JPS64643Y2 - - Google Patents
Info
- Publication number
- JPS64643Y2 JPS64643Y2 JP6424583U JP6424583U JPS64643Y2 JP S64643 Y2 JPS64643 Y2 JP S64643Y2 JP 6424583 U JP6424583 U JP 6424583U JP 6424583 U JP6424583 U JP 6424583U JP S64643 Y2 JPS64643 Y2 JP S64643Y2
- Authority
- JP
- Japan
- Prior art keywords
- capsule
- force
- outer container
- chemiluminescent
- memory alloy
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000002775 capsule Substances 0.000 claims description 32
- 229910001285 shape-memory alloy Inorganic materials 0.000 claims description 9
- 239000000126 substance Substances 0.000 claims description 9
- 238000011084 recovery Methods 0.000 claims description 6
- OMOVVBIIQSXZSZ-UHFFFAOYSA-N [6-(4-acetyloxy-5,9a-dimethyl-2,7-dioxo-4,5a,6,9-tetrahydro-3h-pyrano[3,4-b]oxepin-5-yl)-5-formyloxy-3-(furan-3-yl)-3a-methyl-7-methylidene-1a,2,3,4,5,6-hexahydroindeno[1,7a-b]oxiren-4-yl] 2-hydroxy-3-methylpentanoate Chemical compound CC12C(OC(=O)C(O)C(C)CC)C(OC=O)C(C3(C)C(CC(=O)OC4(C)COC(=O)CC43)OC(C)=O)C(=C)C32OC3CC1C=1C=COC=1 OMOVVBIIQSXZSZ-UHFFFAOYSA-N 0.000 claims description 2
- 229910045601 alloy Inorganic materials 0.000 description 8
- 239000000956 alloy Substances 0.000 description 8
- 239000000463 material Substances 0.000 description 7
- 230000009466 transformation Effects 0.000 description 6
- 239000007800 oxidant agent Substances 0.000 description 5
- 150000003901 oxalic acid esters Chemical class 0.000 description 4
- 229920003023 plastic Polymers 0.000 description 4
- 230000002441 reversible effect Effects 0.000 description 4
- -1 oxalate ester Chemical class 0.000 description 3
- NIQCNGHVCWTJSM-UHFFFAOYSA-N Dimethyl phthalate Chemical compound COC(=O)C1=CC=CC=C1C(=O)OC NIQCNGHVCWTJSM-UHFFFAOYSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- 229910001566 austenite Inorganic materials 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 229910000734 martensite Inorganic materials 0.000 description 2
- 229910000881 Cu alloy Inorganic materials 0.000 description 1
- ABBQHOQBGMUPJH-UHFFFAOYSA-M Sodium salicylate Chemical compound [Na+].OC1=CC=CC=C1C([O-])=O ABBQHOQBGMUPJH-UHFFFAOYSA-M 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- FBSAITBEAPNWJG-UHFFFAOYSA-N dimethyl phthalate Natural products CC(=O)OC1=CC=CC=C1OC(C)=O FBSAITBEAPNWJG-UHFFFAOYSA-N 0.000 description 1
- 229960001826 dimethylphthalate Drugs 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005281 excited state Effects 0.000 description 1
- 239000012634 fragment Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 230000005283 ground state Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000003446 memory effect Effects 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229910001000 nickel titanium Inorganic materials 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 229960004025 sodium salicylate Drugs 0.000 description 1
Landscapes
- Measuring Temperature Or Quantity Of Heat (AREA)
- Adornments (AREA)
Description
【考案の詳細な説明】
本考案は多くの用途に活用される化学発光体に
関する。[Detailed Description of the Invention] The present invention relates to a chemiluminescent material that is utilized in many applications.
化学発光とは、ある種の修酸エステルと酸化剤
とが反応することにより励起状態に至らしめられ
た物質が基底状態に遷移する事により可視光線を
発するものであり、例えばビス（2.4.5−トリク
ロロ−６−カルボブトキシフエニル）シユウ酸エ
ステル、ビス−9.10−フエニルエチニルアントラ
センをジブチルフタレートに溶かした溶液（以下
修酸エステルとする）と過酸化水素とサリチル酸
ナトリウム等の触媒をジメチルフタレートに溶か
した溶液（以下酸化剤とする）との組合わせがあ
る。この様な化学発光を応用した発光体は電源を
必要としない事、熱を生じないこと等の性質の
為、多くの用途が開発されているが、従来のもの
はすべてその発光方法が円筒状容器を折り曲げる
等の変形を加えることにより、中に入つているカ
プセルを破割し、カプセル内の化学物質とこのカ
プセルの外側で円筒状容器内の化学物質を混合し
て、化学発光せしめるものであるため、次の様な
欠点を有していた。 Chemiluminescence is a substance that is brought to an excited state through the reaction of a certain oxalic acid ester and an oxidizing agent, and then changes to the ground state, emitting visible light. -trichloro-6-carbobutoxyphenyl) oxalate ester, a solution of bis-9.10-phenylethynylanthracene dissolved in dibutyl phthalate (hereinafter referred to as oxalate ester), hydrogen peroxide and a catalyst such as sodium salicylate, and dimethyl phthalate. There is a combination with a solution dissolved in (hereinafter referred to as oxidizing agent). Many uses have been developed for luminescent materials that apply chemiluminescence, as they do not require a power source or generate heat, but all conventional luminescent materials have a cylindrical luminescent method. By deforming the container, such as by bending it, the capsule inside is ruptured, and the chemical inside the capsule is mixed with the chemical inside the cylindrical container outside the capsule, causing chemiluminescence. Therefore, it had the following drawbacks.
○イ 外的な力による容器の変形を加えなければな
らないこと。○B. The container must be deformed by external force.
○ロ 円筒状容器の素材が化学的に安定でしかも可
撓性を有するものでなければならないこと。○B The material of the cylindrical container must be chemically stable and flexible.
○ハ 容器に亀裂が生じたり、カプセルの破片が容
器に突き刺さり、しばしば化学発光液が漏れて
いた。○C The chemiluminescent liquid often leaked due to cracks in the container or fragments of the capsule being stuck in the container.
○ニ 容器を変形せしめると、もとの形状に完全に
復帰しない。○D If the container is deformed, it will not completely return to its original shape.
本考案は上記の欠点を解消する化学発光体を提
供せんとするものであり、その要旨は光透過性外
容器１内に混合時に化学発光現象を呈する２種の
物質Ａ，ＢのうちＡをカプセル２に充填すると共
に、カプセル２の外側で外容器１内に他方の物質
Ｂを封入し、しかも弾性素子３と形状記憶合金素
子４よりなる破割体５とカプセル２を組み合わ
せ、外的温度変化により記憶合金素子４の回復力
と弾性素子３の弾性力との差により破割体５の形
状が変化しカプセル２を破割する構造とした化学
発光体である。 The present invention aims to provide a chemiluminescent substance that eliminates the above-mentioned drawbacks, and the gist thereof is to place A of two substances A and B that exhibit a chemiluminescent phenomenon when mixed in a light-transmissive outer container 1. At the same time as filling the capsule 2, the other substance B is enclosed in the outer container 1 outside the capsule 2, and the capsule 2 is combined with the breakable body 5 made of the elastic element 3 and the shape memory alloy element 4, and the capsule 2 is heated to an external temperature. This chemiluminescent material has a structure in which the shape of the breakable body 5 changes and the capsule 2 is broken due to the difference between the recovery force of the memory alloy element 4 and the elastic force of the elastic element 3.
ここで形状記憶合金とは、ある種の合金に変形
加工を加えて塑性変形させた後、これを加熱する
と合金の形状が塑性変形前の元の形状に戻つてし
まう現象である。この現象はマルテンサイト変
態、それも変態温度と逆変態温度との差の小さい
熱弾性型マルテンサイト変態とその逆変態によつ
て生ずる。現在実用性のある合金としてはNiTi
合金と銅合金が知られている。 Here, the term "shape memory alloy" refers to a phenomenon in which a certain type of alloy is plastically deformed by deformation processing, and then when the alloy is heated, the shape of the alloy returns to its original shape before plastic deformation. This phenomenon is caused by martensitic transformation, specifically thermoelastic martensitic transformation in which the difference between the transformation temperature and the reverse transformation temperature is small, and its reverse transformation. NiTi is currently a practical alloy.
Alloys and copper alloys are known.
本考案の破割体５は低温での変形を形状記憶効
果素子にかけた一定のバイアス力により自動的に
行つて、可逆的な動作を得る構造である。 The breakable body 5 of the present invention has a structure in which deformation at low temperatures is automatically performed by a constant bias force applied to a shape memory effect element, thereby obtaining reversible operation.
バイヤス力Ｘは低温における回復力Ｙより高
く、高温での回復力Ｚより低い値とする。素子を
低温にすればＸ−Ｙの力が、加熱してオーステナ
イト相とすれば逆方向Ｚ−Ｘの力がそれぞれ可逆
的に得られる。バイヤス力例えば弾性素子を適当
に設定することによつて低温、高温いずれにおけ
る発生力をコントロールするものである。 The bias force X has a value higher than the recovery force Y at low temperatures and lower than the recovery force Z at high temperatures. If the element is kept at a low temperature, an X-Y force can be obtained reversibly, and if it is heated to form an austenite phase, a Z-X force in the opposite direction can be obtained reversibly. By appropriately setting the bias force, for example, an elastic element, the generated force at both low and high temperatures can be controlled.
上記の構造の他に２個の形状記憶素子を直列に
接続し、力を差動的に取出す構造がある。これは
一方の素子を高温、他方を低温にすると高温側素
子の形状回復力により低温側素子の変形が行わ
れ、同時に外力を発生する。それぞれの素子の温
度を逆転すれば当然逆方向に働き可逆的な動きが
得られる。 In addition to the above structure, there is a structure in which two shape memory elements are connected in series and force is extracted differentially. This is because when one element is set to a high temperature and the other to a low temperature, the shape recovery force of the high temperature side element deforms the low temperature side element, and at the same time an external force is generated. If the temperature of each element is reversed, it will naturally work in the opposite direction, resulting in reversible movement.
以下図面を参酌しながら本考案を詳述すれば第
１図〜第３図は、破割体５の基本的な一例を示し
た。 The present invention will be described in detail below with reference to the drawings. FIGS. 1 to 3 show a basic example of the breakable body 5.
第１図は最も基本的なもので弾性素子３と記憶
合金素子４を擦動自在に合わせたもので中央を固
定するか若しくは１個所以上を拘束する。 FIG. 1 shows the most basic one, in which an elastic element 3 and a memory alloy element 4 are movably aligned, and either the center is fixed or one or more places are restrained.
第２図はＵ字状のものとスプリング状との組み
合わせであるが、いずれを弾性素子３とするか記
憶合金素子とするかは自由である。 Although FIG. 2 shows a combination of a U-shaped element and a spring-shaped element, it is free to decide which element to use as the elastic element 3 or the memory alloy element.
第３図は略Ｕ字状のもの同士の組み合わせであ
り、これもいずれの素子を使用するか限定するも
のではない。 FIG. 3 shows a combination of substantially U-shaped elements, and this also does not limit which elements are used.
以上のような破割体５が化学発光性物質により
悪影響を受けたり、逆に化学発光性物質を劣化せ
しめるような場合は、化学的に安定なような処理
をう。この破割体５をカプセル２と組み合わせる
構造は基本的にカプセル２の中にセツトする場合
と外側にセツトする場合がある。 If the above-described broken body 5 is adversely affected by the chemiluminescent substance, or conversely causes the chemiluminescent substance to deteriorate, it should be treated to make it chemically stable. The structure in which the broken body 5 is assembled with the capsule 2 is basically set in two cases, one being set inside the capsule 2, and the other being set outside the capsule 2.
第４図と第５図はカプセル２の中にセツトした
場合であり、第６図は外側にセツトした場合であ
る。 4 and 5 show the case when the capsule is set inside the capsule 2, and FIG. 6 shows the case when it is set outside.
以上の如き構成よりなる本考案では、熱処理に
よりあらかじめ形状を記憶させておいた本合金素
子４を第１図に示すように常温にてオーステナイ
ト相とした直線状のものとし、これに例えば湾曲
状に曲がつた弾性素子３を上記合金素子と擦り合
わせに接合せしめたのが第１図のイである。この
破割体５は常温から低温に変化すると記憶合金素
子４の回復力Ｙは低下し、弾性素子３の弾性力Ｘ
よりも低くなるため第１図ロに示すように変形す
る。この変形は、カプセル２内の空間では収容で
きない変形度となつているためカプセルを破割す
る。 In the present invention constructed as described above, the present alloy element 4, whose shape has been memorized in advance by heat treatment, is made into a straight shape with an austenite phase at room temperature as shown in FIG. In Fig. 1A, the elastic element 3, which is bent in a manner similar to the above, is joined to the alloy element by rubbing. When this broken body 5 changes from room temperature to low temperature, the recovery force Y of the memory alloy element 4 decreases, and the elastic force X of the elastic element 3 decreases.
Since it becomes lower than , it deforms as shown in Figure 1B. This deformation has a degree of deformation that cannot be accommodated in the space within the capsule 2, so the capsule ruptures.
上記の場合は常温（高温）から低温となる構造
のものであつたが、逆に低温から高温になる温度
変化の場合は、本合金素子４は低温時マンテンサ
イト変態にあり、塑性変形により直線状となつて
おり、加熱により塑性変形前の湾曲した形状に回
復することにより破割体５を変形せしめる構造で
ある。本考案は主に高い温度から低温に変化する
場合に効果的である。 In the above case, the structure was such that the temperature changes from room temperature (high temperature) to low temperature, but in the case of a temperature change from low temperature to high temperature, the present alloy element 4 is in mantensite transformation at low temperature, and is linear due to plastic deformation. It has a structure in which the breakable body 5 is deformed by heating to restore the curved shape before plastic deformation. The present invention is effective mainly when the temperature changes from high to low.
上記のごとく破割体５の変形によりカプセルが
割れるとカプセル２内の例えば酸化剤とカプセル
の外側で外容器１内の修酸エステルが混合する。
混合により反応がスタートし、化学発光が生起す
る。 When the capsule is broken due to the deformation of the breakable body 5 as described above, the oxidizing agent in the capsule 2, for example, and the oxalic acid ester in the outer container 1 mix on the outside of the capsule.
The reaction starts upon mixing and chemiluminescence occurs.
なお、カプセル２は外容器１内に１個入れたも
のであるが、２個以上のカプセルを入れこのカプ
セルに修酸エステルや酸化剤をそれぞれ入れる場
合やカプセルの中にカプセルを入れ外側のカプセ
ルに酸化剤、中のカプセルに修酸エステル又はそ
の逆の場合も当然可能である。 Note that one capsule 2 is placed inside the outer container 1, but when two or more capsules are placed and each capsule contains an oxalic acid ester and an oxidizing agent, or when a capsule is placed inside a capsule and the outer capsule Of course, it is also possible to use an oxidizing agent in the capsule and an oxalic acid ester in the capsule, or vice versa.
本考案の外容器は特に透明性の高いプラスチツ
クやガラス等の硬質素材がベターである。また外
容器の形状は棒状、立方体、球体等目的や用途に
合わせてるものであり限定しない。 The outer container of the present invention is preferably made of a hard material such as highly transparent plastic or glass. Further, the shape of the outer container is not limited, and may be rod-shaped, cubic, spherical, etc. depending on the purpose and use.
以上の如く本考案品によれば、低温への温度変
化により自動的に化学発光が生じ、防災用、標識
用、レジヤー用、その他マドラー等に広く使用で
きる効果がある。 As described above, the product of the present invention automatically generates chemiluminescence when the temperature changes to a low temperature, and has the effect that it can be widely used for disaster prevention, signs, cash registers, and other stirrers.
なお、用途や目的に応じて外容器１に文字や模
様等を表示したり、外容器をさらにカバーするこ
とも可能である。 Note that it is also possible to display characters, patterns, etc. on the outer container 1, or to further cover the outer container depending on the use and purpose.
第１図〜第３図は本考案に係る化学発光体の破
割体の説明図。第４図〜第６図は本考案に係る化
学発光体の断面説明図。
図中、１……光透過性外容器、２……カプセ
ル、３……弾性素子、４……記憶合金素子、５…
…破割体。
FIGS. 1 to 3 are explanatory diagrams of a split body of a chemiluminescent material according to the present invention. 4 to 6 are cross-sectional explanatory views of the chemiluminescent body according to the present invention. In the figure, 1...light-transparent outer container, 2...capsule, 3...elastic element, 4...memory alloy element, 5...
...Broken body.
Claims (1)
呈する２種の物質Ａ，Ｂのうち物質Ａをカプセル
２に充填すると共に、カプセル２の外側で外容器
１内に他方の物質Ｂを封入し、しかも弾性素子３
と記憶合金素子４よりなる破割体５とカプセル２
を組み合わせ、外的温度変化により記憶合金素子
４の回復力と弾性素子３の弾性力との差により破
割体５の形状が変化しカプセル２を破割する構造
とした化学発光体。 Of two substances A and B that exhibit a chemiluminescent phenomenon when mixed in a light-transmissive outer container 1, substance A is filled into a capsule 2, and the other substance B is enclosed in the outer container 1 outside the capsule 2. Moreover, elastic element 3
A fractured body 5 consisting of a memory alloy element 4 and a capsule 2
The chemiluminescent body has a structure in which the capsule 2 is ruptured by changing the shape of the breakable body 5 due to the difference between the recovery force of the memory alloy element 4 and the elastic force of the elastic element 3 due to an external temperature change.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP6424583U JPS59170302U (en) | 1983-04-28 | 1983-04-28 | chemiluminescent material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP6424583U JPS59170302U (en) | 1983-04-28 | 1983-04-28 | chemiluminescent material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS59170302U JPS59170302U (en) | 1984-11-14 |
| JPS64643Y2 true JPS64643Y2 (en) | 1989-01-09 |
Family
ID=30194431
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP6424583U Granted JPS59170302U (en) | 1983-04-28 | 1983-04-28 | chemiluminescent material |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS59170302U (en) |
-
1983
- 1983-04-28 JP JP6424583U patent/JPS59170302U/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS59170302U (en) | 1984-11-14 |
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