JPS6351978A - Method for applying sol-like synthetic resin material to outer surface of container - Google Patents

Method for applying sol-like synthetic resin material to outer surface of container

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Publication number
JPS6351978A
JPS6351978A JP19654686A JP19654686A JPS6351978A JP S6351978 A JPS6351978 A JP S6351978A JP 19654686 A JP19654686 A JP 19654686A JP 19654686 A JP19654686 A JP 19654686A JP S6351978 A JPS6351978 A JP S6351978A
Authority
JP
Japan
Prior art keywords
container
sol
synthetic resin
compound
compound material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP19654686A
Other languages
Japanese (ja)
Inventor
Toshimitsu Koba
古場 敏光
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
NATL CROWN KK
Original Assignee
NATL CROWN KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by NATL CROWN KK filed Critical NATL CROWN KK
Priority to JP19654686A priority Critical patent/JPS6351978A/en
Publication of JPS6351978A publication Critical patent/JPS6351978A/en
Pending legal-status Critical Current

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Abstract

PURPOSE:To form a film having a two-layered structure and a smooth uniform thickness, by preliminarily providing a sol-like synthetic resin compound material having a predetermined shape and thickness and gelling the compound material by heating the opposite surface to apply the same to the outer surface of the container. CONSTITUTION:A sol-like synthetic resin compound 2 composed of a vinyl chloride resin is provided on a flat plate 1 having a smooth surface so that the compound 2 is made slightly wider than the area corresponding to the range to be coated of the outer surface of a container 3 to be coated in the longitudinal direction and the thicknesses of both ends of the widened part are reduced. Succeedingly, the flat plate 1 is heated by the heating member 4 arranged thereunder to gel the compound 2 at the part in the vicinity of the flat plate 1 to form a two-layered structure consisting of a gel like part 2a and a sol like part 2b. Next, the outer surface of the container is contacted with one side of the sol like part 2b and, for example, by rotating the container 3 so as to move the contact surface, the compound 2 is uniformly applied to the container 3 without generating liquid sagging.

Description

【発明の詳細な説明】 童呈上至且丹圀団 本発明は、ビンや罐等の容器の外面に、破ti防止や保
冷、保温のために合成樹脂膜を形成すべく、ゾル状の合
成樹脂材を塗布するための方法に関する。
[Detailed Description of the Invention] The present invention uses a sol-like resin film to form a synthetic resin film on the outer surface of containers such as bottles and cans for the purpose of preventing rupture, keeping cool, and keeping warm. The present invention relates to a method for applying synthetic resin materials.

逢】迂すえ梃 従来、ビンや罐等の容器の外面に、ゾル状の合成}M脂
材を塗布するには、ハケ等を用いて人手により塗布した
り、第6図に示したように、ゾル状の合成樹脂材10中
に、回転自在なロールl1の一部を浸し、このロール1
1に同じく回転自在なロールl2を対接する一方、容器
l3を回転自在に支持して前記ロールl2に対接させる
ことにより、前記各ロール11.12を回転させてその
円面にゾル状の合成n1脂材lOを導いたうえ、前記容
器13を回転させて、前記ロールl2の周面に導かれた
ゾル状の合成樹脂材10を前記容器13の外周面に塗布
していたものである。
Conventionally, in order to apply a sol-like synthetic M resin material to the outer surface of containers such as bottles and cans, it was applied manually using a brush, etc., or as shown in Figure 6. , a part of the rotatable roll l1 is immersed in the sol-like synthetic resin material 10, and this roll 1
A similarly rotatable roll l2 is placed in contact with the roll l2, and a container l3 is rotatably supported and brought into contact with the roll l2, whereby each of the rolls 11 and 12 is rotated to form a sol-like compound on its circular surface. In addition to guiding the n1 fat lO, the container 13 was rotated to apply the sol-like synthetic resin material 10 guided to the peripheral surface of the roll l2 onto the outer peripheral surface of the container 13.

nが解決しようとする間ス点 上述した従来例にあっては、人手によるハケ塗りの場合
には、作業効率が劣るとともに、塗布面をムラなく均一
に仕上げるにはgキ練を要するという欠点があり、また
、ロールによる場合には、塗布厚を所望厚に設定するこ
とが困ス1であるとともに、容器外面における塗り始め
部分と塗り終わり部分とを正確に一敗させることが田賢
董で、前記画部分が重なってしまい、この部分が厚くな
ってしまうという欠点がある。
The disadvantage of the above-mentioned conventional method is that the work efficiency is poor when painting by hand with a brush, and that it requires hard work to finish the coated surface evenly and uniformly. In addition, when using a roll, it is difficult to set the coating thickness to the desired thickness, and it is difficult to accurately set the coating start and finish areas on the outer surface of the container. However, there is a drawback that the image portions overlap and this portion becomes thick.

本発明は、これらの欠点を解消した、ビンや罐等の容器
の外面にゾル状の合成樹脂材を塗布するための方法に関
する。
The present invention relates to a method for applying a sol-like synthetic resin material to the outer surface of containers such as bottles and cans, which eliminates these drawbacks.

問題点を解ンするための手 平面等の面上に、ゾル状態にある塩化ビニル等の合成樹
脂のコンパウンド材を、ビンや罐等の容器外面の塗布す
べき範囲に対応した広さに、場合によっては長手方向に
若干広くしたうえ、この広くした部分の少なくとも一端
部分の厚みを薄くし、他の部分は塗布すべき厚みとなる
ようして、加熱等により面を熱変化させることにより、
面に近い部分はゲル化しその上方はゾル状態にある2層
状態にした後、ゾル状態にあるコンパウンド材上面に前
記容器の外面を当接させて、当接面が移行するよう前記
容器と前記コンパウンド材を設けた面とを相対的に変位
させ、例えば前記容器を回転させて前記容器外面の所望
範囲にni記コンパウンドキオを塗布するものである.
そして、前述の2層状部にするには、一旦面上に塗布す
べき厚みよりも薄く塗布したゾル状態にある塩化ビニル
等の合成樹脂のコンパウンド材をゲル化した後、その上
にゾル状態にある塩化ビニル等の合成樹脂のコンパウン
ド材を重ねて設ける方法によってもよいものである。
To solve the problem, apply a compound material of synthetic resin such as vinyl chloride in sol state on the surface of your hand or other surface in an area corresponding to the area to be applied on the outer surface of containers such as bottles and cans. In some cases, it may be made slightly wider in the longitudinal direction, and the thickness of at least one end of this widened part is made thinner, and the other parts are made to have the desired thickness, and the surface is thermally changed by heating, etc.
After creating a two-layer state in which the part near the surface is gelled and the upper part is in a sol state, the outer surface of the container is brought into contact with the upper surface of the compound material in a sol state, and the container and the container are brought into contact with each other so that the contact surfaces are transferred. The compound material is applied to a desired range of the outer surface of the container by displacing the surface provided with the compound material, for example, by rotating the container.
In order to form the two-layered part mentioned above, a synthetic resin compound material such as vinyl chloride, which is in a sol state and applied thinner than the thickness that should be applied on the surface, is first gelled, and then a sol state is applied on top of it. A method of layering compound materials of synthetic resin such as vinyl chloride may also be used.

作   用 面上に、容器の外面に塗布すべき範囲及び厚さに、その
上面部分がゾル状の合成樹脂のコンパウンド材を設けて
、これを容器外面に塗布するので、塗布作業の自動化が
可能となり、また、塗布厚を所望厚に設定することが容
易であるとともに、容器外面における塗り始め部分と塗
り終わり部分とを正確に一敗させることが可能であり、
しかも塗布時におけるコンパウンド材の外側部分はゲル
化してあるので、タレることがなく均一かつ平滑に塗布
可能である。
A sol-like synthetic resin compound material is placed on the working surface in the area and thickness that should be applied to the outer surface of the container, and this is applied to the outer surface of the container, making it possible to automate the application work. In addition, it is easy to set the coating thickness to a desired thickness, and it is also possible to accurately set the coating start and finish portions on the outer surface of the container.
Moreover, since the outer portion of the compound material is gelled during application, it can be applied uniformly and smoothly without dripping.

去一止一闇 以下、本発明の好適な実施例を添付図面の第1図乃至第
5図に基づいて詳細に説明する。
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS Preferred embodiments of the present invention will now be described in detail with reference to FIGS. 1 to 5 of the accompanying drawings.

第1図及び第2図に示したように、表面が滑らかな子板
1で構成される平面上に、ゾル状の塩化ビニルコンパウ
ンド2を、塗布対象である容器3外面の塗布すべき範囲
に対応した広さより、長手方向(第1図上左右方向)に
おいて若干広く、かつ、この広くした両端部分の厚みを
1<シたうえ、他の部分は塗布すべき厚みとなるよう設
ける。
As shown in FIGS. 1 and 2, a sol-like vinyl chloride compound 2 is applied to the area to be coated on the outer surface of the container 3 on a flat surface made up of a child plate 1 with a smooth surface. It is slightly wider in the longitudinal direction (in the left-right direction in FIG. 1) than the corresponding width, and the thickness at both end portions of the widened portion is less than 1, and the other portions are provided so as to have the thickness to be coated.

このように設けるには、例えば、塗布すべき範囲に対応
した広さの内法を有する枠(図示せず)内に、ゾル状の
塩化ビニルコンパウンド2を塗布すべき厚み分だけ均一
に流し込み、前記枠を除去した後、長手方向の両端部分
をロール(図示せず)等で伸展して薄くすればよい、ま
た、ゾル状の塩化ビニルコンパウンド2は、ゾル状の塩
化ビニルに、可塑剤を加えたもので、必要に応じてさら
に、発泡剤、安定剤、色剤、充填剤等を加えて形成する
To provide this, for example, the sol-like vinyl chloride compound 2 is poured uniformly to the thickness to be coated into a frame (not shown) having an inner diameter corresponding to the area to be coated. After removing the frame, both ends in the longitudinal direction may be stretched with a roll (not shown) or the like to make it thin.Also, the sol-like vinyl chloride compound 2 can be obtained by adding a plasticizer to the sol-like vinyl chloride. In addition, foaming agents, stabilizers, coloring agents, fillers, etc. may be further added as necessary.

)Aいて、第2図に示したように、平板lをその下方に
配設した加熱部材4によって加熱し、ゾル状の塩化ビニ
ルコンパウンド2における前記平板1近傍部分をゲル化
し、ゲル状部2aとゾル状部2bとの2層構造とする。
) A, as shown in FIG. 2, the flat plate 1 is heated by the heating member 4 disposed below it, and the portion of the sol-like vinyl chloride compound 2 near the flat plate 1 is gelled, forming a gel-like part 2a. It has a two-layer structure including the sol-like portion 2b and the sol-like portion 2b.

このように、塩化ビニルコンパウンド2を2層構造とし
た後、塗布対象である有底円筒状の容器3を、平板1上
に、2層状の塩化ビニルコンパウンド2の一側端とその
軸線が平行になるよう!1’する。そして、第3図に示
したように、n:j記容器3を回転させつつnij記塩
化ビニルコンパウンド2のゾル状部2b上をその他端方
向に向けて移動させると、前記容器3の外周面に、前記
2rr!I状の塩化ビニルコンパウンド2が巻き取られ
るようにして塗布される。このとき、塩化ビニルコンパ
ウンド2の外側部分はゲル状部2aとなっているので、
ゾル状部2bは前記ゲル状部2aに保持されて、塗布時
にフレることがなく、第4図に示したように、均一のI
!7さて塗布される。また、塩化ビニルコンパウンド2
0両端部分は薄く形成されているから、これらの部分が
重なりあっても塗布厚が厚くなることはなり、fi:i
述の均一性は全周にわたって確保できる(第5図参照)
After forming the vinyl chloride compound 2 into a two-layer structure in this way, the bottomed cylindrical container 3 to be coated is placed on the flat plate 1 so that one end of the two-layer vinyl chloride compound 2 and its axis are parallel to each other. Let's become! 1' do. As shown in FIG. 3, when the n:j container 3 is rotated and moved over the sol portion 2b of the nij vinyl chloride compound 2 toward the other end, the outer peripheral surface of the container 3 To, said 2rr! The I-shaped vinyl chloride compound 2 is applied in a rolled-up manner. At this time, since the outer part of the vinyl chloride compound 2 is a gel-like part 2a,
The sol-like part 2b is held by the gel-like part 2a and does not sag during application, and as shown in FIG.
! 7 Now it is applied. In addition, vinyl chloride compound 2
0 Both end portions are formed thinly, so even if these portions overlap, the coating thickness will not increase, and fi:i
The uniformity described above can be ensured over the entire circumference (see Figure 5).
.

以上のようにして容器3の外面に塗布された塩化ビニル
コンパウンド2のゾル状部2b(第41に参照)は、容
器3の内側から高周波加熱等の手段により加熱されるこ
とによりゲル化され、第5図に示したように、前記塩化
ビニルコンパウンド2は全体がゲル状態となって皮膜と
なり、また、必要に応じてゲル化と同時に発泡されるも
のである。
The sol-like portion 2b (see No. 41) of the vinyl chloride compound 2 applied to the outer surface of the container 3 as described above is heated from the inside of the container 3 by means such as high-frequency heating, and thereby gelled. As shown in FIG. 5, the vinyl chloride compound 2 is entirely in a gel state to form a film, and is foamed simultaneously with gelation, if necessary.

また、塩化ビニルコンパウンド2を2層構造にする(第
2図参照)には、上述の如く面1上に所定厚みに設けた
うえ、前記面1を加熱してその近傍部分をゲル化する方
法のほか、所定Jgみよりも薄くゾル状の塩化ビニルコ
ンパウンド2を面1上に設けて、前記面1を加熱するこ
とによりゾル状の塩化ビニルコンパウンド2をゲル化し
、この上にさらにゾル状の塩化ビニルコンパウンド2を
所定)γみとなるよう重ねる方法によることもできる。
In addition, in order to form the vinyl chloride compound 2 into a two-layer structure (see Fig. 2), it is possible to provide the vinyl chloride compound 2 to a predetermined thickness on the surface 1 as described above, and then heat the surface 1 to gel the vicinity thereof. In addition, a sol-like vinyl chloride compound 2 thinner than a predetermined Jg is provided on the surface 1, the sol-like vinyl chloride compound 2 is gelled by heating the surface 1, and a sol-like vinyl chloride compound 2 is further applied on top of this. It is also possible to use a method in which the vinyl chloride compound 2 is layered so as to have a predetermined γ-shape.

なお、本発明は上述した各実施例に限定されるものでは
なく、例えば、合成樹脂は塩化ビニルに限られず、また
、面上に設けるゾル状の合成樹脂コンパウンドはその両
端部を必ず薄<シなければならないものではなく、さら
に、面は平面に限らない等、多くの改変を施すことが可
能である。
Note that the present invention is not limited to the above-mentioned embodiments; for example, the synthetic resin is not limited to vinyl chloride, and the sol-like synthetic resin compound provided on the surface must be made thin at both ends. Further, the surface is not limited to a flat surface, and many modifications can be made.

効   果 以上説明したところで明らかなように、本発明によれば
、次のような諸効果を挙げることができる。
Effects As is clear from the above explanation, according to the present invention, the following effects can be achieved.

第1に、容器に塗布するゾル状の合成樹脂コンパウンド
の範囲及び厚みの設定が容易であり、所望の範囲及び厚
さに均一に塗布することができる。
First, it is easy to set the range and thickness of the sol-like synthetic resin compound to be applied to the container, and the desired range and thickness can be uniformly applied.

第2に、ゾル状の合成樹脂コンパウンドをあらかしめ面
上に設けておくので、塗布表面を平滑に形成できる。
Second, since the sol-like synthetic resin compound is provided on the textured surface, the coating surface can be formed smoothly.

第3に、ゾル状の合成樹脂コンパウンドをあらかじめ設
けておく面上に、池のシートを敷設しておけば、このシ
ートによって、塗布後に形成する皮膜を補強することが
でき、また、印刷シートを用いれば容器の外面に容易に
印刷部を設けることができる。
Thirdly, if a sheet of water is laid down on the surface on which the sol-like synthetic resin compound has been applied in advance, this sheet can reinforce the film that will be formed after application. If used, a printed portion can be easily provided on the outer surface of the container.

第4に、容器に塗布する簡に、ゾル状の合成樹脂コンパ
ウンドを2層構造として、塗布時に外側に位置する部分
をゲル状化しておくので、合成樹脂コンパウンドが塗布
時にダレることがなく、均一かつ平滑に塗布することが
できる。
Fourthly, since the sol-like synthetic resin compound is easily applied to the container and has a two-layer structure, and the outer part is turned into a gel during application, the synthetic resin compound does not sag during application. Can be applied evenly and smoothly.

【図面の簡単な説明】[Brief explanation of drawings]

第1図は本発明の好適な実施例におけるゾル状合成樹脂
コンパウンドを平面上に設けた状態の平面図、第2図は
同じく合成樹脂コンパウンドを2層III造にした状態
の側面図、第3図は同じく塗布動作を示す側面図、第4
図は同じく塗布後の状態を示す容器の断面図、第5図は
同じく塗布後の皮膜化した状態を示す容器の平面図、第
6図は従来例を示す側面図である。 1・・・平Fi   2・・・塩化ビニルコンパウンド
   2a・・・ゲル状部   2b・・・ゾル状部 
  3・・・容器   4・・・加熱部材 第1図
FIG. 1 is a plan view of a preferred embodiment of the present invention in which a sol-like synthetic resin compound is provided on a flat surface, FIG. 2 is a side view of a two-layer structure made of synthetic resin compound, and FIG. The figure is also a side view showing the coating operation.
The figure is a cross-sectional view of the container similarly showing the state after application, FIG. 5 is a plan view of the container showing the state in which a film has been formed after application, and FIG. 6 is a side view showing a conventional example. 1... Flat Fi 2... Vinyl chloride compound 2a... Gel-like part 2b... Sol-like part
3... Container 4... Heating member Fig. 1

Claims (8)

【特許請求の範囲】[Claims] (1)面上に、ゾル状態にある合成樹脂のコンパウンド
材を、容器外面の塗布すべき範囲に対応した広さに、か
つ塗布すべき厚みとなるよう配設し、前記面を熱変化さ
せて配設したコンパウンド材の前記面近傍部分をゲル化
したうえ、ゾル状態にあるコンパウンド材上面に前記容
器の外面を当接させて、当接面が移行するよう前記容器
と前記コンパウンド材を設けた面とを相対的に変位させ
ることにより、容器外面の所望範囲に前記コンパウンド
材を塗布することを特徴とする容器外面に対するゾル状
合成樹脂材の塗布方法。
(1) A synthetic resin compound material in a sol state is placed on the surface so that it has a width corresponding to the area to be coated on the outer surface of the container and a thickness to be coated, and the surface is thermally changed. A portion of the compound material disposed in the vicinity of the surface is gelled, and the outer surface of the container is brought into contact with the upper surface of the compound material in a sol state, and the container and the compound material are provided so that the abutting surface moves. A method for applying a sol-like synthetic resin material to an outer surface of a container, characterized in that the compound material is applied to a desired range of the outer surface of the container by displacing the compound material relative to the outer surface of the container.
(2)合成樹脂は、塩化ビニルであることを特徴とする
前記特許請求の範囲第1項記載の容器外面に対するゾル
状合成樹脂材の塗布方法。
(2) The method for applying a sol-like synthetic resin material to the outer surface of a container according to claim 1, wherein the synthetic resin is vinyl chloride.
(3)面は、平面であることを特徴とする前記特許請求
の範囲第1項記載の容器外面に対するゾル状合成樹脂材
の塗布方法。
(3) A method for applying a sol-like synthetic resin material to an outer surface of a container according to claim 1, wherein the surface is a flat surface.
(4)面上のコンパウンド材は、容器外面の塗布すべき
範囲に対応した広さより若干広く設定されるとともに、
少なくとも一端部の厚みを薄くして設けられたことを特
徴とする前記特許請求の範囲第1項記載の容器外面に対
するゾル状合成樹脂材の塗布方法。
(4) The compound material on the surface is set slightly wider than the area corresponding to the area to be applied on the outer surface of the container, and
A method for applying a sol-like synthetic resin material to an outer surface of a container according to claim 1, wherein the thickness of at least one end portion is reduced.
(5)面上に、ゾル状態にある合成樹脂のコンパウンド
材を、容器外面の塗布すべき範囲に対応した広さに、か
つ塗布すべき厚みよりは薄く配設し、前記面を熱変化さ
せて配設したコンパウンド材をゲル化したうえ、この上
にゾル状態にある合成樹脂のコンパウンド材を容器外面
に塗布すべき厚みとなるよう重ねて配設し、この重ねた
コンパウンド材の上面に前記容器の外面を当接させて、
当接面が移行するよう前記容器と前記コンパウンド材を
設けた面とを相対的に変位させることにより、容器外面
の所望範囲に前記コンパウンド材を塗布することを特徴
とする容器外面に対するゾル状合成樹脂材の塗布方法。
(5) A synthetic resin compound material in a sol state is placed on the surface in a width corresponding to the area to be coated on the outer surface of the container, but thinner than the thickness to be coated, and the surface is thermally changed. After gelling the compound material placed on the container, a synthetic resin compound material in a sol state is layered on top of the compound material to a thickness that should be applied to the outer surface of the container. Touch the outer surface of the container,
Sol-form synthesis on the outer surface of a container, characterized in that the compound material is applied to a desired range of the outer surface of the container by relatively displacing the container and the surface on which the compound material is provided so that the contact surfaces shift. How to apply resin material.
(6)合成樹脂は、塩化ビニルであることを特徴とする
前記特許請求の範囲第5項記載の容器外面に対するゾル
状合成樹脂材の塗布方法。
(6) The method for applying a sol-like synthetic resin material to the outer surface of a container according to claim 5, wherein the synthetic resin is vinyl chloride.
(7)面は、平面であることを特徴とする前記特許請求
の範囲第5項記載の容器外面に対するゾル状合成樹脂材
の塗布方法。
(7) A method for applying a sol-like synthetic resin material to an outer surface of a container according to claim 5, wherein the surface is a flat surface.
(8)面上のコンパウンド材は、容器外面の塗布すべき
範囲に対応した広さより若干広く設定されるとともに、
少なくとも一端部の厚みを薄くして設けられたことを特
徴とする前記特許請求の範囲第5項記載の容器外面に対
するゾル状合成樹脂材の塗布方法。
(8) The compound material on the surface is set slightly wider than the area corresponding to the area to be applied on the outer surface of the container, and
6. A method of applying a sol-like synthetic resin material to an outer surface of a container according to claim 5, wherein the thickness of at least one end portion is reduced.
JP19654686A 1986-08-21 1986-08-21 Method for applying sol-like synthetic resin material to outer surface of container Pending JPS6351978A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP19654686A JPS6351978A (en) 1986-08-21 1986-08-21 Method for applying sol-like synthetic resin material to outer surface of container

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP19654686A JPS6351978A (en) 1986-08-21 1986-08-21 Method for applying sol-like synthetic resin material to outer surface of container

Publications (1)

Publication Number Publication Date
JPS6351978A true JPS6351978A (en) 1988-03-05

Family

ID=16359539

Family Applications (1)

Application Number Title Priority Date Filing Date
JP19654686A Pending JPS6351978A (en) 1986-08-21 1986-08-21 Method for applying sol-like synthetic resin material to outer surface of container

Country Status (1)

Country Link
JP (1) JPS6351978A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS62502042A (en) * 1985-06-21 1987-08-13 ヒユ−ズ・エアクラフト・カンパニ− Reactive atmosphere treatment method for heavy metal fluoride glass
JPH03107890A (en) * 1989-09-22 1991-05-08 Dainippon Ink & Chem Inc Marking film for neon sign board

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS62502042A (en) * 1985-06-21 1987-08-13 ヒユ−ズ・エアクラフト・カンパニ− Reactive atmosphere treatment method for heavy metal fluoride glass
JPH0510286B2 (en) * 1985-06-21 1993-02-09 Hughes Aircraft Co
JPH03107890A (en) * 1989-09-22 1991-05-08 Dainippon Ink & Chem Inc Marking film for neon sign board

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