JPS6384618A - Production for liquid deodorant - Google Patents
Production for liquid deodorantInfo
- Publication number
- JPS6384618A JPS6384618A JP61226085A JP22608586A JPS6384618A JP S6384618 A JPS6384618 A JP S6384618A JP 61226085 A JP61226085 A JP 61226085A JP 22608586 A JP22608586 A JP 22608586A JP S6384618 A JPS6384618 A JP S6384618A
- Authority
- JP
- Japan
- Prior art keywords
- tank
- liquid
- suspension
- soil
- deodorant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000007788 liquid Substances 0.000 title claims abstract description 40
- 239000002781 deodorant agent Substances 0.000 title claims abstract description 29
- 238000004519 manufacturing process Methods 0.000 title claims description 10
- 239000000725 suspension Substances 0.000 claims abstract description 10
- QJZYHAIUNVAGQP-UHFFFAOYSA-N 3-nitrobicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid Chemical compound C1C2C=CC1C(C(=O)O)C2(C(O)=O)[N+]([O-])=O QJZYHAIUNVAGQP-UHFFFAOYSA-N 0.000 claims abstract description 6
- 150000001413 amino acids Chemical class 0.000 claims abstract description 6
- 239000004021 humic acid Substances 0.000 claims abstract description 6
- 235000012239 silicon dioxide Nutrition 0.000 claims abstract description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 6
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000003864 humus Substances 0.000 claims abstract description 4
- 229910052751 metal Inorganic materials 0.000 claims description 4
- 239000002184 metal Substances 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 3
- 239000007787 solid Substances 0.000 claims description 3
- 238000001914 filtration Methods 0.000 claims description 2
- 239000002689 soil Substances 0.000 abstract description 19
- 230000032683 aging Effects 0.000 abstract description 12
- 230000001877 deodorizing effect Effects 0.000 abstract description 10
- 239000000463 material Substances 0.000 abstract description 6
- 239000002994 raw material Substances 0.000 abstract description 6
- 238000010438 heat treatment Methods 0.000 abstract description 2
- 239000006228 supernatant Substances 0.000 abstract description 2
- 239000000706 filtrate Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 description 15
- 239000000126 substance Substances 0.000 description 10
- 230000000052 comparative effect Effects 0.000 description 7
- 229910021536 Zeolite Inorganic materials 0.000 description 6
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 6
- 239000010457 zeolite Substances 0.000 description 6
- 239000004480 active ingredient Substances 0.000 description 4
- 230000005070 ripening Effects 0.000 description 4
- 235000001014 amino acid Nutrition 0.000 description 3
- 229940024606 amino acid Drugs 0.000 description 3
- 230000009965 odorless effect Effects 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- DNJIEGIFACGWOD-UHFFFAOYSA-N ethanethiol Chemical compound CCS DNJIEGIFACGWOD-UHFFFAOYSA-N 0.000 description 2
- 229910021645 metal ion Inorganic materials 0.000 description 2
- 235000019645 odor Nutrition 0.000 description 2
- 239000000419 plant extract Substances 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- ZFRKQXVRDFCRJG-UHFFFAOYSA-N skatole Chemical compound C1=CC=C2C(C)=CNC2=C1 ZFRKQXVRDFCRJG-UHFFFAOYSA-N 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- MTCFGRXMJLQNBG-REOHCLBHSA-N (2S)-2-Amino-3-hydroxypropansäure Chemical compound OC[C@H](N)C(O)=O MTCFGRXMJLQNBG-REOHCLBHSA-N 0.000 description 1
- 239000004475 Arginine Substances 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- WHUUTDBJXJRKMK-UHFFFAOYSA-N Glutamic acid Natural products OC(=O)C(N)CCC(O)=O WHUUTDBJXJRKMK-UHFFFAOYSA-N 0.000 description 1
- 239000004471 Glycine Substances 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- ONIBWKKTOPOVIA-BYPYZUCNSA-N L-Proline Chemical compound OC(=O)[C@@H]1CCCN1 ONIBWKKTOPOVIA-BYPYZUCNSA-N 0.000 description 1
- QNAYBMKLOCPYGJ-REOHCLBHSA-N L-alanine Chemical compound C[C@H](N)C(O)=O QNAYBMKLOCPYGJ-REOHCLBHSA-N 0.000 description 1
- ODKSFYDXXFIFQN-BYPYZUCNSA-P L-argininium(2+) Chemical compound NC(=[NH2+])NCCC[C@H]([NH3+])C(O)=O ODKSFYDXXFIFQN-BYPYZUCNSA-P 0.000 description 1
- CKLJMWTZIZZHCS-REOHCLBHSA-N L-aspartic acid Chemical compound OC(=O)[C@@H](N)CC(O)=O CKLJMWTZIZZHCS-REOHCLBHSA-N 0.000 description 1
- WHUUTDBJXJRKMK-VKHMYHEASA-N L-glutamic acid Chemical compound OC(=O)[C@@H](N)CCC(O)=O WHUUTDBJXJRKMK-VKHMYHEASA-N 0.000 description 1
- HNDVDQJCIGZPNO-YFKPBYRVSA-N L-histidine Chemical compound OC(=O)[C@@H](N)CC1=CN=CN1 HNDVDQJCIGZPNO-YFKPBYRVSA-N 0.000 description 1
- AGPKZVBTJJNPAG-WHFBIAKZSA-N L-isoleucine Chemical compound CC[C@H](C)[C@H](N)C(O)=O AGPKZVBTJJNPAG-WHFBIAKZSA-N 0.000 description 1
- ROHFNLRQFUQHCH-YFKPBYRVSA-N L-leucine Chemical compound CC(C)C[C@H](N)C(O)=O ROHFNLRQFUQHCH-YFKPBYRVSA-N 0.000 description 1
- KDXKERNSBIXSRK-YFKPBYRVSA-N L-lysine Chemical compound NCCCC[C@H](N)C(O)=O KDXKERNSBIXSRK-YFKPBYRVSA-N 0.000 description 1
- COLNVLDHVKWLRT-QMMMGPOBSA-N L-phenylalanine Chemical compound OC(=O)[C@@H](N)CC1=CC=CC=C1 COLNVLDHVKWLRT-QMMMGPOBSA-N 0.000 description 1
- AYFVYJQAPQTCCC-GBXIJSLDSA-N L-threonine Chemical compound C[C@@H](O)[C@H](N)C(O)=O AYFVYJQAPQTCCC-GBXIJSLDSA-N 0.000 description 1
- OUYCCCASQSFEME-QMMMGPOBSA-N L-tyrosine Chemical compound OC(=O)[C@@H](N)CC1=CC=C(O)C=C1 OUYCCCASQSFEME-QMMMGPOBSA-N 0.000 description 1
- KZSNJWFQEVHDMF-BYPYZUCNSA-N L-valine Chemical compound CC(C)[C@H](N)C(O)=O KZSNJWFQEVHDMF-BYPYZUCNSA-N 0.000 description 1
- ROHFNLRQFUQHCH-UHFFFAOYSA-N Leucine Natural products CC(C)CC(N)C(O)=O ROHFNLRQFUQHCH-UHFFFAOYSA-N 0.000 description 1
- KDXKERNSBIXSRK-UHFFFAOYSA-N Lysine Natural products NCCCCC(N)C(O)=O KDXKERNSBIXSRK-UHFFFAOYSA-N 0.000 description 1
- 239000004472 Lysine Substances 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- ONIBWKKTOPOVIA-UHFFFAOYSA-N Proline Natural products OC(=O)C1CCCN1 ONIBWKKTOPOVIA-UHFFFAOYSA-N 0.000 description 1
- 101710196222 Protein 4.3 Proteins 0.000 description 1
- MTCFGRXMJLQNBG-UHFFFAOYSA-N Serine Natural products OCC(N)C(O)=O MTCFGRXMJLQNBG-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 238000000944 Soxhlet extraction Methods 0.000 description 1
- AYFVYJQAPQTCCC-UHFFFAOYSA-N Threonine Natural products CC(O)C(N)C(O)=O AYFVYJQAPQTCCC-UHFFFAOYSA-N 0.000 description 1
- 239000004473 Threonine Substances 0.000 description 1
- KZSNJWFQEVHDMF-UHFFFAOYSA-N Valine Natural products CC(C)C(N)C(O)=O KZSNJWFQEVHDMF-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000003463 adsorbent Substances 0.000 description 1
- 235000004279 alanine Nutrition 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- ODKSFYDXXFIFQN-UHFFFAOYSA-N arginine Natural products OC(=O)C(N)CCCNC(N)=N ODKSFYDXXFIFQN-UHFFFAOYSA-N 0.000 description 1
- 235000003704 aspartic acid Nutrition 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- OQFSQFPPLPISGP-UHFFFAOYSA-N beta-carboxyaspartic acid Natural products OC(=O)C(N)C(C(O)=O)C(O)=O OQFSQFPPLPISGP-UHFFFAOYSA-N 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000004332 deodorization Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 235000013922 glutamic acid Nutrition 0.000 description 1
- 239000004220 glutamic acid Substances 0.000 description 1
- 150000002366 halogen compounds Chemical class 0.000 description 1
- 238000011899 heat drying method Methods 0.000 description 1
- HNDVDQJCIGZPNO-UHFFFAOYSA-N histidine Natural products OC(=O)C(N)CC1=CN=CN1 HNDVDQJCIGZPNO-UHFFFAOYSA-N 0.000 description 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- AGPKZVBTJJNPAG-UHFFFAOYSA-N isoleucine Natural products CCC(C)C(N)C(O)=O AGPKZVBTJJNPAG-UHFFFAOYSA-N 0.000 description 1
- 229960000310 isoleucine Drugs 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 230000000873 masking effect Effects 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- COLNVLDHVKWLRT-UHFFFAOYSA-N phenylalanine Natural products OC(=O)C(N)CC1=CC=CC=C1 COLNVLDHVKWLRT-UHFFFAOYSA-N 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 235000013930 proline Nutrition 0.000 description 1
- 235000018102 proteins Nutrition 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 239000000700 radioactive tracer Substances 0.000 description 1
- 238000006479 redox reaction Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 235000004400 serine Nutrition 0.000 description 1
- 238000004904 shortening Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229940074386 skatole Drugs 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 235000008521 threonine Nutrition 0.000 description 1
- OUYCCCASQSFEME-UHFFFAOYSA-N tyrosine Natural products OC(=O)C(N)CC1=CC=C(O)C=C1 OUYCCCASQSFEME-UHFFFAOYSA-N 0.000 description 1
- 239000004474 valine Substances 0.000 description 1
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- 229940088594 vitamin Drugs 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
Landscapes
- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
- Treating Waste Gases (AREA)
- Gas Separation By Absorption (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は、異臭を放つ物質を吸着し、無臭物質に変化さ
せる消臭剤のうち液体であるもの一製造方法に関するも
のである。DETAILED DESCRIPTION OF THE INVENTION [Industrial Field of Application] The present invention relates to a method for producing a liquid deodorant that adsorbs substances that emit off-odor and converts them into odorless substances.
生活圏から悪臭を除去し、快適な環境にするため消臭法
が各種開発されている。消臭法には主として■悪臭物質
を吸着する機部、■化学反応により悪臭物質を酸化（ま
たは還元）して無臭物質に変える機能、■マスキング乃
至は中和１ｌｔｔｌ＆、などを利用する方法がある。■
の機能を有する吸着剤としては活性炭が多く用いられて
いる。■の＊使を利用するには、例えばハロゲン化合物
や過酸化水素などの酸化剤や還元剤を用いたり、酵素な
どの酸化還元触媒の存在下で空気中の酸素により酸化反
応をさせる。また■のの機能を利用するには、各種の植
物抽出油を用いる。Various deodorizing methods have been developed to remove bad odors from living areas and create a comfortable environment. Deodorization methods mainly include methods that utilize: ■ a device that adsorbs malodorous substances, ■ a function that oxidizes (or reduces) malodorous substances through chemical reactions and turns them into odorless substances, and ■ masking or neutralization. . ■
Activated carbon is often used as an adsorbent with this function. To use the *method of *, for example, use an oxidizing agent or reducing agent such as a halogen compound or hydrogen peroxide, or carry out an oxidation reaction with oxygen in the air in the presence of a redox catalyst such as an enzyme. In addition, to utilize the function of ■, various plant extract oils are used.
しかしながら上記した■〜■の機能は、その境界が必ず
しも明確でなく、単独で応用される場合もあるが、多く
の場合、組合せて利用される０例えばゼオライトは消臭
剤として使用されており、ゼオライトの多孔質な構造に
悪臭物質を吸着、金蔵すると同時に、ゼオライトの金属
イオンと悪臭物質のイオンとがイオン交換反応して消臭
すると考えられている。さらにゼオライトに吸着された
悪臭物質は、微細化し空気との接触面積が大きくなって
いるとともにゼオライトの金属イオンによる電子の授受
により酸化還元反応が促進され、無臭物質に変化するも
のと考えられる。However, the boundaries of the above-mentioned functions (■ to ■) are not necessarily clear, and although they may be applied alone, in many cases they are used in combination.For example, zeolite is used as a deodorant. It is believed that the porous structure of zeolite adsorbs and stores malodorous substances, and at the same time, the metal ions of the zeolite and the ions of the malodorous substances undergo an ion exchange reaction to eliminate odors. Furthermore, it is thought that the malodorous substances adsorbed on the zeolite become finer and have a larger contact area with the air, and that the oxidation-reduction reaction is promoted by the transfer of electrons by the metal ions of the zeolite, turning them into odorless substances.
このように複合的な機能を利用した消臭剤として、前記
のゼオライト以外に各種の土壌が使用されている。In addition to the above-mentioned zeolite, various soils are used as deodorants that utilize such multiple functions.
各種の土壌のなかでも、有機質を多く含む腐食上が消臭
剤として優れている。ところが土壌は固体であるため消
臭剤としての散布がやりにく−１限られた対象にしか使
用できない、また、散布したとしても、消臭の効果は得
られるもの！、汚れとなって残り、好ましくない、その
点、液体の消臭剤は散布がやりやすく、利用範囲も広い
、特にその液体が無色透明であれば、使用痕跡が残らな
いので使いやすい、しかし、土壌中の消臭剤としての有
効成分を液体化する方法は従来なかった。Among various types of soil, soil containing a large amount of organic matter is excellent as a deodorant. However, since soil is solid, it is difficult to spray it as a deodorizer - 1 It can only be used on limited targets, and even if it is sprayed, it will still have a deodorizing effect! On the other hand, liquid deodorants are easy to spray and can be used over a wide range of areas.Especially if the liquid is colorless and transparent, it leaves no traces of use and is therefore easy to use.However, There has never been a method to liquefy the active ingredient as a deodorant in soil.
そのため、消臭剤として優れた土壌であっても、液状に
したものはなかった。Therefore, even though soil is an excellent deodorant, there has been no liquid form of it.
本発明は上記に鑑みてなされたもので、消臭剤として優
れた土壌を原料として、液体の消臭剤を製造する方法を
提供するものである。The present invention has been made in view of the above, and provides a method for producing a liquid deodorant using soil, which is excellent as a deodorant, as a raw material.
本発明者らは、土壌を消臭剤として利用する研究を永年
続けた結果、アミノ酸、フミン酸、珪酸および金属成分
を含む腐植土が上記した■〜■の機能を持ち消臭作用に
優れていることを見出した。そしてその有効成分を損な
うことなく液体化する方法を見出し、本発明を完成する
に至った。As a result of many years of research into the use of soil as a deodorizing agent, the present inventors have discovered that humic soil containing amino acids, humic acid, silicic acid, and metal components has the above-mentioned functions (■ to ■) and has excellent deodorizing effects. I found out that there is. Then, they discovered a method of liquefying it without damaging its active ingredients, and completed the present invention.
すなわち本発明の液体消臭剤の製造方法は、少なくとも
アミノ酸、フミン酸、珪酸および金属成分を含む腐植土
を水に混合して得た懸濁液を９６時間以上放置（−次熟
成）した後、固体成分を癌別した液をさらに１９２９２
時間以上放置次熟成）するものである。That is, the method for producing a liquid deodorant of the present invention involves mixing a suspension obtained by mixing humic soil containing at least amino acids, humic acid, silicic acid, and metal components with water and leaving it for 96 hours or more (secondary ripening). , the liquid from which the solid components were separated was further added to 19292
It is left to ripen for more than an hour.
このように懸濁液を長く放置することにより有効成分が
充分に抽出、熟成され、消臭作用の優れた液体消臭剤が
得られた。しかも驚くべきことに、短期間の放置では濾
別回収した透明液が数［１後には赤濁するのに対し、本
発明の方法により得た透明液（液体消臭剤）にはそのよ
うなことがない、この理由は必ずしも明確ではないが、
本発明の方法により得た液体消臭剤は、溶解している金
属成分の原子価が安定してるためであると考えられる。By allowing the suspension to stand for a long time in this manner, the active ingredients were sufficiently extracted and matured, and a liquid deodorant with excellent deodorizing action was obtained. Surprisingly, when left for a short period of time, the transparent liquid collected by filtration turns red and cloudy after several hours, whereas the transparent liquid (liquid deodorant) obtained by the method of the present invention does not have such a tendency. The reason for this is not always clear, but
This is believed to be because the liquid deodorant obtained by the method of the present invention has a stable valence of the dissolved metal component.
以下、本発明の実施例を詳細に説明する。 Examples of the present invention will be described in detail below.
本発明の方法を実施するための原料として、数千万年以
上前の地層年代と推定される（同位体トレイサで確認）
腐植質土壌を採取する。この土壌は分析の結果、水分５
１．８％（定圧加熱乾燥法）、蛋白質４．３％（ケルブ
ール法）、脂肪分０ ．２％（ソックスレイ抽出法）、
強熱残留成分３３％であった。蛋白質の構成アミノ酸は
、アスパラギン酸、スレオニン、セリン、グルタミン酸
、プロリン、グリシン、アラニン、バリン、イソロイシ
ン、ロイシン、チロシン、フェニルアラニン、リジン、
ヒスチジン、アルギニン等である。またフミン酸が含有
されている。非常に微漬ではあるが、各種のビタミン類
も存在する０強熱残留酸分は、硅素、鉄、アルミニウム
、ナトリウム、カリウム、カルシウム、マグネシウム、
リンなどであり、硅素の多くが二酸化硅素の形で含有さ
れている。As a raw material for carrying out the method of the present invention, the geological age is estimated to be tens of millions of years ago (confirmed with isotope tracer)
Collect humus soil. As a result of analysis, this soil has a moisture content of 5
1.8% (constant pressure heat drying method), protein 4.3% (Kerbourg method), fat content 0. 2% (Soxhlet extraction method),
The residual component on ignition was 33%. The amino acids that make up protein are aspartic acid, threonine, serine, glutamic acid, proline, glycine, alanine, valine, isoleucine, leucine, tyrosine, phenylalanine, lysine,
These include histidine and arginine. It also contains humic acid. Although it is very slightly pickled, various vitamins are also present.Residual acid content on ignition is silicon, iron, aluminum, sodium, potassium, calcium, magnesium,
Phosphorus, etc., and most of the silicon is contained in the form of silicon dioxide.
上記の土壌を原料とし、第１図に示す装置により、以下
の各個に示すように液体消臭剤を製造する。なお実施例
１〜実施例３には本発明を適用した方法により製造した
例、比較例１〜比較例３には本発明を適用外の方法によ
り製造した例を示しである。Using the above soil as a raw material, a liquid deodorant is produced as shown in the following items using the apparatus shown in FIG. Examples 1 to 3 show examples manufactured by a method to which the present invention is applied, and Comparative Examples 1 to 3 show examples manufactured by a method to which the present invention is not applied.
実施例１゜
第１図に示すように、攪拌機１０が取付けられた加熱タ
ンク１１にイオン交換器１２を通った純水２に９．を入
れ、攪拌しながら原料土壌ｌを１００Ｋｇ投入する。ボ
イラ１３からは蒸気を送り、タンクｌｌ内を８０℃にし
て２〜３時間攪拌を続け、懸濁液にする。その懸濁液を
一次熟成タンク１５に移して純水を加え５Ｋｉにし、常
温で６日間（１４４時間）放置して熟成する。すると懸
濁液は分離し、−次熟成タンク１５の底に残香１６が沈
殿する。その上澄み液をポンプ１７により二次熟成タン
ク２０へ汲みＬげる。このとき症材が樹脂メツシュの濾
過器１８で混入してくる残査を除去する。二次熟成タン
ク２０には常温で１１日間（２６４時間）放置して熟成
する。すると二次熟成タンク２０の内壁には第二鉄成分
を含むゲル状物２１が付着する。熟成した液を紙鑓材の
加圧式濾過器２２で濾過して前記のゲル状物を除去し、
完成液タンク２３に移し保存する。Example 1 As shown in FIG. 1, 9. and add 100 kg of raw material soil while stirring. Steam is sent from the boiler 13, the inside of the tank 11 is heated to 80°C, and stirring is continued for 2 to 3 hours to form a suspension. The suspension is transferred to the primary aging tank 15, pure water is added thereto to make it 5 Ki, and the suspension is left at room temperature for 6 days (144 hours) to age. The suspension is then separated, and a residual aroma 16 is precipitated at the bottom of the second aging tank 15. The supernatant liquid is pumped to a secondary aging tank 20 by a pump 17. At this time, the residual material mixed with the diseased material is removed by a resin mesh filter 18. The product is left in the secondary aging tank 20 at room temperature for 11 days (264 hours) to mature. Then, a gel-like material 21 containing a ferric component adheres to the inner wall of the secondary aging tank 20. The aged liquid is filtered with a pressurized filter 22 made of paper paper material to remove the gel-like substance,
The finished liquid is transferred to the tank 23 and stored.
この液（液体消臭剤）を消臭したい区域に適宜散布する
。Spray this liquid (liquid deodorizer) on the area you want to deodorize as appropriate.
実施例２゜
実施例１の製造方法に従うが、−次熟成タンク１５に放
とする時間を４日間（９６時間）に短縮し、他の条件は
同一で液体消臭剤を製造する。Example 2 A liquid deodorizer is manufactured according to the manufacturing method of Example 1, except that the time of leaving it in the secondary aging tank 15 is shortened to 4 days (96 hours), and other conditions are the same.
実施例３゜
同じ〈実施例１製造方法に従うが、二次熟成タンク２０
に放置する時間を８日間（１９２時間）に短縮し、他の
条件は同一で液体消臭剤を製造する。Example 3 Same as Example 1, except that the secondary aging tank 20
A liquid deodorant is produced by shortening the leaving time to 8 days (192 hours) and keeping other conditions the same.
比較例１゜
実施例１の製造方法に従うが、−次熟成タンク１５に放
置する時間を３日間（７２時間）に短縮し、二次熟成タ
ンク１５に放置する時間を７日間（１６８時間）に短縮
し、他の条件は同一で液体消臭剤を製造する。Comparative Example 1 The manufacturing method of Example 1 was followed, but the time left in the secondary ripening tank 15 was shortened to 3 days (72 hours), and the time left in the secondary ripening tank 15 was reduced to 7 days (168 hours). Shorten the process to produce a liquid deodorant under the same conditions.
比較例２゜
実施例１の製造方法に従うが、−次熟成タンク１５に放
置する時間を３日間（７２時間）に短縮し他の条件は同
一で液体消臭剤を製造する。Comparative Example 2 A liquid deodorizer was produced according to the production method of Example 1, except that the time for leaving it in the secondary aging tank 15 was shortened to 3 days (72 hours), and the other conditions were the same.
比較例３゜
実施例１の製造方法に従うが、二次熟成タンク２０に放
置する時間を７日間（１６８時間）に短縮し他の条件は
同一で液体消臭剤を製造する。Comparative Example 3 A liquid deodorizer is produced according to the production method of Example 1, except that the time of leaving it in the secondary aging tank 20 is shortened to 7 days (168 hours), and other conditions are the same.
上記実施例１〜実施例３、比較例１〜比較例３で得られ
た液体消臭剤および市阪品の液体消臭剤（植物抽出物）
をガラス瓶に入れ、アンモニア（１００ＦＰＭ）、硫化
水素（２００ＦＰＭ）、エチルメルカプタン（５０ＰＰ
Ｍ）、スカトール（０，１ＰＰＭ）の蒸気を夫々透過さ
せ、感応試験をした結果が下記第１表に示しである。ま
た、６例の液体消臭剤を製造してから１月経過後の溶液
状態を併記しである。The liquid deodorants obtained in Examples 1 to 3 and Comparative Examples 1 to 3 and Ichisaka's liquid deodorant (plant extract)
into a glass bottle, add ammonia (100 FPM), hydrogen sulfide (200 FPM), and ethyl mercaptan (50 PP).
Table 1 below shows the results of a sensitivity test in which vapors of M) and skatole (0.1 PPM) were permeated. In addition, the state of the solution one month after the six liquid deodorants were manufactured is also shown.
第１表
（以下余白）
上記第１表から解るように、実施例１〜実施例３の液体
消臭剤は、消臭性能が実用上略充分である上、溶液の状
態が安定している。これに対し比較例１〜比較例３の液
体消臭剤は、消臭性能が不充分であるか、溶液の状態が
安定であるという欠点がある。特に比較例３の液体消臭
剤は、消臭性能が充分〒あるにも拘らず、溶液をｌ Ｏ
Ｌ＋程放置しておくと、沈殿物（赤錆色）が現われ、こ
れを散布すると対象物が青色汚染してしまう。Table 1 (blank below) As can be seen from Table 1 above, the liquid deodorants of Examples 1 to 3 have practically sufficient deodorizing performance and are stable in solution state. . On the other hand, the liquid deodorants of Comparative Examples 1 to 3 have drawbacks such as insufficient deodorizing performance or stable solution state. In particular, although the liquid deodorant of Comparative Example 3 has sufficient deodorizing performance, the solution
If left as long as L+, a precipitate (rust red color) will appear, and if this is sprayed, the object will be contaminated with blue color.
以上説明したように、本発明を適用する方法により製造
した液体消臭剤は、消臭剤として優れた土壌を原料とし
てその有効成分を損なうことなく液体化したものであり
、消臭性能が充分あり、溶液の状態も安定している。溶
液中に沈殿物が現われることがないので、スプレィによ
る散布をしてもノズルが詰まってしまうことがなく、ま
た対象物を汚すこともない。As explained above, the liquid deodorant produced by the method to which the present invention is applied is made from soil, which is excellent as a deodorant, and is liquefied without damaging its active ingredients, and has sufficient deodorizing performance. Yes, and the state of the solution is stable. Since no precipitate appears in the solution, the nozzle will not become clogged when sprayed, and the object will not be contaminated.
第１図は本発明を適用する液体消臭剤の製造方法を実施
する装置の構成図である。
１０．原料土壌
１０ 攪拌機
１１、、、 加熱タンク
１５、、、、、−一次熟成タンク
１８−２２．、、、、 ［過器
２０ 、二次熟成タンク
２３ 、、、、、完成液タンクFIG. 1 is a block diagram of an apparatus for carrying out a method for producing a liquid deodorant to which the present invention is applied. 10. Raw material soil 10 Stirrer 11, . . . Heating tank 15, . . . - Primary ripening tank 18-22. ,,,, [filter vessel 20, secondary aging tank 23, finished liquid tank]
Claims (1)
分を含む腐植土を水に混合して得た懸濁液を９６時間以
上放置した後、固体成分を濾別した液をさらに１９２時
間以上放置することを特徴とする液体消臭剤の製造方法
。1. After leaving a suspension obtained by mixing humus containing at least amino acids, humic acid, silicic acid, and metal components with water for at least 96 hours, the liquid after filtering off solid components is left for at least 192 hours. A method for producing a liquid deodorant characterized by:
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61226085A JPH0773655B2 (en) | 1986-09-26 | 1986-09-26 | Liquid deodorant manufacturing method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61226085A JPH0773655B2 (en) | 1986-09-26 | 1986-09-26 | Liquid deodorant manufacturing method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6384618A true JPS6384618A (en) | 1988-04-15 |
| JPH0773655B2 JPH0773655B2 (en) | 1995-08-09 |
Family
ID=16839588
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP61226085A Expired - Fee Related JPH0773655B2 (en) | 1986-09-26 | 1986-09-26 | Liquid deodorant manufacturing method |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0773655B2 (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20010100296A (en) * | 2000-04-11 | 2001-11-14 | 한민수 | Method to manufacture deodorant and that deodorant |
| JP2002126060A (en) * | 2000-10-25 | 2002-05-08 | Enzyme Kk | Odor eliminating and deodorizing liquid for biological humus |
| JP6100411B1 (en) * | 2016-02-02 | 2017-03-22 | Ｗｅｌｌ Ｓｔｏｎｅ 有限会社 | Method for producing deodorant and deodorant |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5032087A (en) * | 1973-07-23 | 1975-03-28 | ||
| JPS61209663A (en) * | 1985-03-13 | 1986-09-17 | エンザイム株式会社 | Deodorant of basic malodor by humus and its production |
-
1986
- 1986-09-26 JP JP61226085A patent/JPH0773655B2/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5032087A (en) * | 1973-07-23 | 1975-03-28 | ||
| JPS61209663A (en) * | 1985-03-13 | 1986-09-17 | エンザイム株式会社 | Deodorant of basic malodor by humus and its production |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20010100296A (en) * | 2000-04-11 | 2001-11-14 | 한민수 | Method to manufacture deodorant and that deodorant |
| JP2002126060A (en) * | 2000-10-25 | 2002-05-08 | Enzyme Kk | Odor eliminating and deodorizing liquid for biological humus |
| JP6100411B1 (en) * | 2016-02-02 | 2017-03-22 | Ｗｅｌｌ Ｓｔｏｎｅ 有限会社 | Method for producing deodorant and deodorant |
| JP2017136153A (en) * | 2016-02-02 | 2017-08-10 | Ｗｅｌｌ Ｓｔｏｎｅ 有限会社 | Production method of deodorant, and deodorant |
| WO2017134948A1 (en) * | 2016-02-02 | 2017-08-10 | Ｗｅｌｌ Ｓｔｏｎｅ 有限会社 | Deodorant production method and deodorant |
| RU2744856C2 (en) * | 2016-02-02 | 2021-03-16 | Велл Стоун Ко. | Deodorant producing method and deodorant |
| US11266595B2 (en) | 2016-02-02 | 2022-03-08 | Well Stone Co. | Deodorant production method and deodorant |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0773655B2 (en) | 1995-08-09 |
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