JPWO2006013713A1 - Coating material release agent and coating material release sheet - Google Patents
Coating material release agent and coating material release sheet Download PDFInfo
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D9/00—Chemical paint or ink removers
- C09D9/005—Chemical paint or ink removers containing organic solvents
Abstract
戸建住宅、集合住宅、工場等の建築物における外壁、内壁、屋根、床、フローリングや、木工家具、建具、工芸品、楽器等の木材や、漁船、旅客船、貨物船、プレジャーボート等の船舶や、航空機、電車、自動車、バス等の車両や、産業機械等の工業用製品、あるいは、橋梁、標識、遊具等の設備などの仕上げ材に使用されている塗装材の剥離に適した塗装材剥離剤及び塗装材剥離シートに関する。沸点１１３℃〜２３０℃である非ハロゲン系高沸点有機溶剤と、重量平均分子量が１万〜１００万である可溶性有機高分子化合物と、チクソトロピー剤とを主成分とする実質的にハロゲン系化合物を含まない組成物を塗装材剥離剤とし、また、上記塗装材剥離剤を不織布等の繊維集合体と有機フィルムとからなるシート基材に含浸させた塗装材剥離シートとする。Woods such as outer walls, inner walls, roofs, floors, flooring, wooden furniture, joinery, crafts, musical instruments, etc., and fishing boats, passenger ships, cargo ships, pleasure boats, etc. Coating materials suitable for peeling coating materials used for finishing materials such as aircraft, trains, automobiles, buses, etc., industrial products such as industrial machinery, or equipment such as bridges, signs, playground equipment, etc. The present invention relates to a release agent and a coating material release sheet. A substantially halogenated compound mainly comprising a non-halogen high boiling point organic solvent having a boiling point of 113 ° C to 230 ° C, a soluble organic polymer compound having a weight average molecular weight of 10,000 to 1,000,000, and a thixotropic agent. A composition that does not contain a coating material release agent, and a coating material release sheet obtained by impregnating a sheet base material composed of a fiber assembly such as a nonwoven fabric and an organic film with the coating material release agent.
Description
本発明は、戸建住宅、集合住宅、工場等の建築物における外壁、内壁、屋根、床、フローリングや、木工家具、建具、工芸品、楽器等の木材や、漁船、旅客船、貨物船、プレジャーボート等の船舶や、航空機、電車、自動車、バス等の車両や、産業機械等の工業用製品、あるいは、橋梁、標識、遊具等の設備などの仕上げ材に使用されている塗装材の剥離に適した塗装材剥離剤及び塗装材剥離シートに関するものである。 The present invention relates to outer walls, inner walls, roofs, floors, flooring, wood furniture, joinery, crafts, musical instruments, etc., and fishing boats, passenger ships, cargo ships, pleasures in buildings such as detached houses, apartment houses, factories, etc. For peeling off coating materials used for finishing materials such as boats, ships, aircraft, trains, cars, buses, industrial products such as industrial machinery, bridges, signs, playground equipment, etc. The present invention relates to a suitable coating material release agent and a coating material release sheet.
現在、仕上げ材には、様々な塗装材が使用されている。また、建築物や木材、船舶、車両、工業用製品、設備等の改装の為に、新塗装材を旧塗装材の上に再塗装する場合もあるが、旧塗装材を剥離してから新塗装材を塗装することも行われる。
塗装材を剥離する場合には、剥離作業時間の短縮などの観点から、通常、剥離剤を塗装材の上から塗布することが一般的に行われている。使用される剥離剤としては、塩化メチレンなどを主成分とする剥離剤が一般的に使用されている。
しかし、塩化メチレンなどの塩素系溶剤は、燃焼時にダイオキシンが発生するなどの環境汚染をもたらす可能性があり、優れた剥離性を有するものの、今後、その使用が制限される可能性がある。
以上のような観点から、近年、塩素系溶剤からなる剥離剤を使用せず、高圧水洗機などを使用して、物理的な力で塗装材を剥離する方法や、非塩素系溶剤からなる剥離剤を使用する方法などが開発されている。
しかし、高圧水洗機などを使用する方法では、水圧に起因する反力等の安全性に注意が必要である。また、非塩素系溶剤からなる剥離剤を使用する方法では、剥離性能の点から、塗装材によっては長時間の養生が必要となり、いずれの場合にも作業効率が低下し、その改善が望まれていた。
以上のような観点から、特開平１０−２７９８５０号公報、特開平１０−３３１４３５号公報、特開２０００−１６３７号公報には、壁面等の塗膜剥離剤及びその剥離方法などが開示されている。
しかし、特開平１０−２７９８５０号公報、特開平１０−３３１４３５号公報、特開２０００−１６３７号公報に記載の方法は、塗膜を剥離する能力を一層高めることは勿論のこと、剥離剤を均一に塗布することが難しく、結果的に、剥離状態にばらつきが発生するという問題があった。また、剥離剤を塗布後、養生する間に剥離剤が蒸発するなどの問題が発生し、その改善なども望まれていた。
本発明の目的は、建築物や木材、船舶、車両、工業用製品、設備等の塗装材を溶解することなく、可塑化して軟化させ、塗装材の剥離作業を容易にでき、かつ、環境への悪影響の少ない塗装材剥離剤及び塗装材剥離シートを提供することにある。Currently, various coating materials are used as finishing materials. In addition, new paint may be repainted on the old paint for renovation of buildings, wood, ships, vehicles, industrial products, equipment, etc. The painting material is also painted.
In the case of peeling the coating material, it is generally performed to apply a release agent on the coating material from the viewpoint of shortening the peeling work time. As the release agent used, a release agent mainly composed of methylene chloride or the like is generally used.
However, a chlorinated solvent such as methylene chloride may cause environmental pollution such as generation of dioxins during combustion and has excellent peelability, but its use may be limited in the future.
In view of the above, in recent years, without using a release agent made of a chlorinated solvent, a method of peeling a coating material with a physical force using a high-pressure water washer, etc., or a release made of a non-chlorine solvent A method of using the agent has been developed.
However, in a method using a high-pressure washing machine, attention must be paid to safety such as reaction force caused by water pressure. In addition, in the method using a release agent composed of a non-chlorine solvent, it is necessary to cure for a long time depending on the coating material from the viewpoint of the release performance. It was.
From the above viewpoints, JP-A-10-279850, JP-A-10-331435, and JP-A-2000-1637 disclose coating film peeling agents such as wall surfaces and the peeling method thereof. .
However, the methods described in JP-A-10-279850, JP-A-10-331435, and JP-A-2000-1637 not only further enhance the ability to release the coating film, but also provide a uniform release agent. As a result, there is a problem that the peeled state varies. In addition, problems such as evaporation of the release agent during curing after application of the release agent have occurred, and improvements have been desired.
The object of the present invention is to plasticize and soften coating materials such as buildings, timber, ships, vehicles, industrial products, equipment, etc., and to make the coating material peeling work easy and to the environment. An object of the present invention is to provide a coating material release agent and a coating material release sheet with less adverse effects.
本発明の目的を達成するために、本発明は請求の範囲に記載のような構成とするものである。
すなわち、本発明の塗装材剥離剤は、実質的にハロゲン系化合物を含まない組成物からなる塗装材剥離剤であって、上記組成物が沸点１１３℃〜２３０℃である非ハロゲン系高沸点有機溶剤と重量平均分子量が１万〜１００万である可溶性有機高分子化合物とチクソトロピー剤とを含む。
この場合、上記非ハロゲン系高沸点有機溶剤と上記可溶性有機高分子化合物からなる溶液１００重量部に対して、上記可溶性有機高分子化合物を１〜５０重量部、上記チクソトロピー剤を１〜１５重量部配合する。
また、本発明の塗装材剥離シートは、上記塗装材剥離剤をシート基材に含浸させる。
この場合、上記シート基材を、不織布等の繊維集合体と有機フィルム基材とからなる複合基材とする。
また、これらの場合、上記塗装材剥離シートを、上記複合基材の上記塗装材剥離剤を含浸させた面同士を２枚重ね合わせた構成とする。
また、これらの場合、上記シート基材に上記塗装材剥離剤を１００〜２０００ｇ／ｍ２含浸させる。In order to achieve the object of the present invention, the present invention is configured as described in the claims.
That is, the coating material release agent of the present invention is a coating material release agent comprising a composition that does not substantially contain a halogen compound, and the above composition has a boiling point of 113 ° C. to 230 ° C. It contains a solvent, a soluble organic polymer compound having a weight average molecular weight of 10,000 to 1,000,000 and a thixotropic agent.
In this case, 1 to 50 parts by weight of the soluble organic polymer compound and 1 to 15 parts by weight of the thixotropic agent with respect to 100 parts by weight of the solution comprising the non-halogen high boiling point organic solvent and the soluble organic polymer compound. Blend.
Moreover, the coating material peeling sheet of this invention makes a sheet base material impregnate the said coating material peeling agent.
In this case, let the said sheet | seat base material be a composite base material which consists of fiber assemblies, such as a nonwoven fabric, and an organic film base material.
In these cases, the coating material release sheet has a configuration in which two surfaces of the composite base material impregnated with the coating material release agent are overlapped.
In these cases, the sheet base material is impregnated with 100 to 2000 g / m 2 of the coating material remover.
上記目的を達成する為に、発明者らは各種材料・プロセスを検討した結果、少なくとも、非ハロゲン系高沸点有機溶剤と可溶性有機高分子化合物及びチクソトロピー剤を主成分としてなる実質的にハロゲン系化合物を含まない組成物を塗装材剥離剤として使用すればよいことを見出した。また、この場合、必要に応じ、界面活性剤、着色剤や充填剤などを添加しても良いことを見出した。
更に、上記した塗装材剥離剤をシート基材に含浸させた塗装材剥離シートとして、使用すれば良いことを見出した。この場合、シート基材に、不織布等の繊維集合体と有機フィルムとの複合基材を使用し、このシート基材の不織布等の繊維集合体の面に塗装材剥離剤を含浸させた塗装材剥離シートとして使用すれば良いことを見出した。
また、上記塗装材剥離シートは、使用前は、不織布面にセパレーターを重ねておくこともできるが、作製時に、２枚の塗装材剥離シートの塗装材剥離剤を含浸させた面同士を重ねておくと、使用時のごみの発生もなく、また、塗装材剥離シートの不織布面にセパレーターを重ねていないので、セパレーターに塗装材剥離剤を取られることもなく、極めて好都合であった。
すなわち、建築物や木材、船舶、車両、工業用製品、設備等の塗装材の剥離に使用する場合には、本発明の塗装材剥離剤を剥離しようとする塗装材に塗布するか、あるいは、塗装材剥離シートの塗装材剥離剤を含浸した面を剥離しようとする塗装材に貼り付け、塗装材を軟化させ、可塑化させることにより、ヘラ等により下地より塗装材を容易に剥離させることができる。
特に、塗装材剥離シートを使用した剥離方法では、当然のことながら、塗装材剥離剤の塗布むらもなく、また、塗装材剥離剤の揮発などもほとんどないことから、均一に、かつ、安定して塗装材を剥離させることができ、剥離に要する作業時間を短縮することができ、難しい熟練度も必要ではなくなる。
次に、本発明で使用される各種材料について、説明する。
非ハロゲン系高沸点有機溶剤としては、沸点が１１３℃〜２３０℃の範囲である有機溶剤が望ましい。さらに好ましくは、沸点が１５６℃〜２３０℃の範囲である有機溶剤が望ましい。沸点が１１３℃未満の場合、溶剤が揮発し易く、塗装材を剥離し難くなり、沸点が２３０℃を超えると、塗装材への浸透力が低下し、剥離性能が劣る。非ハロゲン系高沸点有機溶剤としては、例えば、メチルセロソルブ、ブチルセロソルブ、プロパギルアルコールなどのアルコール系有機溶剤、メチルセロソルブアセテート、エチルセロソルブアセテート、ブチルセロソルブアセテートなどの酢酸エステル系有機溶剤、ジエチレングリコールモノエチルエーテル（カルビトール）、ジエチレングリコールモノメチルエーテル、ジエチレングリコールモノ−ｎ−ブチルエーテル（ブチルカルビトール）、ジエチレングリコールジメチルエーテル、ジエチレングリコールジエチルエーテル、ジエチレングリコールジ−ｎ−ブチルエーテル、ジエチレングリコールモノエチルエーテルアセテート（カルビトールアセテート）、ジエチレングリコールモノ−ｎ−ブチルエーテルアセテートなどのグリコールエーテル類、シクロヘキサノン、Ｎ−メチル−２−ピロリジノン、ピルビン酸メチル、ピルビン酸エチル、Ｎ，Ｎ−ジメチルアセトアミドなどが挙げられる。これらの非ハロゲン系高沸点有機溶剤は、単独もしくは２種類以上混合して使用される。
使用される非ハロゲン系高沸点有機溶剤としては、剥離性能が高いことは勿論のこと、臭気が少ないこと、安全性が高いこと、などが必要である。
更に、塗装材剥離剤の粘度を上げると同時に、塗装材剥離シートを塗装材へ貼り合わせた際の塗装材への密着性、塗装材剥離シートの保持性を高めるために、可溶性有機高分子化合物を使用する。本発明で使用される可溶性有機高分子化合物としては、重量平均分子量が１万〜１００万の範囲の可溶性有機高分子化合物が好ましく、例えば、商品名バイロンＲＶ−１０３、バイロンＲＶ−２００などのポリエステル系高分子材料、商品名パラクロンＳＮ−５０ＤＲ、パラクロンＡＳ−３０００ＤＲ、パラクロンＭＥ−３５００ＤＲなどのポリアクリル酸エステル系高分子材料、商品名ハイパールＭ−４００３、ハイパールＭ−４００６、ハイパールＭ−４２０２、ハイパールＭ−５０００、ハイパールＭ−５００１、ハイパールＭ−４５０１などのポリメタクリル酸エステル系高分子材料などが挙げられる。
その配合量は、上記非ハロゲン系高沸点有機溶剤と上記可溶性有機高分子化合物からなる溶液１００重量部に対して、１〜５０重量部であることが好ましい。さらに好ましくは、１〜３０重量部であることが好ましい。上記可溶性有機高分子化合物が１重量部より少ない場合には、塗装材剥離剤の保持性が低下し、また、５０重量部より多い場合には、特に、塗装材剥離剤が高粘度過ぎる為に、いずれの場合も実用上好ましくない。
なお、上記可溶性有機高分子化合物は、単独もしくは２種以上で使用される。
また、更に、塗装材剥離剤を塗装材へ塗布した際の塗装材剥離剤の保持性、及び、塗装材剥離シートを塗装材へ貼り合わせた際のシートの保持性を高めるために、チクソトロピー剤を使用する。本発明で使用されるチクソトロピー剤としては、微粉末あるいは超微粉末の有機系あるいは無機系化合物が挙げられ、例えば、商品名アエロジル２００、アエロジル３００、アエロジル３８０などの二酸化ケイ素系の超微粉末などが挙げられる。
その配合量は、上記非ハロゲン系高沸点有機溶剤と可溶性有機高分子化合物からなる溶液１００重量部に対して、１〜１５重量部であることが好ましい。チクソトロピー剤が１重量部より少ない場合には、塗装材剥離剤の保持性が低下し、また、１５重量部より多い場合には、塗装材剥離剤が複合基材に含浸しにくくなる為に、いずれの場合も実用上好ましくない。
さらに、必要に応じて、ノニオン系、アニオン系またはカチオン系界面活性剤、着色剤、その他充填剤を添加してもよい。
また、塗装材剥離シートに使用される基材としては、塗装材剥離剤を含浸でき、かつ、塗装材剥離剤の揮発を抑制し、安定して保持できるような基材が好ましく、例えば、不織布、フェルト、立毛編織物、起毛編織物等の繊維集合体と有機フィルムとの複合基材が挙げられる。繊維集合体の坪量としては、必要量の塗装材剥離剤を含漬・保持できる厚みであれば良いが、特に、坪量が２０〜２００ｇ／ｍ２であるものが好ましい。また、上記繊維集合体の替わりにスポンジ等からなるシートを用いても良い。
また、上記基材に含浸させる塗装材剥離剤の量は、剥離しようとする塗装材の種類にも依存するが、通常、１００〜２０００ｇ／ｍ２の範囲で含浸させることが望ましい。塗装材剥離剤の量が１００ｇ／ｍ２より少ない場合には、剥離性能が不十分となる場合があり、２０００ｇ／ｍ２より多い場合には、塗装材剥離剤の保持性の観点から、実用上好ましくない。
［具体例］
本発明の塗装材剥離剤をシート基材に含浸させた塗装材剥離シートを使用して、各種塗装材を剥離させた実験結果を具体例によって具体的に説明する。但し、本発明の塗装材剥離剤及び塗装材剥離シートは、これに限定されるものではない。
なお、具体例及び比較例の記述中における「部」は重量部を表わす。
〔具体例１〕
エチルセロソルブアセテート（沸点１５６℃）９０部、メチルセロソルブ（沸点１２５℃）９部、重量平均分子量約１００万のポリメタクリル酸エステル樹脂（根上工業製パラクロンＡＸ−２ＤＲ）１部、超微粉二酸化ケイ素（アエロジル２００）１５部を十分に混合し、粘度が約１００ｍＰａ・ｓ（測定条件：５回転、２５℃）のペースト状の塗装材剥離剤を得た。次に、上記塗装材剥離剤を坪量２０ｇ／ｍ２の不織布と１２μｍ厚のポリエステルフィルムとの複合基材からなる不織布面に、１００ｇ／ｍ２含浸させ、塗装材剥離シートを得た。この塗装材剥離シートは、シート基材の不織布部に塗装材剥離剤が適度に含浸されていた。なお、製品形態は、塗装材剥離剤を含浸させた不織布面同士を２枚重ね合わせた構成である。これにより、含浸させた塗装材剥離剤の全量使用が可能であり、極めて好都合となる。このようにして作製した塗装材剥離シートを使用して、各種塗装材を剥離させた。この場合、塗装材剥離剤が含浸しているシート基材の不織布面を塗装材面に押し付けて貼り付けた。塗装材剥離シートを貼り付けた塗装材剥離試験用の試料を垂直に立てて放置したが、塗装材剥離シートがずれることもなく、十分な保持性があることを確認した。その後、一定時間放置後、塗装材剥離シートを除去し、ヘラによって塗装材を剥離したが、剥離できるまでの時間に差はあるものの、いずれの塗装材もきれいに剥離することができた。
なお、実験に使用した塗装材（ＪＩＳ Ａ６９０９）のうち、商品名レナラック（呼び名、複層塗材Ｅ）、商品名セラミタウンマイルド、セラミタイトペイント、グラナダ、コートリシン（以上、呼び名、外装薄塗材Ｅ）、商品名スイセイセラミシリコン、日塗工Ｙ０５−８０Ｌ（以上、呼び名、防水系外装薄塗材Ｅ）、商品名弾性ロール（呼び名、防水系複層塗材Ｅ）については、２４時間放置後、ヘラによって塗装材を剥離することができた。また、上記以外の塗装材、商品名ファインコート（呼び名、外装厚塗材Ｅ）、商品名セラミスマイル、ベルアート（以上、呼び名、不明）については、４８時間放置後、ヘラによって塗装材を剥離することができた。
〔具体例２〕
ブチルカルビトール（沸点２３０℃）８５部、プロパギルアルコール（沸点１１３℃）１０部、重量平均分子量約１万のポリエステル樹脂（東洋紡績製バイロンＲＶ−６００）５部、超微粉二酸化ケイ素（アエロジル３００）８部を十分に混合し、粘度が約５００ｍＰａ・ｓ（測定条件：５回転、２５℃）のペースト状の塗装材剥離剤を得た。また、上記した塗装材剥離剤を坪量２００ｇ／ｍ２の不織布と１２μｍ厚のポリエステルフィルムとの複合基材からなる不織布面に、２０００ｇ／ｍ２含浸させ、塗装材剥離シートを得た。この塗装材剥離シートは、シート基材の不織布部に塗装材剥離剤が適度に含浸されていた。なお、製品形態は、塗装材剥離剤を含浸させた不織布面同士を２枚重ね合わせた構成である。これにより、含浸させた塗装材剥離剤の全量使用が可能であり、極めて好都合となる。このようにして作製した塗装材剥離シートを使用して、具体例１と同様に、各種塗装材を剥離させた。塗装材剥離シートを貼り付けた塗装材剥離試験用の試料を垂直に立てて放置したが、塗装材剥離シートがずれることもなく、十分な保持性があることを確認した。その後、一定時間放置後、塗装材剥離シートを除去し、ヘラによって塗装材を剥離したが、剥離できるまでの時間に差はあるものの、具体例１と同様に、いずれの塗装材もきれいに剥離することができた。
〔具体例３〕
カルビトールアセテート（沸点２１８℃）７２部、ピルビン酸エチル（沸点１４８℃）８部、重量平均分子量約２万のポリエステル樹脂（東洋紡績製バイロンＲＶ−１０３）２０部、超微粉二酸化ケイ素（アエロジル３００）６部を十分に混合し、粘度が約２５００ｍＰａ・ｓ（測定条件：５回転、２５℃）のペースト状の塗装材剥離剤を得た。また、上記した塗装材剥離剤を坪量１００ｇ／ｍ２の不織布と１２μｍ厚のポリエステルフィルムとの複合基材からなる不織布面に、８００ｇ／ｍ２含浸させ、塗装材剥離シートを得た。この塗装材剥離シートは、シート基材の不織布部に塗装材剥離剤が適度に含浸されていた。なお、製品形態は、塗装材剥離剤を含浸させた不織布面同士を２枚重ね合わせた構成である。これにより、含浸させた塗装材剥離剤の全量使用が可能であり、極めて好都合となる。このようにして作製した塗装材剥離シートを使用して、具体例１と同様に、各種塗装材を剥離させた。塗装材剥離シートを貼り付けた塗装材剥離試験用の試料を垂直に立てて放置したが、塗装材剥離シートがずれることもなく、十分な保持性があることを確認した。その後、一定時間放置後、塗装材剥離シートを除去し、ヘラによって塗装材を剥離したが、剥離できるまでの時間に差はあるものの、具体例１と同様に、いずれの塗装材もきれいに剥離することができた。
〔具体例４〕
カルビトールアセテート（沸点２１８℃）６５部、ピルビン酸メチル（沸点１２３℃）５部、重量平均分子量約２万のポリエステル樹脂（東洋紡績製バイロンＲＶ−１０３）３０部、超微粉二酸化ケイ素（アエロジル３００）６部を十分に混合し、粘度が約３０００ｍＰａ・ｓ（測定条件：５回転、２５℃）のペースト状の塗装材剥離剤を得た。また、上記した塗装材剥離剤を坪量１００ｇ／ｍ２の不織布と１２μｍ厚のポリエステルフィルムとの複合基材からなる不織布面に、１２００ｇ／ｍ２含浸させ、塗装材剥離シートを得た。この塗装材剥離シートは、シート基材の不織布部に塗装材剥離剤が適度に含浸されていた。なお、製品形態は、塗装材剥離剤を含浸させた不織布面同士を２枚重ね合わせた構成である。これにより、含浸させた塗装材剥離剤の全量使用が可能であり、極めて好都合となる。このようにして作製した塗装材剥離シートを使用して、具体例１と同様に、各種塗装材を剥離させた。塗装材剥離シートを貼り付けた塗装材剥離試験用の試料を垂直に立てて放置したが、塗装材剥離シートがずれることもなく、十分な保持性があることを確認した。その後、一定時間放置後、塗装材剥離シートを除去し、ヘラによって塗装材を剥離したが、剥離できるまでの時間に差はあるものの、具体例１と同様に、いずれの塗装材もきれいに剥離することができた。
〔具体例５〕
カルビトール（沸点２０２℃）４０部、Ｎ−メチル−２−ピロリジノン（沸点２０２℃）１０部、重量平均分子量約６０万のポリアクリル酸エステル樹脂（根上工業製ハイパールＭ−４００３）５０部、超微粉二酸化ケイ素（アエロジル３８０）１部を十分に混合し、粘度が約４５００ｍＰａ・ｓ（測定条件：５回転、２５℃）のペースト状の塗装材剥離剤を得た。また、上記した塗装材剥離剤を坪量８０ｇ／ｍ２の不織布と１２μｍ厚のポリエステルフィルムとの複合基材からなる不織布面に、５００ｇ／ｍ２含浸させ、塗装材剥離シートを得た。この塗装材剥離シートは、シート基材の不織布部に塗装材剥離剤が適度に含浸されていた。なお、製品形態は、塗装材剥離剤を含浸させた不織布面同士を２枚重ね合わせた構成である。これにより、含浸させた塗装材剥離剤の全量使用が可能であり、極めて好都合となる。このようにして作製した塗装材剥離シートを使用して、具体例１と同様に、各種塗装材を剥離させた。塗装材剥離シートを貼り付けた塗装材剥離試験用の試料を垂直に立てて放置したが、塗装材剥離シートがずれることもなく、十分な保持性があることを確認した。その後、一定時間放置後、塗装材剥離シートを除去し、ヘラによって塗装材を剥離したが、剥離できるまでの時間に差はあるものの、具体例１と同様に、いずれの塗装材もきれいに剥離することができた。
〔具体例６〕
Ｎ−メチル−２−ピロリジノン（沸点２０２℃）６０部、カルビトールアセテート（沸点２１８℃）２０部、重量平均分子量約２万のポリエステル樹脂（東洋紡績製バイロンＲＶ−１０３）２０部、超微粉二酸化ケイ素（アエロジル３００）６部を十分に混合し、粘度が約２５００ｍＰａ・ｓ（測定条件：５回転、２５℃）のペースト状の塗装材剥離剤を得た。また、上記した塗装材剥離剤を坪量５０ｇ／ｍ２の不織布と１２μｍ厚のポリエステルフィルムとの複合基材からなる不織布面に、２００ｇ／ｍ２含浸させ、塗装材剥離シートを得た。この塗装材剥離シートは、シート基材の不織布部に塗装材剥離剤が適度に含浸されていた。なお、製品形態は、塗装材剥離剤を含浸させた不織布面同士を２枚重ね合わせた構成である。これにより、含浸させた塗装材剥離剤の全量使用が可能であり、極めて好都合となる。このようにして作製した塗装材剥離シートを使用して、具体例１と同様に、各種塗装材を剥離させた。塗装材剥離シートを貼り付けた塗装材剥離試験用の試料を垂直に立てて放置したが、塗装材剥離シートがずれることもなく、十分な保持性があることを確認した。その後、一定時間放置後、塗装材剥離シートを除去し、ヘラによって塗装材を剥離したが、剥離できるまでの時間に差はあるものの、具体例１と同様に、いずれの塗装材もきれいに剥離することができた。
以上のように、本発明の塗装材剥離剤及び塗装材剥離シートは、優れた剥離性を示すとともに、作業性にも優れていることを確認した。
〔比較例１〕
塗装材剥離剤の塗布量を５０ｇ／ｍ２とした以外は、具体例３と同様の配合並びに構成にて塗装材剥離シートを得た。この塗装材剥離シートは、シート基材の不織布部に塗装材剥離剤が適度に含浸されていたが、具体例３と同様に、塗装材剥離シートを貼り付けた塗装材剥離試験用の試料を垂直に立てて２４時間放置したところ、塗装材剥離シートがずれ、シート保持性が不十分であることが分かった。
〔比較例２〕
塗装材剥離剤の塗布量を２５００ｇ／ｍ２とした以外は、具体例３と同様の配合並びに構成にて塗装材剥離シートを得た。この塗装材剥離シートは、シート基材の不織布部に塗装材剥離剤が適度に含浸されていたが、具体例３と同様に、塗装材剥離シートを貼り付けた塗装材剥離試験用の試料を垂直に立てて２４時間放置したところ、塗装材剥離シートがずれ、シート保持性が不十分であることが分かった。
〔比較例３〕
可溶性有機高分子化合物を使用しなかったこと以外は、具体例１と同様の配合並びに構成にて塗装材剥離シートを得た。この塗装材剥離シートは、シート基材の不織布部に塗装材剥離剤が適度に含浸されていなかった。また、具体例１と同様に、塗装材剥離シートを貼り付けた塗装材剥離試験用の試料を垂直に立てて２４時間放置したところ、塗装材剥離シートがずれ、シート保持性が不十分であることが分かった。
〔比較例４〕
チクソトロピー剤を使用しなかったこと以外は、具体例２と同様の配合並びに構成にて塗装材剥離シートを得た。この塗装材剥離シートは、シート基材の不織布部に塗装材剥離剤が適度に含浸されていたが、具体例２と同様に、塗装材剥離シートを貼り付けた塗装材剥離試験用の試料を垂直に立てて２４時間放置したところ、塗装材剥離シートがずれ、シート保持性が不十分であることが分かった。
〔比較例５〕
可溶性有機高分子材料の配合量を６０部としたこと以外は、具体例３と同様の配合並びに構成にて塗装材剥離シートを得た。この塗装材剥離シートは、シート基材の不織布部へ塗装材剥離剤が含浸しにくく、具体例３と同様に、塗装材剥離シートを貼り付けた塗装材剥離試験用の試料を垂直に立てて２４時間放置したところ、塗装材剥離剤の浸透性が不十分であることが分かった。
〔比較例６〕
チクソトロピー剤の配合量を２０部としたこと以外は、具体例４と同様の配合並びに構成にて塗装材剥離シートを得た。この塗装材剥離シートは、シート基材の不織布部に塗装材剥離剤が適度に含浸されていなかった。また、具体例１と同様に、塗装材剥離シートを貼り付けた塗装材剥離試験用の試料を垂直に立てて２４時間放置したところ、塗装材剥離シートがずれ、シート保持性が不十分であることが分かった。また、塗装材剥離剤の浸透性が不十分であることも分かった。
〔比較例７〕
基材に複合基材でなく、不織布単体を使用したこと以外は、具体例５と同様の配合並びに構成にて塗装材剥離シートを得た。この塗装材剥離シートは、シート基材の不織布部に塗装材剥離剤が適度に含浸されていたが、具体例５と同様に、塗装材剥離シートを貼り付けた塗装材剥離試験用の試料を垂直に立てて２４時間放置したところ、塗装材剥離剤の揮発が認められた。また、塗装材剥離シートがずれ、シート保持性が不十分であることが分かった。In order to achieve the above object, the inventors have studied various materials and processes, and as a result, have substantially at least a halogen-based compound mainly composed of a non-halogen high-boiling organic solvent, a soluble organic polymer compound, and a thixotropic agent. It has been found that a composition that does not contain a coating material may be used as a coating material release agent. Moreover, in this case, it discovered that surfactant, a coloring agent, a filler, etc. may be added as needed.
Furthermore, it discovered that it should just be used as a coating material peeling sheet which impregnated the above-mentioned coating material peeling agent in the sheet base material. In this case, a coating material in which a composite substrate of a fiber assembly such as a nonwoven fabric and an organic film is used as a sheet base material, and a surface of the fiber assembly such as a nonwoven fabric of the sheet base material is impregnated with a coating material release agent. It has been found that it can be used as a release sheet.
Moreover, the said coating material peeling sheet can also overlap | separate a separator on a nonwoven fabric surface before use, but piles the surfaces which impregnated the coating material peeling agent of two coating material peeling sheets at the time of preparation. In other words, there was no generation of dust during use, and since the separator was not stacked on the nonwoven fabric surface of the coating material release sheet, the coating material release agent was not taken off by the separator, which was very convenient.
That is, when used for peeling coating materials such as buildings, wood, ships, vehicles, industrial products, equipment, etc., apply the coating material remover of the present invention to the coating material to be peeled, or The surface of the coating material release sheet impregnated with the coating material release agent is affixed to the coating material to be peeled, and the coating material is softened and plasticized so that the coating material can be easily peeled off from the ground with a spatula or the like. it can.
In particular, in the peeling method using the coating material release sheet, it is natural that there is no uneven coating material release agent and there is almost no volatilization of the coating material release agent. Thus, the coating material can be peeled off, the working time required for peeling can be shortened, and difficult skill level is not required.
Next, various materials used in the present invention will be described.
As the non-halogen high boiling organic solvent, an organic solvent having a boiling point in the range of 113 ° C to 230 ° C is desirable. More preferably, an organic solvent having a boiling point in the range of 156 ° C to 230 ° C is desirable. When the boiling point is less than 113 ° C., the solvent tends to volatilize and it is difficult to peel the coating material. When the boiling point exceeds 230 ° C., the penetrating power to the coating material is reduced and the peeling performance is poor. Non-halogen high boiling point organic solvents include, for example, alcoholic organic solvents such as methyl cellosolve, butyl cellosolve, propargyl alcohol, acetate organic solvents such as methyl cellosolve acetate, ethyl cellosolve acetate, butyl cellosolve acetate, diethylene glycol monoethyl ether ( Carbitol), diethylene glycol monomethyl ether, diethylene glycol mono-n-butyl ether (butyl carbitol), diethylene glycol dimethyl ether, diethylene glycol diethyl ether, diethylene glycol di-n-butyl ether, diethylene glycol monoethyl ether acetate (carbitol acetate), diethylene glycol mono-n- Glyco such as butyl ether acetate Ethers, cyclohexanone, N- methyl-2-pyrrolidinone, methyl pyruvate, ethyl pyruvate, N, etc. N- dimethylacetamide. These non-halogen high boiling organic solvents are used alone or in combination of two or more.
The non-halogen high boiling point organic solvent to be used is required to have not only high peeling performance but also low odor and high safety.
Furthermore, in order to increase the viscosity of the coating material release agent and at the same time improve the adhesion to the coating material and the retention of the coating material release sheet when the coating material release sheet is bonded to the coating material, a soluble organic polymer compound Is used. The soluble organic polymer compound used in the present invention is preferably a soluble organic polymer compound having a weight average molecular weight in the range of 10,000 to 1,000,000, for example, polyesters such as trade names Byron RV-103 and Byron RV-200. -Based polymer materials, trade name Paraclone SN-50DR, Paraclone AS-3000DR, polyacrylic acid ester-based polymer materials such as Paraclone ME-3500DR, trade names Hyperl M4003, Hyperl M-4006, Hyperl M-4202, Hyperl Examples thereof include polymethacrylic acid ester polymer materials such as M-5000, Hyperl M-5001, and Hyperl M-4501.
The blending amount is preferably 1 to 50 parts by weight with respect to 100 parts by weight of the solution composed of the non-halogen high boiling organic solvent and the soluble organic polymer compound. More preferably, it is 1-30 weight part. When the amount of the soluble organic polymer compound is less than 1 part by weight, the retentivity of the coating material release agent is lowered, and when it is more than 50 parts by weight, the coating material release agent is particularly too viscous. In either case, it is not practically preferable.
The soluble organic polymer compounds are used alone or in combination of two or more.
Furthermore, a thixotropic agent is used to enhance the retention of the coating material release agent when the coating material release agent is applied to the coating material, and the retention of the sheet when the coating material release sheet is bonded to the coating material. Is used. Examples of the thixotropic agent used in the present invention include fine or ultrafine organic or inorganic compounds such as silicon dioxide ultrafine powders such as trade names Aerosil 200, Aerosil 300, and Aerosil 380. Is mentioned.
The blending amount is preferably 1 to 15 parts by weight with respect to 100 parts by weight of the solution composed of the non-halogen high boiling point organic solvent and the soluble organic polymer compound. When the thixotropic agent is less than 1 part by weight, the retentivity of the coating material release agent is lowered, and when it is more than 15 parts by weight, the coating material release agent is less likely to be impregnated into the composite substrate. Either case is not practically preferable.
Furthermore, nonionic, anionic or cationic surfactants, colorants, and other fillers may be added as necessary.
The base material used for the coating material release sheet is preferably a base material that can be impregnated with the coating material release agent and that can suppress the volatilization of the coating material release agent and can be stably maintained. And a composite base material of an organic film and a fiber assembly such as felt, napping knitted fabric, and raised knitted fabric. The basis weight of the fiber assembly may be any thickness as long as a necessary amount of the coating material release agent can be included and retained, but a basis weight of 20 to 200 g / m 2 is particularly preferable. Further, a sheet made of sponge or the like may be used instead of the fiber assembly.
Further, the amount of the coating material remover to be impregnated into the substrate depends on the type of the coating material to be peeled, but it is usually desirable to impregnate in the range of 100 to 2000 g / m 2 . When the amount of the coating material release agent is less than 100 g / m 2 , the release performance may be insufficient. When the amount is more than 2000 g / m 2 , it is practical from the viewpoint of the retention of the coating material release agent. Not preferable.
[Concrete example]
The experimental results of peeling various coating materials using the coating material peeling sheet in which the sheet base material is impregnated with the coating material peeling agent of the present invention will be specifically described by way of specific examples. However, the coating material release agent and the coating material release sheet of the present invention are not limited thereto.
In the description of specific examples and comparative examples, “parts” represents parts by weight.
[Specific Example 1]
90 parts of ethyl cellosolve acetate (boiling point 156 ° C.), 9 parts of methyl cellosolve (boiling point 125 ° C.), 1 part of polymethacrylate resin (parachlone AX-2DR manufactured by Negami Kogyo Co., Ltd.) having a weight average molecular weight of 1 part, ultrafine silicon dioxide ( 15 parts of Aerosil 200) were sufficiently mixed to obtain a paste-like coating material release agent having a viscosity of about 100 mPa · s (measurement conditions: 5 revolutions, 25 ° C.). Next, the coating material release agent was impregnated with 100 g / m 2 on a nonwoven fabric surface composed of a composite base material of a nonwoven fabric having a basis weight of 20 g / m 2 and a polyester film having a thickness of 12 μm to obtain a coating material release sheet. In this coating material release sheet, the nonwoven fabric portion of the sheet base material was appropriately impregnated with the coating material release agent. In addition, a product form is the structure which laminated | stacked two sheets of nonwoven fabric surfaces impregnated with the coating material release agent. As a result, the entire amount of the impregnated coating material release agent can be used, which is extremely convenient. Various coating materials were peeled off using the coating material release sheet thus prepared. In this case, the nonwoven fabric surface of the sheet base material impregnated with the coating material release agent was pressed against the coating material surface for pasting. The sample for the coating material peeling test with the coating material peeling sheet attached was left standing vertically, but it was confirmed that the coating material peeling sheet did not shift and had sufficient retention. Then, after leaving for a certain period of time, the coating material release sheet was removed, and the coating material was peeled off with a spatula. However, although there was a difference in the time until peeling was possible, all of the coating materials could be peeled cleanly.
Among the coating materials used in the experiment (JIS A6909), the product name Lenalac (nominal name, multi-layer coating material E), the product name Ceramy Town Mild, Ceramitite Paint, granada, coat lysine (name, exterior thin coating material E). ), Product name Suisei Ceramy Silicon, Nikko Y05-80L (named, waterproof exterior thin coating material E), product name elastic roll (name, waterproof multilayer coating material E), left for 24 hours, then spatula It was possible to peel off the coating material. For paint materials other than the above, trade name fine coat (nominal name, exterior thick coating material E), trade name Ceramismile, bell art (name, unknown name, unknown), left for 48 hours, and then peel off the paint material with a spatula. We were able to.
[Specific Example 2]
85 parts of butyl carbitol (boiling point 230 ° C.), 10 parts of propargyl alcohol (boiling point 113 ° C.), 5 parts of a polyester resin having a weight average molecular weight of about 10,000 (Toyobo's Byron RV-600), ultrafine silicon dioxide (Aerosil 300) ) 8 parts were mixed well to obtain a paste-like coating material release agent having a viscosity of about 500 mPa · s (measurement conditions: 5 revolutions, 25 ° C.). Moreover, the above-mentioned coating material release agent was impregnated at 2000 g / m 2 on a nonwoven fabric surface composed of a composite base material of a nonwoven fabric having a basis weight of 200 g / m 2 and a polyester film having a thickness of 12 μm to obtain a coating material release sheet. In this coating material release sheet, the nonwoven fabric portion of the sheet base material was appropriately impregnated with the coating material release agent. In addition, a product form is the structure which laminated | stacked two sheets of nonwoven fabric surfaces impregnated with the coating material release agent. As a result, the entire amount of the impregnated coating material release agent can be used, which is extremely convenient. Using the coating material release sheet thus prepared, various coating materials were peeled in the same manner as in Example 1. The sample for the coating material peeling test with the coating material peeling sheet attached was left standing vertically, but it was confirmed that the coating material peeling sheet did not shift and had sufficient retention. Then, after leaving for a certain period of time, the coating material release sheet was removed, and the coating material was peeled off with a spatula. I was able to.
[Specific Example 3]
72 parts of carbitol acetate (bp 218 ° C.), 8 parts of ethyl pyruvate (boiling point 148 ° C.), 20 parts of polyester resin having a weight average molecular weight of about 20,000 (Toyobo's Byron RV-103), ultrafine silicon dioxide (Aerosil 300) ) 6 parts were mixed well to obtain a paste-like coating material release agent having a viscosity of about 2500 mPa · s (measurement conditions: 5 revolutions, 25 ° C.). Moreover, the above-mentioned coating material release agent was impregnated with 800 g / m 2 on a nonwoven fabric surface composed of a composite base material of a nonwoven fabric having a basis weight of 100 g / m 2 and a polyester film having a thickness of 12 μm to obtain a coating material release sheet. In this coating material release sheet, the nonwoven fabric portion of the sheet base material was appropriately impregnated with the coating material release agent. In addition, a product form is the structure which laminated | stacked two sheets of nonwoven fabric surfaces impregnated with the coating material release agent. As a result, the entire amount of the impregnated coating material release agent can be used, which is extremely convenient. Using the coating material release sheet thus prepared, various coating materials were peeled in the same manner as in Example 1. The sample for the coating material peeling test with the coating material peeling sheet attached was left standing vertically, but it was confirmed that the coating material peeling sheet did not shift and had sufficient retention. Then, after leaving for a certain period of time, the coating material release sheet was removed, and the coating material was peeled off with a spatula. I was able to.
[Specific Example 4]
65 parts of carbitol acetate (boiling point 218 ° C.), 5 parts of methyl pyruvate (boiling point 123 ° C.), 30 parts of a polyester resin having a weight average molecular weight of about 20,000 (Byron RV-103 manufactured by Toyobo), ultrafine silicon dioxide (Aerosil 300) ) 6 parts were mixed well to obtain a paste-like coating material release agent having a viscosity of about 3000 mPa · s (measurement conditions: 5 revolutions, 25 ° C.). Moreover, the coating material release agent was impregnated at 1200 g / m 2 on a nonwoven fabric surface composed of a composite base material of a nonwoven fabric having a basis weight of 100 g / m 2 and a polyester film having a thickness of 12 μm to obtain a coating material release sheet. In this coating material release sheet, the nonwoven fabric portion of the sheet base material was appropriately impregnated with the coating material release agent. In addition, a product form is the structure which laminated | stacked two sheets of nonwoven fabric surfaces impregnated with the coating material release agent. As a result, the entire amount of the impregnated coating material release agent can be used, which is extremely convenient. Using the coating material release sheet thus prepared, various coating materials were peeled in the same manner as in Example 1. The sample for the coating material peeling test with the coating material peeling sheet attached was left standing vertically, but it was confirmed that the coating material peeling sheet did not shift and had sufficient retention. Then, after leaving for a certain period of time, the coating material release sheet was removed, and the coating material was peeled off with a spatula. I was able to.
[Specific Example 5]
40 parts of carbitol (boiling point 202 ° C.), 10 parts of N-methyl-2-pyrrolidinone (boiling point 202 ° C.), 50 parts of a polyacrylic ester resin (Negami Kogyo Hyperl M4003) having a weight average molecular weight of about 600, One part of finely divided silicon dioxide (Aerosil 380) was sufficiently mixed to obtain a paste-like coating material release agent having a viscosity of about 4500 mPa · s (measurement conditions: 5 revolutions, 25 ° C.). Moreover, the above-mentioned coating material release agent was impregnated with 500 g / m 2 on a nonwoven fabric surface composed of a composite base material of a nonwoven fabric having a basis weight of 80 g / m 2 and a polyester film having a thickness of 12 μm to obtain a coating material release sheet. In this coating material release sheet, the nonwoven fabric portion of the sheet base material was appropriately impregnated with the coating material release agent. In addition, a product form is the structure which laminated | stacked two sheets of nonwoven fabric surfaces impregnated with the coating material release agent. As a result, the entire amount of the impregnated coating material release agent can be used, which is extremely convenient. Using the coating material release sheet thus prepared, various coating materials were peeled in the same manner as in Example 1. The sample for the coating material peeling test with the coating material peeling sheet attached was left standing vertically, but it was confirmed that the coating material peeling sheet did not shift and had sufficient retention. Then, after leaving for a certain period of time, the coating material release sheet was removed, and the coating material was peeled off with a spatula, but although there is a difference in the time until it can be peeled off, all the coating materials are peeled off cleanly as in Example 1. I was able to.
[Specific Example 6]
60 parts of N-methyl-2-pyrrolidinone (boiling point 202 ° C.), 20 parts of carbitol acetate (boiling point 218 ° C.), 20 parts of a polyester resin having a weight average molecular weight of about 20,000 (Byron RV-103 manufactured by Toyobo), ultrafine powder dioxide 6 parts of silicon (Aerosil 300) was sufficiently mixed to obtain a paste-like coating material release agent having a viscosity of about 2500 mPa · s (measurement conditions: 5 revolutions, 25 ° C.). The coating material release agent was impregnated with 200 g / m 2 on a nonwoven fabric surface composed of a composite base material of a nonwoven fabric having a basis weight of 50 g / m 2 and a polyester film having a thickness of 12 μm to obtain a coating material release sheet. In this coating material release sheet, the nonwoven fabric portion of the sheet base material was appropriately impregnated with the coating material release agent. In addition, a product form is the structure which laminated | stacked two sheets of nonwoven fabric surfaces impregnated with the coating material release agent. As a result, the entire amount of the impregnated coating material release agent can be used, which is extremely convenient. Using the coating material release sheet thus prepared, various coating materials were peeled in the same manner as in Example 1. The sample for the coating material peeling test with the coating material peeling sheet attached was left standing vertically, but it was confirmed that the coating material peeling sheet did not shift and had sufficient retention. Then, after leaving for a certain period of time, the coating material release sheet was removed, and the coating material was peeled off with a spatula, but although there is a difference in the time until it can be peeled off, all the coating materials are peeled off cleanly as in Example 1. I was able to.
As described above, it was confirmed that the coating material release agent and the coating material release sheet of the present invention showed excellent peelability and excellent workability.
[Comparative Example 1]
A coating material release sheet was obtained with the same composition and configuration as in Example 3 except that the coating amount of the coating material release agent was 50 g / m 2 . In this coating material release sheet, the nonwoven fabric portion of the sheet base material was appropriately impregnated with the coating material release agent. As in Example 3, a sample for a coating material peeling test with the coating material release sheet attached was used. After standing upright for 24 hours, it was found that the paint release sheet was displaced and the sheet retention was insufficient.
[Comparative Example 2]
A coating material release sheet was obtained with the same composition and configuration as in Example 3 except that the coating amount of the coating material release agent was 2500 g / m 2 . In this coating material release sheet, the nonwoven fabric portion of the sheet base material was appropriately impregnated with the coating material release agent. As in Example 3, a sample for a coating material peeling test with the coating material release sheet attached was used. After standing upright for 24 hours, it was found that the paint release sheet was displaced and the sheet retention was insufficient.
[Comparative Example 3]
A coating material release sheet was obtained with the same composition and configuration as in Example 1 except that the soluble organic polymer compound was not used. In this coating material release sheet, the nonwoven fabric portion of the sheet base material was not appropriately impregnated with the coating material release agent. Further, as in Example 1, when the coating material peeling test sample with the coating material peeling sheet attached was placed vertically and left for 24 hours, the coating material peeling sheet was displaced and the sheet retention was insufficient. I understood that.
[Comparative Example 4]
A coating material release sheet was obtained with the same composition and configuration as in Example 2 except that the thixotropic agent was not used. In this coating material release sheet, the coating material release agent was appropriately impregnated in the nonwoven fabric portion of the sheet base material, but in the same manner as in Example 2, a sample for coating material peeling test with the coating material release sheet attached was used. After standing upright for 24 hours, it was found that the paint release sheet was displaced and the sheet retention was insufficient.
[Comparative Example 5]
A coating material release sheet was obtained with the same composition and configuration as in Example 3 except that the amount of the soluble organic polymer material was 60 parts. This coating material release sheet is difficult to impregnate the coating material release agent into the non-woven fabric portion of the sheet base material, and in the same manner as in Example 3, the sample for the coating material peeling test with the coating material release sheet attached is vertically set up. When left for 24 hours, it was found that the permeability of the coating material remover was insufficient.
[Comparative Example 6]
A coating material release sheet was obtained with the same composition and configuration as in Example 4 except that the amount of the thixotropic agent was 20 parts. In this coating material release sheet, the nonwoven fabric portion of the sheet base material was not appropriately impregnated with the coating material release agent. Further, as in Example 1, when the coating material peeling test sample with the coating material peeling sheet attached was placed vertically and left for 24 hours, the coating material peeling sheet was displaced and the sheet retention was insufficient. I understood that. It was also found that the coating material remover has insufficient permeability.
[Comparative Example 7]
A coating material release sheet was obtained with the same composition and configuration as in Example 5 except that the substrate was not a composite substrate but a single nonwoven fabric. In this coating material release sheet, the coating material release agent was appropriately impregnated in the nonwoven fabric portion of the sheet base material, but in the same manner as in Example 5, the sample for the coating material peeling test with the coating material release sheet attached was used. After standing upright for 24 hours, volatilization of the coating material remover was observed. Moreover, it turned out that a coating material peeling sheet slip | deviates and sheet retention is inadequate.
以上、説明したように、本発明は、沸点１１３℃〜２３０℃である非ハロゲン系高沸点有機溶剤と重量平均分子量が１万〜１００万である可溶性有機高分子化合物とチクソトロピー剤とを主成分とする実質的にハロゲン系化合物を含まない組成物を塗装材剥離剤とし、また、上記塗装材剥離剤を不織布等の繊維集合体と有機フィルム基材とからなるシート基材に含浸させた塗装材剥離シートとしたものであるから、本発明の実施によって、塗装材に対して優れた軟化性を有し、かつ、安全で、環境汚染の面においても優れた塗装材剥離剤及び塗装材剥離シートを提供することができる。 As described above, the present invention is mainly composed of a non-halogen high boiling point organic solvent having a boiling point of 113 ° C. to 230 ° C., a soluble organic polymer compound having a weight average molecular weight of 10,000 to 1,000,000, and a thixotropic agent. A coating material release agent comprising a composition substantially free of a halogen compound, and a coating material obtained by impregnating a sheet base material comprising a fiber assembly such as a nonwoven fabric and an organic film base material with the coating material release agent. Since it is a material release sheet, the present invention has excellent softening properties for coating materials, is safe, and is excellent in terms of environmental pollution. Sheets can be provided.
Claims (6)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2006531360A JP5226213B2 (en) | 2004-07-14 | 2005-07-08 | Coating material release agent and coating material release sheet |
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2004206953 | 2004-07-14 | ||
| JP2004206953 | 2004-07-14 | ||
| JP2006531360A JP5226213B2 (en) | 2004-07-14 | 2005-07-08 | Coating material release agent and coating material release sheet |
| PCT/JP2005/013108 WO2006013713A1 (en) | 2004-07-14 | 2005-07-08 | Coating material stripping agent and coating material stripping sheet |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPWO2006013713A1 true JPWO2006013713A1 (en) | 2008-05-01 |
| JP5226213B2 JP5226213B2 (en) | 2013-07-03 |
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| Application Number | Title | Priority Date | Filing Date |
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| JP2006531360A Expired - Fee Related JP5226213B2 (en) | 2004-07-14 | 2005-07-08 | Coating material release agent and coating material release sheet |
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| Country | Link |
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| JP (1) | JP5226213B2 (en) |
| TW (1) | TW200606229A (en) |
| WO (1) | WO2006013713A1 (en) |
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| JP4457206B1 (en) * | 2009-05-13 | 2010-04-28 | 国立大学法人 岡山大学 | Coating film removing agent and coating film removing method using the same |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5920400A (en) * | 1982-07-27 | 1984-02-02 | 滝口 好 | Detergent |
| JPH06501284A (en) * | 1990-10-01 | 1994-02-10 | ヴェロナ インコーポレイテッド | Method for activating N-methyl-2-pyrrolidone (NMP) and/or γ-butyrolactone (BLO) varnish and paint removal solvents |
| JPH10279850A (en) * | 1997-04-04 | 1998-10-20 | Yamaichi Kagaku Kogyo Kk | Paint remover for wall surface or the like and method for removing therewith |
| JPH11513724A (en) * | 1995-10-18 | 1999-11-24 | エルフ アトケム ソシエテ アノニム | Concentrated composition for paint peeling |
| JP2000001637A (en) * | 1998-06-15 | 2000-01-07 | Yamaichi Kagaku Kogyo Kk | Release agent for coating film of outer wall or the like and plastic tile and peeling |
| JP2000017289A (en) * | 1998-07-01 | 2000-01-18 | Car Mate Mfg Co Ltd | Peeling composition for glassy film and peeling method |
| JP2000290543A (en) * | 1999-03-25 | 2000-10-17 | Atofina | Releasing composition used especially in building industry |
| JP2002030234A (en) * | 2000-05-26 | 2002-01-31 | Atofina | Peelable composition used in building and ship building |
-
2005
- 2005-07-08 JP JP2006531360A patent/JP5226213B2/en not_active Expired - Fee Related
- 2005-07-08 WO PCT/JP2005/013108 patent/WO2006013713A1/en active Application Filing
- 2005-07-11 TW TW094123443A patent/TW200606229A/en not_active IP Right Cessation
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5920400A (en) * | 1982-07-27 | 1984-02-02 | 滝口 好 | Detergent |
| JPH06501284A (en) * | 1990-10-01 | 1994-02-10 | ヴェロナ インコーポレイテッド | Method for activating N-methyl-2-pyrrolidone (NMP) and/or γ-butyrolactone (BLO) varnish and paint removal solvents |
| JPH11513724A (en) * | 1995-10-18 | 1999-11-24 | エルフ アトケム ソシエテ アノニム | Concentrated composition for paint peeling |
| JPH10279850A (en) * | 1997-04-04 | 1998-10-20 | Yamaichi Kagaku Kogyo Kk | Paint remover for wall surface or the like and method for removing therewith |
| JP2000001637A (en) * | 1998-06-15 | 2000-01-07 | Yamaichi Kagaku Kogyo Kk | Release agent for coating film of outer wall or the like and plastic tile and peeling |
| JP2000017289A (en) * | 1998-07-01 | 2000-01-18 | Car Mate Mfg Co Ltd | Peeling composition for glassy film and peeling method |
| JP2000290543A (en) * | 1999-03-25 | 2000-10-17 | Atofina | Releasing composition used especially in building industry |
| JP2002030234A (en) * | 2000-05-26 | 2002-01-31 | Atofina | Peelable composition used in building and ship building |
Also Published As
| Publication number | Publication date |
|---|---|
| TWI339675B (en) | 2011-04-01 |
| JP5226213B2 (en) | 2013-07-03 |
| WO2006013713A1 (en) | 2006-02-09 |
| TW200606229A (en) | 2006-02-16 |
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