JPS6450A - Novel optically active compound having plural asymmetric carbon atoms. - Google Patents
Novel optically active compound having plural asymmetric carbon atoms.Info
- Publication number
- JPS6450A JPS6450A JP63037239A JP3723988A JPS6450A JP S6450 A JPS6450 A JP S6450A JP 63037239 A JP63037239 A JP 63037239A JP 3723988 A JP3723988 A JP 3723988A JP S6450 A JPS6450 A JP S6450A
- Authority
- JP
- Japan
- Prior art keywords
- formula
- optically active
- asymmetric carbon
- expressed
- compound expressed
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 150000001875 compounds Chemical class 0.000 title abstract 6
- 125000004432 carbon atom Chemical group C* 0.000 title 1
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical compound C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 abstract 2
- 229910052736 halogen Inorganic materials 0.000 abstract 2
- 150000002367 halogens Chemical class 0.000 abstract 2
- KEAYESYHFKHZAL-UHFFFAOYSA-N Sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 abstract 1
- 125000003545 alkoxy group Chemical group 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 235000010290 biphenyl Nutrition 0.000 abstract 1
- 239000004305 biphenyl Substances 0.000 abstract 1
- 125000001589 carboacyl group Chemical group 0.000 abstract 1
- 229910052799 carbon Inorganic materials 0.000 abstract 1
- 150000001721 carbon Chemical group 0.000 abstract 1
- 239000005262 ferroelectric liquid crystals (FLCs) Substances 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 230000010287 polarization Effects 0.000 abstract 1
- 125000002572 propoxy group Chemical group [*]OC([H])([H])C(C([H])([H])[H])([H])[H] 0.000 abstract 1
- 229910000104 sodium hydride Inorganic materials 0.000 abstract 1
- 239000012312 sodium hydride Substances 0.000 abstract 1
- 230000002269 spontaneous effect Effects 0.000 abstract 1
Landscapes
- Liquid Crystal Substances (AREA)
- Pyridine Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Liquid Crystal (AREA)
Abstract
NEW MATERIAL:A compound expressed by formula I [R1 is alkyl, alkoxy, alkanoyl, H, halogen, CN, etc.; R2 is optically active group; rings A and B are expressed by formula IIWV (X is halogen, CN, etc.); l is 1W10; m is 0 or 1; * indicates asymmetric carbon atom.].
EXAMPLE: (2'S,2"S)-4'-Octyloxy-4-[2'-(2"-butoxypropionyloxy)propoxy]biphenyl.
USE: Useful as a component in ferroelectric liquid crystal compositions having characteristics of increasing values of spontaneous polarization.
PREPARATION: Compounds expressed by formula VI and VII are reacted in the presence of sodium hydride to provide a compound expressed by formula VIII, which is then deprotected and condensed with a compound expressed by formula IX to afford the aimed compound expressed by formula I.
COPYRIGHT: (C)1989,JPO&Japio
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63037239A JP2561504B2 (en) | 1987-03-04 | 1988-02-19 | New optically active compounds with multiple asymmetric carbon atoms |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62-49796 | 1987-03-04 | ||
| JP4979687 | 1987-03-04 | ||
| JP63037239A JP2561504B2 (en) | 1987-03-04 | 1988-02-19 | New optically active compounds with multiple asymmetric carbon atoms |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JPH0150A JPH0150A (en) | 1989-01-05 |
| JPS6450A true JPS6450A (en) | 1989-01-05 |
| JP2561504B2 JP2561504B2 (en) | 1996-12-11 |
Family
ID=26376366
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP63037239A Expired - Lifetime JP2561504B2 (en) | 1987-03-04 | 1988-02-19 | New optically active compounds with multiple asymmetric carbon atoms |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2561504B2 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4775356A (en) * | 1985-08-06 | 1988-10-04 | Ab Skf | Drive belt and method of manufacturing such |
| JPS6438075A (en) * | 1987-07-10 | 1989-02-08 | Teikoku Chem Ind Co Ltd | Pyrimidinylphenoxyalkyl ester compound |
-
1988
- 1988-02-19 JP JP63037239A patent/JP2561504B2/en not_active Expired - Lifetime
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4775356A (en) * | 1985-08-06 | 1988-10-04 | Ab Skf | Drive belt and method of manufacturing such |
| JPS6438075A (en) * | 1987-07-10 | 1989-02-08 | Teikoku Chem Ind Co Ltd | Pyrimidinylphenoxyalkyl ester compound |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2561504B2 (en) | 1996-12-11 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20080919 Year of fee payment: 12 |
|
| EXPY | Cancellation because of completion of term | ||
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20080919 Year of fee payment: 12 |