JPWO2010070874A1 - Additive oil and fat composition, chocolate using the same, and method for producing the same - Google Patents

Additive oil and fat composition, chocolate using the same, and method for producing the same Download PDF

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JPWO2010070874A1
JPWO2010070874A1 JP2010542868A JP2010542868A JPWO2010070874A1 JP WO2010070874 A1 JPWO2010070874 A1 JP WO2010070874A1 JP 2010542868 A JP2010542868 A JP 2010542868A JP 2010542868 A JP2010542868 A JP 2010542868A JP WO2010070874 A1 JPWO2010070874 A1 JP WO2010070874A1
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oil
chocolates
chocolate
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fat
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JP5625913B2 (en
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弘志 狩野
弘志 狩野
雅子 大河内
雅子 大河内
松井 正行
正行 松井
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Fuji Oil Co Ltd
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    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23DEDIBLE OILS OR FATS, e.g. MARGARINES, SHORTENINGS, COOKING OILS
    • A23D9/00Other edible oils or fats, e.g. shortenings, cooking oils
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23DEDIBLE OILS OR FATS, e.g. MARGARINES, SHORTENINGS, COOKING OILS
    • A23D9/00Other edible oils or fats, e.g. shortenings, cooking oils
    • A23D9/02Other edible oils or fats, e.g. shortenings, cooking oils characterised by the production or working-up
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23GCOCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G1/00Cocoa; Cocoa products, e.g. chocolate; Substitutes therefor
    • A23G1/30Cocoa products, e.g. chocolate; Substitutes therefor
    • A23G1/32Cocoa products, e.g. chocolate; Substitutes therefor characterised by the composition containing organic or inorganic compounds
    • A23G1/36Cocoa products, e.g. chocolate; Substitutes therefor characterised by the composition containing organic or inorganic compounds characterised by the fats used
    • A23G1/38Cocoa butter substitutes
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11CFATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
    • C11C3/00Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom
    • C11C3/04Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom by esterification of fats or fatty oils
    • C11C3/08Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom by esterification of fats or fatty oils with fatty acids

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Food Science & Technology (AREA)
  • Polymers & Plastics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Confectionery (AREA)
  • Edible Oils And Fats (AREA)

Abstract

本発明の目的は、ロウのような口溶けの悪さ(ワキシー感と称する)や、液油の多いチョコレート類にありがちな液油が口腔中に膜を張ったような油性感(オイリー感)をおさえつつ、単に物性的な可塑性やソフト感のみではなく、生チョコレートのようにもったりとした特異的な口溶けを有するチョコレート類と概チョコレート類に用いられるハードバターを提供する事にある。本発明者らは鋭意研究を行った結果、チョコレート類に含まれる油脂中にLU2型(Lは炭素数20以上の長鎖飽和脂肪酸、Uは炭素数18の不飽和脂肪酸)トリアシルグリセロール(以降TGと称す)を1〜35重量%含むことで、あるいはそのチョコレート類を得るにあたってLU2型TGを10重量%以上含有する油脂組成物a、または油脂組成物aを5〜100重量%以上含む油脂組成物Aをチョコレート類に5〜60重量%添加することで、単に物性的な可塑性やソフト感のみではなく、生チョコレートのようにもったりとした特異的な口溶けを有するチョコレート類と概チョコレート類に用いられるハードバターが得られる。The object of the present invention is to suppress the poor melting of the mouth (referred to as waxy feeling) such as wax, and the oily feeling (oily feeling) that the liquid oil, which is often found in chocolates with a lot of liquid oil, stretches the film in the oral cavity. On the other hand, the object is to provide hard butter that is used not only for physical plasticity and soft feeling but also for chocolates having a specific mouth melting like raw chocolate and almost chocolates. As a result of intensive studies, the present inventors have found that LU2 type (L is a long-chain saturated fatty acid having 20 or more carbon atoms, U is an unsaturated fatty acid having 18 carbon atoms), triacylglycerol (hereinafter referred to as “oil”) contained in chocolates. (Referred to as TG) in an amount of 1 to 35% by weight, or an oil / fat composition a containing 10% by weight or more of LU2-type TG, or an oil / fat containing 5 to 100% by weight or more of an oil / fat composition a in obtaining the chocolate By adding 5 to 60% by weight of the composition A to chocolates, chocolates and general chocolates having a specific mouth melting that is not only physical plasticity and soft feeling but also like raw chocolate Hard butter used in the above is obtained.

Description

本発明は、チョコレートに代表されるチョコレート類に関し、ある特定の油脂を添加することで、特に特異な口溶け感を有するチョコレート類を提供する添加油脂に関する。   The present invention relates to chocolates typified by chocolate, and particularly to added fats and oils that provide chocolates having a particular mouth melting feeling by adding certain fats and oils.

代表的な油性菓子である、チョコレート類は、典型的には、カカオマス、ココアバター、砂糖、粉乳等から製造される。ココアバターは主としてPOSt、StOSt、POP(ただし、P:パルミチン酸、O:オレイン酸、St:ステアリン酸)といった1,3位飽和、2位不飽和のトリアシルグリセロール(以下TG)よりなり、単独菓子として食される典型的チョコレート中に約32重量%存在する。また、チョコレートの物性改良や製造コストの節約の目的にて、ココアバターの一部または全部に代えて他の油脂(ハードバター)がしばしば使用され、ハードバターは主としてCBEと称される1,3位飽和、2位不飽和の対称型トリアシルグリセロールに富むものと、CBRと称されるラウリン系もしくは高エライジン酸タイプのものがある。また無脂カカオ固形分をほとんど用いない、所謂ホワイトチョコレート類もある(以下においてチョコレート類というときは、各国などの法令や規格に規定にかかわらず、所謂準チョコレート等も包含して指称する)。   Chocolate, which is a typical oily confectionery, is typically manufactured from cocoa mass, cocoa butter, sugar, powdered milk, and the like. Cocoa butter is mainly composed of 1,3-saturated, 2-saturated triacylglycerol (hereinafter referred to as TG) such as POSt, StOSt, POP (where P: palmitic acid, O: oleic acid, St: stearic acid) It is present at about 32% by weight in typical chocolate eaten as a confectionery. In addition, other fats and oils (hard butter) are often used instead of part or all of cocoa butter for the purpose of improving the physical properties of chocolate and saving manufacturing costs, and hard butter is mainly referred to as CBE 1,3. There are abundant in saturated triacylglycerol which is saturated with 2 and 2-position unsaturated, and a lauric or highly elaidic acid type called CBR. There are also so-called white chocolates that use almost no fat-free cocoa solids (hereinafter referred to as chocolates, including so-called quasi-chocolates, etc., regardless of the laws and standards of each country).

かかるハードバターは、主としてカカオ脂を主成分とするチョコレート本来の性質である、常温で固くスナップ性が良好で体温付近で急激に溶解する口溶けの良さ、室温或いは気温の変化により溶融することのない耐熱保型性、テンパリング処理中に異常な粘度上昇を起こさない作業性の良さ等に着目してカカオ脂類似の特性を持つよう設計されていたり、さらには、カカオ脂の欠点であるブルーム耐性を補強した、耐熱保型性を強化する機能を一般的に有している。   Such hard butter is an inherent property of chocolate mainly composed of cacao butter, hard at room temperature, good snapping properties, good melting in the mouth that dissolves rapidly around body temperature, and does not melt due to changes in room temperature or temperature Designed to have cocoa butter-like properties, focusing on heat-resistant moldability, good workability that does not cause an abnormal increase in viscosity during tempering treatment, and bloom resistance, which is a drawback of cocoa butter Reinforced and generally has a function of enhancing heat-resistant shape retention.

しかしながら、最近の消費者嗜好の多様化に伴い、さまざまな物性や機能を有するチョコレート類並びにその機能を具現化させるためのハードバターが検討されている。   However, with recent diversification of consumer preferences, chocolates having various physical properties and functions and hard butters for realizing the functions are being studied.

例えば、チョコレートに生クリームといった水相を加えた、所謂「生チョコレート」やガナッシュと称されるものは、本来のチョコレート類とは異なり、口腔内でもったりと溶ける物性があり、嗜好性の高いものである。しかしながら、「生チョコレート」はチョコレート類(以降単にチョコレート類と記載した場合は水分が5重量%未満のものを指す)に比べ保存性が劣り、またその流通もチョコレートよりもさらにデリケートな温度管理や品質管理が必要とされる場合が多い。   For example, so-called “raw chocolate” or ganache, which is made by adding an aqueous phase such as fresh cream to chocolate, is different from the original chocolates and has physical properties that melt easily in the oral cavity, and has high palatability Is. However, “raw chocolate” is inferior in storage stability compared to chocolates (hereinafter referred to simply as “chocolate” means that the moisture content is less than 5% by weight), and its distribution is more delicate than chocolate. Quality control is often required.

また、LUSトリアシルグリセロール(この発明においては、Lは、C20:0、C22:0、C24:0を、Uは、C18:1、C18:2を、Sは、C4:0脂肪酸を意味する。)を50%以上含有し、構成脂肪酸炭素数の総和が、40以下のトリアシルグリセロールが10%未満、56以上のトリアシルグリセロールが35%未満であることを特徴とする可塑性油脂および、本可塑性油脂を実質的な油脂分とするチョコレートが提案されており、これにより、テンパリング操作がいらず、成形性・可塑性に優れ、風味、食感が良好で手指へのべとつきがないチョコレートを得ることができたとされている。(特許文献1)   Also, LUS triacylglycerol (in this invention, L means C20: 0, C22: 0, C24: 0, U means C18: 1, C18: 2, and S means C4: 0 fatty acid. )), And the total number of constituent fatty acid carbon atoms is less than 10% for triacylglycerols of 40 or less, and less than 35% for triacylglycerols of 56 or more, and A chocolate with a substantial amount of plastic oil and fat has been proposed. By doing this, a tempering operation is not required, the moldability and plasticity are excellent, the flavor and texture are good, and there is no stickiness on the fingers. It is said that it was possible. (Patent Document 1)

さらに、チョコレート油分中、ジ飽和モノ不飽和グリセロール(S2U)10−85%、ジ不飽和モノ飽和グリセリド(SU2)及びトリ不飽和グリセロール(U3)の合計を15−90%含有し、ジ飽和モノ不飽和グリセリド(S2U)中ジ飽和モノリノレート(S2L、ただしこの発明においては、Sは飽和脂肪酸、Uは不飽和脂肪酸、Lはリノール酸を意味する。)が35% 以上であるチョコレートが提案されており、これによると曲げに対する生地破損性に耐性があり、成形性やソフト感に優れており、また乾きが早いとされている。(特許文献2)
他にも、チョコレート生地の油脂成分に対して、構成脂肪酸算基の炭素数が合計58以上のトリアシルグリセロールを0.5〜15.0重量%を含有することを特徴するチョコレートが提案されており、これによると簡易的条件下で、均一且つ微細な気泡が保持され、外力によって型崩れを起こしにくい気泡入りチョコレートが製造でき、しかも食したときに優れたライト感、冷涼間を発現するとされている。(特許文献3)
しかしながら、上記3つの発明ともに、チョコレートに気泡性や可塑性、ソフト感こそはあるが、生チョコレートのような口溶けなどについては触れられていない。
Further, the chocolate oil contains 15-90% of di-saturated monounsaturated glycerol (S2U) 10-85%, di-unsaturated monosaturated glyceride (SU2) and tri-unsaturated glycerol (U3). A chocolate having a disaturated monolinoleate (S2L, where, in this invention, S represents a saturated fatty acid, U represents an unsaturated fatty acid, and L represents linoleic acid) in the unsaturated glyceride (S2U) is 35% or more. According to this, it is said that it is resistant to fabric breakage against bending, is excellent in formability and softness, and dries quickly. (Patent Document 2)
In addition, a chocolate characterized by containing 0.5 to 15.0% by weight of triacylglycerol having a total of 58 or more carbon atoms in the fatty acid component of the chocolate dough is proposed. According to this, even under simple conditions, uniform and fine bubbles can be maintained, and it is possible to produce a chocolate with bubbles that does not easily lose shape due to external force, and it is said that it expresses an excellent light feeling and coolness when eaten. ing. (Patent Document 3)
However, in all of the above three inventions, chocolate has bubbles, plasticity, and soft feeling, but it does not mention melting in the mouth like raw chocolate.

特開平07−264982号公報Japanese Patent Laid-Open No. 07-264982 特開平06−105655号公報Japanese Patent Laid-Open No. 06-105655 特開平03−201946号公報Japanese Patent Laid-Open No. 03-201946

本発明の目的は、ロウのような口溶けの悪さ(ワキシー感と称する)や、液油の多いチョコレート類にありがちな液油が口腔中に膜を張ったような油性感(オイリー感)をおさえつつ、単に物性的な可塑性やソフト感のみではなく、生チョコレートのようにもったりとした特異的な口溶けを有するチョコレート類と概チョコレート類に用いられるハードバターを提供する事にある。   The object of the present invention is to suppress the poor melting of the mouth (referred to as waxy feeling) such as wax, and the oily feeling (oily feeling) that the liquid oil, which is often found in chocolates with a lot of liquid oil, stretches the film in the mouth. On the other hand, the object is to provide hard butter that is used not only for physical plasticity and soft feeling but also for chocolates having a specific mouth melting like raw chocolate and almost chocolates.

本発明者らは鋭意研究を行った結果、チョコレート類に含まれる油脂中にLU2型(Lは炭素数20以上の長鎖飽和脂肪酸、Uは炭素数18の不飽和脂肪酸)トリアシルグリセロール(以降TGと称す)を1〜35重量%含むことで、あるいはチョコレート類に添加する油脂組成物であって、油脂組成中の全油分に対してLU2型(ただし、Lは炭素数20以上の長鎖飽和脂肪酸、Uは炭素数18の不飽和脂肪酸を意味する。)トリアシルグリセロール20重量%以上含有し、かつ構成脂肪酸の総炭素数が60以上のトリアシルグリセロールは50重量%以下である油脂組成物a、または油脂組成物aを5〜100重量%以上含む油脂組成物Aをチョコレート類に5〜60重量%添加することで、単に物性的な可塑性やソフト感のみではなく、生チョコレートのようにもったりとした特異的な口溶けを有するチョコレート類と概チョコレート類に用いられるハードバターを見出し、本発明を完成するに至った。   As a result of intensive studies, the present inventors have found that LU2 type (L is a long-chain saturated fatty acid having 20 or more carbon atoms, U is an unsaturated fatty acid having 18 carbon atoms) triacylglycerol (hereinafter referred to as “fatty acid”) in fats and oils contained in chocolates. 1 to 35% by weight of TG) or an oil / fat composition to be added to chocolates, and LU2 type (where L is a long chain having 20 or more carbon atoms) relative to the total oil content in the oil / fat composition Saturated fatty acid, U means an unsaturated fatty acid having 18 carbon atoms.) Oil composition containing 20% by weight or more of triacylglycerol and 50% by weight or less of triacylglycerol having a total fatty acid number of 60 or more By adding 5 to 60% by weight of the fat or oil composition A containing 5 to 100% by weight of the product a or the fat and oil composition a to chocolates, not only physical plasticity and soft feeling Found hard butter used in chocolate and approximate chocolate having specific melting properties in the mouth, which was or had as ganache, and have completed the present invention.

即ち、本発明は、(1)としては、チョコレート類に添加する油脂組成物であって、油脂組成中の全油分に対してLU2型(ただし、Lは炭素数20以上の長鎖飽和脂肪酸、Uは炭素数18の不飽和脂肪酸を意味する。)トリアシルグリセロール20重量%以上含有し、かつ構成脂肪酸の総炭素数が60以上のトリアシルグリセロールは50重量%以下である油脂組成物aであり、(2)としては、(1)記載の油脂組成物aをチョコレート類口溶け改良材として使用するチョコレート類の製造方法であり、(3)としては、LU2型トリアシルグリセロールを全油脂分中に対して1〜35重量%含むチョコレート類であり、(4)としては、油脂中に(1)記載の油脂組成物aを5〜100重量%含むことを特徴とする油脂組成物Aであり、(5)としては、(4)記載の油脂組成物Aを5〜60重量%含むことを特徴とするチョコレート類である。   That is, the present invention is an oil composition added to chocolates as (1), and is LU2 type (where L is a long-chain saturated fatty acid having 20 or more carbon atoms, relative to the total oil content in the oil composition, U means an unsaturated fatty acid having 18 carbon atoms.) Fat composition a containing 20% by weight or more of triacylglycerol, and triacylglycerol having a total fatty acid number of 60 or more is 50% by weight or less. Yes, (2) is a method for producing chocolate using the fat composition a as described in (1) as a melting agent for melting chocolate, and (3) is LU2 type triacylglycerol in the total fat content. (4) is an oil / fat composition A characterized by containing 5 to 100% by weight of the oil / fat composition a described in (1) in the oil / fat. (5) as is the chocolate which comprises 5 to 60 wt% of the fat or oil composition A described (4).

本発明により本発明によりワキシー感・オイリー感をおさえつつ、生チョコレートのようにもったりとした特異的な口溶けを有するチョコレート類を平易な方法にて得ることが可能になった。   According to the present invention, it has become possible to obtain chocolates having a specific mouth melt like a raw chocolate by a simple method while suppressing a waxy feeling and oily feeling.

以下、本発明をより詳細に説明する。本発明で言うところのチョコレート類とは、油脂が連続相をなす食品であれば特に限定はされないが、一例を挙げると、チョコレートが該当する。また、ここで言うチョコレート類とは、全国チョコレート業公正取引協議会、チョコレート利用食品公正取引協議会で規定されるチョコレート、準チョコレート、チョコレート利用食品の総称である。なお、チョコレート類の風味は、カカオ原料(カカオマス、ココア、ココアバター)、粉乳類、糖類が主成分であるスィートチョコレート類、ミルクチョコレート類、ホワイトチョコレート類に限らず、種々の粉末類を使用した、コーヒー風味、抹茶風味、果実風味、塩味系風味などの風味バラエティー品も、当然その範囲に入る。また前述のとおり、本発明でいうところのチョコレート類は水分が5重量%未満のものを指す。   Hereinafter, the present invention will be described in more detail. The chocolates referred to in the present invention are not particularly limited as long as the fats and oils are foods that form a continuous phase. Moreover, the chocolates mentioned here are a general term for chocolate, quasi-chocolate, and chocolate-based foods stipulated by the National Chocolate Fair Trade Council and the Chocolate-based Food Fair Trade Council. The flavors of chocolates are not limited to cocoa ingredients (cocoa mass, cocoa, cocoa butter), milk powder, sweet chocolates mainly composed of sugar, milk chocolates, and white chocolates, but various powders are used. Naturally, flavor variety products such as coffee flavor, matcha flavor, fruit flavor and salt flavor are also within the range. As described above, the chocolates referred to in the present invention refer to those having a moisture content of less than 5% by weight.

チョコレート類は上記の通り油脂が連続相であり、その油脂はハードバターと呼ばれる。ここでいうところのハードバターとは、ココアバターとココアバターの代替脂を総称するものであり、ココアバター代用脂とは、上記CBEとCBRがある。ココアバター代替脂の油脂原料としては、ナタネ油、大豆油、ヒマワリ油、綿実油、落花生油、米糠油、コーン油、サフラワー油、オリーブ油、カポック油、ゴマ油、月見草油、パーム油、シア脂、サル脂、ヤシ油、パーム核油等の植物性油脂及び乳脂、牛脂、ラード、魚油、鯨油等の動物性油脂を例示することができ、上記油脂類の単独若しくは混合油、又はそれらの硬化、分別、エステル交換等を施した加工油脂を用いることができる。本願においてはCBE、CBR、油脂原料としては特に限定はされないが、より望ましくは体温付近で急激に溶解する物性を持ち、特にココアバターとCBEのような対称型TGを多く含有するものにおいて効果的である。   As described above, fats and oils in chocolates are a continuous phase, and the fats and oils are called hard butter. Here, hard butter is a general term for cocoa butter and substitute fats for cocoa butter, and cocoa butter substitute fats include CBE and CBR. As fats and oils for cocoa butter, rapeseed oil, soybean oil, sunflower oil, cottonseed oil, peanut oil, rice bran oil, corn oil, safflower oil, olive oil, kapok oil, sesame oil, evening primrose oil, palm oil, shea fat, Examples include vegetable oils and milk fats such as monkey fat, palm oil, palm kernel oil, and animal fats such as beef fat, lard, fish oil, whale oil, and the above oils alone or mixed oils, or curing thereof, Processed oils and fats subjected to fractionation, transesterification and the like can be used. In the present application, CBE, CBR, and oil and fat raw materials are not particularly limited, but more preferably have properties that dissolve rapidly around body temperature, and are particularly effective in those containing many symmetrical TGs such as cocoa butter and CBE. It is.

チョコレート類に含有される全油脂における対称型TG含有量は、POSt、StOSt、POP(ただし、P:パルミチン酸、O:オレイン酸、St:ステアリン酸)の和が全油脂に対して40重量%以上、より望ましくは45重量%以上、さらに望ましくは50重量%以上であることが好ましい。40重量%以下の場合は後述のLU2型TGが配合されることでの口溶けの改善効果が得られにくい。   The symmetric TG content in all fats and oils contained in chocolate is 40% by weight of the total of POSt, StOSt, and POP (where P: palmitic acid, O: oleic acid, St: stearic acid) with respect to the total fats and oils. As mentioned above, it is more preferable that it is 45 weight% or more, More desirably, it is 50 weight% or more. In the case of 40% by weight or less, it is difficult to obtain the effect of improving the melting of the mouth by adding the LU2 type TG described later.

LU2型のTG(以後、単にLU2と呼称した場合はTGを指す)について説明する。Lは炭素数20以上の長鎖飽和脂肪酸であれば特に限定はされず、具体例としては、アラキジン酸(C20:0)、ベヘン酸(C22:0)、リグノセリン酸(C24:0)などが挙げられるが、入手の容易性や口溶けの効果の点で、ベヘン酸であるとより好ましい。ベヘン酸の供給源としては、エルシン酸(炭素数22で二重結合を1つ有する。ナタネなどにハイエルシン酸品種が存在する)を極度硬化したものなどが挙げられる。   An LU2-type TG (hereinafter simply referred to as LU2 indicates TG) will be described. L is not particularly limited as long as it is a long-chain saturated fatty acid having 20 or more carbon atoms. Specific examples include arachidic acid (C20: 0), behenic acid (C22: 0), lignoceric acid (C24: 0) and the like. Although be mentioned, behenic acid is more preferable from the viewpoint of availability and the effect of melting in the mouth. Examples of the source of behenic acid include erucic acid (which has 22 carbon atoms and one double bond. High erucic acid varieties exist in rapeseed, etc.) that are extremely hardened.

Uは炭素数18以上の長鎖不飽和脂肪酸であり、炭素数18以上で不飽和結合を1つ以上有するものであれば特に限定はされず、具体例としては、Uとしてはオレイン酸(C18:1、ただしC(炭素数):(二重結合数)とする)やリノール酸(C18:2)が挙げられるが、入手の容易性や酸化安定性などの点から、オレイン酸であるとより好ましい。二重結合の極端に多い脂肪酸を多く含むと異風味が発生しやすい。オレイン酸を多く含有する油脂としてハイオレイックヒマワリ油、オリーブ油などが挙げられる。   U is a long-chain unsaturated fatty acid having 18 or more carbon atoms, and is not particularly limited as long as it has 18 or more carbon atoms and has one or more unsaturated bonds. Specific examples of U include oleic acid (C18 : 1, but C (the number of carbons) :( the number of double bonds)) and linoleic acid (C18: 2) are mentioned. From the viewpoint of easy availability and oxidative stability, oleic acid More preferred. If it contains a large amount of fatty acids with an extremely large number of double bonds, a different flavor tends to occur. Examples of fats and oils containing a large amount of oleic acid include high oleic sunflower oil and olive oil.

また、LU2はLが1つにUが2つ結合したTGであり、LUU(LがTGの1位または3位に結合している状態を指す)とULU(LがTGの2位に結合している状態を指す)といった位置異性体が存在する。LU2の総量として上記規定を満たしていれば口溶けの改善効果が得られるが、LUUがより多い方がよりのぞましい。特に限定はされないが、LU2に占めるLUU含量が70重量%以上、のぞましくは80重量%以上であることが好ましい。   LU2 is a TG with one L and two U, LUU (L indicates that it is connected to 1st or 3rd position of TG) and ULU (L is connected to 2nd position of TG) There is a positional isomer). If the above-mentioned rule is satisfied as the total amount of LU2, the effect of improving the melting of the mouth can be obtained, but the more LUU is more desirable. Although not particularly limited, it is preferable that the LUU content in LU2 is 70% by weight or more, preferably 80% by weight or more.

本願発明におけるチョコレート類はこのLU2をそのチョコレート類中の全油脂分に対して1〜35重量%含む必要がある。通常従来のチョコレート類の中には、LU2は殆ど含まれていない。稀にチョコレートのシーディング剤としてBOB(1,3−ジベヘノイル−2−オレイルグリセリド)を使用する場合に、BOBの副産物としてBOO(1(3)−ベヘノイル−2,3(1)−ジオレイルグリセリド)が少量混在している場合があるが、このBOOは特にチョコレートに対してシーディング効果を期待されておらず、またこの場合最大でも0.2重量%以上は含まれない。   The chocolates in the present invention are required to contain 1 to 35% by weight of this LU2 with respect to the total fats and oils in the chocolates. Normally, LU2 is hardly contained in conventional chocolates. When BOB (1,3-dibehenoyl-2-oleyl glyceride) is rarely used as a chocolate seeding agent, BOO (1 (3) -behenoyl-2,3 (1) -dioleoyl glyceride as a by-product of BOB ) May be mixed in a small amount, but this BOO is not particularly expected to have a seeding effect on chocolate, and in this case, 0.2% by weight or more is not included at the maximum.

即ちLU2が本願発明で課題とされる特異な口溶け感を発現させるにはチョコレート類中の全油脂分に対して下限が1重量%以上、望ましくは1.5重量%以上、さらに望ましくは2重量%以上であることが好ましい。1重量%未満の場合は、本願発明で課題とされる特異な口溶け感が乏しい。またLU2の上限は35重量%以下、望ましくは30重量%以下、さらに望ましくは25重量%以下であることが好ましい。LU2が35重量%を上回った場合、必要以上のLU2は特異な口溶けには貢献せず、むしろベースとなるチョコレート類の対称型TGの絶対量を減らしてしまい、また可塑性を通り越して流動性を発揮させてしまい目的とする商品設計においては望ましくない結果になりかねない。   In other words, LU2 has a lower limit of 1% by weight or more, preferably 1.5% by weight or more, more preferably 2% by weight based on the total fat and oil content in chocolates in order to develop the unique mouth-melting feeling that is the subject of the present invention. % Or more is preferable. When the amount is less than 1% by weight, the unique mouth-melting sensation that is a problem in the present invention is poor. The upper limit of LU2 is 35% by weight or less, desirably 30% by weight or less, and more desirably 25% by weight or less. When LU2 exceeds 35% by weight, more LU2 than necessary does not contribute to the unique melting of the mouth, but rather reduces the absolute amount of symmetric TG of the base chocolates, and also improves fluidity beyond plasticity. This may cause undesirable results in the intended product design.

本願発明の効果を得るには、チョコレート類の油脂におけるLU2の規定が上記のとおりであれば、特段どのような方法で作ってもかまわないが、上記示したとおり、LU2は従来のチョコレート類には殆ど存在していないので、LU2を多く含んだ油脂(油脂組成物aと称する)をチョコレート類に添加する方法が取られる。
チョコレート類に添加する油脂組成物であって、LU2を多く含んだ油脂組成物aは、油脂中のLU2の含有量は高いほど好ましく、20重量%以上、望ましくは30重量%以上、さらに望ましくは40重量%以上、最も望ましくは50重量%以上であることが好ましい。油脂組成物aとしてLU2含有量が多いほど少量でチョコレートに本願発明で課題とされる特異な口溶け感を発現させることが可能であり、また40重量%未満であるとチョコレートとして求められるLU2量を確保するためには大量に添加する必要が生じ、LU2以外のTG成分が口溶けの点で望ましくない影響を与えかねない。
In order to obtain the effect of the present invention, any method may be used as long as LU2 is defined in the fats and oils of chocolates as described above. However, as indicated above, LU2 can be applied to conventional chocolates. Therefore, a method of adding fats and oils containing a large amount of LU2 (referred to as “fat composition a”) to chocolates is employed.
The fat composition to be added to chocolates, the fat composition a containing a large amount of LU2, the higher the content of LU2 in the fat, the more preferable, 20 wt% or more, desirably 30 wt% or more, more desirably It is preferably 40% by weight or more, most desirably 50% by weight or more. The more LU2 content as the fat and oil composition a, the smaller the amount of LU2 required for chocolate can be expressed in chocolate, and the amount of LU2 required for chocolate to be less than 40% by weight can be expressed in chocolate. In order to ensure, it is necessary to add a large amount, and TG components other than LU2 may have an undesirable effect in terms of melting in the mouth.

一方で、油脂組成物aの構成脂肪酸の総炭素数が60以上のTG含有量は低いほど望ましく、50重量%以下、望ましくは45重量%以下、さらに望ましくは20重量%以下、最も望ましくは10重量%以下であることが好ましい。構成脂肪酸の総炭素数が60以上のTGは融点が高く、チョコレートに含まれる油脂中に構成脂肪酸の総炭素数が60以上のTG含有量が多くなると口溶けに悪影響を与えがちであるため、油脂組成物aとして構成脂肪酸の総炭素数が60以上のTG含有量が多いほど、油脂組成物aが少量であってもチョコレートの口溶けを悪化させる原因となりかねず、また、上記規定としてとして求められるLU2量を確保するよりも少量の添加で口溶けへの悪影響を顕実化させかねない。   On the other hand, the lower the content of TG having 60 or more total carbon atoms of the constituent fatty acids of the fat and oil composition a, the more desirable, 50% or less, desirably 45% or less, more desirably 20% or less, and most desirably 10%. It is preferable that it is below wt%. TG having a total fatty acid number of 60 or more has a high melting point, and if the content of TG having a total carbon number of 60 or more in the fatty acid contained in chocolate tends to adversely affect mouth melting, The greater the TG content of the constituent fatty acids as the composition a is 60 or more, the more the fat and oil composition a may be, the worse the melting of the chocolate may occur, and the above requirement is required. The addition of a smaller amount than securing the amount of LU2 may cause adverse effects on mouth melting.

油脂組成物aの製造法は特に限定はされないが、グリセリド骨格を有する原料を必須としたうえで、構成脂肪酸としてL、Uを有するグリセリン脂肪酸エステル、L(脂肪酸)、U(脂肪酸)、Lのアルコールエステル、及びUのアルコールエステルからなる群より選ばれた1種以上原料を用いてエステル交換し、必要に応じ高融点部及び/又は低融点部を分別除去することによって得ることができる。なお、L及びUのアルコールエステルのアルコールは特に限定はされないが、食品として利用可能なものを適宜用いることができる。   Although the manufacturing method of the oil-fat composition a is not specifically limited, After making the raw material which has a glyceride skeleton essential, glycerin fatty acid ester which has L and U as a constituent fatty acid, L (fatty acid), U (fatty acid), L It can be obtained by transesterification using one or more raw materials selected from the group consisting of alcohol esters and U alcohol esters, and separating and removing the high melting point portion and / or the low melting point portion as necessary. In addition, although alcohol of L and U alcohol ester is not specifically limited, what can be utilized as a foodstuff can be used suitably.

上記脂肪酸のアルコールエステルとしてこれらのメチルエステル、エチルエステルが、酪酸エステルとして酪酸エチルエステル、酪酸メチルエステルが例示できる。(食品用途である場合は分離されるとしてもエチルエステルを用いることが望ましい。)   Examples of these fatty acid alcohol esters include methyl esters and ethyl esters, and examples of butyric acid esters include butyric acid ethyl ester and butyric acid methyl ester. (In the case of food use, it is desirable to use ethyl ester even if separated.)

エステル交換に使用する触媒は特に限定するものではないが、ソディウムメチラート等のアルカリ金属触媒やリパ−ゼ(1,3位選択性の有無はどちらでもかまわない)を採用することができる。   Although the catalyst used for transesterification is not particularly limited, an alkali metal catalyst such as sodium methylate or a lipase (the presence or absence of the 1,3-position selectivity may be used) can be employed.

その際、副産物として、U3(低融点油脂)及びL2U、L3(高融点油脂)が生成するが、前述のとおり最終的なチョコレート類中の油脂分に対するLU2量ならびに油脂組成物aの構成脂肪酸の総炭素数が60以上のTG含有量の規定が満たされていれば特に上記低融点・高融点油脂の量の限定はされないものの、低融点・高融点油脂が多いと、機能発現に十分なLU2を存在させる為の油脂組成物aの添加量が増え、しかも低融点側はオイリー食感(液状油脂が口腔内にべったりと貼り付いた感覚)、高融点側はワキシー食感(ワックス即ち蝋のような口溶けの悪い感覚)を増長させるため好ましくない。   At that time, U3 (low melting point fat and oil) and L2U and L3 (high melting point fat and oil) are produced as by-products. As described above, the amount of LU2 with respect to the fat and oil content in the final chocolate and the constituent fatty acids of the fat and oil composition a Although the amount of the low melting point / high melting point oil / fat is not particularly limited as long as the regulation of the TG content having a total carbon number of 60 or more is satisfied, LU2 sufficient for function expression is obtained when there are many low melting point / high melting point fats / oils. The amount of the oil composition a added to increase the presence of oil is increased, and the low melting point side has an oily texture (sensation of liquid oil sticking to the mouth), and the high melting point side has a waxy texture (wax or wax). This is not preferable because it increases a feeling of poor melting of the mouth).

L2U油脂におけるL2Uの含有量を高める方法としては、エステル交換反応自体でL2Uを高収率にする方法でもよいし、圧濾分別、溶剤分別等でもよい。それぞれ公知の方法を使用することができるが、溶剤分別が工業的に有利である。
また、前述のLUU含量を高めるには、エステル交換に使用する触媒として1,3位選択性を有するリパ−ゼを採用することでできる。1,3位選択性リパ−ゼによるエステル交換はLのアルコールエステルとUを多く含むグリセリン脂肪酸エステルを原料として用いた場合、TGのL3(高融点油脂)が生成しにくいためワキシー食感増長への影響が少ない点でも有利である。
As a method for increasing the content of L2U in the L2U fat, a method of increasing L2U by the transesterification reaction itself, pressure filtration fractionation, solvent fractionation, or the like may be used. Known methods can be used for each, but solvent fractionation is industrially advantageous.
In order to increase the above-mentioned LUU content, a lipase having 1,3-position selectivity can be employed as a catalyst used for transesterification. Transesterification with 1,3-position selective lipase increases the waxy texture because L3 (high melting point fat) of TG is difficult to produce when L alcohol ester and glycerol fatty acid ester containing a large amount of U are used as raw materials. This is also advantageous in that there is little influence.

さらに構成脂肪酸の総炭素数が60以上のTGや低融点・高融点油脂を低減させるのもそれぞれ公知の方法を使用することができるが、溶剤分別が工業的に有利である。
このような方法で得られた、油脂組成物aをチョコレート類口溶け改良材として使用する。
油脂組成物aの口溶け改良材としての使用はチョコレート類に含まれれば特にその使用には限定はないが、一例としては、チョコレート類に油脂組成物aを直接添加する方法やチョコレート類を製造するに際し、その原料の油脂に油脂組成物aを配合する方法、さらには、油脂組成物aを適宜油脂で希釈したもの(油脂組成物Aと称する)をチョコレート類に直接添加したり、あるいは原料に添加する方法が挙げられる。
Further, known methods can be used to reduce TG having a total fatty acid number of 60 or more and low melting point / high melting point fats and oils, but solvent fractionation is industrially advantageous.
The fat and oil composition a obtained by such a method is used as a melting agent for melting chocolate.
The use of the fat composition a as a mouth melting improver is not particularly limited as long as it is contained in chocolates, but as an example, a method of directly adding the fat composition a to chocolates or manufacturing chocolates At the time, the method of blending the fat composition a with the raw fat and oil, and further adding the fat composition a appropriately diluted with the fat (referred to as the fat composition A) directly to the chocolate, or the raw material The method of adding is mentioned.

油脂組成物Aは油脂組成物aを2.5重量%以上、望ましくは5重量%以上であることが好ましいが、油脂組成物aを100重量%、即ち油脂組成物aをそのまま用いてもかまわない。   The oil and fat composition A contains the oil and fat composition a at 2.5% by weight or more, preferably 5% by weight or more, but the oil and fat composition a may be used at 100% by weight, that is, the oil and fat composition a may be used as it is. Absent.

逆に、油脂組成物aは高濃度であればあるほど、本願発明の効果を得る上では有利であったのにわざわざ希釈するケースの利点としては、LU2高濃度の油脂組成物aを用いることで、油脂組成物aのLU2以外の残余分が低融点・高融点油脂がチョコレート類の食感へ与える悪影響を押さえ、且つチョコレートへの分散性を向上させる点でも有利である。また、油脂組成物aを希釈する油脂については特に限定はされないが、上記の理由により、ココアバターのような対称型TGを多く含有するものが好ましい。   Conversely, the higher the concentration of the oil / fat composition a, the more advantageous it is to obtain the effects of the present invention. Thus, the remainder other than LU2 of the oil and fat composition a is advantageous in that the low melting point and high melting point oil and fat suppress the adverse effect of the chocolate on the texture of the chocolate and improve the dispersibility in the chocolate. Moreover, it does not specifically limit about the fats and oils which dilute the fat composition a, However, What contains many symmetrical type TG like cocoa butter for said reason is preferable.

油脂組成物Aとしてはチョコレート類中に5〜60重量%含む必要があり、望ましくは10〜25重量%さらに望ましくは15〜20重量%以上である方が好ましい。
60%以上を添加すると油脂組成物A中の油脂組成物aの割合が多いにせよ、希釈に用いた油脂(たとえそれが対称型TGであっても)が多いにせよ、ベースとなるチョコレートの油分のバランスが崩れ、チョコレートとして目的とした品質を出しにくく、油っぽいチョコレート類になりかねない。
The oil / fat composition A needs to be contained in the chocolates in an amount of 5 to 60% by weight, desirably 10 to 25% by weight, more desirably 15 to 20% by weight or more.
When 60% or more is added, even if the ratio of the fat composition a in the fat composition A is large, even if the fat used for dilution (even if it is a symmetric TG), the base chocolate The oil balance is lost, it is difficult to produce the desired quality as chocolate, and it may become oily chocolates.

対称型TGを多く含有する油脂はその良好な口溶けを発現させる為にはテンパリングと呼ばれる操作が必要であるが、油脂中のLU2が15重量%越えるとテンパリング操作が困難になる。もっとも、シード剤を使えば20重量%程度まではテンパリングを取ることは可能である。   An oil / fat containing a large amount of symmetric TG needs an operation called tempering in order to develop its good mouth melting, but if the LU2 in the oil / fat exceeds 15% by weight, the tempering operation becomes difficult. However, if a seed agent is used, it is possible to remove tempering up to about 20% by weight.

本願発明におけるチョコレート類は上記ハードバーターをはじめとする油脂のほかにも糖類や乳成分等の原料、乳化剤や保存料、酸化防止剤といった添加物を配合するが、従来のチョコレート類で用いられているものなら、所望により任意のものを使用できる。
また、製造方法についても上記の原料を適宜選択して混合し、通常のロールリファイナー、コンチェによる製法はもちろん、アトライターによる方法などの製造法を採用することもできる。また粒度、粘度、油分等など物性面、冷菓用、コーチング用、飾り用などの形状についてもチョコレート類として使用するものであれば任意に製造することができる。
The chocolates in the present invention contain additives such as raw materials such as sugars and milk components, emulsifiers, preservatives, antioxidants in addition to the oils and fats including the hard barter, but are used in conventional chocolates. Any can be used as desired.
As for the production method, the above-mentioned raw materials can be appropriately selected and mixed, and production methods such as a method using an attritor as well as a production method using an ordinary roll refiner and conche can be employed. In addition, physical properties such as particle size, viscosity, and oil content, and shapes such as for frozen desserts, for coaching, and for decoration can be arbitrarily produced as long as they are used as chocolates.

以下に本発明の実施例を示し、本発明をより詳細に説明するが、本発明の精神は以下の実施例に限定されるものではない。なお、例中、%及び部は、いずれも重量基準を意味する。   Examples of the present invention will be described below to explain the present invention in more detail. However, the spirit of the present invention is not limited to the following examples. In the examples, “%” and “part” mean weight basis.

<実施例1〜比較例1>
<高LU2含有油脂の調整>
高オレイン酸ヒマワリ油30部、ベヘン酸エチルエステル70部を1,3位特異性を有するリパーゼを用いてエステル交換反応し、蒸留によりエステル部を除去し、このトリアシルグリセロール画分をヘキサン分別により、LU2トリアシルグリセロール画分(低融点画分)を得た(LU2含量58.9重量%)。
<Example 1 to Comparative Example 1>
<Adjustment of high LU2 content fats and oils>
Transesterification of 30 parts of high oleic sunflower oil and 70 parts of behenic acid ethyl ester using lipase having 1,3-position specificity, the ester part was removed by distillation, and this triacylglycerol fraction was separated by hexane fractionation. The LU2 triacylglycerol fraction (low melting point fraction) was obtained (LU2 content 58.9% by weight).

<検討油脂の調製>
パーム分画油低融点画分(パーム分画油でヨウ素価66以上の低融点画分、不二製油株式会社製、製品名パームエースN)と高LU2含有油脂を以下の表1に従い配合する。
<Preparation of the study oil>
Palm fraction oil low melting point fraction (palm fraction oil, low melting point fraction with iodine value of 66 or more, manufactured by Fuji Oil Co., Ltd., product name Palm Ace N) and oil containing high LU2 are blended according to Table 1 below. .

<チョコレート類の調整>
市販のスイートチョコレート (不二製油株式会社製:油分34重量%)85部に検討油脂各実施例・比較例に対応する検討油脂を15部を添加し、テンパリング処理したのち、モールド(型)に入れ、約10℃の冷温度域に30分冷却した後、モールドより外し、20℃にて1週間保存後に食感の比較を行った。
<Adjustment of chocolates>
After adding 15 parts of examination fats and oils corresponding to each of the examples and comparative examples to 85 parts of commercially available sweet chocolate (Fuji Oil Co., Ltd .: 34% by weight of oil), tempering the molds (molds) Then, after cooling to a cold temperature range of about 10 ° C. for 30 minutes, it was removed from the mold, and the texture was compared after storage at 20 ° C. for 1 week.

<表1>

Figure 2010070874
※ 評価方法は、パネラー20名による官能評価を実施した。
※ 評価基準として良好な方から○、△、×の3段階で評価した。ただし、△までは製品価値あり。
噛み出し:チョコレート類に歯が入る感触で評価。硬い…X、中間…△、軟らかい…○
濃厚感:口腔内での風味発現で評価。ある…○、中間…△、ない…X
口残り:口腔間での溶け残ったチョコレート類の残存感。ない…○、中間…△、する…X
本願発明でいうところの「生チョコレートのようにもったりとした特異的な口溶け」とはこの「噛み出し」・「濃厚感」・「口残り」の官能により構成されており、それぞれが高い評価であることが、より「生チョコレートのもったりとした特異的な口溶け」の評価が高いものとする。<Table 1>
Figure 2010070874
* The evaluation method was a sensory evaluation by 20 panelists.
* As an evaluation standard, the evaluation was made in three stages of ○, Δ, and × from the best. However, there is product value until △.
Chewing: Evaluated by the feeling that teeth enter into chocolates. Hard ... X, Middle ... △, Soft ... ○
Rich feeling: Evaluated by the expression of flavor in the oral cavity. Yes ... ○, Middle ... △, No ... X
Mouth remaining: Residual feeling of unmelted chocolate between the mouths. No ... ○, Intermediate ... △, Yes ... X
In the present invention, “specific melting in the mouth like raw chocolate” is composed of the sensation of “biting”, “thickness”, and “mouth residue”, and each is highly evaluated. It is assumed that the evaluation of “a unique mouth melt of raw chocolate” is higher.

パーム分画油低融点画分はチョコレート類に添加することで、融点を下げて、軟らかな食感を付与することが以前より知られている。実施例1は検討油脂として高LU2含有油脂を100重量%含む(即ち、油脂組成物A=油脂組成物a100重量%)状態では、噛み出しの軟らかさがあり、かつ他の油脂を添加した場合に良く見られるチョコレート本来の風味の濃厚感が低下せず、むしろ良好であり、また単に融点を下げたチョコレート類にみられる口腔中にべったりと広がった油っぽい食感のしつこい口残り感がなかった。
つぎに、徐々に実施例1から比較例1へパーム分画油低融点画分を増やしていく実験を検証した。
噛み出しという点では、すべて同じように軟らかな食感を得ることができたが、濃厚感、特に口残り感が、パーム分画油低融点画分が大多数を占めるに従い悪くなった。ただ検討油脂中に高LU2含有油脂が5重量%以上含まれる実施例1から実施例4まではパーム分画油低融点画分の影響は顕実化せず、また高LU2含有油脂2.5重量%含まれる実施例5も濃厚感、口溶け感ともに、パーム分画油低融点画分100重量%の比較例1に比べて改善されており、十分に市場性のある、新規な食感のチョコレート類であった。
一方、比較例1は濃厚感の発現もさほど特筆するほどでなく、何よりしつこい口残り感があり、既存の単に融点を下げたチョコレート類となんら変わるところはなかった。
It has been known for some time that palm fraction oil low melting point fractions are added to chocolates to lower the melting point and give a soft texture. Example 1 includes 100% by weight of high-LU2 containing fat as the studied fat and oil (that is, fat and oil composition A = oil and fat composition a 100% by weight), and there is softness of biting and when other fats and oils are added The richness of the original flavor of chocolate, which is often seen in foods, does not decrease, but is rather good. There wasn't.
Next, an experiment in which the palm fraction oil low melting point fraction was gradually increased from Example 1 to Comparative Example 1 was verified.
In terms of biting, all of the same soft texture could be obtained, but the richness, particularly the mouthfeel, became worse as the majority of the palm fraction oil low melting point fraction occupied. However, in Examples 1 to 4 in which high-LU2 content fats and oils are included in the examined fats and oils in an amount of 5% by weight or more, the influence of the palm fraction oil low melting point fraction is not clarified, and high-LU2 content fats and oils 2.5 In Example 5 containing 5% by weight, both richness and mouth-melting feeling are improved as compared with Comparative Example 1 in which the palm fraction oil low melting point fraction is 100% by weight, and it is sufficiently marketable and has a new texture. It was chocolate.
On the other hand, Comparative Example 1 was not particularly remarkable in the expression of richness, had a persistent mouthfeel, and was not different from existing chocolates simply having a lowered melting point.

<比較例2〜比較例3>
<検討油脂の調整>
検討油脂として以下のものを調整した。
<高SO2含有油脂>
高オレイン酸ヒマワリ油30部、ステアリン酸エチルエステル70部を1,3位特異性を有するリパーゼを用いてエステル交換反応し、蒸留によりエステル部を除去し、このトリアシルグリセロール画分をヘキサン分別により、LU2トリアシルグリセロール画分(低融点画分)を得た(LU2含量0.5重量%、SU2含量68.6重量%、但しS:炭素数20未満の飽和脂肪酸)。
<POP含有油脂>
パーム分画油中融点画分(製品名:パーメル26、不二製油株式会社製)を用いる(POP50.2重量%)。
<Comparative Example 2 to Comparative Example 3>
<Adjustment of study fats and oils>
The following oils and fats were adjusted.
<High SO2 content fats and oils>
Transesterification of 30 parts of high oleic sunflower oil and 70 parts of stearic acid ethyl ester with lipase having 1,3-position specificity, the ester part was removed by distillation, and this triacylglycerol fraction was separated by hexane fractionation. The LU2 triacylglycerol fraction (low melting point fraction) was obtained (LU2 content 0.5% by weight, SU2 content 68.6% by weight, where S: saturated fatty acid having less than 20 carbon atoms).
<POP-containing fats and oils>
Palm fraction oil middle melting point fraction (product name: Permel 26, manufactured by Fuji Oil Co., Ltd.) is used (POP 50.2% by weight).

<チョコレート類の調整>
実施例1と同様の手法にてチョコレートに配合して各サンプルを得、同様の保存の後に食感の比較を行った。評価は検討油脂の配合と共に表2にしめした。参考の為、実施例1と比較例1も列挙した。
<Adjustment of chocolates>
Each sample was obtained by blending with chocolate in the same manner as in Example 1, and the texture was compared after the same storage. The evaluation is shown in Table 2 together with the composition of the studied fats and oils. For reference, Example 1 and Comparative Example 1 are also listed.

<表2>

Figure 2010070874
※ 評価方法は表1と同様<Table 2>
Figure 2010070874
* Evaluation method is the same as Table 1.

高SO2含有油脂はLU2含量が0.5重量%と殆どはいっていないものの、炭素数20以上のLの替わりに炭素数20未満の飽和脂肪酸であるSを分子中に持つSU2含量が68.6重量%と、脂肪酸の炭素数以外は構造・組成的に極めて似通った油脂であり、噛み出し、口残り感の改善効果はLU2程度にはあるものと見られる。しかし濃厚感の発現がLU2に比べて劣るものであった。また、チョコレートに多く含まれるココアバターやCBEのような対称型TGの中でもっとも融点が低いPOPを多く含むPOP含有油脂を用いた場合は、圧倒的に噛み出しが固く、求める軟らかな口溶けは得られなかった。   Although the high SO2 content fats and oils have almost no LU2 content of 0.5% by weight, instead of L having 20 or more carbon atoms, the content of SU2 having S in the molecule, which is a saturated fatty acid having less than 20 carbon atoms, is 68.6. The fat and oil are very similar in structure and composition except for the weight% and the number of carbon atoms of the fatty acid, and it seems that the improvement effect of biting and mouth feel is about LU2. However, the expression of richness was inferior to LU2. In addition, when using POP-containing fats and oils that contain a large amount of POP with the lowest melting point among symmetric TGs such as cocoa butter and CBE that are abundant in chocolate, the bite is overwhelmingly hard and the soft melting required It was not obtained.

以上記載したように、チョコレート中の油脂成分としてLU2を含有する油脂組成のチョコレートは、一般的なテンパー型チョコレートでありながら、生チョコのような軟らかな噛み出しと、濃厚ながらもあとに残らない良好な口溶けを有する。   As described above, the fat and oil composition chocolate containing LU2 as the fat and oil component in the chocolate is a general temper type chocolate, soft bite like raw chocolate, and thick but not left behind. Has good mouth melt.

Claims (5)

チョコレート類に添加する油脂組成物であって、油脂組成中の全油分に対してLU2型(ただし、Lは炭素数20以上の長鎖飽和脂肪酸、Uは炭素数18の不飽和脂肪酸を意味する。)トリアシルグリセロール20重量%以上含有し、かつ構成脂肪酸の総炭素数が60以上のトリアシルグリセロールは50重量%以下である油脂組成物a。 An oil / fat composition to be added to chocolates, which is LU2 type (where L is a long-chain saturated fatty acid having 20 or more carbon atoms and U is an unsaturated fatty acid having 18 carbon atoms) with respect to the total oil content in the oil / fat composition. .) Oil composition a containing 20% by weight or more of triacylglycerol and having 50% or less of triacylglycerol having a total fatty acid number of 60 or more. 請求項1記載の油脂組成物aをチョコレート類口溶け改良材として使用するチョコレート類の製造方法。 The manufacturing method of chocolate which uses the oil-fat composition a of Claim 1 as a chocolate mouth melt improvement material. LU2型トリアシルグリセロールを全油脂分中に対して1〜35重量%含むチョコレート類。 Chocolates containing 1 to 35% by weight of LU2 type triacylglycerol based on the total fat and oil content. 油脂中に請求項1記載の油脂組成物aを5〜100重量%含むことを特徴とする油脂組成物A。 An oil / fat composition A comprising 5 to 100% by weight of the oil / fat composition a according to claim 1 in the oil / fat. 請求項4記載の油脂組成物Aを5〜60重量%含むことを特徴とするチョコレート類。 Chocolate containing the fat-and-oil composition A of Claim 4 5 to 60weight%.
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