JPS6452729A - Dehydrogenation of compound having carbon-hydrogen bond and production of hydrogen - Google Patents

Dehydrogenation of compound having carbon-hydrogen bond and production of hydrogen

Info

Publication number
JPS6452729A
JPS6452729A JP1524588A JP1524588A JPS6452729A JP S6452729 A JPS6452729 A JP S6452729A JP 1524588 A JP1524588 A JP 1524588A JP 1524588 A JP1524588 A JP 1524588A JP S6452729 A JPS6452729 A JP S6452729A
Authority
JP
Japan
Prior art keywords
hydrogen
carbon
transition metal
bond
compound
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP1524588A
Other languages
Japanese (ja)
Other versions
JPH039091B2 (en
Inventor
Masato Tanaka
Toshiyasu Sakakura
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
National Institute of Advanced Industrial Science and Technology AIST
Original Assignee
Agency of Industrial Science and Technology
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Agency of Industrial Science and Technology filed Critical Agency of Industrial Science and Technology
Priority to JP1524588A priority Critical patent/JPS6452729A/en
Publication of JPS6452729A publication Critical patent/JPS6452729A/en
Publication of JPH039091B2 publication Critical patent/JPH039091B2/ja
Granted legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J19/12—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electromagnetic waves
    • B01J19/122—Incoherent waves

Abstract

PURPOSE:To directly eliminate hydrogen from carbon-hydrogen bond, obtain a dehydrogenation product and simultaneously produce hydrogen, by subjecting a compound having carbon-hydrogen bond to light irradiation in the presence of a transition metal complex. CONSTITUTION:One or more kind of compounds having carbon-hydrogen bond are subjected to light irradiation in the presence of a transition metal complex wherein preferably the transition metal is VIII group transition metal especially Co, Rh, Ir, Fe, Ru, Ni and/or Pt and least one ligand in the ligands is a compound expressed by the formula R<1>R<2>R<3>P or formula R<4>R<5>P-A-PR<6>R<7> (R<1>-R<7> are 1-20C alkyl, aralkyl, aryl or cycloalkyl; A is 1-20C alkylene, cycloalkylene, arylene, aralkylene or ferrocenylene), preferably coexisting a hydrogen acceptor to directly eliminate hydrogen from the above-mentioned bond and directly convert the above-mentioned raw material into a dehydrogenation product and hydrogen under mild conditions.
JP1524588A 1987-01-27 1988-01-26 Dehydrogenation of compound having carbon-hydrogen bond and production of hydrogen Granted JPS6452729A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP1524588A JPS6452729A (en) 1987-01-27 1988-01-26 Dehydrogenation of compound having carbon-hydrogen bond and production of hydrogen

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP1665187 1987-01-27
JP1524588A JPS6452729A (en) 1987-01-27 1988-01-26 Dehydrogenation of compound having carbon-hydrogen bond and production of hydrogen

Publications (2)

Publication Number Publication Date
JPS6452729A true JPS6452729A (en) 1989-02-28
JPH039091B2 JPH039091B2 (en) 1991-02-07

Family

ID=26351368

Family Applications (1)

Application Number Title Priority Date Filing Date
JP1524588A Granted JPS6452729A (en) 1987-01-27 1988-01-26 Dehydrogenation of compound having carbon-hydrogen bond and production of hydrogen

Country Status (1)

Country Link
JP (1) JPS6452729A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003286277A (en) * 2002-03-28 2003-10-10 Mitsubishi Chemicals Corp METHOD FOR PURIFYING gamma-BUTYLOLACTONE
JP2007515363A (en) * 2003-05-06 2007-06-14 エアー．プロダクツ．アンド．ケミカルス．インコーポレーテッド Hydrogen storage by reversible hydrogenation of pi-conjugated substrates

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003286277A (en) * 2002-03-28 2003-10-10 Mitsubishi Chemicals Corp METHOD FOR PURIFYING gamma-BUTYLOLACTONE
JP2007515363A (en) * 2003-05-06 2007-06-14 エアー．プロダクツ．アンド．ケミカルス．インコーポレーテッド Hydrogen storage by reversible hydrogenation of pi-conjugated substrates

Also Published As

Publication number Publication date
JPH039091B2 (en) 1991-02-07

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Legal Events

Date Code Title Description
EXPY Cancellation because of completion of term