JPS638304A - Flowering promoter - Google Patents
Flowering promoterInfo
- Publication number
- JPS638304A JPS638304A JP15360886A JP15360886A JPS638304A JP S638304 A JPS638304 A JP S638304A JP 15360886 A JP15360886 A JP 15360886A JP 15360886 A JP15360886 A JP 15360886A JP S638304 A JPS638304 A JP S638304A
- Authority
- JP
- Japan
- Prior art keywords
- formula
- expressed
- flowering
- active ingredient
- plants
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 230000017260 vegetative to reproductive phase transition of meristem Effects 0.000 title claims abstract description 11
- 239000004480 active ingredient Substances 0.000 claims abstract description 7
- LSBYYJMCRRFQRA-UHFFFAOYSA-N 6-chloro-2-n-cyclohexyl-4-n-ethyl-1,3,5-triazine-2,4-diamine Chemical compound CCNC1=NC(Cl)=NC(NC2CCCCC2)=N1 LSBYYJMCRRFQRA-UHFFFAOYSA-N 0.000 claims abstract 3
- 241000196324 Embryophyta Species 0.000 abstract description 12
- 150000001875 compounds Chemical class 0.000 abstract description 11
- QUSNBJAOOMFDIB-UHFFFAOYSA-N Ethylamine Chemical compound CCN QUSNBJAOOMFDIB-UHFFFAOYSA-N 0.000 abstract description 6
- PAFZNILMFXTMIY-UHFFFAOYSA-N cyclohexylamine Chemical compound NC1CCCCC1 PAFZNILMFXTMIY-UHFFFAOYSA-N 0.000 abstract description 4
- 239000000839 emulsion Substances 0.000 abstract description 4
- 239000002904 solvent Substances 0.000 abstract description 4
- 239000002671 adjuvant Substances 0.000 abstract description 2
- MGNCLNQXLYJVJD-UHFFFAOYSA-N cyanuric chloride Chemical compound ClC1=NC(Cl)=NC(Cl)=N1 MGNCLNQXLYJVJD-UHFFFAOYSA-N 0.000 abstract description 2
- 239000004563 wettable powder Substances 0.000 abstract description 2
- 244000145717 Asparagus aphyllus Species 0.000 abstract 1
- 239000000428 dust Substances 0.000 abstract 1
- 230000001747 exhibiting effect Effects 0.000 abstract 1
- 230000001976 improved effect Effects 0.000 abstract 1
- 239000003814 drug Substances 0.000 description 8
- 229940079593 drug Drugs 0.000 description 8
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
- 241000234427 Asparagus Species 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 238000009331 sowing Methods 0.000 description 5
- QPUYECUOLPXSFR-UHFFFAOYSA-N 1-methylnaphthalene Chemical compound C1=CC=C2C(C)=CC=CC2=C1 QPUYECUOLPXSFR-UHFFFAOYSA-N 0.000 description 4
- 235000005340 Asparagus officinalis Nutrition 0.000 description 4
- -1 alcohol sulfate ester salt Chemical class 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 239000000969 carrier Substances 0.000 description 3
- FIDRAVVQGKNYQK-UHFFFAOYSA-N 1,2,3,4-tetrahydrotriazine Chemical compound C1NNNC=C1 FIDRAVVQGKNYQK-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- 150000001346 alkyl aryl ethers Chemical class 0.000 description 2
- MXWJVTOOROXGIU-UHFFFAOYSA-N atrazine Chemical compound CCNC1=NC(Cl)=NC(NC(C)C)=N1 MXWJVTOOROXGIU-UHFFFAOYSA-N 0.000 description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- OVARTBFNCCXQKS-UHFFFAOYSA-N propan-2-one;hydrate Chemical compound O.CC(C)=O OVARTBFNCCXQKS-UHFFFAOYSA-N 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 239000008096 xylene Substances 0.000 description 2
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
- WZZBNLYBHUDSHF-DHLKQENFSA-N 1-[(3s,4s)-4-[8-(2-chloro-4-pyrimidin-2-yloxyphenyl)-7-fluoro-2-methylimidazo[4,5-c]quinolin-1-yl]-3-fluoropiperidin-1-yl]-2-hydroxyethanone Chemical compound CC1=NC2=CN=C3C=C(F)C(C=4C(=CC(OC=5N=CC=CN=5)=CC=4)Cl)=CC3=C2N1[C@H]1CCN(C(=O)CO)C[C@@H]1F WZZBNLYBHUDSHF-DHLKQENFSA-N 0.000 description 1
- PRPINYUDVPFIRX-UHFFFAOYSA-N 1-naphthaleneacetic acid Chemical compound C1=CC=C2C(CC(=O)O)=CC=CC2=C1 PRPINYUDVPFIRX-UHFFFAOYSA-N 0.000 description 1
- UKUVVAMSXXBMRX-UHFFFAOYSA-N 2,4,5-trithia-1,3-diarsabicyclo[1.1.1]pentane Chemical compound S1[As]2S[As]1S2 UKUVVAMSXXBMRX-UHFFFAOYSA-N 0.000 description 1
- 244000215068 Acacia senegal Species 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 229920000084 Gum arabic Polymers 0.000 description 1
- 239000005909 Kieselgur Substances 0.000 description 1
- NWBJYWHLCVSVIJ-UHFFFAOYSA-N N-benzyladenine Chemical compound N=1C=NC=2NC=NC=2C=1NCC1=CC=CC=C1 NWBJYWHLCVSVIJ-UHFFFAOYSA-N 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 239000000205 acacia gum Substances 0.000 description 1
- 235000010489 acacia gum Nutrition 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 238000012271 agricultural production Methods 0.000 description 1
- 239000003905 agrochemical Substances 0.000 description 1
- 150000008055 alkyl aryl sulfonates Chemical class 0.000 description 1
- 150000004996 alkyl benzenes Chemical class 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 235000011116 calcium hydroxide Nutrition 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 239000007810 chemical reaction solvent Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 238000004440 column chromatography Methods 0.000 description 1
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 230000012010 growth Effects 0.000 description 1
- 239000004009 herbicide Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000029553 photosynthesis Effects 0.000 description 1
- 238000010672 photosynthesis Methods 0.000 description 1
- 239000005648 plant growth regulator Substances 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 238000001953 recrystallisation Methods 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 230000020509 sex determination Effects 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 230000004083 survival effect Effects 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 150000003918 triazines Chemical class 0.000 description 1
- 239000010455 vermiculite Substances 0.000 description 1
- 229910052902 vermiculite Inorganic materials 0.000 description 1
- 235000019354 vermiculite Nutrition 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- 150000003722 vitamin derivatives Chemical class 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Description
【発明の詳細な説明】
（産業上の利用分野）
本発明は２−クロロ−生−シクロへキシルアミノ−６−
ニチルアミノーＬ３ｔ５−）リアジン（以下本発明化合
物という）を有効成分として含有すること暑特徴とする
植物の開花の増加及び促進をする薬剤に関するものであ
ろ０（従来の技術）
食用作物の１つであるアスパラガスは、通常雄株の方が
雌株に比べ収量が３割程度高（、また雄株はビタミン含
量が高く、芽の形が良いなど食用に適しており、農業生
産上有益とされている。従来、アスパラガスの生長を促
進させるために植物生長調節剤としてベンジルアデニン
・ナフチル酢酸、アプシジン酸、ジベンリンを配合する
ことが行われているが、アス・ぞラガスの開花を促進さ
せる効果を有する薬剤については知らねていない。また
、アトラジン等１−ラフジン誘導体が除草剤として有効
なことが仰られているが（特公昭３５−９７９９号公報
）、開花促進作用は示さない。DETAILED DESCRIPTION OF THE INVENTION (Industrial Field of Application) The present invention provides 2-chloro-raw-cyclohexylamino-6-
Contains nitylamino-L3t5-) riazine (hereinafter referred to as the compound of the present invention) as an active ingredient and relates to a drug that increases and promotes flowering of plants characterized by heat (prior art) It is one of the edible crops. Male asparagus plants usually have a yield that is about 30% higher than female plants (also, male plants have higher vitamin content and better-shaped buds, making them suitable for eating and are considered beneficial for agricultural production. Conventionally, benzyladenine/naphthyl acetic acid, apsidic acid, and dibenline have been added as plant growth regulators to promote the growth of asparagus; There is no knowledge of the drugs that have this effect.Furthermore, 1-lafuzine derivatives such as atrazine are said to be effective as herbicides (Japanese Patent Publication No. 35-9799), but they do not exhibit a flowering-promoting effect.
（発明が解決しようとする問題点）
アスパラガスの開花期は播種後２〜３年である。従って
上記の雄株選抜のための雌雄判定？その時期まで待たな
ければならなかった。≠ヰ←開花促進作用により、幼植
物段階で雄株を（選抜し・雄株のみを畑に定植すること
ができれば、アスパラガスの増産ないしは増収に結びつ
くものであり、そのような技術の開発が待望されていた
。(Problems to be Solved by the Invention) The flowering period of asparagus is 2 to 3 years after sowing. Therefore, is it sex determination for male plant selection mentioned above? I had to wait until that time. ≠ヰ← If it were possible to select male plants at the seedling stage and plant only the male plants in the field due to their flowering promotion effect, it would lead to increased production or yield of asparagus, and the development of such technology is It was long awaited.
本発明省らは、従来典型的な光合成阻害型の土壌処理剤
として知られている、トリアジン誘導体について鋭意研
究した結果、本発明化合物をアスパラガスの種子に処理
したところ、播種後２５日〜３０日という短期間で高い
花芽形成率に示して雌雄判定が可能となり、更に本体を
枯死させろこともないことを見出し、本発明化合物させ
るに至った。As a result of intensive research on triazine derivatives, which are conventionally known as typical photosynthesis-inhibiting soil treatment agents, the Ministry of the Invention and others found that asparagus seeds were treated with the compound of the present invention, and 25 to 30 days after sowing. It was discovered that the flower bud formation rate was high in a short period of one day, making it possible to determine the sex of the plant, and the plant did not cause the plant to wither and die, leading to the development of the compound of the present invention.
（問題点を解決するための手段）
本発明の開花促進剤は２−クコロー牛−シクロへキジル
アばノー６−ニチルアミノー１．３．５−トリアジンを
有効成分として含有してなる。(Means for Solving the Problems) The flowering promoter of the present invention contains 2-Cucoro-cyclohexylamino-6-nitylamino-1.3.5-triazine as an active ingredient.
本発明化合物は次の反応式に従って製造することができ
る。The compound of the present invention can be produced according to the following reaction formula.
（Ｉ）
塩化シアヌルを適当な溶媒に溶解するが懸濁させ、シク
ロヘキシルアミンおよび塩基を○℃以下〜１０℃位で加
え反応させろり溶媒としてはアセトン−水、アセトン、
メチルエチルケトン、水、アセトニトリル、エーテル、
テトラヒドロフラン、ジオキサン、ジメチルホルムアミ
ド、ジメチルスルホキシド、ベンゼン、トルエン、キシ
レン等が使用出来るが、アセトン−水に懸濁させるのが
好ましい。塩基としては重炭酸ナトリウム、炭酸ナトリ
ウム、炭酸カリウム、水酸化ナトリウム、水酸化力ＩＪ
ウム、トリエチルアミン等を使用する。反応は０℃以下
にて行う。(I) Cyanuric chloride is dissolved or suspended in a suitable solvent, and cyclohexylamine and a base are added and reacted at a temperature of 10°C or less. Examples of solvents include acetone-water, acetone,
Methyl ethyl ketone, water, acetonitrile, ether,
Tetrahydrofuran, dioxane, dimethylformamide, dimethyl sulfoxide, benzene, toluene, xylene, etc. can be used, but suspension in acetone-water is preferable. Bases include sodium bicarbonate, sodium carbonate, potassium carbonate, sodium hydroxide, hydroxide IJ
um, triethylamine, etc. The reaction is carried out at 0°C or lower.
生成した沈殿を情裂もしくは精製することな（エチルア
ミンとの反応に供する。反応溶媒および塩基は前述した
ものを使用し対応する当量のエチルアミンおよび塩基を
室温にて加える。反応は室温乃至８０℃にて行う。終了
後生成した沈澱を口実し再結晶又はカラムクロマトグラ
フィーにて精製を行い本発明で使用するトリアノン誘導
体を得ることができる。本発明の２−クロロ−４−シク
ロへキシルアミノ−６−ニチルアミノー１ｐ ３ｙ ５
トリアジンは融点１２７〜１３０℃である。The generated precipitate is not separated or purified (subject to reaction with ethylamine. The reaction solvent and base used are those mentioned above, and corresponding equivalent amounts of ethylamine and base are added at room temperature. The reaction is carried out at room temperature to 80°C. After completion, the trianone derivative used in the present invention can be obtained by recrystallization or purification by column chromatography using the precipitate formed.2-chloro-4-cyclohexylamino-6- of the present invention. Nithylamino 1p 3y 5
Triazine has a melting point of 127-130°C.
本発明化合物を開花促進剤として使用する場合、化合物
のみ、またはこれに農薬の製剤化に際し一般的に用いら
れる担体、界面活性剤、分散剤、補助剤等を配合して、
水和剤、乳剤または粉剤等の各種型態ＶＣ製剤して種子
又はその他の部所に処理することができる。When the compound of the present invention is used as a flowering promoter, the compound alone or in combination with carriers, surfactants, dispersants, adjuvants, etc. commonly used in the formulation of agricultural chemicals,
Various types of VC preparations such as wettable powders, emulsions, or powders can be applied to seeds or other parts.
＋３１！Ｉ剤化に際して用いられる担体としては、例え
ば、４ルク、ベントナイト、クレー、カオリン、珪藻土
、ホワイトカーボン、バーミキュライト、消石灰、珪砂
、硫安、尿素等の固体担体、ジメチルスルホキシド、イ
ンプロピルアルコール、キシレン、シクロヘキサン、メ
チルナフタレン等の液体祁体等が挙げられる。界面活性
剤および分子Ｖ１．剤としては、例えば、アルコール硫
酸エステル塩、アルキルアリールスルホン酸塩、ＩＪ
クニンスルホン酸塩、ポリオキシエチレングリコールエ
ーテル、ポリオキシエチレンアルキルアリールエーテル
、ポリオキシエチレンンルビタンモノアルキレート等が
挙げられる。補助剤としては、汐１１えば、カルボキン
メチルセルロース、ポリエチレングリコール、アラビア
ゴム等が挙げられる。製剤した薬剤の使用に際しては、
適当な濃度に希釈して浸漬するかまたは直接施用する。+31! Examples of carriers used in forming the I-forming agent include solid carriers such as quartz, bentonite, clay, kaolin, diatomaceous earth, white carbon, vermiculite, slaked lime, silica sand, ammonium sulfate, and urea, dimethyl sulfoxide, inpropyl alcohol, xylene, and cyclohexane. , methylnaphthalene, and the like. Surfactants and Molecules V1. Examples of the agent include alcohol sulfate ester salt, alkylaryl sulfonate, IJ
Examples include Kuninsulfonate, polyoxyethylene glycol ether, polyoxyethylene alkylaryl ether, polyoxyethylene rubitan monoalkylate, and the like. Examples of the auxiliary agent include Shio 11, carboquine methylcellulose, polyethylene glycol, gum arabic, and the like. When using formulated drugs,
Dilute to appropriate concentration and soak or apply directly.
薬剤を施用する場合の有効成分の濃度は０．１〜３００
０ ｐｐｍである。When applying the drug, the concentration of the active ingredient is 0.1-300
0 ppm.
次に、本発明の開花促進剤の実施例を挙げるが、本発明
はこの範囲に限定されるものではない０なお、％は重量
百分率を示Ｔ０
実施例１ （水和剤）
化合物゛１０％、エマルグン８１０（花王石鹸株式会社
登録商標）ｏ、５％、デモールＮ（花王石鹸株式会社登
録商標）０５％、クニライト２０１ （クニεネ工業株
式会社登録商標）２０．０％およびジ−クライトａＡ（
ジ−クライト株式会社登録商ｆｆ１）６９．０％？均一
に混合粉砕して水和剤とした○
実施例２ （乳剤）
化合物 ３０％、シクロへキサノン２０％、ポリオキシ
エチンンアルキルアリールエーテル１１％、アルキルベ
ンゼンスルホン酸カルシウム４％およびメチルナフタレ
ン３５％を均一に溶解して乳剤とした。Next, Examples of the flowering promoter of the present invention will be given, but the present invention is not limited to this range. Note that % indicates weight percentage. , Emalgun 810 (registered trademark of Kao Soap Co., Ltd.) o, 5%, Demol N (registered trademark of Kao Soap Co., Ltd.) 05%, Kunilite 201 (registered trademark of Kuni Ene Industries Co., Ltd.) 20.0%, and Zikrite aA (
Sickle Co., Ltd. registered trader ff1) 69.0%? Uniformly mixed and ground to make a wettable powder Example 2 (Emulsion) Compound 30%, cyclohexanone 20%, polyoxyethyne alkylaryl ether 11%, calcium alkylbenzene sulfonate 4% and methylnaphthalene 35%. It was uniformly dissolved to form an emulsion.
（発明の効果）
次に本発明化合物の奏する効果を試験例をもって説明す
る。(Effects of the Invention) Next, the effects of the compounds of the present invention will be explained using test examples.
試験例Ｉ
ＩＡ） 試験方法
材料としてアスノぞラガス（樗晒砦亡ＩＣ鳳１１ｓＬ、
）Ｍａｒｙ Ｗａｓｈｉｎｇｔｏｎ ５０ｏＷを用いた
０種子を所定濃度の薬剤溶液に浸漬し、２５℃照射条件
下（インキュベータ、３００ルツクス）で１２日間薬剤
処理を行りた０処理後・培養土に移植し、日長１２時間
、２５℃の温室で育成した。花芽形成は播種後２５日目
に測定した。１試験区は２５ないし５０個体とした◇尚
、薬剤溶液は、供試薬剤を００５％のジメチルスルホキ
シドに溶解し、水で希釈して調整した。Test example I
) 0 seeds using Mary Washington 50oW were immersed in a drug solution with a predetermined concentration, and treated with the drug for 12 days under 25°C irradiation conditions (incubator, 300 lux). After the 0 treatment, they were transplanted into culture soil and The cells were grown in a greenhouse at 25°C for 12 hours. Flower bud formation was measured 25 days after sowing. Each test plot had 25 to 50 individuals.◇The drug solution was prepared by dissolving the test drug in 0.05% dimethyl sulfoxide and diluting it with water.
（尋 試験結果
結果を第１表に示す
第１表
花芽は雄花、雌花ともに観察された。対照剤のアトラジ
ンは、播種後１力月目には半数が、２力月目にはすべて
の実生が枯死した。(Test results are shown in Table 1) Flower buds on the first surface were observed in both male and female flowers.Atrazine, the control agent, affected half of the seedlings in the first month after sowing, and all the seedlings in the second month after sowing. has withered and died.
本発明化合物は、高い花芽形成率を示すとともに、高い
生存率が認められた。The compound of the present invention showed a high flower bud formation rate and a high survival rate.
Claims (1)
チルアミノ−１，３，５−トリアジンを有効成分として
含有する植物の開花促進剤(1) Plant flowering promoter containing 2-chloro-4-cyclohexylamino-6-ethylamino-1,3,5-triazine as an active ingredient
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP15360886A JPS638304A (en) | 1986-06-30 | 1986-06-30 | Flowering promoter |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP15360886A JPS638304A (en) | 1986-06-30 | 1986-06-30 | Flowering promoter |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS638304A true JPS638304A (en) | 1988-01-14 |
Family
ID=15566204
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP15360886A Pending JPS638304A (en) | 1986-06-30 | 1986-06-30 | Flowering promoter |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS638304A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH01208553A (en) * | 1988-11-29 | 1989-08-22 | Honda Motor Co Ltd | Piston for internal combustion engine |
| US10342570B2 (en) | 2014-02-03 | 2019-07-09 | Medinol Ltd. | Device for traversing vessel occlusions and method of use |
| US10426923B2 (en) | 2014-02-03 | 2019-10-01 | Medinol Ltd. | Catheter tip assembled with a spring |
| US10850065B2 (en) | 2010-02-09 | 2020-12-01 | Medinol Ltd. | Catheter tip assembled with a spring |
-
1986
- 1986-06-30 JP JP15360886A patent/JPS638304A/en active Pending
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH01208553A (en) * | 1988-11-29 | 1989-08-22 | Honda Motor Co Ltd | Piston for internal combustion engine |
| US10850065B2 (en) | 2010-02-09 | 2020-12-01 | Medinol Ltd. | Catheter tip assembled with a spring |
| US10342570B2 (en) | 2014-02-03 | 2019-07-09 | Medinol Ltd. | Device for traversing vessel occlusions and method of use |
| US10426923B2 (en) | 2014-02-03 | 2019-10-01 | Medinol Ltd. | Catheter tip assembled with a spring |
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