embodiment in which a treated product or the like is contained can be given.

乾燥卵白とは、液卵白を、例えば、噴霧乾燥(スプレードライ)、静置乾燥(パンドライ)、凍結乾燥(フリーズドライ)、真空乾燥等の種々の方法で乾燥したものである。これら乾燥卵白の中でも、本発明においては、熱蔵処理を施した乾燥卵白、好ましくは65〜120℃で1〜20日程度熱蔵処理を施した乾燥卵白を用いると、酸性水中油型乳化食品の解凍後にも安定した乳化状態を保持する冷凍耐性がより向上するので好ましい。なお、上述の熱蔵処理は常法により行うことができる。   Dry egg white is obtained by drying liquid egg white by various methods such as spray drying (spray drying), standing drying (pan drying), freeze drying (freeze drying), and vacuum drying. Among these dried egg whites, in the present invention, when using dried egg white that has been heat-treated, preferably 65 to 120 ° C. for about 1 to 20 days, acid oil-in-water emulsified food Since the freezing tolerance which maintains the stable emulsified state after thawing | decompression of this improves more, it is preferable. In addition, the above-mentioned heat storage process can be performed by a conventional method.

上記乾燥卵白の原料となる液卵白としては、例えば、卵を割卵して卵黄と分離した生液卵白、これにろ過、殺菌、冷凍、濃縮等の処理を施したものの他、卵白中の特定の成分を除去する処理、例えば、糖分を除去する脱糖処理やリゾチームを除去する処理を行ったもの等を用いることができる。これらの液卵白のなかでも、脱糖処理を行った液卵白を用いることが好ましい。脱糖処理を行わないと、上述した熱蔵処理中に卵白タンパク質中のアミノ基と遊離の糖がメイラード反応を起こし、褐変、不快臭の発生等により品質低下がもたらされる場合があるためである。ここで、脱糖処理は、酵母、酵素、細菌等を用いて常法により行えばよく、液卵白中の遊離の糖含有率が0.1%以下となるように行うことが好ましい。   Examples of the liquid egg white used as the raw material of the dried egg white include, for example, a raw liquid egg white obtained by splitting an egg and separating it from an egg yolk, and those subjected to filtration, sterilization, freezing, concentration, etc. For example, a product that has been subjected to a treatment for removing the above components, for example, a desugaring treatment for removing a sugar content or a treatment for removing lysozyme can be used. Among these liquid egg whites, it is preferable to use liquid egg whites subjected to desugaring treatment. If the desugaring treatment is not performed, the amino group in egg white protein and free sugar cause a Maillard reaction during the above-mentioned heat storage treatment, and browning, generation of unpleasant odor, etc. may result in quality deterioration. . Here, the desugaring treatment may be performed by a conventional method using yeast, enzyme, bacteria, or the like, and is preferably performed so that the free sugar content in the liquid egg white is 0.1% or less.

乳蛋白としては、公知の乳蛋白、例えば、ホエー蛋白、カゼイン、それらの塩(例えば、ナトリウム塩、カリウム塩、カルシウム塩、アンモニウム塩等)あるいは乳蛋白の加水分解物等の一種以上を使用することができる。   As the milk protein, one or more known milk proteins such as whey protein, casein, salts thereof (for example, sodium salt, potassium salt, calcium salt, ammonium salt, etc.) or a hydrolyzate of milk protein are used. be able to.

これらの乳化材の中でも、冷凍耐性向上の点から、卵黄と、乾燥卵白及び/又は乳蛋白を併用することがより好ましい。   Among these emulsifiers, it is more preferable to use egg yolk together with dried egg white and / or milk protein from the viewpoint of improving freezing resistance.

また、本発明の酸性水中油型乳化食品は、酸性水中油型乳化食品に通常用いられている各種原料を適宜選択して含有させることができる。例えば、食酢、クエン酸、乳酸、レモン果汁などの酸味材、グルタミン酸ナトリウム、食塩、砂糖などの各種調味料、動植物のエキス類、からし粉、胡椒などの香辛料、並びに各種蛋白質やこれらの分解物等をあげることができる。   Moreover, the acidic oil-in-water emulsified food of the present invention can contain various raw materials usually used in acidic oil-in-water emulsified foods as appropriate. For example, sour materials such as vinegar, citric acid, lactic acid, lemon juice, various seasonings such as sodium glutamate, salt and sugar, extracts of animals and plants, spices such as mustard powder and pepper, various proteins and their degradation products Etc.

本発明の酸性水中油型乳化食品は、常温で水相に非溶解状態で分散する澱粉を水相又は油相に分散し、常法により水相原料と油相原料を混合乳化することにより、あるいは水相と油相を乳化混合後に、常温で水相に非溶解状態となる澱粉を混合分散させることにより、製造することができるが、その際、澱粉を非溶解状態で分散させている水相は、その澱粉を完全には溶解しない温度以下で酸性水中油型乳化食品を製造する。即ち、常温非溶解性、好ましくは前述の加熱溶解性の澱粉を、予め水相に分散させた後、その水相と油相と混合乳化しても、その澱粉を予め油相に分散させた後、その油相を水相と混合乳化しても、混合乳化後には、澱粉は水相で分散するので、水相に澱粉が非溶解状態で分散している本発明の酸性水中油型乳化食品を製造するためには、水相と油相との混合前に、澱粉は、水相に分散させても油相に分散させてもよい。また、水相と油相を混合分散させた後の乳化物に常温非溶解性の澱粉を添加し分散させてもよく、それによっても澱粉は水相に分散する。いずれの場合においても、水相に澱粉が非溶解状態で分散している状態では、その水相を澱粉が完全に溶解する温度には加温しないようにする。なお、ガム質が油相に分散している状態では、その油相を加熱してもガム質は溶解もゾル化もしない。   The acidic oil-in-water emulsified food of the present invention is obtained by dispersing starch dispersed in an aqueous phase in an aqueous phase at room temperature in an aqueous phase or an oil phase, and mixing and emulsifying an aqueous phase raw material and an oil phase raw material by a conventional method, Alternatively, after emulsifying and mixing the aqueous phase and the oil phase, it can be produced by mixing and dispersing starch that is insoluble in the aqueous phase at room temperature. At that time, water in which the starch is dispersed in an insoluble state The phase produces an acidic oil-in-water emulsified food at a temperature that does not completely dissolve the starch. That is, normal temperature insoluble starch, preferably the aforementioned heat-soluble starch, is dispersed in the aqueous phase in advance, and then the aqueous phase and the oil phase are mixed and emulsified, so that the starch is dispersed in the oil phase in advance. Later, even if the oil phase is mixed and emulsified with the aqueous phase, after the mixed emulsification, the starch is dispersed in the aqueous phase, so the starch is dispersed in the aqueous phase in an undissolved state. In order to produce a food product, the starch may be dispersed in the aqueous phase or the oil phase before mixing the aqueous phase and the oil phase. Moreover, normal temperature insoluble starch may be added and dispersed in the emulsion after the aqueous phase and the oil phase are mixed and dispersed, whereby the starch is also dispersed in the aqueous phase. In any case, when the starch is dispersed in the water phase in an undissolved state, the aqueous phase is not heated to a temperature at which the starch is completely dissolved. In the state where the gum is dispersed in the oil phase, the gum does not dissolve or sol even if the oil phase is heated.

本発明の酸性水中油型乳化食品の製造方法としては、より具体的には、例えば、水相原料として、常温非溶解性の澱粉、好ましくは前述の加熱溶解性の澱粉、乳化材及び調味料を、通常60℃以上に加熱することなく均一に混合し、ミキサー等で撹拌しながら油相原料を注加して粗乳化し、次にコロイドミルなどで仕上げ乳化をした後、ボトル容器やガラス容器などに充填密封する。   More specifically, the method for producing an acidic oil-in-water emulsified food of the present invention includes, for example, a normal temperature insoluble starch, preferably the aforementioned heat-soluble starch, an emulsifying material, and a seasoning as an aqueous phase material. Are normally mixed without heating to 60 ° C. or higher, and the oil phase raw material is poured and coarsely emulsified while stirring with a mixer or the like, then subjected to final emulsification with a colloid mill or the like, and then a bottle container or glass. Fill and seal the container.

実施例1〜3及び比較例1〜4
(1)酸性水中油型乳化食品の製造
表1に示す配合割合で仕上がり100kgの酸性水中油型乳化食品を製した。ここで、表1の架橋澱粉としては、ワキシーコーンスターチを原料とした架橋澱粉(商品名「ファリネックスVA70WM」、松谷化学工業株式会社製)、タピオカ架橋澱粉(タピオカ澱粉を原料とした架橋澱粉(商品名「フードスターチHR−7」、松谷化学工業株式会社製)を使用し、実施例2及び3では、これら架橋澱粉を予め清水に分散し、90℃に加熱して冷却したものを澱粉として使用した。
比較例2では、澱粉として、加熱溶解性米澱粉を予め清水に分散し、90℃に加熱溶解して澱粉粒子を消失させた後、冷却したものを使用した。
比較例3では、澱粉粒子の大きさを変えるために馬鈴薯澱粉を用いた。
また、実施例1〜3及び比較例1〜4では、乳蛋白としてホエー蛋白を用いた。
Examples 1-3 and Comparative Examples 1-4
(1) Manufacture of acidic oil-in-water emulsified food 100 kg of acidic oil-in-water emulsified food finished at the blending ratio shown in Table 1 was produced. Here, as the cross-linked starch of Table 1, cross-linked starch made from waxy corn starch (trade name “FARINEX VA70WM”, manufactured by Matsutani Chemical Industry Co., Ltd.), tapioca cross-linked starch (cross-linked starch made from tapioca starch (product) The names “Food Starch HR-7” (manufactured by Matsutani Chemical Industry Co., Ltd.) were used. In Examples 2 and 3, these crosslinked starches were dispersed in fresh water in advance, heated to 90 ° C. and cooled, and used as starch. did.
In Comparative Example 2, as the starch, heat-dissolved rice starch was dispersed in fresh water in advance, dissolved by heating at 90 ° C. to disappear the starch particles, and then cooled.
In Comparative Example 3, potato starch was used to change the size of the starch particles.
In Examples 1 to 3 and Comparative Examples 1 to 4, whey protein was used as milk protein.

酸性水中油型乳化食品の調製方法としては、澱粉処理物を含有させる場合、まず、これらを清水に分散させ、加熱により糊化させた後(品温
90℃)、冷却して糊化澱粉液(品温 20℃)を調製した。澱粉処理物を使用しない場合には、糊化澱粉液の調製を省略して同様に水相部を調製した。この糊化澱粉液と澱粉と植物油以外の原料をミキサーで均一に混合し水相部を調製した。次いで、この水相部を撹拌しながら菜種サラダ油を徐々に注加して粗乳化物を製した。そして、得られた粗乳化物をコロイドミルで仕上げ乳化し、200mL容量のナイロンポリ袋に150gずつ充填密封した。
比較例4では、油滴径の大きさを変化させるために仕上げ乳化を行わなかった。
As a method for preparing an acidic oil-in-water emulsified food, when containing a starch processed product, first, these are dispersed in fresh water, gelatinized by heating (product temperature 90 ° C.), then cooled and gelatinized starch solution (Product temperature 20 ° C.) was prepared. When the processed starch product was not used, the preparation of the gelatinized starch solution was omitted and the aqueous phase portion was similarly prepared. Raw materials other than the gelatinized starch solution, starch and vegetable oil were uniformly mixed with a mixer to prepare an aqueous phase part. Next, rapeseed salad oil was gradually added while stirring the aqueous phase to prepare a crude emulsion. Then, the obtained coarse emulsion was finished and emulsified with a colloid mill, and 150 g each was filled and sealed in a 200 mL capacity nylon plastic bag.
In Comparative Example 4, final emulsification was not performed in order to change the size of the oil droplet diameter.

(2)評価
(1)で得た酸性水中油型乳化食品について、冷凍耐性の評価、非溶解状態の澱粉粒子の有無の確認、非溶解状態の澱粉粒子の平均粒子径の計測、油滴粒子の平均粒子径の計測を次のように行い、さらに、澱粉粒子の平均粒子径100に対する油滴の平均粒子径の比を算出した。また、食感も次のように評価した。これらの結果を表1に示す。
(2) Evaluation Regarding the acidic oil-in-water emulsified food obtained in (1), evaluation of freezing resistance, confirmation of the presence or absence of undissolved starch particles, measurement of the average particle diameter of undissolved starch particles, oil droplet particles The average particle diameter was measured as follows, and the ratio of the average particle diameter of the oil droplets to the average particle diameter 100 of the starch particles was calculated. The texture was also evaluated as follows. These results are shown in Table 1.

(2-1)冷凍耐性
(1)で得た酸性水中油型乳化食品を、ナイロンポリ袋に充填密封したまま、−20℃の冷凍庫中で2ヵ月間保存し、その後25℃の室内で8時間以上静置し、解凍後の状態を目視観察し、油分離の有無により次の基準で冷凍耐性を評価した。
(2-1) Freezing resistance The acidic oil-in-water emulsified food obtained in (1) is stored for 2 months in a -20 ° C freezer while being filled and sealed in a nylon plastic bag. It left still for more than time, the state after thawing | decompression was visually observed, and the freezing tolerance was evaluated on the following reference | standard by the presence or absence of oil separation.

−:油分離なし
±:表面にわずかににじむ程度の油分離が観察される
+:表面に若干の油分離が観察される
++:著しい油分離が観察される
-: No oil separation ±: A slight oil separation is observed on the surface +: A slight oil separation is observed on the surface ++: A remarkable oil separation is observed

(2-2)澱粉粒子の観察
(1)で得た酸性水中油型乳化食品にヨウ素を添加して澱粉を染色し、光学顕微鏡で観察(倍率:1000倍)し、ヨウ素で染色された澱粉粒子の有無を確認した。実施例1、比較例2の顕微鏡写真を図1、図2に示す。
なお、実施例1の酸性水中油型乳化食品を80℃で10分間加熱したものについても同様に顕微鏡で観察した。その結果、澱粉粒子を確認することができなかったため、非溶解状態で分散していた澱粉粒子が溶解したことがわかる。
(2-2) Observation of starch particles Addition of iodine to the acidic oil-in-water emulsified food obtained in (1) to stain starch, observation with an optical microscope (magnification: 1000 times), starch stained with iodine The presence or absence of particles was confirmed. The micrographs of Example 1 and Comparative Example 2 are shown in FIGS.
In addition, what heated the acidic oil-in-water type emulsified foodstuff of Example 1 for 10 minutes at 80 degreeC was similarly observed with the microscope. As a result, since starch particles could not be confirmed, it can be seen that starch particles dispersed in a non-dissolved state were dissolved.

(2-3)澱粉粒子の平均粒子径
(2-2)で澱粉粒子が観察されたものについては、無作為に選択した100個の澱粉粒子について、粒子径を計測し、その平均値を求めた。この場合、5μm以下の粒子は1μm目盛りのスケールで粒子径を計測し、5μmを超える粒子は5μm目盛りのスケールで粒子径を計測した。
(2-3) Average particle size of starch particles For those in which starch particles were observed in (2-2), the particle size was measured for 100 randomly selected starch particles, and the average value was obtained. It was. In this case, the particle diameter of a particle of 5 μm or less was measured on a scale of 1 μm, and the particle diameter of a particle exceeding 5 μm was measured on a scale of 5 μm.

(2-4)油滴の平均粒子径
(1)で得た酸性水中油型乳化食品について光学顕微鏡で観察(倍率:2000倍)し、無作為に選択した100個の油滴について1μm目盛りのスケールで粒子径を計測し、その平均値を求めた。
(2-4) Average particle size of oil droplets The acid oil-in-water emulsified food obtained in (1) was observed with an optical microscope (magnification: 2000 times), and 100 oil droplets randomly selected were scaled 1 μm. The particle diameter was measured with a scale, and the average value was obtained.

(2-5)食感
(2-1)で冷凍耐性を評価した酸性水中油型乳化食品について、食感を次の基準により評価した。
○:ざらつきもなく口当たりがよい
△:少しざらつき感がある
×:ざらつき感がある
(2-5) The texture of the acidic oil-in-water emulsified food whose freezing resistance was evaluated in the texture (2-1) was evaluated according to the following criteria.
○: Feeling good without any roughness △: Feeling a little rough ×: Feeling rough

Figure 2012002303
Figure 2012002303

表1から、澱粉粒子が非溶解状態で分散していると(実施例1〜3)冷凍耐性が良好であること、これに対し澱粉が常温溶解性である場合(比較例1)あるいは澱粉が予め加熱されることにより溶解し、水相に非溶解状態の粒子が残存していない場合(比較例2)では冷凍耐性が劣ることがわかる。
また、実施例1と比較例3から、澱粉粒子の平均粒子径が3〜60μmの範囲にあると冷凍耐性が良好であることがわかり、実施例1と比較例4から、油相平均粒子径と澱粉平均粒子径との比が(5〜600)/100の範囲にあると冷凍耐性が良好であることがわかる。
From Table 1, when starch particles are dispersed in an undissolved state (Examples 1 to 3), the freezing resistance is good, whereas when starch is soluble at room temperature (Comparative Example 1) or starch It can be seen that the refrigeration resistance is inferior when the particles are dissolved by heating in advance and no undissolved particles remain in the aqueous phase (Comparative Example 2).
Moreover, it turns out from Example 1 and Comparative Example 3 that the freezing tolerance is good when the average particle diameter of the starch particles is in the range of 3 to 60 μm. From Example 1 and Comparative Example 4, the oil phase average particle diameter is It can be seen that the freezing resistance is good when the ratio of the average particle size of starch and starch is in the range of (5-600) / 100.

試験例1-1〜1-4
澱粉処理物の添加が冷凍耐性に及ぼす影響を調べるため、表1に示すように、実施例1の組成に対して澱粉処理物の種類と配合量を異ならせた以外は実施例1と同様にして酸性水中油型乳化食品を製造し、実施例1と同様に評価した。結果を表1に示す。
表1から、水相に、加工澱粉(ヒドロキシプロピル)澱粉、DE12以下の澱粉分解物、又は湿熱処理澱粉を溶解した場合は、馬鈴薯澱粉を溶解した場合に比べて冷凍耐性が向上することがわかる。
Test Examples 1-1 to 1-4
In order to examine the effect of the addition of the processed starch on the freezing resistance, as shown in Table 1, as in Example 1, except that the type and blending amount of the processed starch are different from the composition of Example 1. Then, an acidic oil-in-water emulsified food was produced and evaluated in the same manner as in Example 1. The results are shown in Table 1.
From Table 1, it can be seen that when the processed starch (hydroxypropyl) starch, the starch degradation product of DE12 or less, or the wet heat-treated starch is dissolved in the aqueous phase, the freezing resistance is improved as compared with the case where the potato starch is dissolved. .

試験例2-1〜2-3
乳化材の種類が冷凍耐性に及ぼす影響を調べるため、表1に示すように、乳蛋白又は乾燥卵白の配合を異ならせた。即ち、試験例2-1では、乳蛋白としてカゼインを用いた。試験例2-2では、乾燥卵白として、糖含有率が0.1%以下となるように脱糖した液卵白を噴霧乾燥し、75℃で2週間熱蔵した乾燥卵白(pH10)を用いた。
表1から、乳化材として乳蛋白も乾燥卵白も含まない場合(試験例2-3)は、冷凍耐性が劣ることがわかる。
Test examples 2-1 to 2-3
In order to investigate the effect of the type of emulsifier on freezing tolerance, the composition of milk protein or dried egg white was varied as shown in Table 1. That is, in Test Example 2-1, casein was used as milk protein. In Test Example 2-2, dry egg white (pH 10) that was spray-dried and dried at 75 ° C. for 2 weeks was used as the dried egg white. .
From Table 1, it can be seen that when the emulsion material contains neither milk protein nor dried egg white (Test Example 2-3), the freezing resistance is inferior.

Claims (6)

水相に、非溶解状態の澱粉粒子と油滴が分散している酸性水中油型乳化食品であって、
澱粉粒子の平均粒子径が3〜60μm、
油滴の平均粒子径が1〜20μm、
油滴の平均粒子径と澱粉粒子の平均粒子径との比が(5〜600)/100
である酸性水中油型乳化食品。
An acidic oil-in-water emulsified food in which starch particles and oil droplets in an undissolved state are dispersed in an aqueous phase,
The average particle size of the starch particles is 3-60 μm,
The average particle size of the oil droplets is 1-20 μm,
The ratio of the average particle size of oil droplets to the average particle size of starch particles is (5-600) / 100
An acidic oil-in-water emulsified food.
澱粉粒子が、常温で水に不溶性又は難溶性の澱粉もしくは架橋澱粉の粒子である請求項1記載の酸性水中油型乳化食品。   The acidic oil-in-water emulsified food according to claim 1, wherein the starch particles are particles of starch or crosslinked starch that are insoluble or hardly soluble in water at room temperature. 水相に、DE(dextrose equivalent)12以下の澱粉分解物、加工澱粉及び湿熱処理澱粉から選ばれる1種以上の澱粉処理物を溶解状態で含有する請求項1又は2記載の酸性水中油型乳化食品。   3. The acidic oil-in-water emulsification according to claim 1, wherein the aqueous phase contains one or more starch processed products selected from starch decomposed products having a DE (dextrose equivalent) of 12 or less, processed starches and wet heat-treated starches in a dissolved state. Food. 乳化材として卵黄と、乾燥卵白及び/又は乳蛋白を含有する請求項1〜3のいずれかに記載の酸性水中油型乳化食品。   The acidic oil-in-water emulsified food according to any one of claims 1 to 3, comprising egg yolk and dried egg white and / or milk protein as the emulsifying material. 請求項1〜4のいずれかに記載の酸性水中油型乳化食品の製造方法であって、澱粉粒子が分散した水相の温度を、該澱粉粒子が完全には溶解しない温度以下とする酸性水中油型乳化食品の製造方法。   The method for producing an acidic oil-in-water emulsified food according to any one of claims 1 to 4, wherein the temperature of the aqueous phase in which the starch particles are dispersed is not higher than the temperature at which the starch particles are not completely dissolved. A method for producing an oil-type emulsified food. 澱粉粒子を水相に分散した状態で60℃以上に加熱することなく製造する請求項5記載の酸性水中油型乳化食品の製造方法。
The method for producing an acidic oil-in-water emulsified food according to claim 5, wherein the starch particles are produced in a state dispersed in an aqueous phase without being heated to 60 ° C or higher.
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