JPS6412161B2 - - Google Patents
Info
- Publication number
- JPS6412161B2 JPS6412161B2 JP57205613A JP20561382A JPS6412161B2 JP S6412161 B2 JPS6412161 B2 JP S6412161B2 JP 57205613 A JP57205613 A JP 57205613A JP 20561382 A JP20561382 A JP 20561382A JP S6412161 B2 JPS6412161 B2 JP S6412161B2
- Authority
- JP
- Japan
- Prior art keywords
- conductor
- stranded
- insulation film
- insulating film
- aqueous solution
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000004020 conductor Substances 0.000 claims description 27
- 238000009413 insulation Methods 0.000 claims description 19
- 238000000034 method Methods 0.000 claims description 18
- 239000000243 solution Substances 0.000 claims description 12
- 239000000126 substance Substances 0.000 claims description 10
- 230000008961 swelling Effects 0.000 claims description 7
- 239000007864 aqueous solution Substances 0.000 claims description 6
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 claims description 4
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 claims description 3
- 239000000463 material Substances 0.000 claims description 3
- DZSVIVLGBJKQAP-UHFFFAOYSA-N 1-(2-methyl-5-propan-2-ylcyclohex-2-en-1-yl)propan-1-one Chemical compound CCC(=O)C1CC(C(C)C)CC=C1C DZSVIVLGBJKQAP-UHFFFAOYSA-N 0.000 claims description 2
- 239000005751 Copper oxide Substances 0.000 claims description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 2
- 229920002125 Sokalan® Polymers 0.000 claims description 2
- 229920002472 Starch Polymers 0.000 claims description 2
- 229920002678 cellulose Polymers 0.000 claims description 2
- 239000001913 cellulose Substances 0.000 claims description 2
- 229910000431 copper oxide Inorganic materials 0.000 claims description 2
- ACVYVLVWPXVTIT-UHFFFAOYSA-N phosphinic acid Chemical compound O[PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-N 0.000 claims description 2
- 229920000172 poly(styrenesulfonic acid) Polymers 0.000 claims description 2
- 229920002401 polyacrylamide Polymers 0.000 claims description 2
- 239000004584 polyacrylic acid Substances 0.000 claims description 2
- 229940005642 polystyrene sulfonic acid Drugs 0.000 claims description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 2
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims description 2
- 239000001267 polyvinylpyrrolidone Substances 0.000 claims description 2
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims description 2
- 239000008107 starch Substances 0.000 claims description 2
- 235000019698 starch Nutrition 0.000 claims description 2
- 239000007788 liquid Substances 0.000 description 7
- 239000011248 coating agent Substances 0.000 description 5
- 238000000576 coating method Methods 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 229920000642 polymer Polymers 0.000 description 4
- 238000005498 polishing Methods 0.000 description 2
- 239000002861 polymer material Substances 0.000 description 2
- 238000005488 sandblasting Methods 0.000 description 2
- 239000003082 abrasive agent Substances 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000012733 comparative method Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 229930014626 natural product Natural products 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- 230000002250 progressing effect Effects 0.000 description 1
- -1 starch and cellulose Natural products 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
Landscapes
- Removal Of Insulation Or Armoring From Wires Or Cables (AREA)
Description
本発明は絶縁素線を撚合せた撚合導体の接続等
における端末部の素線絶縁皮膜を除去する方法の
改良に関するものである。
一般に、素線絶縁導体の端末接続には導体端末
部の各素線の絶縁皮膜を除去する必要があり、従
来酸化第2銅(CuO)からなる絶縁皮膜を有する
絶縁素線を撚合せた撚合導体の素線絶縁皮膜を除
去する方法としては、例えば除去すべき素線導体
の端末部を直接素線絶縁皮膜除去液に浸漬するか
或はサンドブラスト等の機械的研磨により除去す
る方法により行つていたものである。
然しながらこれらの方法を適用する場合、特に
大導体撚線の絶縁皮膜を除去するには次の如き問
題を生ずるものであつた。即ち撚線導体を直接素
線絶縁除去液に浸漬すると毛細管現象によつて導
体の内部にまで液が浸入するという所謂導体内に
液の水走りを防止することが出来ず皮膜の除去を
必要としない部分の絶縁皮膜までもその酸化絶縁
皮膜を除去し素線に絶縁皮膜を設ける目的を達成
せしめることが出来ないものであつた。又サンド
ブラスト等による機械的研磨による場合には、研
磨材が試料表面にぶつかりその物理的衝撃力によ
り該皮膜を除去するものであるため、撚線導体の
各層の素線導体を拡げた状態とし研磨材が素線導
体内部に衝突するようにする必要があつた。従つ
て素線表面の酸化絶縁皮膜を除去するためには出
来るだけ素線間を拡げる必要があるが、一方絶縁
皮膜を除去した後はスリーブ圧縮によつて元の状
態に復元しなければならず、その操作に煩雑な手
段を要するものであつた。
本発明は溶液法により素線絶縁皮膜を除去する
において、毛細管現象により、素線内部に液が侵
入するのを阻止し、絶縁皮膜の除去を必要とする
部分のみに該皮膜除去溶液を浸漬して絶縁皮膜を
除去する方法を見出したものである。即ち本発明
方法は酸化銅からなる絶縁皮膜を有する絶縁素線
を撚合せて撚線導体の端末接続部の絶縁皮膜を除
去する方法において、撚線導体を形成する各層の
絶縁素線の間隙部に膨潤性高分子物質を押圧して
充填せしめた後、還元性溶液に浸すことを特徴と
するものである。
本発明において膨潤性高分子物質を使用する理
由は、絶縁皮膜を除去するための還元性溶液が素
線相互の間隙部から侵入し、この液が素線の内部
まで進行しないようにするためであり、必要とす
る液の侵入部分にてこれを阻止することにある。
従つて該膨潤性高分子物質は自重の数百倍の溶液
を吸収することが可能にして且つ多少の圧力をう
けるも一旦吸収した液を離水しないことを必要と
するものであり、吸水能力が少なく、圧力を加え
ると離水するものは対象としない。
この高分子物質は例えば天然物としてデンプ
ン、セルロース、又合成高分子として例えばポリ
アクリル酸、ポリアクリルアミド、ポリビニルア
ルコールポリオキシドの他ポリビニルピロリド
ン、ポリスチレンスルホン酸、ポリ−2アクリル
アミド−2−メチルプロパンスルホン酸の橋かけ
体などである。
これらの物質は単独或は所望の皮膜を有するプ
ラスチツクフイルムの上に重ね合せてシートにし
たものを撚線導体の素線相互の間隙部に加圧状態
にて圧入充填する。
然る後膨潤性高分子物質を充填した部分に素線
絶縁皮膜除去液例えば次亜リン酸水溶液、ヒドラ
ジン水溶液、希塩酸水溶液を滴下するか或は浸漬
する。
これによつて撚線導体における素線の端末接続
部の絶縁皮膜は除去されるから、この部分を加熱
乾燥し、必要に応じて素線間に充填した膨潤性高
分子物質を除去すればよい。又撚線導体上にスリ
ーブをかぶせて圧縮する場合には、圧縮力によつ
て膨潤性高分子物質を破壊させこれを取除くこと
が出来るため、上記の如く予め圧縮前に膨潤性高
分子物質を除去する必要はない。
次に本発明方法の実施例について説明する。
実施例 (1)〜(3)
2000mm2、6分割の絶縁素線(CuO被覆、平均被
覆皮1.5μ)からなる撚線導体において絶縁皮膜の
除去を必要とする部分(端末部)の素線相互の間
隙部に第1表に示す如き膨潤性高分子物質を充填
した後、絶縁皮膜除去液を滴下して夫々絶縁皮膜
を除去した。
The present invention relates to an improvement in a method for removing the wire insulation film at the end portion of a twisted conductor made by twisting insulated wires together. Generally, in order to connect the terminals of stranded insulated conductors, it is necessary to remove the insulation coating of each strand at the terminal end of the conductor. The method for removing the wire insulation film of the composite conductor is, for example, by directly immersing the end portion of the wire conductor to be removed in a wire insulation film removal solution, or by removing it by mechanical polishing such as sandblasting. It was on. However, when these methods are applied, the following problems arise, particularly when removing the insulation coating of large conductor stranded wires. In other words, if a stranded wire conductor is directly immersed in a wire insulation removal solution, the liquid will penetrate into the inside of the conductor due to capillary action, so-called water running inside the conductor cannot be prevented, and the film must be removed. It was not possible to remove the oxidized insulating film even from the parts where the insulating film was not removed, and to achieve the purpose of providing the insulating film on the wire. In addition, in the case of mechanical polishing by sandblasting, etc., the abrasive material hits the sample surface and removes the film due to the physical impact force, so the wire conductors in each layer of the stranded wire conductor are spread out and polished. It was necessary to make the material collide with the inside of the wire conductor. Therefore, in order to remove the oxide insulation film on the surface of the wire, it is necessary to widen the distance between the wires as much as possible, but on the other hand, after the insulation film is removed, the original state must be restored by sleeve compression. , which required complicated means to operate. The present invention prevents the liquid from entering the inside of the wire by capillary action when removing the wire insulation film by a solution method, and immerses the film removal solution only in the part where the insulation film needs to be removed. They discovered a method to remove the insulating film. That is, the method of the present invention is a method of twisting insulated wires having an insulating film made of copper oxide and removing the insulating film at the terminal connection portion of the stranded conductor, in which the gaps between the insulating wires of each layer forming the stranded conductor are removed. The method is characterized in that the swellable polymer material is pressed and filled into the container and then immersed in a reducing solution. The reason why a swelling polymer substance is used in the present invention is to prevent the reducing solution for removing the insulation film from entering through the gaps between the wires and from progressing into the inside of the wires. The purpose is to prevent the necessary liquid from entering the area.
Therefore, the swelling polymeric substance must be capable of absorbing a solution several hundred times its own weight and must not release water from the absorbed liquid even when subjected to some pressure, and its water absorption capacity is Items that are small and release water when pressure is applied are not targeted. Examples of this polymeric substance include natural products such as starch and cellulose, and synthetic polymers such as polyacrylic acid, polyacrylamide, polyvinyl alcohol polyoxide, as well as polyvinylpyrrolidone, polystyrene sulfonic acid, and poly-2-acrylamide-2-methylpropanesulfonic acid. It is a bridge body etc. These materials may be used alone or in a sheet formed by superimposing them on a plastic film having a desired coating, and are press-fitted into the gaps between the strands of the stranded conductor under pressure. Thereafter, a wire insulation film removing solution such as hypophosphorous acid aqueous solution, hydrazine aqueous solution, or dilute hydrochloric acid aqueous solution is dropped or immersed in the part filled with the swelling polymeric substance. This removes the insulating film at the terminal connection part of the wires in the stranded conductor, so this part can be heated and dried, and if necessary, the swelling polymer substance filled between the wires can be removed. . In addition, when compressing a stranded wire conductor by covering it with a sleeve, the swellable polymer material can be destroyed and removed by the compressive force. There is no need to remove it. Next, examples of the method of the present invention will be described. Examples (1) to (3) Stranded wire conductor consisting of 2000 mm 2 6-segment insulated wire (CuO coating, average coating thickness 1.5μ), where the insulation film needs to be removed (terminal part) After filling the mutual gap with a swellable polymeric substance as shown in Table 1, an insulating film removing solution was dropped to remove the insulating film.
【表】
又本発明方法と比較するために上記の撚線導体
に膨潤性高分子物質を使用することなく、上記の
絶縁皮膜除去液のみを滴下して絶縁皮膜を除去し
た。
斯くして得た本発明方法並びに比較例方法によ
る撚線導体の端末部の絶縁皮膜の有無を測定した
結果、本発明方法の場合膨潤性高分子物質の充填
したところまでの絶縁皮膜はきれいに除去されて
おり、素線内部への絶縁皮膜除去液が侵入してい
ることを示した。然し比較例方法の場合には素線
の内部まで絶縁皮膜が除去されており毛細管現象
によつて除去液の水走りがあつたことを示した。
以上詳述した如く本発明方法によれば素線内部
への絶縁皮膜除去液の水走りを防止すると共に絶
縁皮膜を容易に除去しうる等実用上極めて有用で
ある。[Table] Also, for comparison with the method of the present invention, the insulation film was removed by dropping only the insulation film removal solution mentioned above onto the stranded wire conductor without using a swelling polymer substance. As a result of measuring the presence or absence of an insulating film at the end portion of the stranded wire conductor obtained by the method of the present invention and the method of the comparative example, it was found that in the case of the method of the present invention, the insulating film up to the point where the swelling polymer substance was filled was completely removed. This indicated that the insulation film removal liquid had penetrated into the inside of the wire. However, in the case of the comparative method, the insulating film was removed to the inside of the wire, indicating that the removal liquid ran through the water due to capillary action. As described in detail above, the method of the present invention is extremely useful in practice, as it prevents the insulating film removal liquid from running into the inside of the strand and allows the insulating film to be easily removed.
Claims (1)
る撚線導体の端末接続部の該絶縁皮膜を除去する
方法において、撚線導体を形成する各層の絶縁素
線の間隙部に膨潤性高分子物質を押圧して充填せ
しめた後、還元性溶液に浸すことを特徴とする素
線絶縁撚線導体の絶縁皮膜除去方法。 2 膨潤性高分子物質としてデンプン、セルロー
スの天然物質、ポリアクリル酸、ポリアクリルア
ミド、ポリビニルアルコール又はポリビニルピロ
リドン、ポリスチレンスルホン酸、ポリ−2アク
リルアミド−2−メチルプロパンスルホン酸の橋
かけ体を使用することを特徴とする特許請求の範
囲第1項記載の素線絶縁撚線導体の絶縁皮膜除去
方法。 3 還元性溶液として、次亜リン酸水溶液、ヒド
ラジン水溶液、希塩酸水溶液を使用することを特
徴とする特許請求の範囲第1項記載の素線絶縁撚
線導体の絶縁皮膜除去方法。[Scope of Claims] 1. In a method for removing an insulating film from a terminal connection portion of a stranded conductor made of strands having an insulating film made of copper oxide, the gap between the insulating strands of each layer forming the stranded conductor A method for removing an insulation film from a stranded insulated wire conductor, which comprises pressing and filling a swellable polymeric substance into a conductor, and then immersing the conductor in a reducing solution. 2. Use of starch, natural cellulose substances, polyacrylic acid, polyacrylamide, polyvinyl alcohol, or cross-linked products of polyvinylpyrrolidone, polystyrene sulfonic acid, and poly-2-acrylamide-2-methylpropanesulfonic acid as the swelling polymeric material. A method for removing an insulation film from an insulated stranded wire conductor according to claim 1, characterized in that: 3. A method for removing an insulation film from an insulated stranded wire conductor according to claim 1, characterized in that a hypophosphorous acid aqueous solution, a hydrazine aqueous solution, or a dilute hydrochloric acid aqueous solution is used as the reducing solution.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP57205613A JPS5996803A (en) | 1982-11-24 | 1982-11-24 | Method of removing insulating film of strand insulating twisted conductor |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP57205613A JPS5996803A (en) | 1982-11-24 | 1982-11-24 | Method of removing insulating film of strand insulating twisted conductor |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS5996803A JPS5996803A (en) | 1984-06-04 |
JPS6412161B2 true JPS6412161B2 (en) | 1989-02-28 |
Family
ID=16509771
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP57205613A Granted JPS5996803A (en) | 1982-11-24 | 1982-11-24 | Method of removing insulating film of strand insulating twisted conductor |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS5996803A (en) |
-
1982
- 1982-11-24 JP JP57205613A patent/JPS5996803A/en active Granted
Also Published As
Publication number | Publication date |
---|---|
JPS5996803A (en) | 1984-06-04 |
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