JPS6429440A - Fluorinated ion exchange resin and its production - Google Patents
Fluorinated ion exchange resin and its productionInfo
- Publication number
- JPS6429440A JPS6429440A JP18375787A JP18375787A JPS6429440A JP S6429440 A JPS6429440 A JP S6429440A JP 18375787 A JP18375787 A JP 18375787A JP 18375787 A JP18375787 A JP 18375787A JP S6429440 A JPS6429440 A JP S6429440A
- Authority
- JP
- Japan
- Prior art keywords
- ion exchange
- group
- optionally
- exchange group
- ether
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Manufacture Of Macromolecular Shaped Articles (AREA)
Abstract
PURPOSE:To obtain the title resin excellent in ion exchange capacity and crosslinking density, by polymerizing a specified fluorodivinyl ether compound with, optionally, a copolymerizable monomer and introducing anion exchange group into the polymer. CONSTITUTION:A fluorodivinyl ether (A) of formula I (wherein Y is an ion exchange group, or a group which can be easily converted into an ion exchange group, Rf and Rf1-2 are each F or a perfluoroalkyl, k>=1, and l, m and n are each >=0) is (co)polymerized with, optionally, a fluorovinyl monomer (B) copolymerizable therewith at -80-400 deg.C and a pressure of -70mmHg-20kg/ cm<2> in an inert gas in the presence of a polymerization initiator, and ion exchange groups are optionally introduced into the (co)polymer by, for example, hydrolysis with an alkali solution to obtain the title resin having structural units of formula II (wherein X is an ion exchange group) as side chains and optionally having structural units of formulas III-IV (wherein Rf3-4 are each a perfluoroalkylene or a perfluoro ether group, Y is H, a halogen or an ion exchange group, and h is 0-1).
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP18375787A JPH0778137B2 (en) | 1987-07-24 | 1987-07-24 | Fluorine-containing ion exchange resin and method for producing the same |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP18375787A JPH0778137B2 (en) | 1987-07-24 | 1987-07-24 | Fluorine-containing ion exchange resin and method for producing the same |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS6429440A true JPS6429440A (en) | 1989-01-31 |
JPH0778137B2 JPH0778137B2 (en) | 1995-08-23 |
Family
ID=16141446
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP18375787A Expired - Lifetime JPH0778137B2 (en) | 1987-07-24 | 1987-07-24 | Fluorine-containing ion exchange resin and method for producing the same |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH0778137B2 (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2008093570A1 (en) * | 2007-01-31 | 2008-08-07 | Asahi Glass Company, Limited | Ion-exchange membrane for alkali chloride electrolysis |
-
1987
- 1987-07-24 JP JP18375787A patent/JPH0778137B2/en not_active Expired - Lifetime
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2008093570A1 (en) * | 2007-01-31 | 2008-08-07 | Asahi Glass Company, Limited | Ion-exchange membrane for alkali chloride electrolysis |
US8394865B2 (en) | 2007-01-31 | 2013-03-12 | Asahi Glass Company, Limited | Ion-exchange membrane for alkaline chloride electrolysis |
JP5212114B2 (en) * | 2007-01-31 | 2013-06-19 | 旭硝子株式会社 | Ion exchange membrane for alkali chloride electrolysis |
Also Published As
Publication number | Publication date |
---|---|
JPH0778137B2 (en) | 1995-08-23 |
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